Filipović, Suzana

Link to this page

Authority KeyName Variants
orcid::0000-0001-6383-8327
  • Filipović, Suzana (106)
  • Stevanović, Suzana (16)
Projects
Directed synthesis, structure and properties of multifunctional materials Investigation of the relation in triad: Synthesis structure-properties for functional materials
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) Ministry of Education, Youth and Sports (MEYS) of Czech Republic - CEITEC 2020 [LQ1601]
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Synthesis, processing and applications of nanostructured multifunctional materials with defined properties
United States National Aeronautics and Space Administration (NASA), Grant NNX09AV07A United States National Science Foundation (NSF) / Centers of Research Excellence in Science and Technology (CREST), Grant HRD-0833184
Grant Agency of the Czech Republic, Project 15-06390S Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture)
Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing Algorithms and software for frequency-domain and time-domain simulations of RF subsystems and electromagnetic sensors in ICT
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Serbian Academy of Sciences and Arts, Project F-198
Czech Science Foundation (GACR) - 17-05620S Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Serbian Academy of Sciences and Arts, Project F-133 United States National Science Foundation (NSF) / Partnerships for Research and Education in Materials (PREM), Grant 1523617
Bilateral cooperation between Serbia and France, No. 4510339/2016/09/03 “Inteligent econanomaterials and nanocomposites” European Regional Development Fund through a project CEITEC, CZ.1.05/1.1.00/02.0068
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200288 (Innovation Center of the Faculty of Chemistry) Materials Research Center at Missouri S&T
NATO project SPS G5767 - "Super Strong Ceramics for Protection in Harsh Environments and DefenCE" (SUSPENCE) Serbian Academy of Sciences and Arts, Project F-197
Serbian Academy of Sciences and Arts, Project F-7 Serbian Academy of Sciences and Arts, Project F-7/II

Author's Bibliography

Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions

Obradović, Nina; Fahrenholtz, William G.; Corlett, Cole; Filipović, Suzana; Nikolić, Marko; Marinković, Bojan A.; Failla, Simone; Sciti, Diletta; Di Rosa, Daniele; Sani, Elisa

(Basel : MDPI AG, 2021)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Corlett, Cole
AU  - Filipović, Suzana
AU  - Nikolić, Marko
AU  - Marinković, Bojan A.
AU  - Failla, Simone
AU  - Sciti, Diletta
AU  - Di Rosa, Daniele
AU  - Sani, Elisa
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12431
AB  - Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by a solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation for 30 min in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray powder diffraction and scanning electron microscopy. Rietveld analysis revealed 100% pure spinel phase in all sintered specimens, and a decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6% relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve densification of MgAl2O4 prepared from mixed oxide powders, while additives improve microstructure and optical properties.
PB  - Basel : MDPI AG
T2  - Materials
T1  - Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions
SP  - 7674
VL  - 14
IS  - 24
DO  - 10.3390/ma14247674
UR  - https://hdl.handle.net/21.15107/rcub_dais_12431
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Corlett, Cole and Filipović, Suzana and Nikolić, Marko and Marinković, Bojan A. and Failla, Simone and Sciti, Diletta and Di Rosa, Daniele and Sani, Elisa",
year = "2021",
abstract = "Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by a solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation for 30 min in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray powder diffraction and scanning electron microscopy. Rietveld analysis revealed 100% pure spinel phase in all sintered specimens, and a decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6% relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve densification of MgAl2O4 prepared from mixed oxide powders, while additives improve microstructure and optical properties.",
publisher = "Basel : MDPI AG",
journal = "Materials",
title = "Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions",
pages = "7674",
volume = "14",
number = "24",
doi = "10.3390/ma14247674",
url = "https://hdl.handle.net/21.15107/rcub_dais_12431"
}
Obradović, N., Fahrenholtz, W. G., Corlett, C., Filipović, S., Nikolić, M., Marinković, B. A., Failla, S., Sciti, D., Di Rosa, D.,& Sani, E.. (2021). Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions. in Materials
Basel : MDPI AG., 14(24), 7674.
https://doi.org/10.3390/ma14247674
https://hdl.handle.net/21.15107/rcub_dais_12431
Obradović N, Fahrenholtz WG, Corlett C, Filipović S, Nikolić M, Marinković BA, Failla S, Sciti D, Di Rosa D, Sani E. Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions. in Materials. 2021;14(24):7674.
doi:10.3390/ma14247674
https://hdl.handle.net/21.15107/rcub_dais_12431 .
Obradović, Nina, Fahrenholtz, William G., Corlett, Cole, Filipović, Suzana, Nikolić, Marko, Marinković, Bojan A., Failla, Simone, Sciti, Diletta, Di Rosa, Daniele, Sani, Elisa, "Microstructural and Optical Properties of MgAl2O4 Spinel: Effects of Mechanical Activation, Y2O3 and Graphene Additions" in Materials, 14, no. 24 (2021):7674,
https://doi.org/10.3390/ma14247674 .,
https://hdl.handle.net/21.15107/rcub_dais_12431 .
2

High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters

Đorđević, Antonije; Olćan, Dragan; Petrović, Jovana; Obradović, Nina; Filipović, Suzana

(National Library of Serbia, 2021)

TY  - JOUR
AU  - Đorđević, Antonije
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Obradović, Nina
AU  - Filipović, Suzana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12341
AB  - We have developed rotationally symmetrical coaxial chambers for measurements of dielectric parameters of disk-shaped samples, in the frequency range from 1 MHz to several hundred MHz. The reflection coefficient of the chamber is measured and the dielectric parameters are hence extracted utilizing a high-accuracy quasistatic numerical model of the chamber and the sample. We present this model, which is based on the method-of-moments solution of a set of integral equations for composite metallic and dielectric bodies. The equations are tailored to bodies of revolution. The model is efficient and accurate so that the major contribution of the measurement uncertainty comes from the measurement hardware.
PB  - National Library of Serbia
T2  - Facta universitatis - series: Electronics and Energetics
T1  - High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters
SP  - 141
EP  - 156
VL  - 34
IS  - 1
DO  - 10.2298/FUEE2101141D
UR  - https://hdl.handle.net/21.15107/rcub_dais_12341
ER  - 
@article{
author = "Đorđević, Antonije and Olćan, Dragan and Petrović, Jovana and Obradović, Nina and Filipović, Suzana",
year = "2021",
abstract = "We have developed rotationally symmetrical coaxial chambers for measurements of dielectric parameters of disk-shaped samples, in the frequency range from 1 MHz to several hundred MHz. The reflection coefficient of the chamber is measured and the dielectric parameters are hence extracted utilizing a high-accuracy quasistatic numerical model of the chamber and the sample. We present this model, which is based on the method-of-moments solution of a set of integral equations for composite metallic and dielectric bodies. The equations are tailored to bodies of revolution. The model is efficient and accurate so that the major contribution of the measurement uncertainty comes from the measurement hardware.",
publisher = "National Library of Serbia",
journal = "Facta universitatis - series: Electronics and Energetics",
title = "High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters",
pages = "141-156",
volume = "34",
number = "1",
doi = "10.2298/FUEE2101141D",
url = "https://hdl.handle.net/21.15107/rcub_dais_12341"
}
Đorđević, A., Olćan, D., Petrović, J., Obradović, N.,& Filipović, S.. (2021). High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters. in Facta universitatis - series: Electronics and Energetics
National Library of Serbia., 34(1), 141-156.
https://doi.org/10.2298/FUEE2101141D
https://hdl.handle.net/21.15107/rcub_dais_12341
Đorđević A, Olćan D, Petrović J, Obradović N, Filipović S. High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters. in Facta universitatis - series: Electronics and Energetics. 2021;34(1):141-156.
doi:10.2298/FUEE2101141D
https://hdl.handle.net/21.15107/rcub_dais_12341 .
Đorđević, Antonije, Olćan, Dragan, Petrović, Jovana, Obradović, Nina, Filipović, Suzana, "High-accuracy quasistatic numerical model for bodies of revolution tailored for RF measurements of dielectric parameters" in Facta universitatis - series: Electronics and Energetics, 34, no. 1 (2021):141-156,
https://doi.org/10.2298/FUEE2101141D .,
https://hdl.handle.net/21.15107/rcub_dais_12341 .

Sinteza i struktura bakterijske celuloze primenom bakterija sirćetnog vrenja

Janićijević, Aleksandra; Filipović, Suzana; Pavlović, Vladimir B.; Sknepnek, Aleksandra; Kovačević, Danijela; Đorđević, Nenad; Mirković, Miljana; Živković, Predrag

(Čačak : Univerzitet u Kragujevcu, Agronomski fakultet, 2021)

TY  - CONF
AU  - Janićijević, Aleksandra
AU  - Filipović, Suzana
AU  - Pavlović, Vladimir B.
AU  - Sknepnek, Aleksandra
AU  - Kovačević, Danijela
AU  - Đorđević, Nenad
AU  - Mirković, Miljana
AU  - Živković, Predrag
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12356
AB  - Kao jedan od najzastupljenijih biopolimera na Zemlji, celuloza je našla primenu u prehrambenoj industriji, biomedicini i biotehnologiji. Dobijanje celuloznih vlakana iz biljaka je praćeno prisustvom nusproizvoda, čije je uklanjanje zahtevan proces. Stoga, materijali na bazi bakterijske nanoceluloze (BCN), nalaze sve širu primenu u svakodnevnici. Imajući u vidu prednosti BCN, u ovom radu su ispitivane promene u strukturi i morfologiji BCN u funkciji parametara sinteze. Analiziran je uticaj vrste i zapremine medijuma, kao i dužine prečišćavanja u NaOH, na promene u prinosu i strukturi BCN. Navedene promene su ispitivane metodama XRD, FTIR, kao i primenom SEM i EDS analize.
AB  - As one of the most common biopolymers on Earth, cellulose has found an important role in food industry, biomedicine andbiotechnology. The process of obtaining cellulose fibers is often followed with the presence of the byproduct, whose removal is required procedure. From that reason, the process of obtaining material on a bacterial cellulose (BC) basis,finds wide application in everyday life. Having in mind her many features, we have investigated the change in structure and morphology of BC depending on the synthesis parameters. The influence of the medium volume and different time intervals of NaOH treatment relative to different BCN yields and structure. The mentioned changes were examined by XRD, FTIR spectroscopy, as well as SEM and EDS analyzes.
PB  - Čačak : Univerzitet u Kragujevcu, Agronomski fakultet
C3  - Zbornik radova [Elektronski izvor] / XXVI savetovanje o biotehnologiji sa međunarodnim učešćem, Čačak, 12 - 13. mart 2021. godine
T1  - Sinteza i struktura bakterijske celuloze primenom bakterija sirćetnog vrenja
SP  - 281
EP  - 289
DO  - 10.46793/SBT26.281J
UR  - https://hdl.handle.net/21.15107/rcub_dais_12356
ER  - 
@conference{
author = "Janićijević, Aleksandra and Filipović, Suzana and Pavlović, Vladimir B. and Sknepnek, Aleksandra and Kovačević, Danijela and Đorđević, Nenad and Mirković, Miljana and Živković, Predrag",
year = "2021",
abstract = "Kao jedan od najzastupljenijih biopolimera na Zemlji, celuloza je našla primenu u prehrambenoj industriji, biomedicini i biotehnologiji. Dobijanje celuloznih vlakana iz biljaka je praćeno prisustvom nusproizvoda, čije je uklanjanje zahtevan proces. Stoga, materijali na bazi bakterijske nanoceluloze (BCN), nalaze sve širu primenu u svakodnevnici. Imajući u vidu prednosti BCN, u ovom radu su ispitivane promene u strukturi i morfologiji BCN u funkciji parametara sinteze. Analiziran je uticaj vrste i zapremine medijuma, kao i dužine prečišćavanja u NaOH, na promene u prinosu i strukturi BCN. Navedene promene su ispitivane metodama XRD, FTIR, kao i primenom SEM i EDS analize., As one of the most common biopolymers on Earth, cellulose has found an important role in food industry, biomedicine andbiotechnology. The process of obtaining cellulose fibers is often followed with the presence of the byproduct, whose removal is required procedure. From that reason, the process of obtaining material on a bacterial cellulose (BC) basis,finds wide application in everyday life. Having in mind her many features, we have investigated the change in structure and morphology of BC depending on the synthesis parameters. The influence of the medium volume and different time intervals of NaOH treatment relative to different BCN yields and structure. The mentioned changes were examined by XRD, FTIR spectroscopy, as well as SEM and EDS analyzes.",
publisher = "Čačak : Univerzitet u Kragujevcu, Agronomski fakultet",
journal = "Zbornik radova [Elektronski izvor] / XXVI savetovanje o biotehnologiji sa međunarodnim učešćem, Čačak, 12 - 13. mart 2021. godine",
title = "Sinteza i struktura bakterijske celuloze primenom bakterija sirćetnog vrenja",
pages = "281-289",
doi = "10.46793/SBT26.281J",
url = "https://hdl.handle.net/21.15107/rcub_dais_12356"
}
Janićijević, A., Filipović, S., Pavlović, V. B., Sknepnek, A., Kovačević, D., Đorđević, N., Mirković, M.,& Živković, P.. (2021). Sinteza i struktura bakterijske celuloze primenom bakterija sirćetnog vrenja. in Zbornik radova [Elektronski izvor] / XXVI savetovanje o biotehnologiji sa međunarodnim učešćem, Čačak, 12 - 13. mart 2021. godine
Čačak : Univerzitet u Kragujevcu, Agronomski fakultet., 281-289.
https://doi.org/10.46793/SBT26.281J
https://hdl.handle.net/21.15107/rcub_dais_12356
Janićijević A, Filipović S, Pavlović VB, Sknepnek A, Kovačević D, Đorđević N, Mirković M, Živković P. Sinteza i struktura bakterijske celuloze primenom bakterija sirćetnog vrenja. in Zbornik radova [Elektronski izvor] / XXVI savetovanje o biotehnologiji sa međunarodnim učešćem, Čačak, 12 - 13. mart 2021. godine. 2021;:281-289.
doi:10.46793/SBT26.281J
https://hdl.handle.net/21.15107/rcub_dais_12356 .
Janićijević, Aleksandra, Filipović, Suzana, Pavlović, Vladimir B., Sknepnek, Aleksandra, Kovačević, Danijela, Đorđević, Nenad, Mirković, Miljana, Živković, Predrag, "Sinteza i struktura bakterijske celuloze primenom bakterija sirćetnog vrenja" in Zbornik radova [Elektronski izvor] / XXVI savetovanje o biotehnologiji sa međunarodnim učešćem, Čačak, 12 - 13. mart 2021. godine (2021):281-289,
https://doi.org/10.46793/SBT26.281J .,
https://hdl.handle.net/21.15107/rcub_dais_12356 .
1

Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems

Obradović, Nina; Filipović, Suzana; Gilli, N.; Silvestroni, L.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Gilli, N.
AU  - Silvestroni, L.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12352
AB  - ZrB2 ceramics are considered potential materials for hypersonic systems in view of the melting point exceeding 3000 °C and excellent ablation resistance. Second phases, including SiC or CrB2, further improve the oxidation behavior, whereas a lighter phase, like TiB2 can decrease the overall weight. In this work, a powder mixture containing ZrB2, TiB2, CrB2 and SiC was mechanically activated using high energy ball-milling. Sintering was performed by hot pressing following different thermal cycles, and subsequent annealing to remove oxide phases and reduce micro-cracking. The microstructure and hardness of the dense ceramics are compared in relationship to the thermal history. Fully dense ceramics were obtained with different oxide-phases amount depending on the sintering cycle and hardness approaching 24 GPa were achieved. Future works will explore the strength and oxidation resistance of this multi-phase system to check its suitability for hypersonic systems.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems
SP  - 83
EP  - 83
UR  - https://hdl.handle.net/21.15107/rcub_dais_12352
ER  - 
@conference{
author = "Obradović, Nina and Filipović, Suzana and Gilli, N. and Silvestroni, L.",
year = "2021",
abstract = "ZrB2 ceramics are considered potential materials for hypersonic systems in view of the melting point exceeding 3000 °C and excellent ablation resistance. Second phases, including SiC or CrB2, further improve the oxidation behavior, whereas a lighter phase, like TiB2 can decrease the overall weight. In this work, a powder mixture containing ZrB2, TiB2, CrB2 and SiC was mechanically activated using high energy ball-milling. Sintering was performed by hot pressing following different thermal cycles, and subsequent annealing to remove oxide phases and reduce micro-cracking. The microstructure and hardness of the dense ceramics are compared in relationship to the thermal history. Fully dense ceramics were obtained with different oxide-phases amount depending on the sintering cycle and hardness approaching 24 GPa were achieved. Future works will explore the strength and oxidation resistance of this multi-phase system to check its suitability for hypersonic systems.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems",
pages = "83-83",
url = "https://hdl.handle.net/21.15107/rcub_dais_12352"
}
Obradović, N., Filipović, S., Gilli, N.,& Silvestroni, L.. (2021). Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 83-83.
https://hdl.handle.net/21.15107/rcub_dais_12352
Obradović N, Filipović S, Gilli N, Silvestroni L. Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:83-83.
https://hdl.handle.net/21.15107/rcub_dais_12352 .
Obradović, Nina, Filipović, Suzana, Gilli, N., Silvestroni, L., "Preparation and characterization of ZrB2-TiB2 based composites for hypersonic systems" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):83-83,
https://hdl.handle.net/21.15107/rcub_dais_12352 .

BT/ZnO composite materials with improved functional properties

Stanković, Ana; Filipović, Suzana; Stojković Simatović, Ivana; Škapin, Srečo Davor; Mančić, Lidija; Marković, Smilja

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Stanković, Ana
AU  - Filipović, Suzana
AU  - Stojković Simatović, Ivana
AU  - Škapin, Srečo Davor
AU  - Mančić, Lidija
AU  - Marković, Smilja
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12350
AB  - Due to a high-power conversion efficiency (PCE), perovskite solar cells (PSCs) are the most developing area of research in the past decade. Although lead−based inorganic−organic PSCs has achieved the highest PCE of 25.2%, the toxic nature of lead and poor stability of organic components strongly limits its commercialization. This problem can be overcome by developing of inorganic perovskites with a high PCE. Barium titanate (BaTiO3, BT) belongs to the perovskite crystal structure materials with remarkable dielectric, ferroelectric and ferromagnetic properties. In this research, to enhance functional properties of BT we employed functionalization with MEMO silane followed by in-situ alloying with ZnO in different BT to ZnO wt.%. Synthesized ZnO@MEMO@BT composites were tested as photo- and photo-electro catalysts under simulated sunlight irradiation. An enhanced catalytic activity of ZnO@MEMO@BT composites, compared to pure BT is probably due to the modified binding energy and an optimized band structure. In order to investigate the origin of improved catalytic efficiency, pristine BT and composites were characterized using a variety of techniques, including X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance and photoluminescence spectroscopy. The enhanced photo(electro)catalytic activity of the composite materials can be attributed to the synergetic effect of the surface defects and the ZnO/BT heterojunction particles, which enabled charge separation, thereby hindering the recombination of photogenerated carriers.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - BT/ZnO composite materials with improved functional properties
SP  - 81
EP  - 81
UR  - https://hdl.handle.net/21.15107/rcub_dais_12350
ER  - 
@conference{
author = "Stanković, Ana and Filipović, Suzana and Stojković Simatović, Ivana and Škapin, Srečo Davor and Mančić, Lidija and Marković, Smilja",
year = "2021",
abstract = "Due to a high-power conversion efficiency (PCE), perovskite solar cells (PSCs) are the most developing area of research in the past decade. Although lead−based inorganic−organic PSCs has achieved the highest PCE of 25.2%, the toxic nature of lead and poor stability of organic components strongly limits its commercialization. This problem can be overcome by developing of inorganic perovskites with a high PCE. Barium titanate (BaTiO3, BT) belongs to the perovskite crystal structure materials with remarkable dielectric, ferroelectric and ferromagnetic properties. In this research, to enhance functional properties of BT we employed functionalization with MEMO silane followed by in-situ alloying with ZnO in different BT to ZnO wt.%. Synthesized ZnO@MEMO@BT composites were tested as photo- and photo-electro catalysts under simulated sunlight irradiation. An enhanced catalytic activity of ZnO@MEMO@BT composites, compared to pure BT is probably due to the modified binding energy and an optimized band structure. In order to investigate the origin of improved catalytic efficiency, pristine BT and composites were characterized using a variety of techniques, including X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance and photoluminescence spectroscopy. The enhanced photo(electro)catalytic activity of the composite materials can be attributed to the synergetic effect of the surface defects and the ZnO/BT heterojunction particles, which enabled charge separation, thereby hindering the recombination of photogenerated carriers.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "BT/ZnO composite materials with improved functional properties",
pages = "81-81",
url = "https://hdl.handle.net/21.15107/rcub_dais_12350"
}
Stanković, A., Filipović, S., Stojković Simatović, I., Škapin, S. D., Mančić, L.,& Marković, S.. (2021). BT/ZnO composite materials with improved functional properties. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 81-81.
https://hdl.handle.net/21.15107/rcub_dais_12350
Stanković A, Filipović S, Stojković Simatović I, Škapin SD, Mančić L, Marković S. BT/ZnO composite materials with improved functional properties. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:81-81.
https://hdl.handle.net/21.15107/rcub_dais_12350 .
Stanković, Ana, Filipović, Suzana, Stojković Simatović, Ivana, Škapin, Srečo Davor, Mančić, Lidija, Marković, Smilja, "BT/ZnO composite materials with improved functional properties" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):81-81,
https://hdl.handle.net/21.15107/rcub_dais_12350 .

Effects of synthesis parameters on structure and properties of the ceramic/polymer films based on bacterial cellulose

Sknepnek, Aleksandra; Filipović, Suzana; Masković, Pavle; Mirković, Miljana; Miletić, Dunja; Nikšić, Miomir; Pavlović, Vladimir B.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Sknepnek, Aleksandra
AU  - Filipović, Suzana
AU  - Masković, Pavle
AU  - Mirković, Miljana
AU  - Miletić, Dunja
AU  - Nikšić, Miomir
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12348
AB  - Cellulose, as the main constituent of plants, is the most common natural material that is widely used. Bacterial cellulose (BC) is a polymer of β-1,4-glucan chains, extracellularly attached to bacterial cells. It possesses the same structure as plant cellulose but its application has many advantages. BC has tinner threads, better crystallinity, mechanical strength and higher purity. By the means of micro- and nano-pores in the structure, it is possible to retain nano particles and enhance the application of obtained nanostructures. BC lacks antibacterial and antioxidative activity, conductivity and magnetic properties, which lowers the possibility of its application in biomedicine and electronics. To overcome previously mentioned deficiency, it is possible to apply bioactive polymers, nanomaterials or solid particles into the structure. High biocidal potential of TiO2 originates from its photocatalytic properties, and the generation of reactive oxygen species (ROS). At the first site of action, they cause cell membrane damage and afterwards, they attack intracellular components causing cell death. Hydroxyapatite (HAp) is capable to act synergistically with TiO2 and to accelerate its efficiency. Having in mind all characteristics of previously mentioned components, we have investigated the structure, morphology, mechanical properties and antimicrobial activity of advanced ceramics/polymer films. The influence of synthesis duration on BC structure, produced by Komagataeibacter xylinus species, was investigated. Thereafter, the possibility of TiO2/HAp ceramic nanocomposite application in BC was examined. The developed structures were analyzed by SEM and EDS analyzes, as well as XRD and FTIR spectroscopy. Mechanical properties were investigated as well.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - Effects of synthesis parameters on structure and properties of the ceramic/polymer films based on bacterial cellulose
SP  - 78
EP  - 78
UR  - https://hdl.handle.net/21.15107/rcub_dais_12348
ER  - 
@conference{
author = "Sknepnek, Aleksandra and Filipović, Suzana and Masković, Pavle and Mirković, Miljana and Miletić, Dunja and Nikšić, Miomir and Pavlović, Vladimir B.",
year = "2021",
abstract = "Cellulose, as the main constituent of plants, is the most common natural material that is widely used. Bacterial cellulose (BC) is a polymer of β-1,4-glucan chains, extracellularly attached to bacterial cells. It possesses the same structure as plant cellulose but its application has many advantages. BC has tinner threads, better crystallinity, mechanical strength and higher purity. By the means of micro- and nano-pores in the structure, it is possible to retain nano particles and enhance the application of obtained nanostructures. BC lacks antibacterial and antioxidative activity, conductivity and magnetic properties, which lowers the possibility of its application in biomedicine and electronics. To overcome previously mentioned deficiency, it is possible to apply bioactive polymers, nanomaterials or solid particles into the structure. High biocidal potential of TiO2 originates from its photocatalytic properties, and the generation of reactive oxygen species (ROS). At the first site of action, they cause cell membrane damage and afterwards, they attack intracellular components causing cell death. Hydroxyapatite (HAp) is capable to act synergistically with TiO2 and to accelerate its efficiency. Having in mind all characteristics of previously mentioned components, we have investigated the structure, morphology, mechanical properties and antimicrobial activity of advanced ceramics/polymer films. The influence of synthesis duration on BC structure, produced by Komagataeibacter xylinus species, was investigated. Thereafter, the possibility of TiO2/HAp ceramic nanocomposite application in BC was examined. The developed structures were analyzed by SEM and EDS analyzes, as well as XRD and FTIR spectroscopy. Mechanical properties were investigated as well.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "Effects of synthesis parameters on structure and properties of the ceramic/polymer films based on bacterial cellulose",
pages = "78-78",
url = "https://hdl.handle.net/21.15107/rcub_dais_12348"
}
Sknepnek, A., Filipović, S., Masković, P., Mirković, M., Miletić, D., Nikšić, M.,& Pavlović, V. B.. (2021). Effects of synthesis parameters on structure and properties of the ceramic/polymer films based on bacterial cellulose. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 78-78.
https://hdl.handle.net/21.15107/rcub_dais_12348
Sknepnek A, Filipović S, Masković P, Mirković M, Miletić D, Nikšić M, Pavlović VB. Effects of synthesis parameters on structure and properties of the ceramic/polymer films based on bacterial cellulose. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:78-78.
https://hdl.handle.net/21.15107/rcub_dais_12348 .
Sknepnek, Aleksandra, Filipović, Suzana, Masković, Pavle, Mirković, Miljana, Miletić, Dunja, Nikšić, Miomir, Pavlović, Vladimir B., "Effects of synthesis parameters on structure and properties of the ceramic/polymer films based on bacterial cellulose" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):78-78,
https://hdl.handle.net/21.15107/rcub_dais_12348 .

Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG

Obradović, Nina; Filipović, Suzana; Rosenschon, Martin; Füglein, Ekkehard

(Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC), 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Rosenschon, Martin
AU  - Füglein, Ekkehard
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12353
AB  - Ceramic/polymer dielectric composites are widely used as components for electric devices, mainly because of their high chemical stability, mechanical strength, and flexibility. In order to increase dielectric permittivity, ceramic fillers with high dielectric constant have been usually incorporated in the polymer matrix in large amounts. With the aim to enhance dielectric properties of matrix, 5 wt.% of BaTiO3/Fe2O3 core/shell composite was added into the PVDF matrix. Prior to addition, five BaTiO3/Fe2O3 powders were prepared by different synthesis conditions. The changes in crystal structure and lattice dynamics of the obtained ceramic/polymer composite were correlated with changes in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler. Thermal analysis such as DTA/TG/DSC are useful methods to determine various parameters in ceramic/polymer composites. We were able to corroborate that differences in phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have influence on formation of various PVDF allomorph modification, as well as a level of crystallinity.
PB  - Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC)
C3  - Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021)
T1  - Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG
SP  - 29
EP  - 29
UR  - https://hdl.handle.net/21.15107/rcub_dais_12353
ER  - 
@conference{
author = "Obradović, Nina and Filipović, Suzana and Rosenschon, Martin and Füglein, Ekkehard",
year = "2021",
abstract = "Ceramic/polymer dielectric composites are widely used as components for electric devices, mainly because of their high chemical stability, mechanical strength, and flexibility. In order to increase dielectric permittivity, ceramic fillers with high dielectric constant have been usually incorporated in the polymer matrix in large amounts. With the aim to enhance dielectric properties of matrix, 5 wt.% of BaTiO3/Fe2O3 core/shell composite was added into the PVDF matrix. Prior to addition, five BaTiO3/Fe2O3 powders were prepared by different synthesis conditions. The changes in crystal structure and lattice dynamics of the obtained ceramic/polymer composite were correlated with changes in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler. Thermal analysis such as DTA/TG/DSC are useful methods to determine various parameters in ceramic/polymer composites. We were able to corroborate that differences in phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have influence on formation of various PVDF allomorph modification, as well as a level of crystallinity.",
publisher = "Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC)",
journal = "Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021)",
title = "Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG",
pages = "29-29",
url = "https://hdl.handle.net/21.15107/rcub_dais_12353"
}
Obradović, N., Filipović, S., Rosenschon, M.,& Füglein, E.. (2021). Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG. in Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021)
Central and Eastern European Committee for Thermal Analysis and Calorimetry (CEEC-TAC)., 29-29.
https://hdl.handle.net/21.15107/rcub_dais_12353
Obradović N, Filipović S, Rosenschon M, Füglein E. Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG. in Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021). 2021;:29-29.
https://hdl.handle.net/21.15107/rcub_dais_12353 .
Obradović, Nina, Filipović, Suzana, Rosenschon, Martin, Füglein, Ekkehard, "Influence of BaTiO3/Fe2O3 addition on crystallization and polymorphism of PDVF polymer matrix followed by DSC-TG" in Book of abstracts of the 6th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC6) and 15th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2021) (2021):29-29,
https://hdl.handle.net/21.15107/rcub_dais_12353 .

Phase morphological and antimicrobial properties of HAp-TiO2 nanomaterials obtained by different synthesis route

Mirković, Miljana; Filipović, Suzana; Masković, Pavle; Pavlović, Vladimir B.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Mirković, Miljana
AU  - Filipović, Suzana
AU  - Masković, Pavle
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12346
AB  - Due to the growing number of people infected with the new corona virus in the world, there is an increase in bacterial infections, which weakens the immunity. New knowledge about simple and low cost synthesis methods of materials with good structural and antimicrobial properties are of great importance nowadays. Combination of bio ceramic Hydroxyapatite material with good biocompatible characteristics and Titanium dioxide material with good degradation properties of organic molecules when combine together has ability to absorb and decompose the bacteria. Hydroxyapatite/titanium dioxide nanomaterials have been prepared by tree different synthesis route. The morphology and semi quantitative chemical analysis were characterized by scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX). Phase and structural characterization of obtained materials were determined using X-ray powder diffraction method (XRD). The crystallite sizes of the obtained materials were evaluated in the average range from 8 nm to 15 nm. Due to phase analysis by XRD characterization the peak shows presence of anatase phase with hydroxyapatite. Based on XRD peaks positions the hexagonal hydroxyapatite phases are formed in every synthesis route with TiO2 anatase phase. The microstructural studies confirmed that the nanosized HAp coated in a different way with TiO2 depending on a synthesis route. EDX analysis confirmed presence of Ti, Ca, P, O in obtained materials. The IR spectroscopy confirmed vibrational bands characteristic for HAp and titanium with anatase phase. The investigated materials show satisfactory antimicrobial properties.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - Phase morphological and antimicrobial properties of HAp-TiO2 nanomaterials obtained by different synthesis route
SP  - 14
EP  - 14
UR  - https://hdl.handle.net/21.15107/rcub_dais_12346
ER  - 
@conference{
author = "Mirković, Miljana and Filipović, Suzana and Masković, Pavle and Pavlović, Vladimir B.",
year = "2021",
abstract = "Due to the growing number of people infected with the new corona virus in the world, there is an increase in bacterial infections, which weakens the immunity. New knowledge about simple and low cost synthesis methods of materials with good structural and antimicrobial properties are of great importance nowadays. Combination of bio ceramic Hydroxyapatite material with good biocompatible characteristics and Titanium dioxide material with good degradation properties of organic molecules when combine together has ability to absorb and decompose the bacteria. Hydroxyapatite/titanium dioxide nanomaterials have been prepared by tree different synthesis route. The morphology and semi quantitative chemical analysis were characterized by scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX). Phase and structural characterization of obtained materials were determined using X-ray powder diffraction method (XRD). The crystallite sizes of the obtained materials were evaluated in the average range from 8 nm to 15 nm. Due to phase analysis by XRD characterization the peak shows presence of anatase phase with hydroxyapatite. Based on XRD peaks positions the hexagonal hydroxyapatite phases are formed in every synthesis route with TiO2 anatase phase. The microstructural studies confirmed that the nanosized HAp coated in a different way with TiO2 depending on a synthesis route. EDX analysis confirmed presence of Ti, Ca, P, O in obtained materials. The IR spectroscopy confirmed vibrational bands characteristic for HAp and titanium with anatase phase. The investigated materials show satisfactory antimicrobial properties.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "Phase morphological and antimicrobial properties of HAp-TiO2 nanomaterials obtained by different synthesis route",
pages = "14-14",
url = "https://hdl.handle.net/21.15107/rcub_dais_12346"
}
Mirković, M., Filipović, S., Masković, P.,& Pavlović, V. B.. (2021). Phase morphological and antimicrobial properties of HAp-TiO2 nanomaterials obtained by different synthesis route. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 14-14.
https://hdl.handle.net/21.15107/rcub_dais_12346
Mirković M, Filipović S, Masković P, Pavlović VB. Phase morphological and antimicrobial properties of HAp-TiO2 nanomaterials obtained by different synthesis route. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:14-14.
https://hdl.handle.net/21.15107/rcub_dais_12346 .
Mirković, Miljana, Filipović, Suzana, Masković, Pavle, Pavlović, Vladimir B., "Phase morphological and antimicrobial properties of HAp-TiO2 nanomaterials obtained by different synthesis route" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):14-14,
https://hdl.handle.net/21.15107/rcub_dais_12346 .

Optimizacija parametara sinteze nanokompozita na bazi bakterijske nanoceluloze/Fe3O4

Janićijević, Aleksandra; Sknepnek, Aleksandra; Mirković, Miljana; Pavlović, Vladimir; Filipović, Suzana

(Beograd : Savez inženjera i tehničara Srbije, 2021)

TY  - JOUR
AU  - Janićijević, Aleksandra
AU  - Sknepnek, Aleksandra
AU  - Mirković, Miljana
AU  - Pavlović, Vladimir
AU  - Filipović, Suzana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12342
AB  - Napredak u mnogim oblastima tehnike i tehnologije je blisko povezan sa razvojem novih ili unapređenjem postojećih materijala. Imajući u vidu široku primenu bakterijske nanoceluloze (BNC) u raznim oblastima svakodnevnog života, od biomedicine, ekologije do elektronike, kompoziti na bazi BNC su sve rasprostranjeniji i privlače pažnju naučne zajednice. Posebno je značajno detaljno ispitati parametre sinteze koji utiču na promene u kristalnoj strukturi i morfologiji dobijenih kompozita, imajući u vidu da ove promene imaju značajan uticaj na krajnja funkcionalna svojstva. U ovom radu je proučavan kompozitni materijal zasnovan na bakterijskoj nanocelulozi BNC (kao početnoj komponenti) i feromagnetnom Fe3O4. BNC je dobijena aktivnošću bakterija sirćetnog vrenja nakon 7 dana rasta u odgovarajućem medijuma. Istraživanje je usmereno na optimizaciju uslova precipitacije Fe3O4, koji se odnose na promenu intervala stajanja BNC filmova u rastvoru soli gvožđa. Uticaj različitih uslova sinteze je analiziran metodama SEM-EDS, FTIR i XRD.
AB  - Development in many areas of engineering and technology are closely linked to the development of new or improvement of existing materials. Having in mind wide use of bacterial nanocellulose (BNC) in various areas of everyday life, from biomedicine, ecology to electronics, BNC-based composites are becoming widely used and attracting the attention of the scientific community. It is especially important to examine in detail the synthesis parameters that affect the changes in the crystal structure and morphology of the obtained composites, having in mind that these changes have a crucial influence on their final functional properties. In this paper, a composite material based on bacterial nanocellulose BNC (as the matrix) and ferromagnetic Fe3O4 was studied. BNC was obtained by the activity of acetic fermentation bacteria after 7 days of growth in a suitable medium. The research is aimed to optimization of the Fe3O4 precipitation conditions. It's especially considering the time interval of BNC films spend in the iron salt solution. The influence of the performed synthesis conditions was considered by the SEMEDS, FTIR and XRD methods.
PB  - Beograd : Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Optimizacija parametara sinteze nanokompozita na bazi bakterijske nanoceluloze/Fe3O4
SP  - 273
EP  - 278
VL  - 76
IS  - 3
DO  - 10.5937/tehnika2103273J
UR  - https://hdl.handle.net/21.15107/rcub_dais_12342
ER  - 
@article{
author = "Janićijević, Aleksandra and Sknepnek, Aleksandra and Mirković, Miljana and Pavlović, Vladimir and Filipović, Suzana",
year = "2021",
abstract = "Napredak u mnogim oblastima tehnike i tehnologije je blisko povezan sa razvojem novih ili unapređenjem postojećih materijala. Imajući u vidu široku primenu bakterijske nanoceluloze (BNC) u raznim oblastima svakodnevnog života, od biomedicine, ekologije do elektronike, kompoziti na bazi BNC su sve rasprostranjeniji i privlače pažnju naučne zajednice. Posebno je značajno detaljno ispitati parametre sinteze koji utiču na promene u kristalnoj strukturi i morfologiji dobijenih kompozita, imajući u vidu da ove promene imaju značajan uticaj na krajnja funkcionalna svojstva. U ovom radu je proučavan kompozitni materijal zasnovan na bakterijskoj nanocelulozi BNC (kao početnoj komponenti) i feromagnetnom Fe3O4. BNC je dobijena aktivnošću bakterija sirćetnog vrenja nakon 7 dana rasta u odgovarajućem medijuma. Istraživanje je usmereno na optimizaciju uslova precipitacije Fe3O4, koji se odnose na promenu intervala stajanja BNC filmova u rastvoru soli gvožđa. Uticaj različitih uslova sinteze je analiziran metodama SEM-EDS, FTIR i XRD., Development in many areas of engineering and technology are closely linked to the development of new or improvement of existing materials. Having in mind wide use of bacterial nanocellulose (BNC) in various areas of everyday life, from biomedicine, ecology to electronics, BNC-based composites are becoming widely used and attracting the attention of the scientific community. It is especially important to examine in detail the synthesis parameters that affect the changes in the crystal structure and morphology of the obtained composites, having in mind that these changes have a crucial influence on their final functional properties. In this paper, a composite material based on bacterial nanocellulose BNC (as the matrix) and ferromagnetic Fe3O4 was studied. BNC was obtained by the activity of acetic fermentation bacteria after 7 days of growth in a suitable medium. The research is aimed to optimization of the Fe3O4 precipitation conditions. It's especially considering the time interval of BNC films spend in the iron salt solution. The influence of the performed synthesis conditions was considered by the SEMEDS, FTIR and XRD methods.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Optimizacija parametara sinteze nanokompozita na bazi bakterijske nanoceluloze/Fe3O4",
pages = "273-278",
volume = "76",
number = "3",
doi = "10.5937/tehnika2103273J",
url = "https://hdl.handle.net/21.15107/rcub_dais_12342"
}
Janićijević, A., Sknepnek, A., Mirković, M., Pavlović, V.,& Filipović, S.. (2021). Optimizacija parametara sinteze nanokompozita na bazi bakterijske nanoceluloze/Fe3O4. in Tehnika
Beograd : Savez inženjera i tehničara Srbije., 76(3), 273-278.
https://doi.org/10.5937/tehnika2103273J
https://hdl.handle.net/21.15107/rcub_dais_12342
Janićijević A, Sknepnek A, Mirković M, Pavlović V, Filipović S. Optimizacija parametara sinteze nanokompozita na bazi bakterijske nanoceluloze/Fe3O4. in Tehnika. 2021;76(3):273-278.
doi:10.5937/tehnika2103273J
https://hdl.handle.net/21.15107/rcub_dais_12342 .
Janićijević, Aleksandra, Sknepnek, Aleksandra, Mirković, Miljana, Pavlović, Vladimir, Filipović, Suzana, "Optimizacija parametara sinteze nanokompozita na bazi bakterijske nanoceluloze/Fe3O4" in Tehnika, 76, no. 3 (2021):273-278,
https://doi.org/10.5937/tehnika2103273J .,
https://hdl.handle.net/21.15107/rcub_dais_12342 .

Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction

Filipović, Suzana; Obradović, Nina; Anđelković, Ljubica; Olćan, Dragan; Petrović, Jovana; Mirković, Miljana; Pavlović, Vladimir B.; Jeremić, Dejan; Vlahović, Branislav; Đorđević, Antonije

(Belgrade : International Institute for the Science of Sintering, 2021)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Mirković, Miljana
AU  - Pavlović, Vladimir B.
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11230
AB  - Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction
SP  - 1
EP  - 8
VL  - 53
DO  - 10.2298/SOS2101001F
UR  - https://hdl.handle.net/21.15107/rcub_dais_11230
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana and Mirković, Miljana and Pavlović, Vladimir B. and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction",
pages = "1-8",
volume = "53",
doi = "10.2298/SOS2101001F",
url = "https://hdl.handle.net/21.15107/rcub_dais_11230"
}
Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J., Mirković, M., Pavlović, V. B., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 53, 1-8.
https://doi.org/10.2298/SOS2101001F
https://hdl.handle.net/21.15107/rcub_dais_11230
Filipović S, Obradović N, Anđelković L, Olćan D, Petrović J, Mirković M, Pavlović VB, Jeremić D, Vlahović B, Đorđević A. Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering. 2021;53:1-8.
doi:10.2298/SOS2101001F
https://hdl.handle.net/21.15107/rcub_dais_11230 .
Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana, Mirković, Miljana, Pavlović, Vladimir B., Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction" in Science of Sintering, 53 (2021):1-8,
https://doi.org/10.2298/SOS2101001F .,
https://hdl.handle.net/21.15107/rcub_dais_11230 .

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag; Jeremić, Dejan; Pavlović, Vladimir B.; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir B.
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/9515
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
SP  - 111117
VL  - 134
DO  - 10.1016/j.materresbull.2020.111117
UR  - https://hdl.handle.net/21.15107/rcub_dais_9515
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag and Jeremić, Dejan and Pavlović, Vladimir B. and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
pages = "111117",
volume = "134",
doi = "10.1016/j.materresbull.2020.111117",
url = "https://hdl.handle.net/21.15107/rcub_dais_9515"
}
Šuljagić, M., Vulić, P., Jeremić, D., Pavlović, V. B., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M., Nikolić, A. S.,& Anđelković, L.. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
https://hdl.handle.net/21.15107/rcub_dais_9515
Šuljagić M, Vulić P, Jeremić D, Pavlović VB, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković M, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117
https://hdl.handle.net/21.15107/rcub_dais_9515 .
Šuljagić, Marija, Vulić, Predrag, Jeremić, Dejan, Pavlović, Vladimir B., Filipović, Suzana, Kilanski, Lukasz, Lewinska, Sabina, Slawska-Waniewska, Anna, Milenković, Milica, Nikolić, Aleksandar S., Anđelković, Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" in Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 .,
https://hdl.handle.net/21.15107/rcub_dais_9515 .
6
6

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag; Jeremić, Dejan; Pavlović, Vladimir B.; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir B.
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/9514
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
SP  - 111117
VL  - 134
DO  - 10.1016/j.materresbull.2020.111117
UR  - https://hdl.handle.net/21.15107/rcub_dais_9514
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag and Jeremić, Dejan and Pavlović, Vladimir B. and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
pages = "111117",
volume = "134",
doi = "10.1016/j.materresbull.2020.111117",
url = "https://hdl.handle.net/21.15107/rcub_dais_9514"
}
Šuljagić, M., Vulić, P., Jeremić, D., Pavlović, V. B., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M., Nikolić, A. S.,& Anđelković, L.. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
https://hdl.handle.net/21.15107/rcub_dais_9514
Šuljagić M, Vulić P, Jeremić D, Pavlović VB, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković M, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117
https://hdl.handle.net/21.15107/rcub_dais_9514 .
Šuljagić, Marija, Vulić, Predrag, Jeremić, Dejan, Pavlović, Vladimir B., Filipović, Suzana, Kilanski, Lukasz, Lewinska, Sabina, Slawska-Waniewska, Anna, Milenković, Milica, Nikolić, Aleksandar S., Anđelković, Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" in Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 .,
https://hdl.handle.net/21.15107/rcub_dais_9514 .
6
6

Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition

Obradović, Nina; Fahrenholtz, William G.; Corlett, Cole; Filipović, Suzana; Nikolić, Marko G.; Marinković, Bojan A.; Failla, Simone; Sciti, Diletta; Sani, Elisa

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Corlett, Cole
AU  - Filipović, Suzana
AU  - Nikolić, Marko G.
AU  - Marinković, Bojan A.
AU  - Failla, Simone
AU  - Sciti, Diletta
AU  - Sani, Elisa
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11895
AB  - Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation of 30 minutes in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot-pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray diffraction analysis and scanning electron microscopy. Rietveld analysis revealed 100 % pure spinel phase in all sintered specimens, and decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6 % relative density, while other specimens were above 96.5 % relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve the densification behaviour of MgAl2O4 produced from mixed oxide powders, while additives improve microstructure and optical properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition
SP  - 92
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_dais_11895
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Corlett, Cole and Filipović, Suzana and Nikolić, Marko G. and Marinković, Bojan A. and Failla, Simone and Sciti, Diletta and Sani, Elisa",
year = "2021",
abstract = "Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation of 30 minutes in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot-pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray diffraction analysis and scanning electron microscopy. Rietveld analysis revealed 100 % pure spinel phase in all sintered specimens, and decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6 % relative density, while other specimens were above 96.5 % relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve the densification behaviour of MgAl2O4 produced from mixed oxide powders, while additives improve microstructure and optical properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition",
pages = "92-92",
url = "https://hdl.handle.net/21.15107/rcub_dais_11895"
}
Obradović, N., Fahrenholtz, W. G., Corlett, C., Filipović, S., Nikolić, M. G., Marinković, B. A., Failla, S., Sciti, D.,& Sani, E.. (2021). Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 92-92.
https://hdl.handle.net/21.15107/rcub_dais_11895
Obradović N, Fahrenholtz WG, Corlett C, Filipović S, Nikolić MG, Marinković BA, Failla S, Sciti D, Sani E. Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:92-92.
https://hdl.handle.net/21.15107/rcub_dais_11895 .
Obradović, Nina, Fahrenholtz, William G., Corlett, Cole, Filipović, Suzana, Nikolić, Marko G., Marinković, Bojan A., Failla, Simone, Sciti, Diletta, Sani, Elisa, "Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):92-92,
https://hdl.handle.net/21.15107/rcub_dais_11895 .

Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3

Filipović, Suzana; Obradović, Nina; Rosenschon, M.; Füglein, E.; Dojčilović, Radovan; Đorđević, Antonije; Petrović, J.; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Rosenschon, M.
AU  - Füglein, E.
AU  - Dojčilović, Radovan
AU  - Đorđević, Antonije
AU  - Petrović, J.
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11902
AB  - The increase in the utilization of ceramic/polymer composites as components for electric devices is mainly based on their high chemical stability, mechanical strength, and flexibility. The polymers usually have poor dielectric performances. In order to increase the dielectric permittivity, ceramic fillers with high dielectric constant have been used as active fillers, and usually in large amounts, which have a detrimental effect on the mechanical properties of the composite. With the aim to enhance the dielectric properties of the composite without loss of polymer’s flexibility, 5 wt.% of BaTiO3/Fe2O3 core/shell powders, prepared by different synthesis conditions, was added into the PVDF matrix. The effect of the phase composition and morphology of the starting BaTiO3/Fe2O3 core/shell filler on the crystal structure and lattice dynamics was investigated. Based on the results of the thermal analysis, TG/DSC, various parameters of ceramic/polymer composites were determined. We were able to corroborate that differences in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have an influence on the formation of various PVDF allomorph modifications, as well as the level of crystallinity. The dielectric performances of the pure PVDF and polymer/ceramic composites were measured. An enhancement in the dielectric permittivity and decrease in the loss tangent were revealed.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3
SP  - 58
EP  - 58
UR  - https://hdl.handle.net/21.15107/rcub_dais_11902
ER  - 
@conference{
author = "Filipović, Suzana and Obradović, Nina and Rosenschon, M. and Füglein, E. and Dojčilović, Radovan and Đorđević, Antonije and Petrović, J. and Pavlović, Vladimir B.",
year = "2021",
abstract = "The increase in the utilization of ceramic/polymer composites as components for electric devices is mainly based on their high chemical stability, mechanical strength, and flexibility. The polymers usually have poor dielectric performances. In order to increase the dielectric permittivity, ceramic fillers with high dielectric constant have been used as active fillers, and usually in large amounts, which have a detrimental effect on the mechanical properties of the composite. With the aim to enhance the dielectric properties of the composite without loss of polymer’s flexibility, 5 wt.% of BaTiO3/Fe2O3 core/shell powders, prepared by different synthesis conditions, was added into the PVDF matrix. The effect of the phase composition and morphology of the starting BaTiO3/Fe2O3 core/shell filler on the crystal structure and lattice dynamics was investigated. Based on the results of the thermal analysis, TG/DSC, various parameters of ceramic/polymer composites were determined. We were able to corroborate that differences in the phase composition and morphology of BaTiO3/Fe2O3 core/shell filler have an influence on the formation of various PVDF allomorph modifications, as well as the level of crystallinity. The dielectric performances of the pure PVDF and polymer/ceramic composites were measured. An enhancement in the dielectric permittivity and decrease in the loss tangent were revealed.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3",
pages = "58-58",
url = "https://hdl.handle.net/21.15107/rcub_dais_11902"
}
Filipović, S., Obradović, N., Rosenschon, M., Füglein, E., Dojčilović, R., Đorđević, A., Petrović, J.,& Pavlović, V. B.. (2021). Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 58-58.
https://hdl.handle.net/21.15107/rcub_dais_11902
Filipović S, Obradović N, Rosenschon M, Füglein E, Dojčilović R, Đorđević A, Petrović J, Pavlović VB. Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:58-58.
https://hdl.handle.net/21.15107/rcub_dais_11902 .
Filipović, Suzana, Obradović, Nina, Rosenschon, M., Füglein, E., Dojčilović, Radovan, Đorđević, Antonije, Petrović, J., Pavlović, Vladimir B., "Enhanced dielectric properties of PVDF-based composites with BaTiO3 ceramic decorated with Fe2O3" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):58-58,
https://hdl.handle.net/21.15107/rcub_dais_11902 .

Effect of prolonged precipitation on morphology and crystal struture of the bacterial nanocelulose/Fe3O4 composite

Janićijević, Željko; Pavlović, Vladimir B.; Sknepnek, A.; Mirković, M.; Kovačević, D.; Đorđević, Nataša; Filipović, Suzana

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Janićijević, Željko
AU  - Pavlović, Vladimir B.
AU  - Sknepnek, A.
AU  - Mirković, M.
AU  - Kovačević, D.
AU  - Đorđević, Nataša
AU  - Filipović, Suzana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11905
AB  - Cellulose is a biopolymer with a wide range of properties like biocompatibility, hydrophilicity, porosity, good mechanical properties, biodegradability and non-toxicity. The properties and application of cellulose based materials are related to the source of the cellulose production. Despite the fact that the plant cellulose is playing a leading role in obtaining cellulose fibers, it has been found that ecologically and economically, a better source for obtaining cellulose is by fermenting a particular strain of bacteria. Although bacterial nano cellulose (BCN) based materials can be used in numerous industries, from the paper and food industries to biomedicine, their application in electronics is limited because bacterial cellulose does not have conductive and ferromagnetic properties. Having this in mind in this research, the results of the development of nanocomposite materials based on BCN modified with Fe3O4 has been presented. The differences in the interaction of Fe3O4 nanoparticles and BCN obtained by varying precipitation parameters were investigated and the effect of reaction time was followed by SEM-EDS, XRD, and FTIR analysis. It has been found that this type of modifications of the initial BCN, enables development of new composite materials with superior properties, which can be used in various fields of electronics.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Effect of prolonged precipitation on morphology and crystal struture of the bacterial nanocelulose/Fe3O4 composite
SP  - 55
EP  - 56
UR  - https://hdl.handle.net/21.15107/rcub_dais_11905
ER  - 
@conference{
author = "Janićijević, Željko and Pavlović, Vladimir B. and Sknepnek, A. and Mirković, M. and Kovačević, D. and Đorđević, Nataša and Filipović, Suzana",
year = "2021",
abstract = "Cellulose is a biopolymer with a wide range of properties like biocompatibility, hydrophilicity, porosity, good mechanical properties, biodegradability and non-toxicity. The properties and application of cellulose based materials are related to the source of the cellulose production. Despite the fact that the plant cellulose is playing a leading role in obtaining cellulose fibers, it has been found that ecologically and economically, a better source for obtaining cellulose is by fermenting a particular strain of bacteria. Although bacterial nano cellulose (BCN) based materials can be used in numerous industries, from the paper and food industries to biomedicine, their application in electronics is limited because bacterial cellulose does not have conductive and ferromagnetic properties. Having this in mind in this research, the results of the development of nanocomposite materials based on BCN modified with Fe3O4 has been presented. The differences in the interaction of Fe3O4 nanoparticles and BCN obtained by varying precipitation parameters were investigated and the effect of reaction time was followed by SEM-EDS, XRD, and FTIR analysis. It has been found that this type of modifications of the initial BCN, enables development of new composite materials with superior properties, which can be used in various fields of electronics.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Effect of prolonged precipitation on morphology and crystal struture of the bacterial nanocelulose/Fe3O4 composite",
pages = "55-56",
url = "https://hdl.handle.net/21.15107/rcub_dais_11905"
}
Janićijević, Ž., Pavlović, V. B., Sknepnek, A., Mirković, M., Kovačević, D., Đorđević, N.,& Filipović, S.. (2021). Effect of prolonged precipitation on morphology and crystal struture of the bacterial nanocelulose/Fe3O4 composite. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 55-56.
https://hdl.handle.net/21.15107/rcub_dais_11905
Janićijević Ž, Pavlović VB, Sknepnek A, Mirković M, Kovačević D, Đorđević N, Filipović S. Effect of prolonged precipitation on morphology and crystal struture of the bacterial nanocelulose/Fe3O4 composite. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:55-56.
https://hdl.handle.net/21.15107/rcub_dais_11905 .
Janićijević, Željko, Pavlović, Vladimir B., Sknepnek, A., Mirković, M., Kovačević, D., Đorđević, Nataša, Filipović, Suzana, "Effect of prolonged precipitation on morphology and crystal struture of the bacterial nanocelulose/Fe3O4 composite" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):55-56,
https://hdl.handle.net/21.15107/rcub_dais_11905 .

Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal

Obradović, Nina; Rusmirović, Jelena; Filipović, Suzana; Kosanović, Darko; Marinković, Aleksandar; Radić, Danka; Pavlović, Vladimir B.

(Desalination Publications, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Rusmirović, Jelena
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Marinković, Aleksandar
AU  - Radić, Danka
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10040
AB  - Industrial/technological growth is directly connected with environmental pollution, but its influence can be minimized through pollution abatement approaches such as the treatment of industrial wastewater. In this study, novel porous amine-functionalized silicate minerals, specifically, cordierite was investigated for the removal of toxic heavy metals from industrial wastewaters. Cordierite supports were synthesized by mixing MgO, Al2O3 , and SiO2 powders in 2:2:5 molar ratios, and mechanically activated via ball milling in ethanol for 10, 40, or 80 min. Pellets were sintered by heating in air at 20°C min-1 to 1,350°C, for 2 h. Porous supports were produced by coarsely crushing the sintered pellets and mixing the crushed and sieved cordierite powder with 20 wt.% of a pore-forming agent, either nanocellulose or yeast. The resulting pellets were sintered by heating at 5°C min-1 to 700°C in air. The synthetic cordierite support was modified by treatment in poly-ethylenimine. Activated supports were then tested for the removal of Ni2+ and Cd2+ ions. The phase composition of the cordierite supports was analyzed by the X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy. Analysis of adsorption isotherms, kinetics, and thermodynamic parameters indicated that adsorption was a spontaneous, endothermic process with a maximum adsorption capacity of 36 mg g-1 for Cd2+ and 43 mg g-1 for Ni2+. This work has shed light on the mechanism of heavy metal removal from the aquatic medium using the novel hybrid functionalized cordierite-based ceramic.
PB  - Desalination Publications
T2  - Desalination and Water Treatment
T1  - Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal
SP  - 283
EP  - 296
VL  - 192
DO  - 10.5004/dwt.2020.25736
UR  - https://hdl.handle.net/21.15107/rcub_dais_10040
ER  - 
@article{
author = "Obradović, Nina and Rusmirović, Jelena and Filipović, Suzana and Kosanović, Darko and Marinković, Aleksandar and Radić, Danka and Pavlović, Vladimir B.",
year = "2020",
abstract = "Industrial/technological growth is directly connected with environmental pollution, but its influence can be minimized through pollution abatement approaches such as the treatment of industrial wastewater. In this study, novel porous amine-functionalized silicate minerals, specifically, cordierite was investigated for the removal of toxic heavy metals from industrial wastewaters. Cordierite supports were synthesized by mixing MgO, Al2O3 , and SiO2 powders in 2:2:5 molar ratios, and mechanically activated via ball milling in ethanol for 10, 40, or 80 min. Pellets were sintered by heating in air at 20°C min-1 to 1,350°C, for 2 h. Porous supports were produced by coarsely crushing the sintered pellets and mixing the crushed and sieved cordierite powder with 20 wt.% of a pore-forming agent, either nanocellulose or yeast. The resulting pellets were sintered by heating at 5°C min-1 to 700°C in air. The synthetic cordierite support was modified by treatment in poly-ethylenimine. Activated supports were then tested for the removal of Ni2+ and Cd2+ ions. The phase composition of the cordierite supports was analyzed by the X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy. Analysis of adsorption isotherms, kinetics, and thermodynamic parameters indicated that adsorption was a spontaneous, endothermic process with a maximum adsorption capacity of 36 mg g-1 for Cd2+ and 43 mg g-1 for Ni2+. This work has shed light on the mechanism of heavy metal removal from the aquatic medium using the novel hybrid functionalized cordierite-based ceramic.",
publisher = "Desalination Publications",
journal = "Desalination and Water Treatment",
title = "Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal",
pages = "283-296",
volume = "192",
doi = "10.5004/dwt.2020.25736",
url = "https://hdl.handle.net/21.15107/rcub_dais_10040"
}
Obradović, N., Rusmirović, J., Filipović, S., Kosanović, D., Marinković, A., Radić, D.,& Pavlović, V. B.. (2020). Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal. in Desalination and Water Treatment
Desalination Publications., 192, 283-296.
https://doi.org/10.5004/dwt.2020.25736
https://hdl.handle.net/21.15107/rcub_dais_10040
Obradović N, Rusmirović J, Filipović S, Kosanović D, Marinković A, Radić D, Pavlović VB. Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal. in Desalination and Water Treatment. 2020;192:283-296.
doi:10.5004/dwt.2020.25736
https://hdl.handle.net/21.15107/rcub_dais_10040 .
Obradović, Nina, Rusmirović, Jelena, Filipović, Suzana, Kosanović, Darko, Marinković, Aleksandar, Radić, Danka, Pavlović, Vladimir B., "Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal" in Desalination and Water Treatment, 192 (2020):283-296,
https://doi.org/10.5004/dwt.2020.25736 .,
https://hdl.handle.net/21.15107/rcub_dais_10040 .

Study of Nanosized Hydroxyapatite Material Annealing at Different Retention Times

Miljković, Miljana; Kljajević, Ljiljana; Filipović, Suzana; Pavlović, Vladimir B.; Nenadović, Snežana S.

(Belgrade : ETRAN, 2020)

TY  - JOUR
AU  - Miljković, Miljana
AU  - Kljajević, Ljiljana
AU  - Filipović, Suzana
AU  - Pavlović, Vladimir B.
AU  - Nenadović, Snežana S.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10041
AB  - The aim of the study was to investigate the influence of low heating temperatures with two different retention times to optimize the process for obtaining nanosized hydroxyapatite material that can possibly be used in the fields of biology and pharmacy. Nanosized hydroxyapatite was successfully obtained by wet chemical precipitation. The annealing of the material performed at 300 oC with two different retention times i.e. 3 and 6 hours in air atmosphere. Low annealing temperature with extended retention time was selected in terms to reduce energy consumption. FTIR spectroscopy was used to confirm characteristic vibrational bands of hydroxyapatite samples, and presence of carbonate bands of hydroxyapatite annealed for 3h and 6h. X-Ray powder diffraction analysis were used to examine phase composition, determine the size of unit cells and crystallite sizes, and SEMEDS methods were used to obtain particle size and arrangement also grain growth morphology and confirmed the presence of calcium, phosphorous oxygen and carbonate peaks. The results show that different retention time has influence on particle growth as well as unit cell parameters and crystallite sizes changes of hydroxyapatite material.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Study of Nanosized Hydroxyapatite Material Annealing at Different Retention Times
SP  - 405
EP  - 413
VL  - 52
IS  - 4
DO  - 10.2298/SOS2004405M
UR  - https://hdl.handle.net/21.15107/rcub_dais_10041
ER  - 
@article{
author = "Miljković, Miljana and Kljajević, Ljiljana and Filipović, Suzana and Pavlović, Vladimir B. and Nenadović, Snežana S.",
year = "2020",
abstract = "The aim of the study was to investigate the influence of low heating temperatures with two different retention times to optimize the process for obtaining nanosized hydroxyapatite material that can possibly be used in the fields of biology and pharmacy. Nanosized hydroxyapatite was successfully obtained by wet chemical precipitation. The annealing of the material performed at 300 oC with two different retention times i.e. 3 and 6 hours in air atmosphere. Low annealing temperature with extended retention time was selected in terms to reduce energy consumption. FTIR spectroscopy was used to confirm characteristic vibrational bands of hydroxyapatite samples, and presence of carbonate bands of hydroxyapatite annealed for 3h and 6h. X-Ray powder diffraction analysis were used to examine phase composition, determine the size of unit cells and crystallite sizes, and SEMEDS methods were used to obtain particle size and arrangement also grain growth morphology and confirmed the presence of calcium, phosphorous oxygen and carbonate peaks. The results show that different retention time has influence on particle growth as well as unit cell parameters and crystallite sizes changes of hydroxyapatite material.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Study of Nanosized Hydroxyapatite Material Annealing at Different Retention Times",
pages = "405-413",
volume = "52",
number = "4",
doi = "10.2298/SOS2004405M",
url = "https://hdl.handle.net/21.15107/rcub_dais_10041"
}
Miljković, M., Kljajević, L., Filipović, S., Pavlović, V. B.,& Nenadović, S. S.. (2020). Study of Nanosized Hydroxyapatite Material Annealing at Different Retention Times. in Science of Sintering
Belgrade : ETRAN., 52(4), 405-413.
https://doi.org/10.2298/SOS2004405M
https://hdl.handle.net/21.15107/rcub_dais_10041
Miljković M, Kljajević L, Filipović S, Pavlović VB, Nenadović SS. Study of Nanosized Hydroxyapatite Material Annealing at Different Retention Times. in Science of Sintering. 2020;52(4):405-413.
doi:10.2298/SOS2004405M
https://hdl.handle.net/21.15107/rcub_dais_10041 .
Miljković, Miljana, Kljajević, Ljiljana, Filipović, Suzana, Pavlović, Vladimir B., Nenadović, Snežana S., "Study of Nanosized Hydroxyapatite Material Annealing at Different Retention Times" in Science of Sintering, 52, no. 4 (2020):405-413,
https://doi.org/10.2298/SOS2004405M .,
https://hdl.handle.net/21.15107/rcub_dais_10041 .
1

Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis

Filipović, Suzana; Anđelković, Ljubica; Jeremić, Dejan; Vulić, Predrag; Nikolić, Aleksandar; Marković, Smilja; Paunović, Vesna; Lević, Steva; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2020)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Anđelković, Ljubica
AU  - Jeremić, Dejan
AU  - Vulić, Predrag
AU  - Nikolić, Aleksandar
AU  - Marković, Smilja
AU  - Paunović, Vesna
AU  - Lević, Steva
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/9449
AB  - Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180 degrees C, and within a variety of frequencies. Curie temperature was detected at 130 degrees C.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis
SP  - 257
EP  - 268
VL  - 52
DO  - 10.2298/SOS2003257F
UR  - https://hdl.handle.net/21.15107/rcub_dais_9449
ER  - 
@article{
author = "Filipović, Suzana and Anđelković, Ljubica and Jeremić, Dejan and Vulić, Predrag and Nikolić, Aleksandar and Marković, Smilja and Paunović, Vesna and Lević, Steva and Pavlović, Vladimir B.",
year = "2020",
abstract = "Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180 degrees C, and within a variety of frequencies. Curie temperature was detected at 130 degrees C.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis",
pages = "257-268",
volume = "52",
doi = "10.2298/SOS2003257F",
url = "https://hdl.handle.net/21.15107/rcub_dais_9449"
}
Filipović, S., Anđelković, L., Jeremić, D., Vulić, P., Nikolić, A., Marković, S., Paunović, V., Lević, S.,& Pavlović, V. B.. (2020). Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis. in Science of Sintering
Belgrade : ETRAN., 52, 257-268.
https://doi.org/10.2298/SOS2003257F
https://hdl.handle.net/21.15107/rcub_dais_9449
Filipović S, Anđelković L, Jeremić D, Vulić P, Nikolić A, Marković S, Paunović V, Lević S, Pavlović VB. Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis. in Science of Sintering. 2020;52:257-268.
doi:10.2298/SOS2003257F
https://hdl.handle.net/21.15107/rcub_dais_9449 .
Filipović, Suzana, Anđelković, Ljubica, Jeremić, Dejan, Vulić, Predrag, Nikolić, Aleksandar, Marković, Smilja, Paunović, Vesna, Lević, Steva, Pavlović, Vladimir B., "Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis" in Science of Sintering, 52 (2020):257-268,
https://doi.org/10.2298/SOS2003257F .,
https://hdl.handle.net/21.15107/rcub_dais_9449 .

Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Savić, Slobodan; Đorđević, Antonije; Pavlović, Vladimir B.

(Springer, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10027
AB  - Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
SP  - 95
EP  - 107
VL  - 140
DO  - 10.1007/s10973-019-08846-w
UR  - https://hdl.handle.net/21.15107/rcub_dais_10027
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2020",
abstract = "Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "95-107",
volume = "140",
doi = "10.1007/s10973-019-08846-w",
url = "https://hdl.handle.net/21.15107/rcub_dais_10027"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Đorđević, A.,& Pavlović, V. B.. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 140, 95-107.
https://doi.org/10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_10027
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Đorđević A, Pavlović VB. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry. 2020;140:95-107.
doi:10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_10027 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Marković, Smilja, Blagojević, Vladimir A., Lević, Steva, Savić, Slobodan, Đorđević, Antonije, Pavlović, Vladimir B., "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" in Journal of Thermal Analysis and Calorimetry, 140 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w .,
https://hdl.handle.net/21.15107/rcub_dais_10027 .
1
2

Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Savić, Slobodan; Đorđević, Antonije; Pavlović, Vladimir B.

(Springer, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/6910
AB  - Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
SP  - 95
EP  - 107
VL  - 140
DO  - 10.1007/s10973-019-08846-w
UR  - https://hdl.handle.net/21.15107/rcub_dais_6910
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2020",
abstract = "Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "95-107",
volume = "140",
doi = "10.1007/s10973-019-08846-w",
url = "https://hdl.handle.net/21.15107/rcub_dais_6910"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Đorđević, A.,& Pavlović, V. B.. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 140, 95-107.
https://doi.org/10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_6910
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Đorđević A, Pavlović VB. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry. 2020;140:95-107.
doi:10.1007/s10973-019-08846-w
https://hdl.handle.net/21.15107/rcub_dais_6910 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Marković, Smilja, Blagojević, Vladimir A., Lević, Steva, Savić, Slobodan, Đorđević, Antonije, Pavlović, Vladimir B., "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" in Journal of Thermal Analysis and Calorimetry, 140 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w .,
https://hdl.handle.net/21.15107/rcub_dais_6910 .
1
2

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - https://dais.sanu.ac.rs/123456789/5272
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
UR  - https://hdl.handle.net/21.15107/rcub_dais_5272
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095",
url = "https://hdl.handle.net/21.15107/rcub_dais_5272"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5272
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5272 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .,
https://hdl.handle.net/21.15107/rcub_dais_5272 .
12
10

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - https://dais.sanu.ac.rs/123456789/5763
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
UR  - https://hdl.handle.net/21.15107/rcub_dais_5763
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095",
url = "https://hdl.handle.net/21.15107/rcub_dais_5763"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5763
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095
https://hdl.handle.net/21.15107/rcub_dais_5763 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .,
https://hdl.handle.net/21.15107/rcub_dais_5763 .
12
10

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Societa ceramica italiana, 2019)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7022
AB  - Magnesium aluminate, MgAl2O4, and other alumina-based spinels are refractory ceramics with high hardness and resistance to chemical attack while also being possible microwave dielectrics. Pure MgAl2O4 can be optically transparent when fully dense. Spinels exhibit inversion, which results in disorder among occupancy of A and B site cations. The goal of this study was to examine the effects of mechanical activation and composition on the temperature required for spinel formation and the site occupancy in the resulting spinel. 
MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3. The starting powders were mixed by ball milling to homogenize the powders without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1500 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influence of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. 
The main results of this study were that mechanical activation for 60 minutes initiated a mechano-chemical reaction, and resulted in spinel formation at much lower temperatures than within non-activated powders. Microstructures of ceramics sintered below 1400 oC indicated that final stage sintering started at much lower temperatures for activated samples than for non-activated samples. 
Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Societa ceramica italiana
PB  - Politecnico di Torino
C3  - Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 262
EP  - 262
UR  - https://hdl.handle.net/21.15107/rcub_dais_7022
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4, and other alumina-based spinels are refractory ceramics with high hardness and resistance to chemical attack while also being possible microwave dielectrics. Pure MgAl2O4 can be optically transparent when fully dense. Spinels exhibit inversion, which results in disorder among occupancy of A and B site cations. The goal of this study was to examine the effects of mechanical activation and composition on the temperature required for spinel formation and the site occupancy in the resulting spinel. 
MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3. The starting powders were mixed by ball milling to homogenize the powders without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1500 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influence of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. 
The main results of this study were that mechanical activation for 60 minutes initiated a mechano-chemical reaction, and resulted in spinel formation at much lower temperatures than within non-activated powders. Microstructures of ceramics sintered below 1400 oC indicated that final stage sintering started at much lower temperatures for activated samples than for non-activated samples. 
Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Societa ceramica italiana, Politecnico di Torino",
journal = "Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "262-262",
url = "https://hdl.handle.net/21.15107/rcub_dais_7022"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Rogan, J.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
Societa ceramica italiana., 262-262.
https://hdl.handle.net/21.15107/rcub_dais_7022
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Rogan J, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019. 2019;:262-262.
https://hdl.handle.net/21.15107/rcub_dais_7022 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Rogan, Jelena, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019 (2019):262-262,
https://hdl.handle.net/21.15107/rcub_dais_7022 .

Kinetics of thermally activated processes in cordierite-based ceramics

Obradović, Nina; Blagojević, Vladimir A.; Filipović, Suzana; Đorđević, Antonije; Kosanović, Darko; Marković, Smilja; Kachlik, Martin; Maca, Karel; Pavlović, Vladimir B.

(Springer, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir A.
AU  - Filipović, Suzana
AU  - Đorđević, Antonije
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/7048
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
SP  - 2989
EP  - 2998
VL  - 138
DO  - 10.1007/s10973-018-7924-1
UR  - https://hdl.handle.net/21.15107/rcub_dais_7048
ER  - 
@article{
author = "Obradović, Nina and Blagojević, Vladimir A. and Filipović, Suzana and Đorđević, Antonije and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir B.",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2989-2998",
volume = "138",
doi = "10.1007/s10973-018-7924-1",
url = "https://hdl.handle.net/21.15107/rcub_dais_7048"
}
Obradović, N., Blagojević, V. A., Filipović, S., Đorđević, A., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V. B.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 138, 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1
https://hdl.handle.net/21.15107/rcub_dais_7048
Obradović N, Blagojević VA, Filipović S, Đorđević A, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović VB. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138:2989-2998.
doi:10.1007/s10973-018-7924-1
https://hdl.handle.net/21.15107/rcub_dais_7048 .
Obradović, Nina, Blagojević, Vladimir A., Filipović, Suzana, Đorđević, Antonije, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir B., "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 .,
https://hdl.handle.net/21.15107/rcub_dais_7048 .
3
1

Characterization of MgAl2O4 sintered ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Đorđević, Pavle; Marković, Smilja; Rogan, Jelena; Vulić, Predrag J.; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2019)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Đorđević, Pavle
AU  - Marković, Smilja
AU  - Rogan, Jelena
AU  - Vulić, Predrag J.
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6980
AB  - Single crystalline phase MgAl2O4 is made from the predetermined composition of MgO-Al2O3 powder mixture by using ball-milling. Mixtures of MgO and Al2O3 are treated in planetary ball mill for 30, 60, 90 and 120 minutes, in air. The aim of this experiment was to examine phase composition, microstructure, and densification behavior of all sintered samples and to find out which sample has the best features for further use. After sintering in dilatometer at 1500 °C, XRD patterns and SEM images were recorded. The results show that mechanical activation is an efficient method to improve the densification behavior of MgAl2O4 sintered specimens. With the prolonged milling time, densities increased, reaching the maximum value of 2.8 g/cm3 for sample activated 120 minutes.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019
T1  - Characterization of MgAl2O4 sintered ceramics
SP  - 54
EP  - 54
UR  - https://hdl.handle.net/21.15107/rcub_dais_6980
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Đorđević, Pavle and Marković, Smilja and Rogan, Jelena and Vulić, Predrag J. and Pavlović, Vladimir B.",
year = "2019",
abstract = "Single crystalline phase MgAl2O4 is made from the predetermined composition of MgO-Al2O3 powder mixture by using ball-milling. Mixtures of MgO and Al2O3 are treated in planetary ball mill for 30, 60, 90 and 120 minutes, in air. The aim of this experiment was to examine phase composition, microstructure, and densification behavior of all sintered samples and to find out which sample has the best features for further use. After sintering in dilatometer at 1500 °C, XRD patterns and SEM images were recorded. The results show that mechanical activation is an efficient method to improve the densification behavior of MgAl2O4 sintered specimens. With the prolonged milling time, densities increased, reaching the maximum value of 2.8 g/cm3 for sample activated 120 minutes.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019",
title = "Characterization of MgAl2O4 sintered ceramics",
pages = "54-54",
url = "https://hdl.handle.net/21.15107/rcub_dais_6980"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Đorđević, P., Marković, S., Rogan, J., Vulić, P. J.,& Pavlović, V. B.. (2019). Characterization of MgAl2O4 sintered ceramics. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019
Belgrade : Serbian Ceramic Society., 54-54.
https://hdl.handle.net/21.15107/rcub_dais_6980
Obradović N, Fahrenholtz WG, Filipović S, Đorđević P, Marković S, Rogan J, Vulić PJ, Pavlović VB. Characterization of MgAl2O4 sintered ceramics. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019. 2019;:54-54.
https://hdl.handle.net/21.15107/rcub_dais_6980 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Đorđević, Pavle, Marković, Smilja, Rogan, Jelena, Vulić, Predrag J., Pavlović, Vladimir B., "Characterization of MgAl2O4 sintered ceramics" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019 (2019):54-54,
https://hdl.handle.net/21.15107/rcub_dais_6980 .