TY  - JOUR
AU  - Biliškov, Nikola
AU  - Milanović, Igor
AU  - Milović, Miloš
AU  - Takats, Viktor
AU  - Erdelyi, Zoltan
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15194
AB  - The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.
T2  - Journal of Alloys and Compounds
T1  - Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials
SP  - 169293
VL  - 945
DO  - 10.1016/j.jallcom.2023.169293
UR  - https://hdl.handle.net/21.15107/rcub_dais_15194
ER  - 

@article{
author = "Biliškov, Nikola and Milanović, Igor and Milović, Miloš and Takats, Viktor and Erdelyi, Zoltan",
year = "2023",
abstract = "The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.",
journal = "Journal of Alloys and Compounds",
title = "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials",
pages = "169293",
volume = "945",
doi = "10.1016/j.jallcom.2023.169293",
url = "https://hdl.handle.net/21.15107/rcub_dais_15194"
}

Biliškov, N., Milanović, I., Milović, M., Takats, V.,& Erdelyi, Z.. (2023). Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds, 945, 169293.
https://doi.org/10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_15194

Biliškov N, Milanović I, Milović M, Takats V, Erdelyi Z. Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds. 2023;945:169293.
doi:10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_15194 .

Biliškov, Nikola, Milanović, Igor, Milović, Miloš, Takats, Viktor, Erdelyi, Zoltan, "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials" in Journal of Alloys and Compounds, 945 (2023):169293,
https://doi.org/10.1016/j.jallcom.2023.169293 .,
https://hdl.handle.net/21.15107/rcub_dais_15194 .

TY  - JOUR
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag J.
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Biliškov, Nikola
AU  - Milošević Govedarović, Sanja
PY  - 2020
UR  - http://www.sciencedirect.com/science/article/pii/S0360319919327685
UR  - https://dais.sanu.ac.rs/123456789/6455
AB  - The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites
SP  - 7901
EP  - 7911
VL  - 45
IS  - 14
DO  - 10.1016/j.ijhydene.2019.07.167
UR  - https://hdl.handle.net/21.15107/rcub_dais_6455
ER  - 

@article{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević Govedarović, Sanja",
year = "2020",
abstract = "The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites",
pages = "7901-7911",
volume = "45",
number = "14",
doi = "10.1016/j.ijhydene.2019.07.167",
url = "https://hdl.handle.net/21.15107/rcub_dais_6455"
}

Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević Govedarović, S.. (2020). The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy
Elsevier., 45(14), 7901-7911.
https://doi.org/10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_6455

Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević Govedarović S. The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy. 2020;45(14):7901-7911.
doi:10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_6455 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag J., Grbović Novaković, Jasmina, Kurko, Sandra, Biliškov, Nikola, Milošević Govedarović, Sanja, "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7901-7911,
https://doi.org/10.1016/j.ijhydene.2019.07.167 .,
https://hdl.handle.net/21.15107/rcub_dais_6455 .

TY  - JOUR
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag J.
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Biliškov, Nikola
AU  - Milošević Govedarović, Sanja
PY  - 2020
UR  - http://www.sciencedirect.com/science/article/pii/S0360319919327685
UR  - https://dais.sanu.ac.rs/123456789/8963
AB  - The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites
SP  - 7901
EP  - 7911
VL  - 45
IS  - 14
DO  - 10.1016/j.ijhydene.2019.07.167
UR  - https://hdl.handle.net/21.15107/rcub_dais_8963
ER  - 

@article{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević Govedarović, Sanja",
year = "2020",
abstract = "The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites",
pages = "7901-7911",
volume = "45",
number = "14",
doi = "10.1016/j.ijhydene.2019.07.167",
url = "https://hdl.handle.net/21.15107/rcub_dais_8963"
}

Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević Govedarović, S.. (2020). The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy
Elsevier., 45(14), 7901-7911.
https://doi.org/10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_8963

Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević Govedarović S. The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy. 2020;45(14):7901-7911.
doi:10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_8963 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag J., Grbović Novaković, Jasmina, Kurko, Sandra, Biliškov, Nikola, Milošević Govedarović, Sanja, "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7901-7911,
https://doi.org/10.1016/j.ijhydene.2019.07.167 .,
https://hdl.handle.net/21.15107/rcub_dais_8963 .

TY  - CONF
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag J.
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Biliškov, Nikola
AU  - Milošević, Sanja S.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/15451
AB  - Magnesium hydride, as hydrogen storage material, meets the requirements such as high gravimetric hydrogen capacity (7,6 wt%), low cost and weight, abundance and H2 absorption/desorption cycling possibility. Given that the oxide additives show the good impact on desorption properties, mechanical milling of MgH2 with addition of 5, 10 and 15% wt. WO3 was performed. The microstructure and morphology of composites were analysed by XRD, PSD and SEM and correlated to hydrogen desorption properties which have been investigated by DSC. The results have shown that WO3 has a positive effect on the desorption kinetics as well as on the change of the desorption mechanism.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
T1  - Is WO3 catalyst for hydrogen desorption?
SP  - 50
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_dais_15451
ER  - 

@conference{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević, Sanja S.",
year = "2017",
abstract = "Magnesium hydride, as hydrogen storage material, meets the requirements such as high gravimetric hydrogen capacity (7,6 wt%), low cost and weight, abundance and H2 absorption/desorption cycling possibility. Given that the oxide additives show the good impact on desorption properties, mechanical milling of MgH2 with addition of 5, 10 and 15% wt. WO3 was performed. The microstructure and morphology of composites were analysed by XRD, PSD and SEM and correlated to hydrogen desorption properties which have been investigated by DSC. The results have shown that WO3 has a positive effect on the desorption kinetics as well as on the change of the desorption mechanism.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia",
title = "Is WO3 catalyst for hydrogen desorption?",
pages = "50-50",
url = "https://hdl.handle.net/21.15107/rcub_dais_15451"
}

Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević, S. S.. (2017). Is WO3 catalyst for hydrogen desorption?. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 50-50.
https://hdl.handle.net/21.15107/rcub_dais_15451

Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević SS. Is WO3 catalyst for hydrogen desorption?. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia. 2017;:50-50.
https://hdl.handle.net/21.15107/rcub_dais_15451 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag J., Grbović Novaković, Jasmina, Kurko, Sandra, Biliškov, Nikola, Milošević, Sanja S., "Is WO3 catalyst for hydrogen desorption?" in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia (2017):50-50,
https://hdl.handle.net/21.15107/rcub_dais_15451 .

TY  - JOUR
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Rašković Lovre, Željka
AU  - Milošević, Sanja S.
AU  - Milanović, Igor
AU  - Stojanović, Zoran S.
AU  - Vujasin, Radojka
AU  - Matović, Ljiljana Lj.
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/352
AB  - The influence of structural changes caused by irradiation with different ions, their energies and fluences on sorption properties has been investigated. Results suggest that there are several mechanisms of desorption depending on defect concentration, their interaction and ordering. It has been also demonstrated that the changes in near-surface area play the crucial role in hydrogen desorption kinetics. It is confirmed that there is possibility to control the thermodynamic parameters of these systems by controlling vacancies depth profile and concentration.
PB  - Kaunas University of Technology
T2  - Materials Science MEDZIAGOTYRA
T1  - Changes in Storage Properties of Hydrides Induced by Ion Irradiation
SP  - 134
EP  - 139
VL  - 19
IS  - 2
DO  - 10.5755/j01.ms.19.2.1579
UR  - https://hdl.handle.net/21.15107/rcub_dais_352
ER  - 

@article{
author = "Grbović Novaković, Jasmina and Kurko, Sandra and Rašković Lovre, Željka and Milošević, Sanja S. and Milanović, Igor and Stojanović, Zoran S. and Vujasin, Radojka and Matović, Ljiljana Lj.",
year = "2013",
abstract = "The influence of structural changes caused by irradiation with different ions, their energies and fluences on sorption properties has been investigated. Results suggest that there are several mechanisms of desorption depending on defect concentration, their interaction and ordering. It has been also demonstrated that the changes in near-surface area play the crucial role in hydrogen desorption kinetics. It is confirmed that there is possibility to control the thermodynamic parameters of these systems by controlling vacancies depth profile and concentration.",
publisher = "Kaunas University of Technology",
journal = "Materials Science MEDZIAGOTYRA",
title = "Changes in Storage Properties of Hydrides Induced by Ion Irradiation",
pages = "134-139",
volume = "19",
number = "2",
doi = "10.5755/j01.ms.19.2.1579",
url = "https://hdl.handle.net/21.15107/rcub_dais_352"
}

Grbović Novaković, J., Kurko, S., Rašković Lovre, Ž., Milošević, S. S., Milanović, I., Stojanović, Z. S., Vujasin, R.,& Matović, L. Lj.. (2013). Changes in Storage Properties of Hydrides Induced by Ion Irradiation. in Materials Science MEDZIAGOTYRA
Kaunas University of Technology., 19(2), 134-139.
https://doi.org/10.5755/j01.ms.19.2.1579
https://hdl.handle.net/21.15107/rcub_dais_352

Grbović Novaković J, Kurko S, Rašković Lovre Ž, Milošević SS, Milanović I, Stojanović ZS, Vujasin R, Matović LL. Changes in Storage Properties of Hydrides Induced by Ion Irradiation. in Materials Science MEDZIAGOTYRA. 2013;19(2):134-139.
doi:10.5755/j01.ms.19.2.1579
https://hdl.handle.net/21.15107/rcub_dais_352 .

Grbović Novaković, Jasmina, Kurko, Sandra, Rašković Lovre, Željka, Milošević, Sanja S., Milanović, Igor, Stojanović, Zoran S., Vujasin, Radojka, Matović, Ljiljana Lj., "Changes in Storage Properties of Hydrides Induced by Ion Irradiation" in Materials Science MEDZIAGOTYRA, 19, no. 2 (2013):134-139,
https://doi.org/10.5755/j01.ms.19.2.1579 .,
https://hdl.handle.net/21.15107/rcub_dais_352 .

TY  - CONF
AU  - Đukić, Anđelka B.
AU  - Grbović Novaković, Jasmina
AU  - Stojanović, Zoran S.
AU  - Milanović, Igor
AU  - Vujasin, Radojka
AU  - Milošević, Sanja S.
AU  - Matović, Ljiljana Lj.
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/390
AB  - Adsorption on activated carbon cloth is an efficient procedure for removing pollutants from wastewaters, because this material possesses large specific area and high adsorption capacity. In
this study the activated carbon cloth was modified by mechanical milling in order to improve its sorption properties. The microstructure and morphology of the sample was investigated by XRD,
PSD and SEM and surface chemistry was characterized by potentiometric titrations. The result showed that microstructure and morphology was drastically changed with milling: particle sizes
reduction, agglomeration and the loss of fibrous structure occurred. These changes resulted in increase of the acidic and the base groups: the number of basic groups was increased by the factor of 11 while the number of acidic groups by the factor of 1.5.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
T1  - Surface characterisation of mechanochemicaly activated carbon cloth
SP  - 126
EP  - 126
UR  - https://hdl.handle.net/21.15107/rcub_dais_390
ER  - 

@conference{
author = "Đukić, Anđelka B. and Grbović Novaković, Jasmina and Stojanović, Zoran S. and Milanović, Igor and Vujasin, Radojka and Milošević, Sanja S. and Matović, Ljiljana Lj.",
year = "2013",
abstract = "Adsorption on activated carbon cloth is an efficient procedure for removing pollutants from wastewaters, because this material possesses large specific area and high adsorption capacity. In
this study the activated carbon cloth was modified by mechanical milling in order to improve its sorption properties. The microstructure and morphology of the sample was investigated by XRD,
PSD and SEM and surface chemistry was characterized by potentiometric titrations. The result showed that microstructure and morphology was drastically changed with milling: particle sizes
reduction, agglomeration and the loss of fibrous structure occurred. These changes resulted in increase of the acidic and the base groups: the number of basic groups was increased by the factor of 11 while the number of acidic groups by the factor of 1.5.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts",
title = "Surface characterisation of mechanochemicaly activated carbon cloth",
pages = "126-126",
url = "https://hdl.handle.net/21.15107/rcub_dais_390"
}

Đukić, A. B., Grbović Novaković, J., Stojanović, Z. S., Milanović, I., Vujasin, R., Milošević, S. S.,& Matović, L. Lj.. (2013). Surface characterisation of mechanochemicaly activated carbon cloth. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 126-126.
https://hdl.handle.net/21.15107/rcub_dais_390

Đukić AB, Grbović Novaković J, Stojanović ZS, Milanović I, Vujasin R, Milošević SS, Matović LL. Surface characterisation of mechanochemicaly activated carbon cloth. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts. 2013;:126-126.
https://hdl.handle.net/21.15107/rcub_dais_390 .

Đukić, Anđelka B., Grbović Novaković, Jasmina, Stojanović, Zoran S., Milanović, Igor, Vujasin, Radojka, Milošević, Sanja S., Matović, Ljiljana Lj., "Surface characterisation of mechanochemicaly activated carbon cloth" in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts (2013):126-126,
https://hdl.handle.net/21.15107/rcub_dais_390 .