Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications

Link to this page

info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172043/RS//

Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications (en)
Електропроводни и редокс-активни полимери и олигомери: синтеза, структура, својства и примена (sr)
Elektroprovodni i redoks-aktivni polimeri i oligomeri: sinteza, struktura, svojstva i primena (sr_RS)
Authors

Publications

Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite

Jovanović, Zoran; Mravik, Željko; Bajuk Bogdanović, Danica; Jovanović, Sonja; Marković, Smilja; Vujković, Milica; Kovač, Janez; Vengust, Damjan; Uskoković-Marković, Snežana; Holclajtner Antunović, Ivanka

(2020)

TY  - JOUR
AU  - Jovanović, Zoran
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Jovanović, Sonja
AU  - Marković, Smilja
AU  - Vujković, Milica
AU  - Kovač, Janez
AU  - Vengust, Damjan
AU  - Uskoković-Marković, Snežana
AU  - Holclajtner Antunović, Ivanka
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/6882
AB  - In the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.
T2  - Carbon
T1  - Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite
SP  - 166
EP  - 178
VL  - 156
DO  - 10.1016/j.carbon.2019.09.072
UR  - https://hdl.handle.net/21.15107/rcub_dais_6882
ER  - 
@article{
author = "Jovanović, Zoran and Mravik, Željko and Bajuk Bogdanović, Danica and Jovanović, Sonja and Marković, Smilja and Vujković, Milica and Kovač, Janez and Vengust, Damjan and Uskoković-Marković, Snežana and Holclajtner Antunović, Ivanka",
year = "2020",
abstract = "In the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.",
journal = "Carbon",
title = "Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite",
pages = "166-178",
volume = "156",
doi = "10.1016/j.carbon.2019.09.072",
url = "https://hdl.handle.net/21.15107/rcub_dais_6882"
}
Jovanović, Z., Mravik, Ž., Bajuk Bogdanović, D., Jovanović, S., Marković, S., Vujković, M., Kovač, J., Vengust, D., Uskoković-Marković, S.,& Holclajtner Antunović, I.. (2020). Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite. in Carbon, 156, 166-178.
https://doi.org/10.1016/j.carbon.2019.09.072
https://hdl.handle.net/21.15107/rcub_dais_6882
Jovanović Z, Mravik Ž, Bajuk Bogdanović D, Jovanović S, Marković S, Vujković M, Kovač J, Vengust D, Uskoković-Marković S, Holclajtner Antunović I. Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite. in Carbon. 2020;156:166-178.
doi:10.1016/j.carbon.2019.09.072
https://hdl.handle.net/21.15107/rcub_dais_6882 .
Jovanović, Zoran, Mravik, Željko, Bajuk Bogdanović, Danica, Jovanović, Sonja, Marković, Smilja, Vujković, Milica, Kovač, Janez, Vengust, Damjan, Uskoković-Marković, Snežana, Holclajtner Antunović, Ivanka, "Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite" in Carbon, 156 (2020):166-178,
https://doi.org/10.1016/j.carbon.2019.09.072 .,
https://hdl.handle.net/21.15107/rcub_dais_6882 .
8
4
7

NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media

Milikić, Jadranka; Vasić, Milica M.; Amaral, Luis; Cvjetićanin, Nikola; Jugović, Dragana; Hercigonja, Radmila; Šljukić, Biljana

(Elsevier, 2018)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Vasić, Milica M.
AU  - Amaral, Luis
AU  - Cvjetićanin, Nikola
AU  - Jugović, Dragana
AU  - Hercigonja, Radmila
AU  - Šljukić, Biljana
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4588
AB  - NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media
SP  - 18977
EP  - 18991
VL  - 43
IS  - 41
DO  - 10.1016/j.ijhydene.2018.08.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4588
ER  - 
@article{
author = "Milikić, Jadranka and Vasić, Milica M. and Amaral, Luis and Cvjetićanin, Nikola and Jugović, Dragana and Hercigonja, Radmila and Šljukić, Biljana",
year = "2018",
abstract = "NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media",
pages = "18977-18991",
volume = "43",
number = "41",
doi = "10.1016/j.ijhydene.2018.08.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4588"
}
Milikić, J., Vasić, M. M., Amaral, L., Cvjetićanin, N., Jugović, D., Hercigonja, R.,& Šljukić, B.. (2018). NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy
Elsevier., 43(41), 18977-18991.
https://doi.org/10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4588
Milikić J, Vasić MM, Amaral L, Cvjetićanin N, Jugović D, Hercigonja R, Šljukić B. NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy. 2018;43(41):18977-18991.
doi:10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4588 .
Milikić, Jadranka, Vasić, Milica M., Amaral, Luis, Cvjetićanin, Nikola, Jugović, Dragana, Hercigonja, Radmila, Šljukić, Biljana, "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media" in International Journal of Hydrogen Energy, 43, no. 41 (2018):18977-18991,
https://doi.org/10.1016/j.ijhydene.2018.08.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4588 .
16
6
15

NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media

Milikić, Jadranka; Vasić, Milica M.; Amaral, Luis; Cvjetićanin, Nikola; Jugović, Dragana; Hercigonja, Radmila; Šljukić, Biljana

(Elsevier, 2018)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Vasić, Milica M.
AU  - Amaral, Luis
AU  - Cvjetićanin, Nikola
AU  - Jugović, Dragana
AU  - Hercigonja, Radmila
AU  - Šljukić, Biljana
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4077
AB  - NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media
SP  - 18977
EP  - 18991
VL  - 43
IS  - 41
DO  - 10.1016/j.ijhydene.2018.08.063
UR  - https://hdl.handle.net/21.15107/rcub_dais_4077
ER  - 
@article{
author = "Milikić, Jadranka and Vasić, Milica M. and Amaral, Luis and Cvjetićanin, Nikola and Jugović, Dragana and Hercigonja, Radmila and Šljukić, Biljana",
year = "2018",
abstract = "NiA and NiX zeolites were prepared and characterised using XRD, FTIR and SEM, and subsequently tested as electrodes for hydrogen (HER) and oxygen (OER) evolution reactions in alkaline media. Linear sweep voltammetry and chronoamperometry techniques showed that NiA has higher catalytic activity for these two reactions, as evidenced by higher current densities, which can be correlated with a higher weight fraction of Ni in this electrocatalyst than in the NiX and with its higher conductivity. HER and OER kinetic parameters, including Tafel slope, exchange current density and apparent activation energy were evaluated. Electrochemical impedance spectroscopy analysis yielded values of the resistance of the solution, charge transfer and mass transfer, as well as double layer capacitance and pseudo-capacitance of the working electrode, at different potentials and temperatures. Unlike the HER, during which the mass transfer resistance of the adsorbed intermediate is dominant in the case of NiA, the OER impedance response is controlled by the charge transfer process itself at the potentials of interest for these process. The overall resistance related to the HER is lower for NiA than for NiX. © 2018 Hydrogen Energy Publications LLC",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media",
pages = "18977-18991",
volume = "43",
number = "41",
doi = "10.1016/j.ijhydene.2018.08.063",
url = "https://hdl.handle.net/21.15107/rcub_dais_4077"
}
Milikić, J., Vasić, M. M., Amaral, L., Cvjetićanin, N., Jugović, D., Hercigonja, R.,& Šljukić, B.. (2018). NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy
Elsevier., 43(41), 18977-18991.
https://doi.org/10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4077
Milikić J, Vasić MM, Amaral L, Cvjetićanin N, Jugović D, Hercigonja R, Šljukić B. NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media. in International Journal of Hydrogen Energy. 2018;43(41):18977-18991.
doi:10.1016/j.ijhydene.2018.08.063
https://hdl.handle.net/21.15107/rcub_dais_4077 .
Milikić, Jadranka, Vasić, Milica M., Amaral, Luis, Cvjetićanin, Nikola, Jugović, Dragana, Hercigonja, Radmila, Šljukić, Biljana, "NiA and NiX zeolites as bifunctional electrocatalysts for water splitting in alkaline media" in International Journal of Hydrogen Energy, 43, no. 41 (2018):18977-18991,
https://doi.org/10.1016/j.ijhydene.2018.08.063 .,
https://hdl.handle.net/21.15107/rcub_dais_4077 .
16
6
15

Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite

Mravik, Željko; Bajuk Bogdanović, Danica; Marković, Smilja; Kovač, Janez; Holclajtner Antunović, Ivanka; Jovanović, Zoran

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Marković, Smilja
AU  - Kovač, Janez
AU  - Holclajtner Antunović, Ivanka
AU  - Jovanović, Zoran
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/3666
AB  - The rich surface chemistry and large surface area of graphene oxide (GO) provide a platform for various functional materials that synergistically enhance charge storage properties of the composite. In present work we have investigated interaction between GO and 12- thungstophosphoric acid (WPA) in their nanocomposites as a function of different mass ratio of constituents. For this purpose, the Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometry (XPS), temperature programmed desorption method (TPD) and thermogravimetric/differential thermal analysis (TGA-DTA) methods were used. FTIR spectra have shown shifts and splitting of characteristic bands of WPA as a result of interactions with GO. Both XPS and TPD methods have shown an initial decrease of the total amount of surface oxygen groups of GO, with a minimum at around 10 wt.% of WPA, above which a restoration of the amount of surface oxygen groups was noticed. TGA-DTA analysis revealed an improved thermal stability of the material up to 25 wt.% of WPA; at higher loading of WPA the thermal properties of nanocomposite became alike to the ones of individual components. The obtained results suggest optimal conditions for preparation of GO-WPA nanocomposites for electrochemical charge storage applications.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite
SP  - 110
EP  - 110
UR  - https://hdl.handle.net/21.15107/rcub_dais_3666
ER  - 
@conference{
author = "Mravik, Željko and Bajuk Bogdanović, Danica and Marković, Smilja and Kovač, Janez and Holclajtner Antunović, Ivanka and Jovanović, Zoran",
year = "2018",
abstract = "The rich surface chemistry and large surface area of graphene oxide (GO) provide a platform for various functional materials that synergistically enhance charge storage properties of the composite. In present work we have investigated interaction between GO and 12- thungstophosphoric acid (WPA) in their nanocomposites as a function of different mass ratio of constituents. For this purpose, the Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometry (XPS), temperature programmed desorption method (TPD) and thermogravimetric/differential thermal analysis (TGA-DTA) methods were used. FTIR spectra have shown shifts and splitting of characteristic bands of WPA as a result of interactions with GO. Both XPS and TPD methods have shown an initial decrease of the total amount of surface oxygen groups of GO, with a minimum at around 10 wt.% of WPA, above which a restoration of the amount of surface oxygen groups was noticed. TGA-DTA analysis revealed an improved thermal stability of the material up to 25 wt.% of WPA; at higher loading of WPA the thermal properties of nanocomposite became alike to the ones of individual components. The obtained results suggest optimal conditions for preparation of GO-WPA nanocomposites for electrochemical charge storage applications.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite",
pages = "110-110",
url = "https://hdl.handle.net/21.15107/rcub_dais_3666"
}
Mravik, Ž., Bajuk Bogdanović, D., Marković, S., Kovač, J., Holclajtner Antunović, I.,& Jovanović, Z.. (2018). Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
Belgrade : Materials Research Society of Serbia., 110-110.
https://hdl.handle.net/21.15107/rcub_dais_3666
Mravik Ž, Bajuk Bogdanović D, Marković S, Kovač J, Holclajtner Antunović I, Jovanović Z. Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018. 2018;:110-110.
https://hdl.handle.net/21.15107/rcub_dais_3666 .
Mravik, Željko, Bajuk Bogdanović, Danica, Marković, Smilja, Kovač, Janez, Holclajtner Antunović, Ivanka, Jovanović, Zoran, "Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite" in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018 (2018):110-110,
https://hdl.handle.net/21.15107/rcub_dais_3666 .

Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite

Mravik, Željko; Bajuk Bogdanović, Danica; Marković, Smilja; Holclajtner Antunović, Ivanka; Jovanović, Zoran

(Belgrade : Institute of Technical Sciences of SASA, 2017)

TY  - CONF
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Marković, Smilja
AU  - Holclajtner Antunović, Ivanka
AU  - Jovanović, Zoran
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/15450
AB  - In recent years the nanocomposites of graphene oxide (GO) and different inorganic and organic compounds have shown great potential for charge storage applications. In present work we have investigated the influence of 12-tungstophosphoric acid (WPA) on surface chemistry of graphene oxide and thermal stability of nanocomposite. For this purpose nanocomposites with different mass ratios of GO and WPA were prepared. The thermal stability of nanocomposites was investigated by thermogravimetric and differential thermal analysis (TGA-DTA) while changes in surface chemistry of GO and structural properties of WPA were investigated by Fourier transform infrared spectroscopy (FTIR) and temperature programmed desorption (TPD) method. The TGA-DTA measurements of composites have shown that the major mass loss, due to carbon combustion, is shifted to higher temperatures (~500 °C vs. 380 °C of pure GO). Furthermore, when the amount of WPA is higher than 25 mass percent the nanocomposites start to act like individual components, which was also confirmed by FTIR analysis. The amount of surface oxygen groups, monitored by both TPD and FTIR methods, showed ˝V˝ shaped dependence from the quantity of WPA with minimum at about 12 mass percent of WPA. At the same time, the FTIR spectra revealed the structural changes of WPA, displayed as shifting and splitting of characteristic bands of Keggin anion structure.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
T1  - Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite
SP  - 48
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_dais_15450
ER  - 
@conference{
author = "Mravik, Željko and Bajuk Bogdanović, Danica and Marković, Smilja and Holclajtner Antunović, Ivanka and Jovanović, Zoran",
year = "2017",
abstract = "In recent years the nanocomposites of graphene oxide (GO) and different inorganic and organic compounds have shown great potential for charge storage applications. In present work we have investigated the influence of 12-tungstophosphoric acid (WPA) on surface chemistry of graphene oxide and thermal stability of nanocomposite. For this purpose nanocomposites with different mass ratios of GO and WPA were prepared. The thermal stability of nanocomposites was investigated by thermogravimetric and differential thermal analysis (TGA-DTA) while changes in surface chemistry of GO and structural properties of WPA were investigated by Fourier transform infrared spectroscopy (FTIR) and temperature programmed desorption (TPD) method. The TGA-DTA measurements of composites have shown that the major mass loss, due to carbon combustion, is shifted to higher temperatures (~500 °C vs. 380 °C of pure GO). Furthermore, when the amount of WPA is higher than 25 mass percent the nanocomposites start to act like individual components, which was also confirmed by FTIR analysis. The amount of surface oxygen groups, monitored by both TPD and FTIR methods, showed ˝V˝ shaped dependence from the quantity of WPA with minimum at about 12 mass percent of WPA. At the same time, the FTIR spectra revealed the structural changes of WPA, displayed as shifting and splitting of characteristic bands of Keggin anion structure.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia",
title = "Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite",
pages = "48-48",
url = "https://hdl.handle.net/21.15107/rcub_dais_15450"
}
Mravik, Ž., Bajuk Bogdanović, D., Marković, S., Holclajtner Antunović, I.,& Jovanović, Z.. (2017). Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 48-48.
https://hdl.handle.net/21.15107/rcub_dais_15450
Mravik Ž, Bajuk Bogdanović D, Marković S, Holclajtner Antunović I, Jovanović Z. Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia. 2017;:48-48.
https://hdl.handle.net/21.15107/rcub_dais_15450 .
Mravik, Željko, Bajuk Bogdanović, Danica, Marković, Smilja, Holclajtner Antunović, Ivanka, Jovanović, Zoran, "Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite" in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia (2017):48-48,
https://hdl.handle.net/21.15107/rcub_dais_15450 .

Spherical assemblies of titania nanotubes generated through aerosol processing

Jovanović, Dragana J.; Dugandžić, Ivan; Ćirić Marjanović, Gordana; Radetić, Tamara; Ahrenkiel, Scott P.; Milošević, Olivera; Nedeljković, Jovan; Šaponjić, Zoran; Mančić, Lidija

(Elsevier, 2015)

TY  - JOUR
AU  - Jovanović, Dragana J.
AU  - Dugandžić, Ivan
AU  - Ćirić Marjanović, Gordana
AU  - Radetić, Tamara
AU  - Ahrenkiel, Scott P.
AU  - Milošević, Olivera
AU  - Nedeljković, Jovan
AU  - Šaponjić, Zoran
AU  - Mančić, Lidija
PY  - 2015
UR  - https://dais.sanu.ac.rs/123456789/3523
AB  - We report on the possibility to build hierarchically organized three-dimensional (3D) titania spherical particles having high surface-to-volume-ratio, by aerosol processing of nanotubular building blocks. Morphology and crystal structure of titania based spherical assemblies, obtained in the temperature range from 150 to 650°C, were characterized by means of scanning and transmission electron microscopy, x-ray powder diffraction and Raman spectroscopy. Initial shape of 1D building units, nanotubes, was well preserved in the spherical assemblies processed at 150 and 450°C. Processing at 650°C resulted in a collapse of the nanotubular building blocks and formation of the assemblies of irregularly shaped TiO2 nanoparticles. Structural analysis revealed several phase transitions in titania spherical assemblies in course with the temperature increase indicating possibility of in-situ phase composition adjustment during aerosol processing. © 2015 Elsevier Ltd and Techna Group S.r.l.
PB  - Elsevier
T2  - Ceramics International
T1  - Spherical assemblies of titania nanotubes generated through aerosol processing
SP  - 14754
EP  - 14759
VL  - 41
IS  - 10, Part B
DO  - 10.1016/j.ceramint.2015.07.205
UR  - https://hdl.handle.net/21.15107/rcub_dais_3523
ER  - 
@article{
author = "Jovanović, Dragana J. and Dugandžić, Ivan and Ćirić Marjanović, Gordana and Radetić, Tamara and Ahrenkiel, Scott P. and Milošević, Olivera and Nedeljković, Jovan and Šaponjić, Zoran and Mančić, Lidija",
year = "2015",
abstract = "We report on the possibility to build hierarchically organized three-dimensional (3D) titania spherical particles having high surface-to-volume-ratio, by aerosol processing of nanotubular building blocks. Morphology and crystal structure of titania based spherical assemblies, obtained in the temperature range from 150 to 650°C, were characterized by means of scanning and transmission electron microscopy, x-ray powder diffraction and Raman spectroscopy. Initial shape of 1D building units, nanotubes, was well preserved in the spherical assemblies processed at 150 and 450°C. Processing at 650°C resulted in a collapse of the nanotubular building blocks and formation of the assemblies of irregularly shaped TiO2 nanoparticles. Structural analysis revealed several phase transitions in titania spherical assemblies in course with the temperature increase indicating possibility of in-situ phase composition adjustment during aerosol processing. © 2015 Elsevier Ltd and Techna Group S.r.l.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Spherical assemblies of titania nanotubes generated through aerosol processing",
pages = "14754-14759",
volume = "41",
number = "10, Part B",
doi = "10.1016/j.ceramint.2015.07.205",
url = "https://hdl.handle.net/21.15107/rcub_dais_3523"
}
Jovanović, D. J., Dugandžić, I., Ćirić Marjanović, G., Radetić, T., Ahrenkiel, S. P., Milošević, O., Nedeljković, J., Šaponjić, Z.,& Mančić, L.. (2015). Spherical assemblies of titania nanotubes generated through aerosol processing. in Ceramics International
Elsevier., 41(10, Part B), 14754-14759.
https://doi.org/10.1016/j.ceramint.2015.07.205
https://hdl.handle.net/21.15107/rcub_dais_3523
Jovanović DJ, Dugandžić I, Ćirić Marjanović G, Radetić T, Ahrenkiel SP, Milošević O, Nedeljković J, Šaponjić Z, Mančić L. Spherical assemblies of titania nanotubes generated through aerosol processing. in Ceramics International. 2015;41(10, Part B):14754-14759.
doi:10.1016/j.ceramint.2015.07.205
https://hdl.handle.net/21.15107/rcub_dais_3523 .
Jovanović, Dragana J., Dugandžić, Ivan, Ćirić Marjanović, Gordana, Radetić, Tamara, Ahrenkiel, Scott P., Milošević, Olivera, Nedeljković, Jovan, Šaponjić, Zoran, Mančić, Lidija, "Spherical assemblies of titania nanotubes generated through aerosol processing" in Ceramics International, 41, no. 10, Part B (2015):14754-14759,
https://doi.org/10.1016/j.ceramint.2015.07.205 .,
https://hdl.handle.net/21.15107/rcub_dais_3523 .
1
3
2
3