TY  - JOUR
AU  - Nikolić, Nataša
AU  - Marinković, Zorica
AU  - Srecković, Tatjana
PY  - 2004
UR  - https://dais.sanu.ac.rs/123456789/14735
AB  - The aim of this work is the investigation of experimental conditions for mechanochemical synthesis of spinel zinc stannate (Zn2SnO4). Application of this material include manufacturing of CO, H2, NO, NO2, i-C4H10 and C2H5OH gas sensors, production of transparent conducting electrodes, window coatings and anode for use in photoelectrochemistry. Starting powder mixtures of zinc oxide and tin oxide in the molar ratio, in accordance with the stoichiometrics of spinel zinc stannate, were mechanically activated by grinding in a planetary mill for various periods of time in the interval of 0 to 160 min. Changes of physico-chemical characteristics and microstructural parameters in the ZnO-SnO2 system after grinding were followed using surface area analysis and X-ray powder diffraction, while thermal behavior was examined by differential thermal analysis and sensitive dilatometer. The beginning of zinc stannate phase formation was noticed after 40 min of grinding, and prolonged grinding leads to the formation of spinel zinc stannate as the major phase with insignificant amount of unreacted zinc oxide and tin oxide. The formation of spinel was accelerated with the increase of sintering temperature, and monophased zinc stannate was obtained when powder mixture was grinded for 160 min followed by sintering at 1200°C.
PB  - Springer
T2  - Journal of Materials Science
T1  - The influence of grinding conditions on the mechanochemical synthesis of zinc stannate
SP  - 5239
EP  - 5242
VL  - 39
IS  - 16/17
DO  - 10.1023/B:JMSC.0000039218.82254.a4
UR  - https://hdl.handle.net/21.15107/rcub_dais_14735
ER  - 

@article{
author = "Nikolić, Nataša and Marinković, Zorica and Srecković, Tatjana",
year = "2004",
abstract = "The aim of this work is the investigation of experimental conditions for mechanochemical synthesis of spinel zinc stannate (Zn2SnO4). Application of this material include manufacturing of CO, H2, NO, NO2, i-C4H10 and C2H5OH gas sensors, production of transparent conducting electrodes, window coatings and anode for use in photoelectrochemistry. Starting powder mixtures of zinc oxide and tin oxide in the molar ratio, in accordance with the stoichiometrics of spinel zinc stannate, were mechanically activated by grinding in a planetary mill for various periods of time in the interval of 0 to 160 min. Changes of physico-chemical characteristics and microstructural parameters in the ZnO-SnO2 system after grinding were followed using surface area analysis and X-ray powder diffraction, while thermal behavior was examined by differential thermal analysis and sensitive dilatometer. The beginning of zinc stannate phase formation was noticed after 40 min of grinding, and prolonged grinding leads to the formation of spinel zinc stannate as the major phase with insignificant amount of unreacted zinc oxide and tin oxide. The formation of spinel was accelerated with the increase of sintering temperature, and monophased zinc stannate was obtained when powder mixture was grinded for 160 min followed by sintering at 1200°C.",
publisher = "Springer",
journal = "Journal of Materials Science",
title = "The influence of grinding conditions on the mechanochemical synthesis of zinc stannate",
pages = "5239-5242",
volume = "39",
number = "16/17",
doi = "10.1023/B:JMSC.0000039218.82254.a4",
url = "https://hdl.handle.net/21.15107/rcub_dais_14735"
}

Nikolić, N., Marinković, Z.,& Srecković, T.. (2004). The influence of grinding conditions on the mechanochemical synthesis of zinc stannate. in Journal of Materials Science
Springer., 39(16/17), 5239-5242.
https://doi.org/10.1023/B:JMSC.0000039218.82254.a4
https://hdl.handle.net/21.15107/rcub_dais_14735

Nikolić N, Marinković Z, Srecković T. The influence of grinding conditions on the mechanochemical synthesis of zinc stannate. in Journal of Materials Science. 2004;39(16/17):5239-5242.
doi:10.1023/B:JMSC.0000039218.82254.a4
https://hdl.handle.net/21.15107/rcub_dais_14735 .

Nikolić, Nataša, Marinković, Zorica, Srecković, Tatjana, "The influence of grinding conditions on the mechanochemical synthesis of zinc stannate" in Journal of Materials Science, 39, no. 16/17 (2004):5239-5242,
https://doi.org/10.1023/B:JMSC.0000039218.82254.a4 .,
https://hdl.handle.net/21.15107/rcub_dais_14735 .