Čebela, Maria

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orcid::0000-0001-6120-6924
  • Čebela, Maria (13)
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Author's Bibliography

Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus

Stamenković, Tijana; Ranđelović, Marjan; Čebela, Maria; Vuković, Marina; Dinić, Ivana; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Ranđelović, Marjan
AU  - Čebela, Maria
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14662
AB  - The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus
UR  - https://hdl.handle.net/21.15107/rcub_dais_14662
ER  - 
@conference{
author = "Stamenković, Tijana and Ranđelović, Marjan and Čebela, Maria and Vuković, Marina and Dinić, Ivana and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus",
url = "https://hdl.handle.net/21.15107/rcub_dais_14662"
}
Stamenković, T., Ranđelović, M., Čebela, M., Vuković, M., Dinić, I., Mančić, L.,& Lojpur, V.. (2023). Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14662
Stamenković T, Ranđelović M, Čebela M, Vuković M, Dinić I, Mančić L, Lojpur V. Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14662 .
Stamenković, Tijana, Ranđelović, Marjan, Čebela, Maria, Vuković, Marina, Dinić, Ivana, Mančić, Lidija, Lojpur, Vesna, "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14662 .

Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles

Stamenković, Tijana; Radmilović, Nadežda; Dinić, Ivana; Vuković, Marina; Barudžija, Tanja; Čebela, Maria; Lojpur, Vesna

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Barudžija, Tanja
AU  - Čebela, Maria
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14663
AB  - In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles
UR  - https://hdl.handle.net/21.15107/rcub_dais_14663
ER  - 
@conference{
author = "Stamenković, Tijana and Radmilović, Nadežda and Dinić, Ivana and Vuković, Marina and Barudžija, Tanja and Čebela, Maria and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles",
url = "https://hdl.handle.net/21.15107/rcub_dais_14663"
}
Stamenković, T., Radmilović, N., Dinić, I., Vuković, M., Barudžija, T., Čebela, M.,& Lojpur, V.. (2023). Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14663
Stamenković T, Radmilović N, Dinić I, Vuković M, Barudžija T, Čebela M, Lojpur V. Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14663 .
Stamenković, Tijana, Radmilović, Nadežda, Dinić, Ivana, Vuković, Marina, Barudžija, Tanja, Čebela, Maria, Lojpur, Vesna, "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14663 .

Synthesis, structure and magnetic properties of Fe2TiO5

Čebela, Maria; Reddy, Priyanka; Čakar, Uroš; Labus, Nebojša; Lojpur, Vesna; Dodevski, Vladimir; Rosić, Milena

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Čebela, Maria
AU  - Reddy, Priyanka
AU  - Čakar, Uroš
AU  - Labus, Nebojša
AU  - Lojpur, Vesna
AU  - Dodevski, Vladimir
AU  - Rosić, Milena
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14660
AB  - Iron(III) titanates are attracting rapidly growing interest as very promising candidates for applications in solar energy and optoelectronics because they contain earth-rich elements. Potentially, Fe2TiO5 is a thermoelectric material. We used a Vibrating Sample Magnetometer and Superconducting Quantum Interferometer Device Magnetometer to study the magnetic properties of the pseudobrookite material Fe2TiO5. The material was synthesized by the sol-gel method. The structural parameters of the synthesized samples were investigated by X-ray analysis. The diffractogram was refined with the help of Rietveld refinement on FullProf Suite. Temperature-dependent ZFC and FC magnetization was measured on SQUID for lower temperature down to 2 K and on VSM for higher temperatures up to 1000 K. A transition was observed at 815 K with a separation between the ZFC and FC curves. Parallelly the bifurcation in the isothermal hysteresis measurements indicates that the system exhibits dominant canted AFM (or weak FM) with a small amount of spin glass. The small value of the moment was also pointing towards the canted AFM ordering. The size and morphology of the particles was determined using transmission electron microscopy (TEM) and scanning electron microscopy (SEM).
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Synthesis, structure and magnetic properties of Fe2TiO5
UR  - https://hdl.handle.net/21.15107/rcub_dais_14660
ER  - 
@conference{
author = "Čebela, Maria and Reddy, Priyanka and Čakar, Uroš and Labus, Nebojša and Lojpur, Vesna and Dodevski, Vladimir and Rosić, Milena",
year = "2023",
abstract = "Iron(III) titanates are attracting rapidly growing interest as very promising candidates for applications in solar energy and optoelectronics because they contain earth-rich elements. Potentially, Fe2TiO5 is a thermoelectric material. We used a Vibrating Sample Magnetometer and Superconducting Quantum Interferometer Device Magnetometer to study the magnetic properties of the pseudobrookite material Fe2TiO5. The material was synthesized by the sol-gel method. The structural parameters of the synthesized samples were investigated by X-ray analysis. The diffractogram was refined with the help of Rietveld refinement on FullProf Suite. Temperature-dependent ZFC and FC magnetization was measured on SQUID for lower temperature down to 2 K and on VSM for higher temperatures up to 1000 K. A transition was observed at 815 K with a separation between the ZFC and FC curves. Parallelly the bifurcation in the isothermal hysteresis measurements indicates that the system exhibits dominant canted AFM (or weak FM) with a small amount of spin glass. The small value of the moment was also pointing towards the canted AFM ordering. The size and morphology of the particles was determined using transmission electron microscopy (TEM) and scanning electron microscopy (SEM).",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Synthesis, structure and magnetic properties of Fe2TiO5",
url = "https://hdl.handle.net/21.15107/rcub_dais_14660"
}
Čebela, M., Reddy, P., Čakar, U., Labus, N., Lojpur, V., Dodevski, V.,& Rosić, M.. (2023). Synthesis, structure and magnetic properties of Fe2TiO5. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14660
Čebela M, Reddy P, Čakar U, Labus N, Lojpur V, Dodevski V, Rosić M. Synthesis, structure and magnetic properties of Fe2TiO5. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14660 .
Čebela, Maria, Reddy, Priyanka, Čakar, Uroš, Labus, Nebojša, Lojpur, Vesna, Dodevski, Vladimir, Rosić, Milena, "Synthesis, structure and magnetic properties of Fe2TiO5" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14660 .

Influence of Gd-doping on electrical properties in Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, 0.2) perovskites

Rosić, Milena; Čebela, Maria; Labus, Nebojša; Radović, Marko; Aškrabić, Sonja; Dohčević-Mitrović, Zorana; Stojmenović, Marija

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Rosić, Milena
AU  - Čebela, Maria
AU  - Labus, Nebojša
AU  - Radović, Marko
AU  - Aškrabić, Sonja
AU  - Dohčević-Mitrović, Zorana
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14661
AB  - Ca1-xGdxMnO3 (x = 0.05–0.20) nanostructured perovskites were successfully synthesized by modified glycine nitrate procedure (MGNP). Temperature intervals of sintering and phase transition during heating were revealed during dilatometric measurements. In order to determine the band gap values of the tested samples, ellipsometric measurements were performed in the UV-VIS spectral range. Decrease of band gap values with increase of Gd dopant content was attributed to n-type doping and upward shifting of the Fermi level in the conduction band. The investigation of the crystal structure and phase content of nanocrystalline Ca1- xGdxMnO3 powders was continued using micro-Raman spectroscopy. The electrical conductivity of Gd3+ doped sintered samples CaMnO3 as a function of temperature was measured by electrochemical impedance spectroscopy (EIS), in the temperature range of 400–700 °C. The corresponding activation energies of conductivity, measured in the investigated temperature range, were also discussed. The obtained research results showed that the highest hardness values of 7.58 GPa respectively, were achieved and that these nanostructured materials can be used as a high-density ceramic material for various industrial applications.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Influence of Gd-doping on electrical properties in Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, 0.2) perovskites
UR  - https://hdl.handle.net/21.15107/rcub_dais_14661
ER  - 
@conference{
author = "Rosić, Milena and Čebela, Maria and Labus, Nebojša and Radović, Marko and Aškrabić, Sonja and Dohčević-Mitrović, Zorana and Stojmenović, Marija",
year = "2023",
abstract = "Ca1-xGdxMnO3 (x = 0.05–0.20) nanostructured perovskites were successfully synthesized by modified glycine nitrate procedure (MGNP). Temperature intervals of sintering and phase transition during heating were revealed during dilatometric measurements. In order to determine the band gap values of the tested samples, ellipsometric measurements were performed in the UV-VIS spectral range. Decrease of band gap values with increase of Gd dopant content was attributed to n-type doping and upward shifting of the Fermi level in the conduction band. The investigation of the crystal structure and phase content of nanocrystalline Ca1- xGdxMnO3 powders was continued using micro-Raman spectroscopy. The electrical conductivity of Gd3+ doped sintered samples CaMnO3 as a function of temperature was measured by electrochemical impedance spectroscopy (EIS), in the temperature range of 400–700 °C. The corresponding activation energies of conductivity, measured in the investigated temperature range, were also discussed. The obtained research results showed that the highest hardness values of 7.58 GPa respectively, were achieved and that these nanostructured materials can be used as a high-density ceramic material for various industrial applications.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Influence of Gd-doping on electrical properties in Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, 0.2) perovskites",
url = "https://hdl.handle.net/21.15107/rcub_dais_14661"
}
Rosić, M., Čebela, M., Labus, N., Radović, M., Aškrabić, S., Dohčević-Mitrović, Z.,& Stojmenović, M.. (2023). Influence of Gd-doping on electrical properties in Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, 0.2) perovskites. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14661
Rosić M, Čebela M, Labus N, Radović M, Aškrabić S, Dohčević-Mitrović Z, Stojmenović M. Influence of Gd-doping on electrical properties in Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, 0.2) perovskites. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14661 .
Rosić, Milena, Čebela, Maria, Labus, Nebojša, Radović, Marko, Aškrabić, Sonja, Dohčević-Mitrović, Zorana, Stojmenović, Marija, "Influence of Gd-doping on electrical properties in Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, 0.2) perovskites" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14661 .

Investigating sorptive aspects of CoMoO4 nanopowders synthesized by sprt method

Rosić, Milena; Čebela, Maria; Jordanov, Dragana; Labus, Nebojša; Vasić Jovev, Marija; Ljupković, Radomir; Zarubica, Aleksandra

(Belgrade : Institut za multidisciplinarna istraživanja, 2022)

TY  - CONF
AU  - Rosić, Milena
AU  - Čebela, Maria
AU  - Jordanov, Dragana
AU  - Labus, Nebojša
AU  - Vasić Jovev, Marija
AU  - Ljupković, Radomir
AU  - Zarubica, Aleksandra
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13632
AB  - Nanosized CoMoO4 solid solution was successfully synthesized at room temperature using simple and fast Self Propagating Room Temperature procedure (SPRT). The structural, textural, morphological and surface characteristics of the nanosized CoMoO4 were examined in detail by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectra, Field emission scanning electron microscopy (FESEM), and nitrogen sorption method. X-ray powder diffraction (XRPD) reflected the presence of two different phases that are in the same space group. The α-CoMoO4 and the β-CoMoO4 modification crystallizes in the monoclinic space group C2/m, No.12, but the β-phase clearly distinct from the α-phase due to the tetrahedral coordination of the Mo6+ ions. Adsorption tests were studied over CoMoO4 nanopowders under different experimental conditions (material dosage, initial concentration of pollutant textile dye, etc). The obtained results showed acceptable sorption characteristics of the material.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
T1  - Investigating sorptive aspects of CoMoO4 nanopowders synthesized by sprt method
SP  - 55
EP  - 56
UR  - https://hdl.handle.net/21.15107/rcub_dais_13632
ER  - 
@conference{
author = "Rosić, Milena and Čebela, Maria and Jordanov, Dragana and Labus, Nebojša and Vasić Jovev, Marija and Ljupković, Radomir and Zarubica, Aleksandra",
year = "2022",
abstract = "Nanosized CoMoO4 solid solution was successfully synthesized at room temperature using simple and fast Self Propagating Room Temperature procedure (SPRT). The structural, textural, morphological and surface characteristics of the nanosized CoMoO4 were examined in detail by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectra, Field emission scanning electron microscopy (FESEM), and nitrogen sorption method. X-ray powder diffraction (XRPD) reflected the presence of two different phases that are in the same space group. The α-CoMoO4 and the β-CoMoO4 modification crystallizes in the monoclinic space group C2/m, No.12, but the β-phase clearly distinct from the α-phase due to the tetrahedral coordination of the Mo6+ ions. Adsorption tests were studied over CoMoO4 nanopowders under different experimental conditions (material dosage, initial concentration of pollutant textile dye, etc). The obtained results showed acceptable sorption characteristics of the material.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia",
title = "Investigating sorptive aspects of CoMoO4 nanopowders synthesized by sprt method",
pages = "55-56",
url = "https://hdl.handle.net/21.15107/rcub_dais_13632"
}
Rosić, M., Čebela, M., Jordanov, D., Labus, N., Vasić Jovev, M., Ljupković, R.,& Zarubica, A.. (2022). Investigating sorptive aspects of CoMoO4 nanopowders synthesized by sprt method. in Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja., 55-56.
https://hdl.handle.net/21.15107/rcub_dais_13632
Rosić M, Čebela M, Jordanov D, Labus N, Vasić Jovev M, Ljupković R, Zarubica A. Investigating sorptive aspects of CoMoO4 nanopowders synthesized by sprt method. in Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia. 2022;:55-56.
https://hdl.handle.net/21.15107/rcub_dais_13632 .
Rosić, Milena, Čebela, Maria, Jordanov, Dragana, Labus, Nebojša, Vasić Jovev, Marija, Ljupković, Radomir, Zarubica, Aleksandra, "Investigating sorptive aspects of CoMoO4 nanopowders synthesized by sprt method" in Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia (2022):55-56,
https://hdl.handle.net/21.15107/rcub_dais_13632 .

Dilatometric study of nanostructured Ca1-xGdxMnO3 (X=0.05; 0.1; 0.15; 0.2)

Labus, Nebojša; Gulicovski, Jelena; Čebela, Maria; Rosić, Milena

(Belgrade : Institut za multidisciplinarna istraživanja, 2022)

TY  - CONF
AU  - Labus, Nebojša
AU  - Gulicovski, Jelena
AU  - Čebela, Maria
AU  - Rosić, Milena
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13634
AB  - Nanocrystalline powders of Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, and 0.2) have been synthesized by the modified glycine nitrate procedure and pressed into pellets that served as green bodies for a systematic investigation on their structural and microstructural properties [1]. Dilatometric measurements were performed in order to confirm the optimal sintering temperature. Dilatometric curves, besides sintering, are recording superimposed phase transition and linear expansion. Using a dilatometric curve, three temperatures were determined at which the examined sample shows significant changes. At 1055 °C–1194 °C certain second order phase transition is evident, at 1365 °C–1409 °C intensive nitrogen oxide extrusion, and in duration of 86 min at 877 °C heating ramp thorough isothermal holding at 1410 °C until 158 min cooling schedule at 1331 °C sintering is performed. Vickers hardness values were obtained based on the change in the surface area of the diamond pyramid. The results indicate that the hardness of the Ca1-xGdxMnO3 system (x = 0.05; 0.1; 0.15; 0.2) is not conditioned by the amount of doped gadolinium.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
T1  - Dilatometric study of nanostructured Ca1-xGdxMnO3 (X=0.05; 0.1; 0.15; 0.2)
SP  - 68
EP  - 68
UR  - https://hdl.handle.net/21.15107/rcub_dais_13634
ER  - 
@conference{
author = "Labus, Nebojša and Gulicovski, Jelena and Čebela, Maria and Rosić, Milena",
year = "2022",
abstract = "Nanocrystalline powders of Ca1-xGdxMnO3 (x=0.05, 0.1, 0.15, and 0.2) have been synthesized by the modified glycine nitrate procedure and pressed into pellets that served as green bodies for a systematic investigation on their structural and microstructural properties [1]. Dilatometric measurements were performed in order to confirm the optimal sintering temperature. Dilatometric curves, besides sintering, are recording superimposed phase transition and linear expansion. Using a dilatometric curve, three temperatures were determined at which the examined sample shows significant changes. At 1055 °C–1194 °C certain second order phase transition is evident, at 1365 °C–1409 °C intensive nitrogen oxide extrusion, and in duration of 86 min at 877 °C heating ramp thorough isothermal holding at 1410 °C until 158 min cooling schedule at 1331 °C sintering is performed. Vickers hardness values were obtained based on the change in the surface area of the diamond pyramid. The results indicate that the hardness of the Ca1-xGdxMnO3 system (x = 0.05; 0.1; 0.15; 0.2) is not conditioned by the amount of doped gadolinium.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia",
title = "Dilatometric study of nanostructured Ca1-xGdxMnO3 (X=0.05; 0.1; 0.15; 0.2)",
pages = "68-68",
url = "https://hdl.handle.net/21.15107/rcub_dais_13634"
}
Labus, N., Gulicovski, J., Čebela, M.,& Rosić, M.. (2022). Dilatometric study of nanostructured Ca1-xGdxMnO3 (X=0.05; 0.1; 0.15; 0.2). in Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja., 68-68.
https://hdl.handle.net/21.15107/rcub_dais_13634
Labus N, Gulicovski J, Čebela M, Rosić M. Dilatometric study of nanostructured Ca1-xGdxMnO3 (X=0.05; 0.1; 0.15; 0.2). in Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia. 2022;:68-68.
https://hdl.handle.net/21.15107/rcub_dais_13634 .
Labus, Nebojša, Gulicovski, Jelena, Čebela, Maria, Rosić, Milena, "Dilatometric study of nanostructured Ca1-xGdxMnO3 (X=0.05; 0.1; 0.15; 0.2)" in Programme ; and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia (2022):68-68,
https://hdl.handle.net/21.15107/rcub_dais_13634 .

Experimental Investigation of Octahedral Tilting and Related Effects of Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) Compound

Rosić, Milena; Čebela, Maria; Labus, Nebojša

(Belgrade : University of Belgrade, Faculty of Physical Chemistry, 2022)

TY  - CONF
AU  - Rosić, Milena
AU  - Čebela, Maria
AU  - Labus, Nebojša
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13643
AB  - Nanometric size Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) powder particles with perovskite-type structure were obtained by applying a modified glycine-nitrate procedure. [1, 2] All samples were investigated by X-ray diffraction (XRD), Infrared (IR) spectroscopy and EPR (electron paramagnetic resonance) measurements. In the perovskites with space group Pnma, octahedral tilting is most common and it is of great interest for geologists and materials science. It was experimentally observed how the amount of gadolinium dopants affects on the Mn-O bonds angles and distances, MnO6 octahedral tilting, the deformation due to the presence of Jahn-Teller distortion around the Mn3+ cation and relation between the structural and magnetic behavior. [3] The infrared reflection spectra of Ca1-xGdxMnO3 samples confirmed XRD results that Ca1-xGdxMnO3 nanopowders are of Pnma-1 structure and that the octahedral tilting is increased with Gd doping. The EPR spectra are in agreement with the expectation that EPR linewidth depend of Mn-O-Mn angle and that small octahedral tilting brought only a small change of the EPR linewidth.
PB  - Belgrade : University of Belgrade, Faculty of Physical Chemistry
C3  - Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
T1  - Experimental Investigation of Octahedral Tilting and Related Effects of Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) Compound
SP  - 44
EP  - 44
UR  - https://hdl.handle.net/21.15107/rcub_dais_13643
ER  - 
@conference{
author = "Rosić, Milena and Čebela, Maria and Labus, Nebojša",
year = "2022",
abstract = "Nanometric size Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) powder particles with perovskite-type structure were obtained by applying a modified glycine-nitrate procedure. [1, 2] All samples were investigated by X-ray diffraction (XRD), Infrared (IR) spectroscopy and EPR (electron paramagnetic resonance) measurements. In the perovskites with space group Pnma, octahedral tilting is most common and it is of great interest for geologists and materials science. It was experimentally observed how the amount of gadolinium dopants affects on the Mn-O bonds angles and distances, MnO6 octahedral tilting, the deformation due to the presence of Jahn-Teller distortion around the Mn3+ cation and relation between the structural and magnetic behavior. [3] The infrared reflection spectra of Ca1-xGdxMnO3 samples confirmed XRD results that Ca1-xGdxMnO3 nanopowders are of Pnma-1 structure and that the octahedral tilting is increased with Gd doping. The EPR spectra are in agreement with the expectation that EPR linewidth depend of Mn-O-Mn angle and that small octahedral tilting brought only a small change of the EPR linewidth.",
publisher = "Belgrade : University of Belgrade, Faculty of Physical Chemistry",
journal = "Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022",
title = "Experimental Investigation of Octahedral Tilting and Related Effects of Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) Compound",
pages = "44-44",
url = "https://hdl.handle.net/21.15107/rcub_dais_13643"
}
Rosić, M., Čebela, M.,& Labus, N.. (2022). Experimental Investigation of Octahedral Tilting and Related Effects of Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) Compound. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
Belgrade : University of Belgrade, Faculty of Physical Chemistry., 44-44.
https://hdl.handle.net/21.15107/rcub_dais_13643
Rosić M, Čebela M, Labus N. Experimental Investigation of Octahedral Tilting and Related Effects of Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) Compound. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022. 2022;:44-44.
https://hdl.handle.net/21.15107/rcub_dais_13643 .
Rosić, Milena, Čebela, Maria, Labus, Nebojša, "Experimental Investigation of Octahedral Tilting and Related Effects of Ca1-xGdxMnO3 (x = 0.05, 0.1, 0.15, 0.2) Compound" in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022 (2022):44-44,
https://hdl.handle.net/21.15107/rcub_dais_13643 .

Complex Metal Oxide Oxidation State Changes Monitoring by TGA and Dilatometric Means

Labus, Nebojša; Rosić, Milena; Čebela, Maria

(Belgrade : University of Belgrade, Faculty of Physical Chemistry, 2022)

TY  - CONF
AU  - Labus, Nebojša
AU  - Rosić, Milena
AU  - Čebela, Maria
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13645
AB  - Oxidation processes during metal oxide heat treatment are important events that can be monitored by the means of well-known TGA/DTA and dimensional change diagrams. Powders Mn0.63Zn0.37Fe2O4 oxide was milled in different time duration and thermal analysis techniques afterwards during heating were observed. Cation that serves this purpose well for is Mn ion that passes through Mn2+ to Mn3+ state at 360 °C by oxidation and after that from Mn4+ to Mn3+ reduction process at 580 °C. Minimal data treatment of first derivative on shrinkage for obtaining shrinkage rate diagrams and as well first derivative on thermal gravimetric diagram for obtaining differential thermal gravimetric analysis diagram enable the oxidation and reduction processes monitoring.
PB  - Belgrade : University of Belgrade, Faculty of Physical Chemistry
C3  - Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
T1  - Complex Metal Oxide Oxidation State Changes Monitoring by TGA and Dilatometric Means
SP  - 43
EP  - 43
UR  - https://hdl.handle.net/21.15107/rcub_dais_13645
ER  - 
@conference{
author = "Labus, Nebojša and Rosić, Milena and Čebela, Maria",
year = "2022",
abstract = "Oxidation processes during metal oxide heat treatment are important events that can be monitored by the means of well-known TGA/DTA and dimensional change diagrams. Powders Mn0.63Zn0.37Fe2O4 oxide was milled in different time duration and thermal analysis techniques afterwards during heating were observed. Cation that serves this purpose well for is Mn ion that passes through Mn2+ to Mn3+ state at 360 °C by oxidation and after that from Mn4+ to Mn3+ reduction process at 580 °C. Minimal data treatment of first derivative on shrinkage for obtaining shrinkage rate diagrams and as well first derivative on thermal gravimetric diagram for obtaining differential thermal gravimetric analysis diagram enable the oxidation and reduction processes monitoring.",
publisher = "Belgrade : University of Belgrade, Faculty of Physical Chemistry",
journal = "Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022",
title = "Complex Metal Oxide Oxidation State Changes Monitoring by TGA and Dilatometric Means",
pages = "43-43",
url = "https://hdl.handle.net/21.15107/rcub_dais_13645"
}
Labus, N., Rosić, M.,& Čebela, M.. (2022). Complex Metal Oxide Oxidation State Changes Monitoring by TGA and Dilatometric Means. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
Belgrade : University of Belgrade, Faculty of Physical Chemistry., 43-43.
https://hdl.handle.net/21.15107/rcub_dais_13645
Labus N, Rosić M, Čebela M. Complex Metal Oxide Oxidation State Changes Monitoring by TGA and Dilatometric Means. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022. 2022;:43-43.
https://hdl.handle.net/21.15107/rcub_dais_13645 .
Labus, Nebojša, Rosić, Milena, Čebela, Maria, "Complex Metal Oxide Oxidation State Changes Monitoring by TGA and Dilatometric Means" in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022 (2022):43-43,
https://hdl.handle.net/21.15107/rcub_dais_13645 .

Modified glycine nitrate procedure synthesis and properties of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)

Rosić, Milena; Labus, Nebojša; Čebela, Maria

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Rosić, Milena
AU  - Labus, Nebojša
AU  - Čebela, Maria
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11910
AB  - Nanocrystalline manganites Ca1-xGdxMnO3(x=0.05, 0.1, 0.15, 0.2) were synthesized by a modified glycine-nitrate procedure. The subsequent studies were focused on the structural, microstructural and magnetic changes of the starting materials induced by calcination and sintering. Thermal treatments of the green bodies were carried out by conventional sintering method. Phase evolution, lattice parameters, chemical composition and magnetic properties were monitored by Differential thermal analysis (DTA), X-ray diffraction (XRD),Induction coupled Plasma Atomic Emission (ICPES), Scanning electron Microscopy with Energy Dispersive Spectroscopy SEM/EDS and magnetic measurements on Superconducting Quantum Interference Device (Squid).DTA revealed phase transition at ≈918ºC.Chemical analysis has been done by ICPES and EDSwhich confirmed that nominal composition has been attained for all samples. XRD data were analysed by Rietveld refinement which showed that orthorhombic perovskite structure, S.G. Pnma (62), persisted with the change of Gd content, while unit cell parameters depended on the composition. Magnetic measurements show that electron doping by Gd3+ ions substantially changes CaMnO3 antiferromagnetic behavior. After introduction of Gd3+ ions, significant ferromagnetic component appears due to an emergence of double exchange interaction between Mn3+-Mn4+ ions. This resulted in appearance of a low temperature plateau in field cooled magnetization diagram as well as in hysteresis loop with the relatively high coercivity up to 2300 Oe.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Modified glycine nitrate procedure synthesis and properties of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)
SP  - 39
EP  - 40
UR  - https://hdl.handle.net/21.15107/rcub_dais_11910
ER  - 
@conference{
author = "Rosić, Milena and Labus, Nebojša and Čebela, Maria",
year = "2021",
abstract = "Nanocrystalline manganites Ca1-xGdxMnO3(x=0.05, 0.1, 0.15, 0.2) were synthesized by a modified glycine-nitrate procedure. The subsequent studies were focused on the structural, microstructural and magnetic changes of the starting materials induced by calcination and sintering. Thermal treatments of the green bodies were carried out by conventional sintering method. Phase evolution, lattice parameters, chemical composition and magnetic properties were monitored by Differential thermal analysis (DTA), X-ray diffraction (XRD),Induction coupled Plasma Atomic Emission (ICPES), Scanning electron Microscopy with Energy Dispersive Spectroscopy SEM/EDS and magnetic measurements on Superconducting Quantum Interference Device (Squid).DTA revealed phase transition at ≈918ºC.Chemical analysis has been done by ICPES and EDSwhich confirmed that nominal composition has been attained for all samples. XRD data were analysed by Rietveld refinement which showed that orthorhombic perovskite structure, S.G. Pnma (62), persisted with the change of Gd content, while unit cell parameters depended on the composition. Magnetic measurements show that electron doping by Gd3+ ions substantially changes CaMnO3 antiferromagnetic behavior. After introduction of Gd3+ ions, significant ferromagnetic component appears due to an emergence of double exchange interaction between Mn3+-Mn4+ ions. This resulted in appearance of a low temperature plateau in field cooled magnetization diagram as well as in hysteresis loop with the relatively high coercivity up to 2300 Oe.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Modified glycine nitrate procedure synthesis and properties of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)",
pages = "39-40",
url = "https://hdl.handle.net/21.15107/rcub_dais_11910"
}
Rosić, M., Labus, N.,& Čebela, M.. (2021). Modified glycine nitrate procedure synthesis and properties of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2). in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 39-40.
https://hdl.handle.net/21.15107/rcub_dais_11910
Rosić M, Labus N, Čebela M. Modified glycine nitrate procedure synthesis and properties of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2). in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:39-40.
https://hdl.handle.net/21.15107/rcub_dais_11910 .
Rosić, Milena, Labus, Nebojša, Čebela, Maria, "Modified glycine nitrate procedure synthesis and properties of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):39-40,
https://hdl.handle.net/21.15107/rcub_dais_11910 .

Experimental and theoretical study of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)

Rosić, Milena; Milivojević, Dušan; Labus, Nebojša; Čebela, Maria; Dodevski, Vladimir; Jordanov, Dragana; Stojmenović, Marija

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Rosić, Milena
AU  - Milivojević, Dušan
AU  - Labus, Nebojša
AU  - Čebela, Maria
AU  - Dodevski, Vladimir
AU  - Jordanov, Dragana
AU  - Stojmenović, Marija
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11899
AB  - Experimental and theoretical methods have been used to investigate the octahedral tilting and related effects of Ca1-xGdxMnO3(x = 0.05; 0.1; 0.15; 0.2) compound. Both methods have shown that orthorhombic-perovskite structure (space group Pnma) is the most stable form and according to Glazer's classification belongs to a-b+a- tilt system. Bond valence calculations (BVC) have shown ten additional perovskite-related modifications of the equilibrium Ca1- xGdxMnO3 structure, and their stability has been investigated as function of Gd doping. We have further studied the influence of gadolinium amount on Mn-О bond angles and distances, tilting of MnO6octahedra around all three axes and deformation due to the presence of Jahn- Teller distortion around Mn3+ cation, and calculated the amount of Mn3+ in the system. BVC approach is a simple, fast and efficient way of calculating the amount of Mn4+ and Mn3+ in the doped perovskite compound, which, to the best of our knowledge, has not been done before. The infrared reflection spectra of Ca1-xGdxMnO3 samples confirmed XRD results that Ca1-xGdxMnO3 nanopowders are of Pnma-1 structure and that the tilting of octahedra are increased with Gd doping. The EPR (electron paramagnetic resonance) spectra are in accordance with the assumption that EPR line width is Mn-O-Mn angle dependent. The studied samples showed that small octahedra tilting in these samples brought only a small change of the EPR line width.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Experimental and theoretical study of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)
SP  - 70
EP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_dais_11899
ER  - 
@conference{
author = "Rosić, Milena and Milivojević, Dušan and Labus, Nebojša and Čebela, Maria and Dodevski, Vladimir and Jordanov, Dragana and Stojmenović, Marija",
year = "2021",
abstract = "Experimental and theoretical methods have been used to investigate the octahedral tilting and related effects of Ca1-xGdxMnO3(x = 0.05; 0.1; 0.15; 0.2) compound. Both methods have shown that orthorhombic-perovskite structure (space group Pnma) is the most stable form and according to Glazer's classification belongs to a-b+a- tilt system. Bond valence calculations (BVC) have shown ten additional perovskite-related modifications of the equilibrium Ca1- xGdxMnO3 structure, and their stability has been investigated as function of Gd doping. We have further studied the influence of gadolinium amount on Mn-О bond angles and distances, tilting of MnO6octahedra around all three axes and deformation due to the presence of Jahn- Teller distortion around Mn3+ cation, and calculated the amount of Mn3+ in the system. BVC approach is a simple, fast and efficient way of calculating the amount of Mn4+ and Mn3+ in the doped perovskite compound, which, to the best of our knowledge, has not been done before. The infrared reflection spectra of Ca1-xGdxMnO3 samples confirmed XRD results that Ca1-xGdxMnO3 nanopowders are of Pnma-1 structure and that the tilting of octahedra are increased with Gd doping. The EPR (electron paramagnetic resonance) spectra are in accordance with the assumption that EPR line width is Mn-O-Mn angle dependent. The studied samples showed that small octahedra tilting in these samples brought only a small change of the EPR line width.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Experimental and theoretical study of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_dais_11899"
}
Rosić, M., Milivojević, D., Labus, N., Čebela, M., Dodevski, V., Jordanov, D.,& Stojmenović, M.. (2021). Experimental and theoretical study of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2). in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 70-70.
https://hdl.handle.net/21.15107/rcub_dais_11899
Rosić M, Milivojević D, Labus N, Čebela M, Dodevski V, Jordanov D, Stojmenović M. Experimental and theoretical study of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2). in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:70-70.
https://hdl.handle.net/21.15107/rcub_dais_11899 .
Rosić, Milena, Milivojević, Dušan, Labus, Nebojša, Čebela, Maria, Dodevski, Vladimir, Jordanov, Dragana, Stojmenović, Marija, "Experimental and theoretical study of nanostructured Ca1-xGdxMnO3 (x=0.05; 0.1; 0.15; 0.2)" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):70-70,
https://hdl.handle.net/21.15107/rcub_dais_11899 .

Solvent effects on structural changes in self-healing epoxy composites

Radović, Ivana; Stajčić, Aleksandar; Radisavljević, Andjela; Veljković, Filip; Čebela, Maria; Mitić, Vojislav V.; Radojević, Vesna

(Elsevier, 2020)

TY  - JOUR
AU  - Radović, Ivana
AU  - Stajčić, Aleksandar
AU  - Radisavljević, Andjela
AU  - Veljković, Filip
AU  - Čebela, Maria
AU  - Mitić, Vojislav V.
AU  - Radojević, Vesna
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/9539
AB  - Nowadays, there is a very high importance of composite research and variety of their applications in the modern world. In that sense, we researched hollow glass capillaries filled with dissolved Grubbs catalyst (GC) and dicyclopentadiene (DCPD) were incorporated into a fiber-reinforced epoxy with the aim of improving the flow of healing agents to the crack site. The morphological investigation of the crack site was performed using field emission scanning electron microscopy (FESEM), showing the difference between the samples depending on the used solvent. The software analysis of sample photographs has been performed by calculating the fractured/ healed surface area of the samples, revealing that approximately 20% of the volume was affected by the impact. Fourier transform infrared spectroscopy (FTIR) revealed that poly (dicyclopentadiene) (PDCPD) formed at the healed interface. However, the FTIR investigation of catalyst stability in different solvents showed structural changes in GC and partial deactivation. The mechanical tests of the samples showed that a recovery of 60% after 24 h at room temperature could be achieved through the use of a solvent and very low concentration of GC. The performed research results are a good base to develop the model for predicting the processes and morphology, with the goal to design the final mechanical and in the future, thermal, properties in advance. This opens a new direction for future research in the field of composite healing.
PB  - Elsevier
T2  - Materials Chemistry and Physics
T1  - Solvent effects on structural changes in self-healing epoxy composites
SP  - 123761
VL  - 256
DO  - 10.1016/j.matchemphys.2020.123761
UR  - https://hdl.handle.net/21.15107/rcub_dais_9539
ER  - 
@article{
author = "Radović, Ivana and Stajčić, Aleksandar and Radisavljević, Andjela and Veljković, Filip and Čebela, Maria and Mitić, Vojislav V. and Radojević, Vesna",
year = "2020",
abstract = "Nowadays, there is a very high importance of composite research and variety of their applications in the modern world. In that sense, we researched hollow glass capillaries filled with dissolved Grubbs catalyst (GC) and dicyclopentadiene (DCPD) were incorporated into a fiber-reinforced epoxy with the aim of improving the flow of healing agents to the crack site. The morphological investigation of the crack site was performed using field emission scanning electron microscopy (FESEM), showing the difference between the samples depending on the used solvent. The software analysis of sample photographs has been performed by calculating the fractured/ healed surface area of the samples, revealing that approximately 20% of the volume was affected by the impact. Fourier transform infrared spectroscopy (FTIR) revealed that poly (dicyclopentadiene) (PDCPD) formed at the healed interface. However, the FTIR investigation of catalyst stability in different solvents showed structural changes in GC and partial deactivation. The mechanical tests of the samples showed that a recovery of 60% after 24 h at room temperature could be achieved through the use of a solvent and very low concentration of GC. The performed research results are a good base to develop the model for predicting the processes and morphology, with the goal to design the final mechanical and in the future, thermal, properties in advance. This opens a new direction for future research in the field of composite healing.",
publisher = "Elsevier",
journal = "Materials Chemistry and Physics",
title = "Solvent effects on structural changes in self-healing epoxy composites",
pages = "123761",
volume = "256",
doi = "10.1016/j.matchemphys.2020.123761",
url = "https://hdl.handle.net/21.15107/rcub_dais_9539"
}
Radović, I., Stajčić, A., Radisavljević, A., Veljković, F., Čebela, M., Mitić, V. V.,& Radojević, V.. (2020). Solvent effects on structural changes in self-healing epoxy composites. in Materials Chemistry and Physics
Elsevier., 256, 123761.
https://doi.org/10.1016/j.matchemphys.2020.123761
https://hdl.handle.net/21.15107/rcub_dais_9539
Radović I, Stajčić A, Radisavljević A, Veljković F, Čebela M, Mitić VV, Radojević V. Solvent effects on structural changes in self-healing epoxy composites. in Materials Chemistry and Physics. 2020;256:123761.
doi:10.1016/j.matchemphys.2020.123761
https://hdl.handle.net/21.15107/rcub_dais_9539 .
Radović, Ivana, Stajčić, Aleksandar, Radisavljević, Andjela, Veljković, Filip, Čebela, Maria, Mitić, Vojislav V., Radojević, Vesna, "Solvent effects on structural changes in self-healing epoxy composites" in Materials Chemistry and Physics, 256 (2020):123761,
https://doi.org/10.1016/j.matchemphys.2020.123761 .,
https://hdl.handle.net/21.15107/rcub_dais_9539 .
16
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Theoretical and experimental study of polycrystalline phases obtained by the nanometric ZnTiO3 powder sintering

Labus, Nebojša; Rosić, Milena; Čebela, Maria; Jordanov, Dragana; Dodevski, Dragan; Radović, Ivana

(Belgrade : Institute for Multidisciplinary Research, 2019)

TY  - CONF
AU  - Labus, Nebojša
AU  - Rosić, Milena
AU  - Čebela, Maria
AU  - Jordanov, Dragana
AU  - Dodevski, Dragan
AU  - Radović, Ivana
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7001
AB  - In this study we have combined two research methods: structure prediction of ZnTiO3 using computational SPuDS software, and the characterization of binary oxides obtained from ZnO TiO2 system. Pure nanosized ZnTiO3 (99.5%), was compacted in cylindrical shape specimens by uniaxial double sided compaction and then sintered in air atmosphere in a dilatometric device [1,2]. One compact was sintered up to 915 °C to retain metastabile ZnTiO3 and held 5 minutes on that temperature, and another one at the same conditions, but now up to 970 °C to induce phase transition and to obtain stabile Zn2TiO4 and TiO2 according to phase diagram [2]. Reheated samples obtained at different characteristic temperatures in air were analyzed by X-ray diffraction (XRD). The infrared attenuated total reflectivity measurements confirmed XRD results. In order to estimate theoretical stability of these perovskite structure, Goldschmidt tolerance factor Gt and global instability index GII were calculated. Furthermore, the Ti valence states were determined by bond valence calculations (BVC). Also, we have investigated the formation of new phases (Zn2Ti3O8, TiO2 and Zn2TiO4) originating from ZnTiO3 with temperature change, as well as the relation between the crystal structures which have been predicted and the structure of the phases we have experimentally observed.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - Theoretical and experimental study of polycrystalline phases obtained by the nanometric ZnTiO3 powder sintering
SP  - 110
EP  - 110
UR  - https://hdl.handle.net/21.15107/rcub_dais_7001
ER  - 
@conference{
author = "Labus, Nebojša and Rosić, Milena and Čebela, Maria and Jordanov, Dragana and Dodevski, Dragan and Radović, Ivana",
year = "2019",
abstract = "In this study we have combined two research methods: structure prediction of ZnTiO3 using computational SPuDS software, and the characterization of binary oxides obtained from ZnO TiO2 system. Pure nanosized ZnTiO3 (99.5%), was compacted in cylindrical shape specimens by uniaxial double sided compaction and then sintered in air atmosphere in a dilatometric device [1,2]. One compact was sintered up to 915 °C to retain metastabile ZnTiO3 and held 5 minutes on that temperature, and another one at the same conditions, but now up to 970 °C to induce phase transition and to obtain stabile Zn2TiO4 and TiO2 according to phase diagram [2]. Reheated samples obtained at different characteristic temperatures in air were analyzed by X-ray diffraction (XRD). The infrared attenuated total reflectivity measurements confirmed XRD results. In order to estimate theoretical stability of these perovskite structure, Goldschmidt tolerance factor Gt and global instability index GII were calculated. Furthermore, the Ti valence states were determined by bond valence calculations (BVC). Also, we have investigated the formation of new phases (Zn2Ti3O8, TiO2 and Zn2TiO4) originating from ZnTiO3 with temperature change, as well as the relation between the crystal structures which have been predicted and the structure of the phases we have experimentally observed.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "Theoretical and experimental study of polycrystalline phases obtained by the nanometric ZnTiO3 powder sintering",
pages = "110-110",
url = "https://hdl.handle.net/21.15107/rcub_dais_7001"
}
Labus, N., Rosić, M., Čebela, M., Jordanov, D., Dodevski, D.,& Radović, I.. (2019). Theoretical and experimental study of polycrystalline phases obtained by the nanometric ZnTiO3 powder sintering. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 110-110.
https://hdl.handle.net/21.15107/rcub_dais_7001
Labus N, Rosić M, Čebela M, Jordanov D, Dodevski D, Radović I. Theoretical and experimental study of polycrystalline phases obtained by the nanometric ZnTiO3 powder sintering. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:110-110.
https://hdl.handle.net/21.15107/rcub_dais_7001 .
Labus, Nebojša, Rosić, Milena, Čebela, Maria, Jordanov, Dragana, Dodevski, Dragan, Radović, Ivana, "Theoretical and experimental study of polycrystalline phases obtained by the nanometric ZnTiO3 powder sintering" in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):110-110,
https://hdl.handle.net/21.15107/rcub_dais_7001 .

Comprehensive characterization of BiFeO3 powder synthesized by the hydrothermal procedure

Čebela, Maria; Janković, Bojan; Hercigonja, Radmila; Lukić, Miodrag J.; Dohčević-Mitrović, Zorana; Milivojević, Dušan; Matović, Branko

(Novi Sad Faculty of Technology, University of Novi Sad, 2016)

TY  - JOUR
AU  - Čebela, Maria
AU  - Janković, Bojan
AU  - Hercigonja, Radmila
AU  - Lukić, Miodrag J.
AU  - Dohčević-Mitrović, Zorana
AU  - Milivojević, Dušan
AU  - Matović, Branko
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/15964
AB  - In this paper, bismuth ferrite (BFO) particles synthesized by controlled hydrothermal process, where the particles of small sizes and with high purity were obtained. Structural analysis showed that non-annealed powder can be perfectly fitted to rhombohedral space group R3c and contains a very small amount of secondary phase, whereas the final product (annealed at 800 °C) represents single-phase perovskite powder with high crystallinity. HRTEM analysis confirmed existence of twin stacking faults, which are responsible for enhanced magnetic properties. EPR measurements suggested existence of electrons trapped by vacancies or defects. It has been proposed that existence of Fe3+ −OV defect complex could be generated at elevated temperatures followed by formation of trivalent Fe ions, which intensely provide local 3d moments.
PB  - Novi Sad Faculty of Technology, University of Novi Sad
T2  - Processing and Application of Ceramics
T1  - Comprehensive characterization of BiFeO3 powder synthesized by the hydrothermal procedure
SP  - 201
EP  - 208
VL  - 10
IS  - 4
DO  - 10.2298/PAC1604201C
UR  - https://hdl.handle.net/21.15107/rcub_dais_15964
ER  - 
@article{
author = "Čebela, Maria and Janković, Bojan and Hercigonja, Radmila and Lukić, Miodrag J. and Dohčević-Mitrović, Zorana and Milivojević, Dušan and Matović, Branko",
year = "2016",
abstract = "In this paper, bismuth ferrite (BFO) particles synthesized by controlled hydrothermal process, where the particles of small sizes and with high purity were obtained. Structural analysis showed that non-annealed powder can be perfectly fitted to rhombohedral space group R3c and contains a very small amount of secondary phase, whereas the final product (annealed at 800 °C) represents single-phase perovskite powder with high crystallinity. HRTEM analysis confirmed existence of twin stacking faults, which are responsible for enhanced magnetic properties. EPR measurements suggested existence of electrons trapped by vacancies or defects. It has been proposed that existence of Fe3+ −OV defect complex could be generated at elevated temperatures followed by formation of trivalent Fe ions, which intensely provide local 3d moments.",
publisher = "Novi Sad Faculty of Technology, University of Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Comprehensive characterization of BiFeO3 powder synthesized by the hydrothermal procedure",
pages = "201-208",
volume = "10",
number = "4",
doi = "10.2298/PAC1604201C",
url = "https://hdl.handle.net/21.15107/rcub_dais_15964"
}
Čebela, M., Janković, B., Hercigonja, R., Lukić, M. J., Dohčević-Mitrović, Z., Milivojević, D.,& Matović, B.. (2016). Comprehensive characterization of BiFeO3 powder synthesized by the hydrothermal procedure. in Processing and Application of Ceramics
Novi Sad Faculty of Technology, University of Novi Sad., 10(4), 201-208.
https://doi.org/10.2298/PAC1604201C
https://hdl.handle.net/21.15107/rcub_dais_15964
Čebela M, Janković B, Hercigonja R, Lukić MJ, Dohčević-Mitrović Z, Milivojević D, Matović B. Comprehensive characterization of BiFeO3 powder synthesized by the hydrothermal procedure. in Processing and Application of Ceramics. 2016;10(4):201-208.
doi:10.2298/PAC1604201C
https://hdl.handle.net/21.15107/rcub_dais_15964 .
Čebela, Maria, Janković, Bojan, Hercigonja, Radmila, Lukić, Miodrag J., Dohčević-Mitrović, Zorana, Milivojević, Dušan, Matović, Branko, "Comprehensive characterization of BiFeO3 powder synthesized by the hydrothermal procedure" in Processing and Application of Ceramics, 10, no. 4 (2016):201-208,
https://doi.org/10.2298/PAC1604201C .,
https://hdl.handle.net/21.15107/rcub_dais_15964 .
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