Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst
Само за регистроване кориснике
2018
Аутори
Liu, HuiLukić, Ivana
Miladinović, Marija R.
Veljković, Vlada B.
Zdujić, Miodrag
Zhu, Xiaosun
Zhang, Yanan
Skala, Dejan
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) p...roduction. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd
Кључне речи:
biodiesel / kinetic modeling / MnCO3/Na-silicate catalyst / pilot-plant design / subcritical methanolysisИзвор:
Energy Conversion and Management, 2018, 168, 494-504Издавач:
- Elsevier
Финансирање / пројекти:
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- International S&T Cooperation Program of China - Grant No. 2013DFG92250
DOI: 10.1016/j.enconman.2018.05.028
ISSN: 0196-8904
WoS: 000435619500040
Scopus: 2-s2.0-85047264849
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Liu, Hui AU - Lukić, Ivana AU - Miladinović, Marija R. AU - Veljković, Vlada B. AU - Zdujić, Miodrag AU - Zhu, Xiaosun AU - Zhang, Yanan AU - Skala, Dejan PY - 2018 UR - https://dais.sanu.ac.rs/123456789/3701 AB - The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) production. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd PB - Elsevier T2 - Energy Conversion and Management T1 - Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst SP - 494 EP - 504 VL - 168 DO - 10.1016/j.enconman.2018.05.028 UR - https://hdl.handle.net/21.15107/rcub_dais_3701 ER -
@article{ author = "Liu, Hui and Lukić, Ivana and Miladinović, Marija R. and Veljković, Vlada B. and Zdujić, Miodrag and Zhu, Xiaosun and Zhang, Yanan and Skala, Dejan", year = "2018", abstract = "The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) production. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd", publisher = "Elsevier", journal = "Energy Conversion and Management", title = "Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst", pages = "494-504", volume = "168", doi = "10.1016/j.enconman.2018.05.028", url = "https://hdl.handle.net/21.15107/rcub_dais_3701" }
Liu, H., Lukić, I., Miladinović, M. R., Veljković, V. B., Zdujić, M., Zhu, X., Zhang, Y.,& Skala, D.. (2018). Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst. in Energy Conversion and Management Elsevier., 168, 494-504. https://doi.org/10.1016/j.enconman.2018.05.028 https://hdl.handle.net/21.15107/rcub_dais_3701
Liu H, Lukić I, Miladinović MR, Veljković VB, Zdujić M, Zhu X, Zhang Y, Skala D. Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst. in Energy Conversion and Management. 2018;168:494-504. doi:10.1016/j.enconman.2018.05.028 https://hdl.handle.net/21.15107/rcub_dais_3701 .
Liu, Hui, Lukić, Ivana, Miladinović, Marija R., Veljković, Vlada B., Zdujić, Miodrag, Zhu, Xiaosun, Zhang, Yanan, Skala, Dejan, "Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst" in Energy Conversion and Management, 168 (2018):494-504, https://doi.org/10.1016/j.enconman.2018.05.028 ., https://hdl.handle.net/21.15107/rcub_dais_3701 .