Lithium-ion batteries and fuel cells - research and development

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Lithium-ion batteries and fuel cells - research and development (en)
Литијум-јон батерије и горивне ћелије-истраживање и развој (sr)
Litijum-jon baterije i gorivne ćelije-istraživanje i razvoj (sr_RS)
Authors

Publications

Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite

Jovanović, Zoran; Mravik, Željko; Bajuk Bogdanović, Danica; Jovanović, Sonja; Marković, Smilja; Vujković, Milica; Kovač, Janez; Vengust, Damjan; Uskoković-Marković, Snežana; Holclajtner Antunović, Ivanka

(2020)

TY  - JOUR
AU  - Jovanović, Zoran
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Jovanović, Sonja
AU  - Marković, Smilja
AU  - Vujković, Milica
AU  - Kovač, Janez
AU  - Vengust, Damjan
AU  - Uskoković-Marković, Snežana
AU  - Holclajtner Antunović, Ivanka
PY  - 2020
UR  - http://dais.sanu.ac.rs/123456789/6882
AB  - In the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.
T2  - Carbon
T1  - Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite
SP  - 166
EP  - 178
VL  - 156
DO  - 10.1016/j.carbon.2019.09.072
UR  - https://hdl.handle.net/21.15107/rcub_dais_6882
ER  - 
@article{
author = "Jovanović, Zoran and Mravik, Željko and Bajuk Bogdanović, Danica and Jovanović, Sonja and Marković, Smilja and Vujković, Milica and Kovač, Janez and Vengust, Damjan and Uskoković-Marković, Snežana and Holclajtner Antunović, Ivanka",
year = "2020",
abstract = "In the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.",
journal = "Carbon",
title = "Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite",
pages = "166-178",
volume = "156",
doi = "10.1016/j.carbon.2019.09.072",
url = "https://hdl.handle.net/21.15107/rcub_dais_6882"
}
Jovanović, Z., Mravik, Ž., Bajuk Bogdanović, D., Jovanović, S., Marković, S., Vujković, M., Kovač, J., Vengust, D., Uskoković-Marković, S.,& Holclajtner Antunović, I.. (2020). Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite. in Carbon, 156, 166-178.
https://doi.org/10.1016/j.carbon.2019.09.072
https://hdl.handle.net/21.15107/rcub_dais_6882
Jovanović Z, Mravik Ž, Bajuk Bogdanović D, Jovanović S, Marković S, Vujković M, Kovač J, Vengust D, Uskoković-Marković S, Holclajtner Antunović I. Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite. in Carbon. 2020;156:166-178.
doi:10.1016/j.carbon.2019.09.072
https://hdl.handle.net/21.15107/rcub_dais_6882 .
Jovanović, Zoran, Mravik, Željko, Bajuk Bogdanović, Danica, Jovanović, Sonja, Marković, Smilja, Vujković, Milica, Kovač, Janez, Vengust, Damjan, Uskoković-Marković, Snežana, Holclajtner Antunović, Ivanka, "Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite" in Carbon, 156 (2020):166-178,
https://doi.org/10.1016/j.carbon.2019.09.072 .,
https://hdl.handle.net/21.15107/rcub_dais_6882 .
5
3
5

Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing

Nikolić, Maria Vesna; Krstić, Jugoslav; Labus, Nebojša; Luković, Miloljub; Dojčinović, Milena; Radovanović, Milan; Tadić, Nenad

(Elsevier, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Krstić, Jugoslav
AU  - Labus, Nebojša
AU  - Luković, Miloljub
AU  - Dojčinović, Milena
AU  - Radovanović, Milan
AU  - Tadić, Nenad
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10036
AB  - Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.
PB  - Elsevier
T2  - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
T1  - Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing
SP  - 114547
VL  - 257
DO  - 10.1016/j.mseb.2020.114547
UR  - https://hdl.handle.net/21.15107/rcub_dais_10036
ER  - 
@article{
author = "Nikolić, Maria Vesna and Krstić, Jugoslav and Labus, Nebojša and Luković, Miloljub and Dojčinović, Milena and Radovanović, Milan and Tadić, Nenad",
year = "2020",
abstract = "Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.",
publisher = "Elsevier",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
title = "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing",
pages = "114547",
volume = "257",
doi = "10.1016/j.mseb.2020.114547",
url = "https://hdl.handle.net/21.15107/rcub_dais_10036"
}
Nikolić, M. V., Krstić, J., Labus, N., Luković, M., Dojčinović, M., Radovanović, M.,& Tadić, N.. (2020). Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Elsevier., 257, 114547.
https://doi.org/10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_10036
Nikolić MV, Krstić J, Labus N, Luković M, Dojčinović M, Radovanović M, Tadić N. Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020;257:114547.
doi:10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_10036 .
Nikolić, Maria Vesna, Krstić, Jugoslav, Labus, Nebojša, Luković, Miloljub, Dojčinović, Milena, Radovanović, Milan, Tadić, Nenad, "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing" in Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 257 (2020):114547,
https://doi.org/10.1016/j.mseb.2020.114547 .,
https://hdl.handle.net/21.15107/rcub_dais_10036 .
2
2
1

Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing

Nikolić, Maria Vesna; Krstić, Jugoslav; Labus, Nebojša; Luković, Miloljub; Dojčinović, Milena; Radovanović, Milan; Tadić, Nenad

(Elsevier, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Krstić, Jugoslav
AU  - Labus, Nebojša
AU  - Luković, Miloljub
AU  - Dojčinović, Milena
AU  - Radovanović, Milan
AU  - Tadić, Nenad
PY  - 2020
UR  - http://dais.sanu.ac.rs/123456789/8950
AB  - Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.
PB  - Elsevier
T2  - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
T1  - Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing
SP  - 114547
VL  - 257
DO  - 10.1016/j.mseb.2020.114547
UR  - https://hdl.handle.net/21.15107/rcub_dais_8950
ER  - 
@article{
author = "Nikolić, Maria Vesna and Krstić, Jugoslav and Labus, Nebojša and Luković, Miloljub and Dojčinović, Milena and Radovanović, Milan and Tadić, Nenad",
year = "2020",
abstract = "Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.",
publisher = "Elsevier",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
title = "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing",
pages = "114547",
volume = "257",
doi = "10.1016/j.mseb.2020.114547",
url = "https://hdl.handle.net/21.15107/rcub_dais_8950"
}
Nikolić, M. V., Krstić, J., Labus, N., Luković, M., Dojčinović, M., Radovanović, M.,& Tadić, N.. (2020). Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Elsevier., 257, 114547.
https://doi.org/10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_8950
Nikolić MV, Krstić J, Labus N, Luković M, Dojčinović M, Radovanović M, Tadić N. Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020;257:114547.
doi:10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_8950 .
Nikolić, Maria Vesna, Krstić, Jugoslav, Labus, Nebojša, Luković, Miloljub, Dojčinović, Milena, Radovanović, Milan, Tadić, Nenad, "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing" in Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 257 (2020):114547,
https://doi.org/10.1016/j.mseb.2020.114547 .,
https://hdl.handle.net/21.15107/rcub_dais_8950 .
2
2
1

Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Labus, Nebojša

(IEEE, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Labus, Nebojša
PY  - 2020
UR  - http://dais.sanu.ac.rs/123456789/7450
AB  - Nanocomposite Zn2SnO4/SnO2 powder was
obtained by solid state synthesis from homogenized
starting nanopowders of ZnO and SnO2, mixed in the 1:1
molar ratio, structurally and morphologically characterized
using X-ray diffraction (XRD) and Scanning Electron
Microscopy (SEM). Thick film paste was made by adding
organic vehicles to the obtained powder. Three to five
layers (layer thickness approx. 12 µm) were screen printed
on alumina substrate with small test PdAg electrodes and
fired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.
Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where the
relative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overall
sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from
6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and
90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for
application in humidity sensing.
PB  - IEEE
T2  - IEEE Sensors Journal
T1  - Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material
SP  - 7509
EP  - 7516
VL  - 20
IS  - 14
DO  - 10.1109/JSEN.2020.2983135
UR  - https://hdl.handle.net/21.15107/rcub_dais_7450
ER  - 
@article{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Labus, Nebojša",
year = "2020",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder was
obtained by solid state synthesis from homogenized
starting nanopowders of ZnO and SnO2, mixed in the 1:1
molar ratio, structurally and morphologically characterized
using X-ray diffraction (XRD) and Scanning Electron
Microscopy (SEM). Thick film paste was made by adding
organic vehicles to the obtained powder. Three to five
layers (layer thickness approx. 12 µm) were screen printed
on alumina substrate with small test PdAg electrodes and
fired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.
Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where the
relative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overall
sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from
6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and
90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for
application in humidity sensing.",
publisher = "IEEE",
journal = "IEEE Sensors Journal",
title = "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material",
pages = "7509-7516",
volume = "20",
number = "14",
doi = "10.1109/JSEN.2020.2983135",
url = "https://hdl.handle.net/21.15107/rcub_dais_7450"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Ž., Luković, M. D.,& Labus, N.. (2020). Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal
IEEE., 20(14), 7509-7516.
https://doi.org/10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_7450
Nikolić MV, Dojčinović M, Vasiljević ZŽ, Luković MD, Labus N. Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal. 2020;20(14):7509-7516.
doi:10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_7450 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Ž., Luković, Miloljub D., Labus, Nebojša, "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material" in IEEE Sensors Journal, 20, no. 14 (2020):7509-7516,
https://doi.org/10.1109/JSEN.2020.2983135 .,
https://hdl.handle.net/21.15107/rcub_dais_7450 .
5
3
4

Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Labus, Nebojša

(IEEE, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Labus, Nebojša
PY  - 2020
UR  - http://dais.sanu.ac.rs/123456789/8942
AB  - Nanocomposite Zn2SnO4/SnO2 powder wasobtained by solid state synthesis from homogenizedstarting nanopowders of ZnO and SnO2, mixed in the 1:1molar ratio, structurally and morphologically characterizedusing X-ray diffraction (XRD) and Scanning ElectronMicroscopy (SEM). Thick film paste was made by addingorganic vehicles to the obtained powder. Three to fivelayers (layer thickness approx. 12 µm) were screen printedon alumina substrate with small test PdAg electrodes andfired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where therelative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overallsensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential forapplication in humidity sensing.
PB  - IEEE
T2  - IEEE Sensors Journal
T1  - Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material
SP  - 7509
EP  - 7516
VL  - 20
IS  - 14
DO  - 10.1109/JSEN.2020.2983135
UR  - https://hdl.handle.net/21.15107/rcub_dais_8942
ER  - 
@article{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Labus, Nebojša",
year = "2020",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder wasobtained by solid state synthesis from homogenizedstarting nanopowders of ZnO and SnO2, mixed in the 1:1molar ratio, structurally and morphologically characterizedusing X-ray diffraction (XRD) and Scanning ElectronMicroscopy (SEM). Thick film paste was made by addingorganic vehicles to the obtained powder. Three to fivelayers (layer thickness approx. 12 µm) were screen printedon alumina substrate with small test PdAg electrodes andfired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where therelative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overallsensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential forapplication in humidity sensing.",
publisher = "IEEE",
journal = "IEEE Sensors Journal",
title = "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material",
pages = "7509-7516",
volume = "20",
number = "14",
doi = "10.1109/JSEN.2020.2983135",
url = "https://hdl.handle.net/21.15107/rcub_dais_8942"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Ž., Luković, M. D.,& Labus, N.. (2020). Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal
IEEE., 20(14), 7509-7516.
https://doi.org/10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_8942
Nikolić MV, Dojčinović M, Vasiljević ZŽ, Luković MD, Labus N. Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal. 2020;20(14):7509-7516.
doi:10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_8942 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Ž., Luković, Miloljub D., Labus, Nebojša, "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material" in IEEE Sensors Journal, 20, no. 14 (2020):7509-7516,
https://doi.org/10.1109/JSEN.2020.2983135 .,
https://hdl.handle.net/21.15107/rcub_dais_8942 .
5
3
4

Modelling and simulations of nanostructures

Pašti, Igor A.; Dobrota, Ana S.; Mentus, Slavko V.

(Belgrade : SASA, 2020)

TY  - CONF
AU  - Pašti, Igor A.
AU  - Dobrota, Ana S.
AU  - Mentus, Slavko V.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/9252
AB  - Напредак савремених технологија захтева фундаментално разумевање везе између структуре и својстава нових материјала. Методе
прорачуна и симулације показале су се као моћно средство у испитивању
ових веза, омогућавајући анализу система различитих нивоа сложености,
на различитим просторним и временским скалама, са жељеним саставом
и без икаквог ризика од контаминације. Штавише, константно повећање
рачунарских ресурса омогућило је примену неких од најнапреднијих метода
прорачуна на скали која превазилази суб-нанометарску (мали молекули и
кластери атома), која се обично сматра границом за ab initio прорачуне. Иако
се тачност таквих израчунавања приближава грешкама експеримента, овај
приступ такође омогућава (теоријску) претрагу великог броја система, што
није експериментално изводљиво, као и разумевање општих трендова који
су од великог значаја, како за теоретичаре тако и за експериментаторе. Овo
поглавље приказује искуства аутора у моделирању и симулацијама система
нанометарских димензија различите сложености, укључујући оксиде метала,
метале, угљеничне материјале, молекулске мреже и сложене каталитичке
системе.
AB  - Advancements in contemporary technologies require deep
understanding of the link between the structure and properties of novel materials. Computational methods have been proven as a powerful tool in that quest,
allowing investigation of systems of various complexity and at different spatial and
temporal scales, with a desired composition and without any risk of contamination.
Moreover, constant increase of computational power allowed the application of
some of the most advanced computational methods at the scales which overcome
sub-nanometers (small molecules and clusters of atoms), usually considered as a
limit for first principles calculations. While the accuracy of such calculations reaches the experimental one, this approach also allows for the screening of a large number of systems, which is not experimentally feasible, and also the understanding of
general trends which is of great importance for both theoreticians and experimentalists. This text will cover author’s recent experiences in modelling and simulation
of nanoscale systems of different complexity, including metal oxides, metals, carbon
materials, molecular networks and complex catalytic systems.
PB  - Belgrade : SASA
C3  - Fascinating world of nanoscience and nanotechnology
T1  - Modelling and simulations of nanostructures
T1  - Моделирање и симулација наноструктура
SP  - 251
EP  - 282
UR  - https://hdl.handle.net/21.15107/rcub_dais_9252
ER  - 
@conference{
author = "Pašti, Igor A. and Dobrota, Ana S. and Mentus, Slavko V.",
year = "2020",
abstract = "Напредак савремених технологија захтева фундаментално разумевање везе између структуре и својстава нових материјала. Методе
прорачуна и симулације показале су се као моћно средство у испитивању
ових веза, омогућавајући анализу система различитих нивоа сложености,
на различитим просторним и временским скалама, са жељеним саставом
и без икаквог ризика од контаминације. Штавише, константно повећање
рачунарских ресурса омогућило је примену неких од најнапреднијих метода
прорачуна на скали која превазилази суб-нанометарску (мали молекули и
кластери атома), која се обично сматра границом за ab initio прорачуне. Иако
се тачност таквих израчунавања приближава грешкама експеримента, овај
приступ такође омогућава (теоријску) претрагу великог броја система, што
није експериментално изводљиво, као и разумевање општих трендова који
су од великог значаја, како за теоретичаре тако и за експериментаторе. Овo
поглавље приказује искуства аутора у моделирању и симулацијама система
нанометарских димензија различите сложености, укључујући оксиде метала,
метале, угљеничне материјале, молекулске мреже и сложене каталитичке
системе., Advancements in contemporary technologies require deep
understanding of the link between the structure and properties of novel materials. Computational methods have been proven as a powerful tool in that quest,
allowing investigation of systems of various complexity and at different spatial and
temporal scales, with a desired composition and without any risk of contamination.
Moreover, constant increase of computational power allowed the application of
some of the most advanced computational methods at the scales which overcome
sub-nanometers (small molecules and clusters of atoms), usually considered as a
limit for first principles calculations. While the accuracy of such calculations reaches the experimental one, this approach also allows for the screening of a large number of systems, which is not experimentally feasible, and also the understanding of
general trends which is of great importance for both theoreticians and experimentalists. This text will cover author’s recent experiences in modelling and simulation
of nanoscale systems of different complexity, including metal oxides, metals, carbon
materials, molecular networks and complex catalytic systems.",
publisher = "Belgrade : SASA",
journal = "Fascinating world of nanoscience and nanotechnology",
title = "Modelling and simulations of nanostructures, Моделирање и симулација наноструктура",
pages = "251-282",
url = "https://hdl.handle.net/21.15107/rcub_dais_9252"
}
Pašti, I. A., Dobrota, A. S.,& Mentus, S. V.. (2020). Modelling and simulations of nanostructures. in Fascinating world of nanoscience and nanotechnology
Belgrade : SASA., 251-282.
https://hdl.handle.net/21.15107/rcub_dais_9252
Pašti IA, Dobrota AS, Mentus SV. Modelling and simulations of nanostructures. in Fascinating world of nanoscience and nanotechnology. 2020;:251-282.
https://hdl.handle.net/21.15107/rcub_dais_9252 .
Pašti, Igor A., Dobrota, Ana S., Mentus, Slavko V., "Modelling and simulations of nanostructures" in Fascinating world of nanoscience and nanotechnology (2020):251-282,
https://hdl.handle.net/21.15107/rcub_dais_9252 .

Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Krstić, Jugoslav B.; Vujančević, Jelena; Tadić, Nenad B.; Vlahović, Branislav; Pavlović, Vladimir B.

(John Wiley & Sons, Inc., 2019)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Krstić, Jugoslav B.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/ijac.13190
UR  - http://dais.sanu.ac.rs/123456789/4848
AB  - Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.
PB  - John Wiley & Sons, Inc.
T2  - International Journal of Applied Ceramic Technology
T1  - Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing
SP  - 981
EP  - 993
VL  - 16
IS  - 3
DO  - 10.1111/ijac.13190
UR  - https://hdl.handle.net/21.15107/rcub_dais_4848
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Krstić, Jugoslav B. and Vujančević, Jelena and Tadić, Nenad B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.",
publisher = "John Wiley & Sons, Inc.",
journal = "International Journal of Applied Ceramic Technology",
title = "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing",
pages = "981-993",
volume = "16",
number = "3",
doi = "10.1111/ijac.13190",
url = "https://hdl.handle.net/21.15107/rcub_dais_4848"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Krstić, J. B., Vujančević, J., Tadić, N. B., Vlahović, B.,& Pavlović, V. B.. (2019). Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology
John Wiley & Sons, Inc.., 16(3), 981-993.
https://doi.org/10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_4848
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Krstić JB, Vujančević J, Tadić NB, Vlahović B, Pavlović VB. Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology. 2019;16(3):981-993.
doi:10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_4848 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Krstić, Jugoslav B., Vujančević, Jelena, Tadić, Nenad B., Vlahović, Branislav, Pavlović, Vladimir B., "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing" in International Journal of Applied Ceramic Technology, 16, no. 3 (2019):981-993,
https://doi.org/10.1111/ijac.13190 .,
https://hdl.handle.net/21.15107/rcub_dais_4848 .
13
12
12

Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Krstić, Jugoslav B.; Vujančević, Jelena; Tadić, Nenad B.; Vlahović, Branislav; Pavlović, Vladimir B.

(John Wiley & Sons, Inc., 2019)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Krstić, Jugoslav B.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/ijac.13190
UR  - http://dais.sanu.ac.rs/123456789/5766
AB  - Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.
PB  - John Wiley & Sons, Inc.
T2  - International Journal of Applied Ceramic Technology
T1  - Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing
SP  - 981
EP  - 993
VL  - 16
IS  - 3
DO  - 10.1111/ijac.13190
UR  - https://hdl.handle.net/21.15107/rcub_dais_5766
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Krstić, Jugoslav B. and Vujančević, Jelena and Tadić, Nenad B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.",
publisher = "John Wiley & Sons, Inc.",
journal = "International Journal of Applied Ceramic Technology",
title = "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing",
pages = "981-993",
volume = "16",
number = "3",
doi = "10.1111/ijac.13190",
url = "https://hdl.handle.net/21.15107/rcub_dais_5766"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Krstić, J. B., Vujančević, J., Tadić, N. B., Vlahović, B.,& Pavlović, V. B.. (2019). Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology
John Wiley & Sons, Inc.., 16(3), 981-993.
https://doi.org/10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_5766
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Krstić JB, Vujančević J, Tadić NB, Vlahović B, Pavlović VB. Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology. 2019;16(3):981-993.
doi:10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_5766 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Krstić, Jugoslav B., Vujančević, Jelena, Tadić, Nenad B., Vlahović, Branislav, Pavlović, Vladimir B., "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing" in International Journal of Applied Ceramic Technology, 16, no. 3 (2019):981-993,
https://doi.org/10.1111/ijac.13190 .,
https://hdl.handle.net/21.15107/rcub_dais_5766 .
13
12
12

Synthesis temperature influence on the structure, morphology and electrochemical performance of NaxMnO2 as cathode materials for sodium-ion rechearchable batteries

Rakočević, Lazar; Potočnik, Jelena; Novaković, Mirjana; Jugović, Dragana; Stojković Simatović, Ivana

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Rakočević, Lazar
AU  - Potočnik, Jelena
AU  - Novaković, Mirjana
AU  - Jugović, Dragana
AU  - Stojković Simatović, Ivana
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6972
AB  - The lithium-ion batteries are the most commonly used for energy storage in portable devices. Since lithium is relatively rare on earth but rapidly consumed, it is necessary to find an adequate replacement. Owing to the similar chemical properties of sodium and lithium, but much higher availability, sodium ion batteries are one of the best candidates to replace lithium-ion batteries. A variety of materials such as manganese oxide, vanadium oxide or phosphate can be used as an electrode material (anode and cathode) in sodium ion batteries due to the high ability of intercalation of sodium. In this work, NaxMnO2 powder was synthesized by glycine nitrate method. The precursor powder was annealed for four hours at different temperatures: 800, 850, 900 and 950 °C. The characterization of the obtained materials was carried out using following methods: X-ray diffraction (XRD), scanning electron spectroscopy with energy dispersive X-ray spectroscopy (SEM/EDS) and transmission electron spectroscopy with energy dispersive Xray spectroscopy (TEM/EDS). Electrochemical properties were studied using cyclic voltammetry and chronopotentiometry in an aqueous solution of NaNO3. The layer structured Na0.7MnO2.05 with sheet-like morphology and Na0.4MnO2 with 3-D tunnel structure and rod-like morphology was obtained at 800 oC and 900 oC respectively. Na0.44MnO2 with rod-like morphology was annealed at 900 and 950 oC. 3D-tunnel structure Na0.44MnO2 obtained at 900 oC showed the best electrochemical behaviour in aqueous NaNO3 solution.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - Synthesis temperature influence on the structure, morphology and electrochemical performance of NaxMnO2 as cathode materials for sodium-ion rechearchable batteries
SP  - 59
EP  - 59
UR  - https://hdl.handle.net/21.15107/rcub_dais_6972
ER  - 
@conference{
author = "Rakočević, Lazar and Potočnik, Jelena and Novaković, Mirjana and Jugović, Dragana and Stojković Simatović, Ivana",
year = "2019",
abstract = "The lithium-ion batteries are the most commonly used for energy storage in portable devices. Since lithium is relatively rare on earth but rapidly consumed, it is necessary to find an adequate replacement. Owing to the similar chemical properties of sodium and lithium, but much higher availability, sodium ion batteries are one of the best candidates to replace lithium-ion batteries. A variety of materials such as manganese oxide, vanadium oxide or phosphate can be used as an electrode material (anode and cathode) in sodium ion batteries due to the high ability of intercalation of sodium. In this work, NaxMnO2 powder was synthesized by glycine nitrate method. The precursor powder was annealed for four hours at different temperatures: 800, 850, 900 and 950 °C. The characterization of the obtained materials was carried out using following methods: X-ray diffraction (XRD), scanning electron spectroscopy with energy dispersive X-ray spectroscopy (SEM/EDS) and transmission electron spectroscopy with energy dispersive Xray spectroscopy (TEM/EDS). Electrochemical properties were studied using cyclic voltammetry and chronopotentiometry in an aqueous solution of NaNO3. The layer structured Na0.7MnO2.05 with sheet-like morphology and Na0.4MnO2 with 3-D tunnel structure and rod-like morphology was obtained at 800 oC and 900 oC respectively. Na0.44MnO2 with rod-like morphology was annealed at 900 and 950 oC. 3D-tunnel structure Na0.44MnO2 obtained at 900 oC showed the best electrochemical behaviour in aqueous NaNO3 solution.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "Synthesis temperature influence on the structure, morphology and electrochemical performance of NaxMnO2 as cathode materials for sodium-ion rechearchable batteries",
pages = "59-59",
url = "https://hdl.handle.net/21.15107/rcub_dais_6972"
}
Rakočević, L., Potočnik, J., Novaković, M., Jugović, D.,& Stojković Simatović, I.. (2019). Synthesis temperature influence on the structure, morphology and electrochemical performance of NaxMnO2 as cathode materials for sodium-ion rechearchable batteries. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 59-59.
https://hdl.handle.net/21.15107/rcub_dais_6972
Rakočević L, Potočnik J, Novaković M, Jugović D, Stojković Simatović I. Synthesis temperature influence on the structure, morphology and electrochemical performance of NaxMnO2 as cathode materials for sodium-ion rechearchable batteries. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:59-59.
https://hdl.handle.net/21.15107/rcub_dais_6972 .
Rakočević, Lazar, Potočnik, Jelena, Novaković, Mirjana, Jugović, Dragana, Stojković Simatović, Ivana, "Synthesis temperature influence on the structure, morphology and electrochemical performance of NaxMnO2 as cathode materials for sodium-ion rechearchable batteries" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):59-59,
https://hdl.handle.net/21.15107/rcub_dais_6972 .

Electrochemical oxidation of maricite NaFePO4 in mild aqueous solutions as a way to boost its charge storage capacity

Petrović, Tamara; Milović, Miloš; Bajuk Bogdanović, Danica; Vujković, Milica

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Petrović, Tamara
AU  - Milović, Miloš
AU  - Bajuk Bogdanović, Danica
AU  - Vujković, Milica
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6971
AB  - Lithium has a low abundance in the Earth's crust, which in a few years will lead to difficult lithium production, and therefore difficult production of lithium-ion batteries. Sodium-ion batteries, on the other hand, have been proven to be a good replacement. The material obtained from iron combined with the phosphate and pyrophosphate compounds of sodium has attracted attention as a possible cathode material for sodium-ion batteries. NaFePO4 exists in two polymorphic structures (triphylite and maricite). Maricite NaFePO4 is a more thermodynamically stable structure than triphylite NaFePO4 but doesn’t have channels for Na+ movement and electrochemical performance of this structure is low. In comparison to maricite NaFePO4, triphylite NaFePO4 (structural analogue to LiFePO4) has one-dimensional channels for Na+-ions movement and better electrochemical activity but it is not stable and is difficult to synthesize. Herein, the maricite NaFePO4 can be obtained by sintering a polyanionic compound, Na4Fe3(PO4)2P2O7, at temperatures above 600 °C, as shown by XRD. Na4Fe3(PO4)2P2O7 is synthesized by the glycine-nitrate process after which it was sintered at temperatures above 500 °C. The glycine-nitrate process was found to catalyze the decomposition of the sintered Na4Fe3(PO4)2P2O7 to the NaFePO4 maricite. The electrochemical characterization of the sintered material, evaluated in aqueous NaNO3 and LiNO3 electrolyte by cyclic voltammetry, showed poor electrochemical activity of maricite NaFePO4. By exposing the sintered material to high anodic potentials, the electrochemical activity and specific capacity of the material were increased by 50% in case of NaNO3 and 80% in case of LiNO3 relative to the pristine with low activity. After electrochemical measurements, residual powder was characterized by FTIR and Raman spectroscopy. It was shown that high anodic polarization of the material tested in LiNO3 causes the formation of triphylite LiFePO4. Similarly, it is assumed that the electrochemical activity obtained by deep anodic polarization of the material in NaNO3 electrolyte originates from the formed triphylite NaFePO4. The obtained results open novel directions regarding the use of NaFePO4 in metal-ion rechargeable batteries.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - Electrochemical oxidation of maricite NaFePO4 in mild aqueous solutions as a way to boost its charge storage capacity
SP  - 48
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_dais_6971
ER  - 
@conference{
author = "Petrović, Tamara and Milović, Miloš and Bajuk Bogdanović, Danica and Vujković, Milica",
year = "2019",
abstract = "Lithium has a low abundance in the Earth's crust, which in a few years will lead to difficult lithium production, and therefore difficult production of lithium-ion batteries. Sodium-ion batteries, on the other hand, have been proven to be a good replacement. The material obtained from iron combined with the phosphate and pyrophosphate compounds of sodium has attracted attention as a possible cathode material for sodium-ion batteries. NaFePO4 exists in two polymorphic structures (triphylite and maricite). Maricite NaFePO4 is a more thermodynamically stable structure than triphylite NaFePO4 but doesn’t have channels for Na+ movement and electrochemical performance of this structure is low. In comparison to maricite NaFePO4, triphylite NaFePO4 (structural analogue to LiFePO4) has one-dimensional channels for Na+-ions movement and better electrochemical activity but it is not stable and is difficult to synthesize. Herein, the maricite NaFePO4 can be obtained by sintering a polyanionic compound, Na4Fe3(PO4)2P2O7, at temperatures above 600 °C, as shown by XRD. Na4Fe3(PO4)2P2O7 is synthesized by the glycine-nitrate process after which it was sintered at temperatures above 500 °C. The glycine-nitrate process was found to catalyze the decomposition of the sintered Na4Fe3(PO4)2P2O7 to the NaFePO4 maricite. The electrochemical characterization of the sintered material, evaluated in aqueous NaNO3 and LiNO3 electrolyte by cyclic voltammetry, showed poor electrochemical activity of maricite NaFePO4. By exposing the sintered material to high anodic potentials, the electrochemical activity and specific capacity of the material were increased by 50% in case of NaNO3 and 80% in case of LiNO3 relative to the pristine with low activity. After electrochemical measurements, residual powder was characterized by FTIR and Raman spectroscopy. It was shown that high anodic polarization of the material tested in LiNO3 causes the formation of triphylite LiFePO4. Similarly, it is assumed that the electrochemical activity obtained by deep anodic polarization of the material in NaNO3 electrolyte originates from the formed triphylite NaFePO4. The obtained results open novel directions regarding the use of NaFePO4 in metal-ion rechargeable batteries.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "Electrochemical oxidation of maricite NaFePO4 in mild aqueous solutions as a way to boost its charge storage capacity",
pages = "48-48",
url = "https://hdl.handle.net/21.15107/rcub_dais_6971"
}
Petrović, T., Milović, M., Bajuk Bogdanović, D.,& Vujković, M.. (2019). Electrochemical oxidation of maricite NaFePO4 in mild aqueous solutions as a way to boost its charge storage capacity. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 48-48.
https://hdl.handle.net/21.15107/rcub_dais_6971
Petrović T, Milović M, Bajuk Bogdanović D, Vujković M. Electrochemical oxidation of maricite NaFePO4 in mild aqueous solutions as a way to boost its charge storage capacity. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:48-48.
https://hdl.handle.net/21.15107/rcub_dais_6971 .
Petrović, Tamara, Milović, Miloš, Bajuk Bogdanović, Danica, Vujković, Milica, "Electrochemical oxidation of maricite NaFePO4 in mild aqueous solutions as a way to boost its charge storage capacity" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):48-48,
https://hdl.handle.net/21.15107/rcub_dais_6971 .

NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media

Milikić, Jadranka; Vasić, Milica M.; Amaral, Luis; Cvjetićanin, Nikola; Jugović, Dragana; Hercigonja, Radmila; Šljukić, Biljana

(Elsevier, 2018)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Vasić, Milica M.
AU  - Amaral, Luis
AU  - Cvjetićanin, Nikola
AU  - Jugović, Dragana
AU  - Hercigonja, Radmila
AU  - Šljukić, Biljana
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4588
AB  - NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media
SP  - 18977
EP  - 18991
VL  - 43
IS  - 41
DO  - 10.1016/j.ijhydene.2018.08.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4588
ER  - 
@article{
author = "Milikić, Jadranka and Vasić, Milica M. and Amaral, Luis and Cvjetićanin, Nikola and Jugović, Dragana and Hercigonja, Radmila and Šljukić, Biljana",
year = "2018",
abstract = "NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media",
pages = "18977-18991",
volume = "43",
number = "41",
doi = "10.1016/j.ijhydene.2018.08.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4588"
}
Milikić, J., Vasić, M. M., Amaral, L., Cvjetićanin, N., Jugović, D., Hercigonja, R.,& Šljukić, B.. (2018). NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy
Elsevier., 43(41), 18977-18991.
https://doi.org/10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4588
Milikić J, Vasić MM, Amaral L, Cvjetićanin N, Jugović D, Hercigonja R, Šljukić B. NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy. 2018;43(41):18977-18991.
doi:10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4588 .
Milikić, Jadranka, Vasić, Milica M., Amaral, Luis, Cvjetićanin, Nikola, Jugović, Dragana, Hercigonja, Radmila, Šljukić, Biljana, "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media" in International Journal of Hydrogen Energy, 43, no. 41 (2018):18977-18991,
https://doi.org/10.1016/j.ijhydene.2018.08.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4588 .
7
5
7

NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media

Milikić, Jadranka; Vasić, Milica M.; Amaral, Luis; Cvjetićanin, Nikola; Jugović, Dragana; Hercigonja, Radmila; Šljukić, Biljana

(Elsevier, 2018)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Vasić, Milica M.
AU  - Amaral, Luis
AU  - Cvjetićanin, Nikola
AU  - Jugović, Dragana
AU  - Hercigonja, Radmila
AU  - Šljukić, Biljana
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4077
AB  - NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media
SP  - 18977
EP  - 18991
VL  - 43
IS  - 41
DO  - 10.1016/j.ijhydene.2018.08.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4077
ER  - 
@article{
author = "Milikić, Jadranka and Vasić, Milica M. and Amaral, Luis and Cvjetićanin, Nikola and Jugović, Dragana and Hercigonja, Radmila and Šljukić, Biljana",
year = "2018",
abstract = "NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media",
pages = "18977-18991",
volume = "43",
number = "41",
doi = "10.1016/j.ijhydene.2018.08.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4077"
}
Milikić, J., Vasić, M. M., Amaral, L., Cvjetićanin, N., Jugović, D., Hercigonja, R.,& Šljukić, B.. (2018). NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy
Elsevier., 43(41), 18977-18991.
https://doi.org/10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4077
Milikić J, Vasić MM, Amaral L, Cvjetićanin N, Jugović D, Hercigonja R, Šljukić B. NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy. 2018;43(41):18977-18991.
doi:10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4077 .
Milikić, Jadranka, Vasić, Milica M., Amaral, Luis, Cvjetićanin, Nikola, Jugović, Dragana, Hercigonja, Radmila, Šljukić, Biljana, "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media" in International Journal of Hydrogen Energy, 43, no. 41 (2018):18977-18991,
https://doi.org/10.1016/j.ijhydene.2018.08.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4077 .
7
5
6

Synthesis, characterization and electrochemical properties of Na0.44MnO2 in NaNO3 and LiNO3 aqueous solution

Gezović, Aleksandra; Vujković, Milica; Jugović, Dragana; Janković Častvan, Ivona; Stojković Simatović, Ivana; Mentus, Slavko

(Belgrade : Society of Physical Chemists of Serbia, 2018)

TY  - CONF
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Janković Častvan, Ivona
AU  - Stojković Simatović, Ivana
AU  - Mentus, Slavko
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4562
AB  - Na0.44MnO2 synthesized by glycine-nitrate method (GNM) was described in
this paper and it was characterized by X-ray powder diffraction (XRD) and
field-emission scanning electron microscopy (FE-SEM). Electrochemical
performances of Na0.44MnO2 were studied by cycling voltammetry (CV) at
various scan rates in NaNO3 and LiNO3 aqueous solutions in order to
compare the intercalation/deintercalation kinetics of Li+ and Na+ ions. The
initial discharge capacity was found to be 27.1 and 27.44 in the aqueous
solution of NaNO3 and LiNO3, respectively, and after 30 cycles its values
increased for 12% in both electrolytes.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - Physical Chemistry 2018 : proceedings. Vol. 1 / 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018
T1  - Synthesis, characterization and electrochemical properties of Na0.44MnO2 in NaNO3 and LiNO3 aqueous solution
SP  - 407
EP  - 410
UR  - https://hdl.handle.net/21.15107/rcub_dais_4562
ER  - 
@conference{
author = "Gezović, Aleksandra and Vujković, Milica and Jugović, Dragana and Janković Častvan, Ivona and Stojković Simatović, Ivana and Mentus, Slavko",
year = "2018",
abstract = "Na0.44MnO2 synthesized by glycine-nitrate method (GNM) was described in
this paper and it was characterized by X-ray powder diffraction (XRD) and
field-emission scanning electron microscopy (FE-SEM). Electrochemical
performances of Na0.44MnO2 were studied by cycling voltammetry (CV) at
various scan rates in NaNO3 and LiNO3 aqueous solutions in order to
compare the intercalation/deintercalation kinetics of Li+ and Na+ ions. The
initial discharge capacity was found to be 27.1 and 27.44 in the aqueous
solution of NaNO3 and LiNO3, respectively, and after 30 cycles its values
increased for 12% in both electrolytes.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "Physical Chemistry 2018 : proceedings. Vol. 1 / 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018",
title = "Synthesis, characterization and electrochemical properties of Na0.44MnO2 in NaNO3 and LiNO3 aqueous solution",
pages = "407-410",
url = "https://hdl.handle.net/21.15107/rcub_dais_4562"
}
Gezović, A., Vujković, M., Jugović, D., Janković Častvan, I., Stojković Simatović, I.,& Mentus, S.. (2018). Synthesis, characterization and electrochemical properties of Na0.44MnO2 in NaNO3 and LiNO3 aqueous solution. in Physical Chemistry 2018 : proceedings. Vol. 1 / 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018
Belgrade : Society of Physical Chemists of Serbia., 407-410.
https://hdl.handle.net/21.15107/rcub_dais_4562
Gezović A, Vujković M, Jugović D, Janković Častvan I, Stojković Simatović I, Mentus S. Synthesis, characterization and electrochemical properties of Na0.44MnO2 in NaNO3 and LiNO3 aqueous solution. in Physical Chemistry 2018 : proceedings. Vol. 1 / 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018. 2018;:407-410.
https://hdl.handle.net/21.15107/rcub_dais_4562 .
Gezović, Aleksandra, Vujković, Milica, Jugović, Dragana, Janković Častvan, Ivona, Stojković Simatović, Ivana, Mentus, Slavko, "Synthesis, characterization and electrochemical properties of Na0.44MnO2 in NaNO3 and LiNO3 aqueous solution" in Physical Chemistry 2018 : proceedings. Vol. 1 / 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018 (2018):407-410,
https://hdl.handle.net/21.15107/rcub_dais_4562 .

Na0.44Mn02 as a cathode material for aqueous sodium-ion batteries

Gezović, Aleksandra; Vujković, Milica; Jugović, Dragana; Janković Častvan, Ivona; Stojković Simatović, Ivana

(Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade, 2018)

TY  - CONF
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Janković Častvan, Ivona
AU  - Stojković Simatović, Ivana
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4570
AB  - The application of rechargeable batteries is growing significantly and it became the nlost important field for largescale electric energy storage. While lithiuln-ion batteries (LIBs) have great commercial success, due to their large energy and power density, their application was limited because of the availability of lithiunl and its high cost. Sodiunl-ion batteries (SIBs) can be a promissing alternative due to the huge availability of sodium, its low price and similar intercalating electrochelnistry to LIBs. Among various Na-ion battery materials, low-cost and tunnel-type, Na0.44Mn02 (NMO) was regarded as one of the most pronlising cathode materials for sodium-ion batteries, because of its high theoretical specific capacity (122 rnA h g1) and good cyclability [2]. In this work, for the synthesis of NMO powder, rapid glycine-nitrate nlethod (GNM) was used, which, on the basis of the literature review, has not been used to synthesize this material so far.
PB  - Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade
PB  - Belgrade : Hydrogen Economy Initiative Serbia
C3  - Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018
T1  - Na0.44Mn02 as a cathode material for aqueous sodium-ion batteries
SP  - 89
EP  - 89
UR  - https://hdl.handle.net/21.15107/rcub_dais_4570
ER  - 
@conference{
author = "Gezović, Aleksandra and Vujković, Milica and Jugović, Dragana and Janković Častvan, Ivona and Stojković Simatović, Ivana",
year = "2018",
abstract = "The application of rechargeable batteries is growing significantly and it became the nlost important field for largescale electric energy storage. While lithiuln-ion batteries (LIBs) have great commercial success, due to their large energy and power density, their application was limited because of the availability of lithiunl and its high cost. Sodiunl-ion batteries (SIBs) can be a promissing alternative due to the huge availability of sodium, its low price and similar intercalating electrochelnistry to LIBs. Among various Na-ion battery materials, low-cost and tunnel-type, Na0.44Mn02 (NMO) was regarded as one of the most pronlising cathode materials for sodium-ion batteries, because of its high theoretical specific capacity (122 rnA h g1) and good cyclability [2]. In this work, for the synthesis of NMO powder, rapid glycine-nitrate nlethod (GNM) was used, which, on the basis of the literature review, has not been used to synthesize this material so far.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade, Belgrade : Hydrogen Economy Initiative Serbia",
journal = "Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018",
title = "Na0.44Mn02 as a cathode material for aqueous sodium-ion batteries",
pages = "89-89",
url = "https://hdl.handle.net/21.15107/rcub_dais_4570"
}
Gezović, A., Vujković, M., Jugović, D., Janković Častvan, I.,& Stojković Simatović, I.. (2018). Na0.44Mn02 as a cathode material for aqueous sodium-ion batteries. in Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018
Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade., 89-89.
https://hdl.handle.net/21.15107/rcub_dais_4570
Gezović A, Vujković M, Jugović D, Janković Častvan I, Stojković Simatović I. Na0.44Mn02 as a cathode material for aqueous sodium-ion batteries. in Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018. 2018;:89-89.
https://hdl.handle.net/21.15107/rcub_dais_4570 .
Gezović, Aleksandra, Vujković, Milica, Jugović, Dragana, Janković Častvan, Ivona, Stojković Simatović, Ivana, "Na0.44Mn02 as a cathode material for aqueous sodium-ion batteries" in Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018 (2018):89-89,
https://hdl.handle.net/21.15107/rcub_dais_4570 .

Synthesis and characterisation of ZnO synthesized by glycine-nitrate combustion process

Dojčinović, Milena; Marković, Smilja; Stojadinović, S.; Rac, Vladislav; Janković Častvan, Ivona; Stojković Simatović, Ivana

(Belgrade : Institute of Technical Sciences of SASA, 2018)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Marković, Smilja
AU  - Stojadinović, S.
AU  - Rac, Vladislav
AU  - Janković Častvan, Ivona
AU  - Stojković Simatović, Ivana
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4717
AB  - One of the ways to get rid of toxic organic compounds that industries release into natural waters is photocatalysis of the decomposition of organic compounds on the surface of heterogenous photocatalysts such as zinc oxide. Zinc oxide is a semiconductor that interacts with UV and near-UV visible light by generating electron-hole pairs which decompose organic molecules. Therefore it is useful to explore different ways of synthesizing zinc oxide and to test quality and quantity of organic decomposition photocatalysis so as to enable the commercial use of the material. Zinc oxide is also a respectable material for use as a photoelectrocatalyst in water oxidation, for example, which can be useful for generating oxygen while using natural sunlight - a clean and abundant energy source. In this project nanocrystalline zinc oxide was synthesized by glycin-nitrate combustion process and the powder was annealed on temperatures of 400 °C and 500 °C. Obtained particles where characterized in detail using X-ray powder diffraction (XRPD), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, field emission scanning microscopy (FESEM), photoluminescence spectroscopy (PL) and diffuse reflectance spectroscopy (DRS). The results show that obtained samples are nanocrystalline wurtzite zinc oxide, with particle diameters of 33 nm (annealed at 400 °C) ad 48 nm (annealed at 500 °C). Both samples show significant amount of various crystal defects. Zinc oxide band gap of the samples are determined to be lower than the band gap of the bulk zinc oxide. Photoelectrocatalytic properties were investigated via electrochemical methods: linear voltammetry (LV), chronoamperometry (CA) and impedance spectroscopy (EIS). The results show that material is photostable and reactive to the light. Water oxidation is enhanced by exposing to sunlight. Finally, photocatalytic properties are tested with determining kinetic parameters of phenole and methyl blue decomposition. Zinc oxide nanoparticles are efficient photocatalysts, although sample annealed at 500 °C shows better properties than sample annealed at 400 °C.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia
T1  - Synthesis and characterisation of ZnO synthesized by glycine-nitrate combustion process
SP  - 78
EP  - 78
UR  - https://hdl.handle.net/21.15107/rcub_dais_4717
ER  - 
@conference{
author = "Dojčinović, Milena and Marković, Smilja and Stojadinović, S. and Rac, Vladislav and Janković Častvan, Ivona and Stojković Simatović, Ivana",
year = "2018",
abstract = "One of the ways to get rid of toxic organic compounds that industries release into natural waters is photocatalysis of the decomposition of organic compounds on the surface of heterogenous photocatalysts such as zinc oxide. Zinc oxide is a semiconductor that interacts with UV and near-UV visible light by generating electron-hole pairs which decompose organic molecules. Therefore it is useful to explore different ways of synthesizing zinc oxide and to test quality and quantity of organic decomposition photocatalysis so as to enable the commercial use of the material. Zinc oxide is also a respectable material for use as a photoelectrocatalyst in water oxidation, for example, which can be useful for generating oxygen while using natural sunlight - a clean and abundant energy source. In this project nanocrystalline zinc oxide was synthesized by glycin-nitrate combustion process and the powder was annealed on temperatures of 400 °C and 500 °C. Obtained particles where characterized in detail using X-ray powder diffraction (XRPD), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, field emission scanning microscopy (FESEM), photoluminescence spectroscopy (PL) and diffuse reflectance spectroscopy (DRS). The results show that obtained samples are nanocrystalline wurtzite zinc oxide, with particle diameters of 33 nm (annealed at 400 °C) ad 48 nm (annealed at 500 °C). Both samples show significant amount of various crystal defects. Zinc oxide band gap of the samples are determined to be lower than the band gap of the bulk zinc oxide. Photoelectrocatalytic properties were investigated via electrochemical methods: linear voltammetry (LV), chronoamperometry (CA) and impedance spectroscopy (EIS). The results show that material is photostable and reactive to the light. Water oxidation is enhanced by exposing to sunlight. Finally, photocatalytic properties are tested with determining kinetic parameters of phenole and methyl blue decomposition. Zinc oxide nanoparticles are efficient photocatalysts, although sample annealed at 500 °C shows better properties than sample annealed at 400 °C.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia",
title = "Synthesis and characterisation of ZnO synthesized by glycine-nitrate combustion process",
pages = "78-78",
url = "https://hdl.handle.net/21.15107/rcub_dais_4717"
}
Dojčinović, M., Marković, S., Stojadinović, S., Rac, V., Janković Častvan, I.,& Stojković Simatović, I.. (2018). Synthesis and characterisation of ZnO synthesized by glycine-nitrate combustion process. in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 78-78.
https://hdl.handle.net/21.15107/rcub_dais_4717
Dojčinović M, Marković S, Stojadinović S, Rac V, Janković Častvan I, Stojković Simatović I. Synthesis and characterisation of ZnO synthesized by glycine-nitrate combustion process. in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia. 2018;:78-78.
https://hdl.handle.net/21.15107/rcub_dais_4717 .
Dojčinović, Milena, Marković, Smilja, Stojadinović, S., Rac, Vladislav, Janković Častvan, Ivona, Stojković Simatović, Ivana, "Synthesis and characterisation of ZnO synthesized by glycine-nitrate combustion process" in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia (2018):78-78,
https://hdl.handle.net/21.15107/rcub_dais_4717 .

Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Vujančević, Jelena; Radovanović, Milan; Krstić, Jugoslav; Vlahović, Branislav; Pavlović, Vladimir B.

(Elsevier, 2018)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Radovanović, Milan
AU  - Krstić, Jugoslav
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://www.sciencedirect.com/science/article/pii/S0925400518316836
UR  - http://dais.sanu.ac.rs/123456789/4527
AB  - Pseudobrookite based nanopowder was obtained by solid state synthesis of starting hematite and anatase nanopowders in the weight ratio 55:45. Structural and morphological properties were analyzed using X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV/Vis diffuse reflectance spectroscopy, Field emission scanning electron microscopy (FESEM) and Transmission electron microscopy (TEM) confirming the formation of nanocrystalline pseudobrookite. The obtained powder was mixed with a binder (ethyl cellulose), dispersant (α-terpinol) and adhesion agents (acetic acid and distilled water) to obtain a thick film paste. It was screen printed on alumina substrate with interdigitated PdAg electrodes and fired at 600 °C for 30 min. Formation of a porous nanocrystalline thick film structure was shown using Scanning electron microscopy (SEM), while Hall measurements enabled determination of carrier mobility. Change of impedance response in the frequency range 42 Hz–1 MHz with humidity was analyzed at room temperature (25 °C) and 50 °C in the relative humidity range 30–90% and 40–90%, respectively. At 42 Hz, and room temperature the impedance reduced ∼28 times, while at 50 °C it reduced ∼147 times in the relative humidity range 40–90%. The sensor showed rapid response (16 s) and relatively low hysteresis (8.39% at 25 °C and 2.64% at 50 °C) showing that this is a promising material for application in humidity sensing.
PB  - Elsevier
T2  - Sensors and Actuators B: Chemical
T1  - Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films
SP  - 654
EP  - 664
VL  - 277
DO  - 10.1016/j.snb.2018.09.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4527
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Vujančević, Jelena and Radovanović, Milan and Krstić, Jugoslav and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2018",
abstract = "Pseudobrookite based nanopowder was obtained by solid state synthesis of starting hematite and anatase nanopowders in the weight ratio 55:45. Structural and morphological properties were analyzed using X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV/Vis diffuse reflectance spectroscopy, Field emission scanning electron microscopy (FESEM) and Transmission electron microscopy (TEM) confirming the formation of nanocrystalline pseudobrookite. The obtained powder was mixed with a binder (ethyl cellulose), dispersant (α-terpinol) and adhesion agents (acetic acid and distilled water) to obtain a thick film paste. It was screen printed on alumina substrate with interdigitated PdAg electrodes and fired at 600 °C for 30 min. Formation of a porous nanocrystalline thick film structure was shown using Scanning electron microscopy (SEM), while Hall measurements enabled determination of carrier mobility. Change of impedance response in the frequency range 42 Hz–1 MHz with humidity was analyzed at room temperature (25 °C) and 50 °C in the relative humidity range 30–90% and 40–90%, respectively. At 42 Hz, and room temperature the impedance reduced ∼28 times, while at 50 °C it reduced ∼147 times in the relative humidity range 40–90%. The sensor showed rapid response (16 s) and relatively low hysteresis (8.39% at 25 °C and 2.64% at 50 °C) showing that this is a promising material for application in humidity sensing.",
publisher = "Elsevier",
journal = "Sensors and Actuators B: Chemical",
title = "Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films",
pages = "654-664",
volume = "277",
doi = "10.1016/j.snb.2018.09.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4527"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Vujančević, J., Radovanović, M., Krstić, J., Vlahović, B.,& Pavlović, V. B.. (2018). Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films. in Sensors and Actuators B: Chemical
Elsevier., 277, 654-664.
https://doi.org/10.1016/j.snb.2018.09.063
https://hdl.handle.net/21.15107/rcub_dais_4527
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Vujančević J, Radovanović M, Krstić J, Vlahović B, Pavlović VB. Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films. in Sensors and Actuators B: Chemical. 2018;277:654-664.
doi:10.1016/j.snb.2018.09.063
https://hdl.handle.net/21.15107/rcub_dais_4527 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Vujančević, Jelena, Radovanović, Milan, Krstić, Jugoslav, Vlahović, Branislav, Pavlović, Vladimir B., "Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films" in Sensors and Actuators B: Chemical, 277 (2018):654-664,
https://doi.org/10.1016/j.snb.2018.09.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4527 .
21
19
18

Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Vujančević, Jelena; Radovanović, Milan; Krstić, Jugoslav; Vlahović, Branislav; Pavlović, Vladimir B.

(Elsevier, 2018)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Radovanović, Milan
AU  - Krstić, Jugoslav
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://www.sciencedirect.com/science/article/pii/S0925400518316836
UR  - http://dais.sanu.ac.rs/123456789/4605
AB  - Pseudobrookite based nanopowder was obtained by solid state synthesis of starting hematite and anatase nanopowders in the weight ratio 55:45. Structural and morphological properties were analyzed using X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV/Vis diffuse reflectance spectroscopy, Field emission scanning electron microscopy (FESEM) and Transmission electron microscopy (TEM) confirming the formation of nanocrystalline pseudobrookite. The obtained powder was mixed with a binder (ethyl cellulose), dispersant (α-terpinol) and adhesion agents (acetic acid and distilled water) to obtain a thick film paste. It was screen printed on alumina substrate with interdigitated PdAg electrodes and fired at 600 °C for 30 min. Formation of a porous nanocrystalline thick film structure was shown using Scanning electron microscopy (SEM), while Hall measurements enabled determination of carrier mobility. Change of impedance response in the frequency range 42 Hz–1 MHz with humidity was analyzed at room temperature (25 °C) and 50 °C in the relative humidity range 30–90% and 40–90%, respectively. At 42 Hz, and room temperature the impedance reduced ∼28 times, while at 50 °C it reduced ∼147 times in the relative humidity range 40–90%. The sensor showed rapid response (16 s) and relatively low hysteresis (8.39% at 25 °C and 2.64% at 50 °C) showing that this is a promising material for application in humidity sensing.
PB  - Elsevier
T2  - Sensors and Actuators B: Chemical
T1  - Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films
SP  - 654
EP  - 664
VL  - 277
DO  - 10.1016/j.snb.2018.09.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4605
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Vujančević, Jelena and Radovanović, Milan and Krstić, Jugoslav and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2018",
abstract = "Pseudobrookite based nanopowder was obtained by solid state synthesis of starting hematite and anatase nanopowders in the weight ratio 55:45. Structural and morphological properties were analyzed using X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV/Vis diffuse reflectance spectroscopy, Field emission scanning electron microscopy (FESEM) and Transmission electron microscopy (TEM) confirming the formation of nanocrystalline pseudobrookite. The obtained powder was mixed with a binder (ethyl cellulose), dispersant (α-terpinol) and adhesion agents (acetic acid and distilled water) to obtain a thick film paste. It was screen printed on alumina substrate with interdigitated PdAg electrodes and fired at 600 °C for 30 min. Formation of a porous nanocrystalline thick film structure was shown using Scanning electron microscopy (SEM), while Hall measurements enabled determination of carrier mobility. Change of impedance response in the frequency range 42 Hz–1 MHz with humidity was analyzed at room temperature (25 °C) and 50 °C in the relative humidity range 30–90% and 40–90%, respectively. At 42 Hz, and room temperature the impedance reduced ∼28 times, while at 50 °C it reduced ∼147 times in the relative humidity range 40–90%. The sensor showed rapid response (16 s) and relatively low hysteresis (8.39% at 25 °C and 2.64% at 50 °C) showing that this is a promising material for application in humidity sensing.",
publisher = "Elsevier",
journal = "Sensors and Actuators B: Chemical",
title = "Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films",
pages = "654-664",
volume = "277",
doi = "10.1016/j.snb.2018.09.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4605"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Vujančević, J., Radovanović, M., Krstić, J., Vlahović, B.,& Pavlović, V. B.. (2018). Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films. in Sensors and Actuators B: Chemical
Elsevier., 277, 654-664.
https://doi.org/10.1016/j.snb.2018.09.063
https://hdl.handle.net/21.15107/rcub_dais_4605
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Vujančević J, Radovanović M, Krstić J, Vlahović B, Pavlović VB. Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films. in Sensors and Actuators B: Chemical. 2018;277:654-664.
doi:10.1016/j.snb.2018.09.063
https://hdl.handle.net/21.15107/rcub_dais_4605 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Vujančević, Jelena, Radovanović, Milan, Krstić, Jugoslav, Vlahović, Branislav, Pavlović, Vladimir B., "Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films" in Sensors and Actuators B: Chemical, 277 (2018):654-664,
https://doi.org/10.1016/j.snb.2018.09.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4605 .
21
19
18

Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device

Rakočević, Lazar; Novaković, Mirjana; Potočnik, Jelena; Jugović, Dragana; Stojković Simatović, Ivana

(Belgrade : Serbian Academy of Sciences and Arts, 2018)

TY  - CONF
AU  - Rakočević, Lazar
AU  - Novaković, Mirjana
AU  - Potočnik, Jelena
AU  - Jugović, Dragana
AU  - Stojković Simatović, Ivana
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3628
AB  - Due to the increasing use of batteries in everyday life and in industry, there is a need for developing cheaper batteries than the widely used lithium ion batteries. Lower price and higher abundance of sodium compared to lithium mineral resources intensified the development of Na-ion batteries. Aqueous lithium/ sodium rechargeable batteries have attracted considerable attention for energy storage because they do not contain flammable organic electrolytes as commercial batteries do, the ionic conductivity of the aqueous electrolyte is about two orders of magnitude higher than in non-aqueous electrolyte and the electrolyte salt and solvent are cheaper. Various materials such as manganese oxides, vanadium oxide and phosphates have been used as electrode materials (cathodic and anodic) in sodium batteries due to high sodium intercalation ability in both, organic and aqueous electrolytes. The most frequently used type of manganese oxides are Li–Mn–O or Na–Mn–O systems due to their tunnel or layered crystal structures which facilitate the lithium/sodium intercalation-deintercalation. In this work, a glycine-nitrate method (GNM) was applied for the synthesis of cathode material Na0.4MnO2.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
T1  - Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device
SP  - 154
EP  - 156
UR  - https://hdl.handle.net/21.15107/rcub_dais_3628
ER  - 
@conference{
author = "Rakočević, Lazar and Novaković, Mirjana and Potočnik, Jelena and Jugović, Dragana and Stojković Simatović, Ivana",
year = "2018",
abstract = "Due to the increasing use of batteries in everyday life and in industry, there is a need for developing cheaper batteries than the widely used lithium ion batteries. Lower price and higher abundance of sodium compared to lithium mineral resources intensified the development of Na-ion batteries. Aqueous lithium/ sodium rechargeable batteries have attracted considerable attention for energy storage because they do not contain flammable organic electrolytes as commercial batteries do, the ionic conductivity of the aqueous electrolyte is about two orders of magnitude higher than in non-aqueous electrolyte and the electrolyte salt and solvent are cheaper. Various materials such as manganese oxides, vanadium oxide and phosphates have been used as electrode materials (cathodic and anodic) in sodium batteries due to high sodium intercalation ability in both, organic and aqueous electrolytes. The most frequently used type of manganese oxides are Li–Mn–O or Na–Mn–O systems due to their tunnel or layered crystal structures which facilitate the lithium/sodium intercalation-deintercalation. In this work, a glycine-nitrate method (GNM) was applied for the synthesis of cathode material Na0.4MnO2.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia",
title = "Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device",
pages = "154-156",
url = "https://hdl.handle.net/21.15107/rcub_dais_3628"
}
Rakočević, L., Novaković, M., Potočnik, J., Jugović, D.,& Stojković Simatović, I.. (2018). Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
Belgrade : Serbian Academy of Sciences and Arts., 154-156.
https://hdl.handle.net/21.15107/rcub_dais_3628
Rakočević L, Novaković M, Potočnik J, Jugović D, Stojković Simatović I. Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia. 2018;:154-156.
https://hdl.handle.net/21.15107/rcub_dais_3628 .
Rakočević, Lazar, Novaković, Mirjana, Potočnik, Jelena, Jugović, Dragana, Stojković Simatović, Ivana, "Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device" in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia (2018):154-156,
https://hdl.handle.net/21.15107/rcub_dais_3628 .

Synthesis and characterization of Na0.4MnO2 as cathode material for aqueous sodium-ion batteries

Rakočević, Lazar; Novaković, Mirjana; Potočnik, Jelena; Jugović, Dragana; Stojković Simatović, Ivana

(Belgrade : Institute of Technical Sciences of SASA, 2018)

TY  - CONF
AU  - Rakočević, Lazar
AU  - Novaković, Mirjana
AU  - Potočnik, Jelena
AU  - Jugović, Dragana
AU  - Stojković Simatović, Ivana
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4726
AB  - The application of rechargeable batteries is growing significantly and there is a need for developing cheaper batteries with good performances. Sodium-ion batteries could be a viable option due to higher abundance of sodium against lithium mineral resources, its low price and similar principles intercalate Na+ ions as Li+ ions in lithium-ion batteries. Different materials as manganese oxides and vanadium oxide are used as electrode materials in sodium batteries. Na0.44MnO2 was regarded as one of the most promising cathode materials for sodium-ion batteries due to its high specific capacity and good cyclability. In this work, Na0.4MnO2 was synthesized using glycine-nitrate method (GNM). The structure of synthesized powder was characterized by X-Ray Diffraction (XRD), while the particles morphology was examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The elemental mapping was performed by energy-dispersive Xray spectroscopy (EDS). XRD results showed that the phase structure of Na0.4MnO2 was orthorhombic with tunnel structure. TEM and SEM micrographs of obtained powder material showed uniformed rod-like shape particles with the average lengths and widths of 300 nm and 80 nm, respectively and EDS analysis confirmed that the sample contains Na, Mn, and O in an appropriate ration. The electrochemical behavior of Na0.4MnO2 was investigated by cyclic voltammetry (CV) in a saturated aqueous solution of NaNO3 at scan rates from 20 to 400 mV•s-1. The initial discharge capacity of Na0.4MnO2 in NaNO3 solution was 50 mA•h•g- 1, while after 15 cycles its value increased for 9%. while the efficiency (the ratio of the capacity charge and discharge) was amounting to ~ 95%. This indicates that material synthesized by GNM can be used as cathode material in aqueous sodium-ion batteries
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia
T1  - Synthesis and characterization of Na0.4MnO2 as cathode material for aqueous sodium-ion batteries
SP  - 48
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_dais_4726
ER  - 
@conference{
author = "Rakočević, Lazar and Novaković, Mirjana and Potočnik, Jelena and Jugović, Dragana and Stojković Simatović, Ivana",
year = "2018",
abstract = "The application of rechargeable batteries is growing significantly and there is a need for developing cheaper batteries with good performances. Sodium-ion batteries could be a viable option due to higher abundance of sodium against lithium mineral resources, its low price and similar principles intercalate Na+ ions as Li+ ions in lithium-ion batteries. Different materials as manganese oxides and vanadium oxide are used as electrode materials in sodium batteries. Na0.44MnO2 was regarded as one of the most promising cathode materials for sodium-ion batteries due to its high specific capacity and good cyclability. In this work, Na0.4MnO2 was synthesized using glycine-nitrate method (GNM). The structure of synthesized powder was characterized by X-Ray Diffraction (XRD), while the particles morphology was examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The elemental mapping was performed by energy-dispersive Xray spectroscopy (EDS). XRD results showed that the phase structure of Na0.4MnO2 was orthorhombic with tunnel structure. TEM and SEM micrographs of obtained powder material showed uniformed rod-like shape particles with the average lengths and widths of 300 nm and 80 nm, respectively and EDS analysis confirmed that the sample contains Na, Mn, and O in an appropriate ration. The electrochemical behavior of Na0.4MnO2 was investigated by cyclic voltammetry (CV) in a saturated aqueous solution of NaNO3 at scan rates from 20 to 400 mV•s-1. The initial discharge capacity of Na0.4MnO2 in NaNO3 solution was 50 mA•h•g- 1, while after 15 cycles its value increased for 9%. while the efficiency (the ratio of the capacity charge and discharge) was amounting to ~ 95%. This indicates that material synthesized by GNM can be used as cathode material in aqueous sodium-ion batteries",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia",
title = "Synthesis and characterization of Na0.4MnO2 as cathode material for aqueous sodium-ion batteries",
pages = "48-48",
url = "https://hdl.handle.net/21.15107/rcub_dais_4726"
}
Rakočević, L., Novaković, M., Potočnik, J., Jugović, D.,& Stojković Simatović, I.. (2018). Synthesis and characterization of Na0.4MnO2 as cathode material for aqueous sodium-ion batteries. in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 48-48.
https://hdl.handle.net/21.15107/rcub_dais_4726
Rakočević L, Novaković M, Potočnik J, Jugović D, Stojković Simatović I. Synthesis and characterization of Na0.4MnO2 as cathode material for aqueous sodium-ion batteries. in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia. 2018;:48-48.
https://hdl.handle.net/21.15107/rcub_dais_4726 .
Rakočević, Lazar, Novaković, Mirjana, Potočnik, Jelena, Jugović, Dragana, Stojković Simatović, Ivana, "Synthesis and characterization of Na0.4MnO2 as cathode material for aqueous sodium-ion batteries" in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia (2018):48-48,
https://hdl.handle.net/21.15107/rcub_dais_4726 .

Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite

Mravik, Željko; Bajuk Bogdanović, Danica; Marković, Smilja; Kovač, Janez; Holclajtner Antunović, Ivanka; Jovanović, Zoran

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Marković, Smilja
AU  - Kovač, Janez
AU  - Holclajtner Antunović, Ivanka
AU  - Jovanović, Zoran
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3666
AB  - The rich surface chemistry and large surface area of graphene oxide (GO) provide a platform for various functional materials that synergistically enhance charge storage properties of the composite. In present work we have investigated interaction between GO and 12- thungstophosphoric acid (WPA) in their nanocomposites as a function of different mass ratio of constituents. For this purpose, the Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometry (XPS), temperature programmed desorption method (TPD) and thermogravimetric/differential thermal analysis (TGA-DTA) methods were used. FTIR spectra have shown shifts and splitting of characteristic bands of WPA as a result of interactions with GO. Both XPS and TPD methods have shown an initial decrease of the total amount of surface oxygen groups of GO, with a minimum at around 10 wt.% of WPA, above which a restoration of the amount of surface oxygen groups was noticed. TGA-DTA analysis revealed an improved thermal stability of the material up to 25 wt.% of WPA; at higher loading of WPA the thermal properties of nanocomposite became alike to the ones of individual components. The obtained results suggest optimal conditions for preparation of GO-WPA nanocomposites for electrochemical charge storage applications.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite
SP  - 110
EP  - 110
UR  - https://hdl.handle.net/21.15107/rcub_dais_3666
ER  - 
@conference{
author = "Mravik, Željko and Bajuk Bogdanović, Danica and Marković, Smilja and Kovač, Janez and Holclajtner Antunović, Ivanka and Jovanović, Zoran",
year = "2018",
abstract = "The rich surface chemistry and large surface area of graphene oxide (GO) provide a platform for various functional materials that synergistically enhance charge storage properties of the composite. In present work we have investigated interaction between GO and 12- thungstophosphoric acid (WPA) in their nanocomposites as a function of different mass ratio of constituents. For this purpose, the Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometry (XPS), temperature programmed desorption method (TPD) and thermogravimetric/differential thermal analysis (TGA-DTA) methods were used. FTIR spectra have shown shifts and splitting of characteristic bands of WPA as a result of interactions with GO. Both XPS and TPD methods have shown an initial decrease of the total amount of surface oxygen groups of GO, with a minimum at around 10 wt.% of WPA, above which a restoration of the amount of surface oxygen groups was noticed. TGA-DTA analysis revealed an improved thermal stability of the material up to 25 wt.% of WPA; at higher loading of WPA the thermal properties of nanocomposite became alike to the ones of individual components. The obtained results suggest optimal conditions for preparation of GO-WPA nanocomposites for electrochemical charge storage applications.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite",
pages = "110-110",
url = "https://hdl.handle.net/21.15107/rcub_dais_3666"
}
Mravik, Ž., Bajuk Bogdanović, D., Marković, S., Kovač, J., Holclajtner Antunović, I.,& Jovanović, Z.. (2018). Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
Belgrade : Materials Research Society of Serbia., 110-110.
https://hdl.handle.net/21.15107/rcub_dais_3666
Mravik Ž, Bajuk Bogdanović D, Marković S, Kovač J, Holclajtner Antunović I, Jovanović Z. Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018. 2018;:110-110.
https://hdl.handle.net/21.15107/rcub_dais_3666 .
Mravik, Željko, Bajuk Bogdanović, Danica, Marković, Smilja, Kovač, Janez, Holclajtner Antunović, Ivanka, Jovanović, Zoran, "Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite" in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018 (2018):110-110,
https://hdl.handle.net/21.15107/rcub_dais_3666 .

The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Cvjetićanin, Nikola; Jokić, Bojan; Umićević, Ana; Uskoković, Dragan

(Elsevier, 2017)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Cvjetićanin, Nikola
AU  - Jokić, Bojan
AU  - Umićević, Ana
AU  - Uskoković, Dragan
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/2352
AB  - Low intrinsic electronic conductivity is the main disadvantage of LiFePO4 when used as a cathode material in lithium ion batteries. The paper offers experimental proofs of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. The LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. The crystal structure refinements in the Pnma space group reveal that doping with fluorine ions preserves the olivine structure, while reducing both the lattice parameters and the antisite defect, and increasing the crystallite size. A small amount of incorporated fluorine enhances the electrical conductivity from 4.6×10−7 S cm−1 to 2.3×10−6 S cm−1 and has a positive impact on the electrochemical performance. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) reveal differences between the two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.
PB  - Elsevier
T2  - Ceramics International
T1  - The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder
SP  - 3224
EP  - 3230
VL  - 43
IS  - 3
DO  - 10.1016/j.ceramint.2016.11.149
UR  - https://hdl.handle.net/21.15107/rcub_dais_2352
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Cvjetićanin, Nikola and Jokić, Bojan and Umićević, Ana and Uskoković, Dragan",
year = "2017",
abstract = "Low intrinsic electronic conductivity is the main disadvantage of LiFePO4 when used as a cathode material in lithium ion batteries. The paper offers experimental proofs of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. The LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. The crystal structure refinements in the Pnma space group reveal that doping with fluorine ions preserves the olivine structure, while reducing both the lattice parameters and the antisite defect, and increasing the crystallite size. A small amount of incorporated fluorine enhances the electrical conductivity from 4.6×10−7 S cm−1 to 2.3×10−6 S cm−1 and has a positive impact on the electrochemical performance. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) reveal differences between the two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder",
pages = "3224-3230",
volume = "43",
number = "3",
doi = "10.1016/j.ceramint.2016.11.149",
url = "https://hdl.handle.net/21.15107/rcub_dais_2352"
}
Jugović, D., Mitrić, M., Milović, M., Cvjetićanin, N., Jokić, B., Umićević, A.,& Uskoković, D.. (2017). The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder. in Ceramics International
Elsevier., 43(3), 3224-3230.
https://doi.org/10.1016/j.ceramint.2016.11.149
https://hdl.handle.net/21.15107/rcub_dais_2352
Jugović D, Mitrić M, Milović M, Cvjetićanin N, Jokić B, Umićević A, Uskoković D. The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder. in Ceramics International. 2017;43(3):3224-3230.
doi:10.1016/j.ceramint.2016.11.149
https://hdl.handle.net/21.15107/rcub_dais_2352 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Cvjetićanin, Nikola, Jokić, Bojan, Umićević, Ana, Uskoković, Dragan, "The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder" in Ceramics International, 43, no. 3 (2017):3224-3230,
https://doi.org/10.1016/j.ceramint.2016.11.149 .,
https://hdl.handle.net/21.15107/rcub_dais_2352 .
9
12
12

The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Cvjetićanin, Nikola; Jokić, Bojan; Umićević, Ana; Uskoković, Dragan

(Elsevier, 2017)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Cvjetićanin, Nikola
AU  - Jokić, Bojan
AU  - Umićević, Ana
AU  - Uskoković, Dragan
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/15433
AB  - Low intrinsic electronic conductivity is the main disadvantage of LiFePO4 when used as a cathode material in lithium ion batteries. The paper offers experimental proofs of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. The LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. The crystal structure refinements in the Pnma space group reveal that doping with fluorine ions preserves the olivine structure, while reducing both the lattice parameters and the antisite defect, and increasing the crystallite size. A small amount of incorporated fluorine enhances the electrical conductivity from 4.6×10−7 S cm−1 to 2.3×10−6 S cm−1 and has a positive impact on the electrochemical performance. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) reveal differences between the two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.
PB  - Elsevier
T2  - Ceramics International
T1  - The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder
SP  - 3224
EP  - 3230
VL  - 43
IS  - 3
DO  - 10.1016/j.ceramint.2016.11.149
UR  - https://hdl.handle.net/21.15107/rcub_dais_15433
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Cvjetićanin, Nikola and Jokić, Bojan and Umićević, Ana and Uskoković, Dragan",
year = "2017",
abstract = "Low intrinsic electronic conductivity is the main disadvantage of LiFePO4 when used as a cathode material in lithium ion batteries. The paper offers experimental proofs of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. The LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. The crystal structure refinements in the Pnma space group reveal that doping with fluorine ions preserves the olivine structure, while reducing both the lattice parameters and the antisite defect, and increasing the crystallite size. A small amount of incorporated fluorine enhances the electrical conductivity from 4.6×10−7 S cm−1 to 2.3×10−6 S cm−1 and has a positive impact on the electrochemical performance. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) reveal differences between the two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder",
pages = "3224-3230",
volume = "43",
number = "3",
doi = "10.1016/j.ceramint.2016.11.149",
url = "https://hdl.handle.net/21.15107/rcub_dais_15433"
}
Jugović, D., Mitrić, M., Milović, M., Cvjetićanin, N., Jokić, B., Umićević, A.,& Uskoković, D.. (2017). The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder. in Ceramics International
Elsevier., 43(3), 3224-3230.
https://doi.org/10.1016/j.ceramint.2016.11.149
https://hdl.handle.net/21.15107/rcub_dais_15433
Jugović D, Mitrić M, Milović M, Cvjetićanin N, Jokić B, Umićević A, Uskoković D. The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder. in Ceramics International. 2017;43(3):3224-3230.
doi:10.1016/j.ceramint.2016.11.149
https://hdl.handle.net/21.15107/rcub_dais_15433 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Cvjetićanin, Nikola, Jokić, Bojan, Umićević, Ana, Uskoković, Dragan, "The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder" in Ceramics International, 43, no. 3 (2017):3224-3230,
https://doi.org/10.1016/j.ceramint.2016.11.149 .,
https://hdl.handle.net/21.15107/rcub_dais_15433 .
9
12
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Characterisation of Mn0.63Zn0.37Fe2O4 powders after intensive milling and subsequent thermal treatment

Labus, Nebojša; Vasiljević, Zorka Ž.; Aleksić, Obrad S.; Luković, Miloljub D.; Marković, Smilja; Pavlović, Vladimir B.; Mentus, Slavko; Nikolić, Maria Vesna

(2017)

TY  - JOUR
AU  - Labus, Nebojša
AU  - Vasiljević, Zorka Ž.
AU  - Aleksić, Obrad S.
AU  - Luković, Miloljub D.
AU  - Marković, Smilja
AU  - Pavlović, Vladimir B.
AU  - Mentus, Slavko
AU  - Nikolić, Maria Vesna
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/2394
AB  - Commercial Mn-Zn powder (Mn0.63Zn0.37Fe2O4, 93 wt. % and Fe2O3 7 wt. %) was milled 0.5, 1, 2 and 4 hours in a planetary ball mill. The goal was to observe intensive milling influences on oxidation and reduction processes that will happen during subsequent heating. Powders were characterized with XRD, SEM and particle seizer. Subsequent heating was monitored on TGA/DTA in an air atmosphere. After compaction of the milled powders, sintering was also performed in a dilatometric device. Sintered specimens were characterized micro structurally with SEM on a fresh breakage. Obtained differential TGA diagrams suggest intensive changes during prolonged milling of the oxidation kinetics on heating. Ferrite powders changed with milling as well as with second run heating were characterized to enable determination of the potentially best ratio of milling and heating to be applied to obtain the desired microstructure.
T2  - Science of Sintering
T1  - Characterisation of Mn0.63Zn0.37Fe2O4 powders after intensive milling and subsequent thermal treatment
SP  - 455
EP  - 467
VL  - 49
IS  - 4
DO  - 10.2298/SOS1704455L
UR  - https://hdl.handle.net/21.15107/rcub_dais_2394
ER  - 
@article{
author = "Labus, Nebojša and Vasiljević, Zorka Ž. and Aleksić, Obrad S. and Luković, Miloljub D. and Marković, Smilja and Pavlović, Vladimir B. and Mentus, Slavko and Nikolić, Maria Vesna",
year = "2017",
abstract = "Commercial Mn-Zn powder (Mn0.63Zn0.37Fe2O4, 93 wt. % and Fe2O3 7 wt. %) was milled 0.5, 1, 2 and 4 hours in a planetary ball mill. The goal was to observe intensive milling influences on oxidation and reduction processes that will happen during subsequent heating. Powders were characterized with XRD, SEM and particle seizer. Subsequent heating was monitored on TGA/DTA in an air atmosphere. After compaction of the milled powders, sintering was also performed in a dilatometric device. Sintered specimens were characterized micro structurally with SEM on a fresh breakage. Obtained differential TGA diagrams suggest intensive changes during prolonged milling of the oxidation kinetics on heating. Ferrite powders changed with milling as well as with second run heating were characterized to enable determination of the potentially best ratio of milling and heating to be applied to obtain the desired microstructure.",
journal = "Science of Sintering",
title = "Characterisation of Mn0.63Zn0.37Fe2O4 powders after intensive milling and subsequent thermal treatment",
pages = "455-467",
volume = "49",
number = "4",
doi = "10.2298/SOS1704455L",
url = "https://hdl.handle.net/21.15107/rcub_dais_2394"
}
Labus, N., Vasiljević, Z. Ž., Aleksić, O. S., Luković, M. D., Marković, S., Pavlović, V. B., Mentus, S.,& Nikolić, M. V.. (2017). Characterisation of Mn0.63Zn0.37Fe2O4 powders after intensive milling and subsequent thermal treatment. in Science of Sintering, 49(4), 455-467.
https://doi.org/10.2298/SOS1704455L
https://hdl.handle.net/21.15107/rcub_dais_2394
Labus N, Vasiljević ZŽ, Aleksić OS, Luković MD, Marković S, Pavlović VB, Mentus S, Nikolić MV. Characterisation of Mn0.63Zn0.37Fe2O4 powders after intensive milling and subsequent thermal treatment. in Science of Sintering. 2017;49(4):455-467.
doi:10.2298/SOS1704455L
https://hdl.handle.net/21.15107/rcub_dais_2394 .
Labus, Nebojša, Vasiljević, Zorka Ž., Aleksić, Obrad S., Luković, Miloljub D., Marković, Smilja, Pavlović, Vladimir B., Mentus, Slavko, Nikolić, Maria Vesna, "Characterisation of Mn0.63Zn0.37Fe2O4 powders after intensive milling and subsequent thermal treatment" in Science of Sintering, 49, no. 4 (2017):455-467,
https://doi.org/10.2298/SOS1704455L .,
https://hdl.handle.net/21.15107/rcub_dais_2394 .
1
4
4

Structural and electronic properties of screen-printed Fe2O3/TiO2 thick films and their photoelectrochemical behavior

Aleksić, Obrad S.; Vasiljević, Zorka Ž.; Vujković, Milica; Nikolić, Marko G.; Labus, Nebojša; Luković, Miloljub D.; Nikolić, Maria Vesna

(Springer US, 2017)

TY  - JOUR
AU  - Aleksić, Obrad S.
AU  - Vasiljević, Zorka Ž.
AU  - Vujković, Milica
AU  - Nikolić, Marko G.
AU  - Labus, Nebojša
AU  - Luković, Miloljub D.
AU  - Nikolić, Maria Vesna
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/16011
AB  - Nanostructured Fe2TiO5 thick films were deposited on fluorine-doped tin oxide glass substrate using screen printing technology. Starting hematite and anatase nanopowders were mixed in molar ratios 1:1 and 1:1.5 and calcined in air at 900°C for 2 h to form pseudobrookite, Fe2TiO5. Functional powders and sintered thick films were analyzed by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy and transmission electron microscopy. UV–Vis analysis enabled determination of the band gap. Separation and transfer efficiency of photogenerated charge carriers was confirmed by the photoluminescence and electrochemical impedance spectra. Even though a slightly high onset oxygen evolution potential of photoexcited film electrode samples in NaOH was obtained, photocurrent densities were high, especially in the presence of H2O2 (~12 mA cm−2 at 1.7 V RHE). This work shows promise for practical application due to favorable band positions of pseudobrookite and low-cost screen printing technology.
PB  - Springer US
T2  - Journal of Materials Science
T1  - Structural and electronic properties of screen-printed Fe2O3/TiO2 thick films and their photoelectrochemical behavior
SP  - 5938
EP  - 5953
VL  - 52
IS  - 10
DO  - 10.1007/s10853-017-0830-2
UR  - https://hdl.handle.net/21.15107/rcub_dais_16011
ER  - 
@article{
author = "Aleksić, Obrad S. and Vasiljević, Zorka Ž. and Vujković, Milica and Nikolić, Marko G. and Labus, Nebojša and Luković, Miloljub D. and Nikolić, Maria Vesna",
year = "2017",
abstract = "Nanostructured Fe2TiO5 thick films were deposited on fluorine-doped tin oxide glass substrate using screen printing technology. Starting hematite and anatase nanopowders were mixed in molar ratios 1:1 and 1:1.5 and calcined in air at 900°C for 2 h to form pseudobrookite, Fe2TiO5. Functional powders and sintered thick films were analyzed by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy and transmission electron microscopy. UV–Vis analysis enabled determination of the band gap. Separation and transfer efficiency of photogenerated charge carriers was confirmed by the photoluminescence and electrochemical impedance spectra. Even though a slightly high onset oxygen evolution potential of photoexcited film electrode samples in NaOH was obtained, photocurrent densities were high, especially in the presence of H2O2 (~12 mA cm−2 at 1.7 V RHE). This work shows promise for practical application due to favorable band positions of pseudobrookite and low-cost screen printing technology.",
publisher = "Springer US",
journal = "Journal of Materials Science",
title = "Structural and electronic properties of screen-printed Fe2O3/TiO2 thick films and their photoelectrochemical behavior",
pages = "5938-5953",
volume = "52",
number = "10",
doi = "10.1007/s10853-017-0830-2",
url = "https://hdl.handle.net/21.15107/rcub_dais_16011"
}
Aleksić, O. S., Vasiljević, Z. Ž., Vujković, M., Nikolić, M. G., Labus, N., Luković, M. D.,& Nikolić, M. V.. (2017). Structural and electronic properties of screen-printed Fe2O3/TiO2 thick films and their photoelectrochemical behavior. in Journal of Materials Science
Springer US., 52(10), 5938-5953.
https://doi.org/10.1007/s10853-017-0830-2
https://hdl.handle.net/21.15107/rcub_dais_16011
Aleksić OS, Vasiljević ZŽ, Vujković M, Nikolić MG, Labus N, Luković MD, Nikolić MV. Structural and electronic properties of screen-printed Fe2O3/TiO2 thick films and their photoelectrochemical behavior. in Journal of Materials Science. 2017;52(10):5938-5953.
doi:10.1007/s10853-017-0830-2
https://hdl.handle.net/21.15107/rcub_dais_16011 .
Aleksić, Obrad S., Vasiljević, Zorka Ž., Vujković, Milica, Nikolić, Marko G., Labus, Nebojša, Luković, Miloljub D., Nikolić, Maria Vesna, "Structural and electronic properties of screen-printed Fe2O3/TiO2 thick films and their photoelectrochemical behavior" in Journal of Materials Science, 52, no. 10 (2017):5938-5953,
https://doi.org/10.1007/s10853-017-0830-2 .,
https://hdl.handle.net/21.15107/rcub_dais_16011 .
4
3
4

Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures

Nikolić, Maria Vesna; Sekulić, D. L.; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vladimir B.; Aleksić, Obrad S.

(Springer US, 2017)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Sekulić, D. L.
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vladimir B.
AU  - Aleksić, Obrad S.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/15993
AB  - In this work we have investigated changes in dielectric properties, electrical conductivity and complex impedance of Fe2TiO5 nanopowder compacts and bulk samples as a function of elevated temperature (room to 423 K compacts, to 443 K bulk samples), frequency (100 Hz–1 MHz) and composition (starting molar ratio of Fe2O3 and TiO2 1:1—PSB11 and 1:1.5—PSB115). XRD, SEM and TEM analysis of PSB11 and PSB115 powders obtained by a simple solid state process from starting hematite and anatase nanopowders confirmed the formation of nanostructured orthorhombic pseudobrookite with small amounts of excess hematite and rutile. The dielectric constant decreased with frequency and temperature for both compacts and bulk samples. Higher values were determined for bulk samples also reflecting the influence of sample composition. Change in the dielectric loss also reflected the influence of sample composition showing one maximum at high frequencies for compacts, and two maxima at room temperature for bulk samples. Complex impedance was analyzed using equivalent circuits and showed in the case of compacts the influence of both grain and grain boundary components, while in the case of bulk samples the dominant influence of grain boundaries. The temperature dependence of the determined grain and grain boundary resistance for compacts and grain boundary resistance for bulk samples was analyzed using the adiabatic small polaron hopping model enabling determination of activation energies for conduction, while the temperature dependence of relaxation times enabled determination of activation energies for relaxation. Changes in electrical conductivity for compacts and bulk samples followed Jonscher’s power law. The change of the determined frequency constant with temperature showed that at elevated temperatures the quantum mechanical-tunneling model for the case of small polaron hopping explains the conduction mechanism occurring in both compacts and bulk samples.
PB  - Springer US
T2  - Journal of Materials Science: Materials in Electronics
T1  - Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures
SP  - 4796
EP  - 4806
VL  - 28
IS  - 6
DO  - 10.1007/s10854-016-6125-6
UR  - https://hdl.handle.net/21.15107/rcub_dais_15993
ER  - 
@article{
author = "Nikolić, Maria Vesna and Sekulić, D. L. and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vladimir B. and Aleksić, Obrad S.",
year = "2017",
abstract = "In this work we have investigated changes in dielectric properties, electrical conductivity and complex impedance of Fe2TiO5 nanopowder compacts and bulk samples as a function of elevated temperature (room to 423 K compacts, to 443 K bulk samples), frequency (100 Hz–1 MHz) and composition (starting molar ratio of Fe2O3 and TiO2 1:1—PSB11 and 1:1.5—PSB115). XRD, SEM and TEM analysis of PSB11 and PSB115 powders obtained by a simple solid state process from starting hematite and anatase nanopowders confirmed the formation of nanostructured orthorhombic pseudobrookite with small amounts of excess hematite and rutile. The dielectric constant decreased with frequency and temperature for both compacts and bulk samples. Higher values were determined for bulk samples also reflecting the influence of sample composition. Change in the dielectric loss also reflected the influence of sample composition showing one maximum at high frequencies for compacts, and two maxima at room temperature for bulk samples. Complex impedance was analyzed using equivalent circuits and showed in the case of compacts the influence of both grain and grain boundary components, while in the case of bulk samples the dominant influence of grain boundaries. The temperature dependence of the determined grain and grain boundary resistance for compacts and grain boundary resistance for bulk samples was analyzed using the adiabatic small polaron hopping model enabling determination of activation energies for conduction, while the temperature dependence of relaxation times enabled determination of activation energies for relaxation. Changes in electrical conductivity for compacts and bulk samples followed Jonscher’s power law. The change of the determined frequency constant with temperature showed that at elevated temperatures the quantum mechanical-tunneling model for the case of small polaron hopping explains the conduction mechanism occurring in both compacts and bulk samples.",
publisher = "Springer US",
journal = "Journal of Materials Science: Materials in Electronics",
title = "Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures",
pages = "4796-4806",
volume = "28",
number = "6",
doi = "10.1007/s10854-016-6125-6",
url = "https://hdl.handle.net/21.15107/rcub_dais_15993"
}
Nikolić, M. V., Sekulić, D. L., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. B.,& Aleksić, O. S.. (2017). Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures. in Journal of Materials Science: Materials in Electronics
Springer US., 28(6), 4796-4806.
https://doi.org/10.1007/s10854-016-6125-6
https://hdl.handle.net/21.15107/rcub_dais_15993
Nikolić MV, Sekulić DL, Vasiljević ZŽ, Luković MD, Pavlović VB, Aleksić OS. Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures. in Journal of Materials Science: Materials in Electronics. 2017;28(6):4796-4806.
doi:10.1007/s10854-016-6125-6
https://hdl.handle.net/21.15107/rcub_dais_15993 .
Nikolić, Maria Vesna, Sekulić, D. L., Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vladimir B., Aleksić, Obrad S., "Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures" in Journal of Materials Science: Materials in Electronics, 28, no. 6 (2017):4796-4806,
https://doi.org/10.1007/s10854-016-6125-6 .,
https://hdl.handle.net/21.15107/rcub_dais_15993 .
11
11
10