TY  - JOUR
AU  - Mančić, Lidija
AU  - Almeida, Lucas A.
AU  - Machado, Tamires M.
AU  - Gil-Londoño, Jessica
AU  - Dinić, Ivana
AU  - Tomić, Miloš
AU  - Marković, Smilja
AU  - Jardim, Paula
AU  - Marinkovic, Bojan A.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14553
AB  - Novel hybrid core-shell structures, in which up-converting (UC) NaYF4:Yb,Tm core converts near-infrared (NIR) to visible (Vis) light via multiphoton up-conversion processes, while anatase TiO2-acetylacetonate (TiO2-Acac) shell ensures absorption of the Vis light through direct injection of excited electrons from the highest-occupied-molecular-orbital (HOMO) of Acac into the TiO2 conduction band (CB), were successfully synthesized by a two-step wet chemical route. Synthesized NaYF4:Yb,Tm@TiO2-Acac powders were characterized by X-ray powder diffraction, thermogravimetric analysis, scanning and transmission electron microscopy, diffuse-reflectance spectroscopy, Fourier transform infrared spectroscopy, and photoluminescence emission measurement. Tetracycline, as a model drug, was used to investigate the photocatalytic efficiencies of the core-shell structures under irradiation of reduced power Vis and NIR spectra. It was shown that the removal of tetracycline is accompanied by the formation of intermediates, which formed immediately after bringing the drug into contact with the novel hybrid core-shell structures. As a result, ~80% of tetracycline is removed from the solution after 6 h.
PB  - Basel : MDPI AG
T2  - International Journal of Molecular Sciences
T1  - Tetracycline Removal through the Synergy of Catalysis and Photocatalysis by Novel NaYF4:Yb,Tm@TiO2-Acetylacetone Hybrid Core-Shell Structures
SP  - 9441
VL  - 24
IS  - 11
DO  - 10.3390/ijms24119441
UR  - https://hdl.handle.net/21.15107/rcub_dais_14553
ER  - 

@article{
author = "Mančić, Lidija and Almeida, Lucas A. and Machado, Tamires M. and Gil-Londoño, Jessica and Dinić, Ivana and Tomić, Miloš and Marković, Smilja and Jardim, Paula and Marinkovic, Bojan A.",
year = "2023",
abstract = "Novel hybrid core-shell structures, in which up-converting (UC) NaYF4:Yb,Tm core converts near-infrared (NIR) to visible (Vis) light via multiphoton up-conversion processes, while anatase TiO2-acetylacetonate (TiO2-Acac) shell ensures absorption of the Vis light through direct injection of excited electrons from the highest-occupied-molecular-orbital (HOMO) of Acac into the TiO2 conduction band (CB), were successfully synthesized by a two-step wet chemical route. Synthesized NaYF4:Yb,Tm@TiO2-Acac powders were characterized by X-ray powder diffraction, thermogravimetric analysis, scanning and transmission electron microscopy, diffuse-reflectance spectroscopy, Fourier transform infrared spectroscopy, and photoluminescence emission measurement. Tetracycline, as a model drug, was used to investigate the photocatalytic efficiencies of the core-shell structures under irradiation of reduced power Vis and NIR spectra. It was shown that the removal of tetracycline is accompanied by the formation of intermediates, which formed immediately after bringing the drug into contact with the novel hybrid core-shell structures. As a result, ~80% of tetracycline is removed from the solution after 6 h.",
publisher = "Basel : MDPI AG",
journal = "International Journal of Molecular Sciences",
title = "Tetracycline Removal through the Synergy of Catalysis and Photocatalysis by Novel NaYF4:Yb,Tm@TiO2-Acetylacetone Hybrid Core-Shell Structures",
pages = "9441",
volume = "24",
number = "11",
doi = "10.3390/ijms24119441",
url = "https://hdl.handle.net/21.15107/rcub_dais_14553"
}

Mančić, L., Almeida, L. A., Machado, T. M., Gil-Londoño, J., Dinić, I., Tomić, M., Marković, S., Jardim, P.,& Marinkovic, B. A.. (2023). Tetracycline Removal through the Synergy of Catalysis and Photocatalysis by Novel NaYF4:Yb,Tm@TiO2-Acetylacetone Hybrid Core-Shell Structures. in International Journal of Molecular Sciences
Basel : MDPI AG., 24(11), 9441.
https://doi.org/10.3390/ijms24119441
https://hdl.handle.net/21.15107/rcub_dais_14553

Mančić L, Almeida LA, Machado TM, Gil-Londoño J, Dinić I, Tomić M, Marković S, Jardim P, Marinkovic BA. Tetracycline Removal through the Synergy of Catalysis and Photocatalysis by Novel NaYF4:Yb,Tm@TiO2-Acetylacetone Hybrid Core-Shell Structures. in International Journal of Molecular Sciences. 2023;24(11):9441.
doi:10.3390/ijms24119441
https://hdl.handle.net/21.15107/rcub_dais_14553 .

Mančić, Lidija, Almeida, Lucas A., Machado, Tamires M., Gil-Londoño, Jessica, Dinić, Ivana, Tomić, Miloš, Marković, Smilja, Jardim, Paula, Marinkovic, Bojan A., "Tetracycline Removal through the Synergy of Catalysis and Photocatalysis by Novel NaYF4:Yb,Tm@TiO2-Acetylacetone Hybrid Core-Shell Structures" in International Journal of Molecular Sciences, 24, no. 11 (2023):9441,
https://doi.org/10.3390/ijms24119441 .,
https://hdl.handle.net/21.15107/rcub_dais_14553 .