Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing

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Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (en)
0-3D наноструктуре за примену у електроници и обновљивим изворима енергије: синтеза, карактеризација и процесирање (sr)
0-3D nanostrukture za primenu u elektronici i obnovljivim izvorima energije: sinteza, karakterizacija i procesiranje (sr_RS)
Authors

Publications

Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing

Nikolić, Maria Vesna; Krstić, Jugoslav; Labus, Nebojša; Luković, Miloljub; Dojčinović, Milena; Radovanović, Milan; Tadić, Nenad B.

(Elsevier, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Krstić, Jugoslav
AU  - Labus, Nebojša
AU  - Luković, Miloljub
AU  - Dojčinović, Milena
AU  - Radovanović, Milan
AU  - Tadić, Nenad B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10036
AB  - Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.
PB  - Elsevier
T2  - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
T1  - Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing
SP  - 114547
VL  - 257
DO  - 10.1016/j.mseb.2020.114547
UR  - https://hdl.handle.net/21.15107/rcub_dais_10036
ER  - 
@article{
author = "Nikolić, Maria Vesna and Krstić, Jugoslav and Labus, Nebojša and Luković, Miloljub and Dojčinović, Milena and Radovanović, Milan and Tadić, Nenad B.",
year = "2020",
abstract = "Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.",
publisher = "Elsevier",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
title = "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing",
pages = "114547",
volume = "257",
doi = "10.1016/j.mseb.2020.114547",
url = "https://hdl.handle.net/21.15107/rcub_dais_10036"
}
Nikolić, M. V., Krstić, J., Labus, N., Luković, M., Dojčinović, M., Radovanović, M.,& Tadić, N. B.. (2020). Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Elsevier., 257, 114547.
https://doi.org/10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_10036
Nikolić MV, Krstić J, Labus N, Luković M, Dojčinović M, Radovanović M, Tadić NB. Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020;257:114547.
doi:10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_10036 .
Nikolić, Maria Vesna, Krstić, Jugoslav, Labus, Nebojša, Luković, Miloljub, Dojčinović, Milena, Radovanović, Milan, Tadić, Nenad B., "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing" in Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 257 (2020):114547,
https://doi.org/10.1016/j.mseb.2020.114547 .,
https://hdl.handle.net/21.15107/rcub_dais_10036 .
3
3
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Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing

Nikolić, Maria Vesna; Krstić, Jugoslav; Labus, Nebojša; Luković, Miloljub; Dojčinović, Milena; Radovanović, Milan; Tadić, Nenad B.

(Elsevier, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Krstić, Jugoslav
AU  - Labus, Nebojša
AU  - Luković, Miloljub
AU  - Dojčinović, Milena
AU  - Radovanović, Milan
AU  - Tadić, Nenad B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/8950
AB  - Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.
PB  - Elsevier
T2  - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
T1  - Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing
SP  - 114547
VL  - 257
DO  - 10.1016/j.mseb.2020.114547
UR  - https://hdl.handle.net/21.15107/rcub_dais_8950
ER  - 
@article{
author = "Nikolić, Maria Vesna and Krstić, Jugoslav and Labus, Nebojša and Luković, Miloljub and Dojčinović, Milena and Radovanović, Milan and Tadić, Nenad B.",
year = "2020",
abstract = "Iron manganite (FeMnO3) powder with a cubic (bixbyite,−Ia3) crystal structure was obtained by a solid statereaction. Thick film paste (powder+organic vehicles) was screen printed on alumina substrate with test interdigitatedPdAg electrodes. Significant porosity (60.6%) composed of macropores (larger than 100 nm) wasdetermined by Hg porosimetry, changing only slightly from the first extrusion run indicating a stable poresystem. Hg porosimetry evaluation of thick film samples enabled estimation of true textural parameters of thethick film compared to powder. Impedance response of the thick film sensor was monitored in a humiditychamber in the relative humidity (RH) range 30–90%, at room temperature (25 °C) and frequency range from42 Hz to 1 MHz. At 100 Hz the impedance reduced from 10.41 MΩ for RH 30% to 0.68 MΩ for RH 90%. Analysisof complex impedance using an equivalent circuit showed the dominant influence of grain boundaries. Thesensor response and recovery was fast (several seconds) and a relatively low hysteresis value of 2.8% wasobtained.",
publisher = "Elsevier",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
title = "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing",
pages = "114547",
volume = "257",
doi = "10.1016/j.mseb.2020.114547",
url = "https://hdl.handle.net/21.15107/rcub_dais_8950"
}
Nikolić, M. V., Krstić, J., Labus, N., Luković, M., Dojčinović, M., Radovanović, M.,& Tadić, N. B.. (2020). Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Elsevier., 257, 114547.
https://doi.org/10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_8950
Nikolić MV, Krstić J, Labus N, Luković M, Dojčinović M, Radovanović M, Tadić NB. Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020;257:114547.
doi:10.1016/j.mseb.2020.114547
https://hdl.handle.net/21.15107/rcub_dais_8950 .
Nikolić, Maria Vesna, Krstić, Jugoslav, Labus, Nebojša, Luković, Miloljub, Dojčinović, Milena, Radovanović, Milan, Tadić, Nenad B., "Structural, morphological and textural properties of iron manganite (FeMnO3) thick films applied for humidity sensing" in Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 257 (2020):114547,
https://doi.org/10.1016/j.mseb.2020.114547 .,
https://hdl.handle.net/21.15107/rcub_dais_8950 .
3
3
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Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Labus, Nebojša

(IEEE, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Labus, Nebojša
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/7450
AB  - Nanocomposite Zn2SnO4/SnO2 powder was
obtained by solid state synthesis from homogenized
starting nanopowders of ZnO and SnO2, mixed in the 1:1
molar ratio, structurally and morphologically characterized
using X-ray diffraction (XRD) and Scanning Electron
Microscopy (SEM). Thick film paste was made by adding
organic vehicles to the obtained powder. Three to five
layers (layer thickness approx. 12 µm) were screen printed
on alumina substrate with small test PdAg electrodes and
fired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.
Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where the
relative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overall
sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from
6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and
90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for
application in humidity sensing.
PB  - IEEE
T2  - IEEE Sensors Journal
T1  - Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material
SP  - 7509
EP  - 7516
VL  - 20
IS  - 14
DO  - 10.1109/JSEN.2020.2983135
UR  - https://hdl.handle.net/21.15107/rcub_dais_7450
ER  - 
@article{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Labus, Nebojša",
year = "2020",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder was
obtained by solid state synthesis from homogenized
starting nanopowders of ZnO and SnO2, mixed in the 1:1
molar ratio, structurally and morphologically characterized
using X-ray diffraction (XRD) and Scanning Electron
Microscopy (SEM). Thick film paste was made by adding
organic vehicles to the obtained powder. Three to five
layers (layer thickness approx. 12 µm) were screen printed
on alumina substrate with small test PdAg electrodes and
fired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.
Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where the
relative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overall
sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from
6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and
90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for
application in humidity sensing.",
publisher = "IEEE",
journal = "IEEE Sensors Journal",
title = "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material",
pages = "7509-7516",
volume = "20",
number = "14",
doi = "10.1109/JSEN.2020.2983135",
url = "https://hdl.handle.net/21.15107/rcub_dais_7450"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Ž., Luković, M. D.,& Labus, N.. (2020). Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal
IEEE., 20(14), 7509-7516.
https://doi.org/10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_7450
Nikolić MV, Dojčinović M, Vasiljević ZŽ, Luković MD, Labus N. Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal. 2020;20(14):7509-7516.
doi:10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_7450 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Ž., Luković, Miloljub D., Labus, Nebojša, "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material" in IEEE Sensors Journal, 20, no. 14 (2020):7509-7516,
https://doi.org/10.1109/JSEN.2020.2983135 .,
https://hdl.handle.net/21.15107/rcub_dais_7450 .
6
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Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Labus, Nebojša

(IEEE, 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Labus, Nebojša
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/8942
AB  - Nanocomposite Zn2SnO4/SnO2 powder wasobtained by solid state synthesis from homogenizedstarting nanopowders of ZnO and SnO2, mixed in the 1:1molar ratio, structurally and morphologically characterizedusing X-ray diffraction (XRD) and Scanning ElectronMicroscopy (SEM). Thick film paste was made by addingorganic vehicles to the obtained powder. Three to fivelayers (layer thickness approx. 12 µm) were screen printedon alumina substrate with small test PdAg electrodes andfired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where therelative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overallsensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential forapplication in humidity sensing.
PB  - IEEE
T2  - IEEE Sensors Journal
T1  - Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material
SP  - 7509
EP  - 7516
VL  - 20
IS  - 14
DO  - 10.1109/JSEN.2020.2983135
UR  - https://hdl.handle.net/21.15107/rcub_dais_8942
ER  - 
@article{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Labus, Nebojša",
year = "2020",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder wasobtained by solid state synthesis from homogenizedstarting nanopowders of ZnO and SnO2, mixed in the 1:1molar ratio, structurally and morphologically characterizedusing X-ray diffraction (XRD) and Scanning ElectronMicroscopy (SEM). Thick film paste was made by addingorganic vehicles to the obtained powder. Three to fivelayers (layer thickness approx. 12 µm) were screen printedon alumina substrate with small test PdAg electrodes andfired at 600oC for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing.Impedance response was studied at the working temperatures of 25 and 50oC in a humidity chamber where therelative humidity (RH) was 30-90% and measured frequency 42 Hz – 1 MHz. With increase in film thickness the overallsensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 µm), from 23.4 to 0.25 MΩ (48 µm) and from6.8 to 0.02 MΩ (36 µm) at 25 oC, while at 50 oC and also 100 Hz it reduced from 14 MΩ to 0.72 MΩ (48 µm) for RH 30 and90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential forapplication in humidity sensing.",
publisher = "IEEE",
journal = "IEEE Sensors Journal",
title = "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material",
pages = "7509-7516",
volume = "20",
number = "14",
doi = "10.1109/JSEN.2020.2983135",
url = "https://hdl.handle.net/21.15107/rcub_dais_8942"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Ž., Luković, M. D.,& Labus, N.. (2020). Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal
IEEE., 20(14), 7509-7516.
https://doi.org/10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_8942
Nikolić MV, Dojčinović M, Vasiljević ZŽ, Luković MD, Labus N. Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal. 2020;20(14):7509-7516.
doi:10.1109/JSEN.2020.2983135
https://hdl.handle.net/21.15107/rcub_dais_8942 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Ž., Luković, Miloljub D., Labus, Nebojša, "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material" in IEEE Sensors Journal, 20, no. 14 (2020):7509-7516,
https://doi.org/10.1109/JSEN.2020.2983135 .,
https://hdl.handle.net/21.15107/rcub_dais_8942 .
6
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5

Sinteza, struktura, karakterizacija i fotoelektrohemijska primena debelih slojeva pseudobrukita, Fe2TiO5

Vasiljević, Zorka Ž.

(Универзитет у Београду, Технолошко-металуршки факултет, 2019)

TY  - THES
AU  - Vasiljević, Zorka Ž.
PY  - 2019
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=7301
UR  - http://nardus.mpn.gov.rs/handle/123456789/12112
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:21082/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=51887375
UR  - https://dais.sanu.ac.rs/123456789/9153
AB  - U poređenju sa fotonaponskim ćelijama, fotoelektrohemijske ćelije predstavljajuefikasan vid pretvaranja sunčeve energije u električnu, jer se pored energije dobija ivodonik koji se može iskoristiti kao gorivo. Fotoelektrohemijske ćelije sastoje se odpoluprovodničke anode (p- ili n-tipa) koja apsorbuje svetlost, pri čemu se konverzijaenergije odigrava na granici faza poluprovodnik-elektrolit.U ovoj doktorskoj disertaciji primenjena su tri istraživačka pravca za dobijanjefilmova u svojstvu fotoaktivnih anoda. Prvi istraživački pravac bio je pripremananočestičnog poluprovodnika - pseudobrukita, Fe2TiO5, reakcijom u čvrstom stanjuizmeđu anatasa, TiO2 i hematita, α-Fe2O3. Analiza dobijanja najpre je praćena natabletama radi optimizacije sastava, temperature i vremena sinterovanja. Ispitan je uticajpromene temperature sinterovanja (750 – 1250 C) na fazni sastav, temperaturu faznogprelaza, morfologiju, kao i električna svojstva sinterovanih uzoraka. Izabrane su dveoksidne smeše  maseni odnos prahova 40%α-Fe2O3/60%TiO2 (4F6T) i60%α-Fe2O3/40%TiO2 (6F4T) što približno odgovara molskom odnosu početnihprahova hematita i anatasa od 1:3 i 1,5:2, sa ciljem da se dobije pseudobrukit i analizirauticaj viška anatasa. Uzorci sinterovani na temperaturi 850 C sadržali su rutil ipseudobrukit sa rombičnom strukturom čime je potvrđeno da gvožđe ubrzava faznutransformaciju anatasa u rutil pri čemu se formira i pseudobrukitna faza. Dalje povišenjetemperature uticalo je na povećanje gustine uzoraka, promene u veličini zrna ismanjenje električne otpornosti.Drugi istraživački pravac bio je priprema elektrodnih filmova sitoštampanjempasti koje su dobijene mešanjem homogenizovanih prahova sa organskom smolom(butil celuloza), rastvaračem (terpinol) i malom količinom veziva – ROSiO2B2O3staklo (RO-oksid retkih zemalja). Dobijene paste deponovane su sitoštampom nasupstrat od alumine i potom sinterovane u hibridnoj peći 60 minuta u temperaturnomopsegu 800 – 950 C. Rendgenskom difrakcionom analizom utvrđeno je da se na800 C formira monoklinični pseudobrukit i da je završena fazna transformacija anatasau rutil, kao i da je dalje povišenje temperature utiče na prelaz monokliničnog u rombičnipseudobrukit. Uzorci sinterovani na 850 C imali su malu veličinu zrna sa homogenomstrukturom, dok je dalje povišenje temperature uticalo na formiranje pseudobrukita savećim zrnima štapićastog oblika. Strujno-naponska analiza pokazala je da uzorak60%α-Fe2O3/40%TiO2 sinterovan na 850 C ima mogućnost za primenu ufotoelektrohemijskim ćelijama...
AB  - Compared to photovoltaic cells, photoelectrochemical cells represent an efficientway of converting solar into electrical energy, because besides energy, hydrogen is alsoavailable that could be used as a fuel. A photoelectrochemical cell consists of asemiconductor anode (p- or n-type) that absorbs light, whereby energy conversion takesplace at the boundary of the semiconductor-electrolyte phase.This doctoral dissertation is divided into three main research directions, relatedto the preparation of films in the form of photoactive anodes. The first one describespreparation of the nanoparticle semiconductor - pseudobrookite, Fe2TiO5, by a solidstate reaction between anatase, TiO2, and hematite, α-Fe2O3. Pseudobrookite formationwas first monitored on tablets to optimize the composition, temperature and time ofsintering. The influence of the sintering temperature (750 –1250C) on the phasecomposition, phase transition temperature, morphology and electrical properties of bulksintered powder mixtures composed of starting anatase and hematite nanopowders wasinvestigated. Two oxide mixtures were first selected - nanopowders of -Fe2O3(hematite) and TiO2 (anatase 99.7%) were mixed in the weight ratios 40:60 and 60:40,respectively which approximately corresponds to the molar ratios of starting hematiteand anatase powders of 1:3 and 1.5:2, with the aim of obtaining pseudobrookite andanalyzing the effect of excess anatase. Samples sintered at 850 °C contained rutile andpseudobrookite with an orthorhombic structure, which confirmed that iron acceleratesthe phase transformation of anatase to rutile, thereby forming a pseudobrookite phase.Higher sintering temperatures lead to increased sample density, changes in grain sizeand decreased electric resistivity.The second research direction was the preparation of films starting fromprepared oxide mixtures with an organic vehicle (butyl cellulose), solvent (terpinol) anda small amount of binding lead boron silicone oxide glass frit (ROSiO2B2O3). Pasteswere deposited onto alumina substrate using the screen printing technique and thensintered 60 minutes at 800  950 C. X-ray diffraction analysis determined formation ofmonoclinic pseudobrookite at 800 C and completion of the phase transformation ofanatase into rutile. Further increase in temperature leads to the transition of monoclinicpseudobrookite into orthorhombic pseudobrookite. Samples sintered at 850 C still hada small grain size, with a relatively homogenous distribution, while further increase intemperature lead to the formation of larger rod-shaped grains. Analysis of currentvoltage measurements of thick film samples sintered at 850 C showed that the60%α-Fe2O3/40%TiO2 sample had potential for application as a photoanode for lightdriven water splitting...
PB  - Универзитет у Београду, Технолошко-металуршки факултет
T2  - Универзитет у Београду
T1  - Sinteza, struktura, karakterizacija i fotoelektrohemijska primena debelih slojeva pseudobrukita, Fe2TiO5
UR  - https://hdl.handle.net/21.15107/rcub_dais_9153
ER  - 
@phdthesis{
author = "Vasiljević, Zorka Ž.",
year = "2019",
abstract = "U poređenju sa fotonaponskim ćelijama, fotoelektrohemijske ćelije predstavljajuefikasan vid pretvaranja sunčeve energije u električnu, jer se pored energije dobija ivodonik koji se može iskoristiti kao gorivo. Fotoelektrohemijske ćelije sastoje se odpoluprovodničke anode (p- ili n-tipa) koja apsorbuje svetlost, pri čemu se konverzijaenergije odigrava na granici faza poluprovodnik-elektrolit.U ovoj doktorskoj disertaciji primenjena su tri istraživačka pravca za dobijanjefilmova u svojstvu fotoaktivnih anoda. Prvi istraživački pravac bio je pripremananočestičnog poluprovodnika - pseudobrukita, Fe2TiO5, reakcijom u čvrstom stanjuizmeđu anatasa, TiO2 i hematita, α-Fe2O3. Analiza dobijanja najpre je praćena natabletama radi optimizacije sastava, temperature i vremena sinterovanja. Ispitan je uticajpromene temperature sinterovanja (750 – 1250 C) na fazni sastav, temperaturu faznogprelaza, morfologiju, kao i električna svojstva sinterovanih uzoraka. Izabrane su dveoksidne smeše  maseni odnos prahova 40%α-Fe2O3/60%TiO2 (4F6T) i60%α-Fe2O3/40%TiO2 (6F4T) što približno odgovara molskom odnosu početnihprahova hematita i anatasa od 1:3 i 1,5:2, sa ciljem da se dobije pseudobrukit i analizirauticaj viška anatasa. Uzorci sinterovani na temperaturi 850 C sadržali su rutil ipseudobrukit sa rombičnom strukturom čime je potvrđeno da gvožđe ubrzava faznutransformaciju anatasa u rutil pri čemu se formira i pseudobrukitna faza. Dalje povišenjetemperature uticalo je na povećanje gustine uzoraka, promene u veličini zrna ismanjenje električne otpornosti.Drugi istraživački pravac bio je priprema elektrodnih filmova sitoštampanjempasti koje su dobijene mešanjem homogenizovanih prahova sa organskom smolom(butil celuloza), rastvaračem (terpinol) i malom količinom veziva – ROSiO2B2O3staklo (RO-oksid retkih zemalja). Dobijene paste deponovane su sitoštampom nasupstrat od alumine i potom sinterovane u hibridnoj peći 60 minuta u temperaturnomopsegu 800 – 950 C. Rendgenskom difrakcionom analizom utvrđeno je da se na800 C formira monoklinični pseudobrukit i da je završena fazna transformacija anatasau rutil, kao i da je dalje povišenje temperature utiče na prelaz monokliničnog u rombičnipseudobrukit. Uzorci sinterovani na 850 C imali su malu veličinu zrna sa homogenomstrukturom, dok je dalje povišenje temperature uticalo na formiranje pseudobrukita savećim zrnima štapićastog oblika. Strujno-naponska analiza pokazala je da uzorak60%α-Fe2O3/40%TiO2 sinterovan na 850 C ima mogućnost za primenu ufotoelektrohemijskim ćelijama..., Compared to photovoltaic cells, photoelectrochemical cells represent an efficientway of converting solar into electrical energy, because besides energy, hydrogen is alsoavailable that could be used as a fuel. A photoelectrochemical cell consists of asemiconductor anode (p- or n-type) that absorbs light, whereby energy conversion takesplace at the boundary of the semiconductor-electrolyte phase.This doctoral dissertation is divided into three main research directions, relatedto the preparation of films in the form of photoactive anodes. The first one describespreparation of the nanoparticle semiconductor - pseudobrookite, Fe2TiO5, by a solidstate reaction between anatase, TiO2, and hematite, α-Fe2O3. Pseudobrookite formationwas first monitored on tablets to optimize the composition, temperature and time ofsintering. The influence of the sintering temperature (750 –1250C) on the phasecomposition, phase transition temperature, morphology and electrical properties of bulksintered powder mixtures composed of starting anatase and hematite nanopowders wasinvestigated. Two oxide mixtures were first selected - nanopowders of -Fe2O3(hematite) and TiO2 (anatase 99.7%) were mixed in the weight ratios 40:60 and 60:40,respectively which approximately corresponds to the molar ratios of starting hematiteand anatase powders of 1:3 and 1.5:2, with the aim of obtaining pseudobrookite andanalyzing the effect of excess anatase. Samples sintered at 850 °C contained rutile andpseudobrookite with an orthorhombic structure, which confirmed that iron acceleratesthe phase transformation of anatase to rutile, thereby forming a pseudobrookite phase.Higher sintering temperatures lead to increased sample density, changes in grain sizeand decreased electric resistivity.The second research direction was the preparation of films starting fromprepared oxide mixtures with an organic vehicle (butyl cellulose), solvent (terpinol) anda small amount of binding lead boron silicone oxide glass frit (ROSiO2B2O3). Pasteswere deposited onto alumina substrate using the screen printing technique and thensintered 60 minutes at 800  950 C. X-ray diffraction analysis determined formation ofmonoclinic pseudobrookite at 800 C and completion of the phase transformation ofanatase into rutile. Further increase in temperature leads to the transition of monoclinicpseudobrookite into orthorhombic pseudobrookite. Samples sintered at 850 C still hada small grain size, with a relatively homogenous distribution, while further increase intemperature lead to the formation of larger rod-shaped grains. Analysis of currentvoltage measurements of thick film samples sintered at 850 C showed that the60%α-Fe2O3/40%TiO2 sample had potential for application as a photoanode for lightdriven water splitting...",
publisher = "Универзитет у Београду, Технолошко-металуршки факултет",
journal = "Универзитет у Београду",
title = "Sinteza, struktura, karakterizacija i fotoelektrohemijska primena debelih slojeva pseudobrukita, Fe2TiO5",
url = "https://hdl.handle.net/21.15107/rcub_dais_9153"
}
Vasiljević, Z. Ž.. (2019). Sinteza, struktura, karakterizacija i fotoelektrohemijska primena debelih slojeva pseudobrukita, Fe2TiO5. in Универзитет у Београду
Универзитет у Београду, Технолошко-металуршки факултет..
https://hdl.handle.net/21.15107/rcub_dais_9153
Vasiljević ZŽ. Sinteza, struktura, karakterizacija i fotoelektrohemijska primena debelih slojeva pseudobrukita, Fe2TiO5. in Универзитет у Београду. 2019;.
https://hdl.handle.net/21.15107/rcub_dais_9153 .
Vasiljević, Zorka Ž., "Sinteza, struktura, karakterizacija i fotoelektrohemijska primena debelih slojeva pseudobrukita, Fe2TiO5" in Универзитет у Београду (2019),
https://hdl.handle.net/21.15107/rcub_dais_9153 .

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - https://dais.sanu.ac.rs/123456789/5763
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
UR  - https://hdl.handle.net/21.15107/rcub_dais_5763
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095",
url = "https://hdl.handle.net/21.15107/rcub_dais_5763"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5763
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5763 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .,
https://hdl.handle.net/21.15107/rcub_dais_5763 .
10
10
9

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - https://dais.sanu.ac.rs/123456789/5272
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
UR  - https://hdl.handle.net/21.15107/rcub_dais_5272
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095",
url = "https://hdl.handle.net/21.15107/rcub_dais_5272"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5272
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5272 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .,
https://hdl.handle.net/21.15107/rcub_dais_5272 .
10
10
9

Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Krstić, Jugoslav B.; Vujančević, Jelena; Tadić, Nenad B.; Vlahović, Branislav; Pavlović, Vladimir B.

(John Wiley & Sons, Inc., 2019)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Krstić, Jugoslav B.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/ijac.13190
UR  - https://dais.sanu.ac.rs/123456789/5766
AB  - Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.
PB  - John Wiley & Sons, Inc.
T2  - International Journal of Applied Ceramic Technology
T1  - Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing
SP  - 981
EP  - 993
VL  - 16
IS  - 3
DO  - 10.1111/ijac.13190
UR  - https://hdl.handle.net/21.15107/rcub_dais_5766
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Krstić, Jugoslav B. and Vujančević, Jelena and Tadić, Nenad B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.",
publisher = "John Wiley & Sons, Inc.",
journal = "International Journal of Applied Ceramic Technology",
title = "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing",
pages = "981-993",
volume = "16",
number = "3",
doi = "10.1111/ijac.13190",
url = "https://hdl.handle.net/21.15107/rcub_dais_5766"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Krstić, J. B., Vujančević, J., Tadić, N. B., Vlahović, B.,& Pavlović, V. B.. (2019). Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology
John Wiley & Sons, Inc.., 16(3), 981-993.
https://doi.org/10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_5766
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Krstić JB, Vujančević J, Tadić NB, Vlahović B, Pavlović VB. Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology. 2019;16(3):981-993.
doi:10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_5766 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Krstić, Jugoslav B., Vujančević, Jelena, Tadić, Nenad B., Vlahović, Branislav, Pavlović, Vladimir B., "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing" in International Journal of Applied Ceramic Technology, 16, no. 3 (2019):981-993,
https://doi.org/10.1111/ijac.13190 .,
https://hdl.handle.net/21.15107/rcub_dais_5766 .
14
12
13

Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Krstić, Jugoslav B.; Vujančević, Jelena; Tadić, Nenad B.; Vlahović, Branislav; Pavlović, Vladimir B.

(John Wiley & Sons, Inc., 2019)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Krstić, Jugoslav B.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/ijac.13190
UR  - https://dais.sanu.ac.rs/123456789/4848
AB  - Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.
PB  - John Wiley & Sons, Inc.
T2  - International Journal of Applied Ceramic Technology
T1  - Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing
SP  - 981
EP  - 993
VL  - 16
IS  - 3
DO  - 10.1111/ijac.13190
UR  - https://hdl.handle.net/21.15107/rcub_dais_4848
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Krstić, Jugoslav B. and Vujančević, Jelena and Tadić, Nenad B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Zinc ferrite nanocrystalline powder was obtained by solid state synthesis of starting zinc oxide and hematite nanopowders. Field emission scanning electron microscopy (FESEM and transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of nanocrystalline zinc‐ferrite powder with a mixed spinel structure with small amounts of remaining zinc oxide and hematite as impurities. Thick film paste was formed and screen printed on test interdigitated PdAg electrodes on alumina substrate. Formation of a porous nanocrystalline structure was confirmed by scanning electron microscopy (SEM) and Hg porosimetry. Humidity sensing properties of zinc ferrite thick films were investigated by monitoring the change in impedance in the relative humidity interval 30‐90% in the frequency range 42 Hz – 1 MHz at room temperature (25 °C) and 50 °C. At 42 Hz at both analyzed temperatures the impedance reduced ~ 46 times in the humidity range 30‐90%. The dominant influence of grain boundaries was confirmed by analysis of complex impedance with an equivalent circuit.",
publisher = "John Wiley & Sons, Inc.",
journal = "International Journal of Applied Ceramic Technology",
title = "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing",
pages = "981-993",
volume = "16",
number = "3",
doi = "10.1111/ijac.13190",
url = "https://hdl.handle.net/21.15107/rcub_dais_4848"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Krstić, J. B., Vujančević, J., Tadić, N. B., Vlahović, B.,& Pavlović, V. B.. (2019). Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology
John Wiley & Sons, Inc.., 16(3), 981-993.
https://doi.org/10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_4848
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Krstić JB, Vujančević J, Tadić NB, Vlahović B, Pavlović VB. Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing. in International Journal of Applied Ceramic Technology. 2019;16(3):981-993.
doi:10.1111/ijac.13190
https://hdl.handle.net/21.15107/rcub_dais_4848 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Krstić, Jugoslav B., Vujančević, Jelena, Tadić, Nenad B., Vlahović, Branislav, Pavlović, Vladimir B., "Investigation of ZnFe2O4 spinel ferrite nanocrystalline screen‐printed thick films for application in humidity sensing" in International Journal of Applied Ceramic Technology, 16, no. 3 (2019):981-993,
https://doi.org/10.1111/ijac.13190 .,
https://hdl.handle.net/21.15107/rcub_dais_4848 .
14
12
13

Characterization of MgAl2O4 sintered ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Corlett, Cole; Đorđević, Pavle; Rogan, Jelena; Vulić, Predrag J.; Buljak, Vladimir; Pavlović, Vladimir B.

(ETRAN, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Corlett, Cole
AU  - Đorđević, Pavle
AU  - Rogan, Jelena
AU  - Vulić, Predrag J.
AU  - Buljak, Vladimir
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6949
AB  - Single phase MgAl2O4 was made from a one-to-one molar ratio of MgO and Al2O3 powders mixed using ball-milling. Mixtures of MgO and Al2O3 were subsequently treated in planetary ball mill for 30, 60, 90 and 120 minutes in air. The aim of this study was to examine phase composition, microstructure, and densification behavior of sintered specimens. After sintering in dilatometer at 1500 °C, the powder was converted to single phase MgAl2O4. The results show that mechanical activation improved the densification behavior of MgAl2O4 sintered specimens, and it reduced the onset temperature for sintering by approx. 100 oC. Based on dilatometer data, powders were subsequently densified at 1450 oC by hot pressing. Almost аll specimens exhibited full density, while sample activated for 30 minutes showed the fastest densification rate.
PB  - ETRAN
T2  - Science of Sintering
T1  - Characterization of MgAl2O4 sintered ceramics
SP  - 363
EP  - 376
VL  - 51
IS  - 4
DO  - 10.2298/SOS1904363O
UR  - https://hdl.handle.net/21.15107/rcub_dais_6949
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Corlett, Cole and Đorđević, Pavle and Rogan, Jelena and Vulić, Predrag J. and Buljak, Vladimir and Pavlović, Vladimir B.",
year = "2019",
abstract = "Single phase MgAl2O4 was made from a one-to-one molar ratio of MgO and Al2O3 powders mixed using ball-milling. Mixtures of MgO and Al2O3 were subsequently treated in planetary ball mill for 30, 60, 90 and 120 minutes in air. The aim of this study was to examine phase composition, microstructure, and densification behavior of sintered specimens. After sintering in dilatometer at 1500 °C, the powder was converted to single phase MgAl2O4. The results show that mechanical activation improved the densification behavior of MgAl2O4 sintered specimens, and it reduced the onset temperature for sintering by approx. 100 oC. Based on dilatometer data, powders were subsequently densified at 1450 oC by hot pressing. Almost аll specimens exhibited full density, while sample activated for 30 minutes showed the fastest densification rate.",
publisher = "ETRAN",
journal = "Science of Sintering",
title = "Characterization of MgAl2O4 sintered ceramics",
pages = "363-376",
volume = "51",
number = "4",
doi = "10.2298/SOS1904363O",
url = "https://hdl.handle.net/21.15107/rcub_dais_6949"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Corlett, C., Đorđević, P., Rogan, J., Vulić, P. J., Buljak, V.,& Pavlović, V. B.. (2019). Characterization of MgAl2O4 sintered ceramics. in Science of Sintering
ETRAN., 51(4), 363-376.
https://doi.org/10.2298/SOS1904363O
https://hdl.handle.net/21.15107/rcub_dais_6949
Obradović N, Fahrenholtz WG, Filipović S, Corlett C, Đorđević P, Rogan J, Vulić PJ, Buljak V, Pavlović VB. Characterization of MgAl2O4 sintered ceramics. in Science of Sintering. 2019;51(4):363-376.
doi:10.2298/SOS1904363O
https://hdl.handle.net/21.15107/rcub_dais_6949 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Corlett, Cole, Đorđević, Pavle, Rogan, Jelena, Vulić, Predrag J., Buljak, Vladimir, Pavlović, Vladimir B., "Characterization of MgAl2O4 sintered ceramics" in Science of Sintering, 51, no. 4 (2019):363-376,
https://doi.org/10.2298/SOS1904363O .,
https://hdl.handle.net/21.15107/rcub_dais_6949 .
2
5
5

Nanocrystalline iron-manganite (FeMnO3) applied for humidity sensing

Vasiljević, Zorka Ž.; Dojčinović, Milena; Vujančević, Jelena; Tadić, Nenad B.; Nikolić, Maria Vesna

(Belgrade : Institute for Multidisciplinary Research, 2019)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7005
AB  - Nanocrystalline iron manganite was synthesized using a sol-gel self-combustion method with glycine as fuel, followed by calcination at 900 °C for 8 hours. Structural characterization was performed using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). It confirmed the formation of nanocrystalline iron-manganite with a perovskite structure. Humidity sensing properties of bulk and thick film samples of the obtained nanocrystalline iron manganite powder were analyzed. Organic vehicles were added to the powder to form a thick film paste that was screen printed on alumina substrate with test PdAg interdigitated electrodes. Impedance response of bulk and thick film samples was analyzed in a humidity chamber in the relative humidity range 30-90% in the frequency range 42 Hz to 1 MHz in view of applying iron-manganite for humidity sensing applications.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - Nanocrystalline iron-manganite (FeMnO3) applied for humidity sensing
SP  - 94
EP  - 94
UR  - https://hdl.handle.net/21.15107/rcub_dais_7005
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "Nanocrystalline iron manganite was synthesized using a sol-gel self-combustion method with glycine as fuel, followed by calcination at 900 °C for 8 hours. Structural characterization was performed using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). It confirmed the formation of nanocrystalline iron-manganite with a perovskite structure. Humidity sensing properties of bulk and thick film samples of the obtained nanocrystalline iron manganite powder were analyzed. Organic vehicles were added to the powder to form a thick film paste that was screen printed on alumina substrate with test PdAg interdigitated electrodes. Impedance response of bulk and thick film samples was analyzed in a humidity chamber in the relative humidity range 30-90% in the frequency range 42 Hz to 1 MHz in view of applying iron-manganite for humidity sensing applications.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "Nanocrystalline iron-manganite (FeMnO3) applied for humidity sensing",
pages = "94-94",
url = "https://hdl.handle.net/21.15107/rcub_dais_7005"
}
Vasiljević, Z. Ž., Dojčinović, M., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2019). Nanocrystalline iron-manganite (FeMnO3) applied for humidity sensing. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 94-94.
https://hdl.handle.net/21.15107/rcub_dais_7005
Vasiljević ZŽ, Dojčinović M, Vujančević J, Tadić NB, Nikolić MV. Nanocrystalline iron-manganite (FeMnO3) applied for humidity sensing. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:94-94.
https://hdl.handle.net/21.15107/rcub_dais_7005 .
Vasiljević, Zorka Ž., Dojčinović, Milena, Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "Nanocrystalline iron-manganite (FeMnO3) applied for humidity sensing" in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):94-94,
https://hdl.handle.net/21.15107/rcub_dais_7005 .

Influence of Co2+ ions on photocatalytic properties of MgFe2O4 ferrites

Vasiljević, Zorka Ž.; Dojčinović, Milena; Pavlović, Vera P.; Vujančević, Jelena; Marković, Smilja; Tadić, Nenad B.; Nikolić, Maria Vesna

(Belgrade : Institute for Multidisciplinary Research, 2019)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Marković, Smilja
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7003
AB  - In this work, spinel magnesium cobalt ferrites (CoxMg1-xFe2O4, x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9) were synthesized by a sol-gel combustion method. Magnesium nitrate, cobalt nitrate and iron nitrate were used as oxidizers and citric acid was used as a reducing agent. The effects of cobalt ions on structural and morphological properties were investigated and characterized by X-ray diffraction (XRD), Raman spectroscopy, Field emission scanning electron microscope (FESEM) and Fourier transform infrared (FT-IR) spectroscopy. A cubic spinel structure formed with a varied distribution of cobalt and magnesium ions on tetrahedral and octahedral sites that depended on their content. All ferrite powders consisted of multigrain agglomerates. Optical properties were investigated by UV- vis spectrophotometry. The photocatalytic activity of as prepared samples was evaluated by measuring the rate of photodegradation reaction of methylene blue (MB) under visible light irradiation. After 240 min, compared to other samples, the sample labeled as Co0.1Mg0.9Fe2O4 showed the best rate of photodecomposition of MB resulting in reduction of 90% of its initial concentration.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - Influence of Co2+ ions on photocatalytic properties of MgFe2O4 ferrites
SP  - 73
EP  - 73
UR  - https://hdl.handle.net/21.15107/rcub_dais_7003
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena and Pavlović, Vera P. and Vujančević, Jelena and Marković, Smilja and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "In this work, spinel magnesium cobalt ferrites (CoxMg1-xFe2O4, x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9) were synthesized by a sol-gel combustion method. Magnesium nitrate, cobalt nitrate and iron nitrate were used as oxidizers and citric acid was used as a reducing agent. The effects of cobalt ions on structural and morphological properties were investigated and characterized by X-ray diffraction (XRD), Raman spectroscopy, Field emission scanning electron microscope (FESEM) and Fourier transform infrared (FT-IR) spectroscopy. A cubic spinel structure formed with a varied distribution of cobalt and magnesium ions on tetrahedral and octahedral sites that depended on their content. All ferrite powders consisted of multigrain agglomerates. Optical properties were investigated by UV- vis spectrophotometry. The photocatalytic activity of as prepared samples was evaluated by measuring the rate of photodegradation reaction of methylene blue (MB) under visible light irradiation. After 240 min, compared to other samples, the sample labeled as Co0.1Mg0.9Fe2O4 showed the best rate of photodecomposition of MB resulting in reduction of 90% of its initial concentration.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "Influence of Co2+ ions on photocatalytic properties of MgFe2O4 ferrites",
pages = "73-73",
url = "https://hdl.handle.net/21.15107/rcub_dais_7003"
}
Vasiljević, Z. Ž., Dojčinović, M., Pavlović, V. P., Vujančević, J., Marković, S., Tadić, N. B.,& Nikolić, M. V.. (2019). Influence of Co2+ ions on photocatalytic properties of MgFe2O4 ferrites. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 73-73.
https://hdl.handle.net/21.15107/rcub_dais_7003
Vasiljević ZŽ, Dojčinović M, Pavlović VP, Vujančević J, Marković S, Tadić NB, Nikolić MV. Influence of Co2+ ions on photocatalytic properties of MgFe2O4 ferrites. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:73-73.
https://hdl.handle.net/21.15107/rcub_dais_7003 .
Vasiljević, Zorka Ž., Dojčinović, Milena, Pavlović, Vera P., Vujančević, Jelena, Marković, Smilja, Tadić, Nenad B., Nikolić, Maria Vesna, "Influence of Co2+ ions on photocatalytic properties of MgFe2O4 ferrites" in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):73-73,
https://hdl.handle.net/21.15107/rcub_dais_7003 .

Structure and photocatalytic properties of sol-gel synthesized pseudobrookite

Vasiljević, Zorka Ž.; Dojčinović, Milena; Janković Častvan, Ivona; Vujančević, Jelena; Tadić, Nenad B.; Nikolić, Maria Vesna

(Novi Sad : Faculty of Technology, 2019)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Janković Častvan, Ivona
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6988
AB  - Fe2TiO5 nanopartcles were synthesized by modified sol-gel method with aid of
Fe(NO3)3 9H2O and Ti(OC3H7)4 as starting reagents, oxalic acid as chilate agent and cetyltrimethylammonium bromide as surfactant. The aim of this study was to asses the photocatalytic degradaton of the antibiotic Oxytetracycline (OTC) using visible light irradiation. As prepared nanoparticles were characterized by XRD, BET, FESEM and UV-vis DRS. The optimal operating conditions of oxytetracycline photocatalytic degradation were achived by changing the pH of the solution and changing the concentration of photocatalyst.
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad
T1  - Structure and photocatalytic properties of sol-gel synthesized pseudobrookite
SP  - 133
EP  - 133
UR  - https://hdl.handle.net/21.15107/rcub_dais_6988
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena and Janković Častvan, Ivona and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "Fe2TiO5 nanopartcles were synthesized by modified sol-gel method with aid of
Fe(NO3)3 9H2O and Ti(OC3H7)4 as starting reagents, oxalic acid as chilate agent and cetyltrimethylammonium bromide as surfactant. The aim of this study was to asses the photocatalytic degradaton of the antibiotic Oxytetracycline (OTC) using visible light irradiation. As prepared nanoparticles were characterized by XRD, BET, FESEM and UV-vis DRS. The optimal operating conditions of oxytetracycline photocatalytic degradation were achived by changing the pH of the solution and changing the concentration of photocatalyst.",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad",
title = "Structure and photocatalytic properties of sol-gel synthesized pseudobrookite",
pages = "133-133",
url = "https://hdl.handle.net/21.15107/rcub_dais_6988"
}
Vasiljević, Z. Ž., Dojčinović, M., Janković Častvan, I., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2019). Structure and photocatalytic properties of sol-gel synthesized pseudobrookite. in Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad
Novi Sad : Faculty of Technology., 133-133.
https://hdl.handle.net/21.15107/rcub_dais_6988
Vasiljević ZŽ, Dojčinović M, Janković Častvan I, Vujančević J, Tadić NB, Nikolić MV. Structure and photocatalytic properties of sol-gel synthesized pseudobrookite. in Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad. 2019;:133-133.
https://hdl.handle.net/21.15107/rcub_dais_6988 .
Vasiljević, Zorka Ž., Dojčinović, Milena, Janković Častvan, Ivona, Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "Structure and photocatalytic properties of sol-gel synthesized pseudobrookite" in Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad (2019):133-133,
https://hdl.handle.net/21.15107/rcub_dais_6988 .

Visible light photocatalytic activity of nanocrystalline CoxMg1-xFe2O4 (x = 0-1)

Dojčinović, Milena; Vasiljević, Zorka Ž.; Vujančević, Jelena; Pavlović, Vera P.; Marković, Smilja; Tadić, Nenad B.; Nikolić, Marina V.

(Novi Sad : Faculty of Technology, 2019)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Vujančević, Jelena
AU  - Pavlović, Vera P.
AU  - Marković, Smilja
AU  - Tadić, Nenad B.
AU  - Nikolić, Marina V.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6986
AB  - The sol-gel combustion method was applied for synthesis of spinel magnesium cobalt ferrites CoxMg1-xFe2O4, with varying cobalt and magnesium content, x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9. Magnesium nitrate, cobalt nitrate and iron nitrate were used as oxidizers and citric acid was used as a reducing agent. Structural and morphological properties of the obtained ferrite powders were investigated and characterized by X-ray diffraction (XRD), Raman spectroscopy, Field emission scanning electron microscope (FESEM) and Fourier transform infrared (FT-IR) spectroscopy. Optical properties were investigated by UV-VIS spectrophotometry. A cubic spinel structure with multigrain agglomerates formed. Visible light photocatalytic activity of the spinel ferrite powder samples was evaluated by measuring the rate of photodegradation reaction of methylene blue (MB). After 240 min Co0.1Mg0.9Fe2O4 showed the best rate of photodecomposition of MB resulting in 90% of its initial concentration in an alkaline environment.
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad
T1  - Visible light photocatalytic activity of nanocrystalline CoxMg1-xFe2O4 (x = 0-1)
SP  - 136
EP  - 136
UR  - https://hdl.handle.net/21.15107/rcub_dais_6986
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Ž. and Vujančević, Jelena and Pavlović, Vera P. and Marković, Smilja and Tadić, Nenad B. and Nikolić, Marina V.",
year = "2019",
abstract = "The sol-gel combustion method was applied for synthesis of spinel magnesium cobalt ferrites CoxMg1-xFe2O4, with varying cobalt and magnesium content, x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9. Magnesium nitrate, cobalt nitrate and iron nitrate were used as oxidizers and citric acid was used as a reducing agent. Structural and morphological properties of the obtained ferrite powders were investigated and characterized by X-ray diffraction (XRD), Raman spectroscopy, Field emission scanning electron microscope (FESEM) and Fourier transform infrared (FT-IR) spectroscopy. Optical properties were investigated by UV-VIS spectrophotometry. A cubic spinel structure with multigrain agglomerates formed. Visible light photocatalytic activity of the spinel ferrite powder samples was evaluated by measuring the rate of photodegradation reaction of methylene blue (MB). After 240 min Co0.1Mg0.9Fe2O4 showed the best rate of photodecomposition of MB resulting in 90% of its initial concentration in an alkaline environment.",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad",
title = "Visible light photocatalytic activity of nanocrystalline CoxMg1-xFe2O4 (x = 0-1)",
pages = "136-136",
url = "https://hdl.handle.net/21.15107/rcub_dais_6986"
}
Dojčinović, M., Vasiljević, Z. Ž., Vujančević, J., Pavlović, V. P., Marković, S., Tadić, N. B.,& Nikolić, M. V.. (2019). Visible light photocatalytic activity of nanocrystalline CoxMg1-xFe2O4 (x = 0-1). in Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad
Novi Sad : Faculty of Technology., 136-136.
https://hdl.handle.net/21.15107/rcub_dais_6986
Dojčinović M, Vasiljević ZŽ, Vujančević J, Pavlović VP, Marković S, Tadić NB, Nikolić MV. Visible light photocatalytic activity of nanocrystalline CoxMg1-xFe2O4 (x = 0-1). in Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad. 2019;:136-136.
https://hdl.handle.net/21.15107/rcub_dais_6986 .
Dojčinović, Milena, Vasiljević, Zorka Ž., Vujančević, Jelena, Pavlović, Vera P., Marković, Smilja, Tadić, Nenad B., Nikolić, Marina V., "Visible light photocatalytic activity of nanocrystalline CoxMg1-xFe2O4 (x = 0-1)" in Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad (2019):136-136,
https://hdl.handle.net/21.15107/rcub_dais_6986 .

Photocatalytic degradation of methylene blue and oxytetracycline via sol-gel synthesized pseudobrookite

Vasiljević, Zorka Ž.; Dojčinović, Milena; Janković Častvan, Ivona; Vujančević, Jelena; Tadić, Nenad B.; Nikolić, Maria Vesna

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Janković Častvan, Ivona
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6967
AB  - Fe2TiO5 nanoparticles were synthesized by modified sol-gel method using Fe(NO3)3×9H2O and Ti(OC3H7)4 as starting reagents, oxalic acid as chilate agent and cetyltrimethylammonium bromide as surfactant. The aim of this study was to asses the photocatalytic degradaton of water pollutants, methylene blue and the antibiotic Oxytetracycline (OTC) using natural sunlight irradiation. As prepared nanoparticles were characterized by XRD, BET, FESEM and UV-vis DRS. The optimal operating conditions of photocatalytic degradation of water pollutants were achived by changing the pH of the solution and changing the concentration of photocatalyst.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - Photocatalytic degradation of methylene blue and oxytetracycline via sol-gel synthesized pseudobrookite
SP  - 70
EP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_dais_6967
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena and Janković Častvan, Ivona and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "Fe2TiO5 nanoparticles were synthesized by modified sol-gel method using Fe(NO3)3×9H2O and Ti(OC3H7)4 as starting reagents, oxalic acid as chilate agent and cetyltrimethylammonium bromide as surfactant. The aim of this study was to asses the photocatalytic degradaton of water pollutants, methylene blue and the antibiotic Oxytetracycline (OTC) using natural sunlight irradiation. As prepared nanoparticles were characterized by XRD, BET, FESEM and UV-vis DRS. The optimal operating conditions of photocatalytic degradation of water pollutants were achived by changing the pH of the solution and changing the concentration of photocatalyst.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "Photocatalytic degradation of methylene blue and oxytetracycline via sol-gel synthesized pseudobrookite",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_dais_6967"
}
Vasiljević, Z. Ž., Dojčinović, M., Janković Častvan, I., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2019). Photocatalytic degradation of methylene blue and oxytetracycline via sol-gel synthesized pseudobrookite. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 70-70.
https://hdl.handle.net/21.15107/rcub_dais_6967
Vasiljević ZŽ, Dojčinović M, Janković Častvan I, Vujančević J, Tadić NB, Nikolić MV. Photocatalytic degradation of methylene blue and oxytetracycline via sol-gel synthesized pseudobrookite. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:70-70.
https://hdl.handle.net/21.15107/rcub_dais_6967 .
Vasiljević, Zorka Ž., Dojčinović, Milena, Janković Častvan, Ivona, Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "Photocatalytic degradation of methylene blue and oxytetracycline via sol-gel synthesized pseudobrookite" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):70-70,
https://hdl.handle.net/21.15107/rcub_dais_6967 .

Finding optimal conditions and investigating the structure & morphology of cobalt/magnesium ferrite based cubic spinels (CoxMg1-xFe2O4) as photocatalysts

Dojčinović, Milena; Vasiljević, Zorka Ž.; Tadić, Nenad B.; Pavlović, Vera P.; Barišić, Dario; Pajić, Damir; Nikolić, Maria Vesna

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Tadić, Nenad B.
AU  - Pavlović, Vera P.
AU  - Barišić, Dario
AU  - Pajić, Damir
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6963
AB  - Cobalt/magnesium ferrites with various mole percentage ratio of the metals (obtained structures are CoxMg1-xFe2O4 with x being 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0) were synthesized by sol-gel combustion synthesis using glycine as fuel, following the rules of propellant chemistry. The powders were then sintered at 700 °C for 3 hours. Obtained powders were characterized by X-Ray diffraction (XRD), scanning electron microscopy (SEM), Raman
spectroscopy, UV/vis diffuse reflectance spectroscopy (DRS). Investigation of the magnetic properties was also conducted by vibrating sample magnetometry (VSM). The obtained powders were proved to be phase-pure cubic spinels which formed agglomerated micrograins. Series of photocatalytic experiments of methylene blue degradation were done.
The influence of different experimental conditions was investigated including variations of: pH values, concentrations of the pollutant, masses of the photocatalyst, different light sources and therefore different light irradiation. Interesting results, including enhancement of the degradation rate with the introduction of cobalt into MgFe2O4 and decrease of the degradation rate with further increase of cobalt content and formation of hard agglomerates, open new possibilities for further investigation of the utilisation of Co/Mg ferrites as photocatalysts.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - Finding optimal conditions and investigating the structure & morphology of cobalt/magnesium ferrite based cubic spinels (CoxMg1-xFe2O4) as photocatalysts
SP  - 71
EP  - 71
UR  - https://hdl.handle.net/21.15107/rcub_dais_6963
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Ž. and Tadić, Nenad B. and Pavlović, Vera P. and Barišić, Dario and Pajić, Damir and Nikolić, Maria Vesna",
year = "2019",
abstract = "Cobalt/magnesium ferrites with various mole percentage ratio of the metals (obtained structures are CoxMg1-xFe2O4 with x being 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0) were synthesized by sol-gel combustion synthesis using glycine as fuel, following the rules of propellant chemistry. The powders were then sintered at 700 °C for 3 hours. Obtained powders were characterized by X-Ray diffraction (XRD), scanning electron microscopy (SEM), Raman
spectroscopy, UV/vis diffuse reflectance spectroscopy (DRS). Investigation of the magnetic properties was also conducted by vibrating sample magnetometry (VSM). The obtained powders were proved to be phase-pure cubic spinels which formed agglomerated micrograins. Series of photocatalytic experiments of methylene blue degradation were done.
The influence of different experimental conditions was investigated including variations of: pH values, concentrations of the pollutant, masses of the photocatalyst, different light sources and therefore different light irradiation. Interesting results, including enhancement of the degradation rate with the introduction of cobalt into MgFe2O4 and decrease of the degradation rate with further increase of cobalt content and formation of hard agglomerates, open new possibilities for further investigation of the utilisation of Co/Mg ferrites as photocatalysts.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "Finding optimal conditions and investigating the structure & morphology of cobalt/magnesium ferrite based cubic spinels (CoxMg1-xFe2O4) as photocatalysts",
pages = "71-71",
url = "https://hdl.handle.net/21.15107/rcub_dais_6963"
}
Dojčinović, M., Vasiljević, Z. Ž., Tadić, N. B., Pavlović, V. P., Barišić, D., Pajić, D.,& Nikolić, M. V.. (2019). Finding optimal conditions and investigating the structure & morphology of cobalt/magnesium ferrite based cubic spinels (CoxMg1-xFe2O4) as photocatalysts. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 71-71.
https://hdl.handle.net/21.15107/rcub_dais_6963
Dojčinović M, Vasiljević ZŽ, Tadić NB, Pavlović VP, Barišić D, Pajić D, Nikolić MV. Finding optimal conditions and investigating the structure & morphology of cobalt/magnesium ferrite based cubic spinels (CoxMg1-xFe2O4) as photocatalysts. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:71-71.
https://hdl.handle.net/21.15107/rcub_dais_6963 .
Dojčinović, Milena, Vasiljević, Zorka Ž., Tadić, Nenad B., Pavlović, Vera P., Barišić, Dario, Pajić, Damir, Nikolić, Maria Vesna, "Finding optimal conditions and investigating the structure & morphology of cobalt/magnesium ferrite based cubic spinels (CoxMg1-xFe2O4) as photocatalysts" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):71-71,
https://hdl.handle.net/21.15107/rcub_dais_6963 .

Structure, morphology and photocatalytic properties of CoxMg1-xFe2O4 (0<x<1) spinel ferrites obtained by sol-gel synthesis

Vasiljević, Zorka Ž.; Dojčinović, Milena; Pavlović, Vera P.; Vujančević, Jelena; Tadić, Nenad B.; Nikolić, Maria Vesna

(Belgrade : Materials Research Society of Serbia, 2019)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6679
AB  - Nanocrystalline cobalt magnesium ferrites with varying cobalt and magnesium content (CoxMg1-xFe2O4, 0<x<1) were synthesized using the sol-gel self-combustion method with citric acid as fuel, followed by calcination at 700 C for 2 hours. Structural characterization was performed using Xray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and Raman spectroscopy. It confirmed the formation of agglomerated nanocrystalline ferrites with an inverse cubic spinel structure. The optical band gap energy was determined using UV/Vis spectrophotometry. It reduced with increased Co content. Visible light photocatalytic activity was tested using natural and artificial light sources through a series of experimental degradations of the methylene blue (MB) solution.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
T1  - Structure, morphology and photocatalytic properties of CoxMg1-xFe2O4 (0<x<1) spinel ferrites obtained by sol-gel synthesis
SP  - 126
EP  - 126
UR  - https://hdl.handle.net/21.15107/rcub_dais_6679
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena and Pavlović, Vera P. and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "Nanocrystalline cobalt magnesium ferrites with varying cobalt and magnesium content (CoxMg1-xFe2O4, 0<x<1) were synthesized using the sol-gel self-combustion method with citric acid as fuel, followed by calcination at 700 C for 2 hours. Structural characterization was performed using Xray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and Raman spectroscopy. It confirmed the formation of agglomerated nanocrystalline ferrites with an inverse cubic spinel structure. The optical band gap energy was determined using UV/Vis spectrophotometry. It reduced with increased Co content. Visible light photocatalytic activity was tested using natural and artificial light sources through a series of experimental degradations of the methylene blue (MB) solution.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019",
title = "Structure, morphology and photocatalytic properties of CoxMg1-xFe2O4 (0<x<1) spinel ferrites obtained by sol-gel synthesis",
pages = "126-126",
url = "https://hdl.handle.net/21.15107/rcub_dais_6679"
}
Vasiljević, Z. Ž., Dojčinović, M., Pavlović, V. P., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2019). Structure, morphology and photocatalytic properties of CoxMg1-xFe2O4 (0<x<1) spinel ferrites obtained by sol-gel synthesis. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
Belgrade : Materials Research Society of Serbia., 126-126.
https://hdl.handle.net/21.15107/rcub_dais_6679
Vasiljević ZŽ, Dojčinović M, Pavlović VP, Vujančević J, Tadić NB, Nikolić MV. Structure, morphology and photocatalytic properties of CoxMg1-xFe2O4 (0<x<1) spinel ferrites obtained by sol-gel synthesis. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019. 2019;:126-126.
https://hdl.handle.net/21.15107/rcub_dais_6679 .
Vasiljević, Zorka Ž., Dojčinović, Milena, Pavlović, Vera P., Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "Structure, morphology and photocatalytic properties of CoxMg1-xFe2O4 (0<x<1) spinel ferrites obtained by sol-gel synthesis" in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019 (2019):126-126,
https://hdl.handle.net/21.15107/rcub_dais_6679 .

The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles

Vasiljević, Zorka Ž.; Dojčinović, Milena; Vujančević, Jelena; Tadić, Nenad B.; Nikolić, Maria Vesna

(Belgrade : Materials Research Society of Serbia, 2019)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6673
AB  - In this study, pseudobrookite (Fe2TiO5) nanoparticles were fabricated by a modified sol-gel method using Fe(NO3)39H2O and Ti(OC3H7)4 as starting reagents and ethanol as solvent. Oxalic acid was used as a chelating agent while cetyltrimethyammonium bromide (CTAB) and citric monohydrate were used as surfactants. Structral and morphological characterization using X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis confirmed the formation of pseudobrookite nanoparticles. As synthetized Fe2TiO5 nanoparticles were utilized as photocatalysts for decolorisation of Methylene blue (MB) under visible light irradiation. It was observed that the adsorption of MB onto Fe2TiO5 nanoparticles is strongly dependent on the solution pH. Maximum decolorozation was observed for Fe2TiO5 nanoparticles prepared with CTAB under alcaline conditions (pH=10.5).
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
T1  - The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles
SP  - 130
EP  - 130
UR  - https://hdl.handle.net/21.15107/rcub_dais_6673
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "In this study, pseudobrookite (Fe2TiO5) nanoparticles were fabricated by a modified sol-gel method using Fe(NO3)39H2O and Ti(OC3H7)4 as starting reagents and ethanol as solvent. Oxalic acid was used as a chelating agent while cetyltrimethyammonium bromide (CTAB) and citric monohydrate were used as surfactants. Structral and morphological characterization using X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis confirmed the formation of pseudobrookite nanoparticles. As synthetized Fe2TiO5 nanoparticles were utilized as photocatalysts for decolorisation of Methylene blue (MB) under visible light irradiation. It was observed that the adsorption of MB onto Fe2TiO5 nanoparticles is strongly dependent on the solution pH. Maximum decolorozation was observed for Fe2TiO5 nanoparticles prepared with CTAB under alcaline conditions (pH=10.5).",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019",
title = "The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles",
pages = "130-130",
url = "https://hdl.handle.net/21.15107/rcub_dais_6673"
}
Vasiljević, Z. Ž., Dojčinović, M., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2019). The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
Belgrade : Materials Research Society of Serbia., 130-130.
https://hdl.handle.net/21.15107/rcub_dais_6673
Vasiljević ZŽ, Dojčinović M, Vujančević J, Tadić NB, Nikolić MV. The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019. 2019;:130-130.
https://hdl.handle.net/21.15107/rcub_dais_6673 .
Vasiljević, Zorka Ž., Dojčinović, Milena, Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles" in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019 (2019):130-130,
https://hdl.handle.net/21.15107/rcub_dais_6673 .

Structural, photocatalytic and photoelectrochemical characteristics of ZnO nanoparticles synthesized by a glycine-nitrate process

Dojčinović, Milena; Stojković Simatović, Ivana; Marković, Smilja; Janković Častvan, Ivona; Bajuk Bogdanović, Danica; Stojadinović, Stevan; Rac, Vladislav; Nikolić, Maria Vesna

(Budapest : [s. n.], 2019)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Stojković Simatović, Ivana
AU  - Marković, Smilja
AU  - Janković Častvan, Ivona
AU  - Bajuk Bogdanović, Danica
AU  - Stojadinović, Stevan
AU  - Rac, Vladislav
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6998
AB  - Zinc oxide is a semiconductor material which still, after a century of scientific research, shows great potential in modern day utilisements such as heterogenous photocatalysis of organic pollutants and as a photoanode material for efficient water splitting and oxygen generation. In this work zinc oxide was synthesized by a glycine-nitrate combustion process, which is a cheap, simple and efficient method for synthesizing transition metal oxides. The obtained powder was calcined at 400 and 500 °C and samples were characterized in detail using X-ray powder diffraction (XRPD), Fourier-trasform infrared spectroscopy (FTIR), Raman spectroscopy, field emission scanning electron microscopy (FESEM), photoluminescence spectroscopy (PL) and UV-Vis diffuse reflectance spectroscopy (DRS). Photoelectrocatalytic properties were investigated via electrochemical methods: linear voltammetry (LV), chronoamperometry (CA) and impedance spectroscopy (EIS). The results show that the obtained samples are nanocrystalline wurtzite zinc oxide with no impurities, with average particle diameters of 33 nm (annealed at 400 °C) and 48 nm (annealed at 500 °C). Both samples show significant amounts of various crystal deffects. The determined zinc oxide band gap was lower than the band gap of bulk zinc oxide. Photoelectrochemical measurements revealed that this material is photostable and reactive to light. Water oxidation is enhanced by exposing the light. Finally, photocatalytic properties were tested via determining kinetic parameters of organic pollutant decomposition. Both samples showed excellent photocatalytic activity by decomposing methylene blue and phenol.
PB  - Budapest : [s. n.]
C3  - Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest
T1  - Structural, photocatalytic and photoelectrochemical characteristics of ZnO nanoparticles synthesized by a glycine-nitrate process
SP  - 16
EP  - 16
UR  - https://hdl.handle.net/21.15107/rcub_dais_6998
ER  - 
@conference{
author = "Dojčinović, Milena and Stojković Simatović, Ivana and Marković, Smilja and Janković Častvan, Ivona and Bajuk Bogdanović, Danica and Stojadinović, Stevan and Rac, Vladislav and Nikolić, Maria Vesna",
year = "2019",
abstract = "Zinc oxide is a semiconductor material which still, after a century of scientific research, shows great potential in modern day utilisements such as heterogenous photocatalysis of organic pollutants and as a photoanode material for efficient water splitting and oxygen generation. In this work zinc oxide was synthesized by a glycine-nitrate combustion process, which is a cheap, simple and efficient method for synthesizing transition metal oxides. The obtained powder was calcined at 400 and 500 °C and samples were characterized in detail using X-ray powder diffraction (XRPD), Fourier-trasform infrared spectroscopy (FTIR), Raman spectroscopy, field emission scanning electron microscopy (FESEM), photoluminescence spectroscopy (PL) and UV-Vis diffuse reflectance spectroscopy (DRS). Photoelectrocatalytic properties were investigated via electrochemical methods: linear voltammetry (LV), chronoamperometry (CA) and impedance spectroscopy (EIS). The results show that the obtained samples are nanocrystalline wurtzite zinc oxide with no impurities, with average particle diameters of 33 nm (annealed at 400 °C) and 48 nm (annealed at 500 °C). Both samples show significant amounts of various crystal deffects. The determined zinc oxide band gap was lower than the band gap of bulk zinc oxide. Photoelectrochemical measurements revealed that this material is photostable and reactive to light. Water oxidation is enhanced by exposing the light. Finally, photocatalytic properties were tested via determining kinetic parameters of organic pollutant decomposition. Both samples showed excellent photocatalytic activity by decomposing methylene blue and phenol.",
publisher = "Budapest : [s. n.]",
journal = "Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest",
title = "Structural, photocatalytic and photoelectrochemical characteristics of ZnO nanoparticles synthesized by a glycine-nitrate process",
pages = "16-16",
url = "https://hdl.handle.net/21.15107/rcub_dais_6998"
}
Dojčinović, M., Stojković Simatović, I., Marković, S., Janković Častvan, I., Bajuk Bogdanović, D., Stojadinović, S., Rac, V.,& Nikolić, M. V.. (2019). Structural, photocatalytic and photoelectrochemical characteristics of ZnO nanoparticles synthesized by a glycine-nitrate process. in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest
Budapest : [s. n.]., 16-16.
https://hdl.handle.net/21.15107/rcub_dais_6998
Dojčinović M, Stojković Simatović I, Marković S, Janković Častvan I, Bajuk Bogdanović D, Stojadinović S, Rac V, Nikolić MV. Structural, photocatalytic and photoelectrochemical characteristics of ZnO nanoparticles synthesized by a glycine-nitrate process. in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest. 2019;:16-16.
https://hdl.handle.net/21.15107/rcub_dais_6998 .
Dojčinović, Milena, Stojković Simatović, Ivana, Marković, Smilja, Janković Častvan, Ivona, Bajuk Bogdanović, Danica, Stojadinović, Stevan, Rac, Vladislav, Nikolić, Maria Vesna, "Structural, photocatalytic and photoelectrochemical characteristics of ZnO nanoparticles synthesized by a glycine-nitrate process" in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest (2019):16-16,
https://hdl.handle.net/21.15107/rcub_dais_6998 .

Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Labus, Nebojša

(IEEE, 2019)

TY  - CONF
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Labus, Nebojša
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6687
AB  - Nanocomposite Zn2SnO4/SnO2 powder was obtained by solid state synthesis from homogenized starting nanopowders of ZnO and SnO2 mixed in the 1:1 molar ratio, structurally and morphologically characterized using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Thick film paste was made by adding organic vehicles to the obtained powder. Three to five layers (layer thickness approx. 12 μm) were screen printed on alumina substrate with small test PdAg electrodes and fired at 600°C for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing. Impedance response was studied at the working temperatures of 25 and 50°in a humidity chamber where the relative humidity (RH) was 30-90% and measured frequency 42 Hz - 1 MHz. With increase in film thickness the overall sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 μm), from 23.4 to 0.25 MΩ (48 μm) and from 6.8 to 0.02 MΩ (36 μm) at 25°C, while at 50°C the overall measured impedance was lower, and reduced from 14 MΩ to 0.72 MΩ (48 μm) for RH 30 and 90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for application in humidity sensing.
PB  - IEEE
C3  - 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)
T1  - Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material
SP  - 1
EP  - 3
DO  - 10.1109/FLEPS.2019.8792304
UR  - https://hdl.handle.net/21.15107/rcub_dais_6687
ER  - 
@conference{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Labus, Nebojša",
year = "2019",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder was obtained by solid state synthesis from homogenized starting nanopowders of ZnO and SnO2 mixed in the 1:1 molar ratio, structurally and morphologically characterized using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Thick film paste was made by adding organic vehicles to the obtained powder. Three to five layers (layer thickness approx. 12 μm) were screen printed on alumina substrate with small test PdAg electrodes and fired at 600°C for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing. Impedance response was studied at the working temperatures of 25 and 50°in a humidity chamber where the relative humidity (RH) was 30-90% and measured frequency 42 Hz - 1 MHz. With increase in film thickness the overall sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 μm), from 23.4 to 0.25 MΩ (48 μm) and from 6.8 to 0.02 MΩ (36 μm) at 25°C, while at 50°C the overall measured impedance was lower, and reduced from 14 MΩ to 0.72 MΩ (48 μm) for RH 30 and 90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for application in humidity sensing.",
publisher = "IEEE",
journal = "2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)",
title = "Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material",
pages = "1-3",
doi = "10.1109/FLEPS.2019.8792304",
url = "https://hdl.handle.net/21.15107/rcub_dais_6687"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Ž., Luković, M. D.,& Labus, N.. (2019). Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material. in 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)
IEEE., 1-3.
https://doi.org/10.1109/FLEPS.2019.8792304
https://hdl.handle.net/21.15107/rcub_dais_6687
Nikolić MV, Dojčinović M, Vasiljević ZŽ, Luković MD, Labus N. Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material. in 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS). 2019;:1-3.
doi:10.1109/FLEPS.2019.8792304
https://hdl.handle.net/21.15107/rcub_dais_6687 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Ž., Luković, Miloljub D., Labus, Nebojša, "Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material" in 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS) (2019):1-3,
https://doi.org/10.1109/FLEPS.2019.8792304 .,
https://hdl.handle.net/21.15107/rcub_dais_6687 .
1
1

Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Labus, Nebojša

(IEEE, 2019)

TY  - CONF
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Labus, Nebojša
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6688
AB  - Nanocomposite Zn2SnO4/SnO2 powder was obtained by solid state synthesis from homogenized starting nanopowders of ZnO and SnO2 mixed in the 1:1 molar ratio, structurally and morphologically characterized using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Thick film paste was made by adding organic vehicles to the obtained powder. Three to five layers (layer thickness approx. 12 μm) were screen printed on alumina substrate with small test PdAg electrodes and fired at 600°C for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing. Impedance response was studied at the working temperatures of 25 and 50°in a humidity chamber where the relative humidity (RH) was 30-90% and measured frequency 42 Hz - 1 MHz. With increase in film thickness the overall sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 μm), from 23.4 to 0.25 MΩ (48 μm) and from 6.8 to 0.02 MΩ (36 μm) at 25°C, while at 50°C the overall measured impedance was lower, and reduced from 14 MΩ to 0.72 MΩ (48 μm) for RH 30 and 90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for application in humidity sensing.
PB  - IEEE
C3  - 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)
T1  - Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material
SP  - 1
EP  - 3
DO  - 10.1109/FLEPS.2019.8792304
UR  - https://hdl.handle.net/21.15107/rcub_dais_6688
ER  - 
@conference{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Labus, Nebojša",
year = "2019",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder was obtained by solid state synthesis from homogenized starting nanopowders of ZnO and SnO2 mixed in the 1:1 molar ratio, structurally and morphologically characterized using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Thick film paste was made by adding organic vehicles to the obtained powder. Three to five layers (layer thickness approx. 12 μm) were screen printed on alumina substrate with small test PdAg electrodes and fired at 600°C for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing. Impedance response was studied at the working temperatures of 25 and 50°in a humidity chamber where the relative humidity (RH) was 30-90% and measured frequency 42 Hz - 1 MHz. With increase in film thickness the overall sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 MΩ (60 μm), from 23.4 to 0.25 MΩ (48 μm) and from 6.8 to 0.02 MΩ (36 μm) at 25°C, while at 50°C the overall measured impedance was lower, and reduced from 14 MΩ to 0.72 MΩ (48 μm) for RH 30 and 90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for application in humidity sensing.",
publisher = "IEEE",
journal = "2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)",
title = "Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material",
pages = "1-3",
doi = "10.1109/FLEPS.2019.8792304",
url = "https://hdl.handle.net/21.15107/rcub_dais_6688"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Ž., Luković, M. D.,& Labus, N.. (2019). Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material. in 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS)
IEEE., 1-3.
https://doi.org/10.1109/FLEPS.2019.8792304
https://hdl.handle.net/21.15107/rcub_dais_6688
Nikolić MV, Dojčinović M, Vasiljević ZŽ, Luković MD, Labus N. Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material. in 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS). 2019;:1-3.
doi:10.1109/FLEPS.2019.8792304
https://hdl.handle.net/21.15107/rcub_dais_6688 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Ž., Luković, Miloljub D., Labus, Nebojša, "Nanocomposite Zn2SnO4/SnO2 Thick films as a Humidity Sensing Material" in 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS) (2019):1-3,
https://doi.org/10.1109/FLEPS.2019.8792304 .,
https://hdl.handle.net/21.15107/rcub_dais_6688 .
1
1

Humidity sensing potential of iron manganite (FeMNO3)

Nikolić, Maria Vesna; Luković, Miloljub D.; Vasiljević, Zorka Ž.; Dojčinović, Milena; Labus, Nebojša

(Budapest : [s. n.], 2019)

TY  - CONF
AU  - Nikolić, Maria Vesna
AU  - Luković, Miloljub D.
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena
AU  - Labus, Nebojša
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6999
AB  - Though different metal oxide systems have been investigated and applied in humidity sensing as resistive or capacitive ceramic humidity sensors new materials remain the subject of much research. Iron manganite (FeMnO3) has a bixybyite type structure with the cubic space group. Iron manganite powder was obtained by solid state synthesis (milling in a planetary ball mill, calcination at 1000°C for 2 hours, milling) of starting hematite (Fe2O3) and manganese carbonate (MnCO3) powders mixed in a suitable ratio. Bulk samples were obtained by sintering green samples of pressed powder 8 mm in diameter at 1000oC for 4 hours. Thick film paste was obtained by mixing the powder with organic vehicles. Four layers were screen printed on test interdigitated electrodes on alumina substrate and fired at 900oC for 6 h. XRD analysis of bulk and thick film samples confirmed the formation of iron manganite with a perovskite structure. Scanning electron microscopy (SEM) analysis of freshly cleaved bulk samples showed a network of interconnected grains and pores. A similar structure was observed for the thick film sample surface. Change of complex impedance was monitored in a humidity chamber in the relative humidity range 30-90% at the working temperature of 25°C and frequency range 42 Hz to 1 MHz. In bulk samples at 100 Hz the impedance decreased from 32 (RH 30%) to 3 MΩ (RH 90%), while in thick film samples on test interdigitated electrodes it decreased from 8.24 (RH 30%) to 0.87 MΩ ((RH 90%). The thick film sensor response and recovery was several seconds and a low hysteresis value of 2.78% was obtained showing that iron manganite can successfully be applied for humidity sensing applications.
PB  - Budapest : [s. n.]
C3  - Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest
T1  - Humidity sensing potential of iron manganite (FeMNO3)
SP  - 16
EP  - 17
UR  - https://hdl.handle.net/21.15107/rcub_dais_6999
ER  - 
@conference{
author = "Nikolić, Maria Vesna and Luković, Miloljub D. and Vasiljević, Zorka Ž. and Dojčinović, Milena and Labus, Nebojša",
year = "2019",
abstract = "Though different metal oxide systems have been investigated and applied in humidity sensing as resistive or capacitive ceramic humidity sensors new materials remain the subject of much research. Iron manganite (FeMnO3) has a bixybyite type structure with the cubic space group. Iron manganite powder was obtained by solid state synthesis (milling in a planetary ball mill, calcination at 1000°C for 2 hours, milling) of starting hematite (Fe2O3) and manganese carbonate (MnCO3) powders mixed in a suitable ratio. Bulk samples were obtained by sintering green samples of pressed powder 8 mm in diameter at 1000oC for 4 hours. Thick film paste was obtained by mixing the powder with organic vehicles. Four layers were screen printed on test interdigitated electrodes on alumina substrate and fired at 900oC for 6 h. XRD analysis of bulk and thick film samples confirmed the formation of iron manganite with a perovskite structure. Scanning electron microscopy (SEM) analysis of freshly cleaved bulk samples showed a network of interconnected grains and pores. A similar structure was observed for the thick film sample surface. Change of complex impedance was monitored in a humidity chamber in the relative humidity range 30-90% at the working temperature of 25°C and frequency range 42 Hz to 1 MHz. In bulk samples at 100 Hz the impedance decreased from 32 (RH 30%) to 3 MΩ (RH 90%), while in thick film samples on test interdigitated electrodes it decreased from 8.24 (RH 30%) to 0.87 MΩ ((RH 90%). The thick film sensor response and recovery was several seconds and a low hysteresis value of 2.78% was obtained showing that iron manganite can successfully be applied for humidity sensing applications.",
publisher = "Budapest : [s. n.]",
journal = "Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest",
title = "Humidity sensing potential of iron manganite (FeMNO3)",
pages = "16-17",
url = "https://hdl.handle.net/21.15107/rcub_dais_6999"
}
Nikolić, M. V., Luković, M. D., Vasiljević, Z. Ž., Dojčinović, M.,& Labus, N.. (2019). Humidity sensing potential of iron manganite (FeMNO3). in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest
Budapest : [s. n.]., 16-17.
https://hdl.handle.net/21.15107/rcub_dais_6999
Nikolić MV, Luković MD, Vasiljević ZŽ, Dojčinović M, Labus N. Humidity sensing potential of iron manganite (FeMNO3). in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest. 2019;:16-17.
https://hdl.handle.net/21.15107/rcub_dais_6999 .
Nikolić, Maria Vesna, Luković, Miloljub D., Vasiljević, Zorka Ž., Dojčinović, Milena, Labus, Nebojša, "Humidity sensing potential of iron manganite (FeMNO3)" in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest (2019):16-17,
https://hdl.handle.net/21.15107/rcub_dais_6999 .

Nanocrystalline SnO2-Zn2SnO4 composite thick films applied as humidity sensors

Nikolić, Maria Vesna; Luković, Miloljub D.; Dojčinović, Milena; Vasiljević, Zorka Ž.

(Belgrade : Institute for Multidisciplinary Research, 2019)

TY  - CONF
AU  - Nikolić, Maria Vesna
AU  - Luković, Miloljub D.
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7006
AB  - Starting ZnO and SnO2 nanopowders (<100 nm) were mixed in a suitable ratio and calcined at 1050 °C for 2 hours to obtain nanocrystalline SnO2-Zn2SnO4 composite powder. Structural characterization performed by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) showed that a nanocrystalline composite SnO2-Zn2SnO4 powder was obtained. Thick film paste was made by adding organic vehicles to the powder. Screen printing of four and five layers of thick film paste was performed on two interdigitated test electrode configurations. They were calcined at 500 and 600 °C for 30 minutes. Impedance response was analyzed at several working temperatures (20-60 °C) in the relative humidity range 30-90% and frequency 42 Hz to 1 MHz. Increase in relative humidity lead to a decrease in impedance, especially at lower frequencies. The sensor time delay between absorption and desorption processes was low and the response and recovery times fast showing that the nanocystalline SnO2-Zn2SnO4 composite has potential for application in humidity sensing.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - Nanocrystalline SnO2-Zn2SnO4 composite thick films applied as humidity sensors
SP  - 82
EP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_dais_7006
ER  - 
@conference{
author = "Nikolić, Maria Vesna and Luković, Miloljub D. and Dojčinović, Milena and Vasiljević, Zorka Ž.",
year = "2019",
abstract = "Starting ZnO and SnO2 nanopowders (<100 nm) were mixed in a suitable ratio and calcined at 1050 °C for 2 hours to obtain nanocrystalline SnO2-Zn2SnO4 composite powder. Structural characterization performed by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) showed that a nanocrystalline composite SnO2-Zn2SnO4 powder was obtained. Thick film paste was made by adding organic vehicles to the powder. Screen printing of four and five layers of thick film paste was performed on two interdigitated test electrode configurations. They were calcined at 500 and 600 °C for 30 minutes. Impedance response was analyzed at several working temperatures (20-60 °C) in the relative humidity range 30-90% and frequency 42 Hz to 1 MHz. Increase in relative humidity lead to a decrease in impedance, especially at lower frequencies. The sensor time delay between absorption and desorption processes was low and the response and recovery times fast showing that the nanocystalline SnO2-Zn2SnO4 composite has potential for application in humidity sensing.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "Nanocrystalline SnO2-Zn2SnO4 composite thick films applied as humidity sensors",
pages = "82-82",
url = "https://hdl.handle.net/21.15107/rcub_dais_7006"
}
Nikolić, M. V., Luković, M. D., Dojčinović, M.,& Vasiljević, Z. Ž.. (2019). Nanocrystalline SnO2-Zn2SnO4 composite thick films applied as humidity sensors. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 82-82.
https://hdl.handle.net/21.15107/rcub_dais_7006
Nikolić MV, Luković MD, Dojčinović M, Vasiljević ZŽ. Nanocrystalline SnO2-Zn2SnO4 composite thick films applied as humidity sensors. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:82-82.
https://hdl.handle.net/21.15107/rcub_dais_7006 .
Nikolić, Maria Vesna, Luković, Miloljub D., Dojčinović, Milena, Vasiljević, Zorka Ž., "Nanocrystalline SnO2-Zn2SnO4 composite thick films applied as humidity sensors" in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):82-82,
https://hdl.handle.net/21.15107/rcub_dais_7006 .

Physical Properties of Sintered Alumina Doped with Different Oxides

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Đorđević, Antonije; Balać, Igor; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2018)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4537
AB  - Corundum (α-alumina) is a suitable material for usage in various industry fields owing to its chemical stability, electrical and mechanical features. It is known that properties of ceramics could be modified by addition of different oxides, as well as by changing the consolidation parameters. In this respect, alumina was doped with 1 wt.% of Cr2O3, Mn2O3 and NiO, followed by 1 hour of mechanical activation in a high-energy planetary ball mill. A sensitive dilatometer was used for sintering of powder mixtures up to 1400 oC and recording the obtained dilatation. The final density varied between cca. 1.9 and 3.3 g/cm3. Microstructural changes were detected by SEM measurements. Changes in electrical permittivity and loss tangent were associated with the preparation conditions (types of additives, duration of mechanical activation). For a given mixture, the sintering increases the relative permittivity and decreases losses, exhibiting the optimal values of 8.32 and 0.027, respectively, for the sample activated 60 minutes and sintered, with the addition of MnO2. Mechanical measurements indicate significant differences in strength with the addition of different transition metal oxides. Samples with Mn and Ni, activated and sintered, with strength of 121 and 86 MPa, respectively, have a significantly higher tensile strength than the other tested samples, due to their more compact microstructures.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Physical Properties of Sintered Alumina Doped with Different Oxides
SP  - 409
EP  - 419
VL  - 50
IS  - 4
DO  - 10.2298/SOS1804409F
UR  - https://hdl.handle.net/21.15107/rcub_dais_4537
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Đorđević, Antonije and Balać, Igor and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2018",
abstract = "Corundum (α-alumina) is a suitable material for usage in various industry fields owing to its chemical stability, electrical and mechanical features. It is known that properties of ceramics could be modified by addition of different oxides, as well as by changing the consolidation parameters. In this respect, alumina was doped with 1 wt.% of Cr2O3, Mn2O3 and NiO, followed by 1 hour of mechanical activation in a high-energy planetary ball mill. A sensitive dilatometer was used for sintering of powder mixtures up to 1400 oC and recording the obtained dilatation. The final density varied between cca. 1.9 and 3.3 g/cm3. Microstructural changes were detected by SEM measurements. Changes in electrical permittivity and loss tangent were associated with the preparation conditions (types of additives, duration of mechanical activation). For a given mixture, the sintering increases the relative permittivity and decreases losses, exhibiting the optimal values of 8.32 and 0.027, respectively, for the sample activated 60 minutes and sintered, with the addition of MnO2. Mechanical measurements indicate significant differences in strength with the addition of different transition metal oxides. Samples with Mn and Ni, activated and sintered, with strength of 121 and 86 MPa, respectively, have a significantly higher tensile strength than the other tested samples, due to their more compact microstructures.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Physical Properties of Sintered Alumina Doped with Different Oxides",
pages = "409-419",
volume = "50",
number = "4",
doi = "10.2298/SOS1804409F",
url = "https://hdl.handle.net/21.15107/rcub_dais_4537"
}
Filipović, S., Obradović, N., Marković, S., Đorđević, A., Balać, I., Dapčević, A., Rogan, J.,& Pavlović, V. B.. (2018). Physical Properties of Sintered Alumina Doped with Different Oxides. in Science of Sintering
Belgrade : ETRAN., 50(4), 409-419.
https://doi.org/10.2298/SOS1804409F
https://hdl.handle.net/21.15107/rcub_dais_4537
Filipović S, Obradović N, Marković S, Đorđević A, Balać I, Dapčević A, Rogan J, Pavlović VB. Physical Properties of Sintered Alumina Doped with Different Oxides. in Science of Sintering. 2018;50(4):409-419.
doi:10.2298/SOS1804409F
https://hdl.handle.net/21.15107/rcub_dais_4537 .
Filipović, Suzana, Obradović, Nina, Marković, Smilja, Đorđević, Antonije, Balać, Igor, Dapčević, Aleksandra, Rogan, Jelena, Pavlović, Vladimir B., "Physical Properties of Sintered Alumina Doped with Different Oxides" in Science of Sintering, 50, no. 4 (2018):409-419,
https://doi.org/10.2298/SOS1804409F .,
https://hdl.handle.net/21.15107/rcub_dais_4537 .
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Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films

Nikolić, Maria Vesna; Vasiljević, Zorka Ž.; Luković, Miloljub D.; Pavlović, Vera P.; Vujančević, Jelena; Radovanović, Milan; Krstić, Jugoslav; Vlahović, Branislav; Pavlović, Vladimir B.

(Elsevier, 2018)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Ž.
AU  - Luković, Miloljub D.
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Radovanović, Milan
AU  - Krstić, Jugoslav
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://www.sciencedirect.com/science/article/pii/S0925400518316836
UR  - https://dais.sanu.ac.rs/123456789/4605
AB  - Pseudobrookite based nanopowder was obtained by solid state synthesis of starting hematite and anatase nanopowders in the weight ratio 55:45. Structural and morphological properties were analyzed using X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV/Vis diffuse reflectance spectroscopy, Field emission scanning electron microscopy (FESEM) and Transmission electron microscopy (TEM) confirming the formation of nanocrystalline pseudobrookite. The obtained powder was mixed with a binder (ethyl cellulose), dispersant (α-terpinol) and adhesion agents (acetic acid and distilled water) to obtain a thick film paste. It was screen printed on alumina substrate with interdigitated PdAg electrodes and fired at 600 °C for 30 min. Formation of a porous nanocrystalline thick film structure was shown using Scanning electron microscopy (SEM), while Hall measurements enabled determination of carrier mobility. Change of impedance response in the frequency range 42 Hz–1 MHz with humidity was analyzed at room temperature (25 °C) and 50 °C in the relative humidity range 30–90% and 40–90%, respectively. At 42 Hz, and room temperature the impedance reduced ∼28 times, while at 50 °C it reduced ∼147 times in the relative humidity range 40–90%. The sensor showed rapid response (16 s) and relatively low hysteresis (8.39% at 25 °C and 2.64% at 50 °C) showing that this is a promising material for application in humidity sensing.
PB  - Elsevier
T2  - Sensors and Actuators B: Chemical
T1  - Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films
SP  - 654
EP  - 664
VL  - 277
DO  - 10.1016/j.snb.2018.09.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4605
ER  - 
@article{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Ž. and Luković, Miloljub D. and Pavlović, Vera P. and Vujančević, Jelena and Radovanović, Milan and Krstić, Jugoslav and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2018",
abstract = "Pseudobrookite based nanopowder was obtained by solid state synthesis of starting hematite and anatase nanopowders in the weight ratio 55:45. Structural and morphological properties were analyzed using X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV/Vis diffuse reflectance spectroscopy, Field emission scanning electron microscopy (FESEM) and Transmission electron microscopy (TEM) confirming the formation of nanocrystalline pseudobrookite. The obtained powder was mixed with a binder (ethyl cellulose), dispersant (α-terpinol) and adhesion agents (acetic acid and distilled water) to obtain a thick film paste. It was screen printed on alumina substrate with interdigitated PdAg electrodes and fired at 600 °C for 30 min. Formation of a porous nanocrystalline thick film structure was shown using Scanning electron microscopy (SEM), while Hall measurements enabled determination of carrier mobility. Change of impedance response in the frequency range 42 Hz–1 MHz with humidity was analyzed at room temperature (25 °C) and 50 °C in the relative humidity range 30–90% and 40–90%, respectively. At 42 Hz, and room temperature the impedance reduced ∼28 times, while at 50 °C it reduced ∼147 times in the relative humidity range 40–90%. The sensor showed rapid response (16 s) and relatively low hysteresis (8.39% at 25 °C and 2.64% at 50 °C) showing that this is a promising material for application in humidity sensing.",
publisher = "Elsevier",
journal = "Sensors and Actuators B: Chemical",
title = "Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films",
pages = "654-664",
volume = "277",
doi = "10.1016/j.snb.2018.09.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4605"
}
Nikolić, M. V., Vasiljević, Z. Ž., Luković, M. D., Pavlović, V. P., Vujančević, J., Radovanović, M., Krstić, J., Vlahović, B.,& Pavlović, V. B.. (2018). Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films. in Sensors and Actuators B: Chemical
Elsevier., 277, 654-664.
https://doi.org/10.1016/j.snb.2018.09.063
https://hdl.handle.net/21.15107/rcub_dais_4605
Nikolić MV, Vasiljević ZŽ, Luković MD, Pavlović VP, Vujančević J, Radovanović M, Krstić J, Vlahović B, Pavlović VB. Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films. in Sensors and Actuators B: Chemical. 2018;277:654-664.
doi:10.1016/j.snb.2018.09.063
https://hdl.handle.net/21.15107/rcub_dais_4605 .
Nikolić, Maria Vesna, Vasiljević, Zorka Ž., Luković, Miloljub D., Pavlović, Vera P., Vujančević, Jelena, Radovanović, Milan, Krstić, Jugoslav, Vlahović, Branislav, Pavlović, Vladimir B., "Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films" in Sensors and Actuators B: Chemical, 277 (2018):654-664,
https://doi.org/10.1016/j.snb.2018.09.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4605 .
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