Gezović, A., Milović, M., Bajuk-Bogdanović, D., Grudić, V., Dominko, R., Mentus, S.,& Vujković, M. J.. (2024). An effective approach to reaching the theoretical capacity of a low-cost and environmentally friendly Na4Fe3(PO4)2(P2O7) cathode for Na-ion batteries. in Electrochimica Acta
Elsevier BV., 476, 143718.
https://doi.org/10.1016/j.electacta.2023.143718
https://hdl.handle.net/21.15107/rcub_dais_16379

Gezović A, Milović M, Bajuk-Bogdanović D, Grudić V, Dominko R, Mentus S, Vujković MJ. An effective approach to reaching the theoretical capacity of a low-cost and environmentally friendly Na4Fe3(PO4)2(P2O7) cathode for Na-ion batteries. in Electrochimica Acta. 2024;476:143718.
doi:10.1016/j.electacta.2023.143718
https://hdl.handle.net/21.15107/rcub_dais_16379 .

Gezović, Aleksandra, Milović, Miloš, Bajuk-Bogdanović, Danica, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, Vujković, Milica J., "An effective approach to reaching the theoretical capacity of a low-cost and environmentally friendly Na4Fe3(PO4)2(P2O7) cathode for Na-ion batteries" in Electrochimica Acta, 476 (2024):143718,
https://doi.org/10.1016/j.electacta.2023.143718 .,
https://hdl.handle.net/21.15107/rcub_dais_16379 .

TY  - CONF
AU  - Petrović, Tamara
AU  - Milović, Miloš
AU  - Gezović, Aleksandra
AU  - Mišurović, Jana
AU  - Grudić, Veselinka
AU  - Vujković, Milica
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13502
AB  - Moving toward the commercialization of safe and sustainable energy storage systems, the research on aqueous rechargeable batteries (ARBs) becomes more intensive. Moreover, development of alternative ARBs based on more abundant and sustainable element chemistry (Na, Mg, Ca, and Zn) has received significant attention. Great efforts for their development started to pay off when an aqueous sodium battery (NaTi2(PO4)3//1 M Na2SO4//Na0.44MnO2) appeared on the market alongside organic rechargeable batteries. In this study, a hybrid full- cell aqueous configuration was made from biomass-derived activated carbon (anode), 5 M aqueous solution of Ca(NO3)2 (electrolyte), and layered CaV2O6 (cathode). A high surface area carbon was synthesized by the simultaneous carbonization and activation of vine shoot- derived biochar at 700 °C under Ar atmosphere (ACvs). CaV2O6 composite with the carbon (CaVO/C) was obtained by the sol-gel complexation method. The charge storage behaviour of ACvs and CaVO/C materials was investigated in the aqueous solution of 5 M Ca(NO3)2 and showed promising results. Not only do materials individually exhibit good electrochemical behaviour, full-cell configuration ACvs700//5 M Ca(NO3)2//CaVO/C displayed improved charge storage (89 mAh g-1 at 100 mA g-1) in comparison to mentioned commercial aqueous NaTi2(PO4)3//1 M Na2SO4//Na0.44MnO2 model (≈50 mAh g-1 at ≈100 mA g-1). These results enrich the existing hybrid aqueous battery design and open up a new research era for Ca-ion batteries.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Programme and the Book of Abstracts / Twentieth Young Researchers' Conference Materials Science and Engineering, November 30 - December 2, 2022, Belgrade, Serbia
T1  - Hybrid aqueous Ca-ion battery: Design and Performance
SP  - 67
EP  - 67
UR  - https://hdl.handle.net/21.15107/rcub_dais_13502
ER  - 

@conference{
author = "Petrović, Tamara and Milović, Miloš and Gezović, Aleksandra and Mišurović, Jana and Grudić, Veselinka and Vujković, Milica",
year = "2022",
abstract = "Moving toward the commercialization of safe and sustainable energy storage systems, the research on aqueous rechargeable batteries (ARBs) becomes more intensive. Moreover, development of alternative ARBs based on more abundant and sustainable element chemistry (Na, Mg, Ca, and Zn) has received significant attention. Great efforts for their development started to pay off when an aqueous sodium battery (NaTi2(PO4)3//1 M Na2SO4//Na0.44MnO2) appeared on the market alongside organic rechargeable batteries. In this study, a hybrid full- cell aqueous configuration was made from biomass-derived activated carbon (anode), 5 M aqueous solution of Ca(NO3)2 (electrolyte), and layered CaV2O6 (cathode). A high surface area carbon was synthesized by the simultaneous carbonization and activation of vine shoot- derived biochar at 700 °C under Ar atmosphere (ACvs). CaV2O6 composite with the carbon (CaVO/C) was obtained by the sol-gel complexation method. The charge storage behaviour of ACvs and CaVO/C materials was investigated in the aqueous solution of 5 M Ca(NO3)2 and showed promising results. Not only do materials individually exhibit good electrochemical behaviour, full-cell configuration ACvs700//5 M Ca(NO3)2//CaVO/C displayed improved charge storage (89 mAh g-1 at 100 mA g-1) in comparison to mentioned commercial aqueous NaTi2(PO4)3//1 M Na2SO4//Na0.44MnO2 model (≈50 mAh g-1 at ≈100 mA g-1). These results enrich the existing hybrid aqueous battery design and open up a new research era for Ca-ion batteries.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Programme and the Book of Abstracts / Twentieth Young Researchers' Conference Materials Science and Engineering, November 30 - December 2, 2022, Belgrade, Serbia",
title = "Hybrid aqueous Ca-ion battery: Design and Performance",
pages = "67-67",
url = "https://hdl.handle.net/21.15107/rcub_dais_13502"
}

Petrović, T., Milović, M., Gezović, A., Mišurović, J., Grudić, V.,& Vujković, M.. (2022). Hybrid aqueous Ca-ion battery: Design and Performance. in Programme and the Book of Abstracts / Twentieth Young Researchers' Conference Materials Science and Engineering, November 30 - December 2, 2022, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 67-67.
https://hdl.handle.net/21.15107/rcub_dais_13502

Petrović T, Milović M, Gezović A, Mišurović J, Grudić V, Vujković M. Hybrid aqueous Ca-ion battery: Design and Performance. in Programme and the Book of Abstracts / Twentieth Young Researchers' Conference Materials Science and Engineering, November 30 - December 2, 2022, Belgrade, Serbia. 2022;:67-67.
https://hdl.handle.net/21.15107/rcub_dais_13502 .

Petrović, Tamara, Milović, Miloš, Gezović, Aleksandra, Mišurović, Jana, Grudić, Veselinka, Vujković, Milica, "Hybrid aqueous Ca-ion battery: Design and Performance" in Programme and the Book of Abstracts / Twentieth Young Researchers' Conference Materials Science and Engineering, November 30 - December 2, 2022, Belgrade, Serbia (2022):67-67,
https://hdl.handle.net/21.15107/rcub_dais_13502 .

TY  - CONF
AU  - Gezović, Aleksandra
AU  - Milović, Miloš
AU  - Bajuk-Bogdanović, Danica
AU  - Grudić, Veselinka
AU  - Mentus, Slavko
AU  - Vujković, Milica
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13594
AB  - The combination of different structural units in the anionic sublattice (PO4–SO4, PO4–NO3, PO4–CO3, etc.) can provide novel mixed polyanionic structures, which matched properties of Li-ion intercalation materials [1]. Mixed polyanion, Na4Fe3(PO4)2P2O7 (NFPP) is of special interest as a cathode for Na-ion batteries [2]. In this study, the simple citric-assisted sol-gel method was used for NFPP/C preparation, with the aim of evaluating its sodium storage capability. When both phosphates and pyrophosphates are used as precursors, the mixed NFPP phase has been successfully obtained, but only if pH is adjusted to the neutral value. Otherwise, when it comes to spontaneous sol-gel reaction (without pH adjustment), the heterostructure Na4Fe3(PO4)2P2O7/Na2FeP2O7 was formed. The obtained polyanions have been examined in terms of the structural, thermal and morphological behaviour by XRD, FTIR, TG/DTA and FESEM. Their electrochemical examination in NaNO3, by cyclic voltammetry and chronopotentiometry, reveals the substantial difference in sodium storage properties of synthesized nanocomposites. While the heterestrocture delivers the specific capacity of around 90 mAh g-1 with a poor rate capability, the mixed phase can rich theoretical capacity of ≈129 mAh g-1 (at a common scan rate), with a high rate capability of ≈80 C.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
T1  - pH-triggered sol-gel synthesis of Na4Fe3(PO4)2P2O7 cathode material
SP  - 80
EP  - 80
UR  - https://hdl.handle.net/21.15107/rcub_dais_13594
ER  - 

@conference{
author = "Gezović, Aleksandra and Milović, Miloš and Bajuk-Bogdanović, Danica and Grudić, Veselinka and Mentus, Slavko and Vujković, Milica",
year = "2022",
abstract = "The combination of different structural units in the anionic sublattice (PO4–SO4, PO4–NO3, PO4–CO3, etc.) can provide novel mixed polyanionic structures, which matched properties of Li-ion intercalation materials [1]. Mixed polyanion, Na4Fe3(PO4)2P2O7 (NFPP) is of special interest as a cathode for Na-ion batteries [2]. In this study, the simple citric-assisted sol-gel method was used for NFPP/C preparation, with the aim of evaluating its sodium storage capability. When both phosphates and pyrophosphates are used as precursors, the mixed NFPP phase has been successfully obtained, but only if pH is adjusted to the neutral value. Otherwise, when it comes to spontaneous sol-gel reaction (without pH adjustment), the heterostructure Na4Fe3(PO4)2P2O7/Na2FeP2O7 was formed. The obtained polyanions have been examined in terms of the structural, thermal and morphological behaviour by XRD, FTIR, TG/DTA and FESEM. Their electrochemical examination in NaNO3, by cyclic voltammetry and chronopotentiometry, reveals the substantial difference in sodium storage properties of synthesized nanocomposites. While the heterestrocture delivers the specific capacity of around 90 mAh g-1 with a poor rate capability, the mixed phase can rich theoretical capacity of ≈129 mAh g-1 (at a common scan rate), with a high rate capability of ≈80 C.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022",
title = "pH-triggered sol-gel synthesis of Na4Fe3(PO4)2P2O7 cathode material",
pages = "80-80",
url = "https://hdl.handle.net/21.15107/rcub_dais_13594"
}

Gezović, A., Milović, M., Bajuk-Bogdanović, D., Grudić, V., Mentus, S.,& Vujković, M.. (2022). pH-triggered sol-gel synthesis of Na4Fe3(PO4)2P2O7 cathode material. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
Belgrade : Materials Research Society of Serbia., 80-80.
https://hdl.handle.net/21.15107/rcub_dais_13594

Gezović A, Milović M, Bajuk-Bogdanović D, Grudić V, Mentus S, Vujković M. pH-triggered sol-gel synthesis of Na4Fe3(PO4)2P2O7 cathode material. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022. 2022;:80-80.
https://hdl.handle.net/21.15107/rcub_dais_13594 .

Gezović, Aleksandra, Milović, Miloš, Bajuk-Bogdanović, Danica, Grudić, Veselinka, Mentus, Slavko, Vujković, Milica, "pH-triggered sol-gel synthesis of Na4Fe3(PO4)2P2O7 cathode material" in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022 (2022):80-80,
https://hdl.handle.net/21.15107/rcub_dais_13594 .

TY  - JOUR
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11632
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
SP  - 243
EP  - 273
VL  - 37
DO  - 10.1016/j.ensm.2021.02.011
UR  - https://hdl.handle.net/21.15107/rcub_dais_11632
ER  - 

@article{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook",
pages = "243-273",
volume = "37",
doi = "10.1016/j.ensm.2021.02.011",
url = "https://hdl.handle.net/21.15107/rcub_dais_11632"
}

Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials
Elsevier BV., 37, 243-273.
https://doi.org/10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11632

Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials. 2021;37:243-273.
doi:10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11632 .

Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" in Energy Storage Materials, 37 (2021):243-273,
https://doi.org/10.1016/j.ensm.2021.02.011 .,
https://hdl.handle.net/21.15107/rcub_dais_11632 .

TY  - JOUR
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11633
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
SP  - 243
EP  - 273
VL  - 37
DO  - 10.1016/j.ensm.2021.02.011
UR  - https://hdl.handle.net/21.15107/rcub_dais_11633
ER  - 

@article{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook",
pages = "243-273",
volume = "37",
doi = "10.1016/j.ensm.2021.02.011",
url = "https://hdl.handle.net/21.15107/rcub_dais_11633"
}

Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials
Elsevier BV., 37, 243-273.
https://doi.org/10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11633

Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials. 2021;37:243-273.
doi:10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11633 .

Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" in Energy Storage Materials, 37 (2021):243-273,
https://doi.org/10.1016/j.ensm.2021.02.011 .,
https://hdl.handle.net/21.15107/rcub_dais_11633 .

TY  - DATA
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11634
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011
VL  - 37
UR  - https://hdl.handle.net/21.15107/rcub_dais_11634
ER  - 

@misc{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011",
volume = "37",
url = "https://hdl.handle.net/21.15107/rcub_dais_11634"
}

Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011. in Energy Storage Materials
Elsevier BV., 37.
https://hdl.handle.net/21.15107/rcub_dais_11634

Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011. in Energy Storage Materials. 2021;37.
https://hdl.handle.net/21.15107/rcub_dais_11634 .

Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011" in Energy Storage Materials, 37 (2021),
https://hdl.handle.net/21.15107/rcub_dais_11634 .