A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles
Аутори
Stevanović, MagdalenaSavanović, Igor
Uskoković, Vuk
Škapin, Srečo Davor
Bračko, Ines
Jovanović, Uroš
Uskoković, Dragan
Чланак у часопису (Рецензирана верзија)
Метаподаци
Приказ свих података о документуАпстракт
A simple and green chemical method has been developed to synthesize stable bare and capped silver nanoparticles based on the reduction of silver ions by glucose and capping by poly(α,γ,L-glutamic acid) (PGA). The use of ammonia during synthesis was avoided. PGA has had a dual role in the synthesis and was used as a capping agent to make the silver nanoparticle more biocompatible and to protect the nanoparticles from agglomerating in the liquid medium. The synthesized PGA-capped silver nanoparticles in the size range 5–45 nm were stable over long periods of time, without signs of precipitation. Morphological examination has shown that the silver nanoparticles had a nearly spherical, multiply twinned structure. The effects of the reaction temperature and the reaction time during the synthesis were investigated too. The biocompatibility of the PGA-capped silver nano-particles is discussed in terms of in vitro toxicity with human intestinal Caco-2 cells. The samples were characterized by U...V–Visible spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and zeta potential measurements.
Кључне речи:
silver nanoparticles / green method / poly(α,γ,l-glutamic acid) / capping agent / in vitro toxicityИзвор:
Colloid and Polymer Science, 2012, 290, 3, 221-231Издавач:
- Springer-Verlag
Финансирање / пројекти:
- Молекуларно дизајнирање наночестица контролисаних морфолошких и физичко-хемијских карактеристика и функционалних материјала на њиховој основи (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
- United States National Institutes of Health (NIH) / National Institute of Dental and Craniofacial Research (NIDCR), Grant K99-DE021416
Напомена:
- Published version: https://hdl.handle.net/21.15107/rcub_dais_487
- This is the peer-reviewed version of the article: Stevanović, Magdalena, Savanović, Igor, Uskoković, Vuk, Škapin, Srečo Davor, Bračko, Ines, Jovanović, Uroš, Uskoković, Dragan, "A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles" in Colloid and Polymer Science, 290, no. 3 (2012):221-231, https://doi.org/10.1007/s00396-011-2540-7
Повезане информације:
- Друга верзија
https://hdl.handle.net/21.15107/rcub_dais_487 - Друга верзија
http://dx.doi.org/10.1007/s00396-011-2540-7
DOI: 10.1007/s00396-011-2540-7
ISSN: 0303-402X
WoS: 000299511800004
Scopus: 2-s2.0-84857637264
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Stevanović, Magdalena AU - Savanović, Igor AU - Uskoković, Vuk AU - Škapin, Srečo Davor AU - Bračko, Ines AU - Jovanović, Uroš AU - Uskoković, Dragan PY - 2012 UR - https://dais.sanu.ac.rs/123456789/571 AB - A simple and green chemical method has been developed to synthesize stable bare and capped silver nanoparticles based on the reduction of silver ions by glucose and capping by poly(α,γ,L-glutamic acid) (PGA). The use of ammonia during synthesis was avoided. PGA has had a dual role in the synthesis and was used as a capping agent to make the silver nanoparticle more biocompatible and to protect the nanoparticles from agglomerating in the liquid medium. The synthesized PGA-capped silver nanoparticles in the size range 5–45 nm were stable over long periods of time, without signs of precipitation. Morphological examination has shown that the silver nanoparticles had a nearly spherical, multiply twinned structure. The effects of the reaction temperature and the reaction time during the synthesis were investigated too. The biocompatibility of the PGA-capped silver nano-particles is discussed in terms of in vitro toxicity with human intestinal Caco-2 cells. The samples were characterized by UV–Visible spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and zeta potential measurements. PB - Springer-Verlag T2 - Colloid and Polymer Science T1 - A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles SP - 221 EP - 231 VL - 290 IS - 3 DO - 10.1007/s00396-011-2540-7 UR - https://hdl.handle.net/21.15107/rcub_dais_571 ER -
@article{ author = "Stevanović, Magdalena and Savanović, Igor and Uskoković, Vuk and Škapin, Srečo Davor and Bračko, Ines and Jovanović, Uroš and Uskoković, Dragan", year = "2012", abstract = "A simple and green chemical method has been developed to synthesize stable bare and capped silver nanoparticles based on the reduction of silver ions by glucose and capping by poly(α,γ,L-glutamic acid) (PGA). The use of ammonia during synthesis was avoided. PGA has had a dual role in the synthesis and was used as a capping agent to make the silver nanoparticle more biocompatible and to protect the nanoparticles from agglomerating in the liquid medium. The synthesized PGA-capped silver nanoparticles in the size range 5–45 nm were stable over long periods of time, without signs of precipitation. Morphological examination has shown that the silver nanoparticles had a nearly spherical, multiply twinned structure. The effects of the reaction temperature and the reaction time during the synthesis were investigated too. The biocompatibility of the PGA-capped silver nano-particles is discussed in terms of in vitro toxicity with human intestinal Caco-2 cells. The samples were characterized by UV–Visible spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and zeta potential measurements.", publisher = "Springer-Verlag", journal = "Colloid and Polymer Science", title = "A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles", pages = "221-231", volume = "290", number = "3", doi = "10.1007/s00396-011-2540-7", url = "https://hdl.handle.net/21.15107/rcub_dais_571" }
Stevanović, M., Savanović, I., Uskoković, V., Škapin, S. D., Bračko, I., Jovanović, U.,& Uskoković, D.. (2012). A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles. in Colloid and Polymer Science Springer-Verlag., 290(3), 221-231. https://doi.org/10.1007/s00396-011-2540-7 https://hdl.handle.net/21.15107/rcub_dais_571
Stevanović M, Savanović I, Uskoković V, Škapin SD, Bračko I, Jovanović U, Uskoković D. A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles. in Colloid and Polymer Science. 2012;290(3):221-231. doi:10.1007/s00396-011-2540-7 https://hdl.handle.net/21.15107/rcub_dais_571 .
Stevanović, Magdalena, Savanović, Igor, Uskoković, Vuk, Škapin, Srečo Davor, Bračko, Ines, Jovanović, Uroš, Uskoković, Dragan, "A new, simple, green, and one-pot four-component synthesis of bare and poly(α,γ, L-glutamic acid)-capped silver nanoparticles" in Colloid and Polymer Science, 290, no. 3 (2012):221-231, https://doi.org/10.1007/s00396-011-2540-7 ., https://hdl.handle.net/21.15107/rcub_dais_571 .