Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution
Samo za registrovane korisnike
2008
Autori
Krstajić, NedeljkoJović, Vladimir D.
Gajić Krstajić, Ljiljana
Jović, Borka M.
Antozzi, A. L.
Martelli, G. N.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.
Ključne reči:
coatings / EIS measurements / electrodeposition / hydrogen evolution / Ni-Mo alloy / stabilityIzvor:
International Journal of Hydrogen Energy, 2008, 33, 14, 3676-3687Izdavač:
- Elsevier
Finansiranje / projekti:
- Sinteza, karakterizacija i primena nanostruktuiranih katalizatora na različitim nosačima u gorivnim spregovima, elektrolizi vode i elektroorganskoj sintezi (RS-MESTD-MPN2006-2010-142038)
DOI: 10.1016/j.ijhydene.2008.04.039
ISSN: 0360-3199
WoS: 000258987000008
Scopus: 2-s2.0-47749095923
Institucija/grupa
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Krstajić, Nedeljko AU - Jović, Vladimir D. AU - Gajić Krstajić, Ljiljana AU - Jović, Borka M. AU - Antozzi, A. L. AU - Martelli, G. N. PY - 2008 UR - https://dais.sanu.ac.rs/123456789/3579 AB - The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy. PB - Elsevier T2 - International Journal of Hydrogen Energy T1 - Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution SP - 3676 EP - 3687 VL - 33 IS - 14 DO - 10.1016/j.ijhydene.2008.04.039 UR - https://hdl.handle.net/21.15107/rcub_dais_3579 ER -
@article{ author = "Krstajić, Nedeljko and Jović, Vladimir D. and Gajić Krstajić, Ljiljana and Jović, Borka M. and Antozzi, A. L. and Martelli, G. N.", year = "2008", abstract = "The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.", publisher = "Elsevier", journal = "International Journal of Hydrogen Energy", title = "Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution", pages = "3676-3687", volume = "33", number = "14", doi = "10.1016/j.ijhydene.2008.04.039", url = "https://hdl.handle.net/21.15107/rcub_dais_3579" }
Krstajić, N., Jović, V. D., Gajić Krstajić, L., Jović, B. M., Antozzi, A. L.,& Martelli, G. N.. (2008). Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in International Journal of Hydrogen Energy Elsevier., 33(14), 3676-3687. https://doi.org/10.1016/j.ijhydene.2008.04.039 https://hdl.handle.net/21.15107/rcub_dais_3579
Krstajić N, Jović VD, Gajić Krstajić L, Jović BM, Antozzi AL, Martelli GN. Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in International Journal of Hydrogen Energy. 2008;33(14):3676-3687. doi:10.1016/j.ijhydene.2008.04.039 https://hdl.handle.net/21.15107/rcub_dais_3579 .
Krstajić, Nedeljko, Jović, Vladimir D., Gajić Krstajić, Ljiljana, Jović, Borka M., Antozzi, A. L., Martelli, G. N., "Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution" in International Journal of Hydrogen Energy, 33, no. 14 (2008):3676-3687, https://doi.org/10.1016/j.ijhydene.2008.04.039 ., https://hdl.handle.net/21.15107/rcub_dais_3579 .