TY  - CONF
AU  - Lukić, Vladimir
AU  - Čekerevac Mirković, Dragana
AU  - Jugović, Dragana
AU  - Maričić, Aleksa
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4571
AB  - Non-activated powder of nuclear grade graphite and powders of nuclear grade graphite that were milled for 10, 20 and 30 minutes are doped with 0.03% of platinum. XRD analysis of injtial and activated graphite powders was used for structural characterization. Hydrogen adsorption perfonned in isothermal conditions showed that platinization of powder samples of nuclear grade graphite decreases time needed for reaching adsorbent saturation during hydration. Simultaneously it was shown that platinization, due to the hydrogen spillower effect, increases adsorption capacity in a function of mechanical activation duration.
PB  - Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade
PB  - Belgrade : Hydrogen Economy Initiative Serbia
C3  - Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018
T1  - Influence of platinization of mechanically activated nuclear grade graphite powders on the hydrogen adsorption process
SP  - 86
EP  - 86
UR  - https://hdl.handle.net/21.15107/rcub_dais_4571
ER  - 

@conference{
author = "Lukić, Vladimir and Čekerevac Mirković, Dragana and Jugović, Dragana and Maričić, Aleksa",
year = "2018",
abstract = "Non-activated powder of nuclear grade graphite and powders of nuclear grade graphite that were milled for 10, 20 and 30 minutes are doped with 0.03% of platinum. XRD analysis of injtial and activated graphite powders was used for structural characterization. Hydrogen adsorption perfonned in isothermal conditions showed that platinization of powder samples of nuclear grade graphite decreases time needed for reaching adsorbent saturation during hydration. Simultaneously it was shown that platinization, due to the hydrogen spillower effect, increases adsorption capacity in a function of mechanical activation duration.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade, Belgrade : Hydrogen Economy Initiative Serbia",
journal = "Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018",
title = "Influence of platinization of mechanically activated nuclear grade graphite powders on the hydrogen adsorption process",
pages = "86-86",
url = "https://hdl.handle.net/21.15107/rcub_dais_4571"
}

Lukić, V., Čekerevac Mirković, D., Jugović, D.,& Maričić, A.. (2018). Influence of platinization of mechanically activated nuclear grade graphite powders on the hydrogen adsorption process. in Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018
Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade., 86-86.
https://hdl.handle.net/21.15107/rcub_dais_4571

Lukić V, Čekerevac Mirković D, Jugović D, Maričić A. Influence of platinization of mechanically activated nuclear grade graphite powders on the hydrogen adsorption process. in Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018. 2018;:86-86.
https://hdl.handle.net/21.15107/rcub_dais_4571 .

Lukić, Vladimir, Čekerevac Mirković, Dragana, Jugović, Dragana, Maričić, Aleksa, "Influence of platinization of mechanically activated nuclear grade graphite powders on the hydrogen adsorption process" in Program and the Book of Abstracts / 3rd International Symposium on Materials for Energy Storage and Conversion - mESC-IS 2018 (2018):86-86,
https://hdl.handle.net/21.15107/rcub_dais_4571 .

TY  - JOUR
AU  - Blagojević, Vladimir A.
AU  - Lukić, Vladimir
AU  - Begović, Nebojša N.
AU  - Maričić, Aleksa
AU  - Minić, Dragica M.
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/15456
AB  - [Ni2(btc)(en)2]n coordination polymer exhibits a layered two-dimensional structure with weak interaction between the layers. Correlation of experimental measurements, DFT calculations and molecular simulations demonstrated that its structural features, primarily the inherent flexibility of the layered polymeric structure, lead to improved hydrogen storage performance at room temperature, due to significant enhancement in isosteric heats of hydrogen adsorption. Volumetric measurements of hydrogen adsorption at room temperature show up to 0.3 wt.% hydrogen absorbed at 303 K and 2.63 bar of hydrogen pressure, with isosteric heats of adsorption of about 12.5 kJ mol−1. Predicted performance at room temperature is 1.8 wt.% at 48 bar and 3.5 wt.% at 100 bar, better than both MOF-5 and NU-100, with calculated values of isosteric heats for adsorption of hydrogen in 8–13 kJ mol−1 range at both 77 K and 303 K. Grand canonical Monte Carlo calculations show that this material, at 77 K, exhibits gravimetric hydrogen densities of more than 10 wt.% (up to 8.3 wt.% excess) with the corresponding volumetric density of at least 66 gL−1, which is comparable to MOF-5, but achieved with considerably smaller surface area of about 2500 m2 g−1. This study shows that layered two-dimensional MOFs could be a step towards MOF systems with significantly higher isosteric heats of adsorption, which could provide better room temperature hydrogen storage capabilities.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer
SP  - 22171
EP  - 22181
VL  - 41
IS  - 47
DO  - 10.1016/j.ijhydene.2016.08.203
UR  - https://hdl.handle.net/21.15107/rcub_dais_15456
ER  - 

@article{
author = "Blagojević, Vladimir A. and Lukić, Vladimir and Begović, Nebojša N. and Maričić, Aleksa and Minić, Dragica M.",
year = "2016",
abstract = "[Ni2(btc)(en)2]n coordination polymer exhibits a layered two-dimensional structure with weak interaction between the layers. Correlation of experimental measurements, DFT calculations and molecular simulations demonstrated that its structural features, primarily the inherent flexibility of the layered polymeric structure, lead to improved hydrogen storage performance at room temperature, due to significant enhancement in isosteric heats of hydrogen adsorption. Volumetric measurements of hydrogen adsorption at room temperature show up to 0.3 wt.% hydrogen absorbed at 303 K and 2.63 bar of hydrogen pressure, with isosteric heats of adsorption of about 12.5 kJ mol−1. Predicted performance at room temperature is 1.8 wt.% at 48 bar and 3.5 wt.% at 100 bar, better than both MOF-5 and NU-100, with calculated values of isosteric heats for adsorption of hydrogen in 8–13 kJ mol−1 range at both 77 K and 303 K. Grand canonical Monte Carlo calculations show that this material, at 77 K, exhibits gravimetric hydrogen densities of more than 10 wt.% (up to 8.3 wt.% excess) with the corresponding volumetric density of at least 66 gL−1, which is comparable to MOF-5, but achieved with considerably smaller surface area of about 2500 m2 g−1. This study shows that layered two-dimensional MOFs could be a step towards MOF systems with significantly higher isosteric heats of adsorption, which could provide better room temperature hydrogen storage capabilities.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer",
pages = "22171-22181",
volume = "41",
number = "47",
doi = "10.1016/j.ijhydene.2016.08.203",
url = "https://hdl.handle.net/21.15107/rcub_dais_15456"
}

Blagojević, V. A., Lukić, V., Begović, N. N., Maričić, A.,& Minić, D. M.. (2016). Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer. in International Journal of Hydrogen Energy
Elsevier., 41(47), 22171-22181.
https://doi.org/10.1016/j.ijhydene.2016.08.203
https://hdl.handle.net/21.15107/rcub_dais_15456

Blagojević VA, Lukić V, Begović NN, Maričić A, Minić DM. Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer. in International Journal of Hydrogen Energy. 2016;41(47):22171-22181.
doi:10.1016/j.ijhydene.2016.08.203
https://hdl.handle.net/21.15107/rcub_dais_15456 .

Blagojević, Vladimir A., Lukić, Vladimir, Begović, Nebojša N., Maričić, Aleksa, Minić, Dragica M., "Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer" in International Journal of Hydrogen Energy, 41, no. 47 (2016):22171-22181,
https://doi.org/10.1016/j.ijhydene.2016.08.203 .,
https://hdl.handle.net/21.15107/rcub_dais_15456 .

TY  - JOUR
AU  - Blagojević, Vladimir A.
AU  - Lukić, Vladimir
AU  - Begović, Nebojša N.
AU  - Maričić, Aleksa
AU  - Minić, Dragica M.
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/854
AB  - [Ni2(btc)(en)2]n coordination polymer exhibits a layered two-dimensional structure with weak interaction between the layers. Correlation of experimental measurements, DFT calculations and molecular simulations demonstrated that its structural features, primarily the inherent flexibility of the layered polymeric structure, lead to improved hydrogen storage performance at room temperature, due to significant enhancement in isosteric heats of hydrogen adsorption. Volumetric measurements of hydrogen adsorption at room temperature show up to 0.3 wt.% hydrogen absorbed at 303 K and 2.63 bar of hydrogen pressure, with isosteric heats of adsorption of about 12.5 kJ mol−1. Predicted performance at room temperature is 1.8 wt.% at 48 bar and 3.5 wt.% at 100 bar, better than both MOF-5 and NU-100, with calculated values of isosteric heats for adsorption of hydrogen in 8–13 kJ mol−1 range at both 77 K and 303 K. Grand canonical Monte Carlo calculations show that this material, at 77 K, exhibits gravimetric hydrogen densities of more than 10 wt.% (up to 8.3 wt.% excess) with the corresponding volumetric density of at least 66 gL−1, which is comparable to MOF-5, but achieved with considerably smaller surface area of about 2500 m2 g−1. This study shows that layered two-dimensional MOFs could be a step towards MOF systems with significantly higher isosteric heats of adsorption, which could provide better room temperature hydrogen storage capabilities.
T2  - International Journal of Hydrogen Energy
T1  - Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer
SP  - 22171
EP  - 22181
VL  - 41
IS  - 47
DO  - 10.1016/j.ijhydene.2016.08.203
UR  - https://hdl.handle.net/21.15107/rcub_dais_854
ER  - 

@article{
author = "Blagojević, Vladimir A. and Lukić, Vladimir and Begović, Nebojša N. and Maričić, Aleksa and Minić, Dragica M.",
year = "2016",
abstract = "[Ni2(btc)(en)2]n coordination polymer exhibits a layered two-dimensional structure with weak interaction between the layers. Correlation of experimental measurements, DFT calculations and molecular simulations demonstrated that its structural features, primarily the inherent flexibility of the layered polymeric structure, lead to improved hydrogen storage performance at room temperature, due to significant enhancement in isosteric heats of hydrogen adsorption. Volumetric measurements of hydrogen adsorption at room temperature show up to 0.3 wt.% hydrogen absorbed at 303 K and 2.63 bar of hydrogen pressure, with isosteric heats of adsorption of about 12.5 kJ mol−1. Predicted performance at room temperature is 1.8 wt.% at 48 bar and 3.5 wt.% at 100 bar, better than both MOF-5 and NU-100, with calculated values of isosteric heats for adsorption of hydrogen in 8–13 kJ mol−1 range at both 77 K and 303 K. Grand canonical Monte Carlo calculations show that this material, at 77 K, exhibits gravimetric hydrogen densities of more than 10 wt.% (up to 8.3 wt.% excess) with the corresponding volumetric density of at least 66 gL−1, which is comparable to MOF-5, but achieved with considerably smaller surface area of about 2500 m2 g−1. This study shows that layered two-dimensional MOFs could be a step towards MOF systems with significantly higher isosteric heats of adsorption, which could provide better room temperature hydrogen storage capabilities.",
journal = "International Journal of Hydrogen Energy",
title = "Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer",
pages = "22171-22181",
volume = "41",
number = "47",
doi = "10.1016/j.ijhydene.2016.08.203",
url = "https://hdl.handle.net/21.15107/rcub_dais_854"
}

Blagojević, V. A., Lukić, V., Begović, N. N., Maričić, A.,& Minić, D. M.. (2016). Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer. in International Journal of Hydrogen Energy, 41(47), 22171-22181.
https://doi.org/10.1016/j.ijhydene.2016.08.203
https://hdl.handle.net/21.15107/rcub_dais_854

Blagojević VA, Lukić V, Begović NN, Maričić A, Minić DM. Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer. in International Journal of Hydrogen Energy. 2016;41(47):22171-22181.
doi:10.1016/j.ijhydene.2016.08.203
https://hdl.handle.net/21.15107/rcub_dais_854 .

Blagojević, Vladimir A., Lukić, Vladimir, Begović, Nebojša N., Maričić, Aleksa, Minić, Dragica M., "Hydrogen storage in a layered flexible [Ni2(btc)(en)2]n coordination polymer" in International Journal of Hydrogen Energy, 41, no. 47 (2016):22171-22181,
https://doi.org/10.1016/j.ijhydene.2016.08.203 .,
https://hdl.handle.net/21.15107/rcub_dais_854 .