Optimization of the preparation of novel polymer/clay nanocomposites
Аутори
Marković, BojanaStefanović, Ivan S.
Popović, Aleksandar R.
Ignjatović, Nenad
Nastasović, Aleksandra
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Recent advances in material technologies have resulted in the preparation of novel polymer/clay composites with improved thermal, mechanical, optoelectronic/ magnetic properties and increased biodegradability [1]. In this study, six samples of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) nanocomposites with organically-modified montmorillonite clay Cloisite 30B® (C30B), were prepared via suspension copolymerization. In order to obtain nanocomposites with fine spherical beads of regular shape and satisfying thermal stability the optimization of the synthesis conditions was performed. Firstly, the influence of the poly(N-vinyl pyrrolidone) (PVP) quantity in the aqueous phase was varied (1, 3 and 5 wt.%) at a constant stirring rate of 250 rpm and constant clay content C30B (10 wt.%). In the second phase of the optimization of the preparation, samples with a constant composition of the composite reaction mixture (5 wt.% PVP and 10 wt.% C30B) at a stirring rate of 25...0, 325 and 400 rpm, were prepared. According to the obtained results, it was concluded that the optimal conditions for preparation of these composites are 5 wt.% of PVP and 400 rpm. The prepared nanocomposites were characterized with Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) in air. The structure of the prepared nanocomposites was confirmed with FTIR spectroscopy. According to the obtained SEM microphotographs the fine spherical beads, with desired size and homogeneous morphology, were prepared. Furthermore, SEM analysis was also showed that clay nanoparticles are homogeneously dispersed both inside surface and cross-section area. The incorporation of C30B clay increased the thermal stability of the prepared polymer/clay nanocomposites in comparison to the pure PGME copolymer.
Кључне речи:
polymer/clay nanocomposites / poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) / Cloisite 30B® (C30B) / copolymerizationИзвор:
Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia, 2019, 114-114Издавач:
- Belgrade : Institute for Multidisciplinary Research
Финансирање / пројекти:
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Синтеза и карактеризација нових функционалних полимера и полимерних нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172062)
- Проучавање физичкохемијских и биохемијских процеса у животној средини који утичу на загађење и истраживање могућности за минимизирање последица (RS-MESTD-Basic Research (BR or ON)-172001)
- Молекуларно дизајнирање наночестица контролисаних морфолошких и физичко-хемијских карактеристика и функционалних материјала на њиховој основи (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - CONF AU - Marković, Bojana AU - Stefanović, Ivan S. AU - Popović, Aleksandar R. AU - Ignjatović, Nenad AU - Nastasović, Aleksandra PY - 2019 UR - https://dais.sanu.ac.rs/123456789/7007 AB - Recent advances in material technologies have resulted in the preparation of novel polymer/clay composites with improved thermal, mechanical, optoelectronic/ magnetic properties and increased biodegradability [1]. In this study, six samples of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) nanocomposites with organically-modified montmorillonite clay Cloisite 30B® (C30B), were prepared via suspension copolymerization. In order to obtain nanocomposites with fine spherical beads of regular shape and satisfying thermal stability the optimization of the synthesis conditions was performed. Firstly, the influence of the poly(N-vinyl pyrrolidone) (PVP) quantity in the aqueous phase was varied (1, 3 and 5 wt.%) at a constant stirring rate of 250 rpm and constant clay content C30B (10 wt.%). In the second phase of the optimization of the preparation, samples with a constant composition of the composite reaction mixture (5 wt.% PVP and 10 wt.% C30B) at a stirring rate of 250, 325 and 400 rpm, were prepared. According to the obtained results, it was concluded that the optimal conditions for preparation of these composites are 5 wt.% of PVP and 400 rpm. The prepared nanocomposites were characterized with Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) in air. The structure of the prepared nanocomposites was confirmed with FTIR spectroscopy. According to the obtained SEM microphotographs the fine spherical beads, with desired size and homogeneous morphology, were prepared. Furthermore, SEM analysis was also showed that clay nanoparticles are homogeneously dispersed both inside surface and cross-section area. The incorporation of C30B clay increased the thermal stability of the prepared polymer/clay nanocomposites in comparison to the pure PGME copolymer. PB - Belgrade : Institute for Multidisciplinary Research C3 - Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia T1 - Optimization of the preparation of novel polymer/clay nanocomposites SP - 114 EP - 114 UR - https://hdl.handle.net/21.15107/rcub_dais_7007 ER -
@conference{ author = "Marković, Bojana and Stefanović, Ivan S. and Popović, Aleksandar R. and Ignjatović, Nenad and Nastasović, Aleksandra", year = "2019", abstract = "Recent advances in material technologies have resulted in the preparation of novel polymer/clay composites with improved thermal, mechanical, optoelectronic/ magnetic properties and increased biodegradability [1]. In this study, six samples of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) nanocomposites with organically-modified montmorillonite clay Cloisite 30B® (C30B), were prepared via suspension copolymerization. In order to obtain nanocomposites with fine spherical beads of regular shape and satisfying thermal stability the optimization of the synthesis conditions was performed. Firstly, the influence of the poly(N-vinyl pyrrolidone) (PVP) quantity in the aqueous phase was varied (1, 3 and 5 wt.%) at a constant stirring rate of 250 rpm and constant clay content C30B (10 wt.%). In the second phase of the optimization of the preparation, samples with a constant composition of the composite reaction mixture (5 wt.% PVP and 10 wt.% C30B) at a stirring rate of 250, 325 and 400 rpm, were prepared. According to the obtained results, it was concluded that the optimal conditions for preparation of these composites are 5 wt.% of PVP and 400 rpm. The prepared nanocomposites were characterized with Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) in air. The structure of the prepared nanocomposites was confirmed with FTIR spectroscopy. According to the obtained SEM microphotographs the fine spherical beads, with desired size and homogeneous morphology, were prepared. Furthermore, SEM analysis was also showed that clay nanoparticles are homogeneously dispersed both inside surface and cross-section area. The incorporation of C30B clay increased the thermal stability of the prepared polymer/clay nanocomposites in comparison to the pure PGME copolymer.", publisher = "Belgrade : Institute for Multidisciplinary Research", journal = "Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia", title = "Optimization of the preparation of novel polymer/clay nanocomposites", pages = "114-114", url = "https://hdl.handle.net/21.15107/rcub_dais_7007" }
Marković, B., Stefanović, I. S., Popović, A. R., Ignjatović, N.,& Nastasović, A.. (2019). Optimization of the preparation of novel polymer/clay nanocomposites. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia Belgrade : Institute for Multidisciplinary Research., 114-114. https://hdl.handle.net/21.15107/rcub_dais_7007
Marković B, Stefanović IS, Popović AR, Ignjatović N, Nastasović A. Optimization of the preparation of novel polymer/clay nanocomposites. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:114-114. https://hdl.handle.net/21.15107/rcub_dais_7007 .
Marković, Bojana, Stefanović, Ivan S., Popović, Aleksandar R., Ignjatović, Nenad, Nastasović, Aleksandra, "Optimization of the preparation of novel polymer/clay nanocomposites" in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):114-114, https://hdl.handle.net/21.15107/rcub_dais_7007 .