TY  - JOUR
AU  - Grgur, Branimir
AU  - Žugić, Dragana
AU  - Gvozdenović, Milica M.
AU  - Trišović, Tomislav
PY  - 2006
UR  - https://dais.sanu.ac.rs/123456789/11713
AB  - The kinetics of the oxidation Of D-glucose to D-gluconic acid by bromine in aqueous solution were studied using potentiometric techniques and theoretical considerations of complex bromine-bromide-pH equilibria. The pH has a strong influence on reaction rate. At pH  lt  8 the reaction is very slow, while in the pH range pH 8-9.5 the reaction is sufficiently fast and seems optimal for the reaction. The proposed active species at that pH region is hypobromous acid. At pH  gt  9.5, the reaction is further accelerated due to the formation of hypobromite. The proposed kinetics expression for gluconic acid formation, based on the determined kinetic parameters at pH 9.24, is of the form dc(GA)/dt = 160c(2)(G)c(0)(HOBr)c(0)(H+)c(0)(Br)
PB  - Oxford : Elsevier Sci Ltd.
T2  - Carbohydrate Research
T1  - A kinetic study of D-glucose oxidation by bromine in aqueous solutions
SP  - 1779
EP  - 1787
VL  - 341
IS  - 11
DO  - 10.1016/j.carres.2006.04.035
UR  - https://hdl.handle.net/21.15107/rcub_dais_11713
ER  - 

@article{
author = "Grgur, Branimir and Žugić, Dragana and Gvozdenović, Milica M. and Trišović, Tomislav",
year = "2006",
abstract = "The kinetics of the oxidation Of D-glucose to D-gluconic acid by bromine in aqueous solution were studied using potentiometric techniques and theoretical considerations of complex bromine-bromide-pH equilibria. The pH has a strong influence on reaction rate. At pH  lt  8 the reaction is very slow, while in the pH range pH 8-9.5 the reaction is sufficiently fast and seems optimal for the reaction. The proposed active species at that pH region is hypobromous acid. At pH  gt  9.5, the reaction is further accelerated due to the formation of hypobromite. The proposed kinetics expression for gluconic acid formation, based on the determined kinetic parameters at pH 9.24, is of the form dc(GA)/dt = 160c(2)(G)c(0)(HOBr)c(0)(H+)c(0)(Br)",
publisher = "Oxford : Elsevier Sci Ltd.",
journal = "Carbohydrate Research",
title = "A kinetic study of D-glucose oxidation by bromine in aqueous solutions",
pages = "1779-1787",
volume = "341",
number = "11",
doi = "10.1016/j.carres.2006.04.035",
url = "https://hdl.handle.net/21.15107/rcub_dais_11713"
}

Grgur, B., Žugić, D., Gvozdenović, M. M.,& Trišović, T.. (2006). A kinetic study of D-glucose oxidation by bromine in aqueous solutions. in Carbohydrate Research
Oxford : Elsevier Sci Ltd.., 341(11), 1779-1787.
https://doi.org/10.1016/j.carres.2006.04.035
https://hdl.handle.net/21.15107/rcub_dais_11713

Grgur B, Žugić D, Gvozdenović MM, Trišović T. A kinetic study of D-glucose oxidation by bromine in aqueous solutions. in Carbohydrate Research. 2006;341(11):1779-1787.
doi:10.1016/j.carres.2006.04.035
https://hdl.handle.net/21.15107/rcub_dais_11713 .

Grgur, Branimir, Žugić, Dragana, Gvozdenović, Milica M., Trišović, Tomislav, "A kinetic study of D-glucose oxidation by bromine in aqueous solutions" in Carbohydrate Research, 341, no. 11 (2006):1779-1787,
https://doi.org/10.1016/j.carres.2006.04.035 .,
https://hdl.handle.net/21.15107/rcub_dais_11713 .