TY  - JOUR
AU  - Veselinović, Ljiljana
AU  - Mitrić, Miodrag
AU  - Mančić, Lidija
AU  - Vukomanović, Marija
AU  - Hadžić, Branka
AU  - Marković, Smilja
AU  - Uskoković, Dragan
PY  - 2014
UR  - https://dais.sanu.ac.rs/123456789/668
AB  - The effect of Sn for Ti substitution on the crystal structure of a perovskite, barium titanate stannate (BTS), BaTi1−xSnxO3 for x = 0, 0.025, 0.05, 0.07, 0.10, 0.12, 0.15 and 0.20, was investigated. The powders were prepared by the conventional solid-state reaction technique. The structural investigations of the BTS powders were done at room temperature by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), selected-area electron diffraction (SAED) and Raman spectroscopy analyses. Rietveld refinement of XRD data indicates that gradual replacement of titanium by tin in BaTiO3 provokes a phase transition from tetragonal for 0 ≤x≤ 0.07 to cubic for x = 0.12, 0.15 and 0.20. The coexistence of tetragonal (P4mm) and cubic (Pminline imagem) crystal phases was established in powder with nominal composition BaTi0.9Sn0.1O3. The crystal phases determined by Rietveld refinement were confirmed by HRTEM and SAED analyses. The crystal structures of the BTS powders at short-range scale were studied by Raman spectroscopy, which shows tetragonal (P4mm) and a small fraction of orthorhombic (Pmm2) crystal phases for all the examined BTS powders, implying a lower local ordering when compared to the average symmetry.
PB  - Hoboken, NJ : John Wiley & Sons
T2  - Journal of Applied Crystallography
T1  - The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)
SP  - 999
EP  - 1007
VL  - 47
IS  - 3
DO  - 10.1107/S1600576714007584
UR  - https://hdl.handle.net/21.15107/rcub_dais_668
ER  - 

@article{
author = "Veselinović, Ljiljana and Mitrić, Miodrag and Mančić, Lidija and Vukomanović, Marija and Hadžić, Branka and Marković, Smilja and Uskoković, Dragan",
year = "2014",
abstract = "The effect of Sn for Ti substitution on the crystal structure of a perovskite, barium titanate stannate (BTS), BaTi1−xSnxO3 for x = 0, 0.025, 0.05, 0.07, 0.10, 0.12, 0.15 and 0.20, was investigated. The powders were prepared by the conventional solid-state reaction technique. The structural investigations of the BTS powders were done at room temperature by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), selected-area electron diffraction (SAED) and Raman spectroscopy analyses. Rietveld refinement of XRD data indicates that gradual replacement of titanium by tin in BaTiO3 provokes a phase transition from tetragonal for 0 ≤x≤ 0.07 to cubic for x = 0.12, 0.15 and 0.20. The coexistence of tetragonal (P4mm) and cubic (Pminline imagem) crystal phases was established in powder with nominal composition BaTi0.9Sn0.1O3. The crystal phases determined by Rietveld refinement were confirmed by HRTEM and SAED analyses. The crystal structures of the BTS powders at short-range scale were studied by Raman spectroscopy, which shows tetragonal (P4mm) and a small fraction of orthorhombic (Pmm2) crystal phases for all the examined BTS powders, implying a lower local ordering when compared to the average symmetry.",
publisher = "Hoboken, NJ : John Wiley & Sons",
journal = "Journal of Applied Crystallography",
title = "The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)",
pages = "999-1007",
volume = "47",
number = "3",
doi = "10.1107/S1600576714007584",
url = "https://hdl.handle.net/21.15107/rcub_dais_668"
}

Veselinović, L., Mitrić, M., Mančić, L., Vukomanović, M., Hadžić, B., Marković, S.,& Uskoković, D.. (2014). The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20). in Journal of Applied Crystallography
Hoboken, NJ : John Wiley & Sons., 47(3), 999-1007.
https://doi.org/10.1107/S1600576714007584
https://hdl.handle.net/21.15107/rcub_dais_668

Veselinović L, Mitrić M, Mančić L, Vukomanović M, Hadžić B, Marković S, Uskoković D. The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20). in Journal of Applied Crystallography. 2014;47(3):999-1007.
doi:10.1107/S1600576714007584
https://hdl.handle.net/21.15107/rcub_dais_668 .

Veselinović, Ljiljana, Mitrić, Miodrag, Mančić, Lidija, Vukomanović, Marija, Hadžić, Branka, Marković, Smilja, Uskoković, Dragan, "The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)" in Journal of Applied Crystallography, 47, no. 3 (2014):999-1007,
https://doi.org/10.1107/S1600576714007584 .,
https://hdl.handle.net/21.15107/rcub_dais_668 .