TY  - JOUR
AU  - Đorđević, Biljana S.
AU  - Kostić, Milan
AU  - Todorović, Zoran
AU  - Stamenković, Olivera
AU  - Veselinović, Ljiljana
AU  - Veljković, Vlada
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15142
AB  - The application of triethanolamine (TEOA)-based deep eutectic solvents (DESs) with glycerol (G), propylene glycol (PEG), 1,3-dimethylurea (DMU), ethylene glycol (EG), menthol (M), oleic acid (OLA), decanoic acid (DEA), and choline chloride (ChCl) (1:1, 1:2 or 2:1 mol/mol) in the CaO-catalyzed black mustard seed oil (BMSO) ethanolysis was studied. The ethanolysis was performed at 70 ºC, 12:1 ethanol-to-oil molar ratio, 20% DES, and 10% CaO (to BMSO). It was accelerated by the DESs with G, PEG, ChCl, DMU, M, and DEA and resulted in a higher fatty acid ethyl ester (FAEE) content (≥95.2 ± 0.6%) in 15 min than the control reaction. The TEOA:ChCl DES was most effective, providing within only 1.5 min an FAEE content of about 98.5%. With the TEOA:M and TEOA:PEG DESs, the FAEE content of over 91% was achieved for this time. Furthermore, the final product separation was achieved faster with all the applied DES than in the control reaction. With the TEOA:M and TEOA:ChCl DESs, separation was achieved immediately after the stopping of mixing and for 1 min, respectively. Two kinetic models were used for modeling the BMSO ethanolysis over CaO assisted by the TEOA:ChCl DES. The CaO reusability in three runs exceeded the FAEE content of 90%.
PB  - Elsevier BV
T2  - Chemical Engineering Research and Design
T1  - Triethanolamine-based deep eutectic solvents as cosolvents in biodiesel production from black mustard (Brassica nigra L.) seed oil
SP  - 526
EP  - 536
VL  - 195
DO  - 10.1016/j.cherd.2023.06.016
UR  - https://hdl.handle.net/21.15107/rcub_dais_15142
ER  - 

@article{
author = "Đorđević, Biljana S. and Kostić, Milan and Todorović, Zoran and Stamenković, Olivera and Veselinović, Ljiljana and Veljković, Vlada",
year = "2023",
abstract = "The application of triethanolamine (TEOA)-based deep eutectic solvents (DESs) with glycerol (G), propylene glycol (PEG), 1,3-dimethylurea (DMU), ethylene glycol (EG), menthol (M), oleic acid (OLA), decanoic acid (DEA), and choline chloride (ChCl) (1:1, 1:2 or 2:1 mol/mol) in the CaO-catalyzed black mustard seed oil (BMSO) ethanolysis was studied. The ethanolysis was performed at 70 ºC, 12:1 ethanol-to-oil molar ratio, 20% DES, and 10% CaO (to BMSO). It was accelerated by the DESs with G, PEG, ChCl, DMU, M, and DEA and resulted in a higher fatty acid ethyl ester (FAEE) content (≥95.2 ± 0.6%) in 15 min than the control reaction. The TEOA:ChCl DES was most effective, providing within only 1.5 min an FAEE content of about 98.5%. With the TEOA:M and TEOA:PEG DESs, the FAEE content of over 91% was achieved for this time. Furthermore, the final product separation was achieved faster with all the applied DES than in the control reaction. With the TEOA:M and TEOA:ChCl DESs, separation was achieved immediately after the stopping of mixing and for 1 min, respectively. Two kinetic models were used for modeling the BMSO ethanolysis over CaO assisted by the TEOA:ChCl DES. The CaO reusability in three runs exceeded the FAEE content of 90%.",
publisher = "Elsevier BV",
journal = "Chemical Engineering Research and Design",
title = "Triethanolamine-based deep eutectic solvents as cosolvents in biodiesel production from black mustard (Brassica nigra L.) seed oil",
pages = "526-536",
volume = "195",
doi = "10.1016/j.cherd.2023.06.016",
url = "https://hdl.handle.net/21.15107/rcub_dais_15142"
}

Đorđević, B. S., Kostić, M., Todorović, Z., Stamenković, O., Veselinović, L.,& Veljković, V.. (2023). Triethanolamine-based deep eutectic solvents as cosolvents in biodiesel production from black mustard (Brassica nigra L.) seed oil. in Chemical Engineering Research and Design
Elsevier BV., 195, 526-536.
https://doi.org/10.1016/j.cherd.2023.06.016
https://hdl.handle.net/21.15107/rcub_dais_15142

Đorđević BS, Kostić M, Todorović Z, Stamenković O, Veselinović L, Veljković V. Triethanolamine-based deep eutectic solvents as cosolvents in biodiesel production from black mustard (Brassica nigra L.) seed oil. in Chemical Engineering Research and Design. 2023;195:526-536.
doi:10.1016/j.cherd.2023.06.016
https://hdl.handle.net/21.15107/rcub_dais_15142 .

Đorđević, Biljana S., Kostić, Milan, Todorović, Zoran, Stamenković, Olivera, Veselinović, Ljiljana, Veljković, Vlada, "Triethanolamine-based deep eutectic solvents as cosolvents in biodiesel production from black mustard (Brassica nigra L.) seed oil" in Chemical Engineering Research and Design, 195 (2023):526-536,
https://doi.org/10.1016/j.cherd.2023.06.016 .,
https://hdl.handle.net/21.15107/rcub_dais_15142 .