United States National Science Foundation (NSF) / Partnerships for Research and Education in Materials (PREM), Grant 1523617

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United States National Science Foundation (NSF) / Partnerships for Research and Education in Materials (PREM), Grant 1523617

Authors

Publications

Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction

Filipović, Suzana; Obradović, Nina; Anđelković, Ljubica; Olćan, Dragan; Petrović, Jovana; Mirković, Miljana; Pavlović, Vladimir B.; Jeremić, Dejan; Vlahović, Branislav; Đorđević, Antonije

(Belgrade : International Institute for the Science of Sintering, 2021)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Mirković, Miljana
AU  - Pavlović, Vladimir B.
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11230
AB  - Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction
SP  - 1
EP  - 8
VL  - 53
DO  - 10.2298/SOS2101001F
UR  - https://hdl.handle.net/21.15107/rcub_dais_11230
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana and Mirković, Miljana and Pavlović, Vladimir B. and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction",
pages = "1-8",
volume = "53",
doi = "10.2298/SOS2101001F",
url = "https://hdl.handle.net/21.15107/rcub_dais_11230"
}
Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J., Mirković, M., Pavlović, V. B., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 53, 1-8.
https://doi.org/10.2298/SOS2101001F
https://hdl.handle.net/21.15107/rcub_dais_11230
Filipović S, Obradović N, Anđelković L, Olćan D, Petrović J, Mirković M, Pavlović VB, Jeremić D, Vlahović B, Đorđević A. Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering. 2021;53:1-8.
doi:10.2298/SOS2101001F
https://hdl.handle.net/21.15107/rcub_dais_11230 .
Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana, Mirković, Miljana, Pavlović, Vladimir B., Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction" in Science of Sintering, 53 (2021):1-8,
https://doi.org/10.2298/SOS2101001F .,
https://hdl.handle.net/21.15107/rcub_dais_11230 .
2
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PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix

Pavlović, Vera P.; Tošić, Dragana; Dojčilović, Radovan; Dudić, Duško; Dramićanin, Miroslav D.; Medić, Mina; McPherson, Michael M.; Pavlović, Vladimir B.; Vlahović, Branislav; Đoković, Vladimir

(Elsevier BV, 2021)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Tošić, Dragana
AU  - Dojčilović, Radovan
AU  - Dudić, Duško
AU  - Dramićanin, Miroslav D.
AU  - Medić, Mina
AU  - McPherson, Michael M.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
AU  - Đoković, Vladimir
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/10535
AB  - Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar β- and γ-crystals, while there is also a contribution of the non-polar α-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of ~2 kHz, the observed process appears at ~10 °C (about 45° above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from −100 to 100 °C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and ~50 kHz.
PB  - Elsevier BV
T2  - Polymer Testing
T1  - PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix
SP  - 107093
VL  - 96
DO  - 10.1016/j.polymertesting.2021.107093
UR  - https://hdl.handle.net/21.15107/rcub_dais_10535
ER  - 
@article{
author = "Pavlović, Vera P. and Tošić, Dragana and Dojčilović, Radovan and Dudić, Duško and Dramićanin, Miroslav D. and Medić, Mina and McPherson, Michael M. and Pavlović, Vladimir B. and Vlahović, Branislav and Đoković, Vladimir",
year = "2021",
abstract = "Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar β- and γ-crystals, while there is also a contribution of the non-polar α-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of ~2 kHz, the observed process appears at ~10 °C (about 45° above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from −100 to 100 °C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and ~50 kHz.",
publisher = "Elsevier BV",
journal = "Polymer Testing",
title = "PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix",
pages = "107093",
volume = "96",
doi = "10.1016/j.polymertesting.2021.107093",
url = "https://hdl.handle.net/21.15107/rcub_dais_10535"
}
Pavlović, V. P., Tošić, D., Dojčilović, R., Dudić, D., Dramićanin, M. D., Medić, M., McPherson, M. M., Pavlović, V. B., Vlahović, B.,& Đoković, V.. (2021). PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix. in Polymer Testing
Elsevier BV., 96, 107093.
https://doi.org/10.1016/j.polymertesting.2021.107093
https://hdl.handle.net/21.15107/rcub_dais_10535
Pavlović VP, Tošić D, Dojčilović R, Dudić D, Dramićanin MD, Medić M, McPherson MM, Pavlović VB, Vlahović B, Đoković V. PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix. in Polymer Testing. 2021;96:107093.
doi:10.1016/j.polymertesting.2021.107093
https://hdl.handle.net/21.15107/rcub_dais_10535 .
Pavlović, Vera P., Tošić, Dragana, Dojčilović, Radovan, Dudić, Duško, Dramićanin, Miroslav D., Medić, Mina, McPherson, Michael M., Pavlović, Vladimir B., Vlahović, Branislav, Đoković, Vladimir, "PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix" in Polymer Testing, 96 (2021):107093,
https://doi.org/10.1016/j.polymertesting.2021.107093 .,
https://hdl.handle.net/21.15107/rcub_dais_10535 .
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Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering

Obradović, Nina; Pavlović, Vera P.; Kachlik, Martin; Maca, Karel; Olćan, Dragan; Đorđević, Antonije; Tshantshapanyan, Ani; Vlahović, Branislav; Pavlović, Vladimir B.

(Taylor and Francis, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Pavlović, Vera P.
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Tshantshapanyan, Ani
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/4557
AB  - Sintering of pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with the addition of 5 mass % TeO2 was studied. Green bodies were prepared from powder mixtures mechanically activated in a high-energy planetary mill, shaped by uniaxial (20 MPa) and cold isostatic pressing (1000 MPa). The pressure-less sintering of these specimens was performed at 1350°C for 1 h. High relative density over 95% of the theoretical value was obtained through solid-state reaction and pressure-less sintering of powder activated for 40 min, and for the first time reported in the literature. Phase composition and microstructures of sintered samples were determined by XRD and SEM, coupled with EDS mapping. The real part of the complex relative permittivity of the samples was measured at 200 MHz. The loss tangent of all samples was below the resolution of the measurement setup. A strong correlation between the relative permittivity and the density agrees with previously published data.
PB  - Taylor and Francis
T2  - Advances in Applied Ceramics
T1  - Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering
SP  - 241
EP  - 248
VL  - 118
IS  - 5
DO  - 10.1080/17436753.2018.1548150
UR  - https://hdl.handle.net/21.15107/rcub_dais_4557
ER  - 
@article{
author = "Obradović, Nina and Pavlović, Vera P. and Kachlik, Martin and Maca, Karel and Olćan, Dragan and Đorđević, Antonije and Tshantshapanyan, Ani and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Sintering of pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with the addition of 5 mass % TeO2 was studied. Green bodies were prepared from powder mixtures mechanically activated in a high-energy planetary mill, shaped by uniaxial (20 MPa) and cold isostatic pressing (1000 MPa). The pressure-less sintering of these specimens was performed at 1350°C for 1 h. High relative density over 95% of the theoretical value was obtained through solid-state reaction and pressure-less sintering of powder activated for 40 min, and for the first time reported in the literature. Phase composition and microstructures of sintered samples were determined by XRD and SEM, coupled with EDS mapping. The real part of the complex relative permittivity of the samples was measured at 200 MHz. The loss tangent of all samples was below the resolution of the measurement setup. A strong correlation between the relative permittivity and the density agrees with previously published data.",
publisher = "Taylor and Francis",
journal = "Advances in Applied Ceramics",
title = "Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering",
pages = "241-248",
volume = "118",
number = "5",
doi = "10.1080/17436753.2018.1548150",
url = "https://hdl.handle.net/21.15107/rcub_dais_4557"
}
Obradović, N., Pavlović, V. P., Kachlik, M., Maca, K., Olćan, D., Đorđević, A., Tshantshapanyan, A., Vlahović, B.,& Pavlović, V. B.. (2019). Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering. in Advances in Applied Ceramics
Taylor and Francis., 118(5), 241-248.
https://doi.org/10.1080/17436753.2018.1548150
https://hdl.handle.net/21.15107/rcub_dais_4557
Obradović N, Pavlović VP, Kachlik M, Maca K, Olćan D, Đorđević A, Tshantshapanyan A, Vlahović B, Pavlović VB. Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering. in Advances in Applied Ceramics. 2019;118(5):241-248.
doi:10.1080/17436753.2018.1548150
https://hdl.handle.net/21.15107/rcub_dais_4557 .
Obradović, Nina, Pavlović, Vera P., Kachlik, Martin, Maca, Karel, Olćan, Dragan, Đorđević, Antonije, Tshantshapanyan, Ani, Vlahović, Branislav, Pavlović, Vladimir B., "Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering" in Advances in Applied Ceramics, 118, no. 5 (2019):241-248,
https://doi.org/10.1080/17436753.2018.1548150 .,
https://hdl.handle.net/21.15107/rcub_dais_4557 .
10
5
11

Structure and enhanced antimicrobial activity of mechanically activated nano TiO2

Pavlović, Vera P.; Vujančević, Jelena; Mašković, Pavle; Ćirković, Jovana; Papan, Jelena M.; Kosanović, Darko; Dramićanin, Miroslav; Petrović, Predrag B.; Vlahović, Branislav; Pavlović, Vladimir B.

(Wiley, 2019)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Mašković, Pavle
AU  - Ćirković, Jovana
AU  - Papan, Jelena M.
AU  - Kosanović, Darko
AU  - Dramićanin, Miroslav
AU  - Petrović, Predrag B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/jace.16668
UR  - https://dais.sanu.ac.rs/123456789/6454
AB  - Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.
PB  - Wiley
T2  - Journal of the American Ceramic Society
T1  - Structure and enhanced antimicrobial activity of mechanically activated nano TiO2
SP  - 7735
EP  - 7745
VL  - 102
IS  - 12
DO  - 10.1111/jace.16668
UR  - https://hdl.handle.net/21.15107/rcub_dais_6454
ER  - 
@article{
author = "Pavlović, Vera P. and Vujančević, Jelena and Mašković, Pavle and Ćirković, Jovana and Papan, Jelena M. and Kosanović, Darko and Dramićanin, Miroslav and Petrović, Predrag B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.",
publisher = "Wiley",
journal = "Journal of the American Ceramic Society",
title = "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2",
pages = "7735-7745",
volume = "102",
number = "12",
doi = "10.1111/jace.16668",
url = "https://hdl.handle.net/21.15107/rcub_dais_6454"
}
Pavlović, V. P., Vujančević, J., Mašković, P., Ćirković, J., Papan, J. M., Kosanović, D., Dramićanin, M., Petrović, P. B., Vlahović, B.,& Pavlović, V. B.. (2019). Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society
Wiley., 102(12), 7735-7745.
https://doi.org/10.1111/jace.16668
https://hdl.handle.net/21.15107/rcub_dais_6454
Pavlović VP, Vujančević J, Mašković P, Ćirković J, Papan JM, Kosanović D, Dramićanin M, Petrović PB, Vlahović B, Pavlović VB. Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society. 2019;102(12):7735-7745.
doi:10.1111/jace.16668
https://hdl.handle.net/21.15107/rcub_dais_6454 .
Pavlović, Vera P., Vujančević, Jelena, Mašković, Pavle, Ćirković, Jovana, Papan, Jelena M., Kosanović, Darko, Dramićanin, Miroslav, Petrović, Predrag B., Vlahović, Branislav, Pavlović, Vladimir B., "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2" in Journal of the American Ceramic Society, 102, no. 12 (2019):7735-7745,
https://doi.org/10.1111/jace.16668 .,
https://hdl.handle.net/21.15107/rcub_dais_6454 .
12
4
11

Structure and enhanced antimicrobial activity of mechanically activated nano TiO2

Pavlović, Vera P.; Vujančević, Jelena; Mašković, Pavle; Ćirković, Jovana; Papan, Jelena M.; Kosanović, Darko; Dramićanin, Miroslav; Petrović, Predrag B.; Vlahović, Branislav; Pavlović, Vladimir B.

(Wiley, 2019)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Mašković, Pavle
AU  - Ćirković, Jovana
AU  - Papan, Jelena M.
AU  - Kosanović, Darko
AU  - Dramićanin, Miroslav
AU  - Petrović, Predrag B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/jace.16668
UR  - https://dais.sanu.ac.rs/123456789/6453
AB  - Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.
PB  - Wiley
T2  - Journal of the American Ceramic Society
T1  - Structure and enhanced antimicrobial activity of mechanically activated nano TiO2
SP  - 7735
EP  - 7745
VL  - 102
IS  - 12
DO  - 10.1111/jace.16668
UR  - https://hdl.handle.net/21.15107/rcub_dais_6453
ER  - 
@article{
author = "Pavlović, Vera P. and Vujančević, Jelena and Mašković, Pavle and Ćirković, Jovana and Papan, Jelena M. and Kosanović, Darko and Dramićanin, Miroslav and Petrović, Predrag B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.",
publisher = "Wiley",
journal = "Journal of the American Ceramic Society",
title = "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2",
pages = "7735-7745",
volume = "102",
number = "12",
doi = "10.1111/jace.16668",
url = "https://hdl.handle.net/21.15107/rcub_dais_6453"
}
Pavlović, V. P., Vujančević, J., Mašković, P., Ćirković, J., Papan, J. M., Kosanović, D., Dramićanin, M., Petrović, P. B., Vlahović, B.,& Pavlović, V. B.. (2019). Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society
Wiley., 102(12), 7735-7745.
https://doi.org/10.1111/jace.16668
https://hdl.handle.net/21.15107/rcub_dais_6453
Pavlović VP, Vujančević J, Mašković P, Ćirković J, Papan JM, Kosanović D, Dramićanin M, Petrović PB, Vlahović B, Pavlović VB. Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society. 2019;102(12):7735-7745.
doi:10.1111/jace.16668
https://hdl.handle.net/21.15107/rcub_dais_6453 .
Pavlović, Vera P., Vujančević, Jelena, Mašković, Pavle, Ćirković, Jovana, Papan, Jelena M., Kosanović, Darko, Dramićanin, Miroslav, Petrović, Predrag B., Vlahović, Branislav, Pavlović, Vladimir B., "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2" in Journal of the American Ceramic Society, 102, no. 12 (2019):7735-7745,
https://doi.org/10.1111/jace.16668 .,
https://hdl.handle.net/21.15107/rcub_dais_6453 .
12
4
12

Supplementary material for the article: Rusmirović, J.D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A.D., Pavlović, V.B., 2019. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environ Sci Pollut Res 26, 12379–12398. https://doi.org/10.1007/s11356-019-04625-0

Rusmirović, Jelena; Obradović, Nina; Perendija, Jovana; Umićević, Ana; Kapidžić, Ana; Vlahović, Branislav; Pavlović, Vera P.; Marinković, Aleksandar D.; Pavlović, Vladimir B.

(Springer, 2019)

TY  - DATA
AU  - Rusmirović, Jelena
AU  - Obradović, Nina
AU  - Perendija, Jovana
AU  - Umićević, Ana
AU  - Kapidžić, Ana
AU  - Vlahović, Branislav
AU  - Pavlović, Vera P.
AU  - Marinković, Aleksandar D.
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/5805
AB  - Effect of pH on Cd2+ and Ni2+ ions removal by W-MG and W-γ-APS/MG; Adsorption/desorption study of Cd2+, Ni2+, HCrO4-/CrO42- and H2PO4-/HPO42-
on WL/MG and WL-γ-APS/MG adsorbents; 9
Adsorption kinetic study
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Supplementary material for the article: Rusmirović, J.D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A.D., Pavlović, V.B., 2019. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environ Sci Pollut Res 26, 12379–12398. https://doi.org/10.1007/s11356-019-04625-0
UR  - https://hdl.handle.net/21.15107/rcub_dais_5805
ER  - 
@misc{
author = "Rusmirović, Jelena and Obradović, Nina and Perendija, Jovana and Umićević, Ana and Kapidžić, Ana and Vlahović, Branislav and Pavlović, Vera P. and Marinković, Aleksandar D. and Pavlović, Vladimir B.",
year = "2019",
abstract = "Effect of pH on Cd2+ and Ni2+ ions removal by W-MG and W-γ-APS/MG; Adsorption/desorption study of Cd2+, Ni2+, HCrO4-/CrO42- and H2PO4-/HPO42-
on WL/MG and WL-γ-APS/MG adsorbents; 9
Adsorption kinetic study",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Supplementary material for the article: Rusmirović, J.D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A.D., Pavlović, V.B., 2019. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environ Sci Pollut Res 26, 12379–12398. https://doi.org/10.1007/s11356-019-04625-0",
url = "https://hdl.handle.net/21.15107/rcub_dais_5805"
}
Rusmirović, J., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V. P., Marinković, A. D.,& Pavlović, V. B.. (2019). Supplementary material for the article: Rusmirović, J.D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A.D., Pavlović, V.B., 2019. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environ Sci Pollut Res 26, 12379–12398. https://doi.org/10.1007/s11356-019-04625-0. in Environmental Science and Pollution Research
Springer..
https://hdl.handle.net/21.15107/rcub_dais_5805
Rusmirović J, Obradović N, Perendija J, Umićević A, Kapidžić A, Vlahović B, Pavlović VP, Marinković AD, Pavlović VB. Supplementary material for the article: Rusmirović, J.D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A.D., Pavlović, V.B., 2019. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environ Sci Pollut Res 26, 12379–12398. https://doi.org/10.1007/s11356-019-04625-0. in Environmental Science and Pollution Research. 2019;.
https://hdl.handle.net/21.15107/rcub_dais_5805 .
Rusmirović, Jelena, Obradović, Nina, Perendija, Jovana, Umićević, Ana, Kapidžić, Ana, Vlahović, Branislav, Pavlović, Vera P., Marinković, Aleksandar D., Pavlović, Vladimir B., "Supplementary material for the article: Rusmirović, J.D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A.D., Pavlović, V.B., 2019. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environ Sci Pollut Res 26, 12379–12398. https://doi.org/10.1007/s11356-019-04625-0" in Environmental Science and Pollution Research (2019),
https://hdl.handle.net/21.15107/rcub_dais_5805 .

Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal

Rusmirović, Jelena; Obradović, Nina; Perendija, Jovana; Umićević, Ana; Kapidžić, Ana; Vlahović, Branislav; Pavlović, Vera P.; Marinković, Aleksandar D.; Pavlović, Vladimir B.

(Springer, 2019)

TY  - JOUR
AU  - Rusmirović, Jelena
AU  - Obradović, Nina
AU  - Perendija, Jovana
AU  - Umićević, Ana
AU  - Kapidžić, Ana
AU  - Vlahović, Branislav
AU  - Pavlović, Vera P.
AU  - Marinković, Aleksandar D.
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/5764
AB  - Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal
SP  - 12379
EP  - 12398
VL  - 26
IS  - 12
DO  - 10.1007/s11356-019-04625-0
UR  - https://hdl.handle.net/21.15107/rcub_dais_5764
ER  - 
@article{
author = "Rusmirović, Jelena and Obradović, Nina and Perendija, Jovana and Umićević, Ana and Kapidžić, Ana and Vlahović, Branislav and Pavlović, Vera P. and Marinković, Aleksandar D. and Pavlović, Vladimir B.",
year = "2019",
abstract = "Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal",
pages = "12379-12398",
volume = "26",
number = "12",
doi = "10.1007/s11356-019-04625-0",
url = "https://hdl.handle.net/21.15107/rcub_dais_5764"
}
Rusmirović, J., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V. P., Marinković, A. D.,& Pavlović, V. B.. (2019). Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research
Springer., 26(12), 12379-12398.
https://doi.org/10.1007/s11356-019-04625-0
https://hdl.handle.net/21.15107/rcub_dais_5764
Rusmirović J, Obradović N, Perendija J, Umićević A, Kapidžić A, Vlahović B, Pavlović VP, Marinković AD, Pavlović VB. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research. 2019;26(12):12379-12398.
doi:10.1007/s11356-019-04625-0
https://hdl.handle.net/21.15107/rcub_dais_5764 .
Rusmirović, Jelena, Obradović, Nina, Perendija, Jovana, Umićević, Ana, Kapidžić, Ana, Vlahović, Branislav, Pavlović, Vera P., Marinković, Aleksandar D., Pavlović, Vladimir B., "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal" in Environmental Science and Pollution Research, 26, no. 12 (2019):12379-12398,
https://doi.org/10.1007/s11356-019-04625-0 .,
https://hdl.handle.net/21.15107/rcub_dais_5764 .
1
11
6
13

Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal

Rusmirović, Jelena; Obradović, Nina; Perendija, Jovana; Umićević, Ana; Kapidžić, Ana; Vlahović, Branislav; Pavlović, Vera; Marinković, Aleksandar D.; Pavlović, Vladimir B.

(Springer, 2019)

TY  - JOUR
AU  - Rusmirović, Jelena
AU  - Obradović, Nina
AU  - Perendija, Jovana
AU  - Umićević, Ana
AU  - Kapidžić, Ana
AU  - Vlahović, Branislav
AU  - Pavlović, Vera
AU  - Marinković, Aleksandar D.
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/5273
AB  - Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal
SP  - 12379
EP  - 12398
VL  - 26
IS  - 12
DO  - 10.1007/s11356-019-04625-0
UR  - https://hdl.handle.net/21.15107/rcub_dais_5273
ER  - 
@article{
author = "Rusmirović, Jelena and Obradović, Nina and Perendija, Jovana and Umićević, Ana and Kapidžić, Ana and Vlahović, Branislav and Pavlović, Vera and Marinković, Aleksandar D. and Pavlović, Vladimir B.",
year = "2019",
abstract = "Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal",
pages = "12379-12398",
volume = "26",
number = "12",
doi = "10.1007/s11356-019-04625-0",
url = "https://hdl.handle.net/21.15107/rcub_dais_5273"
}
Rusmirović, J., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A. D.,& Pavlović, V. B.. (2019). Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research
Springer., 26(12), 12379-12398.
https://doi.org/10.1007/s11356-019-04625-0
https://hdl.handle.net/21.15107/rcub_dais_5273
Rusmirović J, Obradović N, Perendija J, Umićević A, Kapidžić A, Vlahović B, Pavlović V, Marinković AD, Pavlović VB. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research. 2019;26(12):12379-12398.
doi:10.1007/s11356-019-04625-0
https://hdl.handle.net/21.15107/rcub_dais_5273 .
Rusmirović, Jelena, Obradović, Nina, Perendija, Jovana, Umićević, Ana, Kapidžić, Ana, Vlahović, Branislav, Pavlović, Vera, Marinković, Aleksandar D., Pavlović, Vladimir B., "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal" in Environmental Science and Pollution Research, 26, no. 12 (2019):12379-12398,
https://doi.org/10.1007/s11356-019-04625-0 .,
https://hdl.handle.net/21.15107/rcub_dais_5273 .
1
11
6
13

Synthesis and characterization of BaTiO3/α-Fe2O3 core/shell structure

Filipović, Suzana; Pavlović, Vera P.; Mitrić, Miodrag; Lević, Steva; Mitrović, Nebojša; Maričić, Aleksa; Vlahović, Branislav; Pavlović, Vladimir B.

(Springer, 2019)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Pavlović, Vera P.
AU  - Mitrić, Miodrag
AU  - Lević, Steva
AU  - Mitrović, Nebojša
AU  - Maričić, Aleksa
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://doi.org/10.1007/s40145-018-0301-5
UR  - https://dais.sanu.ac.rs/123456789/5271
AB  - Multiferroic materials attracted a lot of attention in recent years because of their significant scientific interest and technological applications. The multiferroic core/shell powders have a better connectivity between the phases, resulting in superior dielectric and magneto electric properties. In this study, the influence of preparation condition on structure and properties of BaTiO3/α-Fe2O3 core/shell composite materials was examined. The five samples were obtained by varying synthesis conditions, such as synthesized method (co-precipitation and sonochemical method) and pH values of solution. XRD and Raman spectroscopy analyses were performed in order to determine phase composition and structural changes within samples. Morphology modifications were examined by SEM and EDS analyses. Finally, effect of structural and microstructural changes on magnetic and electrical properties was detected and explained.
PB  - Springer
T2  - Journal of Advanced Ceramics
T1  - Synthesis and characterization of BaTiO3/α-Fe2O3 core/shell structure
SP  - 133
EP  - 147
VL  - 8
IS  - 1
DO  - 10.1007/s40145-018-0301-5
UR  - https://hdl.handle.net/21.15107/rcub_dais_5271
ER  - 
@article{
author = "Filipović, Suzana and Pavlović, Vera P. and Mitrić, Miodrag and Lević, Steva and Mitrović, Nebojša and Maričić, Aleksa and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
abstract = "Multiferroic materials attracted a lot of attention in recent years because of their significant scientific interest and technological applications. The multiferroic core/shell powders have a better connectivity between the phases, resulting in superior dielectric and magneto electric properties. In this study, the influence of preparation condition on structure and properties of BaTiO3/α-Fe2O3 core/shell composite materials was examined. The five samples were obtained by varying synthesis conditions, such as synthesized method (co-precipitation and sonochemical method) and pH values of solution. XRD and Raman spectroscopy analyses were performed in order to determine phase composition and structural changes within samples. Morphology modifications were examined by SEM and EDS analyses. Finally, effect of structural and microstructural changes on magnetic and electrical properties was detected and explained.",
publisher = "Springer",
journal = "Journal of Advanced Ceramics",
title = "Synthesis and characterization of BaTiO3/α-Fe2O3 core/shell structure",
pages = "133-147",
volume = "8",
number = "1",
doi = "10.1007/s40145-018-0301-5",
url = "https://hdl.handle.net/21.15107/rcub_dais_5271"
}
Filipović, S., Pavlović, V. P., Mitrić, M., Lević, S., Mitrović, N., Maričić, A., Vlahović, B.,& Pavlović, V. B.. (2019). Synthesis and characterization of BaTiO3/α-Fe2O3 core/shell structure. in Journal of Advanced Ceramics
Springer., 8(1), 133-147.
https://doi.org/10.1007/s40145-018-0301-5
https://hdl.handle.net/21.15107/rcub_dais_5271
Filipović S, Pavlović VP, Mitrić M, Lević S, Mitrović N, Maričić A, Vlahović B, Pavlović VB. Synthesis and characterization of BaTiO3/α-Fe2O3 core/shell structure. in Journal of Advanced Ceramics. 2019;8(1):133-147.
doi:10.1007/s40145-018-0301-5
https://hdl.handle.net/21.15107/rcub_dais_5271 .
Filipović, Suzana, Pavlović, Vera P., Mitrić, Miodrag, Lević, Steva, Mitrović, Nebojša, Maričić, Aleksa, Vlahović, Branislav, Pavlović, Vladimir B., "Synthesis and characterization of BaTiO3/α-Fe2O3 core/shell structure" in Journal of Advanced Ceramics, 8, no. 1 (2019):133-147,
https://doi.org/10.1007/s40145-018-0301-5 .,
https://hdl.handle.net/21.15107/rcub_dais_5271 .
1
9
9
11

Influence of mechanical activation on functional properties of barium hexaferrite ceramics

Kosanović, Darko; Blagojević, Vladimir A.; Maričić, Aleksa; Aleksić, S.; Pavlović, Vera P.; Pavlović, Vladimir B.; Vlahović, Branislav

(Elsevier, 2018)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maričić, Aleksa
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4606
AB  - Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100–240 min) and sintered at 1100 and 1200 °C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84–89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 °C are superior to those sintered at 1100 °C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350–420 °C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 °C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min. © 2018 Elsevier Ltd and Techna Group S.r.l.
PB  - Elsevier
T2  - Ceramics International
T1  - Influence of mechanical activation on functional properties of barium hexaferrite ceramics
SP  - 6666
EP  - 6672
VL  - 44
IS  - 6
DO  - 10.1016/j.ceramint.2018.01.078
UR  - https://hdl.handle.net/21.15107/rcub_dais_4606
ER  - 
@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maričić, Aleksa and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir B. and Vlahović, Branislav",
year = "2018",
abstract = "Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100–240 min) and sintered at 1100 and 1200 °C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84–89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 °C are superior to those sintered at 1100 °C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350–420 °C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 °C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min. © 2018 Elsevier Ltd and Techna Group S.r.l.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Influence of mechanical activation on functional properties of barium hexaferrite ceramics",
pages = "6666-6672",
volume = "44",
number = "6",
doi = "10.1016/j.ceramint.2018.01.078",
url = "https://hdl.handle.net/21.15107/rcub_dais_4606"
}
Kosanović, D., Blagojević, V. A., Maričić, A., Aleksić, S., Pavlović, V. P., Pavlović, V. B.,& Vlahović, B.. (2018). Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International
Elsevier., 44(6), 6666-6672.
https://doi.org/10.1016/j.ceramint.2018.01.078
https://hdl.handle.net/21.15107/rcub_dais_4606
Kosanović D, Blagojević VA, Maričić A, Aleksić S, Pavlović VP, Pavlović VB, Vlahović B. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International. 2018;44(6):6666-6672.
doi:10.1016/j.ceramint.2018.01.078
https://hdl.handle.net/21.15107/rcub_dais_4606 .
Kosanović, Darko, Blagojević, Vladimir A., Maričić, Aleksa, Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir B., Vlahović, Branislav, "Influence of mechanical activation on functional properties of barium hexaferrite ceramics" in Ceramics International, 44, no. 6 (2018):6666-6672,
https://doi.org/10.1016/j.ceramint.2018.01.078 .,
https://hdl.handle.net/21.15107/rcub_dais_4606 .
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Influence of mechanical activation on functional properties of barium hexaferrite ceramics

Kosanović, Darko; Blagojević, Vladimir A.; Maričić, Aleksa; Aleksić, S.; Pavlović, Vera P.; Pavlović, Vladimir B.; Vlahović, Branislav

(Elsevier, 2018)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maričić, Aleksa
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/3742
AB  - Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100–240 min) and sintered at 1100 and 1200 °C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84–89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 °C are superior to those sintered at 1100 °C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350–420 °C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 °C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min. © 2018 Elsevier Ltd and Techna Group S.r.l.
PB  - Elsevier
T2  - Ceramics International
T1  - Influence of mechanical activation on functional properties of barium hexaferrite ceramics
SP  - 6666
EP  - 6672
VL  - 44
IS  - 6
DO  - 10.1016/j.ceramint.2018.01.078
UR  - https://hdl.handle.net/21.15107/rcub_dais_3742
ER  - 
@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maričić, Aleksa and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir B. and Vlahović, Branislav",
year = "2018",
abstract = "Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100–240 min) and sintered at 1100 and 1200 °C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84–89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 °C are superior to those sintered at 1100 °C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350–420 °C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 °C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min. © 2018 Elsevier Ltd and Techna Group S.r.l.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Influence of mechanical activation on functional properties of barium hexaferrite ceramics",
pages = "6666-6672",
volume = "44",
number = "6",
doi = "10.1016/j.ceramint.2018.01.078",
url = "https://hdl.handle.net/21.15107/rcub_dais_3742"
}
Kosanović, D., Blagojević, V. A., Maričić, A., Aleksić, S., Pavlović, V. P., Pavlović, V. B.,& Vlahović, B.. (2018). Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International
Elsevier., 44(6), 6666-6672.
https://doi.org/10.1016/j.ceramint.2018.01.078
https://hdl.handle.net/21.15107/rcub_dais_3742
Kosanović D, Blagojević VA, Maričić A, Aleksić S, Pavlović VP, Pavlović VB, Vlahović B. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International. 2018;44(6):6666-6672.
doi:10.1016/j.ceramint.2018.01.078
https://hdl.handle.net/21.15107/rcub_dais_3742 .
Kosanović, Darko, Blagojević, Vladimir A., Maričić, Aleksa, Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir B., Vlahović, Branislav, "Influence of mechanical activation on functional properties of barium hexaferrite ceramics" in Ceramics International, 44, no. 6 (2018):6666-6672,
https://doi.org/10.1016/j.ceramint.2018.01.078 .,
https://hdl.handle.net/21.15107/rcub_dais_3742 .
9
8
11

Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement

Kosanović, Darko; Blagojević, Vladimir A.; Maričić, Aleksa; Aleksić, S.; Pavlović, Vera P.; Pavlović, Vladimir B.; Vlahović, Branislav

(2018)

TY  - DATA
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maričić, Aleksa
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
PY  - 2018
UR  - https://ars.els-cdn.com/content/image/1-s2.0-S0272884218300919-mmc1.pdf
UR  - https://dais.sanu.ac.rs/123456789/3788
AB  - Rietveld analysis of XRD patterns of mechanically activated Fe:BaTiO3 powder mixtures sintered at 1200°C
T2  - Ceramics International
T1  - Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement
VL  - 44
IS  - 6
UR  - https://hdl.handle.net/21.15107/rcub_dais_3788
ER  - 
@misc{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maričić, Aleksa and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir B. and Vlahović, Branislav",
year = "2018",
abstract = "Rietveld analysis of XRD patterns of mechanically activated Fe:BaTiO3 powder mixtures sintered at 1200°C",
journal = "Ceramics International",
title = "Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement",
volume = "44",
number = "6",
url = "https://hdl.handle.net/21.15107/rcub_dais_3788"
}
Kosanović, D., Blagojević, V. A., Maričić, A., Aleksić, S., Pavlović, V. P., Pavlović, V. B.,& Vlahović, B.. (2018). Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement. in Ceramics International, 44(6).
https://hdl.handle.net/21.15107/rcub_dais_3788
Kosanović D, Blagojević VA, Maričić A, Aleksić S, Pavlović VP, Pavlović VB, Vlahović B. Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement. in Ceramics International. 2018;44(6).
https://hdl.handle.net/21.15107/rcub_dais_3788 .
Kosanović, Darko, Blagojević, Vladimir A., Maričić, Aleksa, Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir B., Vlahović, Branislav, "Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement" in Ceramics International, 44, no. 6 (2018),
https://hdl.handle.net/21.15107/rcub_dais_3788 .

A high-sensitive current-mode pressure/force detector based on piezoelectric polymer PVDF

Petrović, Predrag B.; Pavlović, Vladimir B.; Vlahović, Branislav; Mijailović, Vladica

(Elsevier, 2018)

TY  - JOUR
AU  - Petrović, Predrag B.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
AU  - Mijailović, Vladica
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/3704
AB  - This paper introduces new electronic sensor circuits based on the usage of a piezoelectric Polyvinylidene fluoride-PVDF pressure detector coupled with a current-mode instrumentation amplifier, Schmitt comparator, and only grounded resistors. Pressure/force is measured in terms of the charge generated by the PVDF element as a result of the direct piezoelectric effect. The experimental test results demonstrated that the dynamic pressure response, the sensitivity and linearity of the designed sensor were higher than the sensitivity and linearity of a traditional piezoelectric sensor. The sensitivity of the PVDF sensor was 0.08 mV/Pa. The detector is calibrated over a frequency range of 1 Hz–1 kHz. The proposed signal conditioning electronics offer a potential for future miniaturization in order to be integrated with different commercial devices, for detecting certain tiny activities including finger movements, robotics and smart electronic devices. © 2018 Elsevier B.V.
PB  - Elsevier
T2  - Sensors and Actuators, A: Physical
T1  - A high-sensitive current-mode pressure/force detector based on piezoelectric polymer PVDF
SP  - 165
EP  - 175
VL  - 276
DO  - 10.1016/j.sna.2018.04.014
UR  - https://hdl.handle.net/21.15107/rcub_dais_3704
ER  - 
@article{
author = "Petrović, Predrag B. and Pavlović, Vladimir B. and Vlahović, Branislav and Mijailović, Vladica",
year = "2018",
abstract = "This paper introduces new electronic sensor circuits based on the usage of a piezoelectric Polyvinylidene fluoride-PVDF pressure detector coupled with a current-mode instrumentation amplifier, Schmitt comparator, and only grounded resistors. Pressure/force is measured in terms of the charge generated by the PVDF element as a result of the direct piezoelectric effect. The experimental test results demonstrated that the dynamic pressure response, the sensitivity and linearity of the designed sensor were higher than the sensitivity and linearity of a traditional piezoelectric sensor. The sensitivity of the PVDF sensor was 0.08 mV/Pa. The detector is calibrated over a frequency range of 1 Hz–1 kHz. The proposed signal conditioning electronics offer a potential for future miniaturization in order to be integrated with different commercial devices, for detecting certain tiny activities including finger movements, robotics and smart electronic devices. © 2018 Elsevier B.V.",
publisher = "Elsevier",
journal = "Sensors and Actuators, A: Physical",
title = "A high-sensitive current-mode pressure/force detector based on piezoelectric polymer PVDF",
pages = "165-175",
volume = "276",
doi = "10.1016/j.sna.2018.04.014",
url = "https://hdl.handle.net/21.15107/rcub_dais_3704"
}
Petrović, P. B., Pavlović, V. B., Vlahović, B.,& Mijailović, V.. (2018). A high-sensitive current-mode pressure/force detector based on piezoelectric polymer PVDF. in Sensors and Actuators, A: Physical
Elsevier., 276, 165-175.
https://doi.org/10.1016/j.sna.2018.04.014
https://hdl.handle.net/21.15107/rcub_dais_3704
Petrović PB, Pavlović VB, Vlahović B, Mijailović V. A high-sensitive current-mode pressure/force detector based on piezoelectric polymer PVDF. in Sensors and Actuators, A: Physical. 2018;276:165-175.
doi:10.1016/j.sna.2018.04.014
https://hdl.handle.net/21.15107/rcub_dais_3704 .
Petrović, Predrag B., Pavlović, Vladimir B., Vlahović, Branislav, Mijailović, Vladica, "A high-sensitive current-mode pressure/force detector based on piezoelectric polymer PVDF" in Sensors and Actuators, A: Physical, 276 (2018):165-175,
https://doi.org/10.1016/j.sna.2018.04.014 .,
https://hdl.handle.net/21.15107/rcub_dais_3704 .
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