Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO
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2018
Authors
Habran, MargaritaPontón, Patricia I.
Mančić, Lidija
Pandoli, Omar
Krambrock, Klaus
Maia da Costa, Marcelo Eduardo Huguenin
Letichevsky, Sonia
Costa, Antonio Mario Leal Martins
Morgado, Edisson Jr.
Marinković, Bojan A.
Article (Published version)
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Show full item recordAbstract
The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active towa...rd photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V.
Keywords:
acetylacetonate / air remediation / charge separation / heterostructure / TiO2-based nanostructuresSource:
Journal of Photochemistry and Photobiology A: Chemistry, 2018, 365, 133-144Publisher:
- Elsevier
Funding / projects:
- National Council for Scientific and Technological Development of Brazil
Note:
- Supporting information: https://hdl.handle.net/21.15107/rcub_dais_3758
- Peer-reviewed manuscript: https://hdl.handle.net/21.15107/rcub_dais_4084
Related info:
- Version of
https://hdl.handle.net/21.15107/rcub_dais_4084 - Referenced by
https://hdl.handle.net/21.15107/rcub_dais_3758
DOI: 10.1016/j.jphotochem.2018.07.038
ISSN: 1010-6030
WoS: 000444356600018
Scopus: 2-s2.0-85051045212
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Habran, Margarita AU - Pontón, Patricia I. AU - Mančić, Lidija AU - Pandoli, Omar AU - Krambrock, Klaus AU - Maia da Costa, Marcelo Eduardo Huguenin AU - Letichevsky, Sonia AU - Costa, Antonio Mario Leal Martins AU - Morgado, Edisson Jr. AU - Marinković, Bojan A. PY - 2018 UR - https://dais.sanu.ac.rs/123456789/3692 AB - The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active toward photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V. PB - Elsevier T2 - Journal of Photochemistry and Photobiology A: Chemistry T1 - Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO SP - 133 EP - 144 VL - 365 DO - 10.1016/j.jphotochem.2018.07.038 UR - https://hdl.handle.net/21.15107/rcub_dais_3692 ER -
@article{ author = "Habran, Margarita and Pontón, Patricia I. and Mančić, Lidija and Pandoli, Omar and Krambrock, Klaus and Maia da Costa, Marcelo Eduardo Huguenin and Letichevsky, Sonia and Costa, Antonio Mario Leal Martins and Morgado, Edisson Jr. and Marinković, Bojan A.", year = "2018", abstract = "The efficiency of photo-oxidation of pollutants catalysed by semiconductors is still limited for real-world applications due to several drawbacks, such as a) insufficient absorption of visible radiation, which predominates in solar spectrum, b) rapid free electron to hole recombination, c) small surface area, built from equilibrium crystallographic facets with low adsorption capacities and d) photo-corrosion. The present study disclosures new mesoporous heterostructures, built from exfoliated lepidocrocite-like ferrititanates and TiO2 (anatase)-acetylacetone charge transfer complex, capable of reducing free electron-to-hole recombination rate through a robust charge separation and sensitive to the visible light spectrum. The synthesis route is based on soft-chemistry and low temperature calcination at 300 °C. Two different partially pillarized heterostructures, denoted as HM-1 and HM-2, have been synthesized. It was observed that the heterostructure HM-1 was four times more active toward photocatalytic degradation of NO gas in comparison to the benchmark photocatalytic material P25. The lower activity of the heterostructure HM-2, comparable to that of P-25, was attributed to the high value of Urbach energy that indicates high number of defect sites within energy band-gap of the constituent semiconductor components. [Ti] anatase/[Ti] ferrititanate mol ratio might also play a role in photocatalytic efficiency. © 2018 Elsevier B.V.", publisher = "Elsevier", journal = "Journal of Photochemistry and Photobiology A: Chemistry", title = "Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO", pages = "133-144", volume = "365", doi = "10.1016/j.jphotochem.2018.07.038", url = "https://hdl.handle.net/21.15107/rcub_dais_3692" }
Habran, M., Pontón, P. I., Mančić, L., Pandoli, O., Krambrock, K., Maia da Costa, M. E. H., Letichevsky, S., Costa, A. M. L. M., Morgado, E. Jr.,& Marinković, B. A.. (2018). Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry Elsevier., 365, 133-144. https://doi.org/10.1016/j.jphotochem.2018.07.038 https://hdl.handle.net/21.15107/rcub_dais_3692
Habran M, Pontón PI, Mančić L, Pandoli O, Krambrock K, Maia da Costa MEH, Letichevsky S, Costa AMLM, Morgado EJ, Marinković BA. Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO. in Journal of Photochemistry and Photobiology A: Chemistry. 2018;365:133-144. doi:10.1016/j.jphotochem.2018.07.038 https://hdl.handle.net/21.15107/rcub_dais_3692 .
Habran, Margarita, Pontón, Patricia I., Mančić, Lidija, Pandoli, Omar, Krambrock, Klaus, Maia da Costa, Marcelo Eduardo Huguenin, Letichevsky, Sonia, Costa, Antonio Mario Leal Martins, Morgado, Edisson Jr., Marinković, Bojan A., "Visible light sensitive mesoporous nanohybrids of lepidocrocite-like ferrititanate coupled to a charge transfer complex: Synthesis, characterization and photocatalytic degradation of NO" in Journal of Photochemistry and Photobiology A: Chemistry, 365 (2018):133-144, https://doi.org/10.1016/j.jphotochem.2018.07.038 ., https://hdl.handle.net/21.15107/rcub_dais_3692 .