TY  - JOUR
AU  - Omymen, Waleed M.
AU  - Rogan, Jelena
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica M.
AU  - Grgur, Branimir
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/2339
AB  - The electrochemical oxidation of the urea in near neutral pH is investigated on platinum electrode. It is shown that oxidation reaction is practically inhibited up to the potentials of ∼0.9 V. The same reaction is investigated onto electrochemically obtained titanium dioxide nanotubes modified by hematite using facile, low-cost successive ion layer adsorption and reaction (SILAR) method. It is shown that such system possesses electrocatalytic activity at very low potentials, and activity can be further improved by the illumination of the electrode in the photo-assisted reaction. The possible application of the photoactive anode is considered in the application of urea based water electrolysis and urea based fuel cell.
PB  - Elsevier
T2  - Journal of Saudi Chemical Society
T1  - Photo-assisted electrochemical oxidation of the urea onto TiO2-nanotubes modified by hematite
SP  - 990
EP  - 997
VL  - 21
IS  - 8
DO  - 10.1016/j.jscs.2017.05.010
UR  - https://hdl.handle.net/21.15107/rcub_dais_2339
ER  - 

@article{
author = "Omymen, Waleed M. and Rogan, Jelena and Jugović, Branimir and Gvozdenović, Milica M. and Grgur, Branimir",
year = "2017",
abstract = "The electrochemical oxidation of the urea in near neutral pH is investigated on platinum electrode. It is shown that oxidation reaction is practically inhibited up to the potentials of ∼0.9 V. The same reaction is investigated onto electrochemically obtained titanium dioxide nanotubes modified by hematite using facile, low-cost successive ion layer adsorption and reaction (SILAR) method. It is shown that such system possesses electrocatalytic activity at very low potentials, and activity can be further improved by the illumination of the electrode in the photo-assisted reaction. The possible application of the photoactive anode is considered in the application of urea based water electrolysis and urea based fuel cell.",
publisher = "Elsevier",
journal = "Journal of Saudi Chemical Society",
title = "Photo-assisted electrochemical oxidation of the urea onto TiO2-nanotubes modified by hematite",
pages = "990-997",
volume = "21",
number = "8",
doi = "10.1016/j.jscs.2017.05.010",
url = "https://hdl.handle.net/21.15107/rcub_dais_2339"
}

Omymen, W. M., Rogan, J., Jugović, B., Gvozdenović, M. M.,& Grgur, B.. (2017). Photo-assisted electrochemical oxidation of the urea onto TiO2-nanotubes modified by hematite. in Journal of Saudi Chemical Society
Elsevier., 21(8), 990-997.
https://doi.org/10.1016/j.jscs.2017.05.010
https://hdl.handle.net/21.15107/rcub_dais_2339

Omymen WM, Rogan J, Jugović B, Gvozdenović MM, Grgur B. Photo-assisted electrochemical oxidation of the urea onto TiO2-nanotubes modified by hematite. in Journal of Saudi Chemical Society. 2017;21(8):990-997.
doi:10.1016/j.jscs.2017.05.010
https://hdl.handle.net/21.15107/rcub_dais_2339 .

Omymen, Waleed M., Rogan, Jelena, Jugović, Branimir, Gvozdenović, Milica M., Grgur, Branimir, "Photo-assisted electrochemical oxidation of the urea onto TiO2-nanotubes modified by hematite" in Journal of Saudi Chemical Society, 21, no. 8 (2017):990-997,
https://doi.org/10.1016/j.jscs.2017.05.010 .,
https://hdl.handle.net/21.15107/rcub_dais_2339 .

TY  - JOUR
AU  - Omymen, Waleed M.
AU  - Ebshish, Ali S.
AU  - Jugović, Branimir
AU  - Trišović, Tomislav
AU  - Gvozdenović, Milica M.
AU  - Grgur, Branimir
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/15997
AB  - The fast reaction of forced hydrolysis of iron(III) nitrate in hypochlorite solution at room temperature, leads to the formation of mainly hematite, α-Fe2O3. Successive ion adsorption and reaction (SILAR) is applied to decorate an electrochemically formed TiO2 nanotube electrode. The anodic photoelectrochemical behavior of pure TiO2-NT’s and modified electrodes are investigated in a sulfate containing solution at pH = 9.2. It is shown that such a modification leads to an increase of anodic photoactivity, as well as that at the same current density, the photoelectrochemical cell with a modified electrode operates at a voltage lower by 0.7 V. The band gap and flat band potentials are estimated, and the structure of the band gap and possible charge transfer reactions and mechanism are discussed.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Photoelectochemical behavior of TiO2-NT’s modified with SILAR deposited iron oxide
SP  - 136
EP  - 143
VL  - 203
DO  - 10.1016/j.electacta.2016.04.038
UR  - https://hdl.handle.net/21.15107/rcub_dais_15997
ER  - 

@article{
author = "Omymen, Waleed M. and Ebshish, Ali S. and Jugović, Branimir and Trišović, Tomislav and Gvozdenović, Milica M. and Grgur, Branimir",
year = "2016",
abstract = "The fast reaction of forced hydrolysis of iron(III) nitrate in hypochlorite solution at room temperature, leads to the formation of mainly hematite, α-Fe2O3. Successive ion adsorption and reaction (SILAR) is applied to decorate an electrochemically formed TiO2 nanotube electrode. The anodic photoelectrochemical behavior of pure TiO2-NT’s and modified electrodes are investigated in a sulfate containing solution at pH = 9.2. It is shown that such a modification leads to an increase of anodic photoactivity, as well as that at the same current density, the photoelectrochemical cell with a modified electrode operates at a voltage lower by 0.7 V. The band gap and flat band potentials are estimated, and the structure of the band gap and possible charge transfer reactions and mechanism are discussed.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Photoelectochemical behavior of TiO2-NT’s modified with SILAR deposited iron oxide",
pages = "136-143",
volume = "203",
doi = "10.1016/j.electacta.2016.04.038",
url = "https://hdl.handle.net/21.15107/rcub_dais_15997"
}

Omymen, W. M., Ebshish, A. S., Jugović, B., Trišović, T., Gvozdenović, M. M.,& Grgur, B.. (2016). Photoelectochemical behavior of TiO2-NT’s modified with SILAR deposited iron oxide. in Electrochimica Acta
Elsevier., 203, 136-143.
https://doi.org/10.1016/j.electacta.2016.04.038
https://hdl.handle.net/21.15107/rcub_dais_15997

Omymen WM, Ebshish AS, Jugović B, Trišović T, Gvozdenović MM, Grgur B. Photoelectochemical behavior of TiO2-NT’s modified with SILAR deposited iron oxide. in Electrochimica Acta. 2016;203:136-143.
doi:10.1016/j.electacta.2016.04.038
https://hdl.handle.net/21.15107/rcub_dais_15997 .

Omymen, Waleed M., Ebshish, Ali S., Jugović, Branimir, Trišović, Tomislav, Gvozdenović, Milica M., Grgur, Branimir, "Photoelectochemical behavior of TiO2-NT’s modified with SILAR deposited iron oxide" in Electrochimica Acta, 203 (2016):136-143,
https://doi.org/10.1016/j.electacta.2016.04.038 .,
https://hdl.handle.net/21.15107/rcub_dais_15997 .