TY  - JOUR
AU  - Biliškov, Nikola
AU  - Milanović, Igor
AU  - Milović, Miloš
AU  - Takats, Viktor
AU  - Erdelyi, Zoltan
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15194
AB  - The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.
T2  - Journal of Alloys and Compounds
T1  - Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials
SP  - 169293
VL  - 945
DO  - 10.1016/j.jallcom.2023.169293
UR  - https://hdl.handle.net/21.15107/rcub_dais_15194
ER  - 

@article{
author = "Biliškov, Nikola and Milanović, Igor and Milović, Miloš and Takats, Viktor and Erdelyi, Zoltan",
year = "2023",
abstract = "The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.",
journal = "Journal of Alloys and Compounds",
title = "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials",
pages = "169293",
volume = "945",
doi = "10.1016/j.jallcom.2023.169293",
url = "https://hdl.handle.net/21.15107/rcub_dais_15194"
}

Biliškov, N., Milanović, I., Milović, M., Takats, V.,& Erdelyi, Z.. (2023). Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds, 945, 169293.
https://doi.org/10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_15194

Biliškov N, Milanović I, Milović M, Takats V, Erdelyi Z. Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds. 2023;945:169293.
doi:10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_15194 .

Biliškov, Nikola, Milanović, Igor, Milović, Miloš, Takats, Viktor, Erdelyi, Zoltan, "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials" in Journal of Alloys and Compounds, 945 (2023):169293,
https://doi.org/10.1016/j.jallcom.2023.169293 .,
https://hdl.handle.net/21.15107/rcub_dais_15194 .

TY  - JOUR
AU  - Biliškov, Nikola
AU  - Milanović, Igor
AU  - Milović, Miloš
AU  - Takats, Viktor
AU  - Erdelyi, Zoltan
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14288
AB  - The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.
T2  - Journal of Alloys and Compounds
T1  - Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials
SP  - 169293
VL  - 945
DO  - 10.1016/j.jallcom.2023.169293
UR  - https://hdl.handle.net/21.15107/rcub_dais_14288
ER  - 

@article{
author = "Biliškov, Nikola and Milanović, Igor and Milović, Miloš and Takats, Viktor and Erdelyi, Zoltan",
year = "2023",
abstract = "The maximization of the number of exposed edges of layered MoS2-type transition metal dichalcogenides of general formula MX2 (M = Mo, W; X = S, Se) is difficult yet meaningful way to improve their electrochemical and electrocatalytic performance. In this work, an all-solid ball milling method for simultaneous introduction of defects and their hybridization through binding of ammonia borane (NH3BH3) to defect sites of MX2 is demonstrated. The milling conditions leads to partial separation and nanosizing of MX2 layers, simultaneously extensively introducing defects (cracks, vacancies, strains, voids etc.), while the detailed analysis revealed the functionalization of the material by binding of NH3BH3 to defect sites, which results in highly improved electrocatalytic performance of thus obtained composites with respect to MX2 for hydrogen evolution reaction. The mechanochemical approach thus enables preparation of MoS2-type materials with improved, highly tunable activity, potentially relevant for energy conversion and storage.",
journal = "Journal of Alloys and Compounds",
title = "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials",
pages = "169293",
volume = "945",
doi = "10.1016/j.jallcom.2023.169293",
url = "https://hdl.handle.net/21.15107/rcub_dais_14288"
}

Biliškov, N., Milanović, I., Milović, M., Takats, V.,& Erdelyi, Z.. (2023). Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds, 945, 169293.
https://doi.org/10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_14288

Biliškov N, Milanović I, Milović M, Takats V, Erdelyi Z. Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials. in Journal of Alloys and Compounds. 2023;945:169293.
doi:10.1016/j.jallcom.2023.169293
https://hdl.handle.net/21.15107/rcub_dais_14288 .

Biliškov, Nikola, Milanović, Igor, Milović, Miloš, Takats, Viktor, Erdelyi, Zoltan, "Ammonia borane assisted mechanochemical boost of electrochemical performance of basal planes of MoS2-type materials" in Journal of Alloys and Compounds, 945 (2023):169293,
https://doi.org/10.1016/j.jallcom.2023.169293 .,
https://hdl.handle.net/21.15107/rcub_dais_14288 .

TY  - JOUR
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag J.
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Biliškov, Nikola
AU  - Milošević Govedarović, Sanja
PY  - 2020
UR  - http://www.sciencedirect.com/science/article/pii/S0360319919327685
UR  - https://dais.sanu.ac.rs/123456789/6455
AB  - The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites
SP  - 7901
EP  - 7911
VL  - 45
IS  - 14
DO  - 10.1016/j.ijhydene.2019.07.167
UR  - https://hdl.handle.net/21.15107/rcub_dais_6455
ER  - 

@article{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević Govedarović, Sanja",
year = "2020",
abstract = "The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites",
pages = "7901-7911",
volume = "45",
number = "14",
doi = "10.1016/j.ijhydene.2019.07.167",
url = "https://hdl.handle.net/21.15107/rcub_dais_6455"
}

Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević Govedarović, S.. (2020). The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy
Elsevier., 45(14), 7901-7911.
https://doi.org/10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_6455

Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević Govedarović S. The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy. 2020;45(14):7901-7911.
doi:10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_6455 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag J., Grbović Novaković, Jasmina, Kurko, Sandra, Biliškov, Nikola, Milošević Govedarović, Sanja, "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7901-7911,
https://doi.org/10.1016/j.ijhydene.2019.07.167 .,
https://hdl.handle.net/21.15107/rcub_dais_6455 .

TY  - JOUR
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag J.
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Biliškov, Nikola
AU  - Milošević Govedarović, Sanja
PY  - 2020
UR  - http://www.sciencedirect.com/science/article/pii/S0360319919327685
UR  - https://dais.sanu.ac.rs/123456789/8963
AB  - The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites
SP  - 7901
EP  - 7911
VL  - 45
IS  - 14
DO  - 10.1016/j.ijhydene.2019.07.167
UR  - https://hdl.handle.net/21.15107/rcub_dais_8963
ER  - 

@article{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević Govedarović, Sanja",
year = "2020",
abstract = "The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites",
pages = "7901-7911",
volume = "45",
number = "14",
doi = "10.1016/j.ijhydene.2019.07.167",
url = "https://hdl.handle.net/21.15107/rcub_dais_8963"
}

Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević Govedarović, S.. (2020). The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy
Elsevier., 45(14), 7901-7911.
https://doi.org/10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_8963

Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević Govedarović S. The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy. 2020;45(14):7901-7911.
doi:10.1016/j.ijhydene.2019.07.167
https://hdl.handle.net/21.15107/rcub_dais_8963 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag J., Grbović Novaković, Jasmina, Kurko, Sandra, Biliškov, Nikola, Milošević Govedarović, Sanja, "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7901-7911,
https://doi.org/10.1016/j.ijhydene.2019.07.167 .,
https://hdl.handle.net/21.15107/rcub_dais_8963 .

TY  - CONF
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag J.
AU  - Grbović Novaković, Jasmina
AU  - Kurko, Sandra
AU  - Biliškov, Nikola
AU  - Milošević, Sanja S.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/15451
AB  - Magnesium hydride, as hydrogen storage material, meets the requirements such as high gravimetric hydrogen capacity (7,6 wt%), low cost and weight, abundance and H2 absorption/desorption cycling possibility. Given that the oxide additives show the good impact on desorption properties, mechanical milling of MgH2 with addition of 5, 10 and 15% wt. WO3 was performed. The microstructure and morphology of composites were analysed by XRD, PSD and SEM and correlated to hydrogen desorption properties which have been investigated by DSC. The results have shown that WO3 has a positive effect on the desorption kinetics as well as on the change of the desorption mechanism.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
T1  - Is WO3 catalyst for hydrogen desorption?
SP  - 50
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_dais_15451
ER  - 

@conference{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević, Sanja S.",
year = "2017",
abstract = "Magnesium hydride, as hydrogen storage material, meets the requirements such as high gravimetric hydrogen capacity (7,6 wt%), low cost and weight, abundance and H2 absorption/desorption cycling possibility. Given that the oxide additives show the good impact on desorption properties, mechanical milling of MgH2 with addition of 5, 10 and 15% wt. WO3 was performed. The microstructure and morphology of composites were analysed by XRD, PSD and SEM and correlated to hydrogen desorption properties which have been investigated by DSC. The results have shown that WO3 has a positive effect on the desorption kinetics as well as on the change of the desorption mechanism.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia",
title = "Is WO3 catalyst for hydrogen desorption?",
pages = "50-50",
url = "https://hdl.handle.net/21.15107/rcub_dais_15451"
}

Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević, S. S.. (2017). Is WO3 catalyst for hydrogen desorption?. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 50-50.
https://hdl.handle.net/21.15107/rcub_dais_15451

Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević SS. Is WO3 catalyst for hydrogen desorption?. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia. 2017;:50-50.
https://hdl.handle.net/21.15107/rcub_dais_15451 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag J., Grbović Novaković, Jasmina, Kurko, Sandra, Biliškov, Nikola, Milošević, Sanja S., "Is WO3 catalyst for hydrogen desorption?" in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia (2017):50-50,
https://hdl.handle.net/21.15107/rcub_dais_15451 .