TY  - JOUR
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Yamamoto, Kazuhiro
AU  - Ohara, Satoshi
AU  - Tamura, Sayaka
AU  - Koji, Tomita
AU  - Costa, Antonio Mario Leal Martins
AU  - Marinković, Bojan A.
AU  - Milošević, Olivera
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/3687
AB  - In this feature article, we highlight our works on compositional and structural dependence of up-converting rare earth (RE) fluorides obtained through ethylenediamine tetraacetic acid (EDTA) assisted hydrothermal synthesis. Various nanostructures were obtained by tuning of experimental conditions, such as precursor’s concentration, degree of doping, reaction time and solvent used during synthesis. We correlated in detail the structural, morphological and optical properties of YF3 and NaYF4 compounds co-doped with Yb3+ and Er3+ (introduced in total mol% of 8 and 20). For this purpose, X-ray powder diffraction, scanning and transmission electron microscopy, energy dispersive X-ray and Furrier transform infrared spectroscopy, as well as, the photoluminescence spectra and decay times were recorded and analyzed. The particle size and phase content were found to be dependent on the nucleation rate, which, in turn, was governed by the precursor concentration, degree of doping and solvent type. The transformation from cubic to hexagonal NaYF4:Yb3+/Er3+ phase was found to be sensitive to the reaction time and precursors concentration, while the crystallization of orthorhombic YF3:Yb3+/Er3+ phase is achieved through lowering of dopants concentration or by changing of solvent during hydrothermal treatment. The up-conversion photoluminescence demonstrated morphology and crystal phase dependence and is found to be superior in microcrystalline samples, independent on their phase composition.
PB  - Elsevier
T2  - Advanced Powder Technology
T2  - Advanced Powder Technology
T1  - Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis
SP  - 73
EP  - 82
VL  - 28
IS  - 1
DO  - 10.1016/j.apt.2016.09.021
UR  - https://hdl.handle.net/21.15107/rcub_dais_3687
ER  - 

@article{
author = "Dinić, Ivana and Mančić, Lidija and Rabanal, Maria Eugenia and Yamamoto, Kazuhiro and Ohara, Satoshi and Tamura, Sayaka and Koji, Tomita and Costa, Antonio Mario Leal Martins and Marinković, Bojan A. and Milošević, Olivera",
year = "2017",
abstract = "In this feature article, we highlight our works on compositional and structural dependence of up-converting rare earth (RE) fluorides obtained through ethylenediamine tetraacetic acid (EDTA) assisted hydrothermal synthesis. Various nanostructures were obtained by tuning of experimental conditions, such as precursor’s concentration, degree of doping, reaction time and solvent used during synthesis. We correlated in detail the structural, morphological and optical properties of YF3 and NaYF4 compounds co-doped with Yb3+ and Er3+ (introduced in total mol% of 8 and 20). For this purpose, X-ray powder diffraction, scanning and transmission electron microscopy, energy dispersive X-ray and Furrier transform infrared spectroscopy, as well as, the photoluminescence spectra and decay times were recorded and analyzed. The particle size and phase content were found to be dependent on the nucleation rate, which, in turn, was governed by the precursor concentration, degree of doping and solvent type. The transformation from cubic to hexagonal NaYF4:Yb3+/Er3+ phase was found to be sensitive to the reaction time and precursors concentration, while the crystallization of orthorhombic YF3:Yb3+/Er3+ phase is achieved through lowering of dopants concentration or by changing of solvent during hydrothermal treatment. The up-conversion photoluminescence demonstrated morphology and crystal phase dependence and is found to be superior in microcrystalline samples, independent on their phase composition.",
publisher = "Elsevier",
journal = "Advanced Powder Technology, Advanced Powder Technology",
title = "Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis",
pages = "73-82",
volume = "28",
number = "1",
doi = "10.1016/j.apt.2016.09.021",
url = "https://hdl.handle.net/21.15107/rcub_dais_3687"
}

Dinić, I., Mančić, L., Rabanal, M. E., Yamamoto, K., Ohara, S., Tamura, S., Koji, T., Costa, A. M. L. M., Marinković, B. A.,& Milošević, O.. (2017). Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis. in Advanced Powder Technology
Elsevier., 28(1), 73-82.
https://doi.org/10.1016/j.apt.2016.09.021
https://hdl.handle.net/21.15107/rcub_dais_3687

Dinić I, Mančić L, Rabanal ME, Yamamoto K, Ohara S, Tamura S, Koji T, Costa AMLM, Marinković BA, Milošević O. Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis. in Advanced Powder Technology. 2017;28(1):73-82.
doi:10.1016/j.apt.2016.09.021
https://hdl.handle.net/21.15107/rcub_dais_3687 .

Dinić, Ivana, Mančić, Lidija, Rabanal, Maria Eugenia, Yamamoto, Kazuhiro, Ohara, Satoshi, Tamura, Sayaka, Koji, Tomita, Costa, Antonio Mario Leal Martins, Marinković, Bojan A., Milošević, Olivera, "Compositional and structural dependence of up-converting rare earth fluorides obtained through EDTA assisted hydro/solvothermal synthesis" in Advanced Powder Technology, 28, no. 1 (2017):73-82,
https://doi.org/10.1016/j.apt.2016.09.021 .,
https://hdl.handle.net/21.15107/rcub_dais_3687 .

TY  - JOUR
AU  - Dinić, Ivana
AU  - Rabanal, Maria Eugenia
AU  - Yamamoto, Kazuhiro
AU  - Tan, Zhenquan
AU  - Ohara, Satoshi
AU  - Mančić, Lidija
AU  - Milošević, Olivera
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/15965
AB  - Owing to their unique optical properties, up-converting rare earth fluorides have attracted extensive attention in recent years. Varieties of synthesis procedures which generate nano- and micro-crystals with controllable compositions have been reported. In the vast majority, surfactants, complexing agents and solvents play essential role in controlling particles morphology and surface characteristics. Here we report on a rapid solvothermal synthesis (200 °C, 2 h) of either PEG or PVP capped NaYF4:Yb3+/Er3+ particles. Their structural, morphological and luminescence characteristics have been studied based on X-ray powder diffractometry (XRPD), Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), high resolution transmission electron microscopy (HRTEM) and photoluminescence measurements. Both polymers proved to be a good structure directing agents enabling generation of the well crystalline polymer coated up-converting particles with efficient emissions in visible spectrum. It was shown that generation of the hexagonal P63/m β-NaYF4:Yb3+/Er3+ phase with the most efficient green emission (CIE 0.31, 0.66) is enhanced when PVP is used during synthesis, while promotion of the cubic Fm-3m α-NaYF4:Yb3+/Er3+ phase that has a yellowish spectral output (CIE 0.41, 0.56) was observed in the particles produced in the presence of PEG. Beneficial effect on the luminescence intensity was observed with additional particles annealing in argon atmosphere.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - PEG and PVP assisted solvothermal synthesis of NaYF4:Yb3+/Er3+ up-conversion nanoparticles
SP  - 845
EP  - 853
VL  - 27
IS  - 3
DO  - 10.1016/j.apt.2015.11.010
UR  - https://hdl.handle.net/21.15107/rcub_dais_15965
ER  - 

@article{
author = "Dinić, Ivana and Rabanal, Maria Eugenia and Yamamoto, Kazuhiro and Tan, Zhenquan and Ohara, Satoshi and Mančić, Lidija and Milošević, Olivera",
year = "2016",
abstract = "Owing to their unique optical properties, up-converting rare earth fluorides have attracted extensive attention in recent years. Varieties of synthesis procedures which generate nano- and micro-crystals with controllable compositions have been reported. In the vast majority, surfactants, complexing agents and solvents play essential role in controlling particles morphology and surface characteristics. Here we report on a rapid solvothermal synthesis (200 °C, 2 h) of either PEG or PVP capped NaYF4:Yb3+/Er3+ particles. Their structural, morphological and luminescence characteristics have been studied based on X-ray powder diffractometry (XRPD), Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), high resolution transmission electron microscopy (HRTEM) and photoluminescence measurements. Both polymers proved to be a good structure directing agents enabling generation of the well crystalline polymer coated up-converting particles with efficient emissions in visible spectrum. It was shown that generation of the hexagonal P63/m β-NaYF4:Yb3+/Er3+ phase with the most efficient green emission (CIE 0.31, 0.66) is enhanced when PVP is used during synthesis, while promotion of the cubic Fm-3m α-NaYF4:Yb3+/Er3+ phase that has a yellowish spectral output (CIE 0.41, 0.56) was observed in the particles produced in the presence of PEG. Beneficial effect on the luminescence intensity was observed with additional particles annealing in argon atmosphere.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "PEG and PVP assisted solvothermal synthesis of NaYF4:Yb3+/Er3+ up-conversion nanoparticles",
pages = "845-853",
volume = "27",
number = "3",
doi = "10.1016/j.apt.2015.11.010",
url = "https://hdl.handle.net/21.15107/rcub_dais_15965"
}

Dinić, I., Rabanal, M. E., Yamamoto, K., Tan, Z., Ohara, S., Mančić, L.,& Milošević, O.. (2016). PEG and PVP assisted solvothermal synthesis of NaYF4:Yb3+/Er3+ up-conversion nanoparticles. in Advanced Powder Technology
Elsevier., 27(3), 845-853.
https://doi.org/10.1016/j.apt.2015.11.010
https://hdl.handle.net/21.15107/rcub_dais_15965

Dinić I, Rabanal ME, Yamamoto K, Tan Z, Ohara S, Mančić L, Milošević O. PEG and PVP assisted solvothermal synthesis of NaYF4:Yb3+/Er3+ up-conversion nanoparticles. in Advanced Powder Technology. 2016;27(3):845-853.
doi:10.1016/j.apt.2015.11.010
https://hdl.handle.net/21.15107/rcub_dais_15965 .

Dinić, Ivana, Rabanal, Maria Eugenia, Yamamoto, Kazuhiro, Tan, Zhenquan, Ohara, Satoshi, Mančić, Lidija, Milošević, Olivera, "PEG and PVP assisted solvothermal synthesis of NaYF4:Yb3+/Er3+ up-conversion nanoparticles" in Advanced Powder Technology, 27, no. 3 (2016):845-853,
https://doi.org/10.1016/j.apt.2015.11.010 .,
https://hdl.handle.net/21.15107/rcub_dais_15965 .