Ivanovski, Valentin N.

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orcid::0000-0001-7036-7631
  • Ivanovski, Valentin N. (11)
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Author's Bibliography

A study of defect structures in Fe-alloyed ZnO: Morphology, magnetism, and hyperfine interactions

Ivanovski, Valentin N.; Belošević-Čavor, Jelena; Rajić, Vladimir; Umićević, Ana; Marković, Smilja; Kusigerski, Vladan; Mitrić, Miodrag; Koteski, Vasil

(AIP Publishing, 2019)

TY  - JOUR
AU  - Ivanovski, Valentin N.
AU  - Belošević-Čavor, Jelena
AU  - Rajić, Vladimir
AU  - Umićević, Ana
AU  - Marković, Smilja
AU  - Kusigerski, Vladan
AU  - Mitrić, Miodrag
AU  - Koteski, Vasil
PY  - 2019
UR  - https://aip.scitation.org/doi/10.1063/1.5095837
UR  - http://dais.sanu.ac.rs/123456789/6883
AB  - In order to study the effect of Fe cation substitution on the local structure, defect formation, and hyperfine interactions in ZnO, Mössbauer spectroscopy measurements of the microwave processed Zn1−xFexO (x=0.05, 0.10, 0.15, and 0.20) nanoparticles, together with ab initio calculations, were performed. Complementary information on the distribution of particle size and morphology, as well as magnetic properties, were obtained by X-ray diffraction, transmission electron microscopy, and squid-magnetometry. The selected model for analyzing the Mössbauer spectra of our samples is a distribution of quadrupole splittings. The fitting model with two Lorentz doublets was rejected due to its failure to include larger doublets. The Fe3+ ions do not yield magnetic ordering in the samples at room temperature. The results from first-principles calculations confirm that the major component of the Mössbauer spectra corresponds to the Fe-alloyed ZnO with Zn vacancy in the next nearest neighbor environment. The magnetic measurements are consistent with the description of the distribution of iron ions over the randomly formed clusters in the ZnO host lattice. While at room temperature all the samples are paramagnetic, magnetic interactions cause a transition into a cluster spin-glass state at low temperatures.
PB  - AIP Publishing
T2  - Journal of Applied Physics
T1  - A study of defect structures in Fe-alloyed ZnO: Morphology, magnetism, and hyperfine interactions
SP  - 125703
VL  - 126
IS  - 12
DO  - 10.1063/1.5095837
UR  - https://hdl.handle.net/21.15107/rcub_dais_6883
ER  - 
@article{
author = "Ivanovski, Valentin N. and Belošević-Čavor, Jelena and Rajić, Vladimir and Umićević, Ana and Marković, Smilja and Kusigerski, Vladan and Mitrić, Miodrag and Koteski, Vasil",
year = "2019",
abstract = "In order to study the effect of Fe cation substitution on the local structure, defect formation, and hyperfine interactions in ZnO, Mössbauer spectroscopy measurements of the microwave processed Zn1−xFexO (x=0.05, 0.10, 0.15, and 0.20) nanoparticles, together with ab initio calculations, were performed. Complementary information on the distribution of particle size and morphology, as well as magnetic properties, were obtained by X-ray diffraction, transmission electron microscopy, and squid-magnetometry. The selected model for analyzing the Mössbauer spectra of our samples is a distribution of quadrupole splittings. The fitting model with two Lorentz doublets was rejected due to its failure to include larger doublets. The Fe3+ ions do not yield magnetic ordering in the samples at room temperature. The results from first-principles calculations confirm that the major component of the Mössbauer spectra corresponds to the Fe-alloyed ZnO with Zn vacancy in the next nearest neighbor environment. The magnetic measurements are consistent with the description of the distribution of iron ions over the randomly formed clusters in the ZnO host lattice. While at room temperature all the samples are paramagnetic, magnetic interactions cause a transition into a cluster spin-glass state at low temperatures.",
publisher = "AIP Publishing",
journal = "Journal of Applied Physics",
title = "A study of defect structures in Fe-alloyed ZnO: Morphology, magnetism, and hyperfine interactions",
pages = "125703",
volume = "126",
number = "12",
doi = "10.1063/1.5095837",
url = "https://hdl.handle.net/21.15107/rcub_dais_6883"
}
Ivanovski, V. N., Belošević-Čavor, J., Rajić, V., Umićević, A., Marković, S., Kusigerski, V., Mitrić, M.,& Koteski, V.. (2019). A study of defect structures in Fe-alloyed ZnO: Morphology, magnetism, and hyperfine interactions. in Journal of Applied Physics
AIP Publishing., 126(12), 125703.
https://doi.org/10.1063/1.5095837
https://hdl.handle.net/21.15107/rcub_dais_6883
Ivanovski VN, Belošević-Čavor J, Rajić V, Umićević A, Marković S, Kusigerski V, Mitrić M, Koteski V. A study of defect structures in Fe-alloyed ZnO: Morphology, magnetism, and hyperfine interactions. in Journal of Applied Physics. 2019;126(12):125703.
doi:10.1063/1.5095837
https://hdl.handle.net/21.15107/rcub_dais_6883 .
Ivanovski, Valentin N., Belošević-Čavor, Jelena, Rajić, Vladimir, Umićević, Ana, Marković, Smilja, Kusigerski, Vladan, Mitrić, Miodrag, Koteski, Vasil, "A study of defect structures in Fe-alloyed ZnO: Morphology, magnetism, and hyperfine interactions" in Journal of Applied Physics, 126, no. 12 (2019):125703,
https://doi.org/10.1063/1.5095837 .,
https://hdl.handle.net/21.15107/rcub_dais_6883 .
4
5
4

Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Ivanovski, Valentin N.; Škapin, Srečo Davor; Dojčinović, Biljana; Uskoković, Dragan

(Elsevier, 2019)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Škapin, Srečo Davor
AU  - Dojčinović, Biljana
AU  - Uskoković, Dragan
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4937
AB  - A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose
SP  - 912
EP  - 919
VL  - 786
DO  - 10.1016/j.jallcom.2019.01.392
UR  - https://hdl.handle.net/21.15107/rcub_dais_4937
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Dojčinović, Biljana and Uskoković, Dragan",
year = "2019",
abstract = "A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose",
pages = "912-919",
volume = "786",
doi = "10.1016/j.jallcom.2019.01.392",
url = "https://hdl.handle.net/21.15107/rcub_dais_4937"
}
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D., Dojčinović, B.,& Uskoković, D.. (2019). Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds
Elsevier., 786, 912-919.
https://doi.org/10.1016/j.jallcom.2019.01.392
https://hdl.handle.net/21.15107/rcub_dais_4937
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Dojčinović B, Uskoković D. Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds. 2019;786:912-919.
doi:10.1016/j.jallcom.2019.01.392
https://hdl.handle.net/21.15107/rcub_dais_4937 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Dojčinović, Biljana, Uskoković, Dragan, "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose" in Journal of Alloys and Compounds, 786 (2019):912-919,
https://doi.org/10.1016/j.jallcom.2019.01.392 .,
https://hdl.handle.net/21.15107/rcub_dais_4937 .
2
3
4

Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Ivanovski, Valentin N.; Škapin, Srečo Davor; Dojčinović, Biljana; Uskoković, Dragan

(Elsevier, 2019)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Škapin, Srečo Davor
AU  - Dojčinović, Biljana
AU  - Uskoković, Dragan
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4938
AB  - A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose
SP  - 912
EP  - 919
VL  - 786
DO  - 10.1016/j.jallcom.2019.01.392
UR  - https://hdl.handle.net/21.15107/rcub_dais_4938
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Dojčinović, Biljana and Uskoković, Dragan",
year = "2019",
abstract = "A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose",
pages = "912-919",
volume = "786",
doi = "10.1016/j.jallcom.2019.01.392",
url = "https://hdl.handle.net/21.15107/rcub_dais_4938"
}
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D., Dojčinović, B.,& Uskoković, D.. (2019). Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds
Elsevier., 786, 912-919.
https://doi.org/10.1016/j.jallcom.2019.01.392
https://hdl.handle.net/21.15107/rcub_dais_4938
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Dojčinović B, Uskoković D. Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds. 2019;786:912-919.
doi:10.1016/j.jallcom.2019.01.392
https://hdl.handle.net/21.15107/rcub_dais_4938 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Dojčinović, Biljana, Uskoković, Dragan, "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose" in Journal of Alloys and Compounds, 786 (2019):912-919,
https://doi.org/10.1016/j.jallcom.2019.01.392 .,
https://hdl.handle.net/21.15107/rcub_dais_4938 .
2
3
4

The structure and electrochemical properties of fayalite Fe2SiO4

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Ivanovski, Valentin N.; Škapin, Srečo Davor; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2019)

TY  - CONF
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Škapin, Srečo Davor
AU  - Uskoković, Dragan
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6674
AB  - Fayalite has been found various applications in many fields. Here is presented its use as anode material for lithium ion batteries. The syntheses of Fe2SiO4 and its composite with carbon are conducted through solid-state reaction at 850 °C under inert atmosphere of argon, using cheap and abundant precursors (Fe(NO3)3×9H2O and amorphous silica). Citric acid served as carbon source. The phase-purity of synthesized powders is checked by X-ray powder diffraction. The crystal structure of the powders is refined in orthorhombic Pbnm space group. Half-cell configuration, with lithium metal as counter electrode and fayalite as working electrode, is used for electrochemical measurements: galvanostatic cycling and electrochemical impedance spectroscopy.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
T1  - The structure and electrochemical properties of fayalite Fe2SiO4
SP  - 47
EP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_dais_6674
ER  - 
@conference{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Uskoković, Dragan",
year = "2019",
abstract = "Fayalite has been found various applications in many fields. Here is presented its use as anode material for lithium ion batteries. The syntheses of Fe2SiO4 and its composite with carbon are conducted through solid-state reaction at 850 °C under inert atmosphere of argon, using cheap and abundant precursors (Fe(NO3)3×9H2O and amorphous silica). Citric acid served as carbon source. The phase-purity of synthesized powders is checked by X-ray powder diffraction. The crystal structure of the powders is refined in orthorhombic Pbnm space group. Half-cell configuration, with lithium metal as counter electrode and fayalite as working electrode, is used for electrochemical measurements: galvanostatic cycling and electrochemical impedance spectroscopy.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019",
title = "The structure and electrochemical properties of fayalite Fe2SiO4",
pages = "47-47",
url = "https://hdl.handle.net/21.15107/rcub_dais_6674"
}
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D.,& Uskoković, D.. (2019). The structure and electrochemical properties of fayalite Fe2SiO4. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
Belgrade : Materials Research Society of Serbia., 47-47.
https://hdl.handle.net/21.15107/rcub_dais_6674
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Uskoković D. The structure and electrochemical properties of fayalite Fe2SiO4. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019. 2019;:47-47.
https://hdl.handle.net/21.15107/rcub_dais_6674 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Uskoković, Dragan, "The structure and electrochemical properties of fayalite Fe2SiO4" in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019 (2019):47-47,
https://hdl.handle.net/21.15107/rcub_dais_6674 .

Point defect-enhanced optical and photoelectrochemical water splitting activity of nanostructured Zn1-xFeyO(1-x+1.5y)

Marković, Smilja; Rajić, Vladimir B.; Stojković Simatović, Ivana; Veselinović, Ljiljana; Belošević Čavor, Jelena; Ivanovski, Valentin N.; Novaković, Mirjana; Škapin, Srečo Davor; Stojadinović, Stevan; Rac, Vladislav; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2019)

TY  - CONF
AU  - Marković, Smilja
AU  - Rajić, Vladimir B.
AU  - Stojković Simatović, Ivana
AU  - Veselinović, Ljiljana
AU  - Belošević Čavor, Jelena
AU  - Ivanovski, Valentin N.
AU  - Novaković, Mirjana
AU  - Škapin, Srečo Davor
AU  - Stojadinović, Stevan
AU  - Rac, Vladislav
AU  - Uskoković, Dragan
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6677
AB  - Even has been under study since 1935, zinc oxide (ZnO) based materials still attract a huge scientific attention. Owing to a wide band gap energy (3.37 eV at room temperature) and a large exciton binding energy (60 meV) ZnO has a variety of application, e.g. in electronics, optoelectronics, spintronics and photocatalysis. Besides, it has been shown that zinc oxide-based materials have a great potential as photoelectrocatalysts in the processes of water splitting, yielding an increased both photocurrent density and photoconversion efficiency. However, with a band gap energy of 3.37 eV, ZnO is restricted to absorb UV light only. This restriction can be overcome by modifying optical properties of zinc oxide particles. During the years different approaches have been applied to modify the visible light photocatalytic activity of ZnO materials, for example: (1) metal and nonmetal ion doping, (2) hydrogenation, (3) the incorporation of crystalline defects in the form of vacancies and interstitials, (4) the modification of particles morphology and surface topology, etc.
In this study we employed 3d metal ion substitution to improve visible light-driven photoactivity of zinc oxide particles. We investigated the influence of Fe concentration in Zn1-xFeyO(1-x+1.5y) nanoparticles on crystal structure, textural, optical and photoelectrocatalytic properties. Zn1-xFeyO(1-x+1.5y) nanoparticles with nominally 5, 10, 15 and 20 at.% of Fe ions were synthesized by microwave processing of a precipitate. The crystal structure and phase purity of the samples were investigated by X-ray diffraction, Raman and ATR-FTIR spectroscopy. Mössbauer spectroscopy was carried out to clarify the valence state of the iron ions in the ZnO crystal structure. Effects of the iron ions concentration on particles morphology and texture properties were observed with field emission scanning electron microscopy (FE–SEM), transmission electron microscopy (TEM) with elemental mapping, and nitrogen adsorption–desorption isotherm, respectively. The optical properties were studied using UV–Vis diffuse reflectance and photoluminescence (PL) spectroscopy. Photoelectrochemical activity of the Zn1-xFeyO(1-x+1.5y) samples as anode material was evaluated by linear sweep voltammetry in Na2SO4 electrolyte; the oxygen evolution kinetics were determined and compared. In addition, a series of first principles calculations were performed to address the influence of the iron concentration on the electronic structure of Zn1-xFeyO(1-x+1.5y) samples.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
T1  - Point defect-enhanced optical and photoelectrochemical water splitting activity of nanostructured Zn1-xFeyO(1-x+1.5y)
SP  - 54
EP  - 54
UR  - https://hdl.handle.net/21.15107/rcub_dais_6677
ER  - 
@conference{
author = "Marković, Smilja and Rajić, Vladimir B. and Stojković Simatović, Ivana and Veselinović, Ljiljana and Belošević Čavor, Jelena and Ivanovski, Valentin N. and Novaković, Mirjana and Škapin, Srečo Davor and Stojadinović, Stevan and Rac, Vladislav and Uskoković, Dragan",
year = "2019",
abstract = "Even has been under study since 1935, zinc oxide (ZnO) based materials still attract a huge scientific attention. Owing to a wide band gap energy (3.37 eV at room temperature) and a large exciton binding energy (60 meV) ZnO has a variety of application, e.g. in electronics, optoelectronics, spintronics and photocatalysis. Besides, it has been shown that zinc oxide-based materials have a great potential as photoelectrocatalysts in the processes of water splitting, yielding an increased both photocurrent density and photoconversion efficiency. However, with a band gap energy of 3.37 eV, ZnO is restricted to absorb UV light only. This restriction can be overcome by modifying optical properties of zinc oxide particles. During the years different approaches have been applied to modify the visible light photocatalytic activity of ZnO materials, for example: (1) metal and nonmetal ion doping, (2) hydrogenation, (3) the incorporation of crystalline defects in the form of vacancies and interstitials, (4) the modification of particles morphology and surface topology, etc.
In this study we employed 3d metal ion substitution to improve visible light-driven photoactivity of zinc oxide particles. We investigated the influence of Fe concentration in Zn1-xFeyO(1-x+1.5y) nanoparticles on crystal structure, textural, optical and photoelectrocatalytic properties. Zn1-xFeyO(1-x+1.5y) nanoparticles with nominally 5, 10, 15 and 20 at.% of Fe ions were synthesized by microwave processing of a precipitate. The crystal structure and phase purity of the samples were investigated by X-ray diffraction, Raman and ATR-FTIR spectroscopy. Mössbauer spectroscopy was carried out to clarify the valence state of the iron ions in the ZnO crystal structure. Effects of the iron ions concentration on particles morphology and texture properties were observed with field emission scanning electron microscopy (FE–SEM), transmission electron microscopy (TEM) with elemental mapping, and nitrogen adsorption–desorption isotherm, respectively. The optical properties were studied using UV–Vis diffuse reflectance and photoluminescence (PL) spectroscopy. Photoelectrochemical activity of the Zn1-xFeyO(1-x+1.5y) samples as anode material was evaluated by linear sweep voltammetry in Na2SO4 electrolyte; the oxygen evolution kinetics were determined and compared. In addition, a series of first principles calculations were performed to address the influence of the iron concentration on the electronic structure of Zn1-xFeyO(1-x+1.5y) samples.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019",
title = "Point defect-enhanced optical and photoelectrochemical water splitting activity of nanostructured Zn1-xFeyO(1-x+1.5y)",
pages = "54-54",
url = "https://hdl.handle.net/21.15107/rcub_dais_6677"
}
Marković, S., Rajić, V. B., Stojković Simatović, I., Veselinović, L., Belošević Čavor, J., Ivanovski, V. N., Novaković, M., Škapin, S. D., Stojadinović, S., Rac, V.,& Uskoković, D.. (2019). Point defect-enhanced optical and photoelectrochemical water splitting activity of nanostructured Zn1-xFeyO(1-x+1.5y). in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
Belgrade : Materials Research Society of Serbia., 54-54.
https://hdl.handle.net/21.15107/rcub_dais_6677
Marković S, Rajić VB, Stojković Simatović I, Veselinović L, Belošević Čavor J, Ivanovski VN, Novaković M, Škapin SD, Stojadinović S, Rac V, Uskoković D. Point defect-enhanced optical and photoelectrochemical water splitting activity of nanostructured Zn1-xFeyO(1-x+1.5y). in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019. 2019;:54-54.
https://hdl.handle.net/21.15107/rcub_dais_6677 .
Marković, Smilja, Rajić, Vladimir B., Stojković Simatović, Ivana, Veselinović, Ljiljana, Belošević Čavor, Jelena, Ivanovski, Valentin N., Novaković, Mirjana, Škapin, Srečo Davor, Stojadinović, Stevan, Rac, Vladislav, Uskoković, Dragan, "Point defect-enhanced optical and photoelectrochemical water splitting activity of nanostructured Zn1-xFeyO(1-x+1.5y)" in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019 (2019):54-54,
https://hdl.handle.net/21.15107/rcub_dais_6677 .

Structural and electrochemical study of lithium iron (II) pyrophosphate

Jugović, Dragana; Milović, Miloš; Mitrić, Miodrag; Ivanovski, Valentin N.; Škapin, Srečo Davor; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Mitrić, Miodrag
AU  - Ivanovski, Valentin N.
AU  - Škapin, Srečo Davor
AU  - Uskoković, Dragan
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3632
AB  - Lithium iron(II) pyrophosphate, Li2FeP2O7, attracts attention of researchers for application as a cathode material in rechargeable lithium batteries. Li2FeP2O7 has somewhat higher voltage than commercial LiFePO4 (3.5 and 3.4 V, respectively), thus enables higher energy density, and also provides the possibility of two-electron reaction during intercalation. Within this study, pristine Li2FeP2O7 and its composite with carbon Li2FeP2O7/C were synthesized, with the carbon being formed by the pyrolysis of organic precursor in situ during formation of Li2FeP2O7 at high temperature. The polymer of methylcellulose was used as carbon source because of its ability to reversibly, depending on temperature, dissolve or gel in water. The structural, electrical and electrochemical characteristics of prepared powders were investigated by means of X-ray diffraction analysis, Mossbauer spectroscopy, impedance spectroscopy and galvanostatic charge/discharge testing. The results imply that in situ formation of carbon alters lattice parameters, decreases crystallite size, and facilitates lithium ion intercalation/deintercalation processes. The Ministry of Education, Science and Technological Development of the Republic of Serbia provided financial support for this study under Grant No. III 45004
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - Structural and electrochemical study of lithium iron (II) pyrophosphate
SP  - 68
EP  - 68
UR  - https://hdl.handle.net/21.15107/rcub_dais_3632
ER  - 
@conference{
author = "Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Ivanovski, Valentin N. and Škapin, Srečo Davor and Uskoković, Dragan",
year = "2018",
abstract = "Lithium iron(II) pyrophosphate, Li2FeP2O7, attracts attention of researchers for application as a cathode material in rechargeable lithium batteries. Li2FeP2O7 has somewhat higher voltage than commercial LiFePO4 (3.5 and 3.4 V, respectively), thus enables higher energy density, and also provides the possibility of two-electron reaction during intercalation. Within this study, pristine Li2FeP2O7 and its composite with carbon Li2FeP2O7/C were synthesized, with the carbon being formed by the pyrolysis of organic precursor in situ during formation of Li2FeP2O7 at high temperature. The polymer of methylcellulose was used as carbon source because of its ability to reversibly, depending on temperature, dissolve or gel in water. The structural, electrical and electrochemical characteristics of prepared powders were investigated by means of X-ray diffraction analysis, Mossbauer spectroscopy, impedance spectroscopy and galvanostatic charge/discharge testing. The results imply that in situ formation of carbon alters lattice parameters, decreases crystallite size, and facilitates lithium ion intercalation/deintercalation processes. The Ministry of Education, Science and Technological Development of the Republic of Serbia provided financial support for this study under Grant No. III 45004",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "Structural and electrochemical study of lithium iron (II) pyrophosphate",
pages = "68-68",
url = "https://hdl.handle.net/21.15107/rcub_dais_3632"
}
Jugović, D., Milović, M., Mitrić, M., Ivanovski, V. N., Škapin, S. D.,& Uskoković, D.. (2018). Structural and electrochemical study of lithium iron (II) pyrophosphate. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
Belgrade : Materials Research Society of Serbia., 68-68.
https://hdl.handle.net/21.15107/rcub_dais_3632
Jugović D, Milović M, Mitrić M, Ivanovski VN, Škapin SD, Uskoković D. Structural and electrochemical study of lithium iron (II) pyrophosphate. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018. 2018;:68-68.
https://hdl.handle.net/21.15107/rcub_dais_3632 .
Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Ivanovski, Valentin N., Škapin, Srečo Davor, Uskoković, Dragan, "Structural and electrochemical study of lithium iron (II) pyrophosphate" in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018 (2018):68-68,
https://hdl.handle.net/21.15107/rcub_dais_3632 .

Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy

Jugović, Dragana; Milović, Miloš; Ivanovski, Valentin N.; Avdeev, Maxim; Dominko, Robert; Jokić, Bojan; Uskoković, Dragan

(2014)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Avdeev, Maxim
AU  - Dominko, Robert
AU  - Jokić, Bojan
AU  - Uskoković, Dragan
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/755
AB  - A composite powder Li2FeSiO4/C is synthesized through a solid state reaction at 750 °C. The Rietveld crystal structure refinement is done in the monoclinic P21/n space group. It is found that the crystal structure is prone to “antisite” defect where small part of iron ion occupies exclusively Li(2) crystallographic position, of two different lithium tetrahedral positions (Li(1) and Li(2)). This finding is also confirmed by Mössbauer spectroscopy study: the sextet evidenced in the Mössbauer spectrum is assigned to the iron ions positioned at the Li(2) sites. A bond-valence energy landscape calculation is used to predict the conduction pathways of lithium ions. The calculations suggest that Li conductivity is two-dimensional in the (101) plane. Upon galvanostatic cyclings the structure starts to rearrange to inverse βII polymorph.
T2  - Journal of Power Sources
T1  - Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy
SP  - 75
EP  - 80
VL  - 265
DO  - 10.1016/j.jpowsour.2014.04.121
UR  - https://hdl.handle.net/21.15107/rcub_dais_755
ER  - 
@article{
author = "Jugović, Dragana and Milović, Miloš and Ivanovski, Valentin N. and Avdeev, Maxim and Dominko, Robert and Jokić, Bojan and Uskoković, Dragan",
year = "2014",
abstract = "A composite powder Li2FeSiO4/C is synthesized through a solid state reaction at 750 °C. The Rietveld crystal structure refinement is done in the monoclinic P21/n space group. It is found that the crystal structure is prone to “antisite” defect where small part of iron ion occupies exclusively Li(2) crystallographic position, of two different lithium tetrahedral positions (Li(1) and Li(2)). This finding is also confirmed by Mössbauer spectroscopy study: the sextet evidenced in the Mössbauer spectrum is assigned to the iron ions positioned at the Li(2) sites. A bond-valence energy landscape calculation is used to predict the conduction pathways of lithium ions. The calculations suggest that Li conductivity is two-dimensional in the (101) plane. Upon galvanostatic cyclings the structure starts to rearrange to inverse βII polymorph.",
journal = "Journal of Power Sources",
title = "Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy",
pages = "75-80",
volume = "265",
doi = "10.1016/j.jpowsour.2014.04.121",
url = "https://hdl.handle.net/21.15107/rcub_dais_755"
}
Jugović, D., Milović, M., Ivanovski, V. N., Avdeev, M., Dominko, R., Jokić, B.,& Uskoković, D.. (2014). Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy. in Journal of Power Sources, 265, 75-80.
https://doi.org/10.1016/j.jpowsour.2014.04.121
https://hdl.handle.net/21.15107/rcub_dais_755
Jugović D, Milović M, Ivanovski VN, Avdeev M, Dominko R, Jokić B, Uskoković D. Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy. in Journal of Power Sources. 2014;265:75-80.
doi:10.1016/j.jpowsour.2014.04.121
https://hdl.handle.net/21.15107/rcub_dais_755 .
Jugović, Dragana, Milović, Miloš, Ivanovski, Valentin N., Avdeev, Maxim, Dominko, Robert, Jokić, Bojan, Uskoković, Dragan, "Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy" in Journal of Power Sources, 265 (2014):75-80,
https://doi.org/10.1016/j.jpowsour.2014.04.121 .,
https://hdl.handle.net/21.15107/rcub_dais_755 .
10
12
13

Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy

Jugović, Dragana; Milović, Miloš; Ivanovski, Valentin N.; Avdeev, Maxim; Dominko, Robert; Jokić, Bojan; Uskoković, Dragan

(Elsevier, 2014)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Avdeev, Maxim
AU  - Dominko, Robert
AU  - Jokić, Bojan
AU  - Uskoković, Dragan
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/542
AB  - A composite powder Li2FeSiO4/C is synthesized through a solid state reaction at 750 °C. The Rietveld crystal structure refinement is done in the monoclinic P21/n space group. It is found that the crystal structure is prone to “antisite” defect where small part of iron ion occupies exclusively Li(2) crystallographic position, of two different lithium tetrahedral positions (Li(1) and Li(2)). This finding is also confirmed by Mössbauer spectroscopy study: the sextet evidenced in the Mössbauer spectrum is assigned to the iron ions positioned at the Li(2) sites. A bond-valence energy landscape calculation is used to predict the conduction pathways of lithium ions. The calculations suggest that Li conductivity is two-dimensional in the (101) plane. Upon galvanostatic cyclings the structure starts to rearrange to inverse βII polymorph.
PB  - Elsevier
T2  - Journal of Power Sources
T1  - Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy
SP  - 75
EP  - 80
VL  - 265
DO  - 10.1016/j.jpowsour.2014.04.121
UR  - https://hdl.handle.net/21.15107/rcub_dais_542
ER  - 
@article{
author = "Jugović, Dragana and Milović, Miloš and Ivanovski, Valentin N. and Avdeev, Maxim and Dominko, Robert and Jokić, Bojan and Uskoković, Dragan",
year = "2014",
abstract = "A composite powder Li2FeSiO4/C is synthesized through a solid state reaction at 750 °C. The Rietveld crystal structure refinement is done in the monoclinic P21/n space group. It is found that the crystal structure is prone to “antisite” defect where small part of iron ion occupies exclusively Li(2) crystallographic position, of two different lithium tetrahedral positions (Li(1) and Li(2)). This finding is also confirmed by Mössbauer spectroscopy study: the sextet evidenced in the Mössbauer spectrum is assigned to the iron ions positioned at the Li(2) sites. A bond-valence energy landscape calculation is used to predict the conduction pathways of lithium ions. The calculations suggest that Li conductivity is two-dimensional in the (101) plane. Upon galvanostatic cyclings the structure starts to rearrange to inverse βII polymorph.",
publisher = "Elsevier",
journal = "Journal of Power Sources",
title = "Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy",
pages = "75-80",
volume = "265",
doi = "10.1016/j.jpowsour.2014.04.121",
url = "https://hdl.handle.net/21.15107/rcub_dais_542"
}
Jugović, D., Milović, M., Ivanovski, V. N., Avdeev, M., Dominko, R., Jokić, B.,& Uskoković, D.. (2014). Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy. in Journal of Power Sources
Elsevier., 265, 75-80.
https://doi.org/10.1016/j.jpowsour.2014.04.121
https://hdl.handle.net/21.15107/rcub_dais_542
Jugović D, Milović M, Ivanovski VN, Avdeev M, Dominko R, Jokić B, Uskoković D. Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy. in Journal of Power Sources. 2014;265:75-80.
doi:10.1016/j.jpowsour.2014.04.121
https://hdl.handle.net/21.15107/rcub_dais_542 .
Jugović, Dragana, Milović, Miloš, Ivanovski, Valentin N., Avdeev, Maxim, Dominko, Robert, Jokić, Bojan, Uskoković, Dragan, "Structural study of monoclinic Li2FeSiO4 by X-ray diffraction and Mössbauer spectroscopy" in Journal of Power Sources, 265 (2014):75-80,
https://doi.org/10.1016/j.jpowsour.2014.04.121 .,
https://hdl.handle.net/21.15107/rcub_dais_542 .
10
12
13

Li2FeSiO4 cathode material: the structure and electrochemical performances

Jugović, Dragana; Milović, Miloš; Mitrić, Miodrag; Ivanovski, Valentin N.; Avdeev, Maxim; Jokić, Bojan; Dominko, Robert; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2014)

TY  - CONF
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Mitrić, Miodrag
AU  - Ivanovski, Valentin N.
AU  - Avdeev, Maxim
AU  - Jokić, Bojan
AU  - Dominko, Robert
AU  - Uskoković, Dragan
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/590
AB  - Monoclinic Li2FeSiO4 that crystallizes in P21/n space group was investigated as a potential cathode material for lithium-ion batteries. A combined X-ray diffraction and Mössbauer spectroscopy study was used for the structural investigation. It was found that the crystal structure is prone to an “antisite” defect, the one in which the Fe ion and the Li ion exchange places. This finding was also confirmed by the Mössbauer spectroscopy. In order to obtain composites of Li2FeSiO4 and carbon, several synthesis techniques that use different carbon sources were involved. Electrochemical performances were investigated through galvanostatic charge/discharge tests. Discharge curve profile did not reflect a two-phase intercalation reaction (no obvious voltage plateau) due to the low conductivity at room temperature.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts
T1  - Li2FeSiO4 cathode material: the structure and electrochemical performances
SP  - 6
EP  - 6
UR  - https://hdl.handle.net/21.15107/rcub_dais_590
ER  - 
@conference{
author = "Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Ivanovski, Valentin N. and Avdeev, Maxim and Jokić, Bojan and Dominko, Robert and Uskoković, Dragan",
year = "2014",
abstract = "Monoclinic Li2FeSiO4 that crystallizes in P21/n space group was investigated as a potential cathode material for lithium-ion batteries. A combined X-ray diffraction and Mössbauer spectroscopy study was used for the structural investigation. It was found that the crystal structure is prone to an “antisite” defect, the one in which the Fe ion and the Li ion exchange places. This finding was also confirmed by the Mössbauer spectroscopy. In order to obtain composites of Li2FeSiO4 and carbon, several synthesis techniques that use different carbon sources were involved. Electrochemical performances were investigated through galvanostatic charge/discharge tests. Discharge curve profile did not reflect a two-phase intercalation reaction (no obvious voltage plateau) due to the low conductivity at room temperature.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts",
title = "Li2FeSiO4 cathode material: the structure and electrochemical performances",
pages = "6-6",
url = "https://hdl.handle.net/21.15107/rcub_dais_590"
}
Jugović, D., Milović, M., Mitrić, M., Ivanovski, V. N., Avdeev, M., Jokić, B., Dominko, R.,& Uskoković, D.. (2014). Li2FeSiO4 cathode material: the structure and electrochemical performances. in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 6-6.
https://hdl.handle.net/21.15107/rcub_dais_590
Jugović D, Milović M, Mitrić M, Ivanovski VN, Avdeev M, Jokić B, Dominko R, Uskoković D. Li2FeSiO4 cathode material: the structure and electrochemical performances. in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts. 2014;:6-6.
https://hdl.handle.net/21.15107/rcub_dais_590 .
Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Ivanovski, Valentin N., Avdeev, Maxim, Jokić, Bojan, Dominko, Robert, Uskoković, Dragan, "Li2FeSiO4 cathode material: the structure and electrochemical performances" in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts (2014):6-6,
https://hdl.handle.net/21.15107/rcub_dais_590 .

Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid

Jugović, Dragana; Mitrić, Miodrag; Kuzmanović, Maja; Cvjetićanin, Nikola; Škapin, Srečo Davor; Cekić, Božidar; Ivanovski, Valentin N.; Uskoković, Dragan

(2011)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Kuzmanović, Maja
AU  - Cvjetićanin, Nikola
AU  - Škapin, Srečo Davor
AU  - Cekić, Božidar
AU  - Ivanovski, Valentin N.
AU  - Uskoković, Dragan
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/751
AB  - The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.
T2  - Journal of Power Sources
T1  - Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid
SP  - 4613
SP  - 4618
EP  - 4618
VL  - 196
IS  - 10
DO  - 10.1016/j.jpowsour.2011.01.072
UR  - https://hdl.handle.net/21.15107/rcub_dais_751
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Kuzmanović, Maja and Cvjetićanin, Nikola and Škapin, Srečo Davor and Cekić, Božidar and Ivanovski, Valentin N. and Uskoković, Dragan",
year = "2011",
abstract = "The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.",
journal = "Journal of Power Sources",
title = "Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid",
pages = "4613-4618-4618",
volume = "196",
number = "10",
doi = "10.1016/j.jpowsour.2011.01.072",
url = "https://hdl.handle.net/21.15107/rcub_dais_751"
}
Jugović, D., Mitrić, M., Kuzmanović, M., Cvjetićanin, N., Škapin, S. D., Cekić, B., Ivanovski, V. N.,& Uskoković, D.. (2011). Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid. in Journal of Power Sources, 196(10), 4613-4618.
https://doi.org/10.1016/j.jpowsour.2011.01.072
https://hdl.handle.net/21.15107/rcub_dais_751
Jugović D, Mitrić M, Kuzmanović M, Cvjetićanin N, Škapin SD, Cekić B, Ivanovski VN, Uskoković D. Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid. in Journal of Power Sources. 2011;196(10):4613-4618.
doi:10.1016/j.jpowsour.2011.01.072
https://hdl.handle.net/21.15107/rcub_dais_751 .
Jugović, Dragana, Mitrić, Miodrag, Kuzmanović, Maja, Cvjetićanin, Nikola, Škapin, Srečo Davor, Cekić, Božidar, Ivanovski, Valentin N., Uskoković, Dragan, "Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid" in Journal of Power Sources, 196, no. 10 (2011):4613-4618,
https://doi.org/10.1016/j.jpowsour.2011.01.072 .,
https://hdl.handle.net/21.15107/rcub_dais_751 .
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Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid

Jugović, Dragana; Mitrić, Miodrag; Kuzmanović, Maja; Cvjetićanin, Nikola; Škapin, Srečo Davor; Cekić, Božidar; Ivanovski, Valentin N.; Uskoković, Dragan

(Elsevier, 2011)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Kuzmanović, Maja
AU  - Cvjetićanin, Nikola
AU  - Škapin, Srečo Davor
AU  - Cekić, Božidar
AU  - Ivanovski, Valentin N.
AU  - Uskoković, Dragan
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/708
AB  - The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.
PB  - Elsevier
T2  - Journal of Power Sources
T1  - Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid
SP  - 4613
EP  - 4618
DO  - 10.1016/j.jpowsour.2011.01.072
UR  - https://hdl.handle.net/21.15107/rcub_dais_708
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Kuzmanović, Maja and Cvjetićanin, Nikola and Škapin, Srečo Davor and Cekić, Božidar and Ivanovski, Valentin N. and Uskoković, Dragan",
year = "2011",
abstract = "The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.",
publisher = "Elsevier",
journal = "Journal of Power Sources",
title = "Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid",
pages = "4613-4618",
doi = "10.1016/j.jpowsour.2011.01.072",
url = "https://hdl.handle.net/21.15107/rcub_dais_708"
}
Jugović, D., Mitrić, M., Kuzmanović, M., Cvjetićanin, N., Škapin, S. D., Cekić, B., Ivanovski, V. N.,& Uskoković, D.. (2011). Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid. in Journal of Power Sources
Elsevier., 4613-4618.
https://doi.org/10.1016/j.jpowsour.2011.01.072
https://hdl.handle.net/21.15107/rcub_dais_708
Jugović D, Mitrić M, Kuzmanović M, Cvjetićanin N, Škapin SD, Cekić B, Ivanovski VN, Uskoković D. Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid. in Journal of Power Sources. 2011;:4613-4618.
doi:10.1016/j.jpowsour.2011.01.072
https://hdl.handle.net/21.15107/rcub_dais_708 .
Jugović, Dragana, Mitrić, Miodrag, Kuzmanović, Maja, Cvjetićanin, Nikola, Škapin, Srečo Davor, Cekić, Božidar, Ivanovski, Valentin N., Uskoković, Dragan, "Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid" in Journal of Power Sources (2011):4613-4618,
https://doi.org/10.1016/j.jpowsour.2011.01.072 .,
https://hdl.handle.net/21.15107/rcub_dais_708 .
30
30
32