TY  - JOUR
AU  - Ivanović, Marija
AU  - Nenadović, Snežana
AU  - Pavlović, Vera P.
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
AU  - Pavlović, Vladimir B.
AU  - Kljajević, Ljiljana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11800
AB  - Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 °C for the process of geopolymerization. Mixtures of Na2SiO3and NaOH of different molar concentrations (from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentrationalso shows the highest values of all thermodynamic parameters.Metakaolin, obtained by calcination of kaolin at 750 °C, was used as the starting material.The samples were characterized by X-ray diffraction (XRD),FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentra-tions of activators do not notably change the Si/Al ratio.
PB  - Society of Chemists and Technologists of Macedonia
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers
SP  - 99
VL  - 40
IS  - 1
DO  - 10.20450/mjcce.2021.2127
UR  - https://hdl.handle.net/21.15107/rcub_dais_11800
ER  - 

@article{
author = "Ivanović, Marija and Nenadović, Snežana and Pavlović, Vera P. and Radović, Ivona and Kijevčanin, Mirjana and Pavlović, Vladimir B. and Kljajević, Ljiljana",
year = "2021",
abstract = "Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 °C for the process of geopolymerization. Mixtures of Na2SiO3and NaOH of different molar concentrations (from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentrationalso shows the highest values of all thermodynamic parameters.Metakaolin, obtained by calcination of kaolin at 750 °C, was used as the starting material.The samples were characterized by X-ray diffraction (XRD),FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentra-tions of activators do not notably change the Si/Al ratio.",
publisher = "Society of Chemists and Technologists of Macedonia",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers",
pages = "99",
volume = "40",
number = "1",
doi = "10.20450/mjcce.2021.2127",
url = "https://hdl.handle.net/21.15107/rcub_dais_11800"
}

Ivanović, M., Nenadović, S., Pavlović, V. P., Radović, I., Kijevčanin, M., Pavlović, V. B.,& Kljajević, L.. (2021). The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering
Society of Chemists and Technologists of Macedonia., 40(1), 99.
https://doi.org/10.20450/mjcce.2021.2127
https://hdl.handle.net/21.15107/rcub_dais_11800

Ivanović M, Nenadović S, Pavlović VP, Radović I, Kijevčanin M, Pavlović VB, Kljajević L. The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering. 2021;40(1):99.
doi:10.20450/mjcce.2021.2127
https://hdl.handle.net/21.15107/rcub_dais_11800 .

Ivanović, Marija, Nenadović, Snežana, Pavlović, Vera P., Radović, Ivona, Kijevčanin, Mirjana, Pavlović, Vladimir B., Kljajević, Ljiljana, "The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers" in Macedonian Journal of Chemistry and Chemical Engineering, 40, no. 1 (2021):99,
https://doi.org/10.20450/mjcce.2021.2127 .,
https://hdl.handle.net/21.15107/rcub_dais_11800 .

TY  - JOUR
AU  - Lopičić, Zorica
AU  - Stojanović, Mirjana
AU  - Marković, Smilja
AU  - Milojković, Jelena V.
AU  - Mihajlović, Marija L.
AU  - Kaluđerović Radoičić, Tatjana S.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/2312
AB  - In this paper, the character of structural changes induced by different mechanical treatments to Prunus persica stones (PSs), and its subsequent effect on biosorption kinetics of Cu(II) were investigated. PSs were processed in vibratory disk mill (PS-V) and ultra-centrifugal mill (PS-C) and characterized by XRD, BET, SEM and FTIR spectroscopy. It was shown that PS-V was smaller and more reactive with less crystallinity index and hydrogen bond intensity compared to PS-C. In opposite, surface area of the PS-C was bigger than that of the PS-V. The total pore volume was about threefold, while the volume of micro pores was 9.29 times higher in PS-Cs than in PS-Vs.

The kinetics of Cu(II) biosorption by both PSs was tested through various kinetic models: pseudo-first and pseudo-second order rate equations, Elovich equation, Boyd model, Weber–Morris and Urano–Tachikawa intraparticle diffusion model. For both sample types, Cu(II) biosorption occurred through combination of intraparticle and film diffusion mechanism, while kinetic results were best described by the pseudo-second order kinetic model. At the same time, the results indicated that together with kinetic rate the biosorption capacity of PS-C (21.20 mg g−1) was higher than that of PS-V (16.30 mg g−1).

Mechanical activation like crushing and grinding will change material particle size, specific surface area and porosity, as well as its crystallinity. However, this paper elucidates that such physical structural changes will impact on heavy metal ions removal efficiency. This investigation suggests that the type of size reduction in lignocellulosic biosorbent preparation plays a very important role in overall biosorption performance, so it should be carefully considered every time when the mechanical treatment of material is necessary to be applied.
PB  - Elsevier
T2  - Arabian Journal of Chemistry
T1  - Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics
SP  - 4091
EP  - 4103
VL  - 12
IS  - 8
DO  - 10.1016/j.arabjc.2016.04.005
UR  - https://hdl.handle.net/21.15107/rcub_dais_2312
ER  - 

@article{
author = "Lopičić, Zorica and Stojanović, Mirjana and Marković, Smilja and Milojković, Jelena V. and Mihajlović, Marija L. and Kaluđerović Radoičić, Tatjana S. and Kijevčanin, Mirjana Lj.",
year = "2019",
abstract = "In this paper, the character of structural changes induced by different mechanical treatments to Prunus persica stones (PSs), and its subsequent effect on biosorption kinetics of Cu(II) were investigated. PSs were processed in vibratory disk mill (PS-V) and ultra-centrifugal mill (PS-C) and characterized by XRD, BET, SEM and FTIR spectroscopy. It was shown that PS-V was smaller and more reactive with less crystallinity index and hydrogen bond intensity compared to PS-C. In opposite, surface area of the PS-C was bigger than that of the PS-V. The total pore volume was about threefold, while the volume of micro pores was 9.29 times higher in PS-Cs than in PS-Vs.

The kinetics of Cu(II) biosorption by both PSs was tested through various kinetic models: pseudo-first and pseudo-second order rate equations, Elovich equation, Boyd model, Weber–Morris and Urano–Tachikawa intraparticle diffusion model. For both sample types, Cu(II) biosorption occurred through combination of intraparticle and film diffusion mechanism, while kinetic results were best described by the pseudo-second order kinetic model. At the same time, the results indicated that together with kinetic rate the biosorption capacity of PS-C (21.20 mg g−1) was higher than that of PS-V (16.30 mg g−1).

Mechanical activation like crushing and grinding will change material particle size, specific surface area and porosity, as well as its crystallinity. However, this paper elucidates that such physical structural changes will impact on heavy metal ions removal efficiency. This investigation suggests that the type of size reduction in lignocellulosic biosorbent preparation plays a very important role in overall biosorption performance, so it should be carefully considered every time when the mechanical treatment of material is necessary to be applied.",
publisher = "Elsevier",
journal = "Arabian Journal of Chemistry",
title = "Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics",
pages = "4091-4103",
volume = "12",
number = "8",
doi = "10.1016/j.arabjc.2016.04.005",
url = "https://hdl.handle.net/21.15107/rcub_dais_2312"
}

Lopičić, Z., Stojanović, M., Marković, S., Milojković, J. V., Mihajlović, M. L., Kaluđerović Radoičić, T. S.,& Kijevčanin, M. Lj.. (2019). Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics. in Arabian Journal of Chemistry
Elsevier., 12(8), 4091-4103.
https://doi.org/10.1016/j.arabjc.2016.04.005
https://hdl.handle.net/21.15107/rcub_dais_2312

Lopičić Z, Stojanović M, Marković S, Milojković JV, Mihajlović ML, Kaluđerović Radoičić TS, Kijevčanin ML. Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics. in Arabian Journal of Chemistry. 2019;12(8):4091-4103.
doi:10.1016/j.arabjc.2016.04.005
https://hdl.handle.net/21.15107/rcub_dais_2312 .

Lopičić, Zorica, Stojanović, Mirjana, Marković, Smilja, Milojković, Jelena V., Mihajlović, Marija L., Kaluđerović Radoičić, Tatjana S., Kijevčanin, Mirjana Lj., "Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics" in Arabian Journal of Chemistry, 12, no. 8 (2019):4091-4103,
https://doi.org/10.1016/j.arabjc.2016.04.005 .,
https://hdl.handle.net/21.15107/rcub_dais_2312 .