TY  - JOUR
AU  - Sekulić, Zorana
AU  - Grbović Novaković, Jasmina
AU  - Babić, Bojana
AU  - Prvulović, Milica
AU  - Milanović, Igor
AU  - Novaković, Nikola
AU  - Rajnović, Dragan
AU  - Filipović, Nenad
AU  - Asanović, Vanja
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15140
AB  - The effects of catalysis using vanadium as an additive (2 and 5 wt.%) in a high-energy ball mill on composite desorption properties were examined. The influence of microstructure on the dehydration temperature and hydrogen desorption kinetics was monitored. Morphological and microstructural studies of the synthesized sample were performed by X-ray diffraction (XRD), laser particle size distribution (PSD), and scanning electron microscopy (SEM) methods, while differential scanning calorimetry (DSC) determined thermal properties. To further access amorph species in the milling blend, the absorption spectra were obtained by FTIR-ATR analysis (Fourier transform infrared spectroscopy attenuated total reflection). The results show lower apparent activation energy (Eapp) and H2 desorption temperature are obtained for milling bland with 5 wt.% added vanadium. The best explanation of hydrogen desorption reaction shows the Avrami-Erofeev model for parameter n = 4. Since the obtained value of apparent activation energy is close to the Mg-H bond-breaking energy, one can conclude that breaking this bond would be the rate-limiting step of the process.
T2  - Materials
T1  - The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time
SP  - 5480
VL  - 16
IS  - 15
DO  - 10.3390/ma16155480
UR  - https://hdl.handle.net/21.15107/rcub_dais_15140
ER  - 

@article{
author = "Sekulić, Zorana and Grbović Novaković, Jasmina and Babić, Bojana and Prvulović, Milica and Milanović, Igor and Novaković, Nikola and Rajnović, Dragan and Filipović, Nenad and Asanović, Vanja",
year = "2023",
abstract = "The effects of catalysis using vanadium as an additive (2 and 5 wt.%) in a high-energy ball mill on composite desorption properties were examined. The influence of microstructure on the dehydration temperature and hydrogen desorption kinetics was monitored. Morphological and microstructural studies of the synthesized sample were performed by X-ray diffraction (XRD), laser particle size distribution (PSD), and scanning electron microscopy (SEM) methods, while differential scanning calorimetry (DSC) determined thermal properties. To further access amorph species in the milling blend, the absorption spectra were obtained by FTIR-ATR analysis (Fourier transform infrared spectroscopy attenuated total reflection). The results show lower apparent activation energy (Eapp) and H2 desorption temperature are obtained for milling bland with 5 wt.% added vanadium. The best explanation of hydrogen desorption reaction shows the Avrami-Erofeev model for parameter n = 4. Since the obtained value of apparent activation energy is close to the Mg-H bond-breaking energy, one can conclude that breaking this bond would be the rate-limiting step of the process.",
journal = "Materials",
title = "The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time",
pages = "5480",
volume = "16",
number = "15",
doi = "10.3390/ma16155480",
url = "https://hdl.handle.net/21.15107/rcub_dais_15140"
}

Sekulić, Z., Grbović Novaković, J., Babić, B., Prvulović, M., Milanović, I., Novaković, N., Rajnović, D., Filipović, N.,& Asanović, V.. (2023). The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time. in Materials, 16(15), 5480.
https://doi.org/10.3390/ma16155480
https://hdl.handle.net/21.15107/rcub_dais_15140

Sekulić Z, Grbović Novaković J, Babić B, Prvulović M, Milanović I, Novaković N, Rajnović D, Filipović N, Asanović V. The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time. in Materials. 2023;16(15):5480.
doi:10.3390/ma16155480
https://hdl.handle.net/21.15107/rcub_dais_15140 .

Sekulić, Zorana, Grbović Novaković, Jasmina, Babić, Bojana, Prvulović, Milica, Milanović, Igor, Novaković, Nikola, Rajnović, Dragan, Filipović, Nenad, Asanović, Vanja, "The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time" in Materials, 16, no. 15 (2023):5480,
https://doi.org/10.3390/ma16155480 .,
https://hdl.handle.net/21.15107/rcub_dais_15140 .

TY  - CONF
AU  - Prvulović, Milica
AU  - Babić, Bojana
AU  - Filipović, Nenad
AU  - Mravik, Željko
AU  - Milošević Govedarović, Sanja
AU  - Sekulić, Zorana
AU  - Milanović, Igor
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15640
AB  - The effect of pure Ni addition (5 wt.%) in MgH2 powder was investigated mechanochemically for short milling times (15, 30, and 45 min). Obtained MgH2-Ni system was characterized by XRD, SEM-EDS, PSD, DSC, and TPD. Compared to pure MgH2, uniform distribution of nickel reduces the temperature of H2 desorption by more than 100 °C. It is shown that influence of two important processes, grinding and catalysis, may be followed separately. We can conclude that the catalysis of H2 desorption by Ni particles on MgH2 matrix is the dominant effect for the investigated short milling times.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Twenty-first Young Researchers' Conference Materials Science and Engineering, November 29 – December 1, 2023, Belgrade, Serbia
T1  - Hydrogen storage properties of MgH2-Ni system
SP  - 39
EP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_dais_15640
ER  - 

@conference{
author = "Prvulović, Milica and Babić, Bojana and Filipović, Nenad and Mravik, Željko and Milošević Govedarović, Sanja and Sekulić, Zorana and Milanović, Igor",
year = "2023",
abstract = "The effect of pure Ni addition (5 wt.%) in MgH2 powder was investigated mechanochemically for short milling times (15, 30, and 45 min). Obtained MgH2-Ni system was characterized by XRD, SEM-EDS, PSD, DSC, and TPD. Compared to pure MgH2, uniform distribution of nickel reduces the temperature of H2 desorption by more than 100 °C. It is shown that influence of two important processes, grinding and catalysis, may be followed separately. We can conclude that the catalysis of H2 desorption by Ni particles on MgH2 matrix is the dominant effect for the investigated short milling times.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Twenty-first Young Researchers' Conference Materials Science and Engineering, November 29 – December 1, 2023, Belgrade, Serbia",
title = "Hydrogen storage properties of MgH2-Ni system",
pages = "39-39",
url = "https://hdl.handle.net/21.15107/rcub_dais_15640"
}

Prvulović, M., Babić, B., Filipović, N., Mravik, Ž., Milošević Govedarović, S., Sekulić, Z.,& Milanović, I.. (2023). Hydrogen storage properties of MgH2-Ni system. in Program and the Book of abstracts / Twenty-first Young Researchers' Conference Materials Science and Engineering, November 29 – December 1, 2023, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 39-39.
https://hdl.handle.net/21.15107/rcub_dais_15640

Prvulović M, Babić B, Filipović N, Mravik Ž, Milošević Govedarović S, Sekulić Z, Milanović I. Hydrogen storage properties of MgH2-Ni system. in Program and the Book of abstracts / Twenty-first Young Researchers' Conference Materials Science and Engineering, November 29 – December 1, 2023, Belgrade, Serbia. 2023;:39-39.
https://hdl.handle.net/21.15107/rcub_dais_15640 .

Prvulović, Milica, Babić, Bojana, Filipović, Nenad, Mravik, Željko, Milošević Govedarović, Sanja, Sekulić, Zorana, Milanović, Igor, "Hydrogen storage properties of MgH2-Ni system" in Program and the Book of abstracts / Twenty-first Young Researchers' Conference Materials Science and Engineering, November 29 – December 1, 2023, Belgrade, Serbia (2023):39-39,
https://hdl.handle.net/21.15107/rcub_dais_15640 .