Obradović, Nina

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Authority KeyName Variants
orcid::0000-0002-7993-293X
  • Obradović, Nina (183)
  • Obradović, Nina N. (1)
Projects
Directed synthesis, structure and properties of multifunctional materials Investigation of the relation in triad: Synthesis structure-properties for functional materials
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) Ministry of Education, Youth and Sports (MEYS) of Czech Republic - CEITEC 2020 [LQ1601]
Development and application of multifunctional materials using domestic raw materials in upgraded processing lines United States National Aeronautics and Space Administration (NASA), Grant NNX09AV07A
Serbian Academy of Sciences and Arts, Project F-198 Synthesis, processing and applications of nanostructured multifunctional materials with defined properties
Algorithms and software for frequency-domain and time-domain simulations of RF subsystems and electromagnetic sensors in ICT Serbian Academy of Sciences and Arts, Project F-133
United States National Science Foundation (NSF) / Centers of Research Excellence in Science and Technology (CREST), Grant HRD-0833184 United States National Science Foundation (NSF) / Partnerships for Research and Education in Materials (PREM), Grant 1523617
Bilateral cooperation between Serbia and France, No. 4510339/2016/09/03 “Inteligent econanomaterials and nanocomposites” Grant Agency of the Czech Republic, Project 15-06390S
Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing National Science Foundation, North Carolina State University, Project No. HRD-1345219
Czech Science Foundation (GACR) - 17-05620S Investigation of intermetallics and semiconductors and possible application in renewable energy sources
Geologic and ecotoxicologic research in identification of geopathogen zones of toxic elements in drinking water reservoirs- research into methods and procedures for reduction of biochemical anomalies Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Brno University of Technology - BUT Internal Projects: STI-J-18-5456, Czechia CEITEC Nano RI, MEYS CR, 2016–2019
CONACYT grant 2018-000022-01EXTV-00188, Mexico DAAD scholarship project "Development of materials and manufacturing technologies for electric discharge machinable Zirconia–CNT/Graphene composites"
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200131 (University of Belgrade, Technical Faculty, Bor)
Innovative electronic components and systems based on inorganic and organic technologies embedded in consumer goods and products Serbian Academy of Sciences and Arts, Project F-7/II
Austrian Federal Funding Agency (FFG), MagnetoPIM (programme CIR-CE - Cooperation in Innovation and Research with Central and Eastern Europe) European Regional Development Fund through a project CEITEC, CZ.1.05/1.1.00/02.0068

Author's Bibliography

High-Precision Method of Moments Applied to Measurement of Dielectric Parameters at Microwave Frequencies

Petrović, Jovana G.; Olćan, Dragan I.; Obradović, Nina N.; Đorđević, Antonije R.

(Institute of Electrical and Electronics Engineers (IEEE), 2021)

TY  - JOUR
AU  - Petrović, Jovana G.
AU  - Olćan, Dragan I.
AU  - Obradović, Nina N.
AU  - Đorđević, Antonije R.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12534
AB  - A novel high-precision model of a custom-made coaxial chamber used for broadband measurement of the relative complex permittivity at microwave frequencies is presented. The model is based on a surface integral-equation formulation of the method of moments tailored for bodies of revolution. All singular integrals encountered in the numerical analysis are calculated in a unified way with a novel integral transformation, which enables the precision of up to 12 significant digits using the 64-bit representation of real numbers. The dielectric parameters are estimated from the reflection-coefficient measurement of the chamber with a disk-shaped dielectric sample by comparison of the measured data with the high-precision numerical analysis of the chamber. The complete measurement procedure is illustrated and verified using samples of known dielectric properties.
PB  - Institute of Electrical and Electronics Engineers (IEEE)
T2  - IEEE Transactions on Microwave Theory and Techniques
T1  - High-Precision Method of Moments Applied to Measurement of Dielectric Parameters at Microwave Frequencies
DO  - 10.1109/TMTT.2021.3136294
UR  - https://hdl.handle.net/21.15107/rcub_dais_12534
ER  - 
@article{
author = "Petrović, Jovana G. and Olćan, Dragan I. and Obradović, Nina N. and Đorđević, Antonije R.",
year = "2021",
abstract = "A novel high-precision model of a custom-made coaxial chamber used for broadband measurement of the relative complex permittivity at microwave frequencies is presented. The model is based on a surface integral-equation formulation of the method of moments tailored for bodies of revolution. All singular integrals encountered in the numerical analysis are calculated in a unified way with a novel integral transformation, which enables the precision of up to 12 significant digits using the 64-bit representation of real numbers. The dielectric parameters are estimated from the reflection-coefficient measurement of the chamber with a disk-shaped dielectric sample by comparison of the measured data with the high-precision numerical analysis of the chamber. The complete measurement procedure is illustrated and verified using samples of known dielectric properties.",
publisher = "Institute of Electrical and Electronics Engineers (IEEE)",
journal = "IEEE Transactions on Microwave Theory and Techniques",
title = "High-Precision Method of Moments Applied to Measurement of Dielectric Parameters at Microwave Frequencies",
doi = "10.1109/TMTT.2021.3136294",
url = "https://hdl.handle.net/21.15107/rcub_dais_12534"
}
Petrović, J. G., Olćan, D. I., Obradović, N. N.,& Đorđević, A. R.. (2021). High-Precision Method of Moments Applied to Measurement of Dielectric Parameters at Microwave Frequencies. in IEEE Transactions on Microwave Theory and Techniques
Institute of Electrical and Electronics Engineers (IEEE)..
https://doi.org/10.1109/TMTT.2021.3136294
https://hdl.handle.net/21.15107/rcub_dais_12534
Petrović JG, Olćan DI, Obradović NN, Đorđević AR. High-Precision Method of Moments Applied to Measurement of Dielectric Parameters at Microwave Frequencies. in IEEE Transactions on Microwave Theory and Techniques. 2021;.
doi:10.1109/TMTT.2021.3136294
https://hdl.handle.net/21.15107/rcub_dais_12534 .
Petrović, Jovana G., Olćan, Dragan I., Obradović, Nina N., Đorđević, Antonije R., "High-Precision Method of Moments Applied to Measurement of Dielectric Parameters at Microwave Frequencies" in IEEE Transactions on Microwave Theory and Techniques (2021),
https://doi.org/10.1109/TMTT.2021.3136294 .,
https://hdl.handle.net/21.15107/rcub_dais_12534 .

Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions

Obradović, Nina; Fahrenholtz, William G.; Corlett, Cole; Filipović, Suzana; Nikolić, Marko; Marinković, Bojan A.; Failla, Simone; Sciti, Diletta; Di Rosa, Daniele; Sani, Elisa

(Basel : MDPI AG, 2021)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Corlett, Cole
AU  - Filipović, Suzana
AU  - Nikolić, Marko
AU  - Marinković, Bojan A.
AU  - Failla, Simone
AU  - Sciti, Diletta
AU  - Di Rosa, Daniele
AU  - Sani, Elisa
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12431
AB  - Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by a solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation for 30 min in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray powder diffraction and scanning electron microscopy. Rietveld analysis revealed 100% pure spinel phase in all sintered specimens, and a decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6% relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve densification of MgAl2O4 prepared from mixed oxide powders, while additives improve microstructure and optical properties.
PB  - Basel : MDPI AG
T2  - Materials
T1  - Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions
SP  - 7674
VL  - 14
IS  - 24
DO  - 10.3390/ma14247674
UR  - https://hdl.handle.net/21.15107/rcub_dais_12431
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Corlett, Cole and Filipović, Suzana and Nikolić, Marko and Marinković, Bojan A. and Failla, Simone and Sciti, Diletta and Di Rosa, Daniele and Sani, Elisa",
year = "2021",
abstract = "Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by a solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation for 30 min in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray powder diffraction and scanning electron microscopy. Rietveld analysis revealed 100% pure spinel phase in all sintered specimens, and a decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6% relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve densification of MgAl2O4 prepared from mixed oxide powders, while additives improve microstructure and optical properties.",
publisher = "Basel : MDPI AG",
journal = "Materials",
title = "Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions",
pages = "7674",
volume = "14",
number = "24",
doi = "10.3390/ma14247674",
url = "https://hdl.handle.net/21.15107/rcub_dais_12431"
}
Obradović, N., Fahrenholtz, W. G., Corlett, C., Filipović, S., Nikolić, M., Marinković, B. A., Failla, S., Sciti, D., Di Rosa, D.,& Sani, E.. (2021). Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions. in Materials
Basel : MDPI AG., 14(24), 7674.
https://doi.org/10.3390/ma14247674
https://hdl.handle.net/21.15107/rcub_dais_12431
Obradović N, Fahrenholtz WG, Corlett C, Filipović S, Nikolić M, Marinković BA, Failla S, Sciti D, Di Rosa D, Sani E. Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions. in Materials. 2021;14(24):7674.
doi:10.3390/ma14247674
https://hdl.handle.net/21.15107/rcub_dais_12431 .
Obradović, Nina, Fahrenholtz, William G., Corlett, Cole, Filipović, Suzana, Nikolić, Marko, Marinković, Bojan A., Failla, Simone, Sciti, Diletta, Di Rosa, Daniele, Sani, Elisa, "Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions" in Materials, 14, no. 24 (2021):7674,
https://doi.org/10.3390/ma14247674 .,
https://hdl.handle.net/21.15107/rcub_dais_12431 .
2

High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters

Đorđević, Antonije; Olćan, Dragan; Petrović, Jovana; Obradović, Nina; Filipović, Suzana

(National Library of Serbia, 2021)

TY  - JOUR
AU  - Đorđević, Antonije
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Obradović, Nina
AU  - Filipović, Suzana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12341
AB  - We have developed rotationally symmetrical coaxial chambers for measurements of dielectric parameters of disk-shaped samples, in the frequency range from 1 MHz to several hundred MHz. The reflection coefficient of the chamber is measured and the dielectric parameters are hence extracted utilizing a high-accuracy quasistatic numerical model of the chamber and the sample. We present this model, which is based on the method-of-moments solution of a set of integral equations for composite metallic and dielectric bodies. The equations are tailored to bodies of revolution. The model is efficient and accurate so that the major contribution of the measurement uncertainty comes from the measurement hardware.
PB  - National Library of Serbia
T2  - Facta universitatis - series: Electronics and Energetics
T1  - High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters
SP  - 141
EP  - 156
VL  - 34
IS  - 1
DO  - 10.2298/FUEE2101141D
UR  - https://hdl.handle.net/21.15107/rcub_dais_12341
ER  - 
@article{
author = "Đorđević, Antonije and Olćan, Dragan and Petrović, Jovana and Obradović, Nina and Filipović, Suzana",
year = "2021",
abstract = "We have developed rotationally symmetrical coaxial chambers for measurements of dielectric parameters of disk-shaped samples, in the frequency range from 1 MHz to several hundred MHz. The reflection coefficient of the chamber is measured and the dielectric parameters are hence extracted utilizing a high-accuracy quasistatic numerical model of the chamber and the sample. We present this model, which is based on the method-of-moments solution of a set of integral equations for composite metallic and dielectric bodies. The equations are tailored to bodies of revolution. The model is efficient and accurate so that the major contribution of the measurement uncertainty comes from the measurement hardware.",
publisher = "National Library of Serbia",
journal = "Facta universitatis - series: Electronics and Energetics",
title = "High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters",
pages = "141-156",
volume = "34",
number = "1",
doi = "10.2298/FUEE2101141D",
url = "https://hdl.handle.net/21.15107/rcub_dais_12341"
}
Đorđević, A., Olćan, D., Petrović, J., Obradović, N.,& Filipović, S.. (2021). High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters. in Facta universitatis - series: Electronics and Energetics
National Library of Serbia., 34(1), 141-156.
https://doi.org/10.2298/FUEE2101141D
https://hdl.handle.net/21.15107/rcub_dais_12341
Đorđević A, Olćan D, Petrović J, Obradović N, Filipović S. High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters. in Facta universitatis - series: Electronics and Energetics. 2021;34(1):141-156.
doi:10.2298/FUEE2101141D
https://hdl.handle.net/21.15107/rcub_dais_12341 .
Đorđević, Antonije, Olćan, Dragan, Petrović, Jovana, Obradović, Nina, Filipović, Suzana, "High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters" in Facta universitatis - series: Electronics and Energetics, 34, no. 1 (2021):141-156,
https://doi.org/10.2298/FUEE2101141D .,
https://hdl.handle.net/21.15107/rcub_dais_12341 .

Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time

Đorđević, Nataša; Peleš, Adriana; Obradović, Nina; Vlahović, Milica; Mihajlović, Slavica; Martinović, Sanja

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS, 2021)

TY  - CONF
AU  - Đorđević, Nataša
AU  - Peleš, Adriana
AU  - Obradović, Nina
AU  - Vlahović, Milica
AU  - Mihajlović, Slavica
AU  - Martinović, Sanja
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12355
AB  - The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties.
AB  - Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS
C3  - Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
T1  - Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time
T1  - Električna svojstva izotermski sinterovane keramike na bazi kordierita kao funkcija vremena sinterovanja i aktivacije
SP  - 269
EP  - 272
UR  - https://hdl.handle.net/21.15107/rcub_dais_12355
ER  - 
@conference{
author = "Đorđević, Nataša and Peleš, Adriana and Obradović, Nina and Vlahović, Milica and Mihajlović, Slavica and Martinović, Sanja",
year = "2021",
abstract = "The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties., Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS",
journal = "Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021",
title = "Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time, Električna svojstva izotermski sinterovane keramike na bazi kordierita kao funkcija vremena sinterovanja i aktivacije",
pages = "269-272",
url = "https://hdl.handle.net/21.15107/rcub_dais_12355"
}
Đorđević, N., Peleš, A., Obradović, N., Vlahović, M., Mihajlović, S.,& Martinović, S.. (2021). Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS., 269-272.
https://hdl.handle.net/21.15107/rcub_dais_12355
Đorđević N, Peleš A, Obradović N, Vlahović M, Mihajlović S, Martinović S. Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021. 2021;:269-272.
https://hdl.handle.net/21.15107/rcub_dais_12355 .
Đorđević, Nataša, Peleš, Adriana, Obradović, Nina, Vlahović, Milica, Mihajlović, Slavica, Martinović, Sanja, "Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time" in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021 (2021):269-272,
https://hdl.handle.net/21.15107/rcub_dais_12355 .

Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics

Đorđević, Nataša; Peleš, Adriana; Obradović, Nina; Vlahović, Milica; Mihajlović, Slavica; Martinović, Sanja

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS, 2021)

TY  - CONF
AU  - Đorđević, Nataša
AU  - Peleš, Adriana
AU  - Obradović, Nina
AU  - Vlahović, Milica
AU  - Mihajlović, Slavica
AU  - Martinović, Sanja
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12354
AB  - The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties.
AB  - Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS
C3  - Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
T1  - Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics
T1  - Uticaj vremena sinterovanja na gustinu i SEM analiza kordijeritne keramike
SP  - 265
EP  - 268
UR  - https://hdl.handle.net/21.15107/rcub_dais_12354
ER  - 
@conference{
author = "Đorđević, Nataša and Peleš, Adriana and Obradović, Nina and Vlahović, Milica and Mihajlović, Slavica and Martinović, Sanja",
year = "2021",
abstract = "The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties., Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS",
journal = "Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021",
title = "Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics, Uticaj vremena sinterovanja na gustinu i SEM analiza kordijeritne keramike",
pages = "265-268",
url = "https://hdl.handle.net/21.15107/rcub_dais_12354"
}
Đorđević, N., Peleš, A., Obradović, N., Vlahović, M., Mihajlović, S.,& Martinović, S.. (2021). Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS., 265-268.
https://hdl.handle.net/21.15107/rcub_dais_12354
Đorđević N, Peleš A, Obradović N, Vlahović M, Mihajlović S, Martinović S. Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021. 2021;:265-268.
https://hdl.handle.net/21.15107/rcub_dais_12354 .
Đorđević, Nataša, Peleš, Adriana, Obradović, Nina, Vlahović, Milica, Mihajlović, Slavica, Martinović, Sanja, "Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics" in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021 (2021):265-268,
https://hdl.handle.net/21.15107/rcub_dais_12354 .

Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems

Obradović, Nina; Filipović, Suzana; Gilli, N.; Silvestroni, L.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Gilli, N.
AU  - Silvestroni, L.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12352
AB  - ZrB2 ceramics are considered potential materials for hypersonic systems in view of the melting point exceeding 3000 °C and excellent ablation resistance. Second phases, including SiC or CrB2, further improve the oxidation behavior, whereas a lighter phase, like TiB2 can decrease the overall weight. In this work, a powder mixture containing ZrB2, TiB2, CrB2 and SiC was mechanically activated using high energy ball-milling. Sintering was performed by hot pressing following different thermal cycles, and subsequent annealing to remove oxide phases and reduce micro-cracking. The microstructure and hardness of the dense ceramics are compared in relationship to the thermal history. Fully dense ceramics were obtained with different oxide-phases amount depending on the sintering cycle and hardness approaching 24 GPa were achieved. Future works will explore the strength and oxidation resistance of this multi-phase system to check its suitability for hypersonic systems.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems
SP  - 83
EP  - 83
UR  - https://hdl.handle.net/21.15107/rcub_dais_12352
ER  - 
@conference{
author = "Obradović, Nina and Filipović, Suzana and Gilli, N. and Silvestroni, L.",
year = "2021",
abstract = "ZrB2 ceramics are considered potential materials for hypersonic systems in view of the melting point exceeding 3000 °C and excellent ablation resistance. Second phases, including SiC or CrB2, further improve the oxidation behavior, whereas a lighter phase, like TiB2 can decrease the overall weight. In this work, a powder mixture containing ZrB2, TiB2, CrB2 and SiC was mechanically activated using high energy ball-milling. Sintering was performed by hot pressing following different thermal cycles, and subsequent annealing to remove oxide phases and reduce micro-cracking. The microstructure and hardness of the dense ceramics are compared in relationship to the thermal history. Fully dense ceramics were obtained with different oxide-phases amount depending on the sintering cycle and hardness approaching 24 GPa were achieved. Future works will explore the strength and oxidation resistance of this multi-phase system to check its suitability for hypersonic systems.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems",
pages = "83-83",
url = "https://hdl.handle.net/21.15107/rcub_dais_12352"
}
Obradović, N., Filipović, S., Gilli, N.,& Silvestroni, L.. (2021). Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 83-83.
https://hdl.handle.net/21.15107/rcub_dais_12352
Obradović N, Filipović S, Gilli N, Silvestroni L. Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:83-83.
https://hdl.handle.net/21.15107/rcub_dais_12352 .
Obradović, Nina, Filipović, Suzana, Gilli, N., Silvestroni, L., "Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):83-83,
https://hdl.handle.net/21.15107/rcub_dais_12352 .

Measurement of dielectric permitivity using coaxial chambers and electromagnetic-modeling software

Obradović, Nina; Peleš, Adriana; Olćan, Dragan; Fahrenholtz, William G.; Đorđević, Antonije; Pavlović, Vladimir B.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Peleš, Adriana
AU  - Olćan, Dragan
AU  - Fahrenholtz, William G.
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12351
AB  - Our research group has developed a method for measurement of complex relative permittivity of various dielectric materials in the frequency range from around 1 kHz up to several GHz. Material samples have preferably a disk shape. The thicknesses of the samples can be in a wide range, from about 10 μm (thick films) up to several mm. We have designed and manufactured a set of coaxial chambers, which we use as test fixtures. We have also developed two numerical-simulation programs for the electromagnetic analysis of bodies with rotational symmetry. One program is suitable for the low-frequency analysis. It is based on an electrostatic approach. The other program is based on an electrodynamic approach and it is tailored for microwave frequencies. In measurements, we use impedance meters and network analyzers to obtain the input impedance of a chamber with a sample. Thereafter, we implement our software for the electromagnetic modeling to extract the relative permittivity of the measured sample. As examples of verification of our method, we present here results for the relative permittivities of two sets of samples whose sizes are on the extreme limits of the method. The first set comprises poly (vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films, whose relative permittivities are around 1.8. The second set comprises large, high-density samples of spinel (aluminum magnesium oxide) ceramics, sintered under various conditions. The measured relative permittivities of these samples are around 7.5. In all cases, good agreement with other available data has been obtained.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - Measurement of dielectric permitivity using coaxial chambers and electromagnetic-modeling software
SP  - 82
EP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_dais_12351
ER  - 
@conference{
author = "Obradović, Nina and Peleš, Adriana and Olćan, Dragan and Fahrenholtz, William G. and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2021",
abstract = "Our research group has developed a method for measurement of complex relative permittivity of various dielectric materials in the frequency range from around 1 kHz up to several GHz. Material samples have preferably a disk shape. The thicknesses of the samples can be in a wide range, from about 10 μm (thick films) up to several mm. We have designed and manufactured a set of coaxial chambers, which we use as test fixtures. We have also developed two numerical-simulation programs for the electromagnetic analysis of bodies with rotational symmetry. One program is suitable for the low-frequency analysis. It is based on an electrostatic approach. The other program is based on an electrodynamic approach and it is tailored for microwave frequencies. In measurements, we use impedance meters and network analyzers to obtain the input impedance of a chamber with a sample. Thereafter, we implement our software for the electromagnetic modeling to extract the relative permittivity of the measured sample. As examples of verification of our method, we present here results for the relative permittivities of two sets of samples whose sizes are on the extreme limits of the method. The first set comprises poly (vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films, whose relative permittivities are around 1.8. The second set comprises large, high-density samples of spinel (aluminum magnesium oxide) ceramics, sintered under various conditions. The measured relative permittivities of these samples are around 7.5. In all cases, good agreement with other available data has been obtained.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "Measurement of dielectric permitivity using coaxial chambers and electromagnetic-modeling software",
pages = "82-82",
url = "https://hdl.handle.net/21.15107/rcub_dais_12351"
}
Obradović, N., Peleš, A., Olćan, D., Fahrenholtz, W. G., Đorđević, A.,& Pavlović, V. B.. (2021). Measurement of dielectric permitivity using coaxial chambers and electromagnetic-modeling software. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 82-82.
https://hdl.handle.net/21.15107/rcub_dais_12351
Obradović N, Peleš A, Olćan D, Fahrenholtz WG, Đorđević A, Pavlović VB. Measurement of dielectric permitivity using coaxial chambers and electromagnetic-modeling software. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:82-82.
https://hdl.handle.net/21.15107/rcub_dais_12351 .
Obradović, Nina, Peleš, Adriana, Olćan, Dragan, Fahrenholtz, William G., Đorđević, Antonije, Pavlović, Vladimir B., "Measurement of dielectric permitivity using coaxial chambers and electromagnetic-modeling software" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):82-82,
https://hdl.handle.net/21.15107/rcub_dais_12351 .

Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG

Obradović, Nina; Filipović, Suzana; Rosenschon, Martin; Füglein, Ekkehard

(Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC), 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Rosenschon, Martin
AU  - Füglein, Ekkehard
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12353
AB  - Ceramic/polymer dielectric composites are widely used as components for electric devices, mainly because of their high chemical stability, mechanical strength, and flexibility. In order to increase dielectric permittivity, ceramic fillers with high dielectric constant have been usually incorporated in the polymer matrix in large amounts. With the aim to enhance dielectric properties of matrix, 5 wt.% of BaTiO3/Fe2O3 core/shell composite was added into the PVDF matrix. Prior to addition, five BaTiO3/Fe2O3 powders were prepared by different synthesis conditions. The changes in crystal structure and lattice dynamics of the obtained ceramic/polymer composite were correlated with changes in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler. Thermal analysis such as DTA/TG/DSC are useful methods to determine various parameters in ceramic/polymer composites. We were able to corroborate that differences in phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have influence on formation of various PVDF allomorph modification, as well as a level of crystallinity.
PB  - Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC)
C3  - Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021)
T1  - Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG
SP  - 29
EP  - 29
UR  - https://hdl.handle.net/21.15107/rcub_dais_12353
ER  - 
@conference{
author = "Obradović, Nina and Filipović, Suzana and Rosenschon, Martin and Füglein, Ekkehard",
year = "2021",
abstract = "Ceramic/polymer dielectric composites are widely used as components for electric devices, mainly because of their high chemical stability, mechanical strength, and flexibility. In order to increase dielectric permittivity, ceramic fillers with high dielectric constant have been usually incorporated in the polymer matrix in large amounts. With the aim to enhance dielectric properties of matrix, 5 wt.% of BaTiO3/Fe2O3 core/shell composite was added into the PVDF matrix. Prior to addition, five BaTiO3/Fe2O3 powders were prepared by different synthesis conditions. The changes in crystal structure and lattice dynamics of the obtained ceramic/polymer composite were correlated with changes in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler. Thermal analysis such as DTA/TG/DSC are useful methods to determine various parameters in ceramic/polymer composites. We were able to corroborate that differences in phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have influence on formation of various PVDF allomorph modification, as well as a level of crystallinity.",
publisher = "Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC)",
journal = "Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021)",
title = "Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG",
pages = "29-29",
url = "https://hdl.handle.net/21.15107/rcub_dais_12353"
}
Obradović, N., Filipović, S., Rosenschon, M.,& Füglein, E.. (2021). Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG. in Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021)
Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC)., 29-29.
https://hdl.handle.net/21.15107/rcub_dais_12353
Obradović N, Filipović S, Rosenschon M, Füglein E. Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG. in Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021). 2021;:29-29.
https://hdl.handle.net/21.15107/rcub_dais_12353 .
Obradović, Nina, Filipović, Suzana, Rosenschon, Martin, Füglein, Ekkehard, "Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG" in Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021) (2021):29-29,
https://hdl.handle.net/21.15107/rcub_dais_12353 .

Dielectric characteristics of polymer nanocomposites based on PVDF and mechanically activated ZnO powder

Peleš Tadić, Adriana; Obradović, Nina; Kosanović, Darko; Petrović, J.; Blagojević, Vladimir A.; Đorđević, Antonije; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Peleš Tadić, Adriana
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Petrović, J.
AU  - Blagojević, Vladimir A.
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11903
AB  - ZnO powder was mechanically activated for 10 and 30 minutes in a high energy planetary ball mill, and mixed with 2 wt% PVDF solution to obtain nanocomposite films (50 μm) by casting. ZnO powder activated for 10 and 30 minutes was used as filler. The difference in the dielectric properties for composites with the powder with prolonged time of mechanical activation was investigated, as well as the influence of ageing using dielectric measurements at higher frequencies. Dielectric measurement showed that the ageing process does not significantly affect the properties of the composites, while the prolonged activation times can be correlated with the changes in the values of the dielectric constant. The introduction of mechanically activated ZnO powders into the matrix leads to an increase in the dielectric permittivity of the polymer. Values of dielectric permittivity for different frequencies at 300 K decrease from approximately 3.1 (60 Hz) to 1.8 (30 MHz) for nanocomposite with ZnO activated for 10 minutes, while the permittivity for nanocopomosite with ZnO activated for 30 minutes permittivity was 2.6.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Dielectric characteristics of polymer nanocomposites based on PVDF and mechanically activated ZnO powder
SP  - 57
EP  - 57
UR  - https://hdl.handle.net/21.15107/rcub_dais_11903
ER  - 
@conference{
author = "Peleš Tadić, Adriana and Obradović, Nina and Kosanović, Darko and Petrović, J. and Blagojević, Vladimir A. and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2021",
abstract = "ZnO powder was mechanically activated for 10 and 30 minutes in a high energy planetary ball mill, and mixed with 2 wt% PVDF solution to obtain nanocomposite films (50 μm) by casting. ZnO powder activated for 10 and 30 minutes was used as filler. The difference in the dielectric properties for composites with the powder with prolonged time of mechanical activation was investigated, as well as the influence of ageing using dielectric measurements at higher frequencies. Dielectric measurement showed that the ageing process does not significantly affect the properties of the composites, while the prolonged activation times can be correlated with the changes in the values of the dielectric constant. The introduction of mechanically activated ZnO powders into the matrix leads to an increase in the dielectric permittivity of the polymer. Values of dielectric permittivity for different frequencies at 300 K decrease from approximately 3.1 (60 Hz) to 1.8 (30 MHz) for nanocomposite with ZnO activated for 10 minutes, while the permittivity for nanocopomosite with ZnO activated for 30 minutes permittivity was 2.6.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Dielectric characteristics of polymer nanocomposites based on PVDF and mechanically activated ZnO powder",
pages = "57-57",
url = "https://hdl.handle.net/21.15107/rcub_dais_11903"
}
Peleš Tadić, A., Obradović, N., Kosanović, D., Petrović, J., Blagojević, V. A., Đorđević, A.,& Pavlović, V. B.. (2021). Dielectric characteristics of polymer nanocomposites based on PVDF and mechanically activated ZnO powder. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 57-57.
https://hdl.handle.net/21.15107/rcub_dais_11903
Peleš Tadić A, Obradović N, Kosanović D, Petrović J, Blagojević VA, Đorđević A, Pavlović VB. Dielectric characteristics of polymer nanocomposites based on PVDF and mechanically activated ZnO powder. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:57-57.
https://hdl.handle.net/21.15107/rcub_dais_11903 .
Peleš Tadić, Adriana, Obradović, Nina, Kosanović, Darko, Petrović, J., Blagojević, Vladimir A., Đorđević, Antonije, Pavlović, Vladimir B., "Dielectric characteristics of polymer nanocomposites based on PVDF and mechanically activated ZnO powder" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):57-57,
https://hdl.handle.net/21.15107/rcub_dais_11903 .

Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction

Filipović, Suzana; Obradović, Nina; Anđelković, Ljubica; Olćan, Dragan; Petrović, Jovana; Mirković, Miljana; Pavlović, Vladimir B.; Jeremić, Dejan; Vlahović, Branislav; Đorđević, Antonije

(Belgrade : International Institute for the Science of Sintering, 2021)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Mirković, Miljana
AU  - Pavlović, Vladimir B.
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11230
AB  - Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction
SP  - 1
EP  - 8
VL  - 53
DO  - 10.2298/SOS2101001F
UR  - https://hdl.handle.net/21.15107/rcub_dais_11230
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana and Mirković, Miljana and Pavlović, Vladimir B. and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction",
pages = "1-8",
volume = "53",
doi = "10.2298/SOS2101001F",
url = "https://hdl.handle.net/21.15107/rcub_dais_11230"
}
Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J., Mirković, M., Pavlović, V. B., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 53, 1-8.
https://doi.org/10.2298/SOS2101001F
https://hdl.handle.net/21.15107/rcub_dais_11230
Filipović S, Obradović N, Anđelković L, Olćan D, Petrović J, Mirković M, Pavlović VB, Jeremić D, Vlahović B, Đorđević A. Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering. 2021;53:1-8.
doi:10.2298/SOS2101001F
https://hdl.handle.net/21.15107/rcub_dais_11230 .
Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana, Mirković, Miljana, Pavlović, Vladimir B., Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction" in Science of Sintering, 53 (2021):1-8,
https://doi.org/10.2298/SOS2101001F .,
https://hdl.handle.net/21.15107/rcub_dais_11230 .

Structural And Functional Investigation Of Fe/Pb/Zr-co-doped Barium Titanate Ceramics: From Theory To The Experiment

Stojanović, Nemanja; Zagorac, Dejan; Butulija, Svetlana; Lojpur, Vesna; Kalezić-Glišović, Aleksandra; Obradović, Nina; Maričić, Aleksa

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Stojanović, Nemanja
AU  - Zagorac, Dejan
AU  - Butulija, Svetlana
AU  - Lojpur, Vesna
AU  - Kalezić-Glišović, Aleksandra
AU  - Obradović, Nina
AU  - Maričić, Aleksa
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11898
AB  - Mixtures of high purity powders of 50 mass% Fe, 4 mass% Pb, 3 mass% Zr and 43 mass% BaTiO3 were activated in a rotary ball mill for durations ranging from 30 min to 300 min; samples were then sintered in the air atmosphere for 2 hours at 1200 °C. Crystal structure prediction has been performed using Bond ValenceCalculation (BVC) method.Moreover, theoretical stability of theperovskite structure for synthesized and calculated Fe/Pb/Zr-codoped barium titanatecompounds has been investigated using the Goldschmidttolerance factor (Gt) and global instability index (GII).It was observed that magnetization of the system decreased after the sintering, with the most dramatic drop of 90.11% belonging to the sample activated for 150 min. In comparison with initial powders, X-ray powder diffractiondata confirmed the presence of newphases of BaFe12O19 and Ba1.696Ti0.228O3 in sintered samples. Utilizing the field emission scanning electron microscopy (FESEM), it was found that with the increase of activation time the morphology of the samples progressed from irregural, spherical grains to mostly rod-like ones. Energy dispersive X-ray (EDX) analysis identified the presence of Pb and Zr occupying the same locations on the surface of sintered samples, whilst Fe was uniformly deployed regardless of the activation time.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Structural And Functional Investigation Of Fe/Pb/Zr-co-doped Barium Titanate Ceramics: From Theory To The Experiment
SP  - 77
EP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_dais_11898
ER  - 
@conference{
author = "Stojanović, Nemanja and Zagorac, Dejan and Butulija, Svetlana and Lojpur, Vesna and Kalezić-Glišović, Aleksandra and Obradović, Nina and Maričić, Aleksa",
year = "2021",
abstract = "Mixtures of high purity powders of 50 mass% Fe, 4 mass% Pb, 3 mass% Zr and 43 mass% BaTiO3 were activated in a rotary ball mill for durations ranging from 30 min to 300 min; samples were then sintered in the air atmosphere for 2 hours at 1200 °C. Crystal structure prediction has been performed using Bond ValenceCalculation (BVC) method.Moreover, theoretical stability of theperovskite structure for synthesized and calculated Fe/Pb/Zr-codoped barium titanatecompounds has been investigated using the Goldschmidttolerance factor (Gt) and global instability index (GII).It was observed that magnetization of the system decreased after the sintering, with the most dramatic drop of 90.11% belonging to the sample activated for 150 min. In comparison with initial powders, X-ray powder diffractiondata confirmed the presence of newphases of BaFe12O19 and Ba1.696Ti0.228O3 in sintered samples. Utilizing the field emission scanning electron microscopy (FESEM), it was found that with the increase of activation time the morphology of the samples progressed from irregural, spherical grains to mostly rod-like ones. Energy dispersive X-ray (EDX) analysis identified the presence of Pb and Zr occupying the same locations on the surface of sintered samples, whilst Fe was uniformly deployed regardless of the activation time.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Structural And Functional Investigation Of Fe/Pb/Zr-co-doped Barium Titanate Ceramics: From Theory To The Experiment",
pages = "77-77",
url = "https://hdl.handle.net/21.15107/rcub_dais_11898"
}
Stojanović, N., Zagorac, D., Butulija, S., Lojpur, V., Kalezić-Glišović, A., Obradović, N.,& Maričić, A.. (2021). Structural And Functional Investigation Of Fe/Pb/Zr-co-doped Barium Titanate Ceramics: From Theory To The Experiment. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 77-77.
https://hdl.handle.net/21.15107/rcub_dais_11898
Stojanović N, Zagorac D, Butulija S, Lojpur V, Kalezić-Glišović A, Obradović N, Maričić A. Structural And Functional Investigation Of Fe/Pb/Zr-co-doped Barium Titanate Ceramics: From Theory To The Experiment. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:77-77.
https://hdl.handle.net/21.15107/rcub_dais_11898 .
Stojanović, Nemanja, Zagorac, Dejan, Butulija, Svetlana, Lojpur, Vesna, Kalezić-Glišović, Aleksandra, Obradović, Nina, Maričić, Aleksa, "Structural And Functional Investigation Of Fe/Pb/Zr-co-doped Barium Titanate Ceramics: From Theory To The Experiment" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):77-77,
https://hdl.handle.net/21.15107/rcub_dais_11898 .

Ispitivanje strukturnih svojstava legure FeCoV metodom skenirajuće elektronske mikroskopije - SEM

Nedeljković, Borivoje; Pavlović, Vladimir B.; Obradović, Nina; Mitrović, Nebojša S.

(Belgrade : ETRAN, 2021)

TY  - CONF
AU  - Nedeljković, Borivoje
AU  - Pavlović, Vladimir B.
AU  - Obradović, Nina
AU  - Mitrović, Nebojša S.
PY  - 2021
UR  - https://www.etran.rs/2021/wp-content/uploads/2021/08/PROGRAM_ETRAN_2021_final_b5_za_web.pdf
UR  - https://dais.sanu.ac.rs/123456789/11922
AB  - U radu su ispitivani strukturna svojstva legure 49Fe49Co2V proizvedene PIM/MIM tehnologijom, tako što je polazni granulat pripremljen mešanjem FeCoV praha sa niskoviskoznim vezivom. Nakon brizganja sirovi uzorci su najpre tretirani rastvaračem a zatim i termički s istim ciljem odstranjivanja
veziva. MIM tehnologija je završena visokotemperaturskim sinterovanjem tokom 3,5 sata na temperaturama od 1370 °C do 1460 °C u atmosferi vodonika, kojim se obezbedjuju potrebne magnetne i mehaničke karakteristike. Strukturna svojstva veličine čestica Dmax, Feret X, Feret Y su ispitivana u zavisnosti od temperature sinterovanja.
PB  - Belgrade : ETRAN
C3  - Zbornik apstrakta i program 65. konferencije ETRAN i 8. konferencije IcETRAN, Etno selo Stanišići, Republika Srpska, 8-10. septembra 2021. godine = Proceedings of Abstracts and Program 8th Conference IcETRAN in conjunction with the 65th ETRAN Conference, Etno village Stanišići, Republic of Srpska, Bosnia and Herzegovina
T1  - Ispitivanje strukturnih svojstava legure FeCoV metodom skenirajuće elektronske mikroskopije - SEM
SP  - 33
EP  - 33
UR  - https://hdl.handle.net/21.15107/rcub_dais_11922
ER  - 
@conference{
author = "Nedeljković, Borivoje and Pavlović, Vladimir B. and Obradović, Nina and Mitrović, Nebojša S.",
year = "2021",
abstract = "U radu su ispitivani strukturna svojstva legure 49Fe49Co2V proizvedene PIM/MIM tehnologijom, tako što je polazni granulat pripremljen mešanjem FeCoV praha sa niskoviskoznim vezivom. Nakon brizganja sirovi uzorci su najpre tretirani rastvaračem a zatim i termički s istim ciljem odstranjivanja
veziva. MIM tehnologija je završena visokotemperaturskim sinterovanjem tokom 3,5 sata na temperaturama od 1370 °C do 1460 °C u atmosferi vodonika, kojim se obezbedjuju potrebne magnetne i mehaničke karakteristike. Strukturna svojstva veličine čestica Dmax, Feret X, Feret Y su ispitivana u zavisnosti od temperature sinterovanja.",
publisher = "Belgrade : ETRAN",
journal = "Zbornik apstrakta i program 65. konferencije ETRAN i 8. konferencije IcETRAN, Etno selo Stanišići, Republika Srpska, 8-10. septembra 2021. godine = Proceedings of Abstracts and Program 8th Conference IcETRAN in conjunction with the 65th ETRAN Conference, Etno village Stanišići, Republic of Srpska, Bosnia and Herzegovina",
title = "Ispitivanje strukturnih svojstava legure FeCoV metodom skenirajuće elektronske mikroskopije - SEM",
pages = "33-33",
url = "https://hdl.handle.net/21.15107/rcub_dais_11922"
}
Nedeljković, B., Pavlović, V. B., Obradović, N.,& Mitrović, N. S.. (2021). Ispitivanje strukturnih svojstava legure FeCoV metodom skenirajuće elektronske mikroskopije - SEM. in Zbornik apstrakta i program 65. konferencije ETRAN i 8. konferencije IcETRAN, Etno selo Stanišići, Republika Srpska, 8-10. septembra 2021. godine = Proceedings of Abstracts and Program 8th Conference IcETRAN in conjunction with the 65th ETRAN Conference, Etno village Stanišići, Republic of Srpska, Bosnia and Herzegovina
Belgrade : ETRAN., 33-33.
https://hdl.handle.net/21.15107/rcub_dais_11922
Nedeljković B, Pavlović VB, Obradović N, Mitrović NS. Ispitivanje strukturnih svojstava legure FeCoV metodom skenirajuće elektronske mikroskopije - SEM. in Zbornik apstrakta i program 65. konferencije ETRAN i 8. konferencije IcETRAN, Etno selo Stanišići, Republika Srpska, 8-10. septembra 2021. godine = Proceedings of Abstracts and Program 8th Conference IcETRAN in conjunction with the 65th ETRAN Conference, Etno village Stanišići, Republic of Srpska, Bosnia and Herzegovina. 2021;:33-33.
https://hdl.handle.net/21.15107/rcub_dais_11922 .
Nedeljković, Borivoje, Pavlović, Vladimir B., Obradović, Nina, Mitrović, Nebojša S., "Ispitivanje strukturnih svojstava legure FeCoV metodom skenirajuće elektronske mikroskopije - SEM" in Zbornik apstrakta i program 65. konferencije ETRAN i 8. konferencije IcETRAN, Etno selo Stanišići, Republika Srpska, 8-10. septembra 2021. godine = Proceedings of Abstracts and Program 8th Conference IcETRAN in conjunction with the 65th ETRAN Conference, Etno village Stanišići, Republic of Srpska, Bosnia and Herzegovina (2021):33-33,
https://hdl.handle.net/21.15107/rcub_dais_11922 .

Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition

Obradović, Nina; Fahrenholtz, William G.; Corlett, Cole; Filipović, Suzana; Nikolić, Marko G.; Marinković, Bojan A.; Failla, Simone; Sciti, Diletta; Sani, Elisa

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Corlett, Cole
AU  - Filipović, Suzana
AU  - Nikolić, Marko G.
AU  - Marinković, Bojan A.
AU  - Failla, Simone
AU  - Sciti, Diletta
AU  - Sani, Elisa
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11895
AB  - Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation of 30 minutes in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot-pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray diffraction analysis and scanning electron microscopy. Rietveld analysis revealed 100 % pure spinel phase in all sintered specimens, and decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6 % relative density, while other specimens were above 96.5 % relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve the densification behaviour of MgAl2O4 produced from mixed oxide powders, while additives improve microstructure and optical properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition
SP  - 92
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_dais_11895
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Corlett, Cole and Filipović, Suzana and Nikolić, Marko G. and Marinković, Bojan A. and Failla, Simone and Sciti, Diletta and Sani, Elisa",
year = "2021",
abstract = "Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation of 30 minutes in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot-pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray diffraction analysis and scanning electron microscopy. Rietveld analysis revealed 100 % pure spinel phase in all sintered specimens, and decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6 % relative density, while other specimens were above 96.5 % relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve the densification behaviour of MgAl2O4 produced from mixed oxide powders, while additives improve microstructure and optical properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition",
pages = "92-92",
url = "https://hdl.handle.net/21.15107/rcub_dais_11895"
}
Obradović, N., Fahrenholtz, W. G., Corlett, C., Filipović, S., Nikolić, M. G., Marinković, B. A., Failla, S., Sciti, D.,& Sani, E.. (2021). Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 92-92.
https://hdl.handle.net/21.15107/rcub_dais_11895
Obradović N, Fahrenholtz WG, Corlett C, Filipović S, Nikolić MG, Marinković BA, Failla S, Sciti D, Sani E. Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:92-92.
https://hdl.handle.net/21.15107/rcub_dais_11895 .
Obradović, Nina, Fahrenholtz, William G., Corlett, Cole, Filipović, Suzana, Nikolić, Marko G., Marinković, Bojan A., Failla, Simone, Sciti, Diletta, Sani, Elisa, "Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):92-92,
https://hdl.handle.net/21.15107/rcub_dais_11895 .

Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3

Filipović, Suzana; Obradović, Nina; Rosenschon, M.; Füglein, E.; Dojčilović, Radovan; Đorđević, Antonije; Petrović, J.; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Rosenschon, M.
AU  - Füglein, E.
AU  - Dojčilović, Radovan
AU  - Đorđević, Antonije
AU  - Petrović, J.
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11902
AB  - The increase in the utilization of ceramic/polymer composites as components for electric devices is mainly based on their high chemical stability, mechanical strength, and flexibility. The polymers usually have poor dielectric performances. In order to increase the dielectric permittivity, ceramic fillers with high dielectric constant have been used as active fillers, and usually in large amounts, which have a detrimental effect on the mechanical properties of the composite. With the aim to enhance the dielectric properties of the composite without loss of polymer’s flexibility, 5 wt.% of BaTiO3/Fe2O3 core/shell powders, prepared by different synthesis conditions, was added into the PVDF matrix. The effect of the phase composition and morphology of the starting BaTiO3/Fe2O3 core/shell filler on the crystal structure and lattice dynamics was investigated. Based on the results of the thermal analysis, TG/DSC, various parameters of ceramic/polymer composites were determined. We were able to corroborate that differences in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have an influence on the formation of various PVDF allomorph modifications, as well as the level of crystallinity. The dielectric performances of the pure PVDF and polymer/ceramic composites were measured. An enhancement in the dielectric permittivity and decrease in the loss tangent were revealed.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3
SP  - 58
EP  - 58
UR  - https://hdl.handle.net/21.15107/rcub_dais_11902
ER  - 
@conference{
author = "Filipović, Suzana and Obradović, Nina and Rosenschon, M. and Füglein, E. and Dojčilović, Radovan and Đorđević, Antonije and Petrović, J. and Pavlović, Vladimir B.",
year = "2021",
abstract = "The increase in the utilization of ceramic/polymer composites as components for electric devices is mainly based on their high chemical stability, mechanical strength, and flexibility. The polymers usually have poor dielectric performances. In order to increase the dielectric permittivity, ceramic fillers with high dielectric constant have been used as active fillers, and usually in large amounts, which have a detrimental effect on the mechanical properties of the composite. With the aim to enhance the dielectric properties of the composite without loss of polymer’s flexibility, 5 wt.% of BaTiO3/Fe2O3 core/shell powders, prepared by different synthesis conditions, was added into the PVDF matrix. The effect of the phase composition and morphology of the starting BaTiO3/Fe2O3 core/shell filler on the crystal structure and lattice dynamics was investigated. Based on the results of the thermal analysis, TG/DSC, various parameters of ceramic/polymer composites were determined. We were able to corroborate that differences in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have an influence on the formation of various PVDF allomorph modifications, as well as the level of crystallinity. The dielectric performances of the pure PVDF and polymer/ceramic composites were measured. An enhancement in the dielectric permittivity and decrease in the loss tangent were revealed.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3",
pages = "58-58",
url = "https://hdl.handle.net/21.15107/rcub_dais_11902"
}
Filipović, S., Obradović, N., Rosenschon, M., Füglein, E., Dojčilović, R., Đorđević, A., Petrović, J.,& Pavlović, V. B.. (2021). Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 58-58.
https://hdl.handle.net/21.15107/rcub_dais_11902
Filipović S, Obradović N, Rosenschon M, Füglein E, Dojčilović R, Đorđević A, Petrović J, Pavlović VB. Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:58-58.
https://hdl.handle.net/21.15107/rcub_dais_11902 .
Filipović, Suzana, Obradović, Nina, Rosenschon, M., Füglein, E., Dojčilović, Radovan, Đorđević, Antonije, Petrović, J., Pavlović, Vladimir B., "Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):58-58,
https://hdl.handle.net/21.15107/rcub_dais_11902 .

Magnetic features of MnZn ferrite for electronic applications

Mitrović, Nebojša S.; Nedeljković, Borivoje; Obradović, Nina

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Mitrović, Nebojša S.
AU  - Nedeljković, Borivoje
AU  - Obradović, Nina
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11901
AB  - MnZn ferrites are one of the most common soft magnetic materials for application in microelectronics as a material for microwave components (transformers, transducers, inductors, magnetic fluids, sensors,). MnZn ferrites attracted attention due to wide range of relative magnetic permeability values (from 103 to 104), high resistivity (consequently low magnetic losses) as well as high thermal stability (high saturation magnetic flux density at high temperatures (Bs > 0.4 T at 100 OC) and a relatively high Curie temperature of about 230 OC).Recently, a variety of technologies have been examined for MnZn ferrite production: powder/ceramic injection moulding (PIM/CIM), chemical co-precipitation method, conventional ceramic processing, sol-gel or microemulsion. In this study a toroidal samples of MnZn ferrites with dimensions appropriate for applications in electronic industry (i.e. microelectronics: inner diameter 3.5 mm, outer diameter 7 mm, height 2 mm) were investigated. Magnetic properties were measured by hysteresis graph (B-H curve at level of magnetic excitation up to 1 kA/m and at different frequencies from 5 Hz to 10 kHz). Relative magnetic permeability as well as magnetic power (active) losses was analyzed as frequency dependent. Very stable maximum magnetic permeability was observed for magnetic field of 200 A/m in the frequency range from 50 Hz (μr ≈ 480) to 10 kHz (μr ≈ 450). Active power referred to unit mass of about 30 W/kg was recorded at frequency of 1 kHz (@ 280 mT). As the hysteresis losses are proportionally to the frequency (~ f) and eddy-current losses are proportionally to the square of frequency (~ f2) it was performed separation between these two components from total magnetic power (active) losses. Numerical fitting of this functionality on frequency were performed and analysed. The results obtained were compared with the catalogue data for other MnZn ferrite components for applications in electronics.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Magnetic features of MnZn ferrite for electronic applications
SP  - 59
EP  - 59
UR  - https://hdl.handle.net/21.15107/rcub_dais_11901
ER  - 
@conference{
author = "Mitrović, Nebojša S. and Nedeljković, Borivoje and Obradović, Nina",
year = "2021",
abstract = "MnZn ferrites are one of the most common soft magnetic materials for application in microelectronics as a material for microwave components (transformers, transducers, inductors, magnetic fluids, sensors,). MnZn ferrites attracted attention due to wide range of relative magnetic permeability values (from 103 to 104), high resistivity (consequently low magnetic losses) as well as high thermal stability (high saturation magnetic flux density at high temperatures (Bs > 0.4 T at 100 OC) and a relatively high Curie temperature of about 230 OC).Recently, a variety of technologies have been examined for MnZn ferrite production: powder/ceramic injection moulding (PIM/CIM), chemical co-precipitation method, conventional ceramic processing, sol-gel or microemulsion. In this study a toroidal samples of MnZn ferrites with dimensions appropriate for applications in electronic industry (i.e. microelectronics: inner diameter 3.5 mm, outer diameter 7 mm, height 2 mm) were investigated. Magnetic properties were measured by hysteresis graph (B-H curve at level of magnetic excitation up to 1 kA/m and at different frequencies from 5 Hz to 10 kHz). Relative magnetic permeability as well as magnetic power (active) losses was analyzed as frequency dependent. Very stable maximum magnetic permeability was observed for magnetic field of 200 A/m in the frequency range from 50 Hz (μr ≈ 480) to 10 kHz (μr ≈ 450). Active power referred to unit mass of about 30 W/kg was recorded at frequency of 1 kHz (@ 280 mT). As the hysteresis losses are proportionally to the frequency (~ f) and eddy-current losses are proportionally to the square of frequency (~ f2) it was performed separation between these two components from total magnetic power (active) losses. Numerical fitting of this functionality on frequency were performed and analysed. The results obtained were compared with the catalogue data for other MnZn ferrite components for applications in electronics.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Magnetic features of MnZn ferrite for electronic applications",
pages = "59-59",
url = "https://hdl.handle.net/21.15107/rcub_dais_11901"
}
Mitrović, N. S., Nedeljković, B.,& Obradović, N.. (2021). Magnetic features of MnZn ferrite for electronic applications. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 59-59.
https://hdl.handle.net/21.15107/rcub_dais_11901
Mitrović NS, Nedeljković B, Obradović N. Magnetic features of MnZn ferrite for electronic applications. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:59-59.
https://hdl.handle.net/21.15107/rcub_dais_11901 .
Mitrović, Nebojša S., Nedeljković, Borivoje, Obradović, Nina, "Magnetic features of MnZn ferrite for electronic applications" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):59-59,
https://hdl.handle.net/21.15107/rcub_dais_11901 .

Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal

Obradović, Nina; Rusmirović, Jelena; Filipović, Suzana; Kosanović, Darko; Marinković, Aleksandar; Radić, Danka; Pavlović, Vladimir B.

(Desalination Publications, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Rusmirović, Jelena
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Marinković, Aleksandar
AU  - Radić, Danka
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10040
AB  - Industrial/technological growth is directly connected with environmental pollution, but its influence can be minimized through pollution abatement approaches such as the treatment of industrial wastewater. In this study, novel porous amine-functionalized silicate minerals, specifically, cordierite was investigated for the removal of toxic heavy metals from industrial wastewaters. Cordierite supports were synthesized by mixing MgO, Al2O3 , and SiO2 powders in 2:2:5 molar ratios, and mechanically activated via ball milling in ethanol for 10, 40, or 80 min. Pellets were sintered by heating in air at 20°C min-1 to 1,350°C, for 2 h. Porous supports were produced by coarsely crushing the sintered pellets and mixing the crushed and sieved cordierite powder with 20 wt.% of a pore-forming agent, either nanocellulose or yeast. The resulting pellets were sintered by heating at 5°C min-1 to 700°C in air. The synthetic cordierite support was modified by treatment in poly-ethylenimine. Activated supports were then tested for the removal of Ni2+ and Cd2+ ions. The phase composition of the cordierite supports was analyzed by the X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy. Analysis of adsorption isotherms, kinetics, and thermodynamic parameters indicated that adsorption was a spontaneous, endothermic process with a maximum adsorption capacity of 36 mg g-1 for Cd2+ and 43 mg g-1 for Ni2+. This work has shed light on the mechanism of heavy metal removal from the aquatic medium using the novel hybrid functionalized cordierite-based ceramic.
PB  - Desalination Publications
T2  - Desalination and Water Treatment
T1  - Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal
SP  - 283
EP  - 296
VL  - 192
DO  - 10.5004/dwt.2020.25736
UR  - https://hdl.handle.net/21.15107/rcub_dais_10040
ER  - 
@article{
author = "Obradović, Nina and Rusmirović, Jelena and Filipović, Suzana and Kosanović, Darko and Marinković, Aleksandar and Radić, Danka and Pavlović, Vladimir B.",
year = "2020",
abstract = "Industrial/technological growth is directly connected with environmental pollution, but its influence can be minimized through pollution abatement approaches such as the treatment of industrial wastewater. In this study, novel porous amine-functionalized silicate minerals, specifically, cordierite was investigated for the removal of toxic heavy metals from industrial wastewaters. Cordierite supports were synthesized by mixing MgO, Al2O3 , and SiO2 powders in 2:2:5 molar ratios, and mechanically activated via ball milling in ethanol for 10, 40, or 80 min. Pellets were sintered by heating in air at 20°C min-1 to 1,350°C, for 2 h. Porous supports were produced by coarsely crushing the sintered pellets and mixing the crushed and sieved cordierite powder with 20 wt.% of a pore-forming agent, either nanocellulose or yeast. The resulting pellets were sintered by heating at 5°C min-1 to 700°C in air. The synthetic cordierite support was modified by treatment in poly-ethylenimine. Activated supports were then tested for the removal of Ni2+ and Cd2+ ions. The phase composition of the cordierite supports was analyzed by the X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy. Analysis of adsorption isotherms, kinetics, and thermodynamic parameters indicated that adsorption was a spontaneous, endothermic process with a maximum adsorption capacity of 36 mg g-1 for Cd2+ and 43 mg g-1 for Ni2+. This work has shed light on the mechanism of heavy metal removal from the aquatic medium using the novel hybrid functionalized cordierite-based ceramic.",
publisher = "Desalination Publications",
journal = "Desalination and Water Treatment",
title = "Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal",
pages = "283-296",
volume = "192",
doi = "10.5004/dwt.2020.25736",
url = "https://hdl.handle.net/21.15107/rcub_dais_10040"
}
Obradović, N., Rusmirović, J., Filipović, S., Kosanović, D., Marinković, A., Radić, D.,& Pavlović, V. B.. (2020). Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal. in Desalination and Water Treatment
Desalination Publications., 192, 283-296.
https://doi.org/10.5004/dwt.2020.25736
https://hdl.handle.net/21.15107/rcub_dais_10040
Obradović N, Rusmirović J, Filipović S, Kosanović D, Marinković A, Radić D, Pavlović VB. Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal. in Desalination and Water Treatment. 2020;192:283-296.
doi:10.5004/dwt.2020.25736
https://hdl.handle.net/21.15107/rcub_dais_10040 .
Obradović, Nina, Rusmirović, Jelena, Filipović, Suzana, Kosanović, Darko, Marinković, Aleksandar, Radić, Danka, Pavlović, Vladimir B., "Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal" in Desalination and Water Treatment, 192 (2020):283-296,
https://doi.org/10.5004/dwt.2020.25736 .,
https://hdl.handle.net/21.15107/rcub_dais_10040 .

Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Savić, Slobodan; Đorđević, Antonije; Pavlović, Vladimir B.

(Springer, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10027
AB  - Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
SP  - 95
EP  - 107
VL  - 140
DO  - 10.1007/s10973-019-08846-w
UR  - https://hdl.handle.net/21.15107/rcub_dais_10027
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2020",
abstract = "Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "95-107",
volume = "140",
doi = "10.1007/s10973-019-08846-w",
url = "https://hdl.handle.net/21.15107/rcub_dais_10027"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Đorđević, A.,& Pavlović, V. B.. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 140, 95-107.
https://doi.org/10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_10027
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Đorđević A, Pavlović VB. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry. 2020;140:95-107.
doi:10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_10027 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Marković, Smilja, Blagojević, Vladimir A., Lević, Steva, Savić, Slobodan, Đorđević, Antonije, Pavlović, Vladimir B., "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" in Journal of Thermal Analysis and Calorimetry, 140 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w .,
https://hdl.handle.net/21.15107/rcub_dais_10027 .
1
2
2

Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Savić, Slobodan; Đorđević, Antonije; Pavlović, Vladimir B.

(Springer, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/6910
AB  - Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
SP  - 95
EP  - 107
VL  - 140
DO  - 10.1007/s10973-019-08846-w
UR  - https://hdl.handle.net/21.15107/rcub_dais_6910
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2020",
abstract = "Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "95-107",
volume = "140",
doi = "10.1007/s10973-019-08846-w",
url = "https://hdl.handle.net/21.15107/rcub_dais_6910"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Đorđević, A.,& Pavlović, V. B.. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 140, 95-107.
https://doi.org/10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_6910
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Đorđević A, Pavlović VB. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry. 2020;140:95-107.
doi:10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_6910 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Marković, Smilja, Blagojević, Vladimir A., Lević, Steva, Savić, Slobodan, Đorđević, Antonije, Pavlović, Vladimir B., "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" in Journal of Thermal Analysis and Calorimetry, 140 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w .,
https://hdl.handle.net/21.15107/rcub_dais_6910 .
1
2
2

Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior

Casas-Luna, Mariano; Torres-Rodríguez, Jorge Alberto; Valdés-Martínez, Omar Uriel; Obradović, Nina; Slámečka, Karel; Maca, Karel; Kaiser, Jozef; Montúfar, Edgar B.; Čelko, Ladislav

(Elsevier, 2020)

TY  - JOUR
AU  - Casas-Luna, Mariano
AU  - Torres-Rodríguez, Jorge Alberto
AU  - Valdés-Martínez, Omar Uriel
AU  - Obradović, Nina
AU  - Slámečka, Karel
AU  - Maca, Karel
AU  - Kaiser, Jozef
AU  - Montúfar, Edgar B.
AU  - Čelko, Ladislav
PY  - 2020
UR  - https://linkinghub.elsevier.com/retrieve/pii/S027288421933620X
UR  - https://dais.sanu.ac.rs/123456789/6942
AB  - Wollastonite (CaSiO3) based porous structures are useful in a wide range of applications including catalysis. Furthermore, the use of additive manufac…
PB  - Elsevier
T2  - Ceramics International
T1  - Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior
SP  - 8853
EP  - 8861
VL  - 46
IS  - 7
DO  - 10.1016/j.ceramint.2019.12.130
UR  - https://hdl.handle.net/21.15107/rcub_dais_6942
ER  - 
@article{
author = "Casas-Luna, Mariano and Torres-Rodríguez, Jorge Alberto and Valdés-Martínez, Omar Uriel and Obradović, Nina and Slámečka, Karel and Maca, Karel and Kaiser, Jozef and Montúfar, Edgar B. and Čelko, Ladislav",
year = "2020",
abstract = "Wollastonite (CaSiO3) based porous structures are useful in a wide range of applications including catalysis. Furthermore, the use of additive manufac…",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior",
pages = "8853-8861",
volume = "46",
number = "7",
doi = "10.1016/j.ceramint.2019.12.130",
url = "https://hdl.handle.net/21.15107/rcub_dais_6942"
}
Casas-Luna, M., Torres-Rodríguez, J. A., Valdés-Martínez, O. U., Obradović, N., Slámečka, K., Maca, K., Kaiser, J., Montúfar, E. B.,& Čelko, L.. (2020). Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior. in Ceramics International
Elsevier., 46(7), 8853-8861.
https://doi.org/10.1016/j.ceramint.2019.12.130
https://hdl.handle.net/21.15107/rcub_dais_6942
Casas-Luna M, Torres-Rodríguez JA, Valdés-Martínez OU, Obradović N, Slámečka K, Maca K, Kaiser J, Montúfar EB, Čelko L. Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior. in Ceramics International. 2020;46(7):8853-8861.
doi:10.1016/j.ceramint.2019.12.130
https://hdl.handle.net/21.15107/rcub_dais_6942 .
Casas-Luna, Mariano, Torres-Rodríguez, Jorge Alberto, Valdés-Martínez, Omar Uriel, Obradović, Nina, Slámečka, Karel, Maca, Karel, Kaiser, Jozef, Montúfar, Edgar B., Čelko, Ladislav, "Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior" in Ceramics International, 46, no. 7 (2020):8853-8861,
https://doi.org/10.1016/j.ceramint.2019.12.130 .,
https://hdl.handle.net/21.15107/rcub_dais_6942 .
8
7
7

Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior

Casas-Luna, Mariano; Torres-Rodríguez, Jorge Alberto; Valdés-Martínez, Omar Uriel; Obradović, Nina; Slámečka, Karel; Maca, Karel; Kaiser, Jozef; Montúfar, Edgar B.; Čelko, Ladislav

(Elsevier, 2020)

TY  - JOUR
AU  - Casas-Luna, Mariano
AU  - Torres-Rodríguez, Jorge Alberto
AU  - Valdés-Martínez, Omar Uriel
AU  - Obradović, Nina
AU  - Slámečka, Karel
AU  - Maca, Karel
AU  - Kaiser, Jozef
AU  - Montúfar, Edgar B.
AU  - Čelko, Ladislav
PY  - 2020
UR  - https://linkinghub.elsevier.com/retrieve/pii/S027288421933620X
UR  - https://dais.sanu.ac.rs/123456789/8943
AB  - Wollastonite (CaSiO3) based porous structures are useful in a wide range of applications including catalysis. Furthermore, the use of additive manufac…
PB  - Elsevier
T2  - Ceramics International
T1  - Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior
SP  - 8853
EP  - 8861
VL  - 46
IS  - 7
DO  - 10.1016/j.ceramint.2019.12.130
UR  - https://hdl.handle.net/21.15107/rcub_dais_8943
ER  - 
@article{
author = "Casas-Luna, Mariano and Torres-Rodríguez, Jorge Alberto and Valdés-Martínez, Omar Uriel and Obradović, Nina and Slámečka, Karel and Maca, Karel and Kaiser, Jozef and Montúfar, Edgar B. and Čelko, Ladislav",
year = "2020",
abstract = "Wollastonite (CaSiO3) based porous structures are useful in a wide range of applications including catalysis. Furthermore, the use of additive manufac…",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior",
pages = "8853-8861",
volume = "46",
number = "7",
doi = "10.1016/j.ceramint.2019.12.130",
url = "https://hdl.handle.net/21.15107/rcub_dais_8943"
}
Casas-Luna, M., Torres-Rodríguez, J. A., Valdés-Martínez, O. U., Obradović, N., Slámečka, K., Maca, K., Kaiser, J., Montúfar, E. B.,& Čelko, L.. (2020). Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior. in Ceramics International
Elsevier., 46(7), 8853-8861.
https://doi.org/10.1016/j.ceramint.2019.12.130
https://hdl.handle.net/21.15107/rcub_dais_8943
Casas-Luna M, Torres-Rodríguez JA, Valdés-Martínez OU, Obradović N, Slámečka K, Maca K, Kaiser J, Montúfar EB, Čelko L. Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior. in Ceramics International. 2020;46(7):8853-8861.
doi:10.1016/j.ceramint.2019.12.130
https://hdl.handle.net/21.15107/rcub_dais_8943 .
Casas-Luna, Mariano, Torres-Rodríguez, Jorge Alberto, Valdés-Martínez, Omar Uriel, Obradović, Nina, Slámečka, Karel, Maca, Karel, Kaiser, Jozef, Montúfar, Edgar B., Čelko, Ladislav, "Robocasting of controlled porous CaSiO3–SiO2 structures: Architecture – Strength relationship and material catalytic behavior" in Ceramics International, 46, no. 7 (2020):8853-8861,
https://doi.org/10.1016/j.ceramint.2019.12.130 .,
https://hdl.handle.net/21.15107/rcub_dais_8943 .
8
7
7

Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics

Terzić, Anja; Obradović, Nina; Kosanović, Darko; Stojanović, Jovica; Đorđević, Antonije; Andrić, Ljubiša; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Đorđević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884218329262
UR  - https://dais.sanu.ac.rs/123456789/4635
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
SP  - 3013
EP  - 3022
VL  - 45
IS  - 3
DO  - 10.1016/j.ceramint.2018.10.120
UR  - https://hdl.handle.net/21.15107/rcub_dais_4635
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Đorđević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir B.",
year = "2019",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3013-3022",
volume = "45",
number = "3",
doi = "10.1016/j.ceramint.2018.10.120",
url = "https://hdl.handle.net/21.15107/rcub_dais_4635"
}
Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Đorđević, A., Andrić, L.,& Pavlović, V. B.. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International
Elsevier., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120
https://hdl.handle.net/21.15107/rcub_dais_4635
Terzić A, Obradović N, Kosanović D, Stojanović J, Đorđević A, Andrić L, Pavlović VB. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International. 2019;45(3):3013-3022.
doi:10.1016/j.ceramint.2018.10.120
https://hdl.handle.net/21.15107/rcub_dais_4635 .
Terzić, Anja, Obradović, Nina, Kosanović, Darko, Stojanović, Jovica, Đorđević, Antonije, Andrić, Ljubiša, Pavlović, Vladimir B., "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" in Ceramics International, 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 .,
https://hdl.handle.net/21.15107/rcub_dais_4635 .
1
1
2

Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics

Terzić, Anja; Obradović, Nina; Kosanović, Darko; Stojanović, Jovica; Đorđević, Antonije; Andrić, Ljubiša; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Đorđević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884218329262
UR  - https://dais.sanu.ac.rs/123456789/4645
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
SP  - 3013
EP  - 3022
VL  - 45
IS  - 3
DO  - 10.1016/j.ceramint.2018.10.120
UR  - https://hdl.handle.net/21.15107/rcub_dais_4645
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Đorđević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir B.",
year = "2019",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3013-3022",
volume = "45",
number = "3",
doi = "10.1016/j.ceramint.2018.10.120",
url = "https://hdl.handle.net/21.15107/rcub_dais_4645"
}
Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Đorđević, A., Andrić, L.,& Pavlović, V. B.. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International
Elsevier., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120
https://hdl.handle.net/21.15107/rcub_dais_4645
Terzić A, Obradović N, Kosanović D, Stojanović J, Đorđević A, Andrić L, Pavlović VB. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International. 2019;45(3):3013-3022.
doi:10.1016/j.ceramint.2018.10.120
https://hdl.handle.net/21.15107/rcub_dais_4645 .
Terzić, Anja, Obradović, Nina, Kosanović, Darko, Stojanović, Jovica, Đorđević, Antonije, Andrić, Ljubiša, Pavlović, Vladimir B., "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" in Ceramics International, 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 .,
https://hdl.handle.net/21.15107/rcub_dais_4645 .
1
1
2

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - https://dais.sanu.ac.rs/123456789/5272
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
UR  - https://hdl.handle.net/21.15107/rcub_dais_5272
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095",
url = "https://hdl.handle.net/21.15107/rcub_dais_5272"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5272
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5272 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .,
https://hdl.handle.net/21.15107/rcub_dais_5272 .
11
10
10

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - https://dais.sanu.ac.rs/123456789/5763
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
UR  - https://hdl.handle.net/21.15107/rcub_dais_5763
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095",
url = "https://hdl.handle.net/21.15107/rcub_dais_5763"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5763
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5763 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .,
https://hdl.handle.net/21.15107/rcub_dais_5763 .
12
10
10

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Societa ceramica italiana, 2019)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7022
AB  - Magnesium aluminate, MgAl2O4, and other alumina-based spinels are refractory ceramics with high hardness and resistance to chemical attack while also being possible microwave dielectrics. Pure MgAl2O4 can be optically transparent when fully dense. Spinels exhibit inversion, which results in disorder among occupancy of A and B site cations. The goal of this study was to examine the effects of mechanical activation and composition on the temperature required for spinel formation and the site occupancy in the resulting spinel. 
MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3. The starting powders were mixed by ball milling to homogenize the powders without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1500 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influence of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. 
The main results of this study were that mechanical activation for 60 minutes initiated a mechano-chemical reaction, and resulted in spinel formation at much lower temperatures than within non-activated powders. Microstructures of ceramics sintered below 1400 oC indicated that final stage sintering started at much lower temperatures for activated samples than for non-activated samples. 
Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Societa ceramica italiana
PB  - Politecnico di Torino
C3  - Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 262
EP  - 262
UR  - https://hdl.handle.net/21.15107/rcub_dais_7022
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4, and other alumina-based spinels are refractory ceramics with high hardness and resistance to chemical attack while also being possible microwave dielectrics. Pure MgAl2O4 can be optically transparent when fully dense. Spinels exhibit inversion, which results in disorder among occupancy of A and B site cations. The goal of this study was to examine the effects of mechanical activation and composition on the temperature required for spinel formation and the site occupancy in the resulting spinel. 
MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3. The starting powders were mixed by ball milling to homogenize the powders without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1500 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influence of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. 
The main results of this study were that mechanical activation for 60 minutes initiated a mechano-chemical reaction, and resulted in spinel formation at much lower temperatures than within non-activated powders. Microstructures of ceramics sintered below 1400 oC indicated that final stage sintering started at much lower temperatures for activated samples than for non-activated samples. 
Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Societa ceramica italiana, Politecnico di Torino",
journal = "Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "262-262",
url = "https://hdl.handle.net/21.15107/rcub_dais_7022"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Rogan, J.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
Societa ceramica italiana., 262-262.
https://hdl.handle.net/21.15107/rcub_dais_7022
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Rogan J, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019. 2019;:262-262.
https://hdl.handle.net/21.15107/rcub_dais_7022 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Rogan, Jelena, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019 (2019):262-262,
https://hdl.handle.net/21.15107/rcub_dais_7022 .