Holclajtner Antunović, Ivanka

Link to this page

Authority KeyName Variants
orcid::0000-0003-1055-9716
  • Holclajtner Antunović, Ivanka (5)

Author's Bibliography

The Role of Surface Chemistry, Structure and Interactions in the Electrochemical Charge Storage Properties of Graphene Oxide and 12-tungstophoshoric Acid Nanocomposites

Jovanović, Zoran; Bajuk-Bogdanović, Danica; Vujković, Milica; Mravik, Željko; Jovanović, Sonja; Marković, Smilja; Pejčić, Milica; Holclajtner Antunović, Ivanka

(Belgrade : University of Belgrade, Faculty of Physical Chemistry, 2022)

TY  - CONF
AU  - Jovanović, Zoran
AU  - Bajuk-Bogdanović, Danica
AU  - Vujković, Milica
AU  - Mravik, Željko
AU  - Jovanović, Sonja
AU  - Marković, Smilja
AU  - Pejčić, Milica
AU  - Holclajtner Antunović, Ivanka
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13644
AB  - Gaining a momentum from newly emerging properties of nanomaterials the further enhancement and integration of various functionalities have been made possible. Also, it became apparent that interaction between nano-objects can provide additional synergy capable of yielding new or significantly improved properties. This particularly applies to the surfaces and interfaces of nanomaterials where the intimate contact between components amplifies possible contributions of interfacial interactions. Since this aspect of interaction-property relation in many nanocomposites is still insufficiently explored, it is of interest to identify to what extent the properties emerge as a result of interaction-based synergy or a co-action of individual components. To address these aspects, we have investigated a nanocomposite of graphene oxide (GO) and 12-tungstophosporic acid (WPA) – a combination of materials that are known for the rich “portfolio” of properties. In the talk the novel findings will be presented that contribute to better the understanding of interactions between nano-objects and how they contribute to novel properties. The results are showing how simple temperature treatment and weight ratio of components is influencing the evolution of surface, structural properties and charge storage properties – all closely connected to interactions between components. Finally, the implications on synthetic approaches and fine-tuning of the functionality of GO/WPA nanocomposites will be discussed from the perspective of the obtained results.
PB  - Belgrade : University of Belgrade, Faculty of Physical Chemistry
C3  - Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
T1  - The Role of Surface Chemistry, Structure and Interactions in the Electrochemical Charge Storage Properties of Graphene Oxide and 12-tungstophoshoric Acid Nanocomposites
SP  - 16
EP  - 16
UR  - https://hdl.handle.net/21.15107/rcub_dais_13644
ER  - 
@conference{
author = "Jovanović, Zoran and Bajuk-Bogdanović, Danica and Vujković, Milica and Mravik, Željko and Jovanović, Sonja and Marković, Smilja and Pejčić, Milica and Holclajtner Antunović, Ivanka",
year = "2022",
abstract = "Gaining a momentum from newly emerging properties of nanomaterials the further enhancement and integration of various functionalities have been made possible. Also, it became apparent that interaction between nano-objects can provide additional synergy capable of yielding new or significantly improved properties. This particularly applies to the surfaces and interfaces of nanomaterials where the intimate contact between components amplifies possible contributions of interfacial interactions. Since this aspect of interaction-property relation in many nanocomposites is still insufficiently explored, it is of interest to identify to what extent the properties emerge as a result of interaction-based synergy or a co-action of individual components. To address these aspects, we have investigated a nanocomposite of graphene oxide (GO) and 12-tungstophosporic acid (WPA) – a combination of materials that are known for the rich “portfolio” of properties. In the talk the novel findings will be presented that contribute to better the understanding of interactions between nano-objects and how they contribute to novel properties. The results are showing how simple temperature treatment and weight ratio of components is influencing the evolution of surface, structural properties and charge storage properties – all closely connected to interactions between components. Finally, the implications on synthetic approaches and fine-tuning of the functionality of GO/WPA nanocomposites will be discussed from the perspective of the obtained results.",
publisher = "Belgrade : University of Belgrade, Faculty of Physical Chemistry",
journal = "Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022",
title = "The Role of Surface Chemistry, Structure and Interactions in the Electrochemical Charge Storage Properties of Graphene Oxide and 12-tungstophoshoric Acid Nanocomposites",
pages = "16-16",
url = "https://hdl.handle.net/21.15107/rcub_dais_13644"
}
Jovanović, Z., Bajuk-Bogdanović, D., Vujković, M., Mravik, Ž., Jovanović, S., Marković, S., Pejčić, M.,& Holclajtner Antunović, I.. (2022). The Role of Surface Chemistry, Structure and Interactions in the Electrochemical Charge Storage Properties of Graphene Oxide and 12-tungstophoshoric Acid Nanocomposites. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
Belgrade : University of Belgrade, Faculty of Physical Chemistry., 16-16.
https://hdl.handle.net/21.15107/rcub_dais_13644
Jovanović Z, Bajuk-Bogdanović D, Vujković M, Mravik Ž, Jovanović S, Marković S, Pejčić M, Holclajtner Antunović I. The Role of Surface Chemistry, Structure and Interactions in the Electrochemical Charge Storage Properties of Graphene Oxide and 12-tungstophoshoric Acid Nanocomposites. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022. 2022;:16-16.
https://hdl.handle.net/21.15107/rcub_dais_13644 .
Jovanović, Zoran, Bajuk-Bogdanović, Danica, Vujković, Milica, Mravik, Željko, Jovanović, Sonja, Marković, Smilja, Pejčić, Milica, Holclajtner Antunović, Ivanka, "The Role of Surface Chemistry, Structure and Interactions in the Electrochemical Charge Storage Properties of Graphene Oxide and 12-tungstophoshoric Acid Nanocomposites" in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022 (2022):16-16,
https://hdl.handle.net/21.15107/rcub_dais_13644 .

Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite

Jovanović, Zoran; Mravik, Željko; Bajuk Bogdanović, Danica; Jovanović, Sonja; Marković, Smilja; Vujković, Milica; Kovač, Janez; Vengust, Damjan; Uskoković-Marković, Snežana; Holclajtner Antunović, Ivanka

(2020)

TY  - JOUR
AU  - Jovanović, Zoran
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Jovanović, Sonja
AU  - Marković, Smilja
AU  - Vujković, Milica
AU  - Kovač, Janez
AU  - Vengust, Damjan
AU  - Uskoković-Marković, Snežana
AU  - Holclajtner Antunović, Ivanka
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/6882
AB  - In the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.
T2  - Carbon
T1  - Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite
SP  - 166
EP  - 178
VL  - 156
DO  - 10.1016/j.carbon.2019.09.072
UR  - https://hdl.handle.net/21.15107/rcub_dais_6882
ER  - 
@article{
author = "Jovanović, Zoran and Mravik, Željko and Bajuk Bogdanović, Danica and Jovanović, Sonja and Marković, Smilja and Vujković, Milica and Kovač, Janez and Vengust, Damjan and Uskoković-Marković, Snežana and Holclajtner Antunović, Ivanka",
year = "2020",
abstract = "In the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.",
journal = "Carbon",
title = "Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite",
pages = "166-178",
volume = "156",
doi = "10.1016/j.carbon.2019.09.072",
url = "https://hdl.handle.net/21.15107/rcub_dais_6882"
}
Jovanović, Z., Mravik, Ž., Bajuk Bogdanović, D., Jovanović, S., Marković, S., Vujković, M., Kovač, J., Vengust, D., Uskoković-Marković, S.,& Holclajtner Antunović, I.. (2020). Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite. in Carbon, 156, 166-178.
https://doi.org/10.1016/j.carbon.2019.09.072
https://hdl.handle.net/21.15107/rcub_dais_6882
Jovanović Z, Mravik Ž, Bajuk Bogdanović D, Jovanović S, Marković S, Vujković M, Kovač J, Vengust D, Uskoković-Marković S, Holclajtner Antunović I. Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite. in Carbon. 2020;156:166-178.
doi:10.1016/j.carbon.2019.09.072
https://hdl.handle.net/21.15107/rcub_dais_6882 .
Jovanović, Zoran, Mravik, Željko, Bajuk Bogdanović, Danica, Jovanović, Sonja, Marković, Smilja, Vujković, Milica, Kovač, Janez, Vengust, Damjan, Uskoković-Marković, Snežana, Holclajtner Antunović, Ivanka, "Self-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite" in Carbon, 156 (2020):166-178,
https://doi.org/10.1016/j.carbon.2019.09.072 .,
https://hdl.handle.net/21.15107/rcub_dais_6882 .
8
4
7

Synergic activity of graphene oxide and 12-tungstophosphoric acid in their nanocomposite for supercapacitor applications

Mravik, Željko; Bajuk-Bogdanović, Danica; Vujković, Milica; Marković, Smilja; Kovač, Janez; Jovanović, Sonja; Holclajtner Antunović, Ivanka; Jovanović, Zoran

(Belgrade : Faculty of physical chemistry, 2018)

TY  - CONF
AU  - Mravik, Željko
AU  - Bajuk-Bogdanović, Danica
AU  - Vujković, Milica
AU  - Marković, Smilja
AU  - Kovač, Janez
AU  - Jovanović, Sonja
AU  - Holclajtner Antunović, Ivanka
AU  - Jovanović, Zoran
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/14865
AB  - Graphene oxide (GO) has shown great potential for applications in charge storage devices. Its two dimensional structure, high specific surface area as well as hydrophilicity and pseudocapacity are making it an exceptional candidate for electrochemical supercapacitors. Recent studies have shown that charge storage properties of GO can be significantly improved in nanocomposites with different inorganic materials. Therefore, in the present work we have combined GO and 12-tungstophosphoric acid (WPA) into a nanocomposite that exerts high synergic activity of the components.
Graphene oxide was synthesized via modified Hummers method and characterized by Temperature programmed desorption method (TPD), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectrometry (XPS) in order to establish its initial surface chemistry, while thermal reduction was used for altering the composition of surface oxygen groups. Cyclic voltammetry (CV) was used to access the contribution of individual surface oxygen groups on the capacitance of graphene oxide. Analysis of initial and thermally reduced GO revealed that desorption of low-temperature groups and their conversion to phenolic and carbonyl groups is the reason for almost doubled capacitance at 500 °C.
Next, we studied the interactions between GO and WPA by altering their mass ratio in the nanocomposite. The FTIR analysis have revealed that WPA interacts with GO via terminal oxygen of a tungstate octahedron. Furthermore, these interactions are the most pronounced at 10-20 wt.% of WPA in the nanocomposite.
PB  - Belgrade : Faculty of physical chemistry
C3  - Book of Abstracts / 3rd International Meeting on materials science for energy related applications, september 25-26, 2018, Belgrade
T1  - Synergic activity of graphene oxide and 12-tungstophosphoric acid in their nanocomposite for supercapacitor applications
SP  - 23
EP  - 23
UR  - https://hdl.handle.net/21.15107/rcub_dais_14865
ER  - 
@conference{
author = "Mravik, Željko and Bajuk-Bogdanović, Danica and Vujković, Milica and Marković, Smilja and Kovač, Janez and Jovanović, Sonja and Holclajtner Antunović, Ivanka and Jovanović, Zoran",
year = "2018",
abstract = "Graphene oxide (GO) has shown great potential for applications in charge storage devices. Its two dimensional structure, high specific surface area as well as hydrophilicity and pseudocapacity are making it an exceptional candidate for electrochemical supercapacitors. Recent studies have shown that charge storage properties of GO can be significantly improved in nanocomposites with different inorganic materials. Therefore, in the present work we have combined GO and 12-tungstophosphoric acid (WPA) into a nanocomposite that exerts high synergic activity of the components.
Graphene oxide was synthesized via modified Hummers method and characterized by Temperature programmed desorption method (TPD), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectrometry (XPS) in order to establish its initial surface chemistry, while thermal reduction was used for altering the composition of surface oxygen groups. Cyclic voltammetry (CV) was used to access the contribution of individual surface oxygen groups on the capacitance of graphene oxide. Analysis of initial and thermally reduced GO revealed that desorption of low-temperature groups and their conversion to phenolic and carbonyl groups is the reason for almost doubled capacitance at 500 °C.
Next, we studied the interactions between GO and WPA by altering their mass ratio in the nanocomposite. The FTIR analysis have revealed that WPA interacts with GO via terminal oxygen of a tungstate octahedron. Furthermore, these interactions are the most pronounced at 10-20 wt.% of WPA in the nanocomposite.",
publisher = "Belgrade : Faculty of physical chemistry",
journal = "Book of Abstracts / 3rd International Meeting on materials science for energy related applications, september 25-26, 2018, Belgrade",
title = "Synergic activity of graphene oxide and 12-tungstophosphoric acid in their nanocomposite for supercapacitor applications",
pages = "23-23",
url = "https://hdl.handle.net/21.15107/rcub_dais_14865"
}
Mravik, Ž., Bajuk-Bogdanović, D., Vujković, M., Marković, S., Kovač, J., Jovanović, S., Holclajtner Antunović, I.,& Jovanović, Z.. (2018). Synergic activity of graphene oxide and 12-tungstophosphoric acid in their nanocomposite for supercapacitor applications. in Book of Abstracts / 3rd International Meeting on materials science for energy related applications, september 25-26, 2018, Belgrade
Belgrade : Faculty of physical chemistry., 23-23.
https://hdl.handle.net/21.15107/rcub_dais_14865
Mravik Ž, Bajuk-Bogdanović D, Vujković M, Marković S, Kovač J, Jovanović S, Holclajtner Antunović I, Jovanović Z. Synergic activity of graphene oxide and 12-tungstophosphoric acid in their nanocomposite for supercapacitor applications. in Book of Abstracts / 3rd International Meeting on materials science for energy related applications, september 25-26, 2018, Belgrade. 2018;:23-23.
https://hdl.handle.net/21.15107/rcub_dais_14865 .
Mravik, Željko, Bajuk-Bogdanović, Danica, Vujković, Milica, Marković, Smilja, Kovač, Janez, Jovanović, Sonja, Holclajtner Antunović, Ivanka, Jovanović, Zoran, "Synergic activity of graphene oxide and 12-tungstophosphoric acid in their nanocomposite for supercapacitor applications" in Book of Abstracts / 3rd International Meeting on materials science for energy related applications, september 25-26, 2018, Belgrade (2018):23-23,
https://hdl.handle.net/21.15107/rcub_dais_14865 .

Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite

Mravik, Željko; Bajuk Bogdanović, Danica; Marković, Smilja; Kovač, Janez; Holclajtner Antunović, Ivanka; Jovanović, Zoran

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Marković, Smilja
AU  - Kovač, Janez
AU  - Holclajtner Antunović, Ivanka
AU  - Jovanović, Zoran
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/3666
AB  - The rich surface chemistry and large surface area of graphene oxide (GO) provide a platform for various functional materials that synergistically enhance charge storage properties of the composite. In present work we have investigated interaction between GO and 12- thungstophosphoric acid (WPA) in their nanocomposites as a function of different mass ratio of constituents. For this purpose, the Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometry (XPS), temperature programmed desorption method (TPD) and thermogravimetric/differential thermal analysis (TGA-DTA) methods were used. FTIR spectra have shown shifts and splitting of characteristic bands of WPA as a result of interactions with GO. Both XPS and TPD methods have shown an initial decrease of the total amount of surface oxygen groups of GO, with a minimum at around 10 wt.% of WPA, above which a restoration of the amount of surface oxygen groups was noticed. TGA-DTA analysis revealed an improved thermal stability of the material up to 25 wt.% of WPA; at higher loading of WPA the thermal properties of nanocomposite became alike to the ones of individual components. The obtained results suggest optimal conditions for preparation of GO-WPA nanocomposites for electrochemical charge storage applications.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite
SP  - 110
EP  - 110
UR  - https://hdl.handle.net/21.15107/rcub_dais_3666
ER  - 
@conference{
author = "Mravik, Željko and Bajuk Bogdanović, Danica and Marković, Smilja and Kovač, Janez and Holclajtner Antunović, Ivanka and Jovanović, Zoran",
year = "2018",
abstract = "The rich surface chemistry and large surface area of graphene oxide (GO) provide a platform for various functional materials that synergistically enhance charge storage properties of the composite. In present work we have investigated interaction between GO and 12- thungstophosphoric acid (WPA) in their nanocomposites as a function of different mass ratio of constituents. For this purpose, the Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometry (XPS), temperature programmed desorption method (TPD) and thermogravimetric/differential thermal analysis (TGA-DTA) methods were used. FTIR spectra have shown shifts and splitting of characteristic bands of WPA as a result of interactions with GO. Both XPS and TPD methods have shown an initial decrease of the total amount of surface oxygen groups of GO, with a minimum at around 10 wt.% of WPA, above which a restoration of the amount of surface oxygen groups was noticed. TGA-DTA analysis revealed an improved thermal stability of the material up to 25 wt.% of WPA; at higher loading of WPA the thermal properties of nanocomposite became alike to the ones of individual components. The obtained results suggest optimal conditions for preparation of GO-WPA nanocomposites for electrochemical charge storage applications.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite",
pages = "110-110",
url = "https://hdl.handle.net/21.15107/rcub_dais_3666"
}
Mravik, Ž., Bajuk Bogdanović, D., Marković, S., Kovač, J., Holclajtner Antunović, I.,& Jovanović, Z.. (2018). Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
Belgrade : Materials Research Society of Serbia., 110-110.
https://hdl.handle.net/21.15107/rcub_dais_3666
Mravik Ž, Bajuk Bogdanović D, Marković S, Kovač J, Holclajtner Antunović I, Jovanović Z. Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite. in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018. 2018;:110-110.
https://hdl.handle.net/21.15107/rcub_dais_3666 .
Mravik, Željko, Bajuk Bogdanović, Danica, Marković, Smilja, Kovač, Janez, Holclajtner Antunović, Ivanka, Jovanović, Zoran, "Study of the interaction between graphene oxide and 12-tungstophosphoric acid in their nanocomposite" in Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018 (2018):110-110,
https://hdl.handle.net/21.15107/rcub_dais_3666 .

Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite

Mravik, Željko; Bajuk Bogdanović, Danica; Marković, Smilja; Holclajtner Antunović, Ivanka; Jovanović, Zoran

(Belgrade : Institute of Technical Sciences of SASA, 2017)

TY  - CONF
AU  - Mravik, Željko
AU  - Bajuk Bogdanović, Danica
AU  - Marković, Smilja
AU  - Holclajtner Antunović, Ivanka
AU  - Jovanović, Zoran
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/15450
AB  - In recent years the nanocomposites of graphene oxide (GO) and different inorganic and organic compounds have shown great potential for charge storage applications. In present work we have investigated the influence of 12-tungstophosphoric acid (WPA) on surface chemistry of graphene oxide and thermal stability of nanocomposite. For this purpose nanocomposites with different mass ratios of GO and WPA were prepared. The thermal stability of nanocomposites was investigated by thermogravimetric and differential thermal analysis (TGA-DTA) while changes in surface chemistry of GO and structural properties of WPA were investigated by Fourier transform infrared spectroscopy (FTIR) and temperature programmed desorption (TPD) method. The TGA-DTA measurements of composites have shown that the major mass loss, due to carbon combustion, is shifted to higher temperatures (~500 °C vs. 380 °C of pure GO). Furthermore, when the amount of WPA is higher than 25 mass percent the nanocomposites start to act like individual components, which was also confirmed by FTIR analysis. The amount of surface oxygen groups, monitored by both TPD and FTIR methods, showed ˝V˝ shaped dependence from the quantity of WPA with minimum at about 12 mass percent of WPA. At the same time, the FTIR spectra revealed the structural changes of WPA, displayed as shifting and splitting of characteristic bands of Keggin anion structure.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
T1  - Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite
SP  - 48
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_dais_15450
ER  - 
@conference{
author = "Mravik, Željko and Bajuk Bogdanović, Danica and Marković, Smilja and Holclajtner Antunović, Ivanka and Jovanović, Zoran",
year = "2017",
abstract = "In recent years the nanocomposites of graphene oxide (GO) and different inorganic and organic compounds have shown great potential for charge storage applications. In present work we have investigated the influence of 12-tungstophosphoric acid (WPA) on surface chemistry of graphene oxide and thermal stability of nanocomposite. For this purpose nanocomposites with different mass ratios of GO and WPA were prepared. The thermal stability of nanocomposites was investigated by thermogravimetric and differential thermal analysis (TGA-DTA) while changes in surface chemistry of GO and structural properties of WPA were investigated by Fourier transform infrared spectroscopy (FTIR) and temperature programmed desorption (TPD) method. The TGA-DTA measurements of composites have shown that the major mass loss, due to carbon combustion, is shifted to higher temperatures (~500 °C vs. 380 °C of pure GO). Furthermore, when the amount of WPA is higher than 25 mass percent the nanocomposites start to act like individual components, which was also confirmed by FTIR analysis. The amount of surface oxygen groups, monitored by both TPD and FTIR methods, showed ˝V˝ shaped dependence from the quantity of WPA with minimum at about 12 mass percent of WPA. At the same time, the FTIR spectra revealed the structural changes of WPA, displayed as shifting and splitting of characteristic bands of Keggin anion structure.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia",
title = "Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite",
pages = "48-48",
url = "https://hdl.handle.net/21.15107/rcub_dais_15450"
}
Mravik, Ž., Bajuk Bogdanović, D., Marković, S., Holclajtner Antunović, I.,& Jovanović, Z.. (2017). Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 48-48.
https://hdl.handle.net/21.15107/rcub_dais_15450
Mravik Ž, Bajuk Bogdanović D, Marković S, Holclajtner Antunović I, Jovanović Z. Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia. 2017;:48-48.
https://hdl.handle.net/21.15107/rcub_dais_15450 .
Mravik, Željko, Bajuk Bogdanović, Danica, Marković, Smilja, Holclajtner Antunović, Ivanka, Jovanović, Zoran, "Surface chemistry, thermal stability and structural properties of graphene oxide/12-tungstophosphoric acid nanocomposite" in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia (2017):48-48,
https://hdl.handle.net/21.15107/rcub_dais_15450 .