Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200175 (Institut tehničkih nauka SANU, Beograd) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200175 (Институт техничких наука САНУ, Београд) (sr)
Authors

Publications

Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric

Milošević, Milica V.; Radoičić, Marija; Ohara, Satoshi; Abe, Hiroya; Spasojević, Jelena; Mančić, Lidija; Šaponjić, Zoran

(Springer Science and Business Media LLC, 2023-04-01)

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Radoičić, Marija
AU  - Ohara, Satoshi
AU  - Abe, Hiroya
AU  - Spasojević, Jelena
AU  - Mančić, Lidija
AU  - Šaponjić, Zoran
PY  - 2023-04-01
UR  - https://dais.sanu.ac.rs/123456789/14316
AB  - Novel cotton-based TiO2/Ag/TiO2 nanocomposites for wastewater treatment were developed by fine chemical synthesis path with the goal of coping with wastewater issues and environmental remediation. The photocatalytic performances of nanocomposites were tested during photodegradation processes of RB, AO7 and MR under simulated solar light. Double- and single-loaded nanocomposites were synthesized by a simple bottom-up approach implying in situ photoreduction of Ag+ ions on the surface of TiO2 NPs previously deposited on cotton fibers from colloids. The spherical-like colloidal TiO2 NPs (4.5 nm) and TiO2/Ag NPs (8 nm) and the formation of uniform TiO2/Ag and TiO2/Ag/TiO2 nano-coatings on cotton fibers were examined by TEM and FESEM. The reduction of Ag+ ions on TiO2 surface was undoubtedly proven by the appearance of SPR band of Ag NPs in UV/Vis spectra. Raman spectroscopy clearly confirmed the presence of anatase TiO2 in nanocomposites. Quantitative determination of TiO2 and Ag in nanocomposites was accomplished using EDX and ICP–OES. The cotton-based TiO2/Ag/TiO2 nanocomposite showed the highest photocatalytic efficiency (> 90%) and maintained its removal efficiency after three reuse cycles, indicated its exceptional photochemical ability. The initial idea of improved photocatalytic performances of a TiO2 NPs double-layer with immobilized Ag NPs was justified as the TiO2/Ag/TiO2 processed sample contributed additional binding sites for dye molecules. Considering that the photocatalytic activity of the cotton-based TiO2 and TiO2/Ag samples was practically imperceptible, it can be assumed that the synthesized Ag NPs act predominantly as electron traps in the double-loaded synthesized system.
PB  - Springer Science and Business Media LLC
T2  - Cellulose
T1  - Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric
DO  - 10.1007/s10570-023-05165-0
UR  - https://hdl.handle.net/21.15107/rcub_dais_14316
ER  - 
@article{
author = "Milošević, Milica V. and Radoičić, Marija and Ohara, Satoshi and Abe, Hiroya and Spasojević, Jelena and Mančić, Lidija and Šaponjić, Zoran",
year = "2023-04-01",
abstract = "Novel cotton-based TiO2/Ag/TiO2 nanocomposites for wastewater treatment were developed by fine chemical synthesis path with the goal of coping with wastewater issues and environmental remediation. The photocatalytic performances of nanocomposites were tested during photodegradation processes of RB, AO7 and MR under simulated solar light. Double- and single-loaded nanocomposites were synthesized by a simple bottom-up approach implying in situ photoreduction of Ag+ ions on the surface of TiO2 NPs previously deposited on cotton fibers from colloids. The spherical-like colloidal TiO2 NPs (4.5 nm) and TiO2/Ag NPs (8 nm) and the formation of uniform TiO2/Ag and TiO2/Ag/TiO2 nano-coatings on cotton fibers were examined by TEM and FESEM. The reduction of Ag+ ions on TiO2 surface was undoubtedly proven by the appearance of SPR band of Ag NPs in UV/Vis spectra. Raman spectroscopy clearly confirmed the presence of anatase TiO2 in nanocomposites. Quantitative determination of TiO2 and Ag in nanocomposites was accomplished using EDX and ICP–OES. The cotton-based TiO2/Ag/TiO2 nanocomposite showed the highest photocatalytic efficiency (> 90%) and maintained its removal efficiency after three reuse cycles, indicated its exceptional photochemical ability. The initial idea of improved photocatalytic performances of a TiO2 NPs double-layer with immobilized Ag NPs was justified as the TiO2/Ag/TiO2 processed sample contributed additional binding sites for dye molecules. Considering that the photocatalytic activity of the cotton-based TiO2 and TiO2/Ag samples was practically imperceptible, it can be assumed that the synthesized Ag NPs act predominantly as electron traps in the double-loaded synthesized system.",
publisher = "Springer Science and Business Media LLC",
journal = "Cellulose",
title = "Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric",
doi = "10.1007/s10570-023-05165-0",
url = "https://hdl.handle.net/21.15107/rcub_dais_14316"
}
Milošević, M. V., Radoičić, M., Ohara, S., Abe, H., Spasojević, J., Mančić, L.,& Šaponjić, Z.. (2023-04-01). Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric. in Cellulose
Springer Science and Business Media LLC..
https://doi.org/10.1007/s10570-023-05165-0
https://hdl.handle.net/21.15107/rcub_dais_14316
Milošević MV, Radoičić M, Ohara S, Abe H, Spasojević J, Mančić L, Šaponjić Z. Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric. in Cellulose. 2023;.
doi:10.1007/s10570-023-05165-0
https://hdl.handle.net/21.15107/rcub_dais_14316 .
Milošević, Milica V., Radoičić, Marija, Ohara, Satoshi, Abe, Hiroya, Spasojević, Jelena, Mančić, Lidija, Šaponjić, Zoran, "Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric" in Cellulose (2023-04-01),
https://doi.org/10.1007/s10570-023-05165-0 .,
https://hdl.handle.net/21.15107/rcub_dais_14316 .

Estimation of honey bee colony infection with Nosema ceranae and Varroa destructor using fluorescence spectroscopy in combination with differential scanning calorimetry of honey samples

Stanković, Mira; Bartolić, Dragana; Mutavdžić, Dragosav; Marković, Smilja; Grubić, Saša; Jovanović, Nemanja M.; Radotić, Ksenija

(Taylor and Francis, 2023)

TY  - JOUR
AU  - Stanković, Mira
AU  - Bartolić, Dragana
AU  - Mutavdžić, Dragosav
AU  - Marković, Smilja
AU  - Grubić, Saša
AU  - Jovanović, Nemanja M.
AU  - Radotić, Ksenija
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/12336
AB  - In this preliminary study, we applied the Multivariate Curve Resolution- Alternating Least Squares (MCR-ALS) method to analyze the excitation-emission matrices of multifloral honey samples, combined with differential scanning calorimetry (DSC) to estimate infection of honey bee colonies with N. ceranae or V. destructor. Fluorescence spectroscopy combined with MCR-ALS was used to determine the ratio of the spectral components originating from proteins (C1) and phenolics (C2), two minor but essential constituents of honey, as a ratiometric indicator of infection level in related hives. The C1/C2 ratio decreased linearly with the increase of infection in both N. ceranae and V. destructor cases, the R2 was 0.941 and 0.912, respectively. Additionally, DSC has shown that the magnitude of changes in sugar environments of the honey samples, reflected in sugar phase transitions, rises with increasing infection level in bee colonies. These results indicate that fluorescence combined with MCR-ALS could be used for rapid, non-destructive and cheap screening of honey to estimate the level of infection of honey bee colonies.
PB  - Taylor and Francis
T2  - Journal of Apicultural Research
T1  - Estimation of honey bee colony infection with Nosema ceranae and Varroa destructor using fluorescence spectroscopy in combination with differential scanning calorimetry of honey samples
SP  - 507
EP  - 513
VL  - 62
IS  - 3
DO  - 10.1080/00218839.2021.1889803
UR  - https://hdl.handle.net/21.15107/rcub_dais_12336
ER  - 
@article{
author = "Stanković, Mira and Bartolić, Dragana and Mutavdžić, Dragosav and Marković, Smilja and Grubić, Saša and Jovanović, Nemanja M. and Radotić, Ksenija",
year = "2023",
abstract = "In this preliminary study, we applied the Multivariate Curve Resolution- Alternating Least Squares (MCR-ALS) method to analyze the excitation-emission matrices of multifloral honey samples, combined with differential scanning calorimetry (DSC) to estimate infection of honey bee colonies with N. ceranae or V. destructor. Fluorescence spectroscopy combined with MCR-ALS was used to determine the ratio of the spectral components originating from proteins (C1) and phenolics (C2), two minor but essential constituents of honey, as a ratiometric indicator of infection level in related hives. The C1/C2 ratio decreased linearly with the increase of infection in both N. ceranae and V. destructor cases, the R2 was 0.941 and 0.912, respectively. Additionally, DSC has shown that the magnitude of changes in sugar environments of the honey samples, reflected in sugar phase transitions, rises with increasing infection level in bee colonies. These results indicate that fluorescence combined with MCR-ALS could be used for rapid, non-destructive and cheap screening of honey to estimate the level of infection of honey bee colonies.",
publisher = "Taylor and Francis",
journal = "Journal of Apicultural Research",
title = "Estimation of honey bee colony infection with Nosema ceranae and Varroa destructor using fluorescence spectroscopy in combination with differential scanning calorimetry of honey samples",
pages = "507-513",
volume = "62",
number = "3",
doi = "10.1080/00218839.2021.1889803",
url = "https://hdl.handle.net/21.15107/rcub_dais_12336"
}
Stanković, M., Bartolić, D., Mutavdžić, D., Marković, S., Grubić, S., Jovanović, N. M.,& Radotić, K.. (2023). Estimation of honey bee colony infection with Nosema ceranae and Varroa destructor using fluorescence spectroscopy in combination with differential scanning calorimetry of honey samples. in Journal of Apicultural Research
Taylor and Francis., 62(3), 507-513.
https://doi.org/10.1080/00218839.2021.1889803
https://hdl.handle.net/21.15107/rcub_dais_12336
Stanković M, Bartolić D, Mutavdžić D, Marković S, Grubić S, Jovanović NM, Radotić K. Estimation of honey bee colony infection with Nosema ceranae and Varroa destructor using fluorescence spectroscopy in combination with differential scanning calorimetry of honey samples. in Journal of Apicultural Research. 2023;62(3):507-513.
doi:10.1080/00218839.2021.1889803
https://hdl.handle.net/21.15107/rcub_dais_12336 .
Stanković, Mira, Bartolić, Dragana, Mutavdžić, Dragosav, Marković, Smilja, Grubić, Saša, Jovanović, Nemanja M., Radotić, Ksenija, "Estimation of honey bee colony infection with Nosema ceranae and Varroa destructor using fluorescence spectroscopy in combination with differential scanning calorimetry of honey samples" in Journal of Apicultural Research, 62, no. 3 (2023):507-513,
https://doi.org/10.1080/00218839.2021.1889803 .,
https://hdl.handle.net/21.15107/rcub_dais_12336 .

Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion

Stamenković, Tijana; Radmilović, Nadežda; Prekajski-Đorđević, Marija D.; Rabasović, Mihailo; Dinić, Ivana; Tomić, Miloš; Lojpur, Vesna; Mančić, Lidija

(2023)

TY  - JOUR
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Prekajski-Đorđević, Marija D.
AU  - Rabasović, Mihailo
AU  - Dinić, Ivana
AU  - Tomić, Miloš
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14550
AB  - Nanopowders of up-conversion SrGd2O4 orthorhombic (Pnma) phase co-doped with different Yb3+ (1, 2.5 and 5 at%) and constant Er3+ (0.5 at%) ions were successfully prepared via sol-gel assisted combustion. Rietveld refinement indicated unit cell lattice parameters increase with Yb3+ and Er3+ ions doping. Scanning transmission electron microscopy with corresponding energy-dispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the up-conversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum yield of 0.055% is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc = 976 nm, power density 200 W/cm2).
T2  - Journal of Luminescence
T1  - Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion
SP  - 119491
VL  - 253
DO  - 10.1016/j.jlumin.2022.119491
UR  - https://hdl.handle.net/21.15107/rcub_dais_13491
ER  - 
@article{
author = "Stamenković, Tijana and Radmilović, Nadežda and Prekajski-Đorđević, Marija D. and Rabasović, Mihailo and Dinić, Ivana and Tomić, Miloš and Lojpur, Vesna and Mančić, Lidija",
year = "2023",
abstract = "Nanopowders of up-conversion SrGd2O4 orthorhombic (Pnma) phase co-doped with different Yb3+ (1, 2.5 and 5 at%) and constant Er3+ (0.5 at%) ions were successfully prepared via sol-gel assisted combustion. Rietveld refinement indicated unit cell lattice parameters increase with Yb3+ and Er3+ ions doping. Scanning transmission electron microscopy with corresponding energy-dispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the up-conversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum yield of 0.055% is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc = 976 nm, power density 200 W/cm2).",
journal = "Journal of Luminescence",
title = "Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion",
pages = "119491",
volume = "253",
doi = "10.1016/j.jlumin.2022.119491",
url = "https://hdl.handle.net/21.15107/rcub_dais_13491"
}
Stamenković, T., Radmilović, N., Prekajski-Đorđević, M. D., Rabasović, M., Dinić, I., Tomić, M., Lojpur, V.,& Mančić, L.. (2023). Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion. in Journal of Luminescence, 253, 119491.
https://doi.org/10.1016/j.jlumin.2022.119491
https://hdl.handle.net/21.15107/rcub_dais_13491
Stamenković T, Radmilović N, Prekajski-Đorđević MD, Rabasović M, Dinić I, Tomić M, Lojpur V, Mančić L. Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion. in Journal of Luminescence. 2023;253:119491.
doi:10.1016/j.jlumin.2022.119491
https://hdl.handle.net/21.15107/rcub_dais_13491 .
Stamenković, Tijana, Radmilović, Nadežda, Prekajski-Đorđević, Marija D., Rabasović, Mihailo, Dinić, Ivana, Tomić, Miloš, Lojpur, Vesna, Mančić, Lidija, "Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion" in Journal of Luminescence, 253 (2023):119491,
https://doi.org/10.1016/j.jlumin.2022.119491 .,
https://hdl.handle.net/21.15107/rcub_dais_13491 .

Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion

Stamenković, Tijana; Radmilović, Nadežda; Prekajski-Đorđević, Marija D.; Rabasović, Mihailo; Dinić, Ivana; Tomić, Miloš; Lojpur, Vesna; Mančić, Lidija

(2023)

TY  - JOUR
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Prekajski-Đorđević, Marija D.
AU  - Rabasović, Mihailo
AU  - Dinić, Ivana
AU  - Tomić, Miloš
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13491
AB  - Nanopowders of up-conversion SrGd2O4 orthorhombic (Pnma) phase co-doped with different Yb3+ (1, 2.5 and 5 at%) and constant Er3+ (0.5 at%) ions were successfully prepared via sol-gel assisted combustion. Rietveld refinement indicated unit cell lattice parameters increase with Yb3+ and Er3+ ions doping. Scanning transmission electron microscopy with corresponding energy-dispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the up-conversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum yield of 0.055% is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc = 976 nm, power density 200 W/cm2).
T2  - Journal of Luminescence
T1  - Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion
SP  - 119491
VL  - 253
DO  - 10.1016/j.jlumin.2022.119491
UR  - https://hdl.handle.net/21.15107/rcub_dais_13491
ER  - 
@article{
author = "Stamenković, Tijana and Radmilović, Nadežda and Prekajski-Đorđević, Marija D. and Rabasović, Mihailo and Dinić, Ivana and Tomić, Miloš and Lojpur, Vesna and Mančić, Lidija",
year = "2023",
abstract = "Nanopowders of up-conversion SrGd2O4 orthorhombic (Pnma) phase co-doped with different Yb3+ (1, 2.5 and 5 at%) and constant Er3+ (0.5 at%) ions were successfully prepared via sol-gel assisted combustion. Rietveld refinement indicated unit cell lattice parameters increase with Yb3+ and Er3+ ions doping. Scanning transmission electron microscopy with corresponding energy-dispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the up-conversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum yield of 0.055% is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc = 976 nm, power density 200 W/cm2).",
journal = "Journal of Luminescence",
title = "Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion",
pages = "119491",
volume = "253",
doi = "10.1016/j.jlumin.2022.119491",
url = "https://hdl.handle.net/21.15107/rcub_dais_13491"
}
Stamenković, T., Radmilović, N., Prekajski-Đorđević, M. D., Rabasović, M., Dinić, I., Tomić, M., Lojpur, V.,& Mančić, L.. (2023). Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion. in Journal of Luminescence, 253, 119491.
https://doi.org/10.1016/j.jlumin.2022.119491
https://hdl.handle.net/21.15107/rcub_dais_13491
Stamenković T, Radmilović N, Prekajski-Đorđević MD, Rabasović M, Dinić I, Tomić M, Lojpur V, Mančić L. Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion. in Journal of Luminescence. 2023;253:119491.
doi:10.1016/j.jlumin.2022.119491
https://hdl.handle.net/21.15107/rcub_dais_13491 .
Stamenković, Tijana, Radmilović, Nadežda, Prekajski-Đorđević, Marija D., Rabasović, Mihailo, Dinić, Ivana, Tomić, Miloš, Lojpur, Vesna, Mančić, Lidija, "Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion" in Journal of Luminescence, 253 (2023):119491,
https://doi.org/10.1016/j.jlumin.2022.119491 .,
https://hdl.handle.net/21.15107/rcub_dais_13491 .

Electrochemical formation and behavior of silver and lead chlorides as potential cathodes for quasi-rechargeable magnesium seawater cell

Popović, Aleksandra S.; Jugović, Dragana; Grgur, Branimir

(Springer Science and Business Media LLC, 2023)

TY  - JOUR
AU  - Popović, Aleksandra S.
AU  - Jugović, Dragana
AU  - Grgur, Branimir
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14544
AB  - Primary seawater magnesium-based cell with AgCl or PbCl2 cathodes is widely used as power sources. In this paper, we consider the cyclic galvanostatic formation of silver and lead chlorides and their electrochemical behavior for potential applications in the new concept of the seawater quasi-rechargeable magnesium cell. For potential cells, the voltage for Mg alloy AZ63 and AgCl is ~ 1.5 V, and for the PbCl2, ~ 1 V. High discharge specific capacity, energy, and power are obtained under the very high discharge rate. It is also presented that systems could be potentially used in emergency situations for a few days up to a few weeks as a power source in the life-saving boat for sporadic emitting GPS-SOS tacking signals and night signal lights.
PB  - Springer Science and Business Media LLC
T2  - Journal of Materials Science: Materials in Electronics
T1  - Electrochemical formation and behavior of silver and lead chlorides as potential cathodes for quasi-rechargeable magnesium seawater cell
VL  - 34
IS  - 14
DO  - 10.1007/s10854-023-10558-9
UR  - https://hdl.handle.net/21.15107/rcub_dais_14544
ER  - 
@article{
author = "Popović, Aleksandra S. and Jugović, Dragana and Grgur, Branimir",
year = "2023",
abstract = "Primary seawater magnesium-based cell with AgCl or PbCl2 cathodes is widely used as power sources. In this paper, we consider the cyclic galvanostatic formation of silver and lead chlorides and their electrochemical behavior for potential applications in the new concept of the seawater quasi-rechargeable magnesium cell. For potential cells, the voltage for Mg alloy AZ63 and AgCl is ~ 1.5 V, and for the PbCl2, ~ 1 V. High discharge specific capacity, energy, and power are obtained under the very high discharge rate. It is also presented that systems could be potentially used in emergency situations for a few days up to a few weeks as a power source in the life-saving boat for sporadic emitting GPS-SOS tacking signals and night signal lights.",
publisher = "Springer Science and Business Media LLC",
journal = "Journal of Materials Science: Materials in Electronics",
title = "Electrochemical formation and behavior of silver and lead chlorides as potential cathodes for quasi-rechargeable magnesium seawater cell",
volume = "34",
number = "14",
doi = "10.1007/s10854-023-10558-9",
url = "https://hdl.handle.net/21.15107/rcub_dais_14544"
}
Popović, A. S., Jugović, D.,& Grgur, B.. (2023). Electrochemical formation and behavior of silver and lead chlorides as potential cathodes for quasi-rechargeable magnesium seawater cell. in Journal of Materials Science: Materials in Electronics
Springer Science and Business Media LLC., 34(14).
https://doi.org/10.1007/s10854-023-10558-9
https://hdl.handle.net/21.15107/rcub_dais_14544
Popović AS, Jugović D, Grgur B. Electrochemical formation and behavior of silver and lead chlorides as potential cathodes for quasi-rechargeable magnesium seawater cell. in Journal of Materials Science: Materials in Electronics. 2023;34(14).
doi:10.1007/s10854-023-10558-9
https://hdl.handle.net/21.15107/rcub_dais_14544 .
Popović, Aleksandra S., Jugović, Dragana, Grgur, Branimir, "Electrochemical formation and behavior of silver and lead chlorides as potential cathodes for quasi-rechargeable magnesium seawater cell" in Journal of Materials Science: Materials in Electronics, 34, no. 14 (2023),
https://doi.org/10.1007/s10854-023-10558-9 .,
https://hdl.handle.net/21.15107/rcub_dais_14544 .

Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants

Pantović-Pavlović, Marijana R.; Ignjatović, Nenad; Panić, Vladimir V.; Mirkov, Ivana I.; Kulaš, Jelena B.; Malešević, Anastasija Lj.; Pavlović, Miroslav M.

(Basel : MDPI AG, 2023)

TY  - JOUR
AU  - Pantović-Pavlović, Marijana R.
AU  - Ignjatović, Nenad
AU  - Panić, Vladimir V.
AU  - Mirkov, Ivana I.
AU  - Kulaš, Jelena B.
AU  - Malešević, Anastasija Lj.
AU  - Pavlović, Miroslav M.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14406
AB  - The aim of this work is in situ anodization/anaphoretic deposition of a nano amorphous calcium phosphate (ACP)/chitosan oligosaccharide lactate (ChOL) multifunctional hybrid coating decorated with selenium (Se) on a titanium substrate and in vivo investigation of its immunomodulatory and anti-inflammatory effect. Investigating phenomena at the implant–tissue interface of interest for controlled inflammation and immunomodulation was also the aim of the research. In our earlier research, we designed coatings based on ACP and ChOL on titanium with anticorrosive, antibacterial and biocompatible properties, while in the presented results we show that selenium addition makes this coating an immunomodulator. The immunomodulatory effect of the novel hybrid coating is characterized by the examination of the functional aspects in the tissue around the implant (in vivo): proinflammatory cytokines’ gene expression, M1 (iNOS) and M2 (Arg1) macrophages, fibrous capsule formation (TGF-β) and vascularization (VEGF). The EDS, FTIR and XRD analyses prove the formation of a ACP/ChOL/Se multifunctional hybrid coating on Ti and the presence of Se. A higher M2/M1 macrophage ratio in the ACP/ChOL/Se-coated implants compared to pure titanium implants (a higher level of Arg1 expression) is noted at all time points examined (after 7, 14 and 28 days). Lower inflammation measured by gene expression of proinflammatory cytokines IL-1β and TNF, lower expression of TGF-β in the surrounding tissue and higher IL-6 expression (solely at day 7 post-implantation) is noted in presence of the ACP/ChOL/Se-coated implants.
PB  - Basel : MDPI AG
T2  - Journal of Functional Biomaterials
T1  - Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants
SP  - 227
VL  - 14
IS  - 4
DO  - 10.3390/jfb14040227
UR  - https://hdl.handle.net/21.15107/rcub_dais_14406
ER  - 
@article{
author = "Pantović-Pavlović, Marijana R. and Ignjatović, Nenad and Panić, Vladimir V. and Mirkov, Ivana I. and Kulaš, Jelena B. and Malešević, Anastasija Lj. and Pavlović, Miroslav M.",
year = "2023",
abstract = "The aim of this work is in situ anodization/anaphoretic deposition of a nano amorphous calcium phosphate (ACP)/chitosan oligosaccharide lactate (ChOL) multifunctional hybrid coating decorated with selenium (Se) on a titanium substrate and in vivo investigation of its immunomodulatory and anti-inflammatory effect. Investigating phenomena at the implant–tissue interface of interest for controlled inflammation and immunomodulation was also the aim of the research. In our earlier research, we designed coatings based on ACP and ChOL on titanium with anticorrosive, antibacterial and biocompatible properties, while in the presented results we show that selenium addition makes this coating an immunomodulator. The immunomodulatory effect of the novel hybrid coating is characterized by the examination of the functional aspects in the tissue around the implant (in vivo): proinflammatory cytokines’ gene expression, M1 (iNOS) and M2 (Arg1) macrophages, fibrous capsule formation (TGF-β) and vascularization (VEGF). The EDS, FTIR and XRD analyses prove the formation of a ACP/ChOL/Se multifunctional hybrid coating on Ti and the presence of Se. A higher M2/M1 macrophage ratio in the ACP/ChOL/Se-coated implants compared to pure titanium implants (a higher level of Arg1 expression) is noted at all time points examined (after 7, 14 and 28 days). Lower inflammation measured by gene expression of proinflammatory cytokines IL-1β and TNF, lower expression of TGF-β in the surrounding tissue and higher IL-6 expression (solely at day 7 post-implantation) is noted in presence of the ACP/ChOL/Se-coated implants.",
publisher = "Basel : MDPI AG",
journal = "Journal of Functional Biomaterials",
title = "Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants",
pages = "227",
volume = "14",
number = "4",
doi = "10.3390/jfb14040227",
url = "https://hdl.handle.net/21.15107/rcub_dais_14406"
}
Pantović-Pavlović, M. R., Ignjatović, N., Panić, V. V., Mirkov, I. I., Kulaš, J. B., Malešević, A. Lj.,& Pavlović, M. M.. (2023). Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants. in Journal of Functional Biomaterials
Basel : MDPI AG., 14(4), 227.
https://doi.org/10.3390/jfb14040227
https://hdl.handle.net/21.15107/rcub_dais_14406
Pantović-Pavlović MR, Ignjatović N, Panić VV, Mirkov II, Kulaš JB, Malešević AL, Pavlović MM. Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants. in Journal of Functional Biomaterials. 2023;14(4):227.
doi:10.3390/jfb14040227
https://hdl.handle.net/21.15107/rcub_dais_14406 .
Pantović-Pavlović, Marijana R., Ignjatović, Nenad, Panić, Vladimir V., Mirkov, Ivana I., Kulaš, Jelena B., Malešević, Anastasija Lj., Pavlović, Miroslav M., "Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants" in Journal of Functional Biomaterials, 14, no. 4 (2023):227,
https://doi.org/10.3390/jfb14040227 .,
https://hdl.handle.net/21.15107/rcub_dais_14406 .

Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric

Milošević, Milica V.; Radoičić, Marija; Ohara, Satoshi; Abe, Hiroya; Spasojević, Jelena; Mančić, Lidija; Šaponjić, Zoran

(Springer Science and Business Media LLC, 2023)

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Radoičić, Marija
AU  - Ohara, Satoshi
AU  - Abe, Hiroya
AU  - Spasojević, Jelena
AU  - Mančić, Lidija
AU  - Šaponjić, Zoran
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14403
AB  - Novel cotton-based TiO2/Ag/TiO2 nanocomposites for wastewater treatment were developed by fine chemical synthesis path with the goal of coping with wastewater issues and environmental remediation. The photocatalytic performances of nanocomposites were tested during photodegradation processes of RB, AO7 and MR under simulated solar light. Double- and single-loaded nanocomposites were synthesized by a simple bottom-up approach implying in situ photoreduction of Ag+ ions on the surface of TiO2 NPs previously deposited on cotton fibers from colloids. The spherical-like colloidal TiO2 NPs (4.5 nm) and TiO2/Ag NPs (8 nm) and the formation of uniform TiO2/Ag and TiO2/Ag/TiO2 nano-coatings on cotton fibers were examined by TEM and FESEM. The reduction of Ag+ ions on TiO2 surface was undoubtedly proven by the appearance of SPR band of Ag NPs in UV/Vis spectra. Raman spectroscopy clearly confirmed the presence of anatase TiO2 in nanocomposites. Quantitative determination of TiO2 and Ag in nanocomposites was accomplished using EDX and ICP–OES. The cotton-based TiO2/Ag/TiO2 nanocomposite showed the highest photocatalytic efficiency (> 90%) and maintained its removal efficiency after three reuse cycles, indicated its exceptional photochemical ability. The initial idea of improved photocatalytic performances of a TiO2 NPs double-layer with immobilized Ag NPs was justified as the TiO2/Ag/TiO2 processed sample contributed additional binding sites for dye molecules. Considering that the photocatalytic activity of the cotton-based TiO2 and TiO2/Ag samples was practically imperceptible, it can be assumed that the synthesized Ag NPs act predominantly as electron traps in the double-loaded synthesized system.
PB  - Springer Science and Business Media LLC
T2  - Cellulose
T1  - Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric
DO  - 10.1007/s10570-023-05165-0
UR  - https://hdl.handle.net/21.15107/rcub_dais_14403
ER  - 
@article{
author = "Milošević, Milica V. and Radoičić, Marija and Ohara, Satoshi and Abe, Hiroya and Spasojević, Jelena and Mančić, Lidija and Šaponjić, Zoran",
year = "2023",
abstract = "Novel cotton-based TiO2/Ag/TiO2 nanocomposites for wastewater treatment were developed by fine chemical synthesis path with the goal of coping with wastewater issues and environmental remediation. The photocatalytic performances of nanocomposites were tested during photodegradation processes of RB, AO7 and MR under simulated solar light. Double- and single-loaded nanocomposites were synthesized by a simple bottom-up approach implying in situ photoreduction of Ag+ ions on the surface of TiO2 NPs previously deposited on cotton fibers from colloids. The spherical-like colloidal TiO2 NPs (4.5 nm) and TiO2/Ag NPs (8 nm) and the formation of uniform TiO2/Ag and TiO2/Ag/TiO2 nano-coatings on cotton fibers were examined by TEM and FESEM. The reduction of Ag+ ions on TiO2 surface was undoubtedly proven by the appearance of SPR band of Ag NPs in UV/Vis spectra. Raman spectroscopy clearly confirmed the presence of anatase TiO2 in nanocomposites. Quantitative determination of TiO2 and Ag in nanocomposites was accomplished using EDX and ICP–OES. The cotton-based TiO2/Ag/TiO2 nanocomposite showed the highest photocatalytic efficiency (> 90%) and maintained its removal efficiency after three reuse cycles, indicated its exceptional photochemical ability. The initial idea of improved photocatalytic performances of a TiO2 NPs double-layer with immobilized Ag NPs was justified as the TiO2/Ag/TiO2 processed sample contributed additional binding sites for dye molecules. Considering that the photocatalytic activity of the cotton-based TiO2 and TiO2/Ag samples was practically imperceptible, it can be assumed that the synthesized Ag NPs act predominantly as electron traps in the double-loaded synthesized system.",
publisher = "Springer Science and Business Media LLC",
journal = "Cellulose",
title = "Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric",
doi = "10.1007/s10570-023-05165-0",
url = "https://hdl.handle.net/21.15107/rcub_dais_14403"
}
Milošević, M. V., Radoičić, M., Ohara, S., Abe, H., Spasojević, J., Mančić, L.,& Šaponjić, Z.. (2023). Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric. in Cellulose
Springer Science and Business Media LLC..
https://doi.org/10.1007/s10570-023-05165-0
https://hdl.handle.net/21.15107/rcub_dais_14403
Milošević MV, Radoičić M, Ohara S, Abe H, Spasojević J, Mančić L, Šaponjić Z. Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric. in Cellulose. 2023;.
doi:10.1007/s10570-023-05165-0
https://hdl.handle.net/21.15107/rcub_dais_14403 .
Milošević, Milica V., Radoičić, Marija, Ohara, Satoshi, Abe, Hiroya, Spasojević, Jelena, Mančić, Lidija, Šaponjić, Zoran, "Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric" in Cellulose (2023),
https://doi.org/10.1007/s10570-023-05165-0 .,
https://hdl.handle.net/21.15107/rcub_dais_14403 .

Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal

Vujančević, Jelena; Andričević, Pavao; Đokić, Veljko; Blagojević, Vladimir A.; Pavlović, Vera P.; Ćirković, Jovana; Horváth, Endre; Forró, László; Karoui, Abdennaceur; Pavlović, Vladimir B.; Janaćković, Đorđe

(MDPI, 2023)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Đokić, Veljko
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vera P.
AU  - Ćirković, Jovana
AU  - Horváth, Endre
AU  - Forró, László
AU  - Karoui, Abdennaceur
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14229
AB  - In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.
PB  - MDPI
T2  - Catalysts
T1  - Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal
SP  - 352
VL  - 13
IS  - 2
DO  - 10.3390/catal13020352
UR  - https://hdl.handle.net/21.15107/rcub_dais_14229
ER  - 
@article{
author = "Vujančević, Jelena and Andričević, Pavao and Đokić, Veljko and Blagojević, Vladimir A. and Pavlović, Vera P. and Ćirković, Jovana and Horváth, Endre and Forró, László and Karoui, Abdennaceur and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2023",
abstract = "In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.",
publisher = "MDPI",
journal = "Catalysts",
title = "Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal",
pages = "352",
volume = "13",
number = "2",
doi = "10.3390/catal13020352",
url = "https://hdl.handle.net/21.15107/rcub_dais_14229"
}
Vujančević, J., Andričević, P., Đokić, V., Blagojević, V. A., Pavlović, V. P., Ćirković, J., Horváth, E., Forró, L., Karoui, A., Pavlović, V. B.,& Janaćković, Đ.. (2023). Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal. in Catalysts
MDPI., 13(2), 352.
https://doi.org/10.3390/catal13020352
https://hdl.handle.net/21.15107/rcub_dais_14229
Vujančević J, Andričević P, Đokić V, Blagojević VA, Pavlović VP, Ćirković J, Horváth E, Forró L, Karoui A, Pavlović VB, Janaćković Đ. Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal. in Catalysts. 2023;13(2):352.
doi:10.3390/catal13020352
https://hdl.handle.net/21.15107/rcub_dais_14229 .
Vujančević, Jelena, Andričević, Pavao, Đokić, Veljko, Blagojević, Vladimir A., Pavlović, Vera P., Ćirković, Jovana, Horváth, Endre, Forró, László, Karoui, Abdennaceur, Pavlović, Vladimir B., Janaćković, Đorđe, "Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal" in Catalysts, 13, no. 2 (2023):352,
https://doi.org/10.3390/catal13020352 .,
https://hdl.handle.net/21.15107/rcub_dais_14229 .

Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites

Dojčinović, Milena P.; Vasiljević, Zorka Ž.; Rakočević, Lazar; Pavlović, Vera P.; Ammar-Merah, Souad; Vujančević, Jelena D.; Nikolić, Maria Vesna

(Basel : MDPI AG, 2023)

TY  - JOUR
AU  - Dojčinović, Milena P.
AU  - Vasiljević, Zorka Ž.
AU  - Rakočević, Lazar
AU  - Pavlović, Vera P.
AU  - Ammar-Merah, Souad
AU  - Vujančević, Jelena D.
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14025
AB  - Temperature- and humidity-sensing properties were evaluated of NixMg1-x spinel ferrites (0 ≤ x ≤ 1) synthesized by a sol-gel combustion method using citric acid as fuel and nitrate ions as oxidizing agents. After the exothermic reaction, amorphous powders were calcined at 700 °C followed by characterization with XRD, FTIR, XPS, EDS and Raman spectroscopy and FESEM microscopy. Synthesized powders were tested as humidity- and temperature-sensing materials in the form of thick films on interdigitated electrodes on alumina substrate in a climatic chamber. The physicochemical investigation of synthesized materials revealed a cubic spinel Fd3¯m phase, nanosized but agglomerated particles with a partially to completely inverse spinel structure with increasing Ni content. Ni0.1Mg0.9Fe2O4 showed the highest material constant (B30,90) value of 3747 K and temperature sensitivity (α) of −4.08%/K compared to pure magnesium ferrite (B30,90 value of 3426 K and α of −3.73%/K) and the highest average sensitivity towards humidity of 922 kΩ/%RH in the relative humidity (RH) range of 40–90% at the working temperature of 25 °C.
PB  - Basel : MDPI AG
T2  - Chemosensors
T1  - Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites
SP  - 34
VL  - 11
IS  - 1
DO  - 10.3390/chemosensors11010034
UR  - https://hdl.handle.net/21.15107/rcub_dais_14025
ER  - 
@article{
author = "Dojčinović, Milena P. and Vasiljević, Zorka Ž. and Rakočević, Lazar and Pavlović, Vera P. and Ammar-Merah, Souad and Vujančević, Jelena D. and Nikolić, Maria Vesna",
year = "2023",
abstract = "Temperature- and humidity-sensing properties were evaluated of NixMg1-x spinel ferrites (0 ≤ x ≤ 1) synthesized by a sol-gel combustion method using citric acid as fuel and nitrate ions as oxidizing agents. After the exothermic reaction, amorphous powders were calcined at 700 °C followed by characterization with XRD, FTIR, XPS, EDS and Raman spectroscopy and FESEM microscopy. Synthesized powders were tested as humidity- and temperature-sensing materials in the form of thick films on interdigitated electrodes on alumina substrate in a climatic chamber. The physicochemical investigation of synthesized materials revealed a cubic spinel Fd3¯m phase, nanosized but agglomerated particles with a partially to completely inverse spinel structure with increasing Ni content. Ni0.1Mg0.9Fe2O4 showed the highest material constant (B30,90) value of 3747 K and temperature sensitivity (α) of −4.08%/K compared to pure magnesium ferrite (B30,90 value of 3426 K and α of −3.73%/K) and the highest average sensitivity towards humidity of 922 kΩ/%RH in the relative humidity (RH) range of 40–90% at the working temperature of 25 °C.",
publisher = "Basel : MDPI AG",
journal = "Chemosensors",
title = "Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites",
pages = "34",
volume = "11",
number = "1",
doi = "10.3390/chemosensors11010034",
url = "https://hdl.handle.net/21.15107/rcub_dais_14025"
}
Dojčinović, M. P., Vasiljević, Z. Ž., Rakočević, L., Pavlović, V. P., Ammar-Merah, S., Vujančević, J. D.,& Nikolić, M. V.. (2023). Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites. in Chemosensors
Basel : MDPI AG., 11(1), 34.
https://doi.org/10.3390/chemosensors11010034
https://hdl.handle.net/21.15107/rcub_dais_14025
Dojčinović MP, Vasiljević ZŽ, Rakočević L, Pavlović VP, Ammar-Merah S, Vujančević JD, Nikolić MV. Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites. in Chemosensors. 2023;11(1):34.
doi:10.3390/chemosensors11010034
https://hdl.handle.net/21.15107/rcub_dais_14025 .
Dojčinović, Milena P., Vasiljević, Zorka Ž., Rakočević, Lazar, Pavlović, Vera P., Ammar-Merah, Souad, Vujančević, Jelena D., Nikolić, Maria Vesna, "Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites" in Chemosensors, 11, no. 1 (2023):34,
https://doi.org/10.3390/chemosensors11010034 .,
https://hdl.handle.net/21.15107/rcub_dais_14025 .
1

Integer codes capable of correcting burst asymmetric errors

Pokhrel, Nabin Kumar; Das, Pankaj Kumar; Radonjic, Aleksandar

(2023)

TY  - JOUR
AU  - Pokhrel, Nabin Kumar
AU  - Das, Pankaj Kumar
AU  - Radonjic, Aleksandar
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13515
AB  - In this paper, we present a class of integer codes capable of correcting burst asymmetric errors. The presented codes are constructed with the help of a computer and have the potential to be used in various practical systems, such as optical networks and VLSI memories. In order to evaluate the performance of the proposed codes, the paper analyzes the probability of erroneous decoding for different bit error rates. The presented codes are also analyzed from a rate-efficiency point of view. The obtained results show that for many data lengths they require less check-bits than optimal burst error correcting codes.
T2  - Journal of Applied Mathematics and Computing
T1  - Integer codes capable of correcting burst asymmetric errors
SP  - 771
EP  - 784
VL  - 69
DO  - 10.1007/s12190-022-01770-7
UR  - https://hdl.handle.net/21.15107/rcub_dais_13515
ER  - 
@article{
author = "Pokhrel, Nabin Kumar and Das, Pankaj Kumar and Radonjic, Aleksandar",
year = "2023",
abstract = "In this paper, we present a class of integer codes capable of correcting burst asymmetric errors. The presented codes are constructed with the help of a computer and have the potential to be used in various practical systems, such as optical networks and VLSI memories. In order to evaluate the performance of the proposed codes, the paper analyzes the probability of erroneous decoding for different bit error rates. The presented codes are also analyzed from a rate-efficiency point of view. The obtained results show that for many data lengths they require less check-bits than optimal burst error correcting codes.",
journal = "Journal of Applied Mathematics and Computing",
title = "Integer codes capable of correcting burst asymmetric errors",
pages = "771-784",
volume = "69",
doi = "10.1007/s12190-022-01770-7",
url = "https://hdl.handle.net/21.15107/rcub_dais_13515"
}
Pokhrel, N. K., Das, P. K.,& Radonjic, A.. (2023). Integer codes capable of correcting burst asymmetric errors. in Journal of Applied Mathematics and Computing, 69, 771-784.
https://doi.org/10.1007/s12190-022-01770-7
https://hdl.handle.net/21.15107/rcub_dais_13515
Pokhrel NK, Das PK, Radonjic A. Integer codes capable of correcting burst asymmetric errors. in Journal of Applied Mathematics and Computing. 2023;69:771-784.
doi:10.1007/s12190-022-01770-7
https://hdl.handle.net/21.15107/rcub_dais_13515 .
Pokhrel, Nabin Kumar, Das, Pankaj Kumar, Radonjic, Aleksandar, "Integer codes capable of correcting burst asymmetric errors" in Journal of Applied Mathematics and Computing, 69 (2023):771-784,
https://doi.org/10.1007/s12190-022-01770-7 .,
https://hdl.handle.net/21.15107/rcub_dais_13515 .
2
1

Integer codes capable of correcting burst asymmetric errors

Pokhrel, Nabin Kumar; Das, Pankaj Kumar; Radonjic, Aleksandar

(2023)

TY  - JOUR
AU  - Pokhrel, Nabin Kumar
AU  - Das, Pankaj Kumar
AU  - Radonjic, Aleksandar
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13578
AB  - In this paper, we present a class of integer codes capable of correcting burst asymmetric errors. The presented codes are constructed with the help of a computer and have the potential to be used in various practical systems, such as optical networks and VLSI memories. In order to evaluate the performance of the proposed codes, the paper analyzes the probability of erroneous decoding for different bit error rates. The presented codes are also analyzed from a rate-efficiency point of view. The obtained results show that for many data lengths they require less check-bits than optimal burst error correcting codes.
T2  - Journal of Applied Mathematics and Computing
T1  - Integer codes capable of correcting burst asymmetric errors
SP  - 771
EP  - 784
VL  - 69
DO  - 10.1007/s12190-022-01770-7
UR  - https://hdl.handle.net/21.15107/rcub_dais_13578
ER  - 
@article{
author = "Pokhrel, Nabin Kumar and Das, Pankaj Kumar and Radonjic, Aleksandar",
year = "2023",
abstract = "In this paper, we present a class of integer codes capable of correcting burst asymmetric errors. The presented codes are constructed with the help of a computer and have the potential to be used in various practical systems, such as optical networks and VLSI memories. In order to evaluate the performance of the proposed codes, the paper analyzes the probability of erroneous decoding for different bit error rates. The presented codes are also analyzed from a rate-efficiency point of view. The obtained results show that for many data lengths they require less check-bits than optimal burst error correcting codes.",
journal = "Journal of Applied Mathematics and Computing",
title = "Integer codes capable of correcting burst asymmetric errors",
pages = "771-784",
volume = "69",
doi = "10.1007/s12190-022-01770-7",
url = "https://hdl.handle.net/21.15107/rcub_dais_13578"
}
Pokhrel, N. K., Das, P. K.,& Radonjic, A.. (2023). Integer codes capable of correcting burst asymmetric errors. in Journal of Applied Mathematics and Computing, 69, 771-784.
https://doi.org/10.1007/s12190-022-01770-7
https://hdl.handle.net/21.15107/rcub_dais_13578
Pokhrel NK, Das PK, Radonjic A. Integer codes capable of correcting burst asymmetric errors. in Journal of Applied Mathematics and Computing. 2023;69:771-784.
doi:10.1007/s12190-022-01770-7
https://hdl.handle.net/21.15107/rcub_dais_13578 .
Pokhrel, Nabin Kumar, Das, Pankaj Kumar, Radonjic, Aleksandar, "Integer codes capable of correcting burst asymmetric errors" in Journal of Applied Mathematics and Computing, 69 (2023):771-784,
https://doi.org/10.1007/s12190-022-01770-7 .,
https://hdl.handle.net/21.15107/rcub_dais_13578 .
2
1

Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials

Biliškov, Nikola; Milanović, Igor; Milović, Miloš; Takats, Viktor; Erdelyi, Zoltan

(2023)

TY  - JOUR
AU  - Biliškov, Nikola
AU  - Milanović, Igor
AU  - Milović, Miloš
AU  - Takats, Viktor
AU  - Erdelyi, Zoltan
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14288
AB  - The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.
T2  - Journal of Alloys and Compounds
T1  - Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials
SP  - 169293
VL  - 945
DO  - 10.1016/j.jallcom.2023.169293
UR  - https://hdl.handle.net/21.15107/rcub_dais_14288
ER  - 
@article{
author = "Biliškov, Nikola and Milanović, Igor and Milović, Miloš and Takats, Viktor and Erdelyi, Zoltan",
year = "2023",
abstract = "The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.",
journal = "Journal of Alloys and Compounds",
title = "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials",
pages = "169293",
volume = "945",
doi = "10.1016/j.jallcom.2023.169293",
url = "https://hdl.handle.net/21.15107/rcub_dais_14288"
}
Biliškov, N., Milanović, I., Milović, M., Takats, V.,& Erdelyi, Z.. (2023). Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds, 945, 169293.
https://doi.org/10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_14288
Biliškov N, Milanović I, Milović M, Takats V, Erdelyi Z. Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds. 2023;945:169293.
doi:10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_14288 .
Biliškov, Nikola, Milanović, Igor, Milović, Miloš, Takats, Viktor, Erdelyi, Zoltan, "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials" in Journal of Alloys and Compounds, 945 (2023):169293,
https://doi.org/10.1016/j.jallcom.2023.169293 .,
https://hdl.handle.net/21.15107/rcub_dais_14288 .

Antimicrobial and Osteogenic Effects of Collagen Membrane Decorated with Chitosan–Nano-Hydroxyapatite

Lazarević, Miloš; Petrović, Sanja; Pierfelice, Tania Vanessa; Ignjatović, Nenad; Piattelli, Adriano; Vlajić Tovilović, Tamara; Radunović, Milena

(Basel : MDPI AG, 2023)

TY  - JOUR
AU  - Lazarević, Miloš
AU  - Petrović, Sanja
AU  - Pierfelice, Tania Vanessa
AU  - Ignjatović, Nenad
AU  - Piattelli, Adriano
AU  - Vlajić Tovilović, Tamara
AU  - Radunović, Milena
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14287
AB  - Collagen membranes are routinely used in oral surgery for bone regeneration. Despite their numerous advantages, such as stimulating bone growth, bacterial contamination still remains one of the disadvantages of membrane use. Thus, we assessed the biocompatibility and osteogenic and antibacterial properties of a collagen membrane (OsteoBiol) modified with chitosan (CHI) and hydroxyapatite nanoparticles (HApNPs). Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR FT-IR), X-ray powder diffraction (XRD), and field emission scanning electron microscopy (FE-SEM) were performed for membrane characterization. Biocompatibility was assessed on dental pulp stem cells (DPSCs) by an MTT assay, while the osteogenic effect was assessed by an ALP activity assay and qPCR analysis of osteogenic markers (BMP4, ALP, RUNX2, and OCN). Antimicrobial properties were investigated by counting colony-forming units (CFUs) of Streptococcus mitis, Porphyromonas gingivalis, and Fusobaterium nucleatum on membranes and in the surrounding medium. Membranes showed no cytotoxicity. ALP activity was higher and ALP, BMP4, and OCN genes were up-regulated in DPSCs on modified membranes compared to unmodified membranes. The CFUs were reduced on modified membranes and in the medium. Modified membranes showed great biocompatibility and a high osteoinductive effect. Additionally, they showed antimicrobial and antibiofilm effects against periopathogens. It can be concluded that the incorporation of CHI and hydroxyapatite nanoparticles in collagen membranes may be advantageous to promote osteogenesis and reduce bacterial adhesion.
PB  - Basel : MDPI AG
T2  - Biomolecules
T1  - Antimicrobial and Osteogenic Effects of Collagen Membrane Decorated with Chitosan–Nano-Hydroxyapatite
SP  - 579
VL  - 13
IS  - 4
DO  - 10.3390/biom13040579
UR  - https://hdl.handle.net/21.15107/rcub_dais_14287
ER  - 
@article{
author = "Lazarević, Miloš and Petrović, Sanja and Pierfelice, Tania Vanessa and Ignjatović, Nenad and Piattelli, Adriano and Vlajić Tovilović, Tamara and Radunović, Milena",
year = "2023",
abstract = "Collagen membranes are routinely used in oral surgery for bone regeneration. Despite their numerous advantages, such as stimulating bone growth, bacterial contamination still remains one of the disadvantages of membrane use. Thus, we assessed the biocompatibility and osteogenic and antibacterial properties of a collagen membrane (OsteoBiol) modified with chitosan (CHI) and hydroxyapatite nanoparticles (HApNPs). Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR FT-IR), X-ray powder diffraction (XRD), and field emission scanning electron microscopy (FE-SEM) were performed for membrane characterization. Biocompatibility was assessed on dental pulp stem cells (DPSCs) by an MTT assay, while the osteogenic effect was assessed by an ALP activity assay and qPCR analysis of osteogenic markers (BMP4, ALP, RUNX2, and OCN). Antimicrobial properties were investigated by counting colony-forming units (CFUs) of Streptococcus mitis, Porphyromonas gingivalis, and Fusobaterium nucleatum on membranes and in the surrounding medium. Membranes showed no cytotoxicity. ALP activity was higher and ALP, BMP4, and OCN genes were up-regulated in DPSCs on modified membranes compared to unmodified membranes. The CFUs were reduced on modified membranes and in the medium. Modified membranes showed great biocompatibility and a high osteoinductive effect. Additionally, they showed antimicrobial and antibiofilm effects against periopathogens. It can be concluded that the incorporation of CHI and hydroxyapatite nanoparticles in collagen membranes may be advantageous to promote osteogenesis and reduce bacterial adhesion.",
publisher = "Basel : MDPI AG",
journal = "Biomolecules",
title = "Antimicrobial and Osteogenic Effects of Collagen Membrane Decorated with Chitosan–Nano-Hydroxyapatite",
pages = "579",
volume = "13",
number = "4",
doi = "10.3390/biom13040579",
url = "https://hdl.handle.net/21.15107/rcub_dais_14287"
}
Lazarević, M., Petrović, S., Pierfelice, T. V., Ignjatović, N., Piattelli, A., Vlajić Tovilović, T.,& Radunović, M.. (2023). Antimicrobial and Osteogenic Effects of Collagen Membrane Decorated with Chitosan–Nano-Hydroxyapatite. in Biomolecules
Basel : MDPI AG., 13(4), 579.
https://doi.org/10.3390/biom13040579
https://hdl.handle.net/21.15107/rcub_dais_14287
Lazarević M, Petrović S, Pierfelice TV, Ignjatović N, Piattelli A, Vlajić Tovilović T, Radunović M. Antimicrobial and Osteogenic Effects of Collagen Membrane Decorated with Chitosan–Nano-Hydroxyapatite. in Biomolecules. 2023;13(4):579.
doi:10.3390/biom13040579
https://hdl.handle.net/21.15107/rcub_dais_14287 .
Lazarević, Miloš, Petrović, Sanja, Pierfelice, Tania Vanessa, Ignjatović, Nenad, Piattelli, Adriano, Vlajić Tovilović, Tamara, Radunović, Milena, "Antimicrobial and Osteogenic Effects of Collagen Membrane Decorated with Chitosan–Nano-Hydroxyapatite" in Biomolecules, 13, no. 4 (2023):579,
https://doi.org/10.3390/biom13040579 .,
https://hdl.handle.net/21.15107/rcub_dais_14287 .

Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid

Batinić, Petar M.; Đorđević, Verica; Obradović, Nataša S.; Krstić, Aleksandar D.; Stevanović, Sanja; Balanč, Bojana; Marković, Smilja; Pjanović, Rada; Mijin, Dušan; Bugarski, Branko

(Wiley, 2023)

TY  - JOUR
AU  - Batinić, Petar M.
AU  - Đorđević, Verica
AU  - Obradović, Nataša S.
AU  - Krstić, Aleksandar D.
AU  - Stevanović, Sanja
AU  - Balanč, Bojana
AU  - Marković, Smilja
AU  - Pjanović, Rada
AU  - Mijin, Dušan
AU  - Bugarski, Branko
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14283
AB  - Liposome-encapsulated folic acid was incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of carboxymethyl cellulose and solagum (9:1 w/w) using the film-forming cast solution method. Histidine was used to increase solubility for folic acid in liposomes (1-5 mg/ml), and propylene glycol was used as a film plasticizer (2.6 mas%). The obtained films (50-60 µm tick) containing 3.12-20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films were scrutinized. Folic acid gave yellow color to the films and contributed to stronger chemical bonds which resulted in improved strength of the film. Liposomes prolonged the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degraded homogeneity of the films, which could be ascribed to its agglomeration within the film matrix as revealed by AFM. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg/ml liposome-encapsulated folic acid is recommended from the point of view of release kinetics determined by its solubility.  Practical application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.
PB  - Wiley
T2  - European Journal of Lipid Science and Technology
T1  - Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid
SP  - 2200169
DO  - 10.1002/ejlt.202200169
UR  - https://hdl.handle.net/21.15107/rcub_dais_14283
ER  - 
@article{
author = "Batinić, Petar M. and Đorđević, Verica and Obradović, Nataša S. and Krstić, Aleksandar D. and Stevanović, Sanja and Balanč, Bojana and Marković, Smilja and Pjanović, Rada and Mijin, Dušan and Bugarski, Branko",
year = "2023",
abstract = "Liposome-encapsulated folic acid was incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of carboxymethyl cellulose and solagum (9:1 w/w) using the film-forming cast solution method. Histidine was used to increase solubility for folic acid in liposomes (1-5 mg/ml), and propylene glycol was used as a film plasticizer (2.6 mas%). The obtained films (50-60 µm tick) containing 3.12-20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films were scrutinized. Folic acid gave yellow color to the films and contributed to stronger chemical bonds which resulted in improved strength of the film. Liposomes prolonged the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degraded homogeneity of the films, which could be ascribed to its agglomeration within the film matrix as revealed by AFM. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg/ml liposome-encapsulated folic acid is recommended from the point of view of release kinetics determined by its solubility.  Practical application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.",
publisher = "Wiley",
journal = "European Journal of Lipid Science and Technology",
title = "Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid",
pages = "2200169",
doi = "10.1002/ejlt.202200169",
url = "https://hdl.handle.net/21.15107/rcub_dais_14283"
}
Batinić, P. M., Đorđević, V., Obradović, N. S., Krstić, A. D., Stevanović, S., Balanč, B., Marković, S., Pjanović, R., Mijin, D.,& Bugarski, B.. (2023). Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid. in European Journal of Lipid Science and Technology
Wiley., 2200169.
https://doi.org/10.1002/ejlt.202200169
https://hdl.handle.net/21.15107/rcub_dais_14283
Batinić PM, Đorđević V, Obradović NS, Krstić AD, Stevanović S, Balanč B, Marković S, Pjanović R, Mijin D, Bugarski B. Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid. in European Journal of Lipid Science and Technology. 2023;:2200169.
doi:10.1002/ejlt.202200169
https://hdl.handle.net/21.15107/rcub_dais_14283 .
Batinić, Petar M., Đorđević, Verica, Obradović, Nataša S., Krstić, Aleksandar D., Stevanović, Sanja, Balanč, Bojana, Marković, Smilja, Pjanović, Rada, Mijin, Dušan, Bugarski, Branko, "Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid" in European Journal of Lipid Science and Technology (2023):2200169,
https://doi.org/10.1002/ejlt.202200169 .,
https://hdl.handle.net/21.15107/rcub_dais_14283 .

The effect of the refractory material on the phase transformation parameteres during forming of the Al-8wt%Si-3wt%Cu structure

Mitrašinović, Aleksandar; Nešković, Jasmina; Labus, Nebojša; Radosavljević, Milinko

(Beograd : Savez inženjera i tehničara Srbije, 2023)

TY  - JOUR
AU  - Mitrašinović, Aleksandar
AU  - Nešković, Jasmina
AU  - Labus, Nebojša
AU  - Radosavljević, Milinko
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14224
AB  - Očvršćavanje legura aluminijuma se najčešće odvija u termootpornim oblogama sačinjenim ili od metala ili od oksida koji su stabilni na visokim temperaturama. Značajno različita toplotna provodljivost između metala i termootpornih oksida prouzrokuje očvršćavanje sa različitim brzinama hlađenja. U ovom radu smo formirali sekundarnu leguru Al-8wt%Si-3wt%Cu u kalupu od nerđajućeg čelika, tankozidnoj čaši od nerđajućeg čelika i debelozidnoj čaši od cirkonijum oksida. Tok formiranja očvrsle strukture je praćen zaronjenim termoparovima koji su omogućili kompjutersku analizu krive hlađenja. Parametri na koje je brzina hlađenja imala najznačajniji uticaj su vrednosti pothlađenja formiranja primarnih kristala aluminijuma, vreme rasta primarnih kristala aluminijuma i ukupno vreme očvršćavanja od pojave prvih čvrstih kristala do formiranja potpuno očvrsle strukture. Al-8wt%Si-3wt%Cu legura aluminijuma formirana u metalnim kalupima ima manju veličinu zrna i posledočno veću zateznu čvrstoću, manju makroporoznost i manje hrapavu površinu od legure formirane u oblogama od termootpornih oksida. Ispitivane termootporne obloge su uticale na formiranje tri osnovna mikrokonstituenta u Al-8wt%Si-3wt%Cu leguri u različitim vremenskim intervalima, što je dovelo do formiranja različite mikrostrukture, gde odluka o izboru materijala termootporne obloge zavisi od isplativosti celokupnog procesa, zahtevanog kvaliteta spoljnih površina i zahtevane minimalne čvrstoće konačnog proizvoda.
AB  - Solidification of the aluminum alloys takes place in heat-resistant refractory materials made of either metal or oxides that are stable at high temperatures. The significantly different thermal conductivities between metals and heat-resistant oxides cause solidification with significantly different cooling rates. In this work, we formed a secondary Al-8wt%Si-3wt%Cu alloy in a stainless steel mould, a thin-walled stainless steel cup, and a thick-walled zirconium oxide cup. The course of the formation of the solidified structure was monitored by immersed thermocouples, which enabled the computer analysis of the cooling curves. The parameters on which the cooling rate had the most significant influence are the undercooling values of the formation of primary aluminum crystals, the time of the growth of primary aluminum crystals and the total solidification time from the formation of the first solid crystals to the formation of a fully solidified structure. The Al-8wt%Si-3wt%Cu aluminum alloy formed in metal mould has a smaller grain size and consequently higher tensile strength, lower macro-porosity and less rough surface than the alloy formed in refractory oxide coatings. The examined heat-resistant refractory material influenced the formation of three basic micro-constituents in the Al-8wt%Si-3wt%Cu alloy in different time intervals, which led to the formation of a different microstructure, where the decision on the choice of material for the heat-resistant refractory material depends on the profitability of the entire process, the required quality of the external surfaces and required minimum strength of the final product.
PB  - Beograd : Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - The effect of the refractory material on the phase transformation parameteres during forming of the Al-8wt%Si-3wt%Cu structure
T1  - Uticaj termootporne obloge na parametre fazne transformacije tokom formiranja Al-8wt%Si-3wt%Cu strukture
SP  - 9
EP  - 14
VL  - 78
IS  - 1
DO  - 10.5937/tehnika2301009M
UR  - https://hdl.handle.net/21.15107/rcub_dais_14224
ER  - 
@article{
author = "Mitrašinović, Aleksandar and Nešković, Jasmina and Labus, Nebojša and Radosavljević, Milinko",
year = "2023",
abstract = "Očvršćavanje legura aluminijuma se najčešće odvija u termootpornim oblogama sačinjenim ili od metala ili od oksida koji su stabilni na visokim temperaturama. Značajno različita toplotna provodljivost između metala i termootpornih oksida prouzrokuje očvršćavanje sa različitim brzinama hlađenja. U ovom radu smo formirali sekundarnu leguru Al-8wt%Si-3wt%Cu u kalupu od nerđajućeg čelika, tankozidnoj čaši od nerđajućeg čelika i debelozidnoj čaši od cirkonijum oksida. Tok formiranja očvrsle strukture je praćen zaronjenim termoparovima koji su omogućili kompjutersku analizu krive hlađenja. Parametri na koje je brzina hlađenja imala najznačajniji uticaj su vrednosti pothlađenja formiranja primarnih kristala aluminijuma, vreme rasta primarnih kristala aluminijuma i ukupno vreme očvršćavanja od pojave prvih čvrstih kristala do formiranja potpuno očvrsle strukture. Al-8wt%Si-3wt%Cu legura aluminijuma formirana u metalnim kalupima ima manju veličinu zrna i posledočno veću zateznu čvrstoću, manju makroporoznost i manje hrapavu površinu od legure formirane u oblogama od termootpornih oksida. Ispitivane termootporne obloge su uticale na formiranje tri osnovna mikrokonstituenta u Al-8wt%Si-3wt%Cu leguri u različitim vremenskim intervalima, što je dovelo do formiranja različite mikrostrukture, gde odluka o izboru materijala termootporne obloge zavisi od isplativosti celokupnog procesa, zahtevanog kvaliteta spoljnih površina i zahtevane minimalne čvrstoće konačnog proizvoda., Solidification of the aluminum alloys takes place in heat-resistant refractory materials made of either metal or oxides that are stable at high temperatures. The significantly different thermal conductivities between metals and heat-resistant oxides cause solidification with significantly different cooling rates. In this work, we formed a secondary Al-8wt%Si-3wt%Cu alloy in a stainless steel mould, a thin-walled stainless steel cup, and a thick-walled zirconium oxide cup. The course of the formation of the solidified structure was monitored by immersed thermocouples, which enabled the computer analysis of the cooling curves. The parameters on which the cooling rate had the most significant influence are the undercooling values of the formation of primary aluminum crystals, the time of the growth of primary aluminum crystals and the total solidification time from the formation of the first solid crystals to the formation of a fully solidified structure. The Al-8wt%Si-3wt%Cu aluminum alloy formed in metal mould has a smaller grain size and consequently higher tensile strength, lower macro-porosity and less rough surface than the alloy formed in refractory oxide coatings. The examined heat-resistant refractory material influenced the formation of three basic micro-constituents in the Al-8wt%Si-3wt%Cu alloy in different time intervals, which led to the formation of a different microstructure, where the decision on the choice of material for the heat-resistant refractory material depends on the profitability of the entire process, the required quality of the external surfaces and required minimum strength of the final product.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "The effect of the refractory material on the phase transformation parameteres during forming of the Al-8wt%Si-3wt%Cu structure, Uticaj termootporne obloge na parametre fazne transformacije tokom formiranja Al-8wt%Si-3wt%Cu strukture",
pages = "9-14",
volume = "78",
number = "1",
doi = "10.5937/tehnika2301009M",
url = "https://hdl.handle.net/21.15107/rcub_dais_14224"
}
Mitrašinović, A., Nešković, J., Labus, N.,& Radosavljević, M.. (2023). The effect of the refractory material on the phase transformation parameteres during forming of the Al-8wt%Si-3wt%Cu structure. in Tehnika
Beograd : Savez inženjera i tehničara Srbije., 78(1), 9-14.
https://doi.org/10.5937/tehnika2301009M
https://hdl.handle.net/21.15107/rcub_dais_14224
Mitrašinović A, Nešković J, Labus N, Radosavljević M. The effect of the refractory material on the phase transformation parameteres during forming of the Al-8wt%Si-3wt%Cu structure. in Tehnika. 2023;78(1):9-14.
doi:10.5937/tehnika2301009M
https://hdl.handle.net/21.15107/rcub_dais_14224 .
Mitrašinović, Aleksandar, Nešković, Jasmina, Labus, Nebojša, Radosavljević, Milinko, "The effect of the refractory material on the phase transformation parameteres during forming of the Al-8wt%Si-3wt%Cu structure" in Tehnika, 78, no. 1 (2023):9-14,
https://doi.org/10.5937/tehnika2301009M .,
https://hdl.handle.net/21.15107/rcub_dais_14224 .
1

Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer

Labus, Nebojša; Krstić, Jugoslav; Matijašević, Srđan; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2023)

TY  - JOUR
AU  - Labus, Nebojša
AU  - Krstić, Jugoslav
AU  - Matijašević, Srđan
AU  - Pavlović, Vladimir B.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14120
AB  - Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550 ºC with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer
UR  - https://hdl.handle.net/21.15107/rcub_dais_14120
ER  - 
@article{
author = "Labus, Nebojša and Krstić, Jugoslav and Matijašević, Srđan and Pavlović, Vladimir B.",
year = "2023",
abstract = "Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550 ºC with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer",
url = "https://hdl.handle.net/21.15107/rcub_dais_14120"
}
Labus, N., Krstić, J., Matijašević, S.,& Pavlović, V. B.. (2023). Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer. in Science of Sintering
Belgrade : ETRAN..
https://hdl.handle.net/21.15107/rcub_dais_14120
Labus N, Krstić J, Matijašević S, Pavlović VB. Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer. in Science of Sintering. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14120 .
Labus, Nebojša, Krstić, Jugoslav, Matijašević, Srđan, Pavlović, Vladimir B., "Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer" in Science of Sintering (2023),
https://hdl.handle.net/21.15107/rcub_dais_14120 .

Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles

Dorm, Bruna Carolina; Iemma, Mônica Rosas Costa; Neto, Benedito Domingos; Francisco, Rauany Cristina Lopes; Dinić, Ivana; Ignjatović, Nenad; Marković, Smilja; Vuković, Marina; Škapin, Srečo; Trovatti, Eliane; Mančić, Lidija

(2023)

TY  - JOUR
AU  - Dorm, Bruna Carolina
AU  - Iemma, Mônica Rosas Costa
AU  - Neto, Benedito Domingos
AU  - Francisco, Rauany Cristina Lopes
AU  - Dinić, Ivana
AU  - Ignjatović, Nenad
AU  - Marković, Smilja
AU  - Vuković, Marina
AU  - Škapin, Srečo
AU  - Trovatti, Eliane
AU  - Mančić, Lidija
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13685
AB  - Hydroxyapatite attracts great attention as hard tissues implant material for bones and teeth. Its application in reconstructive medicine depends on its biocompatibility, which is in a function of composition and surface properties. The insertion of a protein element in the composition of implants can improve the cell adhesion and the osseointegration. Having this in mind, the proposal of this work was to develop L-alanine-grafted hydroxyapatite nanoparticles and to study their biocompatibility. Two L-alanine sources and three grafting methods were used for hydroxyapatite surface functionalization. The efficiency of grafting was determined based on X-ray powder diffraction, Fourier-transform infrared spectroscopy, thermal analyses, and field-emission scanning electron microscopy. The results indicated the formation of hydroxyapatite with 8–25 wt% of organic content, depending on the grafting method. Protein adsorption, cell adhesion, and viability studies were carried out to evaluate biological properties of grafted materials. The viability of MG-63 human osteoblastic cells following 24 h incubation with the alanine-grafted hydroxyapatite samples is well preserved, being in all cases above the viability of cells incubated with hydroxyapatite. The alanine-grafted hydroxyapatite prepared in situ and by simple mixture showed higher protein adsorption and cell adhesion, respectively, indicating their potential toward use in regenerative medicine.
T2  - Life
T1  - Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles
SP  - 116
VL  - 13
IS  - 1
DO  - 10.3390/life13010116
UR  - https://hdl.handle.net/21.15107/rcub_dais_13685
ER  - 
@article{
author = "Dorm, Bruna Carolina and Iemma, Mônica Rosas Costa and Neto, Benedito Domingos and Francisco, Rauany Cristina Lopes and Dinić, Ivana and Ignjatović, Nenad and Marković, Smilja and Vuković, Marina and Škapin, Srečo and Trovatti, Eliane and Mančić, Lidija",
year = "2023",
abstract = "Hydroxyapatite attracts great attention as hard tissues implant material for bones and teeth. Its application in reconstructive medicine depends on its biocompatibility, which is in a function of composition and surface properties. The insertion of a protein element in the composition of implants can improve the cell adhesion and the osseointegration. Having this in mind, the proposal of this work was to develop L-alanine-grafted hydroxyapatite nanoparticles and to study their biocompatibility. Two L-alanine sources and three grafting methods were used for hydroxyapatite surface functionalization. The efficiency of grafting was determined based on X-ray powder diffraction, Fourier-transform infrared spectroscopy, thermal analyses, and field-emission scanning electron microscopy. The results indicated the formation of hydroxyapatite with 8–25 wt% of organic content, depending on the grafting method. Protein adsorption, cell adhesion, and viability studies were carried out to evaluate biological properties of grafted materials. The viability of MG-63 human osteoblastic cells following 24 h incubation with the alanine-grafted hydroxyapatite samples is well preserved, being in all cases above the viability of cells incubated with hydroxyapatite. The alanine-grafted hydroxyapatite prepared in situ and by simple mixture showed higher protein adsorption and cell adhesion, respectively, indicating their potential toward use in regenerative medicine.",
journal = "Life",
title = "Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles",
pages = "116",
volume = "13",
number = "1",
doi = "10.3390/life13010116",
url = "https://hdl.handle.net/21.15107/rcub_dais_13685"
}
Dorm, B. C., Iemma, M. R. C., Neto, B. D., Francisco, R. C. L., Dinić, I., Ignjatović, N., Marković, S., Vuković, M., Škapin, S., Trovatti, E.,& Mančić, L.. (2023). Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles. in Life, 13(1), 116.
https://doi.org/10.3390/life13010116
https://hdl.handle.net/21.15107/rcub_dais_13685
Dorm BC, Iemma MRC, Neto BD, Francisco RCL, Dinić I, Ignjatović N, Marković S, Vuković M, Škapin S, Trovatti E, Mančić L. Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles. in Life. 2023;13(1):116.
doi:10.3390/life13010116
https://hdl.handle.net/21.15107/rcub_dais_13685 .
Dorm, Bruna Carolina, Iemma, Mônica Rosas Costa, Neto, Benedito Domingos, Francisco, Rauany Cristina Lopes, Dinić, Ivana, Ignjatović, Nenad, Marković, Smilja, Vuković, Marina, Škapin, Srečo, Trovatti, Eliane, Mančić, Lidija, "Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles" in Life, 13, no. 1 (2023):116,
https://doi.org/10.3390/life13010116 .,
https://hdl.handle.net/21.15107/rcub_dais_13685 .

Properties of Hydroxyapatite-Based Biomaterials Important for Interactions with Cells and Tissues

Živković, Jelena M.; Ignjatović, Nenad; Najman, Stevo

(Springer International Publishing, 2023)

TY  - CHAP
AU  - Živković, Jelena M.
AU  - Ignjatović, Nenad
AU  - Najman, Stevo
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13683
AB  - Mammal bone tissue is mainly composed of an inorganic component consisting of calcium phosphate (CaPCalcium phosphateCaP) ceramics, predominantly calcium hydroxyapatiteCalcium phosphatecalcium hydroxyapatite (HAp)Calcium phosphateHAp, in addition to the organic component. Properties of HAp enable the modification of its structure, surface, design of particle size at the micro and the macro levels, hybridization with polymers, metals, etc., which makes it a very important biomaterial in the future as well. The properties of HAp can be improved by combination with a large number of therapeuticBiomaterialtherapeuticCalcium phosphateBioceramics and/or diagnosticBiomaterialdiagnosticBioceramicsCalcium phosphate agents. CaP and HAp occupy a significant place in the research of different types of multifunctionalMaterialsmultifunctional and hybridMaterialshybrid materials for potential application in diagnostic, preventiveMaterialspreventive, oncological, reconstructiveMaterialsreconstructiveRegenerative medicine and regenerative medicine. There are numerous data on the properties of HAp and HAp-based biomaterials relevant to their use, such as composition, particle sizeBiomaterialparticle sizeBioceramicsCalcium phosphate, material shape, porosity, surface charge, topography, etc. This chapter also discusses the different properties of hydroxyapatite and hydroxyapatite-based biomaterials important for interactionBiomaterialinteractionTissueCell with cells and tissues. In addition to references to literature data, the results of our research with different hydroxyapatite-based biomaterials in different in vitroModelsin vitroCellMethod and in vivoModelsin vivoMethodTissue engineering experimentalModelsexperimental modelsModels in the field of bone tissue engineeringTissue engineeringbone tissue engineering and regenerative medicine are presented.
PB  - Springer International Publishing
T2  - Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications
T1  - Properties of Hydroxyapatite-Based Biomaterials Important for Interactions with Cells and Tissues
SP  - 115
EP  - 135
DO  - 10.1007/978-3-031-17269-4_6
UR  - https://hdl.handle.net/21.15107/rcub_dais_13683
ER  - 
@inbook{
author = "Živković, Jelena M. and Ignjatović, Nenad and Najman, Stevo",
year = "2023",
abstract = "Mammal bone tissue is mainly composed of an inorganic component consisting of calcium phosphate (CaPCalcium phosphateCaP) ceramics, predominantly calcium hydroxyapatiteCalcium phosphatecalcium hydroxyapatite (HAp)Calcium phosphateHAp, in addition to the organic component. Properties of HAp enable the modification of its structure, surface, design of particle size at the micro and the macro levels, hybridization with polymers, metals, etc., which makes it a very important biomaterial in the future as well. The properties of HAp can be improved by combination with a large number of therapeuticBiomaterialtherapeuticCalcium phosphateBioceramics and/or diagnosticBiomaterialdiagnosticBioceramicsCalcium phosphate agents. CaP and HAp occupy a significant place in the research of different types of multifunctionalMaterialsmultifunctional and hybridMaterialshybrid materials for potential application in diagnostic, preventiveMaterialspreventive, oncological, reconstructiveMaterialsreconstructiveRegenerative medicine and regenerative medicine. There are numerous data on the properties of HAp and HAp-based biomaterials relevant to their use, such as composition, particle sizeBiomaterialparticle sizeBioceramicsCalcium phosphate, material shape, porosity, surface charge, topography, etc. This chapter also discusses the different properties of hydroxyapatite and hydroxyapatite-based biomaterials important for interactionBiomaterialinteractionTissueCell with cells and tissues. In addition to references to literature data, the results of our research with different hydroxyapatite-based biomaterials in different in vitroModelsin vitroCellMethod and in vivoModelsin vivoMethodTissue engineering experimentalModelsexperimental modelsModels in the field of bone tissue engineeringTissue engineeringbone tissue engineering and regenerative medicine are presented.",
publisher = "Springer International Publishing",
journal = "Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications",
booktitle = "Properties of Hydroxyapatite-Based Biomaterials Important for Interactions with Cells and Tissues",
pages = "115-135",
doi = "10.1007/978-3-031-17269-4_6",
url = "https://hdl.handle.net/21.15107/rcub_dais_13683"
}
Živković, J. M., Ignjatović, N.,& Najman, S.. (2023). Properties of Hydroxyapatite-Based Biomaterials Important for Interactions with Cells and Tissues. in Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications
Springer International Publishing., 115-135.
https://doi.org/10.1007/978-3-031-17269-4_6
https://hdl.handle.net/21.15107/rcub_dais_13683
Živković JM, Ignjatović N, Najman S. Properties of Hydroxyapatite-Based Biomaterials Important for Interactions with Cells and Tissues. in Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications. 2023;:115-135.
doi:10.1007/978-3-031-17269-4_6
https://hdl.handle.net/21.15107/rcub_dais_13683 .
Živković, Jelena M., Ignjatović, Nenad, Najman, Stevo, "Properties of Hydroxyapatite-Based Biomaterials Important for Interactions with Cells and Tissues" in Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications (2023):115-135,
https://doi.org/10.1007/978-3-031-17269-4_6 .,
https://hdl.handle.net/21.15107/rcub_dais_13683 .

A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells

Lović, Jelena; Eraković Pantović, Sanja; Rakočević, Lazar; Ignjatović, Nenad; Dimitrijević, Silvana B.; Nikolić, Nebojša D.

(2023)

TY  - JOUR
AU  - Lović, Jelena
AU  - Eraković Pantović, Sanja
AU  - Rakočević, Lazar
AU  - Ignjatović, Nenad
AU  - Dimitrijević, Silvana B.
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13684
AB  - Sn-Pd electrocatalysts with a constant atomic ratio of 60 at.% Sn‒40 at.% Pd suitable for potential application in direct ethanol fuel cells were synthesized using a novel two-step electrodeposition method. First, Sn was electrodeposited in various forms of dendrites, from spear-like and needle-like to individual fern-like dendrites to a network of intertwined fern-like dendrites, by varying the cathodic potential and then performing electrodeposition of Pd at a constant current density in the second step. A morphological and elemental analysis of Sn and Sn-Pd electrocatalysts was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) techniques, while the size of Sn dendrites was analyzed using the particle size distribution (PSD) method. Cyclic voltammetry (CV) and chronoamperometry were applied in order to study the catalytic behavior of Sn-Pd electrocatalysts in the ethanol oxidation reaction (EOR), while CO stripping was used to estimate the antipoisoning capability of the electrocatalysts. The Sn surface morphology of the sub-layer was highly correlated with the electrocatalytic activity of the examined Sn-Pd electrocatalysts. The high activity it presented towards the EOR showed the suitability of the Sn-Pd electrocatalyst constructed from individual fern-like Sn dendrites as a sub-layer. Compared to Pd alone, this Sn-Pd catalyst showed more than 3 times higher activity and improved EOR kinetics. This enhancement in the catalytic activity of the Sn-Pd electrocatalysts is attributed to both the morphological characteristics of Sn as a sub-layer and the bifunctional effect.
T2  - Processes
T1  - A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells
SP  - 120
VL  - 11
IS  - 1
DO  - 10.3390/pr11010120
UR  - https://hdl.handle.net/21.15107/rcub_dais_13684
ER  - 
@article{
author = "Lović, Jelena and Eraković Pantović, Sanja and Rakočević, Lazar and Ignjatović, Nenad and Dimitrijević, Silvana B. and Nikolić, Nebojša D.",
year = "2023",
abstract = "Sn-Pd electrocatalysts with a constant atomic ratio of 60 at.% Sn‒40 at.% Pd suitable for potential application in direct ethanol fuel cells were synthesized using a novel two-step electrodeposition method. First, Sn was electrodeposited in various forms of dendrites, from spear-like and needle-like to individual fern-like dendrites to a network of intertwined fern-like dendrites, by varying the cathodic potential and then performing electrodeposition of Pd at a constant current density in the second step. A morphological and elemental analysis of Sn and Sn-Pd electrocatalysts was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) techniques, while the size of Sn dendrites was analyzed using the particle size distribution (PSD) method. Cyclic voltammetry (CV) and chronoamperometry were applied in order to study the catalytic behavior of Sn-Pd electrocatalysts in the ethanol oxidation reaction (EOR), while CO stripping was used to estimate the antipoisoning capability of the electrocatalysts. The Sn surface morphology of the sub-layer was highly correlated with the electrocatalytic activity of the examined Sn-Pd electrocatalysts. The high activity it presented towards the EOR showed the suitability of the Sn-Pd electrocatalyst constructed from individual fern-like Sn dendrites as a sub-layer. Compared to Pd alone, this Sn-Pd catalyst showed more than 3 times higher activity and improved EOR kinetics. This enhancement in the catalytic activity of the Sn-Pd electrocatalysts is attributed to both the morphological characteristics of Sn as a sub-layer and the bifunctional effect.",
journal = "Processes",
title = "A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells",
pages = "120",
volume = "11",
number = "1",
doi = "10.3390/pr11010120",
url = "https://hdl.handle.net/21.15107/rcub_dais_13684"
}
Lović, J., Eraković Pantović, S., Rakočević, L., Ignjatović, N., Dimitrijević, S. B.,& Nikolić, N. D.. (2023). A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells. in Processes, 11(1), 120.
https://doi.org/10.3390/pr11010120
https://hdl.handle.net/21.15107/rcub_dais_13684
Lović J, Eraković Pantović S, Rakočević L, Ignjatović N, Dimitrijević SB, Nikolić ND. A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells. in Processes. 2023;11(1):120.
doi:10.3390/pr11010120
https://hdl.handle.net/21.15107/rcub_dais_13684 .
Lović, Jelena, Eraković Pantović, Sanja, Rakočević, Lazar, Ignjatović, Nenad, Dimitrijević, Silvana B., Nikolić, Nebojša D., "A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells" in Processes, 11, no. 1 (2023):120,
https://doi.org/10.3390/pr11010120 .,
https://hdl.handle.net/21.15107/rcub_dais_13684 .

Nanomechanical properties of PVDF–ZnO polymer nanocomposite

Peleš Tadić, Adriana; Blagojević, Vladimir A.; Stojanović, Dušica; Ostojić, Sanja B.; Tasić, Nikola; Kosanović, Darko; Uskoković, Petar; Pavlović, Vladimir B.

(Elsevier BV, 2023)

TY  - JOUR
AU  - Peleš Tadić, Adriana
AU  - Blagojević, Vladimir A.
AU  - Stojanović, Dušica
AU  - Ostojić, Sanja B.
AU  - Tasić, Nikola
AU  - Kosanović, Darko
AU  - Uskoković, Petar
AU  - Pavlović, Vladimir B.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13560
AB  - Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.
PB  - Elsevier BV
T2  - Materials Science and Engineering: B
T1  - Nanomechanical properties of PVDF–ZnO polymer nanocomposite
SP  - 116126
VL  - 287
DO  - 10.1016/j.mseb.2022.116126
UR  - https://hdl.handle.net/21.15107/rcub_dais_13436
ER  - 
@article{
author = "Peleš Tadić, Adriana and Blagojević, Vladimir A. and Stojanović, Dušica and Ostojić, Sanja B. and Tasić, Nikola and Kosanović, Darko and Uskoković, Petar and Pavlović, Vladimir B.",
year = "2023",
abstract = "Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.",
publisher = "Elsevier BV",
journal = "Materials Science and Engineering: B",
title = "Nanomechanical properties of PVDF–ZnO polymer nanocomposite",
pages = "116126",
volume = "287",
doi = "10.1016/j.mseb.2022.116126",
url = "https://hdl.handle.net/21.15107/rcub_dais_13436"
}
Peleš Tadić, A., Blagojević, V. A., Stojanović, D., Ostojić, S. B., Tasić, N., Kosanović, D., Uskoković, P.,& Pavlović, V. B.. (2023). Nanomechanical properties of PVDF–ZnO polymer nanocomposite. in Materials Science and Engineering: B
Elsevier BV., 287, 116126.
https://doi.org/10.1016/j.mseb.2022.116126
https://hdl.handle.net/21.15107/rcub_dais_13436
Peleš Tadić A, Blagojević VA, Stojanović D, Ostojić SB, Tasić N, Kosanović D, Uskoković P, Pavlović VB. Nanomechanical properties of PVDF–ZnO polymer nanocomposite. in Materials Science and Engineering: B. 2023;287:116126.
doi:10.1016/j.mseb.2022.116126
https://hdl.handle.net/21.15107/rcub_dais_13436 .
Peleš Tadić, Adriana, Blagojević, Vladimir A., Stojanović, Dušica, Ostojić, Sanja B., Tasić, Nikola, Kosanović, Darko, Uskoković, Petar, Pavlović, Vladimir B., "Nanomechanical properties of PVDF–ZnO polymer nanocomposite" in Materials Science and Engineering: B, 287 (2023):116126,
https://doi.org/10.1016/j.mseb.2022.116126 .,
https://hdl.handle.net/21.15107/rcub_dais_13436 .
2
1

Nanomechanical properties of PVDF–ZnO polymer nanocomposite

Peleš Tadić, Adriana; Blagojević, Vladimir A.; Stojanović, Dušica; Ostojić, Sanja B.; Tasić, Nikola; Kosanović, Darko; Uskoković, Petar; Pavlović, Vladimir B.

(Elsevier BV, 2023)

TY  - JOUR
AU  - Peleš Tadić, Adriana
AU  - Blagojević, Vladimir A.
AU  - Stojanović, Dušica
AU  - Ostojić, Sanja B.
AU  - Tasić, Nikola
AU  - Kosanović, Darko
AU  - Uskoković, Petar
AU  - Pavlović, Vladimir B.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/13436
AB  - Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.
PB  - Elsevier BV
T2  - Materials Science and Engineering: B
T1  - Nanomechanical properties of PVDF–ZnO polymer nanocomposite
SP  - 116126
VL  - 287
DO  - 10.1016/j.mseb.2022.116126
UR  - https://hdl.handle.net/21.15107/rcub_dais_13436
ER  - 
@article{
author = "Peleš Tadić, Adriana and Blagojević, Vladimir A. and Stojanović, Dušica and Ostojić, Sanja B. and Tasić, Nikola and Kosanović, Darko and Uskoković, Petar and Pavlović, Vladimir B.",
year = "2023",
abstract = "Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.",
publisher = "Elsevier BV",
journal = "Materials Science and Engineering: B",
title = "Nanomechanical properties of PVDF–ZnO polymer nanocomposite",
pages = "116126",
volume = "287",
doi = "10.1016/j.mseb.2022.116126",
url = "https://hdl.handle.net/21.15107/rcub_dais_13436"
}
Peleš Tadić, A., Blagojević, V. A., Stojanović, D., Ostojić, S. B., Tasić, N., Kosanović, D., Uskoković, P.,& Pavlović, V. B.. (2023). Nanomechanical properties of PVDF–ZnO polymer nanocomposite. in Materials Science and Engineering: B
Elsevier BV., 287, 116126.
https://doi.org/10.1016/j.mseb.2022.116126
https://hdl.handle.net/21.15107/rcub_dais_13436
Peleš Tadić A, Blagojević VA, Stojanović D, Ostojić SB, Tasić N, Kosanović D, Uskoković P, Pavlović VB. Nanomechanical properties of PVDF–ZnO polymer nanocomposite. in Materials Science and Engineering: B. 2023;287:116126.
doi:10.1016/j.mseb.2022.116126
https://hdl.handle.net/21.15107/rcub_dais_13436 .
Peleš Tadić, Adriana, Blagojević, Vladimir A., Stojanović, Dušica, Ostojić, Sanja B., Tasić, Nikola, Kosanović, Darko, Uskoković, Petar, Pavlović, Vladimir B., "Nanomechanical properties of PVDF–ZnO polymer nanocomposite" in Materials Science and Engineering: B, 287 (2023):116126,
https://doi.org/10.1016/j.mseb.2022.116126 .,
https://hdl.handle.net/21.15107/rcub_dais_13436 .
2
1

Rational design in photoresponsive hierarchical nanomaterials processing

Milošević, Olivera; Rabanal, Maria Eugenia; Mančić, Lidija; Milošević, Milica V.

(Kyoto : The Society of Powder Technology, 2022)

TY  - CONF
AU  - Milošević, Olivera
AU  - Rabanal, Maria Eugenia
AU  - Mančić, Lidija
AU  - Milošević, Milica V.
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13646
PB  - Kyoto : The Society of Powder Technology
C3  - Program and Abstracts / ICCCI 2022 : The 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology, Fujiyoshida, Japan, November 15-18, 2022
T1  - Rational design in photoresponsive hierarchical nanomaterials processing
UR  - https://hdl.handle.net/21.15107/rcub_dais_13646
ER  - 
@conference{
author = "Milošević, Olivera and Rabanal, Maria Eugenia and Mančić, Lidija and Milošević, Milica V.",
year = "2022",
publisher = "Kyoto : The Society of Powder Technology",
journal = "Program and Abstracts / ICCCI 2022 : The 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology, Fujiyoshida, Japan, November 15-18, 2022",
title = "Rational design in photoresponsive hierarchical nanomaterials processing",
url = "https://hdl.handle.net/21.15107/rcub_dais_13646"
}
Milošević, O., Rabanal, M. E., Mančić, L.,& Milošević, M. V.. (2022). Rational design in photoresponsive hierarchical nanomaterials processing. in Program and Abstracts / ICCCI 2022 : The 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology, Fujiyoshida, Japan, November 15-18, 2022
Kyoto : The Society of Powder Technology..
https://hdl.handle.net/21.15107/rcub_dais_13646
Milošević O, Rabanal ME, Mančić L, Milošević MV. Rational design in photoresponsive hierarchical nanomaterials processing. in Program and Abstracts / ICCCI 2022 : The 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology, Fujiyoshida, Japan, November 15-18, 2022. 2022;.
https://hdl.handle.net/21.15107/rcub_dais_13646 .
Milošević, Olivera, Rabanal, Maria Eugenia, Mančić, Lidija, Milošević, Milica V., "Rational design in photoresponsive hierarchical nanomaterials processing" in Program and Abstracts / ICCCI 2022 : The 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology, Fujiyoshida, Japan, November 15-18, 2022 (2022),
https://hdl.handle.net/21.15107/rcub_dais_13646 .

Scanning and Transmission Electron Microscopy Investigation of SrGd2O4: Yb,Tm Up-conversion Luminescent Material

Stamenković, Tijana; Dinić, Ivana; Vuković, Marina; Rajić, Vladimir B.; Radmilović, Nadežda; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Rajić, Vladimir B.
AU  - Radmilović, Nadežda
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/14275
AB  - In recent decades, inorganic luminescent materials have gathered significant attention due to their great potential for various applications [1-4]. The rare-earth (RE)-based UC luminescent materials are particularly interesting for their exceptional optical, electronic, and magnetic properties. These materials have distinct intra-4f electronic transitions and existence of plenty long-living electronic excited states at different energies, all of which makes electron promotion to high-energy states possible [5, 6]. RE-based UC luminescent materials are composed of a host material (matrix), a sensitizer (absorbs the IC radiation), and an activator (provides emission in the visible and UV part of the spectrum) [7]. So far, the best results have been gained by co-doping the matrix using Yb3+ as sensitizer and Er3+, Ho3+, Tm3+, etc. as activators [8-10]. As for the hosts, rare-earth oxides (ARE2O4; A = Ca, Sr, Ba and RE = trivalent rare-earth ions) have great perspective for producing highly efficient luminescent materials. To the best of our knowledge, SrGd2O4 has been poorly investigated so far, although it has an enormous potential for variety of applications since it is environmentally friendly, has high thermal stability and good chemical durability [11]. In this work, we will present new UC luminescent material composed of SrGd2O4 (host) doped with Yb3+ (sensitizer) and Tm3+ (activator). Control of particle morphology has attracted a great deal of attention from researchers, so efforts for finding appropriate synthesis method are still very current issue. The morphology of the obtained particles is mostly influenced by the synthesis methods used for preparing the material. Luminescent properties mainly interested for us, are in very close connection with the morphology. Here, samples were synthesized using glycine-assisted combustion method, with constant concentration of Tm3+ (1 at%) and different concentration of Yb3+ (2, 4, 6 at%). All samples were heated in the furnace at 500 °C for 1.5h and then thermally treated for 2.5 h at 1000 °C. X-ray diffraction (XRD) was used to see phase crystallinity and purity, and revealed that all peaks are assigned to the pure orthorhombic lattice of SrGd2O4 with space group Pnma (JCPDS Card No.:01-072-6387). Luminescent properties were investigated after recording UC luminescence spectra at room temperature under 980 nm excitation for all samples. The spectra revealed strong blue emission bands which originates from Tm3+ ions 1D2 → 3F4 and 1G4 → 3H6 and weak red emission 1G4 → 3F4 transitions. Morphology and structure were thoroughly studied by field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), whilst energy dispersive spectroscopy (EDS) was used to provide additional information about constituting elements and their distribution. FE-SEM analysis revealed irregular spherical-like morphology with all samples, and particle size of around 100 nm. TEM examination showed nanostructures organized as a group of agglomerated nanoparticles. EDS verified uniform distribution of all composing elements through every sample [12].
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
T1  - Scanning and Transmission Electron Microscopy Investigation of SrGd2O4: Yb,Tm Up-conversion Luminescent Material
SP  - 192
EP  - 193
UR  - https://hdl.handle.net/21.15107/rcub_dais_14275
ER  - 
@conference{
author = "Stamenković, Tijana and Dinić, Ivana and Vuković, Marina and Rajić, Vladimir B. and Radmilović, Nadežda and Mančić, Lidija and Lojpur, Vesna",
year = "2022",
abstract = "In recent decades, inorganic luminescent materials have gathered significant attention due to their great potential for various applications [1-4]. The rare-earth (RE)-based UC luminescent materials are particularly interesting for their exceptional optical, electronic, and magnetic properties. These materials have distinct intra-4f electronic transitions and existence of plenty long-living electronic excited states at different energies, all of which makes electron promotion to high-energy states possible [5, 6]. RE-based UC luminescent materials are composed of a host material (matrix), a sensitizer (absorbs the IC radiation), and an activator (provides emission in the visible and UV part of the spectrum) [7]. So far, the best results have been gained by co-doping the matrix using Yb3+ as sensitizer and Er3+, Ho3+, Tm3+, etc. as activators [8-10]. As for the hosts, rare-earth oxides (ARE2O4; A = Ca, Sr, Ba and RE = trivalent rare-earth ions) have great perspective for producing highly efficient luminescent materials. To the best of our knowledge, SrGd2O4 has been poorly investigated so far, although it has an enormous potential for variety of applications since it is environmentally friendly, has high thermal stability and good chemical durability [11]. In this work, we will present new UC luminescent material composed of SrGd2O4 (host) doped with Yb3+ (sensitizer) and Tm3+ (activator). Control of particle morphology has attracted a great deal of attention from researchers, so efforts for finding appropriate synthesis method are still very current issue. The morphology of the obtained particles is mostly influenced by the synthesis methods used for preparing the material. Luminescent properties mainly interested for us, are in very close connection with the morphology. Here, samples were synthesized using glycine-assisted combustion method, with constant concentration of Tm3+ (1 at%) and different concentration of Yb3+ (2, 4, 6 at%). All samples were heated in the furnace at 500 °C for 1.5h and then thermally treated for 2.5 h at 1000 °C. X-ray diffraction (XRD) was used to see phase crystallinity and purity, and revealed that all peaks are assigned to the pure orthorhombic lattice of SrGd2O4 with space group Pnma (JCPDS Card No.:01-072-6387). Luminescent properties were investigated after recording UC luminescence spectra at room temperature under 980 nm excitation for all samples. The spectra revealed strong blue emission bands which originates from Tm3+ ions 1D2 → 3F4 and 1G4 → 3H6 and weak red emission 1G4 → 3F4 transitions. Morphology and structure were thoroughly studied by field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), whilst energy dispersive spectroscopy (EDS) was used to provide additional information about constituting elements and their distribution. FE-SEM analysis revealed irregular spherical-like morphology with all samples, and particle size of around 100 nm. TEM examination showed nanostructures organized as a group of agglomerated nanoparticles. EDS verified uniform distribution of all composing elements through every sample [12].",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022",
title = "Scanning and Transmission Electron Microscopy Investigation of SrGd2O4: Yb,Tm Up-conversion Luminescent Material",
pages = "192-193",
url = "https://hdl.handle.net/21.15107/rcub_dais_14275"
}
Stamenković, T., Dinić, I., Vuković, M., Rajić, V. B., Radmilović, N., Mančić, L.,& Lojpur, V.. (2022). Scanning and Transmission Electron Microscopy Investigation of SrGd2O4: Yb,Tm Up-conversion Luminescent Material. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
Belgrade : Serbian Academy of Sciences and Arts., 192-193.
https://hdl.handle.net/21.15107/rcub_dais_14275
Stamenković T, Dinić I, Vuković M, Rajić VB, Radmilović N, Mančić L, Lojpur V. Scanning and Transmission Electron Microscopy Investigation of SrGd2O4: Yb,Tm Up-conversion Luminescent Material. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022. 2022;:192-193.
https://hdl.handle.net/21.15107/rcub_dais_14275 .
Stamenković, Tijana, Dinić, Ivana, Vuković, Marina, Rajić, Vladimir B., Radmilović, Nadežda, Mančić, Lidija, Lojpur, Vesna, "Scanning and Transmission Electron Microscopy Investigation of SrGd2O4: Yb,Tm Up-conversion Luminescent Material" in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022 (2022):192-193,
https://hdl.handle.net/21.15107/rcub_dais_14275 .

Different Up-conversion Oxides Co-doped with Er3+/Yb3+ Synthesized at High Temperatures

Radmilović, Nadežda; Stamenković, Tijana; Lojpur, Vesna; Dinić, Ivana; Mančić, Lidija

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Radmilović, Nadežda
AU  - Stamenković, Tijana
AU  - Lojpur, Vesna
AU  - Dinić, Ivana
AU  - Mančić, Lidija
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/14276
AB  - The process where long-wavelength excitation radiation is converted into shorter wavelength output radiation is known as photon upconversion (UC). Research of up conversion materials is mainly focused on chloride, bromide, fluoride and oxide compounds doped with Pr3+, Nd3+, Dy3+, Ho3+, Er3+ and Yb3+ as activators [1]. Activators are incorporated in the form of rear earth elements (REE) at a proper position in the host lattice. The unique emission mechanism of REE is associated with the incompletely filled 4f shell which enables large numbers of sharp intra-4f electronic transitions and the existence of abundant, long-living electronic excited states. Oxides possess relatively low phonon energy, high thermal stability and admirable intrinsic luminescence properties compared to chlorides and fluorides as host crystal lattice [2,3]. Various host latticed and dopant metal ions have been implemented for obtaining new UC compounds and in our work we studied Ln2MoO6 (Ln=Y,Gd) and Sr2Gd2O4 doped with various concentrations of Yb3+ at constant Er3+ concentration. Synthesized powders were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and luminescence emission and excitation spectroscopy. XRD analyses showed that SrGd2O4 single phase is obtained at 1100 °C, Gd2MoO6 phase starts to form at 750 °C and the pure phase is obtained at 900 °C, while Y2MoO6 was obtained at the lowest temperature of 600 °C. TEM analyses gave insight into particle size - powders obtained at lowest temperatures (Y2MoO6) have the smallest particle size in the range of ~10 nm (Figure 1a), while SrGd2O4 exhibited grain sizes in 150-200 nm range (Figure 1b). The EDS mapping confirmed presence of Yb3+, uniformly distributed in host lattice. Photoluminescence spectra of SrGd2O4 showed emission peaks that can be assigned to the trivalent Er3+ f-f electronic transitions in the following way: two green emission bands at 523 and 551 nm while the red emission band at 661 nm. Continual intensification of UC with the increase of Yb3+ content indicates that the SrGd2O4 host matrix easily accommodates high dopant concentration without quenching. Photoluminescence properties showed that co-doped Y2MoO6 has double emitting luminescence with green emission band at 546 and 560 nm (2H11/2, 4S3/2 → 4I15/2) and red emission band at 655 nm (4F9/2 → 4I15/2); Gd2MoO6 showed double emitting luminescence with two green emission bands at 525 and 546 nm as well as a red emission band at 657 nm. The green UC emission intensity increased gradually with the increment of Yb3+ ion concentration. In comparison, the optimal doping concentration for the red UC emission was found to be 2.5 at %, which was much higher than that of the green UC emission. While the change of Yb3+ ion concentration does not influence the band position, it led to the change of the emission intensity. Increase of Yb3+ concentration in the host lattice leads to change of the green to red ratio, showing the ability for fine-tuning of the color output. Therefore, these materials can be used in lasers and devices for optical communications because of the infrared-to-visible light conversion.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
T1  - Different Up-conversion Oxides Co-doped with Er3+/Yb3+ Synthesized at High Temperatures
SP  - 194
EP  - 195
UR  - https://hdl.handle.net/21.15107/rcub_dais_14276
ER  - 
@conference{
author = "Radmilović, Nadežda and Stamenković, Tijana and Lojpur, Vesna and Dinić, Ivana and Mančić, Lidija",
year = "2022",
abstract = "The process where long-wavelength excitation radiation is converted into shorter wavelength output radiation is known as photon upconversion (UC). Research of up conversion materials is mainly focused on chloride, bromide, fluoride and oxide compounds doped with Pr3+, Nd3+, Dy3+, Ho3+, Er3+ and Yb3+ as activators [1]. Activators are incorporated in the form of rear earth elements (REE) at a proper position in the host lattice. The unique emission mechanism of REE is associated with the incompletely filled 4f shell which enables large numbers of sharp intra-4f electronic transitions and the existence of abundant, long-living electronic excited states. Oxides possess relatively low phonon energy, high thermal stability and admirable intrinsic luminescence properties compared to chlorides and fluorides as host crystal lattice [2,3]. Various host latticed and dopant metal ions have been implemented for obtaining new UC compounds and in our work we studied Ln2MoO6 (Ln=Y,Gd) and Sr2Gd2O4 doped with various concentrations of Yb3+ at constant Er3+ concentration. Synthesized powders were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and luminescence emission and excitation spectroscopy. XRD analyses showed that SrGd2O4 single phase is obtained at 1100 °C, Gd2MoO6 phase starts to form at 750 °C and the pure phase is obtained at 900 °C, while Y2MoO6 was obtained at the lowest temperature of 600 °C. TEM analyses gave insight into particle size - powders obtained at lowest temperatures (Y2MoO6) have the smallest particle size in the range of ~10 nm (Figure 1a), while SrGd2O4 exhibited grain sizes in 150-200 nm range (Figure 1b). The EDS mapping confirmed presence of Yb3+, uniformly distributed in host lattice. Photoluminescence spectra of SrGd2O4 showed emission peaks that can be assigned to the trivalent Er3+ f-f electronic transitions in the following way: two green emission bands at 523 and 551 nm while the red emission band at 661 nm. Continual intensification of UC with the increase of Yb3+ content indicates that the SrGd2O4 host matrix easily accommodates high dopant concentration without quenching. Photoluminescence properties showed that co-doped Y2MoO6 has double emitting luminescence with green emission band at 546 and 560 nm (2H11/2, 4S3/2 → 4I15/2) and red emission band at 655 nm (4F9/2 → 4I15/2); Gd2MoO6 showed double emitting luminescence with two green emission bands at 525 and 546 nm as well as a red emission band at 657 nm. The green UC emission intensity increased gradually with the increment of Yb3+ ion concentration. In comparison, the optimal doping concentration for the red UC emission was found to be 2.5 at %, which was much higher than that of the green UC emission. While the change of Yb3+ ion concentration does not influence the band position, it led to the change of the emission intensity. Increase of Yb3+ concentration in the host lattice leads to change of the green to red ratio, showing the ability for fine-tuning of the color output. Therefore, these materials can be used in lasers and devices for optical communications because of the infrared-to-visible light conversion.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022",
title = "Different Up-conversion Oxides Co-doped with Er3+/Yb3+ Synthesized at High Temperatures",
pages = "194-195",
url = "https://hdl.handle.net/21.15107/rcub_dais_14276"
}
Radmilović, N., Stamenković, T., Lojpur, V., Dinić, I.,& Mančić, L.. (2022). Different Up-conversion Oxides Co-doped with Er3+/Yb3+ Synthesized at High Temperatures. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
Belgrade : Serbian Academy of Sciences and Arts., 194-195.
https://hdl.handle.net/21.15107/rcub_dais_14276
Radmilović N, Stamenković T, Lojpur V, Dinić I, Mančić L. Different Up-conversion Oxides Co-doped with Er3+/Yb3+ Synthesized at High Temperatures. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022. 2022;:194-195.
https://hdl.handle.net/21.15107/rcub_dais_14276 .
Radmilović, Nadežda, Stamenković, Tijana, Lojpur, Vesna, Dinić, Ivana, Mančić, Lidija, "Different Up-conversion Oxides Co-doped with Er3+/Yb3+ Synthesized at High Temperatures" in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022 (2022):194-195,
https://hdl.handle.net/21.15107/rcub_dais_14276 .

Pathway to tailor the phase composition, microstructure and mechanical properties of pulsed laser deposited cobalt-substituted calcium phosphate coatings on titanium

Marković, Smilja; Rau, Julietta V.; De Bonis, Angela; De Bellis, Giovanni; Stojanović, Zoran; Veselinović, Ljiljana; Mitrić, Miodrag; Ignjatović, Nenad; Škapin, Srečo Davor; Vengust, Damjan

(2022)

TY  - JOUR
AU  - Marković, Smilja
AU  - Rau, Julietta V.
AU  - De Bonis, Angela
AU  - De Bellis, Giovanni
AU  - Stojanović, Zoran
AU  - Veselinović, Ljiljana
AU  - Mitrić, Miodrag
AU  - Ignjatović, Nenad
AU  - Škapin, Srečo Davor
AU  - Vengust, Damjan
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13034
AB  - Dense calcium phosphate-based ceramics were fabricated to be used as targets for pulsed laser deposition (PLD). Nanostructured cobalt-substituted hydroxyapatite (Co:HAP) was used as a starting powder. To vary phase composition and microstructure of targets, two sintering approaches were applied, conventional (CS) and two-step sintering (TSS). The obtained results show that in both cases biphasic calcium phosphate (BCP) ceramics (targets) were prepared, with slightly different HAP-to-β–TCP amount ratio and a significantly different microstructure. While the CS method yielded fully dense ceramics with an average grain size of 1.3 μm, the ceramics prepared by TSS had a density of 98.5%, with a predominant grain size below 100 nm. (Ca + Co)P coatings were prepared by PLD of (Ca + Co)P targets. The temperature of the Ti substrate was adjusted to be 25 and 500 °C. The results show that the phase composition of (Ca + Co)P coatings depended on the phase composition of targets as well as on the temperature of the Ti substrate. The coating prepared at 25 °C using CS target consisted of three calcium phosphate phases, HAP, β–TCP and α–TCP; when the TSS target was used, the coating was biphasic, containing HAP and β–TCP. When the substrate was heated to 500 °C, regardless of whether the CS or the TSS target was used, the deposited coatings were composed of HAP and α–TCP. Due to different phase compositions, the (Ca + Co)P coatings deposited at 25 °C showed an improved hardness compared to those deposited at 500 °C. The obtained results confirmed that the phase composition, morphology and mechanical properties of 0.3 μm thick (Ca + Co)P coatings on a Ti substrate can be tailored by employing (Ca + Co)P targets with different microstructures, and also by varying the temperature of the Ti substrate during deposition experiments.
T2  - Surface and Coatings Technology
T1  - Pathway to tailor the phase composition, microstructure and mechanical properties of pulsed laser deposited cobalt-substituted calcium phosphate coatings on titanium
SP  - 128275
VL  - 437
DO  - 10.1016/j.surfcoat.2022.128275
UR  - https://hdl.handle.net/21.15107/rcub_dais_13034
ER  - 
@article{
author = "Marković, Smilja and Rau, Julietta V. and De Bonis, Angela and De Bellis, Giovanni and Stojanović, Zoran and Veselinović, Ljiljana and Mitrić, Miodrag and Ignjatović, Nenad and Škapin, Srečo Davor and Vengust, Damjan",
year = "2022",
abstract = "Dense calcium phosphate-based ceramics were fabricated to be used as targets for pulsed laser deposition (PLD). Nanostructured cobalt-substituted hydroxyapatite (Co:HAP) was used as a starting powder. To vary phase composition and microstructure of targets, two sintering approaches were applied, conventional (CS) and two-step sintering (TSS). The obtained results show that in both cases biphasic calcium phosphate (BCP) ceramics (targets) were prepared, with slightly different HAP-to-β–TCP amount ratio and a significantly different microstructure. While the CS method yielded fully dense ceramics with an average grain size of 1.3 μm, the ceramics prepared by TSS had a density of 98.5%, with a predominant grain size below 100 nm. (Ca + Co)P coatings were prepared by PLD of (Ca + Co)P targets. The temperature of the Ti substrate was adjusted to be 25 and 500 °C. The results show that the phase composition of (Ca + Co)P coatings depended on the phase composition of targets as well as on the temperature of the Ti substrate. The coating prepared at 25 °C using CS target consisted of three calcium phosphate phases, HAP, β–TCP and α–TCP; when the TSS target was used, the coating was biphasic, containing HAP and β–TCP. When the substrate was heated to 500 °C, regardless of whether the CS or the TSS target was used, the deposited coatings were composed of HAP and α–TCP. Due to different phase compositions, the (Ca + Co)P coatings deposited at 25 °C showed an improved hardness compared to those deposited at 500 °C. The obtained results confirmed that the phase composition, morphology and mechanical properties of 0.3 μm thick (Ca + Co)P coatings on a Ti substrate can be tailored by employing (Ca + Co)P targets with different microstructures, and also by varying the temperature of the Ti substrate during deposition experiments.",
journal = "Surface and Coatings Technology",
title = "Pathway to tailor the phase composition, microstructure and mechanical properties of pulsed laser deposited cobalt-substituted calcium phosphate coatings on titanium",
pages = "128275",
volume = "437",
doi = "10.1016/j.surfcoat.2022.128275",
url = "https://hdl.handle.net/21.15107/rcub_dais_13034"
}
Marković, S., Rau, J. V., De Bonis, A., De Bellis, G., Stojanović, Z., Veselinović, L., Mitrić, M., Ignjatović, N., Škapin, S. D.,& Vengust, D.. (2022). Pathway to tailor the phase composition, microstructure and mechanical properties of pulsed laser deposited cobalt-substituted calcium phosphate coatings on titanium. in Surface and Coatings Technology, 437, 128275.
https://doi.org/10.1016/j.surfcoat.2022.128275
https://hdl.handle.net/21.15107/rcub_dais_13034
Marković S, Rau JV, De Bonis A, De Bellis G, Stojanović Z, Veselinović L, Mitrić M, Ignjatović N, Škapin SD, Vengust D. Pathway to tailor the phase composition, microstructure and mechanical properties of pulsed laser deposited cobalt-substituted calcium phosphate coatings on titanium. in Surface and Coatings Technology. 2022;437:128275.
doi:10.1016/j.surfcoat.2022.128275
https://hdl.handle.net/21.15107/rcub_dais_13034 .
Marković, Smilja, Rau, Julietta V., De Bonis, Angela, De Bellis, Giovanni, Stojanović, Zoran, Veselinović, Ljiljana, Mitrić, Miodrag, Ignjatović, Nenad, Škapin, Srečo Davor, Vengust, Damjan, "Pathway to tailor the phase composition, microstructure and mechanical properties of pulsed laser deposited cobalt-substituted calcium phosphate coatings on titanium" in Surface and Coatings Technology, 437 (2022):128275,
https://doi.org/10.1016/j.surfcoat.2022.128275 .,
https://hdl.handle.net/21.15107/rcub_dais_13034 .
1
1