Obradov, Marko

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orcid::0000-0001-8559-9048
  • Obradov, Marko (2)
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Author's Bibliography

Plasmonic Nanomembranes for Detection and Sensing

Jakšić, Zoran; Matović, Jovan; Obradov, Marko; Tanasković, Dragan; Radovanović, Filip; Jakšić, Olga

(Belgrade : s. n., 2015)

TY  - CONF
AU  - Jakšić, Zoran
AU  - Matović, Jovan
AU  - Obradov, Marko
AU  - Tanasković, Dragan
AU  - Radovanović, Filip
AU  - Jakšić, Olga
PY  - 2015
UR  - http://dais.sanu.ac.rs/123456789/803
AB  - Nanomembranes, freestanding quasi-2D structures with thickness of the order of tens of nm and smaller and a giant aspect ratio with lateral dimensions of the order of millimeters, even centimeters, represent an important building blocks in micro and nanosystems [1], corresponding to ubiquitous bilipid membranes in living cells [2]. In this contribution we present our results in theory, design and experimental fabrication of metallic and metal-dielectric nanomembranes with plasmonic properties, intended for the use in the field of sensing. We first consider different approaches to functionalization and nanostructuring of nanomembranes [3]. These include introduction of noble metal or transparent conductive oxides fillers directly into the nanomembrane, lamination (multilayering) and patterning by 2D arrays of subwavelength nanoholes. Within this context we describe our results on nanofabrication of 8 nm thick chromium-based composite nanomembranes. Biomimetic structures utilizing nanochannel-based pores are also considered. We further present our results related to the design of chemical and biological sensors based on nanomembranes with plasmonic metamaterial properties [4]. Such sensors function as refractometric devices utilizing evanescent near fields as optical concentrators and adsorption-desorption mechanism, which ensures their ultra-high sensitivity that reaches single molecule detection [5]. We present some results on chemical sensors utilizing nanomembranes exhibiting extraordinary optical transmission, as well as those based on doublefishnet structures. Finally we consider the enhancement of infrared detectors by nanomembranes [6] utilizing the designer plasmon mechanism [7].

REFERENCES
1. Jiang, C., Markutsya, S., Pikus, Y., and Tsukruk, V. V., Nature Mater., 3, 721-728 (2004).
2. Matović, J., and Jakšić, Z., "Bionic (Nano)Membranes" in Biomimetics – Materials, Structures and Processes. Examples, Ideas and Case Studies, edited by Gruber, P.; Bruckner, D.; Hellmich, C.; Schmiedmayer, H.-B.; Stachelberger, H.; Gebeshuber, I. C., Berlin: Springer, 2011, pp 9-24.
3. Jakšić, Z., and Matovic, J., Materials, 3, 165-200, (2010).
4. Jakšić, Z., Vuković, S. M., Buha, J., and Matovic, J., J. Nanophotonics, 5, 051818 (2011)
5. Jakšić, Z., Micro and Nanophotonics for Semiconductor Infrared Detectors: Towards an Ultimate Uncooled Device, Cham: Springer, 2014.
6. Zijlstra, P., Paulo, P. M. R., and Orrit, M., Nature Nanotech., 7, 379-382 (2012).
7. Pendry, J. B., Martín-Moreno, L., and Garcia-Vidal, F. J., Science, 305 847-848 (2004).
PB  - Belgrade : s. n.
C3  - XIX Symposium on Condensed Matter Physics SFKM 2015, 7–11 September 2015, Belgrade, Serbia: Book of Abstracts
T1  - Plasmonic Nanomembranes for Detection and Sensing
SP  - 68
EP  - 68
UR  - https://hdl.handle.net/21.15107/rcub_dais_803
ER  - 
@conference{
author = "Jakšić, Zoran and Matović, Jovan and Obradov, Marko and Tanasković, Dragan and Radovanović, Filip and Jakšić, Olga",
year = "2015",
abstract = "Nanomembranes, freestanding quasi-2D structures with thickness of the order of tens of nm and smaller and a giant aspect ratio with lateral dimensions of the order of millimeters, even centimeters, represent an important building blocks in micro and nanosystems [1], corresponding to ubiquitous bilipid membranes in living cells [2]. In this contribution we present our results in theory, design and experimental fabrication of metallic and metal-dielectric nanomembranes with plasmonic properties, intended for the use in the field of sensing. We first consider different approaches to functionalization and nanostructuring of nanomembranes [3]. These include introduction of noble metal or transparent conductive oxides fillers directly into the nanomembrane, lamination (multilayering) and patterning by 2D arrays of subwavelength nanoholes. Within this context we describe our results on nanofabrication of 8 nm thick chromium-based composite nanomembranes. Biomimetic structures utilizing nanochannel-based pores are also considered. We further present our results related to the design of chemical and biological sensors based on nanomembranes with plasmonic metamaterial properties [4]. Such sensors function as refractometric devices utilizing evanescent near fields as optical concentrators and adsorption-desorption mechanism, which ensures their ultra-high sensitivity that reaches single molecule detection [5]. We present some results on chemical sensors utilizing nanomembranes exhibiting extraordinary optical transmission, as well as those based on doublefishnet structures. Finally we consider the enhancement of infrared detectors by nanomembranes [6] utilizing the designer plasmon mechanism [7].

REFERENCES
1. Jiang, C., Markutsya, S., Pikus, Y., and Tsukruk, V. V., Nature Mater., 3, 721-728 (2004).
2. Matović, J., and Jakšić, Z., "Bionic (Nano)Membranes" in Biomimetics – Materials, Structures and Processes. Examples, Ideas and Case Studies, edited by Gruber, P.; Bruckner, D.; Hellmich, C.; Schmiedmayer, H.-B.; Stachelberger, H.; Gebeshuber, I. C., Berlin: Springer, 2011, pp 9-24.
3. Jakšić, Z., and Matovic, J., Materials, 3, 165-200, (2010).
4. Jakšić, Z., Vuković, S. M., Buha, J., and Matovic, J., J. Nanophotonics, 5, 051818 (2011)
5. Jakšić, Z., Micro and Nanophotonics for Semiconductor Infrared Detectors: Towards an Ultimate Uncooled Device, Cham: Springer, 2014.
6. Zijlstra, P., Paulo, P. M. R., and Orrit, M., Nature Nanotech., 7, 379-382 (2012).
7. Pendry, J. B., Martín-Moreno, L., and Garcia-Vidal, F. J., Science, 305 847-848 (2004).",
publisher = "Belgrade : s. n.",
journal = "XIX Symposium on Condensed Matter Physics SFKM 2015, 7–11 September 2015, Belgrade, Serbia: Book of Abstracts",
title = "Plasmonic Nanomembranes for Detection and Sensing",
pages = "68-68",
url = "https://hdl.handle.net/21.15107/rcub_dais_803"
}
Jakšić, Z., Matović, J., Obradov, M., Tanasković, D., Radovanović, F.,& Jakšić, O.. (2015). Plasmonic Nanomembranes for Detection and Sensing. in XIX Symposium on Condensed Matter Physics SFKM 2015, 7–11 September 2015, Belgrade, Serbia: Book of Abstracts
Belgrade : s. n.., 68-68.
https://hdl.handle.net/21.15107/rcub_dais_803
Jakšić Z, Matović J, Obradov M, Tanasković D, Radovanović F, Jakšić O. Plasmonic Nanomembranes for Detection and Sensing. in XIX Symposium on Condensed Matter Physics SFKM 2015, 7–11 September 2015, Belgrade, Serbia: Book of Abstracts. 2015;:68-68.
https://hdl.handle.net/21.15107/rcub_dais_803 .
Jakšić, Zoran, Matović, Jovan, Obradov, Marko, Tanasković, Dragan, Radovanović, Filip, Jakšić, Olga, "Plasmonic Nanomembranes for Detection and Sensing" in XIX Symposium on Condensed Matter Physics SFKM 2015, 7–11 September 2015, Belgrade, Serbia: Book of Abstracts (2015):68-68,
https://hdl.handle.net/21.15107/rcub_dais_803 .

Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity

Radovanović, Filip; Tomković, Tanja; Nastasović, Aleksandra; Obradov, Marko; Jakšić, Zoran

(2013)

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Obradov, Marko
AU  - Jakšić, Zoran
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/805
AB  - Affinity-based devices utilizing plasmonic effects belong to the most sensitive chemical sensors. A membrane having a form which coincides with the distribution of surface electromagnetic waves coupled with collective oscillations of electron gas in the conductive part of the sensor represents an important building block for plasmonics. A way to boost selectivity of a plasmonic sensor is to functionalize such membrane and either to apply it on the sensor surface or even to use it as a stand-alone platform for sensing. In this work we considered a possibility to prepare multifunctional membranes for plasmonic sensing. In our experiments selectivity enhancement was achieved through the use of glycidyl methacrylate whose epoxy group is readily converted to a desired affinity group (e.g. amine, thiol, pyridine, dithiocarbamate) to preferently capture a targeted species. Further plasmonic functionalization was obtained by forming a thin hydrogel film through copolymerization of glycidyl methacrylate with mono- and multi-functional methacrylates and then incorporating silver nanoparticles within these nanocomposites. These plasmonic nanoparticles were produced either photochemically or by chemical reduction. Different schemes for plasmonic sensor selectivity enhancement using multifunctionalized glycidyl methacrylate membranes are considered.
C3  - Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013.
T1  - Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity
SP  - MO2.5.1
EP  - MO2.5.5
UR  - https://hdl.handle.net/21.15107/rcub_dais_805
ER  - 
@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Obradov, Marko and Jakšić, Zoran",
year = "2013",
abstract = "Affinity-based devices utilizing plasmonic effects belong to the most sensitive chemical sensors. A membrane having a form which coincides with the distribution of surface electromagnetic waves coupled with collective oscillations of electron gas in the conductive part of the sensor represents an important building block for plasmonics. A way to boost selectivity of a plasmonic sensor is to functionalize such membrane and either to apply it on the sensor surface or even to use it as a stand-alone platform for sensing. In this work we considered a possibility to prepare multifunctional membranes for plasmonic sensing. In our experiments selectivity enhancement was achieved through the use of glycidyl methacrylate whose epoxy group is readily converted to a desired affinity group (e.g. amine, thiol, pyridine, dithiocarbamate) to preferently capture a targeted species. Further plasmonic functionalization was obtained by forming a thin hydrogel film through copolymerization of glycidyl methacrylate with mono- and multi-functional methacrylates and then incorporating silver nanoparticles within these nanocomposites. These plasmonic nanoparticles were produced either photochemically or by chemical reduction. Different schemes for plasmonic sensor selectivity enhancement using multifunctionalized glycidyl methacrylate membranes are considered.",
journal = "Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013.",
title = "Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity",
pages = "MO2.5.1-MO2.5.5",
url = "https://hdl.handle.net/21.15107/rcub_dais_805"
}
Radovanović, F., Tomković, T., Nastasović, A., Obradov, M.,& Jakšić, Z.. (2013). Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity. in Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013., MO2.5.1-MO2.5.5.
https://hdl.handle.net/21.15107/rcub_dais_805
Radovanović F, Tomković T, Nastasović A, Obradov M, Jakšić Z. Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity. in Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013.. 2013;:MO2.5.1-MO2.5.5.
https://hdl.handle.net/21.15107/rcub_dais_805 .
Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Obradov, Marko, Jakšić, Zoran, "Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity" in Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013. (2013):MO2.5.1-MO2.5.5,
https://hdl.handle.net/21.15107/rcub_dais_805 .