Marinković, Bojan A.

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Authority KeyName Variants
81ae5b65-935f-40b5-9c37-2875f35a325e
  • Marinković, Bojan A. (19)
  • Marinković, Bojan (15)
Projects
Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology CNPq (National Council for Scientific and Technological Development), Research Productivity Grants
Synthesis, characterization and activity of organic and coordination composition and their application in (bio) nanotechnology Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
Fabrication and characterization of nano-photonic functional structrues in biomedicine and informatics Ministry of Education, Science and Technology of the Republic of Serbia - Prognosis of materials properties from the viewpoint of the synthesis structure–properties relationship
National Council for Scientific and Technological Development of Brazil NSERC - Discovery Grants program
Brazilian National Council for the Scientific and Technological Development (CNPq) Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brazil, Research Productivity Grant
Foundation for Research Support of the State of Rio de Janeiro, Brazil, Grant no. E-26/100.055/2014 Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro, E-26/111.150/2011 PRONEM 25/2010
Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ), Brazil Directed synthesis, structure and properties of multifunctional materials
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) Ministry of Science and Environmental Protection of Serbia (post-doctoral scholarship)
MPNS COST Action 539 - Electroceramics from Nanopowders Produced by Innovative Methods (ELENA) National Council for Scientific and Technological Development, Brazil
National Council for Scientific and Technological Development, Brazil, Research productivity Grant Petrobras S.A.
Senescyt (Secretaria Nacional de Educación Superior, Ciencia, Tecnología e Innovación, Ecuador), scholarship

Author's Bibliography

Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition

Obradović, Nina; Fahrenholtz, William G.; Corlett, Cole; Filipović, Suzana; Nikolić, Marko G.; Marinković, Bojan A.; Failla, Simone; Sciti, Diletta; Sani, Elisa

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Corlett, Cole
AU  - Filipović, Suzana
AU  - Nikolić, Marko G.
AU  - Marinković, Bojan A.
AU  - Failla, Simone
AU  - Sciti, Diletta
AU  - Sani, Elisa
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11895
AB  - Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation of 30 minutes in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot-pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray diffraction analysis and scanning electron microscopy. Rietveld analysis revealed 100 % pure spinel phase in all sintered specimens, and decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6 % relative density, while other specimens were above 96.5 % relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve the densification behaviour of MgAl2O4 produced from mixed oxide powders, while additives improve microstructure and optical properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition
SP  - 92
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_dais_11895
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Corlett, Cole and Filipović, Suzana and Nikolić, Marko G. and Marinković, Bojan A. and Failla, Simone and Sciti, Diletta and Sani, Elisa",
year = "2021",
abstract = "Magnesium aluminate and other alumina-based spinels attract attention due to their high hardness, high mechanical strength, and low dielectric constant. MgAl2O4 was produced by solid-state reaction between MgO and α-Al2O3 powders. Mechanical activation of 30 minutes in a planetary ball mill was used to increase the reactivity of powders. Yttrium oxide and graphene were added to prevent abnormal grain growth during sintering. Samples were sintered by hot-pressing under vacuum at 1450 °C. Phase composition and microstructure of sintered specimens were characterized by X-ray diffraction analysis and scanning electron microscopy. Rietveld analysis revealed 100 % pure spinel phase in all sintered specimens, and decrease in crystallite size with the addition of yttria or graphene. Density measurements indicated that the mechanically activated specimen reached 99.6 % relative density, while other specimens were above 96.5 % relative density. Furthermore, the highest solar absorbance and highest spectral selectivity as a function of temperature were detected for the mechanically activated specimen with graphene addition. Mechanical activation is an efficient method to improve the densification behaviour of MgAl2O4 produced from mixed oxide powders, while additives improve microstructure and optical properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition",
pages = "92-92",
url = "https://hdl.handle.net/21.15107/rcub_dais_11895"
}
Obradović, N., Fahrenholtz, W. G., Corlett, C., Filipović, S., Nikolić, M. G., Marinković, B. A., Failla, S., Sciti, D.,& Sani, E.. (2021). Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 92-92.
https://hdl.handle.net/21.15107/rcub_dais_11895
Obradović N, Fahrenholtz WG, Corlett C, Filipović S, Nikolić MG, Marinković BA, Failla S, Sciti D, Sani E. Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:92-92.
https://hdl.handle.net/21.15107/rcub_dais_11895 .
Obradović, Nina, Fahrenholtz, William G., Corlett, Cole, Filipović, Suzana, Nikolić, Marko G., Marinković, Bojan A., Failla, Simone, Sciti, Diletta, Sani, Elisa, "Microstructural and optical properties of MgAl2O4 Spinel: Effect of Mechanical Activation, Yttrium and Graphene addition" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):92-92,
https://hdl.handle.net/21.15107/rcub_dais_11895 .

Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase

Vuković, Marina; Dinić, Ivana; Nikolić, Marko G.; Marinković, Bojan A.; Costa, Antonio Mario Leal Martins; Radulović, Katarina; Milošević, Olivera; Mančić, Lidija

(Springer, 2020)

TY  - JOUR
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Nikolić, Marko G.
AU  - Marinković, Bojan A.
AU  - Costa, Antonio Mario Leal Martins
AU  - Radulović, Katarina
AU  - Milošević, Olivera
AU  - Mančić, Lidija
PY  - 2020
UR  - https://doi.org/10.1007/s12034-019-1975-1
UR  - http://dais.sanu.ac.rs/123456789/6912
AB  - Up-converting NaYF4:Yb,Er nanoparticles were obtained by polymer-assisted solvothermal synthesis using a common solution of hydrated RE nitrates in ethanol or ethylene glycol. It was shown that polymer choice (polyacrylic acid—PAA, polyvinylpyrrolidone—PVP and chitosan—CS) controls the size and shape of NaYF4:Yb,Er nanoparticles, while the solvent type and pH value affect their crystallinity. Consequently, the spherical nanoparticles of a cubic (α) phase, the average size of which ranged from 60 to 140 nm, were obtained either when PVP/ethanol or PVP/ethylene glycol were used solely during synthesis, whereas NaOH addition induced hexagonal (β) phase nucleation. The formation of the hierarchically organized spherical aggregates and nanofoils was observed when CS and PAA were used during synthesis, respectively. The average crystallite size, microstrain, doping level, lattice parameters, as well as, the presence of the certain ligands on the particle surface were determined and correlated with the intensity of visible-light emission observed under 980 nm laser-diode excitation.
PB  - Springer
T2  - Bulletin of Materials Science
T1  - Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase
SP  - 2
VL  - 43
IS  - 1
DO  - 10.1007/s12034-019-1975-1
UR  - https://hdl.handle.net/21.15107/rcub_dais_6912
ER  - 
@article{
author = "Vuković, Marina and Dinić, Ivana and Nikolić, Marko G. and Marinković, Bojan A. and Costa, Antonio Mario Leal Martins and Radulović, Katarina and Milošević, Olivera and Mančić, Lidija",
year = "2020",
abstract = "Up-converting NaYF4:Yb,Er nanoparticles were obtained by polymer-assisted solvothermal synthesis using a common solution of hydrated RE nitrates in ethanol or ethylene glycol. It was shown that polymer choice (polyacrylic acid—PAA, polyvinylpyrrolidone—PVP and chitosan—CS) controls the size and shape of NaYF4:Yb,Er nanoparticles, while the solvent type and pH value affect their crystallinity. Consequently, the spherical nanoparticles of a cubic (α) phase, the average size of which ranged from 60 to 140 nm, were obtained either when PVP/ethanol or PVP/ethylene glycol were used solely during synthesis, whereas NaOH addition induced hexagonal (β) phase nucleation. The formation of the hierarchically organized spherical aggregates and nanofoils was observed when CS and PAA were used during synthesis, respectively. The average crystallite size, microstrain, doping level, lattice parameters, as well as, the presence of the certain ligands on the particle surface were determined and correlated with the intensity of visible-light emission observed under 980 nm laser-diode excitation.",
publisher = "Springer",
journal = "Bulletin of Materials Science",
title = "Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase",
pages = "2",
volume = "43",
number = "1",
doi = "10.1007/s12034-019-1975-1",
url = "https://hdl.handle.net/21.15107/rcub_dais_6912"
}
Vuković, M., Dinić, I., Nikolić, M. G., Marinković, B. A., Costa, A. M. L. M., Radulović, K., Milošević, O.,& Mančić, L.. (2020). Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase. in Bulletin of Materials Science
Springer., 43(1), 2.
https://doi.org/10.1007/s12034-019-1975-1
https://hdl.handle.net/21.15107/rcub_dais_6912
Vuković M, Dinić I, Nikolić MG, Marinković BA, Costa AMLM, Radulović K, Milošević O, Mančić L. Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase. in Bulletin of Materials Science. 2020;43(1):2.
doi:10.1007/s12034-019-1975-1
https://hdl.handle.net/21.15107/rcub_dais_6912 .
Vuković, Marina, Dinić, Ivana, Nikolić, Marko G., Marinković, Bojan A., Costa, Antonio Mario Leal Martins, Radulović, Katarina, Milošević, Olivera, Mančić, Lidija, "Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase" in Bulletin of Materials Science, 43, no. 1 (2020):2,
https://doi.org/10.1007/s12034-019-1975-1 .,
https://hdl.handle.net/21.15107/rcub_dais_6912 .
1

Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase

Vuković, Marina; Dinić, Ivana; Nikolić, Marko G.; Marinković, Bojan A.; Costa, Antonio Mario Leal Martins; Radulović, Katarina; Milošević, Olivera; Mančić, Lidija

(Springer, 2020)

TY  - JOUR
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Nikolić, Marko G.
AU  - Marinković, Bojan A.
AU  - Costa, Antonio Mario Leal Martins
AU  - Radulović, Katarina
AU  - Milošević, Olivera
AU  - Mančić, Lidija
PY  - 2020
UR  - https://doi.org/10.1007/s12034-019-1975-1
UR  - http://dais.sanu.ac.rs/123456789/6911
AB  - Up-converting NaYF4:Yb,Er nanoparticles were obtained by polymer-assisted solvothermal synthesis using a common solution of hydrated RE nitrates in ethanol or ethylene glycol. It was shown that polymer choice (polyacrylic acid—PAA, polyvinylpyrrolidone—PVP and chitosan—CS) controls the size and shape of NaYF4:Yb,Er nanoparticles, while the solvent type and pH value affect their crystallinity. Consequently, the spherical nanoparticles of a cubic (α) phase, the average size of which ranged from 60 to 140 nm, were obtained either when PVP/ethanol or PVP/ethylene glycol were used solely during synthesis, whereas NaOH addition induced hexagonal (β) phase nucleation. The formation of the hierarchically organized spherical aggregates and nanofoils was observed when CS and PAA were used during synthesis, respectively. The average crystallite size, microstrain, doping level, lattice parameters, as well as, the presence of the certain ligands on the particle surface were determined and correlated with the intensity of visible-light emission observed under 980 nm laser-diode excitation.
PB  - Springer
T2  - Bulletin of Materials Science
T1  - Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase
SP  - 2
VL  - 43
IS  - 1
DO  - 10.1007/s12034-019-1975-1
UR  - https://hdl.handle.net/21.15107/rcub_dais_6911
ER  - 
@article{
author = "Vuković, Marina and Dinić, Ivana and Nikolić, Marko G. and Marinković, Bojan A. and Costa, Antonio Mario Leal Martins and Radulović, Katarina and Milošević, Olivera and Mančić, Lidija",
year = "2020",
abstract = "Up-converting NaYF4:Yb,Er nanoparticles were obtained by polymer-assisted solvothermal synthesis using a common solution of hydrated RE nitrates in ethanol or ethylene glycol. It was shown that polymer choice (polyacrylic acid—PAA, polyvinylpyrrolidone—PVP and chitosan—CS) controls the size and shape of NaYF4:Yb,Er nanoparticles, while the solvent type and pH value affect their crystallinity. Consequently, the spherical nanoparticles of a cubic (α) phase, the average size of which ranged from 60 to 140 nm, were obtained either when PVP/ethanol or PVP/ethylene glycol were used solely during synthesis, whereas NaOH addition induced hexagonal (β) phase nucleation. The formation of the hierarchically organized spherical aggregates and nanofoils was observed when CS and PAA were used during synthesis, respectively. The average crystallite size, microstrain, doping level, lattice parameters, as well as, the presence of the certain ligands on the particle surface were determined and correlated with the intensity of visible-light emission observed under 980 nm laser-diode excitation.",
publisher = "Springer",
journal = "Bulletin of Materials Science",
title = "Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase",
pages = "2",
volume = "43",
number = "1",
doi = "10.1007/s12034-019-1975-1",
url = "https://hdl.handle.net/21.15107/rcub_dais_6911"
}
Vuković, M., Dinić, I., Nikolić, M. G., Marinković, B. A., Costa, A. M. L. M., Radulović, K., Milošević, O.,& Mančić, L.. (2020). Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase. in Bulletin of Materials Science
Springer., 43(1), 2.
https://doi.org/10.1007/s12034-019-1975-1
https://hdl.handle.net/21.15107/rcub_dais_6911
Vuković M, Dinić I, Nikolić MG, Marinković BA, Costa AMLM, Radulović K, Milošević O, Mančić L. Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase. in Bulletin of Materials Science. 2020;43(1):2.
doi:10.1007/s12034-019-1975-1
https://hdl.handle.net/21.15107/rcub_dais_6911 .
Vuković, Marina, Dinić, Ivana, Nikolić, Marko G., Marinković, Bojan A., Costa, Antonio Mario Leal Martins, Radulović, Katarina, Milošević, Olivera, Mančić, Lidija, "Effects of different polymers and solvents on crystallization of theNaYF4:Yb/Er phase" in Bulletin of Materials Science, 43, no. 1 (2020):2,
https://doi.org/10.1007/s12034-019-1975-1 .,
https://hdl.handle.net/21.15107/rcub_dais_6911 .
1

Morphological and structural characterization of spinel MgAl2O4

Filipović, Suzana; Obradović, Nina; Fahrenholtz, William G.; Marinković, Bojan A.; Rogan, Jelena; Lević, Steva; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2019)

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Marinković, Bojan A.
AU  - Rogan, Jelena
AU  - Lević, Steva
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6779
AB  - Magnesium aluminate has spinel structure and very good mechanical, chemical, and thermal properties. Owing to these properties, it has a wide range of applications including refractory ceramics, optically transparent ceramic windows and armors. Its low dielectric permeability and low loss tangent enable its using for integrated electronic devices, as well. Furthermore, as a porous ceramic, magnesium aluminate has important application as humidity sensor, catalyst and filter for waste water purification. In this paper, synthesis and characterization of MgAl2O4 was performed. Stochiometric ratio of MgO and Al2O3powders was mixed and calcined within the temperatures range 1500-1800 oC to produce pure spinel phase. Thereafter pellets were crushed and treated in planetary ball mill for 60 minutes to obtained fine grain. All powders, calcined and milled, were examined for phase composition, crystal structure, and morphology. The obtained results showed that by increasing the temperature denser samples but more fragile have been synthesized. Milling for 1 hour leads to crumble of bigger particles and getting finer, single phase powders. XRPD and Raman spectroscopy showed disorder in crystal structure after milling.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019
T1  - Morphological and structural characterization of spinel MgAl2O4
SP  - 32
EP  - 32
UR  - https://hdl.handle.net/21.15107/rcub_dais_6779
ER  - 
@conference{
author = "Filipović, Suzana and Obradović, Nina and Fahrenholtz, William G. and Marinković, Bojan A. and Rogan, Jelena and Lević, Steva and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate has spinel structure and very good mechanical, chemical, and thermal properties. Owing to these properties, it has a wide range of applications including refractory ceramics, optically transparent ceramic windows and armors. Its low dielectric permeability and low loss tangent enable its using for integrated electronic devices, as well. Furthermore, as a porous ceramic, magnesium aluminate has important application as humidity sensor, catalyst and filter for waste water purification. In this paper, synthesis and characterization of MgAl2O4 was performed. Stochiometric ratio of MgO and Al2O3powders was mixed and calcined within the temperatures range 1500-1800 oC to produce pure spinel phase. Thereafter pellets were crushed and treated in planetary ball mill for 60 minutes to obtained fine grain. All powders, calcined and milled, were examined for phase composition, crystal structure, and morphology. The obtained results showed that by increasing the temperature denser samples but more fragile have been synthesized. Milling for 1 hour leads to crumble of bigger particles and getting finer, single phase powders. XRPD and Raman spectroscopy showed disorder in crystal structure after milling.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019",
title = "Morphological and structural characterization of spinel MgAl2O4",
pages = "32-32",
url = "https://hdl.handle.net/21.15107/rcub_dais_6779"
}
Filipović, S., Obradović, N., Fahrenholtz, W. G., Marinković, B. A., Rogan, J., Lević, S.,& Pavlović, V. B.. (2019). Morphological and structural characterization of spinel MgAl2O4. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019
Belgrade : Serbian Ceramic Society., 32-32.
https://hdl.handle.net/21.15107/rcub_dais_6779
Filipović S, Obradović N, Fahrenholtz WG, Marinković BA, Rogan J, Lević S, Pavlović VB. Morphological and structural characterization of spinel MgAl2O4. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019. 2019;:32-32.
https://hdl.handle.net/21.15107/rcub_dais_6779 .
Filipović, Suzana, Obradović, Nina, Fahrenholtz, William G., Marinković, Bojan A., Rogan, Jelena, Lević, Steva, Pavlović, Vladimir B., "Morphological and structural characterization of spinel MgAl2O4" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019 (2019):32-32,
https://hdl.handle.net/21.15107/rcub_dais_6779 .

Supplementary file: Mancic, L., Djukic-Vukovic, A., Dinic, I., Nikolic, M.G., Rabasovic, M.D., Krmpot, A.J., Costa, A.M.L.M., Marinkovic, B.A., Mojovic, L., Milosevic, O., 2018. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for in vitro cell imaging. RSC Adv. 8, 27429–27437. https://doi.org/10.1039/C8RA04178D

Mančić, Lidija; Đukić Vuković, Aleksandra; Dinić, Ivana; Nikolić, Marko G.; Rabasović, Mihailo D.; Krmpot, Aleksandar; Costa, Antonio Mario Leal Martins; Marinković, Bojan A.; Mojović, Ljiljana; Milošević, Olivera

(2018)

TY  - DATA
AU  - Mančić, Lidija
AU  - Đukić Vuković, Aleksandra
AU  - Dinić, Ivana
AU  - Nikolić, Marko G.
AU  - Rabasović, Mihailo D.
AU  - Krmpot, Aleksandar
AU  - Costa, Antonio Mario Leal Martins
AU  - Marinković, Bojan A.
AU  - Mojović, Ljiljana
AU  - Milošević, Olivera
PY  - 2018
UR  - http://www.rsc.org/suppdata/c8/ra/c8ra04178d/c8ra04178d1.pdf
UR  - http://dais.sanu.ac.rs/123456789/3785
AB  - Fig. S1. TEM (a) and HRTEM (b) images of amino modified NaYF4:Yb,Er UCNPs. Corresponding FFT/IFFT given as insets in b, confirms that
much smaller crystallites notable at the particles surfaces (a) revealed periodic array of cubic alpha phase, (111) plane with d value of 3.140 Å; Fig. S2. XPS spectrum of amino-functionalized NaYF4:Yb,Er UCNPs: survey spectrum and fine-scan spectra of Na 1s, Y 3d, Yb 4d, Er 4d, F 1s
and decomposed ones of C 1s, O 1s and N 1s; Fig. S3. Photostability of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles. The emission intensity was traced during 1h;
T2  - RSC Advances
T1  - Supplementary file: Mancic, L., Djukic-Vukovic, A., Dinic, I., Nikolic, M.G., Rabasovic, M.D., Krmpot, A.J., Costa, A.M.L.M., Marinkovic, B.A., Mojovic, L., Milosevic, O., 2018. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for in vitro cell imaging. RSC Adv. 8, 27429–27437. https://doi.org/10.1039/C8RA04178D
VL  - 8
IS  - 48
UR  - https://hdl.handle.net/21.15107/rcub_dais_3785
ER  - 
@misc{
author = "Mančić, Lidija and Đukić Vuković, Aleksandra and Dinić, Ivana and Nikolić, Marko G. and Rabasović, Mihailo D. and Krmpot, Aleksandar and Costa, Antonio Mario Leal Martins and Marinković, Bojan A. and Mojović, Ljiljana and Milošević, Olivera",
year = "2018",
abstract = "Fig. S1. TEM (a) and HRTEM (b) images of amino modified NaYF4:Yb,Er UCNPs. Corresponding FFT/IFFT given as insets in b, confirms that
much smaller crystallites notable at the particles surfaces (a) revealed periodic array of cubic alpha phase, (111) plane with d value of 3.140 Å; Fig. S2. XPS spectrum of amino-functionalized NaYF4:Yb,Er UCNPs: survey spectrum and fine-scan spectra of Na 1s, Y 3d, Yb 4d, Er 4d, F 1s
and decomposed ones of C 1s, O 1s and N 1s; Fig. S3. Photostability of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles. The emission intensity was traced during 1h;",
journal = "RSC Advances",
title = "Supplementary file: Mancic, L., Djukic-Vukovic, A., Dinic, I., Nikolic, M.G., Rabasovic, M.D., Krmpot, A.J., Costa, A.M.L.M., Marinkovic, B.A., Mojovic, L., Milosevic, O., 2018. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for in vitro cell imaging. RSC Adv. 8, 27429–27437. https://doi.org/10.1039/C8RA04178D",
volume = "8",
number = "48",
url = "https://hdl.handle.net/21.15107/rcub_dais_3785"
}
Mančić, L., Đukić Vuković, A., Dinić, I., Nikolić, M. G., Rabasović, M. D., Krmpot, A., Costa, A. M. L. M., Marinković, B. A., Mojović, L.,& Milošević, O.. (2018). Supplementary file: Mancic, L., Djukic-Vukovic, A., Dinic, I., Nikolic, M.G., Rabasovic, M.D., Krmpot, A.J., Costa, A.M.L.M., Marinkovic, B.A., Mojovic, L., Milosevic, O., 2018. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for in vitro cell imaging. RSC Adv. 8, 27429–27437. https://doi.org/10.1039/C8RA04178D. in RSC Advances, 8(48).
https://hdl.handle.net/21.15107/rcub_dais_3785
Mančić L, Đukić Vuković A, Dinić I, Nikolić MG, Rabasović MD, Krmpot A, Costa AMLM, Marinković BA, Mojović L, Milošević O. Supplementary file: Mancic, L., Djukic-Vukovic, A., Dinic, I., Nikolic, M.G., Rabasovic, M.D., Krmpot, A.J., Costa, A.M.L.M., Marinkovic, B.A., Mojovic, L., Milosevic, O., 2018. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for in vitro cell imaging. RSC Adv. 8, 27429–27437. https://doi.org/10.1039/C8RA04178D. in RSC Advances. 2018;8(48).
https://hdl.handle.net/21.15107/rcub_dais_3785 .
Mančić, Lidija, Đukić Vuković, Aleksandra, Dinić, Ivana, Nikolić, Marko G., Rabasović, Mihailo D., Krmpot, Aleksandar, Costa, Antonio Mario Leal Martins, Marinković, Bojan A., Mojović, Ljiljana, Milošević, Olivera, "Supplementary file: Mancic, L., Djukic-Vukovic, A., Dinic, I., Nikolic, M.G., Rabasovic, M.D., Krmpot, A.J., Costa, A.M.L.M., Marinkovic, B.A., Mojovic, L., Milosevic, O., 2018. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for in vitro cell imaging. RSC Adv. 8, 27429–27437. https://doi.org/10.1039/C8RA04178D" in RSC Advances, 8, no. 48 (2018),
https://hdl.handle.net/21.15107/rcub_dais_3785 .

One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for: In vitro cell imaging

Mančić, Lidija; Đukić Vuković, Aleksandra; Dinić, Ivana; Nikolić, Marko G.; Rabasović, Mihailo D.; Krmpot, Aleksandar; Costa, Antonio Mario Leal Martins; Marinković, Bojan A.; Mojović, Ljiljana; Milošević, Olivera

(London : Royal Society of Chemistry, 2018)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Đukić Vuković, Aleksandra
AU  - Dinić, Ivana
AU  - Nikolić, Marko G.
AU  - Rabasović, Mihailo D.
AU  - Krmpot, Aleksandar
AU  - Costa, Antonio Mario Leal Martins
AU  - Marinković, Bojan A.
AU  - Mojović, Ljiljana
AU  - Milošević, Olivera
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3748
AB  - The emerging up-conversion nanoparticles (UCNPs) offer a wide range of biotechnology applications, from biomarkers and deep tissue imaging, to single molecule tracking and drug delivery. Their successful conjugation to biocompatible agents is crucial for specific molecules recognition and usually requires multiple steps which may lead to low reproducibility. Here, we report a simple and rapid one-step procedure for in situ synthesis of biocompatible amino-functionalized NaYF4:Yb,Er UCNPs that could be used for NIR-driven fluorescence cell labeling. X-ray diffraction showed that UCNPs synthesized through chitosan-assisted solvothermal processing are monophasic and crystallize in a cubic α phase. Scanning and transmission electron microscopy revealed that the obtained crystals are spherical in shape with a mean diameter of 120 nm. Photoluminescence spectra indicated weaker green (2H11/2, 4S3/2 → 4I15/2) and stronger red emission (4F9/2 → 4I15/2), as a result of enhanced non-radiative 4I11/2 → 4I13/2 Er3+ relaxation. The presence of chitosan groups at the surface of UCNPs was confirmed by Fourier transform infrared spectroscopy, thermogravimetry and X-ray photoelectron spectroscopy. This provides their enhanced internalization in cells, at low concentration of 10 μg ml-1, without suppression of cell viability after 24 h of exposure. Furthermore, upon 980 nm laser irradiation, the amino-functionalized NaYF4:Yb,Er UCNPs were successfully used in vitro for labeling of two human cell types, normal gingival and oral squamous cell carcinoma. © 2018 The Royal Society of Chemistry.
PB  - London : Royal Society of Chemistry
T2  - RSC Advances
T2  - RSC Advances
T1  - One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for: In vitro cell imaging
SP  - 27429
EP  - 27437
VL  - 8
IS  - 48
DO  - 10.1039/c8ra04178d
UR  - https://hdl.handle.net/21.15107/rcub_dais_3748
ER  - 
@article{
author = "Mančić, Lidija and Đukić Vuković, Aleksandra and Dinić, Ivana and Nikolić, Marko G. and Rabasović, Mihailo D. and Krmpot, Aleksandar and Costa, Antonio Mario Leal Martins and Marinković, Bojan A. and Mojović, Ljiljana and Milošević, Olivera",
year = "2018",
abstract = "The emerging up-conversion nanoparticles (UCNPs) offer a wide range of biotechnology applications, from biomarkers and deep tissue imaging, to single molecule tracking and drug delivery. Their successful conjugation to biocompatible agents is crucial for specific molecules recognition and usually requires multiple steps which may lead to low reproducibility. Here, we report a simple and rapid one-step procedure for in situ synthesis of biocompatible amino-functionalized NaYF4:Yb,Er UCNPs that could be used for NIR-driven fluorescence cell labeling. X-ray diffraction showed that UCNPs synthesized through chitosan-assisted solvothermal processing are monophasic and crystallize in a cubic α phase. Scanning and transmission electron microscopy revealed that the obtained crystals are spherical in shape with a mean diameter of 120 nm. Photoluminescence spectra indicated weaker green (2H11/2, 4S3/2 → 4I15/2) and stronger red emission (4F9/2 → 4I15/2), as a result of enhanced non-radiative 4I11/2 → 4I13/2 Er3+ relaxation. The presence of chitosan groups at the surface of UCNPs was confirmed by Fourier transform infrared spectroscopy, thermogravimetry and X-ray photoelectron spectroscopy. This provides their enhanced internalization in cells, at low concentration of 10 μg ml-1, without suppression of cell viability after 24 h of exposure. Furthermore, upon 980 nm laser irradiation, the amino-functionalized NaYF4:Yb,Er UCNPs were successfully used in vitro for labeling of two human cell types, normal gingival and oral squamous cell carcinoma. © 2018 The Royal Society of Chemistry.",
publisher = "London : Royal Society of Chemistry",
journal = "RSC Advances, RSC Advances",
title = "One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for: In vitro cell imaging",
pages = "27429-27437",
volume = "8",
number = "48",
doi = "10.1039/c8ra04178d",
url = "https://hdl.handle.net/21.15107/rcub_dais_3748"
}
Mančić, L., Đukić Vuković, A., Dinić, I., Nikolić, M. G., Rabasović, M. D., Krmpot, A., Costa, A. M. L. M., Marinković, B. A., Mojović, L.,& Milošević, O.. (2018). One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for: In vitro cell imaging. in RSC Advances
London : Royal Society of Chemistry., 8(48), 27429-27437.
https://doi.org/10.1039/c8ra04178d
https://hdl.handle.net/21.15107/rcub_dais_3748
Mančić L, Đukić Vuković A, Dinić I, Nikolić MG, Rabasović MD, Krmpot A, Costa AMLM, Marinković BA, Mojović L, Milošević O. One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for: In vitro cell imaging. in RSC Advances. 2018;8(48):27429-27437.
doi:10.1039/c8ra04178d
https://hdl.handle.net/21.15107/rcub_dais_3748 .
Mančić, Lidija, Đukić Vuković, Aleksandra, Dinić, Ivana, Nikolić, Marko G., Rabasović, Mihailo D., Krmpot, Aleksandar, Costa, Antonio Mario Leal Martins, Marinković, Bojan A., Mojović, Ljiljana, Milošević, Olivera, "One-step synthesis of amino-functionalized up-converting NaYF4:Yb,Er nanoparticles for: In vitro cell imaging" in RSC Advances, 8, no. 48 (2018):27429-27437,
https://doi.org/10.1039/c8ra04178d .,
https://hdl.handle.net/21.15107/rcub_dais_3748 .
5
4
5

Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO

Habran, Margarita; Pontón, Patricia I.; Mančić, Lidija; Pandoli, Omar; Krambrock, Klaus; Maia da Costa, Marcelo Eduardo Huguenin; Letichevsky, Sonia; Costa, Antonio Mario Leal Martins; Morgado, Edisson Jr; Marinković, Bojan A.

(Elsevier, 2018)

TY  - JOUR
AU  - Habran, Margarita
AU  - Pontón, Patricia I.
AU  - Mančić, Lidija
AU  - Pandoli, Omar
AU  - Krambrock, Klaus
AU  - Maia da Costa, Marcelo Eduardo Huguenin
AU  - Letichevsky, Sonia
AU  - Costa, Antonio Mario Leal Martins
AU  - Morgado, Edisson Jr
AU  - Marinković, Bojan A.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4084
AB  - The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active toward photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Photochemistry and Photobiology A: Chemistry
T1  - Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO
SP  - 133
EP  - 144
VL  - 365
DO  - 10.1016/j.jphotochem.2018.07.038
UR  - https://hdl.handle.net/21.15107/rcub_dais_4084
ER  - 
@article{
author = "Habran, Margarita and Pontón, Patricia I. and Mančić, Lidija and Pandoli, Omar and Krambrock, Klaus and Maia da Costa, Marcelo Eduardo Huguenin and Letichevsky, Sonia and Costa, Antonio Mario Leal Martins and Morgado, Edisson Jr and Marinković, Bojan A.",
year = "2018",
abstract = "The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active toward photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Photochemistry and Photobiology A: Chemistry",
title = "Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO",
pages = "133-144",
volume = "365",
doi = "10.1016/j.jphotochem.2018.07.038",
url = "https://hdl.handle.net/21.15107/rcub_dais_4084"
}
Habran, M., Pontón, P. I., Mančić, L., Pandoli, O., Krambrock, K., Maia da Costa, M. E. H., Letichevsky, S., Costa, A. M. L. M., Morgado, E. J.,& Marinković, B. A.. (2018). Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry
Elsevier., 365, 133-144.
https://doi.org/10.1016/j.jphotochem.2018.07.038
https://hdl.handle.net/21.15107/rcub_dais_4084
Habran M, Pontón PI, Mančić L, Pandoli O, Krambrock K, Maia da Costa MEH, Letichevsky S, Costa AMLM, Morgado EJ, Marinković BA. Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry. 2018;365:133-144.
doi:10.1016/j.jphotochem.2018.07.038
https://hdl.handle.net/21.15107/rcub_dais_4084 .
Habran, Margarita, Pontón, Patricia I., Mančić, Lidija, Pandoli, Omar, Krambrock, Klaus, Maia da Costa, Marcelo Eduardo Huguenin, Letichevsky, Sonia, Costa, Antonio Mario Leal Martins, Morgado, Edisson Jr, Marinković, Bojan A., "Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO" in Journal of Photochemistry and Photobiology A: Chemistry, 365 (2018):133-144,
https://doi.org/10.1016/j.jphotochem.2018.07.038 .,
https://hdl.handle.net/21.15107/rcub_dais_4084 .
3
2
2

Supplementary Material: Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO

Habran, Margarita; Pontón, Patricia I.; Mančić, Lidija; Pandoli, Omar; Krambrock, Klaus; Maia da Costa, Marcelo Eduardo Huguenin; Letichevsky, Sonia; Costa, Antonio Mario Leal Martins; Morgado, Edisson; Marinković, Bojan A.

(2018)

TY  - DATA
AU  - Habran, Margarita
AU  - Pontón, Patricia I.
AU  - Mančić, Lidija
AU  - Pandoli, Omar
AU  - Krambrock, Klaus
AU  - Maia da Costa, Marcelo Eduardo Huguenin
AU  - Letichevsky, Sonia
AU  - Costa, Antonio Mario Leal Martins
AU  - Morgado, Edisson
AU  - Marinković, Bojan A.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3758
T2  - Journal of Photochemistry and Photobiology A: Chemistry
T1  - Supplementary Material: Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO
VL  - 365
UR  - https://hdl.handle.net/21.15107/rcub_dais_3758
ER  - 
@misc{
author = "Habran, Margarita and Pontón, Patricia I. and Mančić, Lidija and Pandoli, Omar and Krambrock, Klaus and Maia da Costa, Marcelo Eduardo Huguenin and Letichevsky, Sonia and Costa, Antonio Mario Leal Martins and Morgado, Edisson and Marinković, Bojan A.",
year = "2018",
journal = "Journal of Photochemistry and Photobiology A: Chemistry",
title = "Supplementary Material: Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO",
volume = "365",
url = "https://hdl.handle.net/21.15107/rcub_dais_3758"
}
Habran, M., Pontón, P. I., Mančić, L., Pandoli, O., Krambrock, K., Maia da Costa, M. E. H., Letichevsky, S., Costa, A. M. L. M., Morgado, E.,& Marinković, B. A.. (2018). Supplementary Material: Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry, 365.
https://hdl.handle.net/21.15107/rcub_dais_3758
Habran M, Pontón PI, Mančić L, Pandoli O, Krambrock K, Maia da Costa MEH, Letichevsky S, Costa AMLM, Morgado E, Marinković BA. Supplementary Material: Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry. 2018;365.
https://hdl.handle.net/21.15107/rcub_dais_3758 .
Habran, Margarita, Pontón, Patricia I., Mančić, Lidija, Pandoli, Omar, Krambrock, Klaus, Maia da Costa, Marcelo Eduardo Huguenin, Letichevsky, Sonia, Costa, Antonio Mario Leal Martins, Morgado, Edisson, Marinković, Bojan A., "Supplementary Material: Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO" in Journal of Photochemistry and Photobiology A: Chemistry, 365 (2018),
https://hdl.handle.net/21.15107/rcub_dais_3758 .

Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO

Habran, Margarita; Pontón, Patricia I.; Mančić, Lidija; Pandoli, Omar; Krambrock, Klaus; Maia da Costa, Marcelo Eduardo Huguenin; Letichevsky, Sonia; Costa, Antonio Mario Leal Martins; Morgado, Edisson Jr.; Marinković, Bojan A.

(Elsevier, 2018)

TY  - JOUR
AU  - Habran, Margarita
AU  - Pontón, Patricia I.
AU  - Mančić, Lidija
AU  - Pandoli, Omar
AU  - Krambrock, Klaus
AU  - Maia da Costa, Marcelo Eduardo Huguenin
AU  - Letichevsky, Sonia
AU  - Costa, Antonio Mario Leal Martins
AU  - Morgado, Edisson Jr.
AU  - Marinković, Bojan A.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3692
AB  - The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active toward photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Photochemistry and Photobiology A: Chemistry
T1  - Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO
SP  - 133
EP  - 144
VL  - 365
DO  - 10.1016/j.jphotochem.2018.07.038
UR  - https://hdl.handle.net/21.15107/rcub_dais_3692
ER  - 
@article{
author = "Habran, Margarita and Pontón, Patricia I. and Mančić, Lidija and Pandoli, Omar and Krambrock, Klaus and Maia da Costa, Marcelo Eduardo Huguenin and Letichevsky, Sonia and Costa, Antonio Mario Leal Martins and Morgado, Edisson Jr. and Marinković, Bojan A.",
year = "2018",
abstract = "The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active toward photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Photochemistry and Photobiology A: Chemistry",
title = "Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO",
pages = "133-144",
volume = "365",
doi = "10.1016/j.jphotochem.2018.07.038",
url = "https://hdl.handle.net/21.15107/rcub_dais_3692"
}
Habran, M., Pontón, P. I., Mančić, L., Pandoli, O., Krambrock, K., Maia da Costa, M. E. H., Letichevsky, S., Costa, A. M. L. M., Morgado, E. Jr.,& Marinković, B. A.. (2018). Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry
Elsevier., 365, 133-144.
https://doi.org/10.1016/j.jphotochem.2018.07.038
https://hdl.handle.net/21.15107/rcub_dais_3692
Habran M, Pontón PI, Mančić L, Pandoli O, Krambrock K, Maia da Costa MEH, Letichevsky S, Costa AMLM, Morgado EJ, Marinković BA. Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry. 2018;365:133-144.
doi:10.1016/j.jphotochem.2018.07.038
https://hdl.handle.net/21.15107/rcub_dais_3692 .
Habran, Margarita, Pontón, Patricia I., Mančić, Lidija, Pandoli, Omar, Krambrock, Klaus, Maia da Costa, Marcelo Eduardo Huguenin, Letichevsky, Sonia, Costa, Antonio Mario Leal Martins, Morgado, Edisson Jr., Marinković, Bojan A., "Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO" in Journal of Photochemistry and Photobiology A: Chemistry, 365 (2018):133-144,
https://doi.org/10.1016/j.jphotochem.2018.07.038 .,
https://hdl.handle.net/21.15107/rcub_dais_3692 .
3
2
2

Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis

Dinić, Ivana; Mančić, Lidija; Rabanal, Maria Eugenia; Yamamoto, Kazuhiro; Ohara, Satoshi; Tamura, Sayaka; Koji, Tomita; Costa, Antonio Mario Leal Martins; Marinković, Bojan A.; Milošević, Olivera

(Elsevier, 2017)

TY  - JOUR
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Yamamoto, Kazuhiro
AU  - Ohara, Satoshi
AU  - Tamura, Sayaka
AU  - Koji, Tomita
AU  - Costa, Antonio Mario Leal Martins
AU  - Marinković, Bojan A.
AU  - Milošević, Olivera
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/3687
AB  - In this feature article, we highlight our works on compositional and structural dependence of up-converting rare earth (RE) fluorides obtained through ethylenediamine tetraacetic acid (EDTA) assisted hydrothermal synthesis. Various nanostructures were obtained by tuning of experimental conditions, such as precursor’s concentration, degree of doping, reaction time and solvent used during synthesis. We correlated in detail the structural, morphological and optical properties of YF3 and NaYF4 compounds co-doped with Yb3+ and Er3+ (introduced in total mol% of 8 and 20). For this purpose, X-ray powder diffraction, scanning and transmission electron microscopy, energy dispersive X-ray and Furrier transform infrared spectroscopy, as well as, the photoluminescence spectra and decay times were recorded and analyzed. The particle size and phase content were found to be dependent on the nucleation rate, which, in turn, was governed by the precursor concentration, degree of doping and solvent type. The transformation from cubic to hexagonal NaYF4:Yb3+/Er3+ phase was found to be sensitive to the reaction time and precursors concentration, while the crystallization of orthorhombic YF3:Yb3+/Er3+ phase is achieved through lowering of dopants concentration or by changing of solvent during hydrothermal treatment. The up-conversion photoluminescence demonstrated morphology and crystal phase dependence and is found to be superior in microcrystalline samples, independent on their phase composition.
PB  - Elsevier
T2  - Advanced Powder Technology
T2  - Advanced Powder Technology
T1  - Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis
SP  - 73
EP  - 82
VL  - 28
IS  - 1
DO  - 10.1016/j.apt.2016.09.021
UR  - https://hdl.handle.net/21.15107/rcub_dais_3687
ER  - 
@article{
author = "Dinić, Ivana and Mančić, Lidija and Rabanal, Maria Eugenia and Yamamoto, Kazuhiro and Ohara, Satoshi and Tamura, Sayaka and Koji, Tomita and Costa, Antonio Mario Leal Martins and Marinković, Bojan A. and Milošević, Olivera",
year = "2017",
abstract = "In this feature article, we highlight our works on compositional and structural dependence of up-converting rare earth (RE) fluorides obtained through ethylenediamine tetraacetic acid (EDTA) assisted hydrothermal synthesis. Various nanostructures were obtained by tuning of experimental conditions, such as precursor’s concentration, degree of doping, reaction time and solvent used during synthesis. We correlated in detail the structural, morphological and optical properties of YF3 and NaYF4 compounds co-doped with Yb3+ and Er3+ (introduced in total mol% of 8 and 20). For this purpose, X-ray powder diffraction, scanning and transmission electron microscopy, energy dispersive X-ray and Furrier transform infrared spectroscopy, as well as, the photoluminescence spectra and decay times were recorded and analyzed. The particle size and phase content were found to be dependent on the nucleation rate, which, in turn, was governed by the precursor concentration, degree of doping and solvent type. The transformation from cubic to hexagonal NaYF4:Yb3+/Er3+ phase was found to be sensitive to the reaction time and precursors concentration, while the crystallization of orthorhombic YF3:Yb3+/Er3+ phase is achieved through lowering of dopants concentration or by changing of solvent during hydrothermal treatment. The up-conversion photoluminescence demonstrated morphology and crystal phase dependence and is found to be superior in microcrystalline samples, independent on their phase composition.",
publisher = "Elsevier",
journal = "Advanced Powder Technology, Advanced Powder Technology",
title = "Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis",
pages = "73-82",
volume = "28",
number = "1",
doi = "10.1016/j.apt.2016.09.021",
url = "https://hdl.handle.net/21.15107/rcub_dais_3687"
}
Dinić, I., Mančić, L., Rabanal, M. E., Yamamoto, K., Ohara, S., Tamura, S., Koji, T., Costa, A. M. L. M., Marinković, B. A.,& Milošević, O.. (2017). Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis. in Advanced Powder Technology
Elsevier., 28(1), 73-82.
https://doi.org/10.1016/j.apt.2016.09.021
https://hdl.handle.net/21.15107/rcub_dais_3687
Dinić I, Mančić L, Rabanal ME, Yamamoto K, Ohara S, Tamura S, Koji T, Costa AMLM, Marinković BA, Milošević O. Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis. in Advanced Powder Technology. 2017;28(1):73-82.
doi:10.1016/j.apt.2016.09.021
https://hdl.handle.net/21.15107/rcub_dais_3687 .
Dinić, Ivana, Mančić, Lidija, Rabanal, Maria Eugenia, Yamamoto, Kazuhiro, Ohara, Satoshi, Tamura, Sayaka, Koji, Tomita, Costa, Antonio Mario Leal Martins, Marinković, Bojan A., Milošević, Olivera, "Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis" in Advanced Powder Technology, 28, no. 1 (2017):73-82,
https://doi.org/10.1016/j.apt.2016.09.021 .,
https://hdl.handle.net/21.15107/rcub_dais_3687 .
10
8
8

Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles

Dinić, Ivana; Mančić, Lidija; Nikolić, Marko G.; Radulović, Katarina; Marinković, Bojan A.; Milošević, Olivera

(Belgrade : Serbian Ceramic Society, 2017)

TY  - CONF
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Nikolić, Marko G.
AU  - Radulović, Katarina
AU  - Marinković, Bojan A.
AU  - Milošević, Olivera
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/2361
AB  - Over the last decade, solvothermal decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse lanthanide doped upconverting fluorides. Due to their hydrophobic nature such particles could not be used for a conjugation of the molecular targeting agents which is necessary for optical imaging of biological tissues. In this work, hydrophilic NaYF4:Yb,Er (17 mol% Yb; 3mol% Er) nanoparticles were synthesized by facile one-pot hydrothermal synthesis performed with a help of chitosan (CS) and poly(acrylic acid) (PAA). Obtained powders were analyzed by X-ray powder diffraction (XRPD), field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR) and photoluminescence (PL) spectroscopy. The obtained results implied that particle size, shape and surface characteristics are dependent on the polymer choice. Although both powders crystallize in the same crystal arrangement (cubic, Fm-3m) more intense red emission, assigned to the Er3+ 4F9/2 → 4I15/2 electronic transitions, characterize spherical NaYF4:Yb,Er@CS particles. To asses a biological safety of their use, viability of the human gingival fibroblasts (HFG) was additionally tested by a colorimetric MTT assay.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
T1  - Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles
SP  - 67
EP  - 67
UR  - https://hdl.handle.net/21.15107/rcub_dais_2361
ER  - 
@conference{
author = "Dinić, Ivana and Mančić, Lidija and Nikolić, Marko G. and Radulović, Katarina and Marinković, Bojan A. and Milošević, Olivera",
year = "2017",
abstract = "Over the last decade, solvothermal decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse lanthanide doped upconverting fluorides. Due to their hydrophobic nature such particles could not be used for a conjugation of the molecular targeting agents which is necessary for optical imaging of biological tissues. In this work, hydrophilic NaYF4:Yb,Er (17 mol% Yb; 3mol% Er) nanoparticles were synthesized by facile one-pot hydrothermal synthesis performed with a help of chitosan (CS) and poly(acrylic acid) (PAA). Obtained powders were analyzed by X-ray powder diffraction (XRPD), field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR) and photoluminescence (PL) spectroscopy. The obtained results implied that particle size, shape and surface characteristics are dependent on the polymer choice. Although both powders crystallize in the same crystal arrangement (cubic, Fm-3m) more intense red emission, assigned to the Er3+ 4F9/2 → 4I15/2 electronic transitions, characterize spherical NaYF4:Yb,Er@CS particles. To asses a biological safety of their use, viability of the human gingival fibroblasts (HFG) was additionally tested by a colorimetric MTT assay.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017",
title = "Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles",
pages = "67-67",
url = "https://hdl.handle.net/21.15107/rcub_dais_2361"
}
Dinić, I., Mančić, L., Nikolić, M. G., Radulović, K., Marinković, B. A.,& Milošević, O.. (2017). Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
Belgrade : Serbian Ceramic Society., 67-67.
https://hdl.handle.net/21.15107/rcub_dais_2361
Dinić I, Mančić L, Nikolić MG, Radulović K, Marinković BA, Milošević O. Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017. 2017;:67-67.
https://hdl.handle.net/21.15107/rcub_dais_2361 .
Dinić, Ivana, Mančić, Lidija, Nikolić, Marko G., Radulović, Katarina, Marinković, Bojan A., Milošević, Olivera, "Facile synthesis of hydrophilic polymer-capped upconverting NaYF4:Yb,Er particles" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 (2017):67-67,
https://hdl.handle.net/21.15107/rcub_dais_2361 .

Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites

Mančić, Lidija; Pontón, Patricia I.; Letichevsky, Sonia; Costa, Antonio Mario Leal Martins; Marinković, Bojan A.; Rizzo, Fernando C.

(Elsevier, 2016)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Pontón, Patricia I.
AU  - Letichevsky, Sonia
AU  - Costa, Antonio Mario Leal Martins
AU  - Marinković, Bojan A.
AU  - Rizzo, Fernando C.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/2316
AB  - Polyamide 11 (PA11) composites reinforced with pristine and silanized titanate nanotubes (TTNT) were prepared using twin-screw melt compounding. A better dispersion of silanized TTNT in PA11 caused increase of crystallinity and decrease of the long period of PA11 lamellar structure. The increase of glass transition (∼33%) and decomposition temperature (∼3%), as well as, the improvement of Young's, storage and loss modulus (of 17, 27 and 17% respectively) was achieved in the composites loaded with the highest content (2 wt%) of nanofiller silanized by 3-aminopropyltriethoxysilane (APTES), owning to a chemical interaction established at the silanized TTNT-PA11 interface. Contrary to it, lack of compatibility at the pristine TTNT-PA11 interface led to drop (up to 20%) in the strength at break in these composites.
PB  - Elsevier
T2  - Composites Part B: Engineering
T1  - Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites
SP  - 153
EP  - 162
VL  - 93
DO  - 10.1016/j.compositesb.2016.03.028
UR  - https://hdl.handle.net/21.15107/rcub_dais_2316
ER  - 
@article{
author = "Mančić, Lidija and Pontón, Patricia I. and Letichevsky, Sonia and Costa, Antonio Mario Leal Martins and Marinković, Bojan A. and Rizzo, Fernando C.",
year = "2016",
abstract = "Polyamide 11 (PA11) composites reinforced with pristine and silanized titanate nanotubes (TTNT) were prepared using twin-screw melt compounding. A better dispersion of silanized TTNT in PA11 caused increase of crystallinity and decrease of the long period of PA11 lamellar structure. The increase of glass transition (∼33%) and decomposition temperature (∼3%), as well as, the improvement of Young's, storage and loss modulus (of 17, 27 and 17% respectively) was achieved in the composites loaded with the highest content (2 wt%) of nanofiller silanized by 3-aminopropyltriethoxysilane (APTES), owning to a chemical interaction established at the silanized TTNT-PA11 interface. Contrary to it, lack of compatibility at the pristine TTNT-PA11 interface led to drop (up to 20%) in the strength at break in these composites.",
publisher = "Elsevier",
journal = "Composites Part B: Engineering",
title = "Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites",
pages = "153-162",
volume = "93",
doi = "10.1016/j.compositesb.2016.03.028",
url = "https://hdl.handle.net/21.15107/rcub_dais_2316"
}
Mančić, L., Pontón, P. I., Letichevsky, S., Costa, A. M. L. M., Marinković, B. A.,& Rizzo, F. C.. (2016). Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites. in Composites Part B: Engineering
Elsevier., 93, 153-162.
https://doi.org/10.1016/j.compositesb.2016.03.028
https://hdl.handle.net/21.15107/rcub_dais_2316
Mančić L, Pontón PI, Letichevsky S, Costa AMLM, Marinković BA, Rizzo FC. Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites. in Composites Part B: Engineering. 2016;93:153-162.
doi:10.1016/j.compositesb.2016.03.028
https://hdl.handle.net/21.15107/rcub_dais_2316 .
Mančić, Lidija, Pontón, Patricia I., Letichevsky, Sonia, Costa, Antonio Mario Leal Martins, Marinković, Bojan A., Rizzo, Fernando C., "Application of silane grafted titanate nanotubes in reinforcing of polyamide 11 composites" in Composites Part B: Engineering, 93 (2016):153-162,
https://doi.org/10.1016/j.compositesb.2016.03.028 .,
https://hdl.handle.net/21.15107/rcub_dais_2316 .
11
11
12

Development of α-Al2O3 Ceramics for Bottom of Sintering Impeller Furnace

Dos Santos Ortega, Fernando; Barreto Carneiro, Marcio; Mančić, Lidija; Santos, Claudinei; Marinković, Bojan

(Zurich : Trans Tech Publications Inc, 2016)

TY  - CONF
AU  - Barreto Carneiro, Marcio
AU  - Mančić, Lidija
AU  - Santos, Claudinei
AU  - Marinković, Bojan
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/2395
AB  - In this work, the processing of α-Al2O3 ceramics is studied in order to attain the microstructure and mechanical and thermal properties suitable for its application as a special refractory material in sintering furnaces. Samples of a commercial powder with addition of 3% polyvinyl alcohol, a binder additive, was compacted by uniaxial cold pressing and sintered in air at 1500 oC. The effects of powder preparation conditions and the consolidation process on density, thermal expansion and conductivity, hardness, flexural strength and microstructure were analyzed. Ceramics with densities of approximately 90% were obtained, with an average hardness of 14.9 ± 0.6 GPa, characteristic strength of 238 MPa and Weibull modulus of 8. The microstructure had grain sizes between 1 and 2 μm. Processing and powder consolidation and sintering parameters resulted in alumina ceramic with suitable properties for its intended purpose.
PB  - Zurich : Trans Tech Publications Inc
C3  - The 59th Brazilian Ceramic Conference
T1  - Development of α-Al2O3 Ceramics for Bottom of Sintering Impeller Furnace
SP  - 91
EP  - 96
DO  - 10.4028/www.scientific.net/MSF.881.91
UR  - https://hdl.handle.net/21.15107/rcub_dais_2395
ER  - 
@conference{
editor = "Dos Santos Ortega, Fernando",
author = "Barreto Carneiro, Marcio and Mančić, Lidija and Santos, Claudinei and Marinković, Bojan",
year = "2016",
abstract = "In this work, the processing of α-Al2O3 ceramics is studied in order to attain the microstructure and mechanical and thermal properties suitable for its application as a special refractory material in sintering furnaces. Samples of a commercial powder with addition of 3% polyvinyl alcohol, a binder additive, was compacted by uniaxial cold pressing and sintered in air at 1500 oC. The effects of powder preparation conditions and the consolidation process on density, thermal expansion and conductivity, hardness, flexural strength and microstructure were analyzed. Ceramics with densities of approximately 90% were obtained, with an average hardness of 14.9 ± 0.6 GPa, characteristic strength of 238 MPa and Weibull modulus of 8. The microstructure had grain sizes between 1 and 2 μm. Processing and powder consolidation and sintering parameters resulted in alumina ceramic with suitable properties for its intended purpose.",
publisher = "Zurich : Trans Tech Publications Inc",
journal = "The 59th Brazilian Ceramic Conference",
title = "Development of α-Al2O3 Ceramics for Bottom of Sintering Impeller Furnace",
pages = "91-96",
doi = "10.4028/www.scientific.net/MSF.881.91",
url = "https://hdl.handle.net/21.15107/rcub_dais_2395"
}
Dos Santos Ortega, F., Barreto Carneiro, M., Mančić, L., Santos, C.,& Marinković, B.. (2016). Development of α-Al2O3 Ceramics for Bottom of Sintering Impeller Furnace. in The 59th Brazilian Ceramic Conference
Zurich : Trans Tech Publications Inc., 91-96.
https://doi.org/10.4028/www.scientific.net/MSF.881.91
https://hdl.handle.net/21.15107/rcub_dais_2395
Dos Santos Ortega F, Barreto Carneiro M, Mančić L, Santos C, Marinković B. Development of α-Al2O3 Ceramics for Bottom of Sintering Impeller Furnace. in The 59th Brazilian Ceramic Conference. 2016;:91-96.
doi:10.4028/www.scientific.net/MSF.881.91
https://hdl.handle.net/21.15107/rcub_dais_2395 .
Dos Santos Ortega, Fernando, Barreto Carneiro, Marcio, Mančić, Lidija, Santos, Claudinei, Marinković, Bojan, "Development of α-Al2O3 Ceramics for Bottom of Sintering Impeller Furnace" in The 59th Brazilian Ceramic Conference (2016):91-96,
https://doi.org/10.4028/www.scientific.net/MSF.881.91 .,
https://hdl.handle.net/21.15107/rcub_dais_2395 .

Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes

Mančić, Lidija; Osman, Renata F. M.; Costa, Antonio Mario Leal Martins; D'Almeida, Jose Roberto; Marinković, Bojan A.; Rizzo, Fernando C.

(Elsevier, 2015)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Osman, Renata F. M.
AU  - Costa, Antonio Mario Leal Martins
AU  - D'Almeida, Jose Roberto
AU  - Marinković, Bojan A.
AU  - Rizzo, Fernando C.
PY  - 2015
UR  - http://dais.sanu.ac.rs/123456789/3517
AB  - The preparation of polyamide 11 (PA11) based composites reinforced with pristine and surface-modified titanate nanotubes (TTNT) is reported. Twin-screw melt compounding was used to produce composites with up to 2. wt% of TTNT. To enhance dispersion and TTNT compatibility with the thermoplastic, these were modified with cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulphate (SDS). Fourier transform infrared spectroscopy and thermogravimetry were used to demonstrate that surface modification prior to composite processing was successful, while scanning transmission electron microscopy combined with energy-dispersive X-ray analysis confirmed the retention of surfactants on TTNT in composites. Nevertheless, scanning and transmission electron microscopy revealed incomplete dispersion of TTNT inside polyamide. The improved wettability on the TTNT-PA11 interface was observed for composites comprising surface-modified TTNT. Consequently, these composites exhibited better thermal and mechanical properties than those containing pristine TTNT. A significant rise of the decomposition temperature was detected in composites containing TTNT modified with CTAB, while the uppermost increment of the storage and Young's modulus (of about 35% and 26%, respectively) was achieved in the composite comprising 0.5. wt% of TTNT modified with SDS. The increase of the nanofiller content improved the yield strength and led to the drop in the strain at break. © 2015 Elsevier Ltd.
PB  - Elsevier
T2  - Materials and Design
T1  - Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes
SP  - 459
EP  - 467
VL  - 83
DO  - 10.1016/j.matdes.2015.06.059
UR  - https://hdl.handle.net/21.15107/rcub_dais_3517
ER  - 
@article{
author = "Mančić, Lidija and Osman, Renata F. M. and Costa, Antonio Mario Leal Martins and D'Almeida, Jose Roberto and Marinković, Bojan A. and Rizzo, Fernando C.",
year = "2015",
abstract = "The preparation of polyamide 11 (PA11) based composites reinforced with pristine and surface-modified titanate nanotubes (TTNT) is reported. Twin-screw melt compounding was used to produce composites with up to 2. wt% of TTNT. To enhance dispersion and TTNT compatibility with the thermoplastic, these were modified with cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulphate (SDS). Fourier transform infrared spectroscopy and thermogravimetry were used to demonstrate that surface modification prior to composite processing was successful, while scanning transmission electron microscopy combined with energy-dispersive X-ray analysis confirmed the retention of surfactants on TTNT in composites. Nevertheless, scanning and transmission electron microscopy revealed incomplete dispersion of TTNT inside polyamide. The improved wettability on the TTNT-PA11 interface was observed for composites comprising surface-modified TTNT. Consequently, these composites exhibited better thermal and mechanical properties than those containing pristine TTNT. A significant rise of the decomposition temperature was detected in composites containing TTNT modified with CTAB, while the uppermost increment of the storage and Young's modulus (of about 35% and 26%, respectively) was achieved in the composite comprising 0.5. wt% of TTNT modified with SDS. The increase of the nanofiller content improved the yield strength and led to the drop in the strain at break. © 2015 Elsevier Ltd.",
publisher = "Elsevier",
journal = "Materials and Design",
title = "Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes",
pages = "459-467",
volume = "83",
doi = "10.1016/j.matdes.2015.06.059",
url = "https://hdl.handle.net/21.15107/rcub_dais_3517"
}
Mančić, L., Osman, R. F. M., Costa, A. M. L. M., D'Almeida, J. R., Marinković, B. A.,& Rizzo, F. C.. (2015). Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes. in Materials and Design
Elsevier., 83, 459-467.
https://doi.org/10.1016/j.matdes.2015.06.059
https://hdl.handle.net/21.15107/rcub_dais_3517
Mančić L, Osman RFM, Costa AMLM, D'Almeida JR, Marinković BA, Rizzo FC. Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes. in Materials and Design. 2015;83:459-467.
doi:10.1016/j.matdes.2015.06.059
https://hdl.handle.net/21.15107/rcub_dais_3517 .
Mančić, Lidija, Osman, Renata F. M., Costa, Antonio Mario Leal Martins, D'Almeida, Jose Roberto, Marinković, Bojan A., Rizzo, Fernando C., "Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes" in Materials and Design, 83 (2015):459-467,
https://doi.org/10.1016/j.matdes.2015.06.059 .,
https://hdl.handle.net/21.15107/rcub_dais_3517 .
26
23
29

Lepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds

Marinković, Bojan A.; Pontón, Patricia I.; Resende, J. M.; Letichevsky, Sonia; Habran, Margarita; Viol, J. B.; Pandoli, Omar; Mančić, Lidija

(Elsevier, 2015)

TY  - JOUR
AU  - Marinković, Bojan A.
AU  - Pontón, Patricia I.
AU  - Resende, J. M.
AU  - Letichevsky, Sonia
AU  - Habran, Margarita
AU  - Viol, J. B.
AU  - Pandoli, Omar
AU  - Mančić, Lidija
PY  - 2015
UR  - http://dais.sanu.ac.rs/123456789/3515
AB  - Efficient methods for the synthesis of layered structure nanomaterials (nanosheets), their complete exfoliation (delamination) into the layers of atomic thickness and design of organic-inorganic nanohybrids present important stages toward development of improved polymer-based nanocomposites and pillared heterostructures with potential application in purification technologies such as photocatalysis. A rapid and efficient exfoliation process of protonated layered ferrititanates with lepidocrocite-like structure and formation of organic-inorganic nanohybrids is performed starting from the nanosheets composed of only a few host layers and nanometric lateral dimensions using quaternary ammonium compounds. These nanosheets are initially synthesized from a highly abundant precursor through an alkaline hydrothermal route. We demonstrated that dimethyldioctadecylammonium cations strongly interact with the exfoliated single host layers (0.75. nm thick) providing thermal stability (~ 500 °C) to the as-prepared organic-inorganic nanohybrid over the temperature range commonly applied for the processing of thermoplastic nanocomposites. © 2015 Elsevier Ltd.
PB  - Elsevier
T2  - Materials and Design
T1  - Lepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds
SP  - 197
EP  - 204
VL  - 85
DO  - 10.1016/j.matdes.2015.06.171
UR  - https://hdl.handle.net/21.15107/rcub_dais_3515
ER  - 
@article{
author = "Marinković, Bojan A. and Pontón, Patricia I. and Resende, J. M. and Letichevsky, Sonia and Habran, Margarita and Viol, J. B. and Pandoli, Omar and Mančić, Lidija",
year = "2015",
abstract = "Efficient methods for the synthesis of layered structure nanomaterials (nanosheets), their complete exfoliation (delamination) into the layers of atomic thickness and design of organic-inorganic nanohybrids present important stages toward development of improved polymer-based nanocomposites and pillared heterostructures with potential application in purification technologies such as photocatalysis. A rapid and efficient exfoliation process of protonated layered ferrititanates with lepidocrocite-like structure and formation of organic-inorganic nanohybrids is performed starting from the nanosheets composed of only a few host layers and nanometric lateral dimensions using quaternary ammonium compounds. These nanosheets are initially synthesized from a highly abundant precursor through an alkaline hydrothermal route. We demonstrated that dimethyldioctadecylammonium cations strongly interact with the exfoliated single host layers (0.75. nm thick) providing thermal stability (~ 500 °C) to the as-prepared organic-inorganic nanohybrid over the temperature range commonly applied for the processing of thermoplastic nanocomposites. © 2015 Elsevier Ltd.",
publisher = "Elsevier",
journal = "Materials and Design",
title = "Lepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds",
pages = "197-204",
volume = "85",
doi = "10.1016/j.matdes.2015.06.171",
url = "https://hdl.handle.net/21.15107/rcub_dais_3515"
}
Marinković, B. A., Pontón, P. I., Resende, J. M., Letichevsky, S., Habran, M., Viol, J. B., Pandoli, O.,& Mančić, L.. (2015). Lepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds. in Materials and Design
Elsevier., 85, 197-204.
https://doi.org/10.1016/j.matdes.2015.06.171
https://hdl.handle.net/21.15107/rcub_dais_3515
Marinković BA, Pontón PI, Resende JM, Letichevsky S, Habran M, Viol JB, Pandoli O, Mančić L. Lepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds. in Materials and Design. 2015;85:197-204.
doi:10.1016/j.matdes.2015.06.171
https://hdl.handle.net/21.15107/rcub_dais_3515 .
Marinković, Bojan A., Pontón, Patricia I., Resende, J. M., Letichevsky, Sonia, Habran, Margarita, Viol, J. B., Pandoli, Omar, Mančić, Lidija, "Lepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds" in Materials and Design, 85 (2015):197-204,
https://doi.org/10.1016/j.matdes.2015.06.171 .,
https://hdl.handle.net/21.15107/rcub_dais_3515 .
3
3
3
3

Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion

Soares, Alexandre Roberto; Pontón, Patricia I.; Mančić, Lidija; D'Almeida, Jose Roberto; Romao, Carl P.; White, Mary Ann; Marinković, Bojan

(Springer, 2014)

TY  - JOUR
AU  - Soares, Alexandre Roberto
AU  - Pontón, Patricia I.
AU  - Mančić, Lidija
AU  - D'Almeida, Jose Roberto
AU  - Romao, Carl P.
AU  - White, Mary Ann
AU  - Marinković, Bojan
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/664
AB  - Recently, polymer composites reinforced with low fractions of thermomiotic nanoceramics have triggered a lot of research. The efforts have been focused on achieving considerable reduction of the coefficient of thermal expansion (CTE) of polymeric materials without deterioration of other physical properties. In this context, polyethylene (PE) composites reinforced with different loads of Al2Mo3O12 nanofillers (0.5–4 mass %) were fabricated by micro-compounding. To enhance the interfacial interaction between the two components, chemical functionalization of Al2Mo3O12 was performed with vinyltrimethoxysilane (VTMS) prior to micro-compounding. Infrared spectroscopy and thermogravimetry demonstrated the successful grafting of VTMS on the Al2Mo3O12 surface. The composites showed strongly decreased CTEs, up to 46 % reduction for loadings of 4 mass % compared with neat PE, suggesting intimate filler–matrix interactions. The variation of CTEs of the composites in terms of the filler fraction was successfully described by Turner’s model allowing calculation of the bulk modulus of monoclinic Al2Mo3O12 (13.6 ± 2.6 GPa), in agreement with the value obtained by an ultrasonic method. The thermal stability of the composites was improved, although the addition of functionalized fillers decreased the degree of crystallinity of the PE to a small extent. The Young’s modulus and yield strength of the composites increased from 6.6 to 19.1 % and 4.0–6.0 %, respectively, supporting the existence of strong filler–matrix interactions, contributing to an efficient load transfer. Finite element analysis of thermal stresses indicated absence of plastic deformation of the matrix or fracture of the nanofillers, for a 100 K temperature drop.
PB  - Springer
T2  - Journal of Materials Science
T1  - Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion
SP  - 7870
EP  - 7882
VL  - 49
IS  - 22
DO  - 10.1007/s10853-014-8498-3
UR  - https://hdl.handle.net/21.15107/rcub_dais_664
ER  - 
@article{
author = "Soares, Alexandre Roberto and Pontón, Patricia I. and Mančić, Lidija and D'Almeida, Jose Roberto and Romao, Carl P. and White, Mary Ann and Marinković, Bojan",
year = "2014",
abstract = "Recently, polymer composites reinforced with low fractions of thermomiotic nanoceramics have triggered a lot of research. The efforts have been focused on achieving considerable reduction of the coefficient of thermal expansion (CTE) of polymeric materials without deterioration of other physical properties. In this context, polyethylene (PE) composites reinforced with different loads of Al2Mo3O12 nanofillers (0.5–4 mass %) were fabricated by micro-compounding. To enhance the interfacial interaction between the two components, chemical functionalization of Al2Mo3O12 was performed with vinyltrimethoxysilane (VTMS) prior to micro-compounding. Infrared spectroscopy and thermogravimetry demonstrated the successful grafting of VTMS on the Al2Mo3O12 surface. The composites showed strongly decreased CTEs, up to 46 % reduction for loadings of 4 mass % compared with neat PE, suggesting intimate filler–matrix interactions. The variation of CTEs of the composites in terms of the filler fraction was successfully described by Turner’s model allowing calculation of the bulk modulus of monoclinic Al2Mo3O12 (13.6 ± 2.6 GPa), in agreement with the value obtained by an ultrasonic method. The thermal stability of the composites was improved, although the addition of functionalized fillers decreased the degree of crystallinity of the PE to a small extent. The Young’s modulus and yield strength of the composites increased from 6.6 to 19.1 % and 4.0–6.0 %, respectively, supporting the existence of strong filler–matrix interactions, contributing to an efficient load transfer. Finite element analysis of thermal stresses indicated absence of plastic deformation of the matrix or fracture of the nanofillers, for a 100 K temperature drop.",
publisher = "Springer",
journal = "Journal of Materials Science",
title = "Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion",
pages = "7870-7882",
volume = "49",
number = "22",
doi = "10.1007/s10853-014-8498-3",
url = "https://hdl.handle.net/21.15107/rcub_dais_664"
}
Soares, A. R., Pontón, P. I., Mančić, L., D'Almeida, J. R., Romao, C. P., White, M. A.,& Marinković, B.. (2014). Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion. in Journal of Materials Science
Springer., 49(22), 7870-7882.
https://doi.org/10.1007/s10853-014-8498-3
https://hdl.handle.net/21.15107/rcub_dais_664
Soares AR, Pontón PI, Mančić L, D'Almeida JR, Romao CP, White MA, Marinković B. Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion. in Journal of Materials Science. 2014;49(22):7870-7882.
doi:10.1007/s10853-014-8498-3
https://hdl.handle.net/21.15107/rcub_dais_664 .
Soares, Alexandre Roberto, Pontón, Patricia I., Mančić, Lidija, D'Almeida, Jose Roberto, Romao, Carl P., White, Mary Ann, Marinković, Bojan, "Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion" in Journal of Materials Science, 49, no. 22 (2014):7870-7882,
https://doi.org/10.1007/s10853-014-8498-3 .,
https://hdl.handle.net/21.15107/rcub_dais_664 .
24
21
23

Effect of processing parameters on structural, morphological and optical Y2O3:Yb3+/Ho3+ powders characteristics

Mančić, Lidija; Lojpur, Vesna; Marinković, Bojan; de Pinho Mauricio, M. H.; Dramićanin, Miroslav; Milošević, Olivera

(Elsevier, 2014)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Marinković, Bojan
AU  - de Pinho Mauricio, M. H.
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/656
AB  - Rod-like and flake-like up-converting Y2O3:Yb3+/Ho3+ particles which are composed of nanoparticles with size less than 100 nm, are prepared by a simple hydrothermal processing at 473 K (3 h) followed by additional thermal treatment at 1373 K (3 and 12 h). The effect of precursor pH value on the formation of Y2O3:Yb3+/Ho3+ is followed through X-ray powder diffractometry (XRPD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Structural refinement confirms formation of the cubic bixbyte structure (S.G. Ia-3) with the non-uniform accommodation of dopants at C2 and S6 cationic sites. Under 978 nm laser excitation, strong green (530–570 nm) up-conversion is observed in all samples. The emission shows a decrease in intensity with an increase in external temperature, indicating FIR (fluorescence intensity ratio) based temperature sensing behavior of 0.52% for the 5F4 → 5I8/5S2 → 5I8 transitions.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - Effect of processing parameters on structural, morphological and optical Y2O3:Yb3+/Ho3+ powders characteristics
SP  - 1449
EP  - 1454
VL  - 25
IS  - 5
DO  - 10.1016/j.apt.2014.03.015
UR  - https://hdl.handle.net/21.15107/rcub_dais_656
ER  - 
@article{
author = "Mančić, Lidija and Lojpur, Vesna and Marinković, Bojan and de Pinho Mauricio, M. H. and Dramićanin, Miroslav and Milošević, Olivera",
year = "2014",
abstract = "Rod-like and flake-like up-converting Y2O3:Yb3+/Ho3+ particles which are composed of nanoparticles with size less than 100 nm, are prepared by a simple hydrothermal processing at 473 K (3 h) followed by additional thermal treatment at 1373 K (3 and 12 h). The effect of precursor pH value on the formation of Y2O3:Yb3+/Ho3+ is followed through X-ray powder diffractometry (XRPD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Structural refinement confirms formation of the cubic bixbyte structure (S.G. Ia-3) with the non-uniform accommodation of dopants at C2 and S6 cationic sites. Under 978 nm laser excitation, strong green (530–570 nm) up-conversion is observed in all samples. The emission shows a decrease in intensity with an increase in external temperature, indicating FIR (fluorescence intensity ratio) based temperature sensing behavior of 0.52% for the 5F4 → 5I8/5S2 → 5I8 transitions.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "Effect of processing parameters on structural, morphological and optical Y2O3:Yb3+/Ho3+ powders characteristics",
pages = "1449-1454",
volume = "25",
number = "5",
doi = "10.1016/j.apt.2014.03.015",
url = "https://hdl.handle.net/21.15107/rcub_dais_656"
}
Mančić, L., Lojpur, V., Marinković, B., de Pinho Mauricio, M. H., Dramićanin, M.,& Milošević, O.. (2014). Effect of processing parameters on structural, morphological and optical Y2O3:Yb3+/Ho3+ powders characteristics. in Advanced Powder Technology
Elsevier., 25(5), 1449-1454.
https://doi.org/10.1016/j.apt.2014.03.015
https://hdl.handle.net/21.15107/rcub_dais_656
Mančić L, Lojpur V, Marinković B, de Pinho Mauricio MH, Dramićanin M, Milošević O. Effect of processing parameters on structural, morphological and optical Y2O3:Yb3+/Ho3+ powders characteristics. in Advanced Powder Technology. 2014;25(5):1449-1454.
doi:10.1016/j.apt.2014.03.015
https://hdl.handle.net/21.15107/rcub_dais_656 .
Mančić, Lidija, Lojpur, Vesna, Marinković, Bojan, de Pinho Mauricio, M. H., Dramićanin, Miroslav, Milošević, Olivera, "Effect of processing parameters on structural, morphological and optical Y2O3:Yb3+/Ho3+ powders characteristics" in Advanced Powder Technology, 25, no. 5 (2014):1449-1454,
https://doi.org/10.1016/j.apt.2014.03.015 .,
https://hdl.handle.net/21.15107/rcub_dais_656 .
8
9
8

Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion

Soares, Alexandre Roberto; Pontón, Patricia I.; Mančić, Lidija; D'Almeida, Jose Roberto; Romao, Carl P.; White, Mary Ann; Marinković, Bojan

(2014)

TY  - JOUR
AU  - Soares, Alexandre Roberto
AU  - Pontón, Patricia I.
AU  - Mančić, Lidija
AU  - D'Almeida, Jose Roberto
AU  - Romao, Carl P.
AU  - White, Mary Ann
AU  - Marinković, Bojan
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/567
AB  - Recently, polymer composites reinforced with low fractions of thermomiotic nanoceramics have triggered a lot of research. The efforts have been focused on achieving considerable reduction of the coefficient of thermal expansion (CTE) of polymeric materials without deterioration of other physical properties. In this context, polyethylene (PE) composites reinforced with different loads of Al2Mo3O12 nanofillers (0.5–4 mass %) were fabricated by micro-compounding. To enhance the interfacial interaction between the two components, chemical functionalization of Al2Mo3O12 was performed with vinyltrimethoxysilane (VTMS) prior to micro-compounding. Infrared spectroscopy and thermogravimetry demonstrated the successful grafting of VTMS on the Al2Mo3O12 surface. The composites showed strongly decreased CTEs, up to 46 % reduction for loadings of 4 mass % compared with neat PE, suggesting intimate filler–matrix interactions. The variation of CTEs of the composites in terms of the filler fraction was successfully described by Turner’s model allowing calculation of the bulk modulus of monoclinic Al2Mo3O12 (13.6 ± 2.6 GPa), in agreement with the value obtained by an ultrasonic method. The thermal stability of the composites was improved, although the addition of functionalized fillers decreased the degree of crystallinity of the PE to a small extent. The Young’s modulus and yield strength of the composites increased from 6.6 to 19.1 % and 4.0–6.0 %, respectively, supporting the existence of strong filler–matrix interactions, contributing to an efficient load transfer. Finite element analysis of thermal stresses indicated absence of plastic deformation of the matrix or fracture of the nanofillers, for a 100 K temperature drop.
T2  - Journal of Materials Science
T1  - Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion
SP  - 7870
EP  - 7882
VL  - 49
IS  - 22
DO  - 10.1007/s10853-014-8498-3
UR  - https://hdl.handle.net/21.15107/rcub_dais_567
ER  - 
@article{
author = "Soares, Alexandre Roberto and Pontón, Patricia I. and Mančić, Lidija and D'Almeida, Jose Roberto and Romao, Carl P. and White, Mary Ann and Marinković, Bojan",
year = "2014",
abstract = "Recently, polymer composites reinforced with low fractions of thermomiotic nanoceramics have triggered a lot of research. The efforts have been focused on achieving considerable reduction of the coefficient of thermal expansion (CTE) of polymeric materials without deterioration of other physical properties. In this context, polyethylene (PE) composites reinforced with different loads of Al2Mo3O12 nanofillers (0.5–4 mass %) were fabricated by micro-compounding. To enhance the interfacial interaction between the two components, chemical functionalization of Al2Mo3O12 was performed with vinyltrimethoxysilane (VTMS) prior to micro-compounding. Infrared spectroscopy and thermogravimetry demonstrated the successful grafting of VTMS on the Al2Mo3O12 surface. The composites showed strongly decreased CTEs, up to 46 % reduction for loadings of 4 mass % compared with neat PE, suggesting intimate filler–matrix interactions. The variation of CTEs of the composites in terms of the filler fraction was successfully described by Turner’s model allowing calculation of the bulk modulus of monoclinic Al2Mo3O12 (13.6 ± 2.6 GPa), in agreement with the value obtained by an ultrasonic method. The thermal stability of the composites was improved, although the addition of functionalized fillers decreased the degree of crystallinity of the PE to a small extent. The Young’s modulus and yield strength of the composites increased from 6.6 to 19.1 % and 4.0–6.0 %, respectively, supporting the existence of strong filler–matrix interactions, contributing to an efficient load transfer. Finite element analysis of thermal stresses indicated absence of plastic deformation of the matrix or fracture of the nanofillers, for a 100 K temperature drop.",
journal = "Journal of Materials Science",
title = "Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion",
pages = "7870-7882",
volume = "49",
number = "22",
doi = "10.1007/s10853-014-8498-3",
url = "https://hdl.handle.net/21.15107/rcub_dais_567"
}
Soares, A. R., Pontón, P. I., Mančić, L., D'Almeida, J. R., Romao, C. P., White, M. A.,& Marinković, B.. (2014). Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion. in Journal of Materials Science, 49(22), 7870-7882.
https://doi.org/10.1007/s10853-014-8498-3
https://hdl.handle.net/21.15107/rcub_dais_567
Soares AR, Pontón PI, Mančić L, D'Almeida JR, Romao CP, White MA, Marinković B. Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion. in Journal of Materials Science. 2014;49(22):7870-7882.
doi:10.1007/s10853-014-8498-3
https://hdl.handle.net/21.15107/rcub_dais_567 .
Soares, Alexandre Roberto, Pontón, Patricia I., Mančić, Lidija, D'Almeida, Jose Roberto, Romao, Carl P., White, Mary Ann, Marinković, Bojan, "Al2Mo3O12/polyethylene composites with reduced coefficient of thermal expansion" in Journal of Materials Science, 49, no. 22 (2014):7870-7882,
https://doi.org/10.1007/s10853-014-8498-3 .,
https://hdl.handle.net/21.15107/rcub_dais_567 .
24
21
23

The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency

Pontón, Patricia I.; D'Almeida, Jose Roberto; Marinković, Bojan; Savić, Slavica M.; Mančić, Lidija; Rey, Nicolás; Morgado, Edisson Jr.; Rizzo, Fernando C.

(Elsevier, 2014)

TY  - JOUR
AU  - Pontón, Patricia I.
AU  - D'Almeida, Jose Roberto
AU  - Marinković, Bojan
AU  - Savić, Slavica M.
AU  - Mančić, Lidija
AU  - Rey, Nicolás
AU  - Morgado, Edisson Jr.
AU  - Rizzo, Fernando C.
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/565
AB  - One of the major challenges in the development of nanocomposites based on a polymer matrix and highly polar ceramic nanofillers is the lack of the compatibility between these two components. In order to improve the chemical interaction between titanate nanotubes (TTNT) and polymer matrix, such as nylon 11,3-aminopropyltriethoxysilane (APTES) was grafted onto TTNT. The effects of the TTNT chemical composition i.e. sodium content and solvent type on the grafting silane efficiency were thoroughly studied through CHN elemental analysis, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), surface area and zeta potential measurements. The present study brings evidences supporting aqueous ethanol as more efficient reaction medium for TTNT functionalization with APTES, independent of the sodium content of nanotubes, when compared with pure water. It is also worth noting that within aqueous ethanol medium, TTNT with low sodium content are more efficiently grafted than TTNT with high sodium content. Successful APTES grafting decreases concentration of the hydroxyl groups on TTNT surfaces and enables its future application for the fabrication of nylon 11 nanocomposites.
PB  - Elsevier
T2  - Applied Surface Science
T1  - The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency
SP  - 315
EP  - 322
VL  - 301
DO  - 10.1016/j.apsusc.2014.02.071
UR  - https://hdl.handle.net/21.15107/rcub_dais_565
ER  - 
@article{
author = "Pontón, Patricia I. and D'Almeida, Jose Roberto and Marinković, Bojan and Savić, Slavica M. and Mančić, Lidija and Rey, Nicolás and Morgado, Edisson Jr. and Rizzo, Fernando C.",
year = "2014",
abstract = "One of the major challenges in the development of nanocomposites based on a polymer matrix and highly polar ceramic nanofillers is the lack of the compatibility between these two components. In order to improve the chemical interaction between titanate nanotubes (TTNT) and polymer matrix, such as nylon 11,3-aminopropyltriethoxysilane (APTES) was grafted onto TTNT. The effects of the TTNT chemical composition i.e. sodium content and solvent type on the grafting silane efficiency were thoroughly studied through CHN elemental analysis, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), surface area and zeta potential measurements. The present study brings evidences supporting aqueous ethanol as more efficient reaction medium for TTNT functionalization with APTES, independent of the sodium content of nanotubes, when compared with pure water. It is also worth noting that within aqueous ethanol medium, TTNT with low sodium content are more efficiently grafted than TTNT with high sodium content. Successful APTES grafting decreases concentration of the hydroxyl groups on TTNT surfaces and enables its future application for the fabrication of nylon 11 nanocomposites.",
publisher = "Elsevier",
journal = "Applied Surface Science",
title = "The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency",
pages = "315-322",
volume = "301",
doi = "10.1016/j.apsusc.2014.02.071",
url = "https://hdl.handle.net/21.15107/rcub_dais_565"
}
Pontón, P. I., D'Almeida, J. R., Marinković, B., Savić, S. M., Mančić, L., Rey, N., Morgado, E. Jr.,& Rizzo, F. C.. (2014). The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency. in Applied Surface Science
Elsevier., 301, 315-322.
https://doi.org/10.1016/j.apsusc.2014.02.071
https://hdl.handle.net/21.15107/rcub_dais_565
Pontón PI, D'Almeida JR, Marinković B, Savić SM, Mančić L, Rey N, Morgado EJ, Rizzo FC. The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency. in Applied Surface Science. 2014;301:315-322.
doi:10.1016/j.apsusc.2014.02.071
https://hdl.handle.net/21.15107/rcub_dais_565 .
Pontón, Patricia I., D'Almeida, Jose Roberto, Marinković, Bojan, Savić, Slavica M., Mančić, Lidija, Rey, Nicolás, Morgado, Edisson Jr., Rizzo, Fernando C., "The effects of the chemical composition of titanate nanotubes and solvent type on 3-aminopropyltriethoxysilane grafting efficiency" in Applied Surface Science, 301 (2014):315-322,
https://doi.org/10.1016/j.apsusc.2014.02.071 .,
https://hdl.handle.net/21.15107/rcub_dais_565 .
36
34
35

Enhancement of titanate nanotubes dispersion for reinforcement of nylon-II nanocomposites

Rizzo, Fernando C.; Patton, Patricia; Fortini, Renata; Marinković, Bojan; D'Almeida, Jose Roberto; Mančić, Lidija; Savić, Slavica M.

(Las Vegas, 2013)

TY  - CONF
AU  - Rizzo, Fernando C.
AU  - Patton, Patricia
AU  - Fortini, Renata
AU  - Marinković, Bojan
AU  - D'Almeida, Jose Roberto
AU  - Mančić, Lidija
AU  - Savić, Slavica M.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/818
AB  - The purpose of the present study was to investigate the effect of titanate nanotubes (TINTs) dispersion in the mechanical properties of Nylon 11 (polyamide 11) polymer. According ,to the existing literature small amounts of TTNTs used as reinforcement in polymer matrix improve properties such as tensile strength and stiffness. However, the addition of these nanoparticles may also lead to a decrease of strength of the composite if the nanotubes are not well dispersed in the polymer matrix. In this work two different routes were investigated to enhance the disl?ersion of TTNTs used as a reinforcement of nylon matrix nanocomposites: (1) chemical functionalization with 3-arninopropyltriethoxysilane; and (2) treatment with 2 kinds of surfactant - a cationic (CTAB) and an anionic (SDS). Characterization of the nanotubes was done by infrared spectroscopy, CHN elemental analysis, measurement of the specific surface area, thermogravimetric analysis, scanning electron microscopy and transmission electron microscopy. Nylon-II matrix nanocomposites were manufactured by microextrusion-microinjection and reinforced with 0.5 to 2.0 wt.-% of functionalized and surfactant treated nanotubes. Finally, mechanical and thermal properties as well as the microstructure of the nanocomposites were evaluated. The presentation will discuss the results and potential applications of these materials.
PB  - Las Vegas
C3  - THERMEC'2013: International Conference on Processing & Manufacturing of Advanced Materials (Processing, Fabrication, Properties, Application), Rio Hotel, Las Vegas, USA, December 2-6, 2013: Book of Abstracts
T1  - Enhancement of titanate nanotubes dispersion for reinforcement of nylon-II nanocomposites
SP  - 67
EP  - 67
UR  - https://hdl.handle.net/21.15107/rcub_dais_818
ER  - 
@conference{
author = "Rizzo, Fernando C. and Patton, Patricia and Fortini, Renata and Marinković, Bojan and D'Almeida, Jose Roberto and Mančić, Lidija and Savić, Slavica M.",
year = "2013",
abstract = "The purpose of the present study was to investigate the effect of titanate nanotubes (TINTs) dispersion in the mechanical properties of Nylon 11 (polyamide 11) polymer. According ,to the existing literature small amounts of TTNTs used as reinforcement in polymer matrix improve properties such as tensile strength and stiffness. However, the addition of these nanoparticles may also lead to a decrease of strength of the composite if the nanotubes are not well dispersed in the polymer matrix. In this work two different routes were investigated to enhance the disl?ersion of TTNTs used as a reinforcement of nylon matrix nanocomposites: (1) chemical functionalization with 3-arninopropyltriethoxysilane; and (2) treatment with 2 kinds of surfactant - a cationic (CTAB) and an anionic (SDS). Characterization of the nanotubes was done by infrared spectroscopy, CHN elemental analysis, measurement of the specific surface area, thermogravimetric analysis, scanning electron microscopy and transmission electron microscopy. Nylon-II matrix nanocomposites were manufactured by microextrusion-microinjection and reinforced with 0.5 to 2.0 wt.-% of functionalized and surfactant treated nanotubes. Finally, mechanical and thermal properties as well as the microstructure of the nanocomposites were evaluated. The presentation will discuss the results and potential applications of these materials.",
publisher = "Las Vegas",
journal = "THERMEC'2013: International Conference on Processing & Manufacturing of Advanced Materials (Processing, Fabrication, Properties, Application), Rio Hotel, Las Vegas, USA, December 2-6, 2013: Book of Abstracts",
title = "Enhancement of titanate nanotubes dispersion for reinforcement of nylon-II nanocomposites",
pages = "67-67",
url = "https://hdl.handle.net/21.15107/rcub_dais_818"
}
Rizzo, F. C., Patton, P., Fortini, R., Marinković, B., D'Almeida, J. R., Mančić, L.,& Savić, S. M.. (2013). Enhancement of titanate nanotubes dispersion for reinforcement of nylon-II nanocomposites. in THERMEC'2013: International Conference on Processing & Manufacturing of Advanced Materials (Processing, Fabrication, Properties, Application), Rio Hotel, Las Vegas, USA, December 2-6, 2013: Book of Abstracts
Las Vegas., 67-67.
https://hdl.handle.net/21.15107/rcub_dais_818
Rizzo FC, Patton P, Fortini R, Marinković B, D'Almeida JR, Mančić L, Savić SM. Enhancement of titanate nanotubes dispersion for reinforcement of nylon-II nanocomposites. in THERMEC'2013: International Conference on Processing & Manufacturing of Advanced Materials (Processing, Fabrication, Properties, Application), Rio Hotel, Las Vegas, USA, December 2-6, 2013: Book of Abstracts. 2013;:67-67.
https://hdl.handle.net/21.15107/rcub_dais_818 .
Rizzo, Fernando C., Patton, Patricia, Fortini, Renata, Marinković, Bojan, D'Almeida, Jose Roberto, Mančić, Lidija, Savić, Slavica M., "Enhancement of titanate nanotubes dispersion for reinforcement of nylon-II nanocomposites" in THERMEC'2013: International Conference on Processing & Manufacturing of Advanced Materials (Processing, Fabrication, Properties, Application), Rio Hotel, Las Vegas, USA, December 2-6, 2013: Book of Abstracts (2013):67-67,
https://hdl.handle.net/21.15107/rcub_dais_818 .

Effect of processing parameters on structural and morphological Y2O3 :Yb3+/Ho3+ powders characteristics

Lojpur, Vesna; Mančić, Lidija; Marinković, Bojan; Dramićanin, Miroslav; Milošević, Olivera

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Marinković, Bojan
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/419
AB  - Up-converting yttrium oxide powders doped with Yb3+ and co-doped with Ho3+ were
synthesized through hydrothermal processing at 200 °C/3 h. Reverse precipitation of the starting nitrates mixture is performed with the help of ammonium hydrogen carbonate (AHC) solution up to pH 7 or pH 9 prior to hydrothermal treatment. Morphological features of the as-prepared (asp)powders and rare earth oxides obtained after powders additional annealing at 1100 oC (3 and 12 h)are discussed based on X-ray powder diffractometry (XRPD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Structural refinement confirmed generation of the cubic bixbyte-structure (S.G. Ia-3) with non-uniform accomodation of dopants at C2 and S6 cationic sites. SEM revealed that the particles have plate-like or rod-like morphology in dependence of hydrothermal processing (pH). Due to the fact that are composed from nanograins (30-100 nm) they demonstrate prominent green luminescence centered at 550 nm after been excited with the infrared laser source (λ=978 nm).
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
T1  - Effect of processing parameters on structural and morphological Y2O3 :Yb3+/Ho3+ powders characteristics
SP  - 41
EP  - 42
UR  - https://hdl.handle.net/21.15107/rcub_dais_419
ER  - 
@conference{
author = "Lojpur, Vesna and Mančić, Lidija and Marinković, Bojan and Dramićanin, Miroslav and Milošević, Olivera",
year = "2013",
abstract = "Up-converting yttrium oxide powders doped with Yb3+ and co-doped with Ho3+ were
synthesized through hydrothermal processing at 200 °C/3 h. Reverse precipitation of the starting nitrates mixture is performed with the help of ammonium hydrogen carbonate (AHC) solution up to pH 7 or pH 9 prior to hydrothermal treatment. Morphological features of the as-prepared (asp)powders and rare earth oxides obtained after powders additional annealing at 1100 oC (3 and 12 h)are discussed based on X-ray powder diffractometry (XRPD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Structural refinement confirmed generation of the cubic bixbyte-structure (S.G. Ia-3) with non-uniform accomodation of dopants at C2 and S6 cationic sites. SEM revealed that the particles have plate-like or rod-like morphology in dependence of hydrothermal processing (pH). Due to the fact that are composed from nanograins (30-100 nm) they demonstrate prominent green luminescence centered at 550 nm after been excited with the infrared laser source (λ=978 nm).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade",
title = "Effect of processing parameters on structural and morphological Y2O3 :Yb3+/Ho3+ powders characteristics",
pages = "41-42",
url = "https://hdl.handle.net/21.15107/rcub_dais_419"
}
Lojpur, V., Mančić, L., Marinković, B., Dramićanin, M.,& Milošević, O.. (2013). Effect of processing parameters on structural and morphological Y2O3 :Yb3+/Ho3+ powders characteristics. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
Belgrade : Serbian Ceramic Society., 41-42.
https://hdl.handle.net/21.15107/rcub_dais_419
Lojpur V, Mančić L, Marinković B, Dramićanin M, Milošević O. Effect of processing parameters on structural and morphological Y2O3 :Yb3+/Ho3+ powders characteristics. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade. 2013;:41-42.
https://hdl.handle.net/21.15107/rcub_dais_419 .
Lojpur, Vesna, Mančić, Lidija, Marinković, Bojan, Dramićanin, Miroslav, Milošević, Olivera, "Effect of processing parameters on structural and morphological Y2O3 :Yb3+/Ho3+ powders characteristics" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade (2013):41-42,
https://hdl.handle.net/21.15107/rcub_dais_419 .

Functionalization of the titanate nanotubes with a silane coupling agent

Pontón, Patricia I.; Mančić, Lidija; Savić, Slavica M.; Marinković, Bojan

(Belgrade : Institute for Multidisciplinary Research, 2013)

TY  - CONF
AU  - Pontón, Patricia I.
AU  - Mančić, Lidija
AU  - Savić, Slavica M.
AU  - Marinković, Bojan
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/408
AB  - In order to develop new nanosized filler compatible with the thermoplastic polymer Nyion-11, trititanate nanotubes (TTNTs) were synthesized by standard alkaline hydrothermal treatment of a TiO2 anatase powder in 10 M NaOH at 120 DC for 24 h. After the synthesis, the as-obtained nanopowder was washed differently (either with water or HC1), in order to prepare TTNTs with high and low sodium contents. Chemical functionalization of TTNTs was performed with 3-minopropyltriethoxisilane (APTES) coupling agent using two different reaction media (water and an ethanol/water mixture) with the aim to improve the bonding between inorganic hydrophilic fillers and hydrophobic polymer matrix. Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA), transmission electron microscopy (TEM), zeta potential and CHN elemental analyses were used to elucidate the grafting mechanism of APTES at TTNTs surface. The obtained results shown that: APTES coupling agent is bounded covalently to the TTNTs surface (Ti-O-Si bond was identified after deconvolution of the IR bands at 800-1000 cm-1); grafted amount of APTES is almost independent of the reaction media; protonation of-NH2 groups shift the isoelectric point from pH 2.4 to pH 6.6; TTNTs kept their original size and shape after silanization.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - 2nd Conference of the Serbian Ceramic Society, 2CSCS-2013, June 5-7, 2013, Belgrade, Serbia :  Programme and th e book of abstracts
T1  - Functionalization of the titanate nanotubes with a silane coupling agent
SP  - 65
EP  - 66
UR  - https://hdl.handle.net/21.15107/rcub_dais_408
ER  - 
@conference{
author = "Pontón, Patricia I. and Mančić, Lidija and Savić, Slavica M. and Marinković, Bojan",
year = "2013",
abstract = "In order to develop new nanosized filler compatible with the thermoplastic polymer Nyion-11, trititanate nanotubes (TTNTs) were synthesized by standard alkaline hydrothermal treatment of a TiO2 anatase powder in 10 M NaOH at 120 DC for 24 h. After the synthesis, the as-obtained nanopowder was washed differently (either with water or HC1), in order to prepare TTNTs with high and low sodium contents. Chemical functionalization of TTNTs was performed with 3-minopropyltriethoxisilane (APTES) coupling agent using two different reaction media (water and an ethanol/water mixture) with the aim to improve the bonding between inorganic hydrophilic fillers and hydrophobic polymer matrix. Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA), transmission electron microscopy (TEM), zeta potential and CHN elemental analyses were used to elucidate the grafting mechanism of APTES at TTNTs surface. The obtained results shown that: APTES coupling agent is bounded covalently to the TTNTs surface (Ti-O-Si bond was identified after deconvolution of the IR bands at 800-1000 cm-1); grafted amount of APTES is almost independent of the reaction media; protonation of-NH2 groups shift the isoelectric point from pH 2.4 to pH 6.6; TTNTs kept their original size and shape after silanization.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "2nd Conference of the Serbian Ceramic Society, 2CSCS-2013, June 5-7, 2013, Belgrade, Serbia :  Programme and th e book of abstracts",
title = "Functionalization of the titanate nanotubes with a silane coupling agent",
pages = "65-66",
url = "https://hdl.handle.net/21.15107/rcub_dais_408"
}
Pontón, P. I., Mančić, L., Savić, S. M.,& Marinković, B.. (2013). Functionalization of the titanate nanotubes with a silane coupling agent. in 2nd Conference of the Serbian Ceramic Society, 2CSCS-2013, June 5-7, 2013, Belgrade, Serbia :  Programme and th e book of abstracts
Belgrade : Institute for Multidisciplinary Research., 65-66.
https://hdl.handle.net/21.15107/rcub_dais_408
Pontón PI, Mančić L, Savić SM, Marinković B. Functionalization of the titanate nanotubes with a silane coupling agent. in 2nd Conference of the Serbian Ceramic Society, 2CSCS-2013, June 5-7, 2013, Belgrade, Serbia :  Programme and th e book of abstracts. 2013;:65-66.
https://hdl.handle.net/21.15107/rcub_dais_408 .
Pontón, Patricia I., Mančić, Lidija, Savić, Slavica M., Marinković, Bojan, "Functionalization of the titanate nanotubes with a silane coupling agent" in 2nd Conference of the Serbian Ceramic Society, 2CSCS-2013, June 5-7, 2013, Belgrade, Serbia :  Programme and th e book of abstracts (2013):65-66,
https://hdl.handle.net/21.15107/rcub_dais_408 .

Hydrothermal synthesis of nanostructured Y2O3 and (Y0.75Gd0.25)2O3 based phosphors

Mančić, Lidija; Lojpur, Vesna; Marinković, Bojan; Dramićanin, Miroslav; Milošević, Olivera

(Elsevier, 2013)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Marinković, Bojan
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/362
AB  - Examples of (Y2O3–Gd2O3):Eu3+ and Y2O3:(Yb3+/Er3+) rare earth oxide-based phosphors are presented to highlight the controlled synthesis of 1D and 2D nanostructures through simple hydrothermal method. Conversion of the starting nitrates mixture into carbonate hydrate phase is performed with the help of ammonium hydrogen carbonate solution during hydrothermal treatment at 200 °C/3 h. Morphological architectures of rare earth oxides obtained after subsequent powders thermal treatment at 600 and 1100 °C for 3 and 12 h and their correlation with the optical characteristics are discussed based on X-ray powder diffractometry, field emission scanning electron microscopy, infrared spectroscopy and photoluminescence measurements. Strong red and green emission followed by the superior decay times are attributed to the high powders purity and homogeneous dopants distribution over the host lattice matrix.
PB  - Elsevier
T2  - Optical Materials
T1  - Hydrothermal synthesis of nanostructured Y2O3 and (Y0.75Gd0.25)2O3 based phosphors
SP  - 1817
EP  - 1823
VL  - 35
IS  - 10
DO  - 10.1016/j.optmat.2013.03.006
UR  - https://hdl.handle.net/21.15107/rcub_dais_362
ER  - 
@article{
author = "Mančić, Lidija and Lojpur, Vesna and Marinković, Bojan and Dramićanin, Miroslav and Milošević, Olivera",
year = "2013",
abstract = "Examples of (Y2O3–Gd2O3):Eu3+ and Y2O3:(Yb3+/Er3+) rare earth oxide-based phosphors are presented to highlight the controlled synthesis of 1D and 2D nanostructures through simple hydrothermal method. Conversion of the starting nitrates mixture into carbonate hydrate phase is performed with the help of ammonium hydrogen carbonate solution during hydrothermal treatment at 200 °C/3 h. Morphological architectures of rare earth oxides obtained after subsequent powders thermal treatment at 600 and 1100 °C for 3 and 12 h and their correlation with the optical characteristics are discussed based on X-ray powder diffractometry, field emission scanning electron microscopy, infrared spectroscopy and photoluminescence measurements. Strong red and green emission followed by the superior decay times are attributed to the high powders purity and homogeneous dopants distribution over the host lattice matrix.",
publisher = "Elsevier",
journal = "Optical Materials",
title = "Hydrothermal synthesis of nanostructured Y2O3 and (Y0.75Gd0.25)2O3 based phosphors",
pages = "1817-1823",
volume = "35",
number = "10",
doi = "10.1016/j.optmat.2013.03.006",
url = "https://hdl.handle.net/21.15107/rcub_dais_362"
}
Mančić, L., Lojpur, V., Marinković, B., Dramićanin, M.,& Milošević, O.. (2013). Hydrothermal synthesis of nanostructured Y2O3 and (Y0.75Gd0.25)2O3 based phosphors. in Optical Materials
Elsevier., 35(10), 1817-1823.
https://doi.org/10.1016/j.optmat.2013.03.006
https://hdl.handle.net/21.15107/rcub_dais_362
Mančić L, Lojpur V, Marinković B, Dramićanin M, Milošević O. Hydrothermal synthesis of nanostructured Y2O3 and (Y0.75Gd0.25)2O3 based phosphors. in Optical Materials. 2013;35(10):1817-1823.
doi:10.1016/j.optmat.2013.03.006
https://hdl.handle.net/21.15107/rcub_dais_362 .
Mančić, Lidija, Lojpur, Vesna, Marinković, Bojan, Dramićanin, Miroslav, Milošević, Olivera, "Hydrothermal synthesis of nanostructured Y2O3 and (Y0.75Gd0.25)2O3 based phosphors" in Optical Materials, 35, no. 10 (2013):1817-1823,
https://doi.org/10.1016/j.optmat.2013.03.006 .,
https://hdl.handle.net/21.15107/rcub_dais_362 .
23
19
23

Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors

Mančić, Lidija; Lojpur, Vesna; Marinković, Bojan; Rabanal, Maria Eugenia; Dramićanin, Miroslav; Milošević, Olivera

(Belgrade : Agencija FORMAT, 2012)

TY  - CONF
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Marinković, Bojan
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/514
AB  - Synthesis of nanostructured rare earth oxide-based phosphor particles with enhanced optical characteristics leads to the creation of the new photonic devices with diverse applications. Tailoring of the phosphors quality depends on our ability to utilize the best of their intrinsic structure through the control of nucleation and growth process of the desired phase. A large number of works have contributed to the better control of particle shape and crystal growth in soft-chemistry routes. Here, examples from (Y2O3-Gd2O3): Eu3+ and Y2O3:(Yb3+/Er3+) will be presented to highlight the controlled synthesis of 1D and 2D nanostructures through simple hydrothermal method. Conversion of the starting nitrates mixture into carbonate hydrate phase is performed with the help of ammonium hydrogen carbonate solution during hydrothermal treatment at 200oC/3h. Morphological architectures of rare earth oxides obtained after subsequent thermal treatment and their correlation with the optical characteristics will be discussed based on X-ray powder diffractometry, particle size analysis, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy and photoluminescence measurements.
PB  - Belgrade : Agencija FORMAT
C3  - ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract
T1  - Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors
SP  - 8
EP  - 8
UR  - https://hdl.handle.net/21.15107/rcub_dais_514
ER  - 
@conference{
author = "Mančić, Lidija and Lojpur, Vesna and Marinković, Bojan and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2012",
abstract = "Synthesis of nanostructured rare earth oxide-based phosphor particles with enhanced optical characteristics leads to the creation of the new photonic devices with diverse applications. Tailoring of the phosphors quality depends on our ability to utilize the best of their intrinsic structure through the control of nucleation and growth process of the desired phase. A large number of works have contributed to the better control of particle shape and crystal growth in soft-chemistry routes. Here, examples from (Y2O3-Gd2O3): Eu3+ and Y2O3:(Yb3+/Er3+) will be presented to highlight the controlled synthesis of 1D and 2D nanostructures through simple hydrothermal method. Conversion of the starting nitrates mixture into carbonate hydrate phase is performed with the help of ammonium hydrogen carbonate solution during hydrothermal treatment at 200oC/3h. Morphological architectures of rare earth oxides obtained after subsequent thermal treatment and their correlation with the optical characteristics will be discussed based on X-ray powder diffractometry, particle size analysis, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy and photoluminescence measurements.",
publisher = "Belgrade : Agencija FORMAT",
journal = "ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract",
title = "Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors",
pages = "8-8",
url = "https://hdl.handle.net/21.15107/rcub_dais_514"
}
Mančić, L., Lojpur, V., Marinković, B., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2012). Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors. in ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract
Belgrade : Agencija FORMAT., 8-8.
https://hdl.handle.net/21.15107/rcub_dais_514
Mančić L, Lojpur V, Marinković B, Rabanal ME, Dramićanin M, Milošević O. Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors. in ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract. 2012;:8-8.
https://hdl.handle.net/21.15107/rcub_dais_514 .
Mančić, Lidija, Lojpur, Vesna, Marinković, Bojan, Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors" in ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract (2012):8-8,
https://hdl.handle.net/21.15107/rcub_dais_514 .

Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics

Mančić, Lidija; Marinković, Bojan; Marinković, Katarina; Dramićanin, Miroslav; Milošević, Olivera

(2011)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Marinković, Bojan
AU  - Marinković, Katarina
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/711
AB  - Phosphors of (Y0.75Gd0.25)2O3:Eu3+ (5 at.%) have been prepared through soft chemistry routes. Conversion of the starting nitrates mixture into oxide is performed through two approaches: (a) hydrothermal treatment (HT) at 200 °C/3 h of an ammonium hydrogen carbonate precipitated mixture and (b) by thermally decomposition of pure nitrate precursor solution at 900 °C in dispersed phase (aerosol) within a tubular flow reactor by spray pyrolysis process (SP). The powders are additionally thermally treated at different temperatures: 600, 1000, and 1100 °C for either 3 or 12 h. HT—derived particles present exclusively one-dimensional morphology (nanorods) up to the temperatures of 600 °C, while the leaf-like particles start to grow afterward. SP—derived particles maintain their spherical shape up to the temperatures of 1100 °C. These submicron sized spheres were actually composed of randomly aggregated nanoparticles. All powders exhibits cubic Ia-3 structure (Y0.75Gd0.25)2O3:Eu and have improved optical characteristics due to their nanocrystalline nature. The detailed study of the influence of structural and morphological powder characteristics on their emission properties is performed based on the results of X-ray powder diffractometry, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy, and photoluminescence measurements.
T2  - Journal of Nanoparticle Research
T1  - Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics
SP  - 5887
EP  - 5897
VL  - 13
IS  - 11
DO  - 10.1007/s11051-010-0215-9
UR  - https://hdl.handle.net/21.15107/rcub_dais_711
ER  - 
@article{
author = "Mančić, Lidija and Marinković, Bojan and Marinković, Katarina and Dramićanin, Miroslav and Milošević, Olivera",
year = "2011",
abstract = "Phosphors of (Y0.75Gd0.25)2O3:Eu3+ (5 at.%) have been prepared through soft chemistry routes. Conversion of the starting nitrates mixture into oxide is performed through two approaches: (a) hydrothermal treatment (HT) at 200 °C/3 h of an ammonium hydrogen carbonate precipitated mixture and (b) by thermally decomposition of pure nitrate precursor solution at 900 °C in dispersed phase (aerosol) within a tubular flow reactor by spray pyrolysis process (SP). The powders are additionally thermally treated at different temperatures: 600, 1000, and 1100 °C for either 3 or 12 h. HT—derived particles present exclusively one-dimensional morphology (nanorods) up to the temperatures of 600 °C, while the leaf-like particles start to grow afterward. SP—derived particles maintain their spherical shape up to the temperatures of 1100 °C. These submicron sized spheres were actually composed of randomly aggregated nanoparticles. All powders exhibits cubic Ia-3 structure (Y0.75Gd0.25)2O3:Eu and have improved optical characteristics due to their nanocrystalline nature. The detailed study of the influence of structural and morphological powder characteristics on their emission properties is performed based on the results of X-ray powder diffractometry, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy, and photoluminescence measurements.",
journal = "Journal of Nanoparticle Research",
title = "Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics",
pages = "5887-5897",
volume = "13",
number = "11",
doi = "10.1007/s11051-010-0215-9",
url = "https://hdl.handle.net/21.15107/rcub_dais_711"
}
Mančić, L., Marinković, B., Marinković, K., Dramićanin, M.,& Milošević, O.. (2011). Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics. in Journal of Nanoparticle Research, 13(11), 5887-5897.
https://doi.org/10.1007/s11051-010-0215-9
https://hdl.handle.net/21.15107/rcub_dais_711
Mančić L, Marinković B, Marinković K, Dramićanin M, Milošević O. Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics. in Journal of Nanoparticle Research. 2011;13(11):5887-5897.
doi:10.1007/s11051-010-0215-9
https://hdl.handle.net/21.15107/rcub_dais_711 .
Mančić, Lidija, Marinković, Bojan, Marinković, Katarina, Dramićanin, Miroslav, Milošević, Olivera, "Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics" in Journal of Nanoparticle Research, 13, no. 11 (2011):5887-5897,
https://doi.org/10.1007/s11051-010-0215-9 .,
https://hdl.handle.net/21.15107/rcub_dais_711 .
9
9
9