Vujančević, Jelena

Link to this page

Authority KeyName Variants
orcid::0000-0002-8038-247X
  • Vujančević, Jelena (56)
  • Vujančević, Jelena D. (3)
Projects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) Directed synthesis, structure and properties of multifunctional materials
Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200053 (University of Belgrade, Institute for Multidisciplinary Research)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Synthesis, processing and applications of nanostructured multifunctional materials with defined properties
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy) Lithium-ion batteries and fuel cells - research and development
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200105 (University of Belgrade, Faculty of Mechanical Engineering) United States National Aeronautics and Space Administration (NASA), Grant NNX09AV07A
United States National Science Foundation (NSF) / Centers of Research Excellence in Science and Technology (CREST), Grant HRD-0833184 CERIC-ERIC (20177018 proposal)
ERC advanced grant “PICOPROP” (Grant No. 670918) Structure Fund Project CZ.02.1.01/0.0/0.0/16_013/0001788
Swiss National Science Foundation (No. 160169) Integration of PAper-based Nucleic acid testing mEthods into Microfluidic devices for improved biosensing Applications
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200156 (University of Novi Sad, Faculty of Technical Science) Innovative electronic components and systems based on inorganic and organic technologies embedded in consumer goods and products
NIMP Core Programme 21 N UEFISCDI, 304/2011
United States National Science Foundation (NSF) / Partnerships for Research and Education in Materials (PREM), Grant 1523617 Bilateral collaboration between Serbia and Slovenia (BI-RS-18-19-026)
CCCDI - UEFISCDI, PN-III-P2-2.1-PED-2019-4642 Core Programme 21N
ERC advanced grant “PICOPROP” (Grant No. 670918). Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture)
National Science Foundation grants HRD-1345219 and DMR-1523617. NCS/CCCDI – UEFISCDI, PN-III-P1-1.1-TE-2019-0688

Author's Bibliography

Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4

Dojčinović, Milena; Vasiljević, Zorka Ž.; Rakočević, Lazar; Pavlović, Vera P.; Ammar-Merah, Souad; Vujančević, Jelena; Nikolić, Maria Vesna

(University of Novi Sad, Faculty of Technology, Novi Sad, Serbia, 2023)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Ž.
AU  - Rakočević, Lazar
AU  - Pavlović, Vera P.
AU  - Ammar-Merah, Souad
AU  - Vujančević, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/16331
AB  - Mixed spinel ferrites MgxNi1-xFe2O4 were synthesized via sol-gel combustion synthesis with citric acid as fuel, followed by calcination at 700 °C for 3 hours. Obtained powders were characterized via X-ray diffraction analysis (XRD), X-ray photoelectron (XPS), FTIR and Raman spectroscopy and FESEM microscopy. Elemental composition was examined via energy dispersive spectroscopy (EDS). Humidity sensing properties were tested by measuring AC impedance in a climactic chamber at 25 °C and in the relative humidity range of 40–90%. Temperature sensing properties were tested by measuring DC resistance at 40% RH in the temperature range 40–90 °C. Synthesized powders were proven to be pure spinel Fd 3m phase with spherical, slightly agglomerated particles. Substitution of Mg with Ni results in structural changes such as a change in inversion parameter and particle agglomeration, which influences sensing properties of the material. Results show that the sensing properties of magnesium ferrite, which is already a well-established NTC sensor, can be improved by incorporating 10% of nickel in the spinel lattice structure. Mg0.9Ni0.1Fe2O4 exhibited higher temperature sensitivity and higher sensitivity towards humidity compared to MgFe2O4, while further substitution of Mg with Ni resulted in the decline of sensing properties, increase in particle size and agglomeration degree.
PB  - University of Novi Sad, Faculty of Technology, Novi Sad, Serbia
C3  - CYSC-2023 : 15th EcerS Conference for Young Scientists in Ceramics, Programme and Book of Abstracts; October 11-14, 2023, Novi Sad, Serbia
T1  - Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4
UR  - https://hdl.handle.net/21.15107/rcub_machinery_7269
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Ž. and Rakočević, Lazar and Pavlović, Vera P. and Ammar-Merah, Souad and Vujančević, Jelena and Nikolić, Maria Vesna",
year = "2023",
abstract = "Mixed spinel ferrites MgxNi1-xFe2O4 were synthesized via sol-gel combustion synthesis with citric acid as fuel, followed by calcination at 700 °C for 3 hours. Obtained powders were characterized via X-ray diffraction analysis (XRD), X-ray photoelectron (XPS), FTIR and Raman spectroscopy and FESEM microscopy. Elemental composition was examined via energy dispersive spectroscopy (EDS). Humidity sensing properties were tested by measuring AC impedance in a climactic chamber at 25 °C and in the relative humidity range of 40–90%. Temperature sensing properties were tested by measuring DC resistance at 40% RH in the temperature range 40–90 °C. Synthesized powders were proven to be pure spinel Fd 3m phase with spherical, slightly agglomerated particles. Substitution of Mg with Ni results in structural changes such as a change in inversion parameter and particle agglomeration, which influences sensing properties of the material. Results show that the sensing properties of magnesium ferrite, which is already a well-established NTC sensor, can be improved by incorporating 10% of nickel in the spinel lattice structure. Mg0.9Ni0.1Fe2O4 exhibited higher temperature sensitivity and higher sensitivity towards humidity compared to MgFe2O4, while further substitution of Mg with Ni resulted in the decline of sensing properties, increase in particle size and agglomeration degree.",
publisher = "University of Novi Sad, Faculty of Technology, Novi Sad, Serbia",
journal = "CYSC-2023 : 15th EcerS Conference for Young Scientists in Ceramics, Programme and Book of Abstracts; October 11-14, 2023, Novi Sad, Serbia",
title = "Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4",
url = "https://hdl.handle.net/21.15107/rcub_machinery_7269"
}
Dojčinović, M., Vasiljević, Z. Ž., Rakočević, L., Pavlović, V. P., Ammar-Merah, S., Vujančević, J.,& Nikolić, M. V.. (2023). Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4. in CYSC-2023 : 15th EcerS Conference for Young Scientists in Ceramics, Programme and Book of Abstracts; October 11-14, 2023, Novi Sad, Serbia
University of Novi Sad, Faculty of Technology, Novi Sad, Serbia..
https://hdl.handle.net/21.15107/rcub_machinery_7269
Dojčinović M, Vasiljević ZŽ, Rakočević L, Pavlović VP, Ammar-Merah S, Vujančević J, Nikolić MV. Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4. in CYSC-2023 : 15th EcerS Conference for Young Scientists in Ceramics, Programme and Book of Abstracts; October 11-14, 2023, Novi Sad, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_machinery_7269 .
Dojčinović, Milena, Vasiljević, Zorka Ž., Rakočević, Lazar, Pavlović, Vera P., Ammar-Merah, Souad, Vujančević, Jelena, Nikolić, Maria Vesna, "Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4" in CYSC-2023 : 15th EcerS Conference for Young Scientists in Ceramics, Programme and Book of Abstracts; October 11-14, 2023, Novi Sad, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_machinery_7269 .

Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal

Vujančević, Jelena; Andričević, Pavao; Đokić, Veljko; Blagojević, Vladimir A.; Pavlović, Vera P.; Ćirković, Jovana; Horváth, Endre; Forró, László; Karoui, Abdennaceur; Pavlović, Vladimir B.; Janaćković, Đorđe

(MDPI, 2023)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Đokić, Veljko
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vera P.
AU  - Ćirković, Jovana
AU  - Horváth, Endre
AU  - Forró, László
AU  - Karoui, Abdennaceur
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14229
AB  - In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.
PB  - MDPI
T2  - Catalysts
T1  - Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal
SP  - 352
VL  - 13
IS  - 2
DO  - 10.3390/catal13020352
UR  - https://hdl.handle.net/21.15107/rcub_dais_14229
ER  - 
@article{
author = "Vujančević, Jelena and Andričević, Pavao and Đokić, Veljko and Blagojević, Vladimir A. and Pavlović, Vera P. and Ćirković, Jovana and Horváth, Endre and Forró, László and Karoui, Abdennaceur and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2023",
abstract = "In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.",
publisher = "MDPI",
journal = "Catalysts",
title = "Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal",
pages = "352",
volume = "13",
number = "2",
doi = "10.3390/catal13020352",
url = "https://hdl.handle.net/21.15107/rcub_dais_14229"
}
Vujančević, J., Andričević, P., Đokić, V., Blagojević, V. A., Pavlović, V. P., Ćirković, J., Horváth, E., Forró, L., Karoui, A., Pavlović, V. B.,& Janaćković, Đ.. (2023). Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal. in Catalysts
MDPI., 13(2), 352.
https://doi.org/10.3390/catal13020352
https://hdl.handle.net/21.15107/rcub_dais_14229
Vujančević J, Andričević P, Đokić V, Blagojević VA, Pavlović VP, Ćirković J, Horváth E, Forró L, Karoui A, Pavlović VB, Janaćković Đ. Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal. in Catalysts. 2023;13(2):352.
doi:10.3390/catal13020352
https://hdl.handle.net/21.15107/rcub_dais_14229 .
Vujančević, Jelena, Andričević, Pavao, Đokić, Veljko, Blagojević, Vladimir A., Pavlović, Vera P., Ćirković, Jovana, Horváth, Endre, Forró, László, Karoui, Abdennaceur, Pavlović, Vladimir B., Janaćković, Đorđe, "Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal" in Catalysts, 13, no. 2 (2023):352,
https://doi.org/10.3390/catal13020352 .,
https://hdl.handle.net/21.15107/rcub_dais_14229 .

Hybrid Nanoscale Materials for Convergent Technologies

Pavlović, Vladimir B.; Vuković, G.; Nikolić, M.; Pavlović, Vera P.; Perić, M.; Nenadović, S.; Ivanović, M.; Mirković, M.; Đoković, V.; Knežević, S.; Šuljagić, Marija; Anđelković, Lj.; Janićijević, Aleksandra; Kovačević, D.; Filipović, Suzana; Vujančević, Jelena; Vlahović, Branislav

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Pavlović, Vladimir B.
AU  - Vuković, G.
AU  - Nikolić, M.
AU  - Pavlović, Vera P.
AU  - Perić, M.
AU  - Nenadović, S.
AU  - Ivanović, M.
AU  - Mirković, M.
AU  - Đoković, V.
AU  - Knežević, S.
AU  - Šuljagić, Marija
AU  - Anđelković, Lj.
AU  - Janićijević, Aleksandra
AU  - Kovačević, D.
AU  - Filipović, Suzana
AU  - Vujančević, Jelena
AU  - Vlahović, Branislav
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15760
AB  - The convergence of nano-, bio-, and information technologies is based on the understanding of complex hierarchical structures and systems, as well as on the material unity at the nanoscale and on technology integration from that scale. A growing interest in these technologies is a result of their potential to provide solutions to numerous societal challenges, such as advanced healthcare, environmental remediation, sustainable development, and adoption of cyber-physical systems based on the Internet of Things and the Internet of Systems. Taking into account that hybrid nanomaterials possess extraordinary physical and chemical properties derived from their size in the nanoscale, the aim of this work is to present the connection between processing parameters and multifunctional properties of nano scale hybrid materials, focusing on the study of ceramic-polymer structures before they can be nano-engineered into functional devices. The unique functionality of these nanostructures has enabled their applications in numerous devices such as: micro and nano-electro-mechanical systems (MEMS/NEMS), sensors, microactuators, surface acoustic wave devices, polymer electrolyte membrane fuel cells, switches, thermistors, resonators and filters, electrooptic devices, etc. In this study special attention has been paid to their applications in the fields of electronics, biotechnology, environmental protection and remediation.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
T1  - Hybrid Nanoscale Materials for Convergent Technologies
SP  - 45
EP  - 45
UR  - https://hdl.handle.net/21.15107/rcub_dais_15760
ER  - 
@conference{
author = "Pavlović, Vladimir B. and Vuković, G. and Nikolić, M. and Pavlović, Vera P. and Perić, M. and Nenadović, S. and Ivanović, M. and Mirković, M. and Đoković, V. and Knežević, S. and Šuljagić, Marija and Anđelković, Lj. and Janićijević, Aleksandra and Kovačević, D. and Filipović, Suzana and Vujančević, Jelena and Vlahović, Branislav",
year = "2023",
abstract = "The convergence of nano-, bio-, and information technologies is based on the understanding of complex hierarchical structures and systems, as well as on the material unity at the nanoscale and on technology integration from that scale. A growing interest in these technologies is a result of their potential to provide solutions to numerous societal challenges, such as advanced healthcare, environmental remediation, sustainable development, and adoption of cyber-physical systems based on the Internet of Things and the Internet of Systems. Taking into account that hybrid nanomaterials possess extraordinary physical and chemical properties derived from their size in the nanoscale, the aim of this work is to present the connection between processing parameters and multifunctional properties of nano scale hybrid materials, focusing on the study of ceramic-polymer structures before they can be nano-engineered into functional devices. The unique functionality of these nanostructures has enabled their applications in numerous devices such as: micro and nano-electro-mechanical systems (MEMS/NEMS), sensors, microactuators, surface acoustic wave devices, polymer electrolyte membrane fuel cells, switches, thermistors, resonators and filters, electrooptic devices, etc. In this study special attention has been paid to their applications in the fields of electronics, biotechnology, environmental protection and remediation.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023",
title = "Hybrid Nanoscale Materials for Convergent Technologies",
pages = "45-45",
url = "https://hdl.handle.net/21.15107/rcub_dais_15760"
}
Pavlović, V. B., Vuković, G., Nikolić, M., Pavlović, V. P., Perić, M., Nenadović, S., Ivanović, M., Mirković, M., Đoković, V., Knežević, S., Šuljagić, M., Anđelković, Lj., Janićijević, A., Kovačević, D., Filipović, S., Vujančević, J.,& Vlahović, B.. (2023). Hybrid Nanoscale Materials for Convergent Technologies. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
Belgrade : Serbian Ceramic Society., 45-45.
https://hdl.handle.net/21.15107/rcub_dais_15760
Pavlović VB, Vuković G, Nikolić M, Pavlović VP, Perić M, Nenadović S, Ivanović M, Mirković M, Đoković V, Knežević S, Šuljagić M, Anđelković L, Janićijević A, Kovačević D, Filipović S, Vujančević J, Vlahović B. Hybrid Nanoscale Materials for Convergent Technologies. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023. 2023;:45-45.
https://hdl.handle.net/21.15107/rcub_dais_15760 .
Pavlović, Vladimir B., Vuković, G., Nikolić, M., Pavlović, Vera P., Perić, M., Nenadović, S., Ivanović, M., Mirković, M., Đoković, V., Knežević, S., Šuljagić, Marija, Anđelković, Lj., Janićijević, Aleksandra, Kovačević, D., Filipović, Suzana, Vujančević, Jelena, Vlahović, Branislav, "Hybrid Nanoscale Materials for Convergent Technologies" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023 (2023):45-45,
https://hdl.handle.net/21.15107/rcub_dais_15760 .

Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites

Dojčinović, Milena P.; Vasiljević, Zorka Ž.; Rakočević, Lazar; Pavlović, Vera P.; Ammar-Merah, Souad; Vujančević, Jelena D.; Nikolić, Maria Vesna

(Basel : MDPI AG, 2023)

TY  - JOUR
AU  - Dojčinović, Milena P.
AU  - Vasiljević, Zorka Ž.
AU  - Rakočević, Lazar
AU  - Pavlović, Vera P.
AU  - Ammar-Merah, Souad
AU  - Vujančević, Jelena D.
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14025
AB  - Temperature- and humidity-sensing properties were evaluated of NixMg1-x spinel ferrites (0 ≤ x ≤ 1) synthesized by a sol-gel combustion method using citric acid as fuel and nitrate ions as oxidizing agents. After the exothermic reaction, amorphous powders were calcined at 700 °C followed by characterization with XRD, FTIR, XPS, EDS and Raman spectroscopy and FESEM microscopy. Synthesized powders were tested as humidity- and temperature-sensing materials in the form of thick films on interdigitated electrodes on alumina substrate in a climatic chamber. The physicochemical investigation of synthesized materials revealed a cubic spinel Fd3¯m phase, nanosized but agglomerated particles with a partially to completely inverse spinel structure with increasing Ni content. Ni0.1Mg0.9Fe2O4 showed the highest material constant (B30,90) value of 3747 K and temperature sensitivity (α) of −4.08%/K compared to pure magnesium ferrite (B30,90 value of 3426 K and α of −3.73%/K) and the highest average sensitivity towards humidity of 922 kΩ/%RH in the relative humidity (RH) range of 40–90% at the working temperature of 25 °C.
PB  - Basel : MDPI AG
T2  - Chemosensors
T1  - Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites
SP  - 34
VL  - 11
IS  - 1
DO  - 10.3390/chemosensors11010034
UR  - https://hdl.handle.net/21.15107/rcub_dais_14025
ER  - 
@article{
author = "Dojčinović, Milena P. and Vasiljević, Zorka Ž. and Rakočević, Lazar and Pavlović, Vera P. and Ammar-Merah, Souad and Vujančević, Jelena D. and Nikolić, Maria Vesna",
year = "2023",
abstract = "Temperature- and humidity-sensing properties were evaluated of NixMg1-x spinel ferrites (0 ≤ x ≤ 1) synthesized by a sol-gel combustion method using citric acid as fuel and nitrate ions as oxidizing agents. After the exothermic reaction, amorphous powders were calcined at 700 °C followed by characterization with XRD, FTIR, XPS, EDS and Raman spectroscopy and FESEM microscopy. Synthesized powders were tested as humidity- and temperature-sensing materials in the form of thick films on interdigitated electrodes on alumina substrate in a climatic chamber. The physicochemical investigation of synthesized materials revealed a cubic spinel Fd3¯m phase, nanosized but agglomerated particles with a partially to completely inverse spinel structure with increasing Ni content. Ni0.1Mg0.9Fe2O4 showed the highest material constant (B30,90) value of 3747 K and temperature sensitivity (α) of −4.08%/K compared to pure magnesium ferrite (B30,90 value of 3426 K and α of −3.73%/K) and the highest average sensitivity towards humidity of 922 kΩ/%RH in the relative humidity (RH) range of 40–90% at the working temperature of 25 °C.",
publisher = "Basel : MDPI AG",
journal = "Chemosensors",
title = "Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites",
pages = "34",
volume = "11",
number = "1",
doi = "10.3390/chemosensors11010034",
url = "https://hdl.handle.net/21.15107/rcub_dais_14025"
}
Dojčinović, M. P., Vasiljević, Z. Ž., Rakočević, L., Pavlović, V. P., Ammar-Merah, S., Vujančević, J. D.,& Nikolić, M. V.. (2023). Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites. in Chemosensors
Basel : MDPI AG., 11(1), 34.
https://doi.org/10.3390/chemosensors11010034
https://hdl.handle.net/21.15107/rcub_dais_14025
Dojčinović MP, Vasiljević ZŽ, Rakočević L, Pavlović VP, Ammar-Merah S, Vujančević JD, Nikolić MV. Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites. in Chemosensors. 2023;11(1):34.
doi:10.3390/chemosensors11010034
https://hdl.handle.net/21.15107/rcub_dais_14025 .
Dojčinović, Milena P., Vasiljević, Zorka Ž., Rakočević, Lazar, Pavlović, Vera P., Ammar-Merah, Souad, Vujančević, Jelena D., Nikolić, Maria Vesna, "Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites" in Chemosensors, 11, no. 1 (2023):34,
https://doi.org/10.3390/chemosensors11010034 .,
https://hdl.handle.net/21.15107/rcub_dais_14025 .
4
3

Electrochemical sensor for detection bisphenols in thermal paper

Vujančević, Jelena; Trafela, Špela; Sodnik, Neža; Samardžija, Zoran; Žagar Soderžnik, Kristina

(Ljubljana : MIDEM - Society for Microelectronics, Electronic Components and Materials, 2023)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Trafela, Špela
AU  - Sodnik, Neža
AU  - Samardžija, Zoran
AU  - Žagar Soderžnik, Kristina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15360
AB  - The substances of very high concern (SVHCs) can be found in a wide range of consumer products. These substances can negatively influence human health depending on the route of exposure, exposure time and duration, amount of intake the substance by body and other factors. Increased number of carcinoma, sterility, diabetes can be due to the contact with SVHCs in our everyday life. Bisphenol A (BPA) is one of the most commercialized SVHC chemicals and is used in many different products such as plastic packaging for water and food, storage media, and even in thermal paper. Thermal paper is used for receipts in stores and tickets for parking, bus, and trains. BPA is applied on thermal paper as a dye developer. As a dye developer, it is not chemically bound to the paper so it can easily migrate and be absorbed by the skin (fingers, palm). Studies showed that typical occupational exposures of work cashiers can increase concentrations of BPA and its metabolites in urine several times. Toxicokinetic studies showed that the route of exposure has a big effect on the concentration of BPA that circulates in the body. If BPA enters the body through dermal exposure, it metabolizes as unconjugated BPA, while oral exposure leads to a conjugated form of BPA. Studies showed that only the unconjugated form can bind to estrogen receptors, leading to the conclusion that the unconjugated form is hazardous. Due to that European Commission restricted usage of BPA to 0.02 mas%. The paper manufacturers replaced BPA with bisphenol S (BPS). It is expected that 61 % of all thermal paper in the EU will be BPS-based till now. However, the wide use of BPS in thermal paper raises concern because it was shown that BPS is also toxic. New studies of urine samples collected around the world showed the presance of BPS. Due to increasing production of BPS there is a need for the development of analytical methods for the detection of SVCHs. The most used are HPLCs with mass spectrometric detection, which are expensive and time-consuming. On a another hand, electrochemical sensors are low-cost and simple method for detection of SVCHs. The present study represents fast, reliable and commercial detection of bisphenols via screen-printed electrodes (SPEs) as receptor elements. Scanning electron microscopy (SEM) was used to study the surface of the SPEs working electrodes. SPE electrodes showed very good electrochemical responses toward BPA and BPS oxidation with linear ranges between 0.5 and 50.0 μM and lower limits of detection of 0.15 μM and 0.37 μM, respectively.
PB  - Ljubljana : MIDEM - Society for Microelectronics, Electronic Components and Materials
C3  - 58th International Conference on Microelectronics, Devices and Materials & The Workshop on Chemical sensors: Materials and Applications : conference 2023 : proceedings : September 27-29, Lipica, Slovenia
T1  - Electrochemical sensor for detection bisphenols in thermal paper
SP  - 91
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_dais_15360
ER  - 
@conference{
author = "Vujančević, Jelena and Trafela, Špela and Sodnik, Neža and Samardžija, Zoran and Žagar Soderžnik, Kristina",
year = "2023",
abstract = "The substances of very high concern (SVHCs) can be found in a wide range of consumer products. These substances can negatively influence human health depending on the route of exposure, exposure time and duration, amount of intake the substance by body and other factors. Increased number of carcinoma, sterility, diabetes can be due to the contact with SVHCs in our everyday life. Bisphenol A (BPA) is one of the most commercialized SVHC chemicals and is used in many different products such as plastic packaging for water and food, storage media, and even in thermal paper. Thermal paper is used for receipts in stores and tickets for parking, bus, and trains. BPA is applied on thermal paper as a dye developer. As a dye developer, it is not chemically bound to the paper so it can easily migrate and be absorbed by the skin (fingers, palm). Studies showed that typical occupational exposures of work cashiers can increase concentrations of BPA and its metabolites in urine several times. Toxicokinetic studies showed that the route of exposure has a big effect on the concentration of BPA that circulates in the body. If BPA enters the body through dermal exposure, it metabolizes as unconjugated BPA, while oral exposure leads to a conjugated form of BPA. Studies showed that only the unconjugated form can bind to estrogen receptors, leading to the conclusion that the unconjugated form is hazardous. Due to that European Commission restricted usage of BPA to 0.02 mas%. The paper manufacturers replaced BPA with bisphenol S (BPS). It is expected that 61 % of all thermal paper in the EU will be BPS-based till now. However, the wide use of BPS in thermal paper raises concern because it was shown that BPS is also toxic. New studies of urine samples collected around the world showed the presance of BPS. Due to increasing production of BPS there is a need for the development of analytical methods for the detection of SVCHs. The most used are HPLCs with mass spectrometric detection, which are expensive and time-consuming. On a another hand, electrochemical sensors are low-cost and simple method for detection of SVCHs. The present study represents fast, reliable and commercial detection of bisphenols via screen-printed electrodes (SPEs) as receptor elements. Scanning electron microscopy (SEM) was used to study the surface of the SPEs working electrodes. SPE electrodes showed very good electrochemical responses toward BPA and BPS oxidation with linear ranges between 0.5 and 50.0 μM and lower limits of detection of 0.15 μM and 0.37 μM, respectively.",
publisher = "Ljubljana : MIDEM - Society for Microelectronics, Electronic Components and Materials",
journal = "58th International Conference on Microelectronics, Devices and Materials & The Workshop on Chemical sensors: Materials and Applications : conference 2023 : proceedings : September 27-29, Lipica, Slovenia",
title = "Electrochemical sensor for detection bisphenols in thermal paper",
pages = "91-92",
url = "https://hdl.handle.net/21.15107/rcub_dais_15360"
}
Vujančević, J., Trafela, Š., Sodnik, N., Samardžija, Z.,& Žagar Soderžnik, K.. (2023). Electrochemical sensor for detection bisphenols in thermal paper. in 58th International Conference on Microelectronics, Devices and Materials & The Workshop on Chemical sensors: Materials and Applications : conference 2023 : proceedings : September 27-29, Lipica, Slovenia
Ljubljana : MIDEM - Society for Microelectronics, Electronic Components and Materials., 91-92.
https://hdl.handle.net/21.15107/rcub_dais_15360
Vujančević J, Trafela Š, Sodnik N, Samardžija Z, Žagar Soderžnik K. Electrochemical sensor for detection bisphenols in thermal paper. in 58th International Conference on Microelectronics, Devices and Materials & The Workshop on Chemical sensors: Materials and Applications : conference 2023 : proceedings : September 27-29, Lipica, Slovenia. 2023;:91-92.
https://hdl.handle.net/21.15107/rcub_dais_15360 .
Vujančević, Jelena, Trafela, Špela, Sodnik, Neža, Samardžija, Zoran, Žagar Soderžnik, Kristina, "Electrochemical sensor for detection bisphenols in thermal paper" in 58th International Conference on Microelectronics, Devices and Materials & The Workshop on Chemical sensors: Materials and Applications : conference 2023 : proceedings : September 27-29, Lipica, Slovenia (2023):91-92,
https://hdl.handle.net/21.15107/rcub_dais_15360 .

Electrochemical sensors for detection of bisphenols

Vujančević, Jelena; Trafela, Špela; Sodnik, Neža; Samardžija, Zoran; Žagar Soderžnik, Kristina

(Belgrade : Association of Metallurgical Engineers of Serbia (AMES), 2023)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Trafela, Špela
AU  - Sodnik, Neža
AU  - Samardžija, Zoran
AU  - Žagar Soderžnik, Kristina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15320
AB  - The endocrine-disrupting chemicals (EDCs) are chemicals of very high concern that have hazards with serious consequences on human health. It influences on development of metabolic disorders, reproduction and respiratory problems. They can be found in our everyday life, from food, and personal care products to medical devices, dental products, special lenses and baby drink cans. Among several EDCs, banned Bisphenol A (BPA) and his substitute Bisphenol S (BPS) have attracted attention due to high usage during the manufacturing process for water and food packaging, in the production of epoxy resins, lacquer coating and can even be found in receipt. Due to that, there is a need for the fast, reliable and commercial detection of Bisphenols in everyday life. The gold standard for the detection of Bisphenols is chromatography and enzyme-linked immunosorbent assay, expensive and robust methods. Electrochemical sensors are a new approach to the detection of EDCs in very small quantities in complex environments. The aim of this research was to study commercial screen-printed electrodes (SPEs) as receptor elements in electrochemical sensors for the detection of BPA and BPS. Scanning electron microscopic (SEM) and Fourier transform infrared spectroscopy (FT-IR) were employed for examining the surface of the SPEs working electrodes. SPE electrodes showed very good voltammetric responses toward BPA and BPS oxidation with linear ranges between 0.5 and 50.0 μM and lower limits of detection of 0.15 μM and 0.37 μM, respectively.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia (AMES)
C3  - MME SEE Congress 2023 : 5th Metallurgical & Materials Engineering Congress of South-East Europe , Trebinje, Bosnia and Herzegovina, 7-10th June 2023 : Book of Abstracts
T1  - Electrochemical sensors for detection of bisphenols
SP  - 32
EP  - 32
UR  - https://hdl.handle.net/21.15107/rcub_dais_15320
ER  - 
@conference{
author = "Vujančević, Jelena and Trafela, Špela and Sodnik, Neža and Samardžija, Zoran and Žagar Soderžnik, Kristina",
year = "2023",
abstract = "The endocrine-disrupting chemicals (EDCs) are chemicals of very high concern that have hazards with serious consequences on human health. It influences on development of metabolic disorders, reproduction and respiratory problems. They can be found in our everyday life, from food, and personal care products to medical devices, dental products, special lenses and baby drink cans. Among several EDCs, banned Bisphenol A (BPA) and his substitute Bisphenol S (BPS) have attracted attention due to high usage during the manufacturing process for water and food packaging, in the production of epoxy resins, lacquer coating and can even be found in receipt. Due to that, there is a need for the fast, reliable and commercial detection of Bisphenols in everyday life. The gold standard for the detection of Bisphenols is chromatography and enzyme-linked immunosorbent assay, expensive and robust methods. Electrochemical sensors are a new approach to the detection of EDCs in very small quantities in complex environments. The aim of this research was to study commercial screen-printed electrodes (SPEs) as receptor elements in electrochemical sensors for the detection of BPA and BPS. Scanning electron microscopic (SEM) and Fourier transform infrared spectroscopy (FT-IR) were employed for examining the surface of the SPEs working electrodes. SPE electrodes showed very good voltammetric responses toward BPA and BPS oxidation with linear ranges between 0.5 and 50.0 μM and lower limits of detection of 0.15 μM and 0.37 μM, respectively.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia (AMES)",
journal = "MME SEE Congress 2023 : 5th Metallurgical & Materials Engineering Congress of South-East Europe , Trebinje, Bosnia and Herzegovina, 7-10th June 2023 : Book of Abstracts",
title = "Electrochemical sensors for detection of bisphenols",
pages = "32-32",
url = "https://hdl.handle.net/21.15107/rcub_dais_15320"
}
Vujančević, J., Trafela, Š., Sodnik, N., Samardžija, Z.,& Žagar Soderžnik, K.. (2023). Electrochemical sensors for detection of bisphenols. in MME SEE Congress 2023 : 5th Metallurgical & Materials Engineering Congress of South-East Europe , Trebinje, Bosnia and Herzegovina, 7-10th June 2023 : Book of Abstracts
Belgrade : Association of Metallurgical Engineers of Serbia (AMES)., 32-32.
https://hdl.handle.net/21.15107/rcub_dais_15320
Vujančević J, Trafela Š, Sodnik N, Samardžija Z, Žagar Soderžnik K. Electrochemical sensors for detection of bisphenols. in MME SEE Congress 2023 : 5th Metallurgical & Materials Engineering Congress of South-East Europe , Trebinje, Bosnia and Herzegovina, 7-10th June 2023 : Book of Abstracts. 2023;:32-32.
https://hdl.handle.net/21.15107/rcub_dais_15320 .
Vujančević, Jelena, Trafela, Špela, Sodnik, Neža, Samardžija, Zoran, Žagar Soderžnik, Kristina, "Electrochemical sensors for detection of bisphenols" in MME SEE Congress 2023 : 5th Metallurgical & Materials Engineering Congress of South-East Europe , Trebinje, Bosnia and Herzegovina, 7-10th June 2023 : Book of Abstracts (2023):32-32,
https://hdl.handle.net/21.15107/rcub_dais_15320 .

Detection of bisphenol S via screen-printed electrodes

Vujančević, Jelena; Trafela, Špela; Sodnik, Neža; Samardžija, Zoran; Žagar Soderžnik, Kristina

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Trafela, Špela
AU  - Sodnik, Neža
AU  - Samardžija, Zoran
AU  - Žagar Soderžnik, Kristina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15321
AB  - Screen-printed electrodes are economical, easy-to-use electrochemical sensors that can be used for in-situ real-time monitoring of toxic substances. This work represents a comparison of two SPEs electrodes for the detection of bisphenol S (BPS). BPS is an endocrine interrupts the hormonal system in humans and shows a genotoxic, cytotoxic and cancerpromoting
effect. Fast and reliable detection of bisphenols is very important.
Chromatographic and spectroscopic techniques are the most used methods for the detection of bisphenols, however they are expensive, complicated and consume a lot of time. On the other hand, electrochemical sensors are promising since they are fast, reliable and simple methods for in-situ measuring. In the present work the detection of BPS was performed via screen-printed electrodes with carbon nanoparticles and carbon single-wall nanotube working electrodes. Determination of BPS was carried out by cyclic voltammetry (CV) anddifferential puls voltammetry (DPV). The influence of different concentrations of BPS, scan rate and influencing BPA on detection were studied. Screen-printed electrodes showed very good electrochemical activity, sensitivity and repeatability. Screen-printed electrodes enable the miniaturization of sensors elements, using smaller volumes of samples, rapid and low cost detection without generating dangerous waste.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
T1  - Detection of bisphenol S via screen-printed electrodes
SP  - 51
EP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_dais_15321
ER  - 
@conference{
author = "Vujančević, Jelena and Trafela, Špela and Sodnik, Neža and Samardžija, Zoran and Žagar Soderžnik, Kristina",
year = "2023",
abstract = "Screen-printed electrodes are economical, easy-to-use electrochemical sensors that can be used for in-situ real-time monitoring of toxic substances. This work represents a comparison of two SPEs electrodes for the detection of bisphenol S (BPS). BPS is an endocrine interrupts the hormonal system in humans and shows a genotoxic, cytotoxic and cancerpromoting
effect. Fast and reliable detection of bisphenols is very important.
Chromatographic and spectroscopic techniques are the most used methods for the detection of bisphenols, however they are expensive, complicated and consume a lot of time. On the other hand, electrochemical sensors are promising since they are fast, reliable and simple methods for in-situ measuring. In the present work the detection of BPS was performed via screen-printed electrodes with carbon nanoparticles and carbon single-wall nanotube working electrodes. Determination of BPS was carried out by cyclic voltammetry (CV) anddifferential puls voltammetry (DPV). The influence of different concentrations of BPS, scan rate and influencing BPA on detection were studied. Screen-printed electrodes showed very good electrochemical activity, sensitivity and repeatability. Screen-printed electrodes enable the miniaturization of sensors elements, using smaller volumes of samples, rapid and low cost detection without generating dangerous waste.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023",
title = "Detection of bisphenol S via screen-printed electrodes",
pages = "51-52",
url = "https://hdl.handle.net/21.15107/rcub_dais_15321"
}
Vujančević, J., Trafela, Š., Sodnik, N., Samardžija, Z.,& Žagar Soderžnik, K.. (2023). Detection of bisphenol S via screen-printed electrodes. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
Belgrade : Serbian Ceramic Society., 51-52.
https://hdl.handle.net/21.15107/rcub_dais_15321
Vujančević J, Trafela Š, Sodnik N, Samardžija Z, Žagar Soderžnik K. Detection of bisphenol S via screen-printed electrodes. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023. 2023;:51-52.
https://hdl.handle.net/21.15107/rcub_dais_15321 .
Vujančević, Jelena, Trafela, Špela, Sodnik, Neža, Samardžija, Zoran, Žagar Soderžnik, Kristina, "Detection of bisphenol S via screen-printed electrodes" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023 (2023):51-52,
https://hdl.handle.net/21.15107/rcub_dais_15321 .

Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5

Vasiljević, Zorka Ž.; Dojčinović, Milena P.; Ilić, Nikola; Vujančević, Jelena; Nikolić, Maria Vesna

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena P.
AU  - Ilić, Nikola
AU  - Vujančević, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14664
AB  - Pure phase orthorhombic pseudobrookite (Fe2TiO5) was synthesized using a modified sol-gel method. Bulk samples were obtained by uniaxial pressing of the obtained powder into compacts sintered at 900 °C for 2 h. A noticeable NTC thermistor effect was noted with a B20/55 value of 5747 K and high resistivity of 45 MΩcm at 25 °C. A non-linear current-voltage characteristic was observed in the voltage range (0.2–1100 V) at room temperature (25 °C). Non-saturated (lossy) P-E loops were obtained at both measured frequencies (100 Hz and 1 kHz) more expressed for the higher measured frequency, with the maximal polarization of 0.291 C/cm2 and remanent polarization of 0.123 °C/cm2 for 20 kV/cm2 and 1 kHz. Complex impedance measured in the temperature range 20–330 °C enabled analysis of the contribution of grain boundary and grains to the conduction mechanism. Bulk conductivity data determined in this temperature range was analyzed using Jonscher’s universal dielectric response model and showed that the conduction process followed the nearest neighbor hopping conduction mechanism.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5
UR  - https://hdl.handle.net/21.15107/rcub_dais_14664
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena P. and Ilić, Nikola and Vujančević, Jelena and Nikolić, Maria Vesna",
year = "2023",
abstract = "Pure phase orthorhombic pseudobrookite (Fe2TiO5) was synthesized using a modified sol-gel method. Bulk samples were obtained by uniaxial pressing of the obtained powder into compacts sintered at 900 °C for 2 h. A noticeable NTC thermistor effect was noted with a B20/55 value of 5747 K and high resistivity of 45 MΩcm at 25 °C. A non-linear current-voltage characteristic was observed in the voltage range (0.2–1100 V) at room temperature (25 °C). Non-saturated (lossy) P-E loops were obtained at both measured frequencies (100 Hz and 1 kHz) more expressed for the higher measured frequency, with the maximal polarization of 0.291 C/cm2 and remanent polarization of 0.123 °C/cm2 for 20 kV/cm2 and 1 kHz. Complex impedance measured in the temperature range 20–330 °C enabled analysis of the contribution of grain boundary and grains to the conduction mechanism. Bulk conductivity data determined in this temperature range was analyzed using Jonscher’s universal dielectric response model and showed that the conduction process followed the nearest neighbor hopping conduction mechanism.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5",
url = "https://hdl.handle.net/21.15107/rcub_dais_14664"
}
Vasiljević, Z. Ž., Dojčinović, M. P., Ilić, N., Vujančević, J.,& Nikolić, M. V.. (2023). Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14664
Vasiljević ZŽ, Dojčinović MP, Ilić N, Vujančević J, Nikolić MV. Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14664 .
Vasiljević, Zorka Ž., Dojčinović, Milena P., Ilić, Nikola, Vujančević, Jelena, Nikolić, Maria Vesna, "Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14664 .

TiO2 nanotubes film/FTO glass interface: Thermal treatment effects

Vujančević, Jelena; Bjelajac, Anđelika; Veltruska, Katerina; Matolin, Vladimir; Siketić, Zdravko; Provatas, Georgios; Jakšić, Milko; Stan, George; Socol, Gabriel; Mihailescu, Ion; Pavlović, Vladimir B.; Janaćkovic, Đorđe

(ETRAN, 2022)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Bjelajac, Anđelika
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketić, Zdravko
AU  - Provatas, Georgios
AU  - Jakšić, Milko
AU  - Stan, George
AU  - Socol, Gabriel
AU  - Mihailescu, Ion
AU  - Pavlović, Vladimir B.
AU  - Janaćkovic, Đorđe
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13160
AB  - Pure Ti films deposited by radio-frequency magnetron sputtering on FTO glass were anodized to fabricate TiO2 nanotubes (NTs) arrays. The TiO2 NTs/FTO samples were sintered at 450, 550 and 630°C, in ambient air. The thermal treatment did not influence the crystal phase composition, preserving in all cases the anatase single phase. As expected, the crystalline anatase quality improved with the annealing temperature. Nevertheless, slight differences in nanotubular morphology, such as the appearance of grains inside the walls, were observed in the case of the sample sintered at 630°C. Chemical analysis by X-ray Photoelectron Spectroscopy of annealed samples revealed the presence of Sn inside TiO2 NTs, due to diffusion of Sn from the substrate to TiO2. For the substrate was used FTO glass whose top layer consists of SnO2 doped with F. Rutherford Backscattering Spectrometry and Time-of-Flight Elastic Recoil Detection Analysis were carried out to study the elemental depth profile of the films. It was found that the temperature of sintering controls the Sn diffusion inside TiO2 film. Sn atoms diffuse towards the TiO2 NTs surface for the samples annealed at 450 and 550°C. The diffusion is however hindered in the case of the heat treatment at 630°C. Besides, the Ti diffusion into the SnO2 underlayer was observed, together with the formation of TiO2/SnO2 interfaces. One then expected but not a great difference in absorption between samples, since all contained anatase phase, as confirmed by Diffuse Reflectance Spectroscopy. A higher amount of Sn was however detected for the sample annealed at 550°C, which accounts for a slight red absorption shift. The importance of controlling the annealing parameters of the anodized TiO2/FTO structures was highlighted through the formation of TiO2-SnO2 interfaces and the Sn insertion from FTO, which can play an essential role in increasing the photoperformances of TiO2 NTs/FTO based structures of photovoltaic cells.
PB  - ETRAN
T2  - Science of Sintering
T1  - TiO2 nanotubes film/FTO glass interface: Thermal treatment effects
SP  - 235
EP  - 248
VL  - 54
IS  - 2
DO  - 10.2298/SOS2202235V
UR  - https://hdl.handle.net/21.15107/rcub_dais_13160
ER  - 
@article{
author = "Vujančević, Jelena and Bjelajac, Anđelika and Veltruska, Katerina and Matolin, Vladimir and Siketić, Zdravko and Provatas, Georgios and Jakšić, Milko and Stan, George and Socol, Gabriel and Mihailescu, Ion and Pavlović, Vladimir B. and Janaćkovic, Đorđe",
year = "2022",
abstract = "Pure Ti films deposited by radio-frequency magnetron sputtering on FTO glass were anodized to fabricate TiO2 nanotubes (NTs) arrays. The TiO2 NTs/FTO samples were sintered at 450, 550 and 630°C, in ambient air. The thermal treatment did not influence the crystal phase composition, preserving in all cases the anatase single phase. As expected, the crystalline anatase quality improved with the annealing temperature. Nevertheless, slight differences in nanotubular morphology, such as the appearance of grains inside the walls, were observed in the case of the sample sintered at 630°C. Chemical analysis by X-ray Photoelectron Spectroscopy of annealed samples revealed the presence of Sn inside TiO2 NTs, due to diffusion of Sn from the substrate to TiO2. For the substrate was used FTO glass whose top layer consists of SnO2 doped with F. Rutherford Backscattering Spectrometry and Time-of-Flight Elastic Recoil Detection Analysis were carried out to study the elemental depth profile of the films. It was found that the temperature of sintering controls the Sn diffusion inside TiO2 film. Sn atoms diffuse towards the TiO2 NTs surface for the samples annealed at 450 and 550°C. The diffusion is however hindered in the case of the heat treatment at 630°C. Besides, the Ti diffusion into the SnO2 underlayer was observed, together with the formation of TiO2/SnO2 interfaces. One then expected but not a great difference in absorption between samples, since all contained anatase phase, as confirmed by Diffuse Reflectance Spectroscopy. A higher amount of Sn was however detected for the sample annealed at 550°C, which accounts for a slight red absorption shift. The importance of controlling the annealing parameters of the anodized TiO2/FTO structures was highlighted through the formation of TiO2-SnO2 interfaces and the Sn insertion from FTO, which can play an essential role in increasing the photoperformances of TiO2 NTs/FTO based structures of photovoltaic cells.",
publisher = "ETRAN",
journal = "Science of Sintering",
title = "TiO2 nanotubes film/FTO glass interface: Thermal treatment effects",
pages = "235-248",
volume = "54",
number = "2",
doi = "10.2298/SOS2202235V",
url = "https://hdl.handle.net/21.15107/rcub_dais_13160"
}
Vujančević, J., Bjelajac, A., Veltruska, K., Matolin, V., Siketić, Z., Provatas, G., Jakšić, M., Stan, G., Socol, G., Mihailescu, I., Pavlović, V. B.,& Janaćkovic, Đ.. (2022). TiO2 nanotubes film/FTO glass interface: Thermal treatment effects. in Science of Sintering
ETRAN., 54(2), 235-248.
https://doi.org/10.2298/SOS2202235V
https://hdl.handle.net/21.15107/rcub_dais_13160
Vujančević J, Bjelajac A, Veltruska K, Matolin V, Siketić Z, Provatas G, Jakšić M, Stan G, Socol G, Mihailescu I, Pavlović VB, Janaćkovic Đ. TiO2 nanotubes film/FTO glass interface: Thermal treatment effects. in Science of Sintering. 2022;54(2):235-248.
doi:10.2298/SOS2202235V
https://hdl.handle.net/21.15107/rcub_dais_13160 .
Vujančević, Jelena, Bjelajac, Anđelika, Veltruska, Katerina, Matolin, Vladimir, Siketić, Zdravko, Provatas, Georgios, Jakšić, Milko, Stan, George, Socol, Gabriel, Mihailescu, Ion, Pavlović, Vladimir B., Janaćkovic, Đorđe, "TiO2 nanotubes film/FTO glass interface: Thermal treatment effects" in Science of Sintering, 54, no. 2 (2022):235-248,
https://doi.org/10.2298/SOS2202235V .,
https://hdl.handle.net/21.15107/rcub_dais_13160 .

Photocatalytic activity of N-TiO2 nanotubes decorated with CdS QD

Vujančević, Jelena; Bjelajac, Anđelika; Horváth, Endre; Forró, Laszlo; Pavlović, Vladimir B.; Janaćković, Đorđe

(Belgrade : Materials Research Society of Serbia, 2022)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Bjelajac, Anđelika
AU  - Horváth, Endre
AU  - Forró, Laszlo
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13597
AB  - The negative consequences of the modern world are environmental pollution. To decrease it, a lot of research is focused on finding solution for its remediation. Photoactive materials have ability to utilize solar energy for the degradation of organic and inorganic pollutants. Among different photoactive material TiO2 has advantages due to its non-toxicity, chemical stability and corrosion resistance. The aim of this study was to investigate the synergetic effect of nitrogen incorporation into crystal structure of TiO2 and deposition of CdS onto amelioration of the photocatalytic degradation of methylen orange compared to the pristine TiO2. For that purpose TiO2 nanotubes were obtained by anodization of titanium foil in HF containing electrolyte. To achieve crystal structure and at the same time to introduce nitrogen in TiO2, the samples were annealed in ammonia atmosphere at 450 °C, for different time of annealing. The highest amount of nitrogen was achieved for the shortest time of annealing (30 min). Beside that, it was observed that the highest level of interstitial nitrogen was also achieved for the shortest time of annealing. Further, CdS quantum dots (QDs) were deposited on the nitrogen doped TiO2 nanotubes via an ex-situ method (using binding reagent). According to the FESEM micrographs, a partial agglomeration of CdS QDs on some domaines on top of the nanotubes was observed. By performing the DRS, the improvement of the optical response after nitrogen doping and deposition of CdS was demonstrated. The sample with the highest amount of total nitrogen and interstitial nitrogen in combination with deposition CdS QDs exhibited the highest photocatalytic efficiency.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
T1  - Photocatalytic activity of N-TiO2 nanotubes decorated with CdS QD
SP  - 140
EP  - 140
UR  - https://hdl.handle.net/21.15107/rcub_dais_13597
ER  - 
@conference{
author = "Vujančević, Jelena and Bjelajac, Anđelika and Horváth, Endre and Forró, Laszlo and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2022",
abstract = "The negative consequences of the modern world are environmental pollution. To decrease it, a lot of research is focused on finding solution for its remediation. Photoactive materials have ability to utilize solar energy for the degradation of organic and inorganic pollutants. Among different photoactive material TiO2 has advantages due to its non-toxicity, chemical stability and corrosion resistance. The aim of this study was to investigate the synergetic effect of nitrogen incorporation into crystal structure of TiO2 and deposition of CdS onto amelioration of the photocatalytic degradation of methylen orange compared to the pristine TiO2. For that purpose TiO2 nanotubes were obtained by anodization of titanium foil in HF containing electrolyte. To achieve crystal structure and at the same time to introduce nitrogen in TiO2, the samples were annealed in ammonia atmosphere at 450 °C, for different time of annealing. The highest amount of nitrogen was achieved for the shortest time of annealing (30 min). Beside that, it was observed that the highest level of interstitial nitrogen was also achieved for the shortest time of annealing. Further, CdS quantum dots (QDs) were deposited on the nitrogen doped TiO2 nanotubes via an ex-situ method (using binding reagent). According to the FESEM micrographs, a partial agglomeration of CdS QDs on some domaines on top of the nanotubes was observed. By performing the DRS, the improvement of the optical response after nitrogen doping and deposition of CdS was demonstrated. The sample with the highest amount of total nitrogen and interstitial nitrogen in combination with deposition CdS QDs exhibited the highest photocatalytic efficiency.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022",
title = "Photocatalytic activity of N-TiO2 nanotubes decorated with CdS QD",
pages = "140-140",
url = "https://hdl.handle.net/21.15107/rcub_dais_13597"
}
Vujančević, J., Bjelajac, A., Horváth, E., Forró, L., Pavlović, V. B.,& Janaćković, Đ.. (2022). Photocatalytic activity of N-TiO2 nanotubes decorated with CdS QD. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
Belgrade : Materials Research Society of Serbia., 140-140.
https://hdl.handle.net/21.15107/rcub_dais_13597
Vujančević J, Bjelajac A, Horváth E, Forró L, Pavlović VB, Janaćković Đ. Photocatalytic activity of N-TiO2 nanotubes decorated with CdS QD. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022. 2022;:140-140.
https://hdl.handle.net/21.15107/rcub_dais_13597 .
Vujančević, Jelena, Bjelajac, Anđelika, Horváth, Endre, Forró, Laszlo, Pavlović, Vladimir B., Janaćković, Đorđe, "Photocatalytic activity of N-TiO2 nanotubes decorated with CdS QD" in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022 (2022):140-140,
https://hdl.handle.net/21.15107/rcub_dais_13597 .

Characteristic of photodiode based on vanadium oxide-TiO2 nanotubes/CH3NH3PbI3

Vujančević, Jelena; Blagojević, Vladimir A.; Andričević, Pavao; Pavlović, Vera P.; Horváth, Endre; Forró, László; Vlahović, Branislav; Pavlović, Vladimir B.; Janaćković, Đorđe

(Belgrade : Serbian Ceramic Society, 2022)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Blagojević, Vladimir A.
AU  - Andričević, Pavao
AU  - Pavlović, Vera P.
AU  - Horváth, Endre
AU  - Forró, László
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13627
AB  - The aim of this study was to investigate the influence of the deposition of vanadium oxide epitaxial layer on the photoresponse of TiO2/CH3NH3PbI3 heterojunction. TiO2 nanotube array was synthesized via anodization of titanium foil at three different voltages. After annealing at 450 °C, vanadium oxide was deposited by direct deposition from vanadyl(IV) sulfate solution. Microstructure analysis has been used for the investigation of the influence of different voltages of anodization on tube diameter. Spectroscopy measurements pointed out the red shift in diffusion reflectance spectra after deposition of vanadium oxide. The presence of V5+ oxidation state has been detected on the surface of nanotube arrays by chemical analysis. CH3NH3PbI3 monocrystal was dry pressed on top of the nanotubes in order to make a photodiode. The current-voltage characteristics of the photodiode were recorded and it was observed that the sample with the smallest wall thickness and higher amount of vanadium has the best photocurrent response.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
T1  - Characteristic of photodiode based on vanadium oxide-TiO2 nanotubes/CH3NH3PbI3
SP  - 90
EP  - 90
UR  - https://hdl.handle.net/21.15107/rcub_dais_13627
ER  - 
@conference{
author = "Vujančević, Jelena and Blagojević, Vladimir A. and Andričević, Pavao and Pavlović, Vera P. and Horváth, Endre and Forró, László and Vlahović, Branislav and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2022",
abstract = "The aim of this study was to investigate the influence of the deposition of vanadium oxide epitaxial layer on the photoresponse of TiO2/CH3NH3PbI3 heterojunction. TiO2 nanotube array was synthesized via anodization of titanium foil at three different voltages. After annealing at 450 °C, vanadium oxide was deposited by direct deposition from vanadyl(IV) sulfate solution. Microstructure analysis has been used for the investigation of the influence of different voltages of anodization on tube diameter. Spectroscopy measurements pointed out the red shift in diffusion reflectance spectra after deposition of vanadium oxide. The presence of V5+ oxidation state has been detected on the surface of nanotube arrays by chemical analysis. CH3NH3PbI3 monocrystal was dry pressed on top of the nanotubes in order to make a photodiode. The current-voltage characteristics of the photodiode were recorded and it was observed that the sample with the smallest wall thickness and higher amount of vanadium has the best photocurrent response.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.",
title = "Characteristic of photodiode based on vanadium oxide-TiO2 nanotubes/CH3NH3PbI3",
pages = "90-90",
url = "https://hdl.handle.net/21.15107/rcub_dais_13627"
}
Vujančević, J., Blagojević, V. A., Andričević, P., Pavlović, V. P., Horváth, E., Forró, L., Vlahović, B., Pavlović, V. B.,& Janaćković, Đ.. (2022). Characteristic of photodiode based on vanadium oxide-TiO2 nanotubes/CH3NH3PbI3. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
Belgrade : Serbian Ceramic Society., 90-90.
https://hdl.handle.net/21.15107/rcub_dais_13627
Vujančević J, Blagojević VA, Andričević P, Pavlović VP, Horváth E, Forró L, Vlahović B, Pavlović VB, Janaćković Đ. Characteristic of photodiode based on vanadium oxide-TiO2 nanotubes/CH3NH3PbI3. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.. 2022;:90-90.
https://hdl.handle.net/21.15107/rcub_dais_13627 .
Vujančević, Jelena, Blagojević, Vladimir A., Andričević, Pavao, Pavlović, Vera P., Horváth, Endre, Forró, László, Vlahović, Branislav, Pavlović, Vladimir B., Janaćković, Đorđe, "Characteristic of photodiode based on vanadium oxide-TiO2 nanotubes/CH3NH3PbI3" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022. (2022):90-90,
https://hdl.handle.net/21.15107/rcub_dais_13627 .

Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora

Stefanović, Milica P.; Vujančević, Jelena; Petrović, Rada P.; Stevanović, Marija S.; Janaćković, Đorđe

(Savez inženjera i tehničara Srbije, 2022)

TY  - JOUR
AU  - Stefanović, Milica P.
AU  - Vujančević, Jelena
AU  - Petrović, Rada P.
AU  - Stevanović, Marija S.
AU  - Janaćković, Đorđe
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/14853
AB  - Organsko-neorganski perovskiti su privukli veliku pažnju istraživača zbog visoke apsorpcije u vidljivomdelu spektra i jeftine proizvodnje. Apsorbovanjem svetlosti dolazi do stvaranja para elektron-šupljina.U cilju razdvajanja nosilaca naelektrisanja, perovskit se kombinuje sa TiO2 što ima za posledicuspontani prelazak elektrona sa perovskita na TiO2. Ovo istraživanje je imalo za cilj povećanje dodirnepovršine između nanocevi TiO2 i perovskita punjenjem nanocevi perovskitnim materijalom. Rastvormetilamonijum olovo(II)-bromidnog perovskita (CH3NH3PbBr3) u dimetilformamidu (DMF) jedeponovan na anodizacijom sintetisane TiO2 nanocevi pomoću sistema visokog vakuuma i inertnoggasa. Postupak je uključivao degazaciju uzorka u visokom vakuumu u trajanju od 3 h na 200 °C, hlađenjeuzorka, a zatim nanošenje rastvora CH3NH3PbBr3 u DMF-u, uz naknadni tretman inertnim gasom (N2)u cilju ostvarenja natpritiska, što je omogućilo punjenje nanocevi perovskitnim materijalom. Difuznorefleksiona spektroskopija pokazala je da taloženje CH3NH3PbBr3 poboljšava apsorpciona svojstvaTiO2 nanocevi. I-V karakteristike uzorka pokazale su fotodiodno ponašanje i histerezisnu krivu, koja jekarakteristična za perovskitni materijal. Vrednost struje uzorka snimljenim pod vidljivom svetlošćuiznosila je 46 μA bez primene prednapona, dok je nakon primene prednapona iznosila 76 μA. Rezultatirada ukazuju da je napravljena perovskitna fotodioda sa povećanim kontaktom između TiO2 i perovskita,koja predstavlja osnovu za buduću konstrukciju solarnih ćelija.
AB  - Organic-inorganic perovskites have attracted much attention from researchers due to their high absorption in the visible part of the spectrum and low-cost fabrication. After absorption of the light, electron-hole pairs are formed. To separate electron-hole pairs and reduce recombination, perovskite is combined with TiO2 which has as a consequence, a spontaneous transition of electrons from perovskite to TiO2. This research aims to increase the contact surface of perovskite and TiO2 nanotubes by filling the nanotubes with perovskite material. The solution of methylammonium lead bromide perovskite (CH3NH3PbBr3) in dimethylformamide (DMF) was deposited on anodically synthesized TiO2 nanotubes by the high vacuum system and inert gas. The procedure involved degassation of the sample under high vacuum for 3 h at 200 °C, cooling of the sample, and putting the solution of CH3NH3PbBr3 in DMF, after which it was treated with inert gas (N2), as an overpressure which enabled the filling of the nanotubes with perovskite material. The diffuse reflectance spectroscopy measurement of the sample proved that deposition of CH3NH3PbBr3 improves the absorption properties of TiO2 nanotubes. The I-V characteristics of the sample showed photodiode behavior and characteristic hysteresis curve for perovskite material. The value of current under visible light for the sample without preconditioning was 46 mA, while after preconditioning value of current was 76 mA. The results indicate that a perovskite photodiode with increased contact between TiO2 and perovskite was made, which is the basis for future solar cell construction.
PB  - Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora
T1  - Improvement of absorption properties of TiO2 nanotubes by using CH3NH3PbBr3 perovskite as photosensitizer
SP  - 15
EP  - 21
VL  - 31
IS  - 1
DO  - 10.5937/tehnika2201015S
UR  - https://hdl.handle.net/21.15107/rcub_dais_14853
ER  - 
@article{
author = "Stefanović, Milica P. and Vujančević, Jelena and Petrović, Rada P. and Stevanović, Marija S. and Janaćković, Đorđe",
year = "2022",
abstract = "Organsko-neorganski perovskiti su privukli veliku pažnju istraživača zbog visoke apsorpcije u vidljivomdelu spektra i jeftine proizvodnje. Apsorbovanjem svetlosti dolazi do stvaranja para elektron-šupljina.U cilju razdvajanja nosilaca naelektrisanja, perovskit se kombinuje sa TiO2 što ima za posledicuspontani prelazak elektrona sa perovskita na TiO2. Ovo istraživanje je imalo za cilj povećanje dodirnepovršine između nanocevi TiO2 i perovskita punjenjem nanocevi perovskitnim materijalom. Rastvormetilamonijum olovo(II)-bromidnog perovskita (CH3NH3PbBr3) u dimetilformamidu (DMF) jedeponovan na anodizacijom sintetisane TiO2 nanocevi pomoću sistema visokog vakuuma i inertnoggasa. Postupak je uključivao degazaciju uzorka u visokom vakuumu u trajanju od 3 h na 200 °C, hlađenjeuzorka, a zatim nanošenje rastvora CH3NH3PbBr3 u DMF-u, uz naknadni tretman inertnim gasom (N2)u cilju ostvarenja natpritiska, što je omogućilo punjenje nanocevi perovskitnim materijalom. Difuznorefleksiona spektroskopija pokazala je da taloženje CH3NH3PbBr3 poboljšava apsorpciona svojstvaTiO2 nanocevi. I-V karakteristike uzorka pokazale su fotodiodno ponašanje i histerezisnu krivu, koja jekarakteristična za perovskitni materijal. Vrednost struje uzorka snimljenim pod vidljivom svetlošćuiznosila je 46 μA bez primene prednapona, dok je nakon primene prednapona iznosila 76 μA. Rezultatirada ukazuju da je napravljena perovskitna fotodioda sa povećanim kontaktom između TiO2 i perovskita,koja predstavlja osnovu za buduću konstrukciju solarnih ćelija., Organic-inorganic perovskites have attracted much attention from researchers due to their high absorption in the visible part of the spectrum and low-cost fabrication. After absorption of the light, electron-hole pairs are formed. To separate electron-hole pairs and reduce recombination, perovskite is combined with TiO2 which has as a consequence, a spontaneous transition of electrons from perovskite to TiO2. This research aims to increase the contact surface of perovskite and TiO2 nanotubes by filling the nanotubes with perovskite material. The solution of methylammonium lead bromide perovskite (CH3NH3PbBr3) in dimethylformamide (DMF) was deposited on anodically synthesized TiO2 nanotubes by the high vacuum system and inert gas. The procedure involved degassation of the sample under high vacuum for 3 h at 200 °C, cooling of the sample, and putting the solution of CH3NH3PbBr3 in DMF, after which it was treated with inert gas (N2), as an overpressure which enabled the filling of the nanotubes with perovskite material. The diffuse reflectance spectroscopy measurement of the sample proved that deposition of CH3NH3PbBr3 improves the absorption properties of TiO2 nanotubes. The I-V characteristics of the sample showed photodiode behavior and characteristic hysteresis curve for perovskite material. The value of current under visible light for the sample without preconditioning was 46 mA, while after preconditioning value of current was 76 mA. The results indicate that a perovskite photodiode with increased contact between TiO2 and perovskite was made, which is the basis for future solar cell construction.",
publisher = "Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora, Improvement of absorption properties of TiO2 nanotubes by using CH3NH3PbBr3 perovskite as photosensitizer",
pages = "15-21",
volume = "31",
number = "1",
doi = "10.5937/tehnika2201015S",
url = "https://hdl.handle.net/21.15107/rcub_dais_14853"
}
Stefanović, M. P., Vujančević, J., Petrović, R. P., Stevanović, M. S.,& Janaćković, Đ.. (2022). Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora. in Tehnika
Savez inženjera i tehničara Srbije., 31(1), 15-21.
https://doi.org/10.5937/tehnika2201015S
https://hdl.handle.net/21.15107/rcub_dais_14853
Stefanović MP, Vujančević J, Petrović RP, Stevanović MS, Janaćković Đ. Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora. in Tehnika. 2022;31(1):15-21.
doi:10.5937/tehnika2201015S
https://hdl.handle.net/21.15107/rcub_dais_14853 .
Stefanović, Milica P., Vujančević, Jelena, Petrović, Rada P., Stevanović, Marija S., Janaćković, Đorđe, "Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora" in Tehnika, 31, no. 1 (2022):15-21,
https://doi.org/10.5937/tehnika2201015S .,
https://hdl.handle.net/21.15107/rcub_dais_14853 .

Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes

Dojčinović, Milena P.; Vasiljević, Zorka Ž.; Pavlović, Vera P.; Vujančević, Jelena; Tadić, Nenad; Nikolić, Maria Vesna

(Belgrade : University of Belgrade, Faculty of Physical Chemistry, 2022)

TY  - CONF
AU  - Dojčinović, Milena P.
AU  - Vasiljević, Zorka Ž.
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13642
AB  - Problems that countries all over the world have in common are dependence of economy and energy production on fossil fuels. There is a growing need for energy production and storage routes that are safe for the environment, renewable, efficient and cheap. One of the directions in which science is moving forward is discovering materials suitable for use in batteries and supercapacitors to improve their operating potential, electrical capacity or biocompatibility. The objective is also to synthesize materials for batteries or supercapacitors that are cheap, consist of earth abundant elements and have high electrochemical activity.
In this work, mixed nickel-magnesium ferrites NixMg1−xFe2O4, with x being 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1, were synthesized via sol-gel combustion synthesis with citric acid used as fuel and nitrate ions used as oxidizing agents. Combusted powders were calcined at 700 °C. The structure and morphology of the powders were characterized with X-ray diffraction method (XRD), field emission scanning electron microscopy (FESEM), Raman and FTIR spectroscopy. The band gap was calculated by using UV/Vis diffuse reflectance spectroscopy (DRS). Samples were cast on nickel foam and tested as energy storage materials in a three-electrode setup in 3 M KOH aqueous solution as electrolyte. The methods used were cyclic voltammetry (CV) and constant current chronopotentiometry to obtain galvanostatic charge-discharge (GCD) curves. Results show that all of the synthesized materials show battery-type charge storage in alkaline electrolyte due to the formation of metal cation oxyhydroxides. With increasing nickel content, electrochemical activity drops. The highest value of capacity, 34.3 mA h g-1 at the current density of 500 mA g-1 is ascribed to magnesium ferrite, MgFe2O4.
PB  - Belgrade : University of Belgrade, Faculty of Physical Chemistry
C3  - Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
T1  - Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes
SP  - 47
EP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_dais_13642
ER  - 
@conference{
author = "Dojčinović, Milena P. and Vasiljević, Zorka Ž. and Pavlović, Vera P. and Vujančević, Jelena and Tadić, Nenad and Nikolić, Maria Vesna",
year = "2022",
abstract = "Problems that countries all over the world have in common are dependence of economy and energy production on fossil fuels. There is a growing need for energy production and storage routes that are safe for the environment, renewable, efficient and cheap. One of the directions in which science is moving forward is discovering materials suitable for use in batteries and supercapacitors to improve their operating potential, electrical capacity or biocompatibility. The objective is also to synthesize materials for batteries or supercapacitors that are cheap, consist of earth abundant elements and have high electrochemical activity.
In this work, mixed nickel-magnesium ferrites NixMg1−xFe2O4, with x being 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1, were synthesized via sol-gel combustion synthesis with citric acid used as fuel and nitrate ions used as oxidizing agents. Combusted powders were calcined at 700 °C. The structure and morphology of the powders were characterized with X-ray diffraction method (XRD), field emission scanning electron microscopy (FESEM), Raman and FTIR spectroscopy. The band gap was calculated by using UV/Vis diffuse reflectance spectroscopy (DRS). Samples were cast on nickel foam and tested as energy storage materials in a three-electrode setup in 3 M KOH aqueous solution as electrolyte. The methods used were cyclic voltammetry (CV) and constant current chronopotentiometry to obtain galvanostatic charge-discharge (GCD) curves. Results show that all of the synthesized materials show battery-type charge storage in alkaline electrolyte due to the formation of metal cation oxyhydroxides. With increasing nickel content, electrochemical activity drops. The highest value of capacity, 34.3 mA h g-1 at the current density of 500 mA g-1 is ascribed to magnesium ferrite, MgFe2O4.",
publisher = "Belgrade : University of Belgrade, Faculty of Physical Chemistry",
journal = "Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022",
title = "Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes",
pages = "47-47",
url = "https://hdl.handle.net/21.15107/rcub_dais_13642"
}
Dojčinović, M. P., Vasiljević, Z. Ž., Pavlović, V. P., Vujančević, J., Tadić, N.,& Nikolić, M. V.. (2022). Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
Belgrade : University of Belgrade, Faculty of Physical Chemistry., 47-47.
https://hdl.handle.net/21.15107/rcub_dais_13642
Dojčinović MP, Vasiljević ZŽ, Pavlović VP, Vujančević J, Tadić N, Nikolić MV. Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022. 2022;:47-47.
https://hdl.handle.net/21.15107/rcub_dais_13642 .
Dojčinović, Milena P., Vasiljević, Zorka Ž., Pavlović, Vera P., Vujančević, Jelena, Tadić, Nenad, Nikolić, Maria Vesna, "Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes" in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022 (2022):47-47,
https://hdl.handle.net/21.15107/rcub_dais_13642 .

Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application

Rizzotto, Francesco; Vasiljević, Zorka Ž.; Stanojević, Gordana; Dojčinović, Milena P.; Janković-Častvan, Ivona; Vujančević, Jelena; Tadić, Nenad B.; Branković, Goran; Magniez, Aurélie; Vidić, Jasmina; Nikolić, Maria Vesna

(Elsevier Ltd, 2022)

TY  - JOUR
AU  - Rizzotto, Francesco
AU  - Vasiljević, Zorka Ž.
AU  - Stanojević, Gordana
AU  - Dojčinović, Milena P.
AU  - Janković-Častvan, Ivona
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Branković, Goran
AU  - Magniez, Aurélie
AU  - Vidić, Jasmina
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13437
AB  - An emerging technology of active packaging enables prolongation of food shelf life by limiting the oxygen transfer and the reactivity of free radicals, which both destruct food freshness. In this work, Fe2TiO5 nanoparticles were synthesized using a modified sol–gel method and evaluated as an enforcement of alginate food packaging film. Pure phase Fe2TiO5 nanoparticles had an average particle size of 44 nm and rhombohedral morphology. Fe2TiO5 nanoparticles induce no cell damage of human Caco-2 epithelial cells and show no inhibitory effect towards growth of a panel of bacterial strains, suggesting good biocompatibility. Films obtained by incorporation of Fe2TiO5 nanoparticles into alginate using the solvent casting method show no migration of iron or titanium ions from films to food simulants again suggesting their safety as a packaging material. Fe2TiO5 nanoparticles also showed strong antioxidant efficiency as determined using the DPPḢ assay, and confirmed further in a preservation test on fresh fruit.
PB  - Elsevier Ltd
T2  - Food Chemistry
T1  - Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application
SP  - 133198
VL  - 390
DO  - 10.1016/j.foodchem.2022.133198
UR  - https://hdl.handle.net/21.15107/rcub_dais_13437
ER  - 
@article{
author = "Rizzotto, Francesco and Vasiljević, Zorka Ž. and Stanojević, Gordana and Dojčinović, Milena P. and Janković-Častvan, Ivona and Vujančević, Jelena and Tadić, Nenad B. and Branković, Goran and Magniez, Aurélie and Vidić, Jasmina and Nikolić, Maria Vesna",
year = "2022",
abstract = "An emerging technology of active packaging enables prolongation of food shelf life by limiting the oxygen transfer and the reactivity of free radicals, which both destruct food freshness. In this work, Fe2TiO5 nanoparticles were synthesized using a modified sol–gel method and evaluated as an enforcement of alginate food packaging film. Pure phase Fe2TiO5 nanoparticles had an average particle size of 44 nm and rhombohedral morphology. Fe2TiO5 nanoparticles induce no cell damage of human Caco-2 epithelial cells and show no inhibitory effect towards growth of a panel of bacterial strains, suggesting good biocompatibility. Films obtained by incorporation of Fe2TiO5 nanoparticles into alginate using the solvent casting method show no migration of iron or titanium ions from films to food simulants again suggesting their safety as a packaging material. Fe2TiO5 nanoparticles also showed strong antioxidant efficiency as determined using the DPPḢ assay, and confirmed further in a preservation test on fresh fruit.",
publisher = "Elsevier Ltd",
journal = "Food Chemistry",
title = "Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application",
pages = "133198",
volume = "390",
doi = "10.1016/j.foodchem.2022.133198",
url = "https://hdl.handle.net/21.15107/rcub_dais_13437"
}
Rizzotto, F., Vasiljević, Z. Ž., Stanojević, G., Dojčinović, M. P., Janković-Častvan, I., Vujančević, J., Tadić, N. B., Branković, G., Magniez, A., Vidić, J.,& Nikolić, M. V.. (2022). Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application. in Food Chemistry
Elsevier Ltd., 390, 133198.
https://doi.org/10.1016/j.foodchem.2022.133198
https://hdl.handle.net/21.15107/rcub_dais_13437
Rizzotto F, Vasiljević ZŽ, Stanojević G, Dojčinović MP, Janković-Častvan I, Vujančević J, Tadić NB, Branković G, Magniez A, Vidić J, Nikolić MV. Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application. in Food Chemistry. 2022;390:133198.
doi:10.1016/j.foodchem.2022.133198
https://hdl.handle.net/21.15107/rcub_dais_13437 .
Rizzotto, Francesco, Vasiljević, Zorka Ž., Stanojević, Gordana, Dojčinović, Milena P., Janković-Častvan, Ivona, Vujančević, Jelena, Tadić, Nenad B., Branković, Goran, Magniez, Aurélie, Vidić, Jasmina, Nikolić, Maria Vesna, "Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application" in Food Chemistry, 390 (2022):133198,
https://doi.org/10.1016/j.foodchem.2022.133198 .,
https://hdl.handle.net/21.15107/rcub_dais_13437 .
10
9

Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application

Rizzotto, Francesco; Vasiljević, Zorka Ž.; Stanojević, Gordana; Dojčinović, Milena P.; Janković-Častvan, Ivona; Vujančević, Jelena; Tadić, Nenad B.; Branković, Goran; Magniez, Aurélie; Vidić, Jasmina; Nikolić, Maria Vesna

(Elsevier Ltd, 2022)

TY  - JOUR
AU  - Rizzotto, Francesco
AU  - Vasiljević, Zorka Ž.
AU  - Stanojević, Gordana
AU  - Dojčinović, Milena P.
AU  - Janković-Častvan, Ivona
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Branković, Goran
AU  - Magniez, Aurélie
AU  - Vidić, Jasmina
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13014
AB  - An emerging technology of active packaging enables prolongation of food shelf life by limiting the oxygen transfer and the reactivity of free radicals, which both destruct food freshness. In this work, Fe2TiO5 nanoparticles were synthesized using a modified sol–gel method and evaluated as an enforcement of alginate food packaging film. Pure phase Fe2TiO5 nanoparticles had an average particle size of 44 nm and rhombohedral morphology. Fe2TiO5 nanoparticles induce no cell damage of human Caco-2 epithelial cells and show no inhibitory effect towards growth of a panel of bacterial strains, suggesting good biocompatibility. Films obtained by incorporation of Fe2TiO5 nanoparticles into alginate using the solvent casting method show no migration of iron or titanium ions from films to food simulants again suggesting their safety as a packaging material. Fe2TiO5 nanoparticles also showed strong antioxidant efficiency as determined using the DPPḢ assay, and confirmed further in a preservation test on fresh fruit.
PB  - Elsevier Ltd
T2  - Food Chemistry
T1  - Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application
SP  - 133198
VL  - 390
DO  - 10.1016/j.foodchem.2022.133198
UR  - https://hdl.handle.net/21.15107/rcub_dais_13014
ER  - 
@article{
author = "Rizzotto, Francesco and Vasiljević, Zorka Ž. and Stanojević, Gordana and Dojčinović, Milena P. and Janković-Častvan, Ivona and Vujančević, Jelena and Tadić, Nenad B. and Branković, Goran and Magniez, Aurélie and Vidić, Jasmina and Nikolić, Maria Vesna",
year = "2022",
abstract = "An emerging technology of active packaging enables prolongation of food shelf life by limiting the oxygen transfer and the reactivity of free radicals, which both destruct food freshness. In this work, Fe2TiO5 nanoparticles were synthesized using a modified sol–gel method and evaluated as an enforcement of alginate food packaging film. Pure phase Fe2TiO5 nanoparticles had an average particle size of 44 nm and rhombohedral morphology. Fe2TiO5 nanoparticles induce no cell damage of human Caco-2 epithelial cells and show no inhibitory effect towards growth of a panel of bacterial strains, suggesting good biocompatibility. Films obtained by incorporation of Fe2TiO5 nanoparticles into alginate using the solvent casting method show no migration of iron or titanium ions from films to food simulants again suggesting their safety as a packaging material. Fe2TiO5 nanoparticles also showed strong antioxidant efficiency as determined using the DPPḢ assay, and confirmed further in a preservation test on fresh fruit.",
publisher = "Elsevier Ltd",
journal = "Food Chemistry",
title = "Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application",
pages = "133198",
volume = "390",
doi = "10.1016/j.foodchem.2022.133198",
url = "https://hdl.handle.net/21.15107/rcub_dais_13014"
}
Rizzotto, F., Vasiljević, Z. Ž., Stanojević, G., Dojčinović, M. P., Janković-Častvan, I., Vujančević, J., Tadić, N. B., Branković, G., Magniez, A., Vidić, J.,& Nikolić, M. V.. (2022). Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application. in Food Chemistry
Elsevier Ltd., 390, 133198.
https://doi.org/10.1016/j.foodchem.2022.133198
https://hdl.handle.net/21.15107/rcub_dais_13014
Rizzotto F, Vasiljević ZŽ, Stanojević G, Dojčinović MP, Janković-Častvan I, Vujančević J, Tadić NB, Branković G, Magniez A, Vidić J, Nikolić MV. Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application. in Food Chemistry. 2022;390:133198.
doi:10.1016/j.foodchem.2022.133198
https://hdl.handle.net/21.15107/rcub_dais_13014 .
Rizzotto, Francesco, Vasiljević, Zorka Ž., Stanojević, Gordana, Dojčinović, Milena P., Janković-Častvan, Ivona, Vujančević, Jelena, Tadić, Nenad B., Branković, Goran, Magniez, Aurélie, Vidić, Jasmina, Nikolić, Maria Vesna, "Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application" in Food Chemistry, 390 (2022):133198,
https://doi.org/10.1016/j.foodchem.2022.133198 .,
https://hdl.handle.net/21.15107/rcub_dais_13014 .
10
8

Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells

Stefanović, Milica; Lukić, Ivana; Vujančević, Jelena; Petrović, Rada; Janaćković, Đorđe

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Stefanović, Milica
AU  - Lukić, Ivana
AU  - Vujančević, Jelena
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13636
AB  - The organo-inorganic perovskites are extraordinary materials that have recently revolutionized the field of photovoltaics due to their low-cost fabrication and high optical absorption. In a short period, they reached great efficiency. Many parameters which affect the quality of perovskite films can be optimized, so the efficiency of these devices can be further improved. In perovskite solar cells, the perovskite layer is an active layer that absorbs the visible part of the spectrum, resulting in the formation of the electron-hole pair. To decrease the recombination of charge carriers, the construction of solar cells requires the existence of two additional layers in order to separate the holes and electrons. TiO2 could be used as an electron transport layer because its conduction band (CB) lies under the CB of perovskite. In that way, electrons diffuse from CB of perovskite to CB of TiO2. For these experiments, TiO2 nanotubular structure provides a one-dimensional transmission channel for the charge carriers, which resulting in faster carrier transport. Perovskite methylammonium lead bromide (MAPbBr3) was coupled with TiO2 nanotube arrays which were synthesized by anodization of Ti foil and annealed at 450 °C. The most used methods for deposition of perovskite materials on mesoporous and planar TiO2 are: one-step deposition, two-step sequential deposition, and vapor-assisted solution processing. Disadvantage of these methods is a small contact area between TiO2 and perovskite. The aim of this research was to increase the contact surface of the perovskite and TiO2 nanotubes by filling the nanotubes with the perovskite material in order to improve electron transport.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
T1  - Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells
SP  - 188
EP  - 189
UR  - https://hdl.handle.net/21.15107/rcub_dais_13636
ER  - 
@conference{
author = "Stefanović, Milica and Lukić, Ivana and Vujančević, Jelena and Petrović, Rada and Janaćković, Đorđe",
year = "2022",
abstract = "The organo-inorganic perovskites are extraordinary materials that have recently revolutionized the field of photovoltaics due to their low-cost fabrication and high optical absorption. In a short period, they reached great efficiency. Many parameters which affect the quality of perovskite films can be optimized, so the efficiency of these devices can be further improved. In perovskite solar cells, the perovskite layer is an active layer that absorbs the visible part of the spectrum, resulting in the formation of the electron-hole pair. To decrease the recombination of charge carriers, the construction of solar cells requires the existence of two additional layers in order to separate the holes and electrons. TiO2 could be used as an electron transport layer because its conduction band (CB) lies under the CB of perovskite. In that way, electrons diffuse from CB of perovskite to CB of TiO2. For these experiments, TiO2 nanotubular structure provides a one-dimensional transmission channel for the charge carriers, which resulting in faster carrier transport. Perovskite methylammonium lead bromide (MAPbBr3) was coupled with TiO2 nanotube arrays which were synthesized by anodization of Ti foil and annealed at 450 °C. The most used methods for deposition of perovskite materials on mesoporous and planar TiO2 are: one-step deposition, two-step sequential deposition, and vapor-assisted solution processing. Disadvantage of these methods is a small contact area between TiO2 and perovskite. The aim of this research was to increase the contact surface of the perovskite and TiO2 nanotubes by filling the nanotubes with the perovskite material in order to improve electron transport.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022",
title = "Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells",
pages = "188-189",
url = "https://hdl.handle.net/21.15107/rcub_dais_13636"
}
Stefanović, M., Lukić, I., Vujančević, J., Petrović, R.,& Janaćković, Đ.. (2022). Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
Belgrade : Serbian Academy of Sciences and Arts., 188-189.
https://hdl.handle.net/21.15107/rcub_dais_13636
Stefanović M, Lukić I, Vujančević J, Petrović R, Janaćković Đ. Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022. 2022;:188-189.
https://hdl.handle.net/21.15107/rcub_dais_13636 .
Stefanović, Milica, Lukić, Ivana, Vujančević, Jelena, Petrović, Rada, Janaćković, Đorđe, "Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells" in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022 (2022):188-189,
https://hdl.handle.net/21.15107/rcub_dais_13636 .

Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes

Stefanović, Milica; Lukić, Ivana; Vujančević, Jelena; Petrović, Rada; Janaćković, Đorđe

(Belgrade : Materials Research Society of Serbia, 2022)

TY  - CONF
AU  - Stefanović, Milica
AU  - Lukić, Ivana
AU  - Vujančević, Jelena
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13591
AB  - Supercritical carbon dioxide (sCO2) is an ideal low-temperature cosolvent for perovskite deposition due to its relatively low critical point (31.2 °C, 73.8 bar), no surface tension, liquid-like density, gas-like viscosity, and diffusivity. It enables faster mass transfer which allows penetration of crystals in nanoporous structure. The study investigates the influence of time of deposition of perovskite assisted with supercritical carbon dioxide on the filling of nanotubes. Perovskite solar cell technology has been developed so fast due to several factors including a tunable band gap, high absorption coefficient, and low-cost fabrication. The quality of the perovskite film is important for the high efficiency of perovskite solar cells. Perovskite precursors are usually deposited from the solution onto a substrate using spin-coating followed by post-deposition treatments, but often it results in low-quality films that cannot provide good photovoltaic performances. Deposition of perovskite in the presence of sCO2 is a promising method for the formation of high-quality perovskite layers. In this work, methylammonium lead bromide perovskite (MAPbBr3) was deposited on TiO2 nanotubes from the solution in dimethylformamide (DMF) by application of sCO2 at 35 °C and 200 bar for 1 h, and 3 h. FESEM results show that TiO2 nanotubes were filled with perovskite material in both cases. The diffuse reflectance spectroscopy measurement of samples proved that the absorption edge of prepared TiO2 nanotubes/MAPbBr3 was extended to the visible range. Measurement of I-V characteristics showed that the sample made for 3 h had a higher value of current than the sample prepared for 1 h. The application of sCO2 during the deposition of perovskite has enabled the preparation of a photodiode with a better contact between TiO2 nanotubes and perovskite which is important for the future development of solar cells.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
T1  - Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes
SP  - 73
EP  - 73
UR  - https://hdl.handle.net/21.15107/rcub_dais_13591
ER  - 
@conference{
author = "Stefanović, Milica and Lukić, Ivana and Vujančević, Jelena and Petrović, Rada and Janaćković, Đorđe",
year = "2022",
abstract = "Supercritical carbon dioxide (sCO2) is an ideal low-temperature cosolvent for perovskite deposition due to its relatively low critical point (31.2 °C, 73.8 bar), no surface tension, liquid-like density, gas-like viscosity, and diffusivity. It enables faster mass transfer which allows penetration of crystals in nanoporous structure. The study investigates the influence of time of deposition of perovskite assisted with supercritical carbon dioxide on the filling of nanotubes. Perovskite solar cell technology has been developed so fast due to several factors including a tunable band gap, high absorption coefficient, and low-cost fabrication. The quality of the perovskite film is important for the high efficiency of perovskite solar cells. Perovskite precursors are usually deposited from the solution onto a substrate using spin-coating followed by post-deposition treatments, but often it results in low-quality films that cannot provide good photovoltaic performances. Deposition of perovskite in the presence of sCO2 is a promising method for the formation of high-quality perovskite layers. In this work, methylammonium lead bromide perovskite (MAPbBr3) was deposited on TiO2 nanotubes from the solution in dimethylformamide (DMF) by application of sCO2 at 35 °C and 200 bar for 1 h, and 3 h. FESEM results show that TiO2 nanotubes were filled with perovskite material in both cases. The diffuse reflectance spectroscopy measurement of samples proved that the absorption edge of prepared TiO2 nanotubes/MAPbBr3 was extended to the visible range. Measurement of I-V characteristics showed that the sample made for 3 h had a higher value of current than the sample prepared for 1 h. The application of sCO2 during the deposition of perovskite has enabled the preparation of a photodiode with a better contact between TiO2 nanotubes and perovskite which is important for the future development of solar cells.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022",
title = "Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes",
pages = "73-73",
url = "https://hdl.handle.net/21.15107/rcub_dais_13591"
}
Stefanović, M., Lukić, I., Vujančević, J., Petrović, R.,& Janaćković, Đ.. (2022). Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
Belgrade : Materials Research Society of Serbia., 73-73.
https://hdl.handle.net/21.15107/rcub_dais_13591
Stefanović M, Lukić I, Vujančević J, Petrović R, Janaćković Đ. Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022. 2022;:73-73.
https://hdl.handle.net/21.15107/rcub_dais_13591 .
Stefanović, Milica, Lukić, Ivana, Vujančević, Jelena, Petrović, Rada, Janaćković, Đorđe, "Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes" in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022 (2022):73-73,
https://hdl.handle.net/21.15107/rcub_dais_13591 .

Influence of calcination temperature on the structure, morphology and optical properties of electrospun pseudobrookite nanofibers

Vasiljević, Zorka Ž.; Dojčinović, Milena P.; Vujančević, Jelena; Spreitzer, Matjaž; Kovač, Janez; Janković-Čaštvan, Ivona; Bartolić, Dragana; Marković, Smilja; Tadić, Nenad; Nikolić, Maria Vesna

(Novi Sad : Faculty of Technology, 2021)

TY  - CONF
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena P.
AU  - Vujančević, Jelena
AU  - Spreitzer, Matjaž
AU  - Kovač, Janez
AU  - Janković-Čaštvan, Ivona
AU  - Bartolić, Dragana
AU  - Marković, Smilja
AU  - Tadić, Nenad
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/15358
AB  - Novel crystalline iron-titanate fibers were synthesized for the first time to the best of our knowledge, through a simple, low cost electrospinning method followed by calcination treatment at different temperatures (500–750 °C for 3 h and at 500 °C for 6 h and at 550 °C for 4 h). The fibers were prepared from a precursor solution containing polyvinylpyrrolidone (PVP), iron(III) nonahydrate, titanium isopropoxide, N,N-Dimethylformamide and ethanol. As spun fibers were smooth, straight, beadless and uniform forming a nonwoven fibrous mat, with an average diameter of ca. 205 nm. Upon calcination in air the PVP matrice was removed and XRD and FTIR analysis showed that the duration of the calcination process, besides the temperature, had a direct influence on phase formation. Pure phase of pseudobrookite was obtained at 600 °C, 500 °C for 6 h and at 550 °C for 4 h. In addition, the morphology of obtained nanofibers was directly affected by the calcination temperature. The surface of fibers obtained after calcination was no longer smooth and the fiber diameter decreased due to complete degradation of PVP. At 700 oC and 750 °C, fibers were thicker which can be attributed to growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles. All samples exhibited a type IV nitrogen adsorption isotherm with a type- H3 indicating slit-shaped mesoporous structure. The BET surface areas of 500 °C for 6 h, 550 °C for 4 h and 600 °C for 3 h were estimated to be 62, 38.7 and 33.2 m2/g, respectively.
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad, 2021
T1  - Influence of calcination temperature on the structure, morphology and optical properties of electrospun pseudobrookite nanofibers
SP  - 124
EP  - 124
UR  - https://hdl.handle.net/21.15107/rcub_dais_15358
ER  - 
@conference{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena P. and Vujančević, Jelena and Spreitzer, Matjaž and Kovač, Janez and Janković-Čaštvan, Ivona and Bartolić, Dragana and Marković, Smilja and Tadić, Nenad and Nikolić, Maria Vesna",
year = "2021",
abstract = "Novel crystalline iron-titanate fibers were synthesized for the first time to the best of our knowledge, through a simple, low cost electrospinning method followed by calcination treatment at different temperatures (500–750 °C for 3 h and at 500 °C for 6 h and at 550 °C for 4 h). The fibers were prepared from a precursor solution containing polyvinylpyrrolidone (PVP), iron(III) nonahydrate, titanium isopropoxide, N,N-Dimethylformamide and ethanol. As spun fibers were smooth, straight, beadless and uniform forming a nonwoven fibrous mat, with an average diameter of ca. 205 nm. Upon calcination in air the PVP matrice was removed and XRD and FTIR analysis showed that the duration of the calcination process, besides the temperature, had a direct influence on phase formation. Pure phase of pseudobrookite was obtained at 600 °C, 500 °C for 6 h and at 550 °C for 4 h. In addition, the morphology of obtained nanofibers was directly affected by the calcination temperature. The surface of fibers obtained after calcination was no longer smooth and the fiber diameter decreased due to complete degradation of PVP. At 700 oC and 750 °C, fibers were thicker which can be attributed to growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles. All samples exhibited a type IV nitrogen adsorption isotherm with a type- H3 indicating slit-shaped mesoporous structure. The BET surface areas of 500 °C for 6 h, 550 °C for 4 h and 600 °C for 3 h were estimated to be 62, 38.7 and 33.2 m2/g, respectively.",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad, 2021",
title = "Influence of calcination temperature on the structure, morphology and optical properties of electrospun pseudobrookite nanofibers",
pages = "124-124",
url = "https://hdl.handle.net/21.15107/rcub_dais_15358"
}
Vasiljević, Z. Ž., Dojčinović, M. P., Vujančević, J., Spreitzer, M., Kovač, J., Janković-Čaštvan, I., Bartolić, D., Marković, S., Tadić, N.,& Nikolić, M. V.. (2021). Influence of calcination temperature on the structure, morphology and optical properties of electrospun pseudobrookite nanofibers. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad, 2021
Novi Sad : Faculty of Technology., 124-124.
https://hdl.handle.net/21.15107/rcub_dais_15358
Vasiljević ZŽ, Dojčinović MP, Vujančević J, Spreitzer M, Kovač J, Janković-Čaštvan I, Bartolić D, Marković S, Tadić N, Nikolić MV. Influence of calcination temperature on the structure, morphology and optical properties of electrospun pseudobrookite nanofibers. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad, 2021. 2021;:124-124.
https://hdl.handle.net/21.15107/rcub_dais_15358 .
Vasiljević, Zorka Ž., Dojčinović, Milena P., Vujančević, Jelena, Spreitzer, Matjaž, Kovač, Janez, Janković-Čaštvan, Ivona, Bartolić, Dragana, Marković, Smilja, Tadić, Nenad, Nikolić, Maria Vesna, "Influence of calcination temperature on the structure, morphology and optical properties of electrospun pseudobrookite nanofibers" in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad, 2021 (2021):124-124,
https://hdl.handle.net/21.15107/rcub_dais_15358 .

Influence of anodization voltage on photocatalztic activity of TiO2 nanotubes

Vujančević, Jelena; Ćirković, Jovana; Horváth, Endre; Forró, László; Pavlović, Vladimir B.; Janaćković, Đorđe

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Ćirković, Jovana
AU  - Horváth, Endre
AU  - Forró, László
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12347
AB  - TiO2 under UV light generates charge carriers (electrons and holes) that take part in the process of decomposition of pollutants, which is a well-known fact for the past few decades. For this reason, TiO2 is used for photocatalytic purification water and air. Photoactivity of TiO2 depends on the amount of generated charge carriers, and one part of those carriers are lost through the process of recombination. In order to improve photoactivity, it is necessary to speed up transport of electrons and holes. For better and faster charge carrier transport a unidirectional path is desired, which can be obtained by synthesizing 1D morphology. Anodization of titanium foil is a good way to obtain perpendicular nanotubular morphology onto a substrate. Nanotubular morphology can be optimized via operative conditions of anodization: applied voltage, anodization time and type of electrolyte. In this work, TiO2 nanotube arrays were synthesized by anodization of titanium foil at different voltages: 10 V, 15 V, 20 V and 25 V. Based on FESEM (Field Emission Scanning Electron Microscopy) micrographs, the microstructure of nanotubes was analysed and data concerning wall thickness, outer diameter of nanotubes and active surface were considered. Also, the influence of nanotube morphology on optical properties was determined. Results of our research show that the increasement in anodization voltage influenced on the appearance of redshift in the absorption spectrum. The sample synthesized at 20 V showed the highest photocatalytic activity due to the optimal nanotube length and nanotube diameter.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - Influence of anodization voltage on photocatalztic activity of TiO2 nanotubes
SP  - 23
EP  - 23
UR  - https://hdl.handle.net/21.15107/rcub_dais_12347
ER  - 
@conference{
author = "Vujančević, Jelena and Ćirković, Jovana and Horváth, Endre and Forró, László and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2021",
abstract = "TiO2 under UV light generates charge carriers (electrons and holes) that take part in the process of decomposition of pollutants, which is a well-known fact for the past few decades. For this reason, TiO2 is used for photocatalytic purification water and air. Photoactivity of TiO2 depends on the amount of generated charge carriers, and one part of those carriers are lost through the process of recombination. In order to improve photoactivity, it is necessary to speed up transport of electrons and holes. For better and faster charge carrier transport a unidirectional path is desired, which can be obtained by synthesizing 1D morphology. Anodization of titanium foil is a good way to obtain perpendicular nanotubular morphology onto a substrate. Nanotubular morphology can be optimized via operative conditions of anodization: applied voltage, anodization time and type of electrolyte. In this work, TiO2 nanotube arrays were synthesized by anodization of titanium foil at different voltages: 10 V, 15 V, 20 V and 25 V. Based on FESEM (Field Emission Scanning Electron Microscopy) micrographs, the microstructure of nanotubes was analysed and data concerning wall thickness, outer diameter of nanotubes and active surface were considered. Also, the influence of nanotube morphology on optical properties was determined. Results of our research show that the increasement in anodization voltage influenced on the appearance of redshift in the absorption spectrum. The sample synthesized at 20 V showed the highest photocatalytic activity due to the optimal nanotube length and nanotube diameter.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "Influence of anodization voltage on photocatalztic activity of TiO2 nanotubes",
pages = "23-23",
url = "https://hdl.handle.net/21.15107/rcub_dais_12347"
}
Vujančević, J., Ćirković, J., Horváth, E., Forró, L., Pavlović, V. B.,& Janaćković, Đ.. (2021). Influence of anodization voltage on photocatalztic activity of TiO2 nanotubes. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 23-23.
https://hdl.handle.net/21.15107/rcub_dais_12347
Vujančević J, Ćirković J, Horváth E, Forró L, Pavlović VB, Janaćković Đ. Influence of anodization voltage on photocatalztic activity of TiO2 nanotubes. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:23-23.
https://hdl.handle.net/21.15107/rcub_dais_12347 .
Vujančević, Jelena, Ćirković, Jovana, Horváth, Endre, Forró, László, Pavlović, Vladimir B., Janaćković, Đorđe, "Influence of anodization voltage on photocatalztic activity of TiO2 nanotubes" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):23-23,
https://hdl.handle.net/21.15107/rcub_dais_12347 .

Photoactivity of vanadium oxide TiO2 nanotubes

Vujančević, Jelena; Blagojević, Vladimir; Andričević, Pavao; Pavlović, Vera P.; Horváth, Endre; Forró, László; Vlahović, Branislav; Pavlović, Vladimir B.; Janaćković, Đorđe

(Novi Sad : Faculty of Technology, 2021)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Blagojević, Vladimir
AU  - Andričević, Pavao
AU  - Pavlović, Vera P.
AU  - Horváth, Endre
AU  - Forró, László
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12398
AB  - The aim of this study was to investigate the influence of vanadium oxide photosensitive surface layer on the photoactivity of TiO2 nanotubes. Nanotube arrays were synthesized by anodization of titanium foil at different voltages, and vanadium-oxide was deposited by wet chemical deposition. Deposition of the vanadium-oxide layer was confirmed by XPS analysis, which provided the chemical composition of the sample surface. Photovoltaic characteristics and photocatalytic performance for photodegradation of methyl orange dye of modified TiO2 nanotubes were correlated with the nanotube morphology (and anodization voltage). Optimal anodization voltage was determined, in conjunction with the deposition of the surface vanadium oxide layer, in order to achieve maximum performance of the modified TiO2 electrodes. This has been correlated with changes in the optical properties of the TiO2 electrodes, the nanotube length and diameter, as they occur with the change in the anodization voltage, as well as the changes in the vanadium-oxide content in the samples, where the vanadium-oxide content was found to be determined by the nanotube morphology. The photovoltaic performance of the optimized modified TiO2 electrode with the surface vanadium-oxide layer was found to be significantly better than both the performance of the corresponding TiO2 electrode, and the performance of all the other TiO2 electrodes included in the study.
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad
T1  - Photoactivity of vanadium oxide TiO2 nanotubes
SP  - 92
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_dais_12398
ER  - 
@conference{
author = "Vujančević, Jelena and Blagojević, Vladimir and Andričević, Pavao and Pavlović, Vera P. and Horváth, Endre and Forró, László and Vlahović, Branislav and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2021",
abstract = "The aim of this study was to investigate the influence of vanadium oxide photosensitive surface layer on the photoactivity of TiO2 nanotubes. Nanotube arrays were synthesized by anodization of titanium foil at different voltages, and vanadium-oxide was deposited by wet chemical deposition. Deposition of the vanadium-oxide layer was confirmed by XPS analysis, which provided the chemical composition of the sample surface. Photovoltaic characteristics and photocatalytic performance for photodegradation of methyl orange dye of modified TiO2 nanotubes were correlated with the nanotube morphology (and anodization voltage). Optimal anodization voltage was determined, in conjunction with the deposition of the surface vanadium oxide layer, in order to achieve maximum performance of the modified TiO2 electrodes. This has been correlated with changes in the optical properties of the TiO2 electrodes, the nanotube length and diameter, as they occur with the change in the anodization voltage, as well as the changes in the vanadium-oxide content in the samples, where the vanadium-oxide content was found to be determined by the nanotube morphology. The photovoltaic performance of the optimized modified TiO2 electrode with the surface vanadium-oxide layer was found to be significantly better than both the performance of the corresponding TiO2 electrode, and the performance of all the other TiO2 electrodes included in the study.",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad",
title = "Photoactivity of vanadium oxide TiO2 nanotubes",
pages = "92-92",
url = "https://hdl.handle.net/21.15107/rcub_dais_12398"
}
Vujančević, J., Blagojević, V., Andričević, P., Pavlović, V. P., Horváth, E., Forró, L., Vlahović, B., Pavlović, V. B.,& Janaćković, Đ.. (2021). Photoactivity of vanadium oxide TiO2 nanotubes. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad
Novi Sad : Faculty of Technology., 92-92.
https://hdl.handle.net/21.15107/rcub_dais_12398
Vujančević J, Blagojević V, Andričević P, Pavlović VP, Horváth E, Forró L, Vlahović B, Pavlović VB, Janaćković Đ. Photoactivity of vanadium oxide TiO2 nanotubes. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad. 2021;:92-92.
https://hdl.handle.net/21.15107/rcub_dais_12398 .
Vujančević, Jelena, Blagojević, Vladimir, Andričević, Pavao, Pavlović, Vera P., Horváth, Endre, Forró, László, Vlahović, Branislav, Pavlović, Vladimir B., Janaćković, Đorđe, "Photoactivity of vanadium oxide TiO2 nanotubes" in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad (2021):92-92,
https://hdl.handle.net/21.15107/rcub_dais_12398 .

Nanocrystalline Zn2SnO4/SnO2: Crystal structure and humidity influence on complex impedance

Nikolić, Maria Vesna; Labus, Nebojša; Pavlović, Vera P.; Marković, Smilja; Luković, Miloljub D.; Tadić, Nenad B.; Vujančević, Jelena; Vlahović, Branislav; Pavlović, Vladimir B.

(Springer, 2021)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Labus, Nebojša
AU  - Pavlović, Vera P.
AU  - Marković, Smilja
AU  - Luković, Miloljub D.
AU  - Tadić, Nenad B.
AU  - Vujančević, Jelena
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11954
AB  - Nanocrystalline Zn2SnO4/SnO2 powder was obtained by a solid state reaction of ZnO and SnO2 nanopowders mixed in the molar ratio 1:1. The phase composition of the obtained powder was studied by XRD and Raman spectroscopy, morphology and texture were characterized by FESEM, TEM, BET and Hg porosimetry, while XPS and FTIR spectroscopy were used to determine the surface chemistry. The influence of humidity on complex impedance was monitored on bulk samples in the relative humidity (RH) range 30–90% in a climatic chamber in the frequency range 42 Hz- 1 MHz at working temperatures of 25 and 50 °C. Change in RH had a significant influence on impedance reduction, especially noticeable in the lower frequency range, indicating potential application of this nanocomposite as a humidity sensing material. Increase in RH led to an increase in AC conductivity that changed with frequency according to the Jonscher power law. The frequency exponent decreased with increase in RH and sample temperature indicating that the correlated hopping barrier model is the dominant conduction mechanism. Complex impedance was analyzed using an equivalent circuit consisting of a parallel resistance and constant phase element, showing the dominant influence of grain boundaries at both working temperatures (25 and 50 °C). The resistance decreased, while the capacitance and relaxation frequency increased with increase in RH. At high humidity an added Wartburg element enabled modeling of the charge diffusion process
PB  - Springer
T2  - Journal of Electroceramics
T1  - Nanocrystalline Zn2SnO4/SnO2: Crystal structure and humidity influence on complex impedance
SP  - 135
EP  - 147
VL  - 45
DO  - 10.1007/s10832-021-00232-z
UR  - https://hdl.handle.net/21.15107/rcub_dais_11954
ER  - 
@article{
author = "Nikolić, Maria Vesna and Labus, Nebojša and Pavlović, Vera P. and Marković, Smilja and Luković, Miloljub D. and Tadić, Nenad B. and Vujančević, Jelena and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2021",
abstract = "Nanocrystalline Zn2SnO4/SnO2 powder was obtained by a solid state reaction of ZnO and SnO2 nanopowders mixed in the molar ratio 1:1. The phase composition of the obtained powder was studied by XRD and Raman spectroscopy, morphology and texture were characterized by FESEM, TEM, BET and Hg porosimetry, while XPS and FTIR spectroscopy were used to determine the surface chemistry. The influence of humidity on complex impedance was monitored on bulk samples in the relative humidity (RH) range 30–90% in a climatic chamber in the frequency range 42 Hz- 1 MHz at working temperatures of 25 and 50 °C. Change in RH had a significant influence on impedance reduction, especially noticeable in the lower frequency range, indicating potential application of this nanocomposite as a humidity sensing material. Increase in RH led to an increase in AC conductivity that changed with frequency according to the Jonscher power law. The frequency exponent decreased with increase in RH and sample temperature indicating that the correlated hopping barrier model is the dominant conduction mechanism. Complex impedance was analyzed using an equivalent circuit consisting of a parallel resistance and constant phase element, showing the dominant influence of grain boundaries at both working temperatures (25 and 50 °C). The resistance decreased, while the capacitance and relaxation frequency increased with increase in RH. At high humidity an added Wartburg element enabled modeling of the charge diffusion process",
publisher = "Springer",
journal = "Journal of Electroceramics",
title = "Nanocrystalline Zn2SnO4/SnO2: Crystal structure and humidity influence on complex impedance",
pages = "135-147",
volume = "45",
doi = "10.1007/s10832-021-00232-z",
url = "https://hdl.handle.net/21.15107/rcub_dais_11954"
}
Nikolić, M. V., Labus, N., Pavlović, V. P., Marković, S., Luković, M. D., Tadić, N. B., Vujančević, J., Vlahović, B.,& Pavlović, V. B.. (2021). Nanocrystalline Zn2SnO4/SnO2: Crystal structure and humidity influence on complex impedance. in Journal of Electroceramics
Springer., 45, 135-147.
https://doi.org/10.1007/s10832-021-00232-z
https://hdl.handle.net/21.15107/rcub_dais_11954
Nikolić MV, Labus N, Pavlović VP, Marković S, Luković MD, Tadić NB, Vujančević J, Vlahović B, Pavlović VB. Nanocrystalline Zn2SnO4/SnO2: Crystal structure and humidity influence on complex impedance. in Journal of Electroceramics. 2021;45:135-147.
doi:10.1007/s10832-021-00232-z
https://hdl.handle.net/21.15107/rcub_dais_11954 .
Nikolić, Maria Vesna, Labus, Nebojša, Pavlović, Vera P., Marković, Smilja, Luković, Miloljub D., Tadić, Nenad B., Vujančević, Jelena, Vlahović, Branislav, Pavlović, Vladimir B., "Nanocrystalline Zn2SnO4/SnO2: Crystal structure and humidity influence on complex impedance" in Journal of Electroceramics, 45 (2021):135-147,
https://doi.org/10.1007/s10832-021-00232-z .,
https://hdl.handle.net/21.15107/rcub_dais_11954 .
3
3

Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing

Dojčinović, Milena P.; Vasiljević, Zorka Ž.; Krstić, Jugoslav B.; Vujančević, Jelena D.; Marković, Smilja; Tadić, Nenad B.; Nikolic, Maria Vesna

(Basel : MDPI AG, 2021)

TY  - JOUR
AU  - Dojčinović, Milena P.
AU  - Vasiljević, Zorka Ž.
AU  - Krstić, Jugoslav B.
AU  - Vujančević, Jelena D.
AU  - Marković, Smilja
AU  - Tadić, Nenad B.
AU  - Nikolic, Maria Vesna
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11797
AB  - Nickel manganite nanocrystalline fibers were obtained by electrospinning and subsequent calcination at 400 °C. As-spun fibers were characterized by TG/DTA, Scanning Electron Microscopy and FT-IR spectroscopy analysis. X-ray diffraction and FT-IR spectroscopy analysis confirmed the formation of nickel manganite with a cubic spinel structure, while N2 physisorption at 77 K enabled determination of the BET specific surface area as 25.3 m2/g and (BJH) mesopore volume as 21.5 m2/g. The material constant (B) of the nanocrystalline nickel manganite fibers applied by drop-casting on test interdigitated electrodes on alumina substrate, dried at room temperature, was determined as 4379 K in the 20–50 °C temperature range and a temperature sensitivity of −4.95%/K at room temperature (25 °C). The change of impedance with relative humidity was monitored at 25 and 50 °C for a relative humidity (RH) change of 40 to 90% in the 42 Hzπ1 MHz frequency range. At 100 Hz and 25 °C, the sensitivity of 327.36 ± 80.12 kΩ/%RH was determined, showing that nickel manganite obtained by electrospinning has potential as a multifunctional material for combined humidity and temperature sensing.
PB  - Basel : MDPI AG
T2  - Sensors
T1  - Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing
SP  - 4357
VL  - 21
IS  - 13
DO  - 10.3390/s21134357
UR  - https://hdl.handle.net/21.15107/rcub_dais_11797
ER  - 
@article{
author = "Dojčinović, Milena P. and Vasiljević, Zorka Ž. and Krstić, Jugoslav B. and Vujančević, Jelena D. and Marković, Smilja and Tadić, Nenad B. and Nikolic, Maria Vesna",
year = "2021",
abstract = "Nickel manganite nanocrystalline fibers were obtained by electrospinning and subsequent calcination at 400 °C. As-spun fibers were characterized by TG/DTA, Scanning Electron Microscopy and FT-IR spectroscopy analysis. X-ray diffraction and FT-IR spectroscopy analysis confirmed the formation of nickel manganite with a cubic spinel structure, while N2 physisorption at 77 K enabled determination of the BET specific surface area as 25.3 m2/g and (BJH) mesopore volume as 21.5 m2/g. The material constant (B) of the nanocrystalline nickel manganite fibers applied by drop-casting on test interdigitated electrodes on alumina substrate, dried at room temperature, was determined as 4379 K in the 20–50 °C temperature range and a temperature sensitivity of −4.95%/K at room temperature (25 °C). The change of impedance with relative humidity was monitored at 25 and 50 °C for a relative humidity (RH) change of 40 to 90% in the 42 Hzπ1 MHz frequency range. At 100 Hz and 25 °C, the sensitivity of 327.36 ± 80.12 kΩ/%RH was determined, showing that nickel manganite obtained by electrospinning has potential as a multifunctional material for combined humidity and temperature sensing.",
publisher = "Basel : MDPI AG",
journal = "Sensors",
title = "Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing",
pages = "4357",
volume = "21",
number = "13",
doi = "10.3390/s21134357",
url = "https://hdl.handle.net/21.15107/rcub_dais_11797"
}
Dojčinović, M. P., Vasiljević, Z. Ž., Krstić, J. B., Vujančević, J. D., Marković, S., Tadić, N. B.,& Nikolic, M. V.. (2021). Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing. in Sensors
Basel : MDPI AG., 21(13), 4357.
https://doi.org/10.3390/s21134357
https://hdl.handle.net/21.15107/rcub_dais_11797
Dojčinović MP, Vasiljević ZŽ, Krstić JB, Vujančević JD, Marković S, Tadić NB, Nikolic MV. Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing. in Sensors. 2021;21(13):4357.
doi:10.3390/s21134357
https://hdl.handle.net/21.15107/rcub_dais_11797 .
Dojčinović, Milena P., Vasiljević, Zorka Ž., Krstić, Jugoslav B., Vujančević, Jelena D., Marković, Smilja, Tadić, Nenad B., Nikolic, Maria Vesna, "Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing" in Sensors, 21, no. 13 (2021):4357,
https://doi.org/10.3390/s21134357 .,
https://hdl.handle.net/21.15107/rcub_dais_11797 .
9
1
8

Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe 2 TiO 5 nanofibers

Vasiljević, Zorka Ž.; Dojčinović, Milena P.; Vujančević, Jelena D.; Spreitzer, Matjaž; Kovač, Janez; Bartolić, Dragana; Marković, Smilja; Janković-Čaštvan, Ivona; Tadić, Nenad B.; Nikolić, Maria Vesna

(Royal Society of Chemistry (RSC), 2021)

TY  - JOUR
AU  - Vasiljević, Zorka Ž.
AU  - Dojčinović, Milena P.
AU  - Vujančević, Jelena D.
AU  - Spreitzer, Matjaž
AU  - Kovač, Janez
AU  - Bartolić, Dragana
AU  - Marković, Smilja
AU  - Janković-Čaštvan, Ivona
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12338
AB  - Nanostructured Fe2TiO5 (pseudobrookite), a mixed metal oxide material holds significant promise for utilization in energy and environmental applications. However, its full application is still hindered due to the difficulty to synthesize monophasic Fe2TiO5 with high crystallinity and a large specific surface area. Herein, Fe2TiO5 nanofibers were synthesized via a versatile and low-cost electrospinning method, followed by a calcination process at different temperatures. We found a significant effect of the calcination process and its duration on the crystalline phase in the form of either pseudobrookite or pseudobrookite–hematite–rutile and the morphology of calcined nanofibers. The crystallite size increased whereas the specific surface area decreased with an increase in calcination temperature. At higher temperatures, the growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles was noted. The highest specific surface area was obtained for the sample calcined at 500 °C for 6 h (SBET = 64.4 m2 g−1). This work opens new opportunities in the synthesis of Fe2TiO5 nanostructures using the electrospinning method and a subsequent optimized calcination process for energy-related applications.
PB  - Royal Society of Chemistry (RSC)
T2  - RSC Advances
T1  - Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe                    2                    TiO                    5                    nanofibers
SP  - 32358
EP  - 32368
VL  - 11
IS  - 51
DO  - 10.1039/D1RA05748K
UR  - https://hdl.handle.net/21.15107/rcub_dais_12338
ER  - 
@article{
author = "Vasiljević, Zorka Ž. and Dojčinović, Milena P. and Vujančević, Jelena D. and Spreitzer, Matjaž and Kovač, Janez and Bartolić, Dragana and Marković, Smilja and Janković-Čaštvan, Ivona and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2021",
abstract = "Nanostructured Fe2TiO5 (pseudobrookite), a mixed metal oxide material holds significant promise for utilization in energy and environmental applications. However, its full application is still hindered due to the difficulty to synthesize monophasic Fe2TiO5 with high crystallinity and a large specific surface area. Herein, Fe2TiO5 nanofibers were synthesized via a versatile and low-cost electrospinning method, followed by a calcination process at different temperatures. We found a significant effect of the calcination process and its duration on the crystalline phase in the form of either pseudobrookite or pseudobrookite–hematite–rutile and the morphology of calcined nanofibers. The crystallite size increased whereas the specific surface area decreased with an increase in calcination temperature. At higher temperatures, the growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles was noted. The highest specific surface area was obtained for the sample calcined at 500 °C for 6 h (SBET = 64.4 m2 g−1). This work opens new opportunities in the synthesis of Fe2TiO5 nanostructures using the electrospinning method and a subsequent optimized calcination process for energy-related applications.",
publisher = "Royal Society of Chemistry (RSC)",
journal = "RSC Advances",
title = "Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe                    2                    TiO                    5                    nanofibers",
pages = "32358-32368",
volume = "11",
number = "51",
doi = "10.1039/D1RA05748K",
url = "https://hdl.handle.net/21.15107/rcub_dais_12338"
}
Vasiljević, Z. Ž., Dojčinović, M. P., Vujančević, J. D., Spreitzer, M., Kovač, J., Bartolić, D., Marković, S., Janković-Čaštvan, I., Tadić, N. B.,& Nikolić, M. V.. (2021). Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe                    2                    TiO                    5                    nanofibers. in RSC Advances
Royal Society of Chemistry (RSC)., 11(51), 32358-32368.
https://doi.org/10.1039/D1RA05748K
https://hdl.handle.net/21.15107/rcub_dais_12338
Vasiljević ZŽ, Dojčinović MP, Vujančević JD, Spreitzer M, Kovač J, Bartolić D, Marković S, Janković-Čaštvan I, Tadić NB, Nikolić MV. Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe                    2                    TiO                    5                    nanofibers. in RSC Advances. 2021;11(51):32358-32368.
doi:10.1039/D1RA05748K
https://hdl.handle.net/21.15107/rcub_dais_12338 .
Vasiljević, Zorka Ž., Dojčinović, Milena P., Vujančević, Jelena D., Spreitzer, Matjaž, Kovač, Janez, Bartolić, Dragana, Marković, Smilja, Janković-Čaštvan, Ivona, Tadić, Nenad B., Nikolić, Maria Vesna, "Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe                    2                    TiO                    5                    nanofibers" in RSC Advances, 11, no. 51 (2021):32358-32368,
https://doi.org/10.1039/D1RA05748K .,
https://hdl.handle.net/21.15107/rcub_dais_12338 .
11
9

Point defects and their effect on dielectric permittivity in strontium titanate ceramics

Kosanović, Darko; Živojinović, Jelena; Vujančević, Jelena; Peleš, Adriana; Blagojević, Vladimir

(Belgrade : ETRAN, 2021)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Vujančević, Jelena
AU  - Peleš, Adriana
AU  - Blagojević, Vladimir
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12344
AB  - The origin of dielectric properties of strontium titanate ceramics is investigated using DFT calculations in periodic system. It was determined that the main factors contributing to the increase in dielectric permittivity are: tetragonal distortion of the normally cubic lattice, and charge imbalance induced displacement of titanium center from its central position. Oxygen vacancies were determined to create significantly larger effects than other types of vacancies, like Ti and SrO. The extent of tetragonal distortion was found to be determined by oxygen vacancy distribution, rather than total concentration: relatively symmetrical distribution of oxygen vacancies resulted in smaller tetragonal distortion of the lattice, and, consequently, smaller increase in dielectric permittivity. Charge imbalance naturally destabilizes the cubic lattice, forcing the Ti-atom out of its central position, resulting in tetragonal lattice with increased dielectric permittivity. The process stabilizes the strontium titanate lattice, while increasing the c/a ratio. Therefore, the dielectric permittivity of strontium titanate can be increased by changes to the system that increase tetragonal distortion of the lattice and/or introduce additional negative charge.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Point defects and their effect on dielectric permittivity in strontium titanate ceramics
SP  - 285
EP  - 299
VL  - 53
IS  - 3
DO  - 10.2298/SOS2103285K
UR  - https://hdl.handle.net/21.15107/rcub_dais_12344
ER  - 
@article{
author = "Kosanović, Darko and Živojinović, Jelena and Vujančević, Jelena and Peleš, Adriana and Blagojević, Vladimir",
year = "2021",
abstract = "The origin of dielectric properties of strontium titanate ceramics is investigated using DFT calculations in periodic system. It was determined that the main factors contributing to the increase in dielectric permittivity are: tetragonal distortion of the normally cubic lattice, and charge imbalance induced displacement of titanium center from its central position. Oxygen vacancies were determined to create significantly larger effects than other types of vacancies, like Ti and SrO. The extent of tetragonal distortion was found to be determined by oxygen vacancy distribution, rather than total concentration: relatively symmetrical distribution of oxygen vacancies resulted in smaller tetragonal distortion of the lattice, and, consequently, smaller increase in dielectric permittivity. Charge imbalance naturally destabilizes the cubic lattice, forcing the Ti-atom out of its central position, resulting in tetragonal lattice with increased dielectric permittivity. The process stabilizes the strontium titanate lattice, while increasing the c/a ratio. Therefore, the dielectric permittivity of strontium titanate can be increased by changes to the system that increase tetragonal distortion of the lattice and/or introduce additional negative charge.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Point defects and their effect on dielectric permittivity in strontium titanate ceramics",
pages = "285-299",
volume = "53",
number = "3",
doi = "10.2298/SOS2103285K",
url = "https://hdl.handle.net/21.15107/rcub_dais_12344"
}
Kosanović, D., Živojinović, J., Vujančević, J., Peleš, A.,& Blagojević, V.. (2021). Point defects and their effect on dielectric permittivity in strontium titanate ceramics. in Science of Sintering
Belgrade : ETRAN., 53(3), 285-299.
https://doi.org/10.2298/SOS2103285K
https://hdl.handle.net/21.15107/rcub_dais_12344
Kosanović D, Živojinović J, Vujančević J, Peleš A, Blagojević V. Point defects and their effect on dielectric permittivity in strontium titanate ceramics. in Science of Sintering. 2021;53(3):285-299.
doi:10.2298/SOS2103285K
https://hdl.handle.net/21.15107/rcub_dais_12344 .
Kosanović, Darko, Živojinović, Jelena, Vujančević, Jelena, Peleš, Adriana, Blagojević, Vladimir, "Point defects and their effect on dielectric permittivity in strontium titanate ceramics" in Science of Sintering, 53, no. 3 (2021):285-299,
https://doi.org/10.2298/SOS2103285K .,
https://hdl.handle.net/21.15107/rcub_dais_12344 .
1
2

Synthesis and deposition of MAPbBr3 perovskite on titania nanotube arrays

Stefanović, Milica; Vujančević, Jelena; Petrović, Rada; Janaćković, Đorđe

(Belgrade : Materials Research Society of Serbia, 2021)

TY  - CONF
AU  - Stefanović, Milica
AU  - Vujančević, Jelena
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12075
AB  - The organo-inorganic perovskites are materials that have recently revolutionized the field of
photovoltaics due to their low-cost fabrication and high optical absorption. The hybrid organoinorganic perovskite absorbs the visible part of the spectrum resulting in the creation of electron-hole pair. To decrease the recombination of charge carriers, the construction of solar cells requires the existence of separate layers for holes and for electrons. TiO2 is usually used as an electron transport layer because its conduction band (CB) lies under the CB of perovskite. In that way, electrons diffuse from CB of perovskite to CB of TiO2. For these experiments, TiO2 nanotubular structure was used as an electron transport layer due to its advantages compared to nanoparticular TiO2. TiO2 nanotubes can provide a one-dimensional transmission channel for the charge carriers, so it will reduce the recombination rate of the carriers and provide a channel for fast carrier transport. However, there is a problem with the contact surface between perovskite and TiO2 nanotubes. The aim of this study is to increase the contact surface of perovskite and TiO2 nanotubes by filling the nanotubes with perovskite material in order to improve electron transport. Methylammonium lead bromide perovskite (MAPbBr3) was deposited on anodically synthesized TiO2 nanotubes which were annealed at 450 °C for 1 h. After degassation of the sample under high vacuum for 3 h at 200 °C, the cooled sample was put in a solution of MAPbBr3 in dimethylformamide (DMF) and it was treated with inert gas (N2), which enabled the filling of the nanotubes with perovskite material to some extent. FESEM and XRD analyses were used for morphological and chemical characterization of the sample. The diffuse reflectance spectroscopy measurement of the sample proved that deposition of MAPbBr3 improves the absorption properties of TiO2 nanotubes. By measuring the I-V characteristics of the sample in the dark and under visible light, a hysteresis curve was obtained.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021
T1  - Synthesis and deposition of MAPbBr3 perovskite on titania nanotube arrays
SP  - 111
EP  - 111
UR  - https://hdl.handle.net/21.15107/rcub_dais_12075
ER  - 
@conference{
author = "Stefanović, Milica and Vujančević, Jelena and Petrović, Rada and Janaćković, Đorđe",
year = "2021",
abstract = "The organo-inorganic perovskites are materials that have recently revolutionized the field of
photovoltaics due to their low-cost fabrication and high optical absorption. The hybrid organoinorganic perovskite absorbs the visible part of the spectrum resulting in the creation of electron-hole pair. To decrease the recombination of charge carriers, the construction of solar cells requires the existence of separate layers for holes and for electrons. TiO2 is usually used as an electron transport layer because its conduction band (CB) lies under the CB of perovskite. In that way, electrons diffuse from CB of perovskite to CB of TiO2. For these experiments, TiO2 nanotubular structure was used as an electron transport layer due to its advantages compared to nanoparticular TiO2. TiO2 nanotubes can provide a one-dimensional transmission channel for the charge carriers, so it will reduce the recombination rate of the carriers and provide a channel for fast carrier transport. However, there is a problem with the contact surface between perovskite and TiO2 nanotubes. The aim of this study is to increase the contact surface of perovskite and TiO2 nanotubes by filling the nanotubes with perovskite material in order to improve electron transport. Methylammonium lead bromide perovskite (MAPbBr3) was deposited on anodically synthesized TiO2 nanotubes which were annealed at 450 °C for 1 h. After degassation of the sample under high vacuum for 3 h at 200 °C, the cooled sample was put in a solution of MAPbBr3 in dimethylformamide (DMF) and it was treated with inert gas (N2), which enabled the filling of the nanotubes with perovskite material to some extent. FESEM and XRD analyses were used for morphological and chemical characterization of the sample. The diffuse reflectance spectroscopy measurement of the sample proved that deposition of MAPbBr3 improves the absorption properties of TiO2 nanotubes. By measuring the I-V characteristics of the sample in the dark and under visible light, a hysteresis curve was obtained.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021",
title = "Synthesis and deposition of MAPbBr3 perovskite on titania nanotube arrays",
pages = "111-111",
url = "https://hdl.handle.net/21.15107/rcub_dais_12075"
}
Stefanović, M., Vujančević, J., Petrović, R.,& Janaćković, Đ.. (2021). Synthesis and deposition of MAPbBr3 perovskite on titania nanotube arrays. in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021
Belgrade : Materials Research Society of Serbia., 111-111.
https://hdl.handle.net/21.15107/rcub_dais_12075
Stefanović M, Vujančević J, Petrović R, Janaćković Đ. Synthesis and deposition of MAPbBr3 perovskite on titania nanotube arrays. in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021. 2021;:111-111.
https://hdl.handle.net/21.15107/rcub_dais_12075 .
Stefanović, Milica, Vujančević, Jelena, Petrović, Rada, Janaćković, Đorđe, "Synthesis and deposition of MAPbBr3 perovskite on titania nanotube arrays" in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021 (2021):111-111,
https://hdl.handle.net/21.15107/rcub_dais_12075 .