Influence of Gd3+ doping on the NaYF4 :YB3+,ER3+ structural and up-conversion properties
2019
Преузимање 🢃
Аутори
Vuković, MarinaMančić, Lidija
Dinić, Ivana
Vulić, Predrag J.
Nikolić, Marko G.
Tan, Zhenquan
Milošević, Olivera
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
application as lasers, displays, photo-thermal agents and biomarkers. Due to efficient two-phonon excitation and the large anti-Stocks shift UCNPs are able to emit visible or UV photons under excitation by near-infrared (NIR). Over the last decade, decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse NaYF4:Yb3+,Er3+ UCNPs with a hexagonal crystal structure. Herein, NaY0.8-xGdxYb0.18Er0.02F4 (x= 0.3 or 0.15) up-conversion nanoparticles crystallized in the hexagonal space group P63/m were successfully synthesized solvothermally utilizing rare earth nitrates, NaF and polyvinylpyrrolidone (PVP) in ethanol-water mixture at 200 °C. Rietveld refinement of the X-ray powder diffraction (XRPD) data and high resolution transmission microscopy (HRTEM) analysis show that all UCNPs are monocrystalline (60-70 nm), have low defect concentration and uniform dopants distribution. Fourier-transform infrared (FTIR) spectroscopy... indicate existence of the PVP ligands at the UCNPs surface, while photoluminescence (PL) spectra shows characteristic green (at 520 and 540 nm, due to 2H11/2, 4S3/2→4I15/2 transitions) and red (at 655 nm, due to 4F9/2 → 4I15/2 transition) emission lines under excitation by NIR (λ =980 nm) light.
Кључне речи:
Gd doping / up-conversion / solvothermal synthesis / NaYF4:Yb3+,Er3+Извор:
Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest, 2019, 19-20Издавач:
- Budapest : [s. n.]
Финансирање / пројекти:
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-MESTD-Basic Research (BR or ON)-172035)
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - CONF AU - Vuković, Marina AU - Mančić, Lidija AU - Dinić, Ivana AU - Vulić, Predrag J. AU - Nikolić, Marko G. AU - Tan, Zhenquan AU - Milošević, Olivera PY - 2019 UR - https://dais.sanu.ac.rs/123456789/7000 AB - application as lasers, displays, photo-thermal agents and biomarkers. Due to efficient two-phonon excitation and the large anti-Stocks shift UCNPs are able to emit visible or UV photons under excitation by near-infrared (NIR). Over the last decade, decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse NaYF4:Yb3+,Er3+ UCNPs with a hexagonal crystal structure. Herein, NaY0.8-xGdxYb0.18Er0.02F4 (x= 0.3 or 0.15) up-conversion nanoparticles crystallized in the hexagonal space group P63/m were successfully synthesized solvothermally utilizing rare earth nitrates, NaF and polyvinylpyrrolidone (PVP) in ethanol-water mixture at 200 °C. Rietveld refinement of the X-ray powder diffraction (XRPD) data and high resolution transmission microscopy (HRTEM) analysis show that all UCNPs are monocrystalline (60-70 nm), have low defect concentration and uniform dopants distribution. Fourier-transform infrared (FTIR) spectroscopy indicate existence of the PVP ligands at the UCNPs surface, while photoluminescence (PL) spectra shows characteristic green (at 520 and 540 nm, due to 2H11/2, 4S3/2→4I15/2 transitions) and red (at 655 nm, due to 4F9/2 → 4I15/2 transition) emission lines under excitation by NIR (λ =980 nm) light. PB - Budapest : [s. n.] C3 - Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest T1 - Influence of Gd3+ doping on the NaYF4 :YB3+,ER3+ structural and up-conversion properties SP - 19 EP - 20 UR - https://hdl.handle.net/21.15107/rcub_dais_7000 ER -
@conference{ author = "Vuković, Marina and Mančić, Lidija and Dinić, Ivana and Vulić, Predrag J. and Nikolić, Marko G. and Tan, Zhenquan and Milošević, Olivera", year = "2019", abstract = "application as lasers, displays, photo-thermal agents and biomarkers. Due to efficient two-phonon excitation and the large anti-Stocks shift UCNPs are able to emit visible or UV photons under excitation by near-infrared (NIR). Over the last decade, decomposition of organometallic compounds has been indicated as one of the most convenient method for the synthesis of monodisperse NaYF4:Yb3+,Er3+ UCNPs with a hexagonal crystal structure. Herein, NaY0.8-xGdxYb0.18Er0.02F4 (x= 0.3 or 0.15) up-conversion nanoparticles crystallized in the hexagonal space group P63/m were successfully synthesized solvothermally utilizing rare earth nitrates, NaF and polyvinylpyrrolidone (PVP) in ethanol-water mixture at 200 °C. Rietveld refinement of the X-ray powder diffraction (XRPD) data and high resolution transmission microscopy (HRTEM) analysis show that all UCNPs are monocrystalline (60-70 nm), have low defect concentration and uniform dopants distribution. Fourier-transform infrared (FTIR) spectroscopy indicate existence of the PVP ligands at the UCNPs surface, while photoluminescence (PL) spectra shows characteristic green (at 520 and 540 nm, due to 2H11/2, 4S3/2→4I15/2 transitions) and red (at 655 nm, due to 4F9/2 → 4I15/2 transition) emission lines under excitation by NIR (λ =980 nm) light.", publisher = "Budapest : [s. n.]", journal = "Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest", title = "Influence of Gd3+ doping on the NaYF4 :YB3+,ER3+ structural and up-conversion properties", pages = "19-20", url = "https://hdl.handle.net/21.15107/rcub_dais_7000" }
Vuković, M., Mančić, L., Dinić, I., Vulić, P. J., Nikolić, M. G., Tan, Z.,& Milošević, O.. (2019). Influence of Gd3+ doping on the NaYF4 :YB3+,ER3+ structural and up-conversion properties. in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest Budapest : [s. n.]., 19-20. https://hdl.handle.net/21.15107/rcub_dais_7000
Vuković M, Mančić L, Dinić I, Vulić PJ, Nikolić MG, Tan Z, Milošević O. Influence of Gd3+ doping on the NaYF4 :YB3+,ER3+ structural and up-conversion properties. in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest. 2019;:19-20. https://hdl.handle.net/21.15107/rcub_dais_7000 .
Vuković, Marina, Mančić, Lidija, Dinić, Ivana, Vulić, Predrag J., Nikolić, Marko G., Tan, Zhenquan, Milošević, Olivera, "Influence of Gd3+ doping on the NaYF4 :YB3+,ER3+ structural and up-conversion properties" in Abstracts / International Workshop on Woman in Ceramic Science (WoCeram2019), April 7-9, 2019/ Budapest, Hungary, Novotel Danube Budapest (2019):19-20, https://hdl.handle.net/21.15107/rcub_dais_7000 .