Džunuzović, Enis S.

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orcid::0000-0002-7791-4076
  • Džunuzović, Enis S. (5)
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Author's Bibliography

The influence of self-doping on electrochemical synthesis and behaviour of polyaniline

Gvozdenović, Milica M.; Jugović, Branimir; Jokić, Bojan; Džunuzović, Enis S.; Grgur, Branimir

(Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM, 2021)

TY  - CONF
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jokić, Bojan
AU  - Džunuzović, Enis S.
AU  - Grgur, Branimir
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12383
AB  - Electrochemical synthesis was used to polymerize aniline and copolymerize aniline and m-aminobenzoic from aqueous acidic electrolyte containing aniline and aniline with different amount of m-aminobenzoic acid. These materials were obtained galvanostatically at graphite electrode at current density of 1.0 mA cm-2 from aqueous electrolyte containing 1.0 mol dm-3 HCl and different amount of monomers. The effect of self-doping due to meta positioned carboxylic group was observed in both synthesis parameters, morphology, degree of oxidation and electrochemical behaviour. The presence of m-aminobenzoic acid led higher copolymerization increasing with the increase of amount of m-aminobenzoic acid if comparing to polymerization potential of aniline. Moreover, the copolymer with equal amount of aniline/m-aminobenzoic acid showed electrochemical activity in neutral electrolyte which might be due to possibility of proton exchange process which can be expelled from the copolymer during oxidation process together by insertion of anions, making this material promising for use in electrochemical biosensors.
AB  - Elektrohemijski postupak korišćen je za polimerizaciju anilina i kopolimerizaciju anilina i m-aminobenzoeve kiseline iz kiselog vodenog rastvora elektrolita sa različitim molskim odnosima anilina i m-aminobezoeve kiseline. Ovi materijali dobijeni su uslovima konstantne gustine struje od 1,0 mA cm-2 iz kiselog vodenog elektrolita koji je sadržavao 1,0 mol dm-3 HCl, anilin i m-aminobenzoevu kiselinu. Uticaj samo-dopovanja koji je posledica prisustva karboskilne grupe u meta položaju ispoljavao se u različitim parametrima sinteze, morfologiji dobijenih materijala, stepenu oksidacije i elektrohemijskom ponašanju. Prisustvo m-aminobenzoeve kiseline uslovilo je veći potencijal sinteze kopolimera u odnosu na polianilin koji je rastao sa porastom udela m-aminobezoeve kiseline. Kopolimer koji je dobijen iz elektrolita sa jednakim molskim odnosom anilina i m-aminobenzoeve kiseline pokazao je elektrohemijsku aktivnost u neutralnom elektrolitu koja može biti posledica razmene protona što ovaj materijal čini perspektivnim za praktičnu primenu u elektrohemijskim biosenzorima.
PB  - Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM
C3  - Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia, 2021
T1  - The influence of self-doping on electrochemical synthesis and behaviour of polyaniline
T1  - Uticaj samodopovanja na elektrohemijsku sintezu i svojstva polianilina
SP  - POSTER-139
UR  - https://hdl.handle.net/21.15107/rcub_dais_12383
ER  - 
@conference{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jokić, Bojan and Džunuzović, Enis S. and Grgur, Branimir",
year = "2021",
abstract = "Electrochemical synthesis was used to polymerize aniline and copolymerize aniline and m-aminobenzoic from aqueous acidic electrolyte containing aniline and aniline with different amount of m-aminobenzoic acid. These materials were obtained galvanostatically at graphite electrode at current density of 1.0 mA cm-2 from aqueous electrolyte containing 1.0 mol dm-3 HCl and different amount of monomers. The effect of self-doping due to meta positioned carboxylic group was observed in both synthesis parameters, morphology, degree of oxidation and electrochemical behaviour. The presence of m-aminobenzoic acid led higher copolymerization increasing with the increase of amount of m-aminobenzoic acid if comparing to polymerization potential of aniline. Moreover, the copolymer with equal amount of aniline/m-aminobenzoic acid showed electrochemical activity in neutral electrolyte which might be due to possibility of proton exchange process which can be expelled from the copolymer during oxidation process together by insertion of anions, making this material promising for use in electrochemical biosensors., Elektrohemijski postupak korišćen je za polimerizaciju anilina i kopolimerizaciju anilina i m-aminobenzoeve kiseline iz kiselog vodenog rastvora elektrolita sa različitim molskim odnosima anilina i m-aminobezoeve kiseline. Ovi materijali dobijeni su uslovima konstantne gustine struje od 1,0 mA cm-2 iz kiselog vodenog elektrolita koji je sadržavao 1,0 mol dm-3 HCl, anilin i m-aminobenzoevu kiselinu. Uticaj samo-dopovanja koji je posledica prisustva karboskilne grupe u meta položaju ispoljavao se u različitim parametrima sinteze, morfologiji dobijenih materijala, stepenu oksidacije i elektrohemijskom ponašanju. Prisustvo m-aminobenzoeve kiseline uslovilo je veći potencijal sinteze kopolimera u odnosu na polianilin koji je rastao sa porastom udela m-aminobezoeve kiseline. Kopolimer koji je dobijen iz elektrolita sa jednakim molskim odnosom anilina i m-aminobenzoeve kiseline pokazao je elektrohemijsku aktivnost u neutralnom elektrolitu koja može biti posledica razmene protona što ovaj materijal čini perspektivnim za praktičnu primenu u elektrohemijskim biosenzorima.",
publisher = "Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM",
journal = "Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia, 2021",
title = "The influence of self-doping on electrochemical synthesis and behaviour of polyaniline, Uticaj samodopovanja na elektrohemijsku sintezu i svojstva polianilina",
pages = "POSTER-139",
url = "https://hdl.handle.net/21.15107/rcub_dais_12383"
}
Gvozdenović, M. M., Jugović, B., Jokić, B., Džunuzović, E. S.,& Grgur, B.. (2021). The influence of self-doping on electrochemical synthesis and behaviour of polyaniline. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia, 2021
Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM., POSTER-139.
https://hdl.handle.net/21.15107/rcub_dais_12383
Gvozdenović MM, Jugović B, Jokić B, Džunuzović ES, Grgur B. The influence of self-doping on electrochemical synthesis and behaviour of polyaniline. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia, 2021. 2021;:POSTER-139.
https://hdl.handle.net/21.15107/rcub_dais_12383 .
Gvozdenović, Milica M., Jugović, Branimir, Jokić, Bojan, Džunuzović, Enis S., Grgur, Branimir, "The influence of self-doping on electrochemical synthesis and behaviour of polyaniline" in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia, 2021 (2021):POSTER-139,
https://hdl.handle.net/21.15107/rcub_dais_12383 .

Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material

Gvozdenović, Milica M.; Jugović, Branimir; Jokić, Bojan; Džunuzović, Enis S.; Grgur, Branimir

(Elsevier, 2019)

TY  - JOUR
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jokić, Bojan
AU  - Džunuzović, Enis S.
AU  - Grgur, Branimir
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6296
AB  - Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at
constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and
0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed
using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different
currents. POT electrode exhibited high energy storage features, with specific energy up to
17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is
obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective
application of POT electrode as energy storage material.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material
SP  - 746
EP  - 752
VL  - 317
DO  - 10.1016/j.electacta.2019.06.046
UR  - https://hdl.handle.net/21.15107/rcub_dais_6296
ER  - 
@article{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jokić, Bojan and Džunuzović, Enis S. and Grgur, Branimir",
year = "2019",
abstract = "Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at
constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and
0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed
using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different
currents. POT electrode exhibited high energy storage features, with specific energy up to
17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is
obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective
application of POT electrode as energy storage material.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material",
pages = "746-752",
volume = "317",
doi = "10.1016/j.electacta.2019.06.046",
url = "https://hdl.handle.net/21.15107/rcub_dais_6296"
}
Gvozdenović, M. M., Jugović, B., Jokić, B., Džunuzović, E. S.,& Grgur, B.. (2019). Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material. in Electrochimica Acta
Elsevier., 317, 746-752.
https://doi.org/10.1016/j.electacta.2019.06.046
https://hdl.handle.net/21.15107/rcub_dais_6296
Gvozdenović MM, Jugović B, Jokić B, Džunuzović ES, Grgur B. Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material. in Electrochimica Acta. 2019;317:746-752.
doi:10.1016/j.electacta.2019.06.046
https://hdl.handle.net/21.15107/rcub_dais_6296 .
Gvozdenović, Milica M., Jugović, Branimir, Jokić, Bojan, Džunuzović, Enis S., Grgur, Branimir, "Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material" in Electrochimica Acta, 317 (2019):746-752,
https://doi.org/10.1016/j.electacta.2019.06.046 .,
https://hdl.handle.net/21.15107/rcub_dais_6296 .
6
2
7

Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material

Gvozdenović, Milica M.; Jugović, Branimir; Jokić, Bojan; Džunuzović, Enis S.; Grgur, Branimir

(Elsevier, 2019)

TY  - JOUR
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jokić, Bojan
AU  - Džunuzović, Enis S.
AU  - Grgur, Branimir
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6297
AB  - Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at
 constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and
 0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed
 using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different
 currents. POT electrode exhibited high energy storage features, with specific energy up to
 17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is
 obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective
 application of POT electrode as energy storage material.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material
SP  - 746
EP  - 752
VL  - 317
DO  - 10.1016/j.electacta.2019.06.046
UR  - https://hdl.handle.net/21.15107/rcub_dais_6297
ER  - 
@article{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jokić, Bojan and Džunuzović, Enis S. and Grgur, Branimir",
year = "2019",
abstract = "Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at
 constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and
 0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed
 using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different
 currents. POT electrode exhibited high energy storage features, with specific energy up to
 17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is
 obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective
 application of POT electrode as energy storage material.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material",
pages = "746-752",
volume = "317",
doi = "10.1016/j.electacta.2019.06.046",
url = "https://hdl.handle.net/21.15107/rcub_dais_6297"
}
Gvozdenović, M. M., Jugović, B., Jokić, B., Džunuzović, E. S.,& Grgur, B.. (2019). Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material. in Electrochimica Acta
Elsevier., 317, 746-752.
https://doi.org/10.1016/j.electacta.2019.06.046
https://hdl.handle.net/21.15107/rcub_dais_6297
Gvozdenović MM, Jugović B, Jokić B, Džunuzović ES, Grgur B. Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material. in Electrochimica Acta. 2019;317:746-752.
doi:10.1016/j.electacta.2019.06.046
https://hdl.handle.net/21.15107/rcub_dais_6297 .
Gvozdenović, Milica M., Jugović, Branimir, Jokić, Bojan, Džunuzović, Enis S., Grgur, Branimir, "Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material" in Electrochimica Acta, 317 (2019):746-752,
https://doi.org/10.1016/j.electacta.2019.06.046 .,
https://hdl.handle.net/21.15107/rcub_dais_6297 .
6
2
7

Elektrohemijska sinteza i karakterizacija kopolimera polianilina i maminobenzoeve kiseline

Džunuzović, Enis S.; Grgur, Branimir; Jugović, Branimir; Trišović, Tomislav; Stevanović, Jasmina; Gvozdenović, Milica

(Beograd : Srpsko hemijsko društvo, 2018)

TY  - CONF
AU  - Džunuzović, Enis S.
AU  - Grgur, Branimir
AU  - Jugović, Branimir
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina
AU  - Gvozdenović, Milica
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/14731
AB  - Kopolimerizacija anilina i m-aminobenzoeve kiseline ostvarena je elektrohemijskim postupkom u uslovima konstantne gustine struje od 1,0 mA cm-2 (galvanostatski). Kao elektrolit za sintezu korišćen je vodeni rastvora 1,0 mol dm-3 HCl sa dodatkom anilina i maminobenzoeve kiseline različitog odnosa koncentracija. Prisustvo karboskilne grupe u meta položaju uslovljava povećanje potencijala kopolimerizacije, drugačiju morfologiju i elektrohemijsko ponašanje kopolimera u poređenju sa polianilinom. Kopolimer polianilina i m-aminobenzoeve kiseline dobijen kopolimerizacijom iz rastvora koji je sadržao istu količinu anilina i m-benzoeve kiseline od 1.0 mol dm-3 pokazuje, za razliku od polianilina, elektrohemijsku aktivnost u neutralnoj sredini.
AB  - Galvanostatic electrochemical syntheses of poly(aniline-co-(m-aminobenzoic acid)) was performed at graphite electrode at constant current density of 1.0 mA cm-2. Aqueous electrolyte used for synthesis was consisted of: 1.0 mol dm-3 HCl and different amounts of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid had influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Poly(aniline-co-(m-aminobenzoic acid)) obtained from electrolyte with an equal amount of aniline and m-aminobenzoic acid exhibits electrochemical activity in neutral electrolyte which can be related to proton exchange process.
PB  - Beograd : Srpsko hemijsko društvo
C3  - Kratki izvodi radova = Book of Abstracts / 55. savetovanje Srpskog hemijskog društva, Novi Sad 8. i 9. juni 2018 = 55th meeting of the Serbian chemical society, Novi Sad, Serbia, June 8-9, 2018
T1  - Elektrohemijska sinteza i karakterizacija kopolimera polianilina i maminobenzoeve kiseline
T1  - Electrochemical synthesis and characterization of poly(aniline-co-(maminobenzoic acid)
UR  - https://hdl.handle.net/21.15107/rcub_dais_14731
ER  - 
@conference{
author = "Džunuzović, Enis S. and Grgur, Branimir and Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina and Gvozdenović, Milica",
year = "2018",
abstract = "Kopolimerizacija anilina i m-aminobenzoeve kiseline ostvarena je elektrohemijskim postupkom u uslovima konstantne gustine struje od 1,0 mA cm-2 (galvanostatski). Kao elektrolit za sintezu korišćen je vodeni rastvora 1,0 mol dm-3 HCl sa dodatkom anilina i maminobenzoeve kiseline različitog odnosa koncentracija. Prisustvo karboskilne grupe u meta položaju uslovljava povećanje potencijala kopolimerizacije, drugačiju morfologiju i elektrohemijsko ponašanje kopolimera u poređenju sa polianilinom. Kopolimer polianilina i m-aminobenzoeve kiseline dobijen kopolimerizacijom iz rastvora koji je sadržao istu količinu anilina i m-benzoeve kiseline od 1.0 mol dm-3 pokazuje, za razliku od polianilina, elektrohemijsku aktivnost u neutralnoj sredini., Galvanostatic electrochemical syntheses of poly(aniline-co-(m-aminobenzoic acid)) was performed at graphite electrode at constant current density of 1.0 mA cm-2. Aqueous electrolyte used for synthesis was consisted of: 1.0 mol dm-3 HCl and different amounts of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid had influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Poly(aniline-co-(m-aminobenzoic acid)) obtained from electrolyte with an equal amount of aniline and m-aminobenzoic acid exhibits electrochemical activity in neutral electrolyte which can be related to proton exchange process.",
publisher = "Beograd : Srpsko hemijsko društvo",
journal = "Kratki izvodi radova = Book of Abstracts / 55. savetovanje Srpskog hemijskog društva, Novi Sad 8. i 9. juni 2018 = 55th meeting of the Serbian chemical society, Novi Sad, Serbia, June 8-9, 2018",
title = "Elektrohemijska sinteza i karakterizacija kopolimera polianilina i maminobenzoeve kiseline, Electrochemical synthesis and characterization of poly(aniline-co-(maminobenzoic acid)",
url = "https://hdl.handle.net/21.15107/rcub_dais_14731"
}
Džunuzović, E. S., Grgur, B., Jugović, B., Trišović, T., Stevanović, J.,& Gvozdenović, M.. (2018). Elektrohemijska sinteza i karakterizacija kopolimera polianilina i maminobenzoeve kiseline. in Kratki izvodi radova = Book of Abstracts / 55. savetovanje Srpskog hemijskog društva, Novi Sad 8. i 9. juni 2018 = 55th meeting of the Serbian chemical society, Novi Sad, Serbia, June 8-9, 2018
Beograd : Srpsko hemijsko društvo..
https://hdl.handle.net/21.15107/rcub_dais_14731
Džunuzović ES, Grgur B, Jugović B, Trišović T, Stevanović J, Gvozdenović M. Elektrohemijska sinteza i karakterizacija kopolimera polianilina i maminobenzoeve kiseline. in Kratki izvodi radova = Book of Abstracts / 55. savetovanje Srpskog hemijskog društva, Novi Sad 8. i 9. juni 2018 = 55th meeting of the Serbian chemical society, Novi Sad, Serbia, June 8-9, 2018. 2018;.
https://hdl.handle.net/21.15107/rcub_dais_14731 .
Džunuzović, Enis S., Grgur, Branimir, Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina, Gvozdenović, Milica, "Elektrohemijska sinteza i karakterizacija kopolimera polianilina i maminobenzoeve kiseline" in Kratki izvodi radova = Book of Abstracts / 55. savetovanje Srpskog hemijskog društva, Novi Sad 8. i 9. juni 2018 = 55th meeting of the Serbian chemical society, Novi Sad, Serbia, June 8-9, 2018 (2018),
https://hdl.handle.net/21.15107/rcub_dais_14731 .

Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6

Radoman, Tijana S.; Džunuzović, Jasna V.; Grgur, Branimir; Gvozdenović, Milica M.; Jugović, Branimir; Milićević, Dejan S.; Džunuzović, Enis S.

(Elsevier, 2016)

TY  - JOUR
AU  - Radoman, Tijana S.
AU  - Džunuzović, Jasna V.
AU  - Grgur, Branimir
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Milićević, Dejan S.
AU  - Džunuzović, Enis S.
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/16000
AB  - Novel TiO2-PANI core-shell nanocomposite, prepared by in situ oxidative polymerization of aniline in the presence of TiO2 nanoparticles surface modified with vitamin B6, was used to reinforce epoxy resin. The size of prepared TiO2 nanoparticles and TiO2-PANI nanocomposite were determined by a transmission electron microscopy (TEM). The surface modification of TiO2 nanoparticles was confirmed by FTIR and UV–vis spectroscopy, while the morphology of PANI and TiO2-PANI nanocomposite was investigated by scanning electron microscopy (SEM). The influence of TiO2-PANI nanocomposite on glass transition temperature, dielectric and dynamic mechanical properties, thermooxidative stability, mechanical and anticorrosion properties of epoxy based nanocomposites was investigated and compared to the properties of epoxy/PANI nanocomposites. It has been observed that the glass transition temperature of epoxy resin increases after introduction of PANI and TiO2-PANI nanocomposite, as well as with increasing their content. Prepared nanocomposites exhibited higher value of dielectric constant than pure epoxy resin. Epoxy based coating containing TiO2-PANI nanocomposite showed lower dielectric loss, higher hardness and better anticorrosion properties than pure epoxy resin and epoxy/PANI nanocomposite.
PB  - Elsevier
T2  - Progress in Organic Coatings
T1  - Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6
SP  - 346
EP  - 355
VL  - 99
DO  - 10.1016/j.porgcoat.2016.06.014
UR  - https://hdl.handle.net/21.15107/rcub_dais_16000
ER  - 
@article{
author = "Radoman, Tijana S. and Džunuzović, Jasna V. and Grgur, Branimir and Gvozdenović, Milica M. and Jugović, Branimir and Milićević, Dejan S. and Džunuzović, Enis S.",
year = "2016",
abstract = "Novel TiO2-PANI core-shell nanocomposite, prepared by in situ oxidative polymerization of aniline in the presence of TiO2 nanoparticles surface modified with vitamin B6, was used to reinforce epoxy resin. The size of prepared TiO2 nanoparticles and TiO2-PANI nanocomposite were determined by a transmission electron microscopy (TEM). The surface modification of TiO2 nanoparticles was confirmed by FTIR and UV–vis spectroscopy, while the morphology of PANI and TiO2-PANI nanocomposite was investigated by scanning electron microscopy (SEM). The influence of TiO2-PANI nanocomposite on glass transition temperature, dielectric and dynamic mechanical properties, thermooxidative stability, mechanical and anticorrosion properties of epoxy based nanocomposites was investigated and compared to the properties of epoxy/PANI nanocomposites. It has been observed that the glass transition temperature of epoxy resin increases after introduction of PANI and TiO2-PANI nanocomposite, as well as with increasing their content. Prepared nanocomposites exhibited higher value of dielectric constant than pure epoxy resin. Epoxy based coating containing TiO2-PANI nanocomposite showed lower dielectric loss, higher hardness and better anticorrosion properties than pure epoxy resin and epoxy/PANI nanocomposite.",
publisher = "Elsevier",
journal = "Progress in Organic Coatings",
title = "Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6",
pages = "346-355",
volume = "99",
doi = "10.1016/j.porgcoat.2016.06.014",
url = "https://hdl.handle.net/21.15107/rcub_dais_16000"
}
Radoman, T. S., Džunuzović, J. V., Grgur, B., Gvozdenović, M. M., Jugović, B., Milićević, D. S.,& Džunuzović, E. S.. (2016). Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6. in Progress in Organic Coatings
Elsevier., 99, 346-355.
https://doi.org/10.1016/j.porgcoat.2016.06.014
https://hdl.handle.net/21.15107/rcub_dais_16000
Radoman TS, Džunuzović JV, Grgur B, Gvozdenović MM, Jugović B, Milićević DS, Džunuzović ES. Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6. in Progress in Organic Coatings. 2016;99:346-355.
doi:10.1016/j.porgcoat.2016.06.014
https://hdl.handle.net/21.15107/rcub_dais_16000 .
Radoman, Tijana S., Džunuzović, Jasna V., Grgur, Branimir, Gvozdenović, Milica M., Jugović, Branimir, Milićević, Dejan S., Džunuzović, Enis S., "Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6" in Progress in Organic Coatings, 99 (2016):346-355,
https://doi.org/10.1016/j.porgcoat.2016.06.014 .,
https://hdl.handle.net/21.15107/rcub_dais_16000 .
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