Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite
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2024
Authors
Filipović, SuzanaObradović, Nina
Corlett, Cole
Fahrenholtz, William G.
Rosenschon, Martin
Füglein, Ekkehard
Dojčilović, Radovan
Tošić, Dragana
Petrović, Jovana
Đorđević, Antonije
Vlahović, Branislav
Pavlović, Vladimir B.
Article (Accepted Version)
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Show full item recordAbstract
Ceramic/polymer composites can be chemically stable, mechanically strong, and flexible, which make them candidates for electric devices, such as pressure or temperature sensors, energy storage or harvesting devices, actuators, and so forth. Depending on the application, various electrical properties are of importance. Polymers usually have low dielectric permittivity, but increased dielectric permittivity can be achieved by the addition of the ceramic fillers with high dielectric constant. With the aim to enhance dielectric properties of the composite without loss of flexibility, 5 wt% of BaTiO3-Fe2O3 powder was added into a polyvinylidene fluoride matrix. The powder was prepared by different synthesis conditions to produce core/shell structures. The effect of the phase composition and morphology of the BaTiO3-Fe2O3 core/shell filler on the structure and lattice dynamics of the polymer composites was investigated. Based on the results of the thermal analysis, various parameters of cera...mic/polymer composites were determined. Differences in the phase composition and morphology of the filler have an influence on the formation of various polyvinylidene fluoride allomorphs and the degree of crystallinity. Furthermore, the dielectric performances of pure polyvinylidene fluoride and the polymer/ceramic composites were measured.
Keywords:
composite materials / polyvinylidene fluoride / BaTiO3-Fe2O3Source:
Journal of Applied Polymer Science, 2024, 141, 10, e55040-Publisher:
- Wiley
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200175 (Institute of Technical Sciences of SASA, Belgrade) (RS-MESTD-inst-2020-200175)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200116 (University of Belgrade, Faculty of Agriculture) (RS-MESTD-inst-2020-200116)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200103 (University of Belgrade, Faculty of Electrical Engineering) (RS-MESTD-inst-2020-200103)
- Serbian Academy of Sciences and Arts, Project F-133
- US National Science Foundation (Grant: DMR EiR 2101041, NSF DMR PREM 2122044)
- US Department of Energy/National Nuclear Security Administration (Grant: NA0003979)
- USA NSF PREM [DMR 11523617]
Note:
- This is the peer reviewed version of the following article: Filipović, Suzana, Obradović, Nina, Corlett, Cole, Fahrenholtz, William G., Rosenschon, Martin, Füglein, Ekkehard, Dojčilović, Radovan, Tošić, Dragana, Petrović, Jovana, Đorđević, Antonije, Vlahović, Branislav, Pavlović, Vladimir B., "Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite" in Journal of Applied Polymer Science, 141, no. 10 (2024), https://doi.org/10.1002/app.55040
- Published version: https://hdl.handle.net/21.15107/rcub_dais_16243
Related info:
- Version of
https://hdl.handle.net/21.15107/rcub_dais_16243 - Version of
https://doi.org/10.1002/app.55040
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Filipović, Suzana AU - Obradović, Nina AU - Corlett, Cole AU - Fahrenholtz, William G. AU - Rosenschon, Martin AU - Füglein, Ekkehard AU - Dojčilović, Radovan AU - Tošić, Dragana AU - Petrović, Jovana AU - Đorđević, Antonije AU - Vlahović, Branislav AU - Pavlović, Vladimir B. PY - 2024 UR - https://dais.sanu.ac.rs/123456789/16516 AB - Ceramic/polymer composites can be chemically stable, mechanically strong, and flexible, which make them candidates for electric devices, such as pressure or temperature sensors, energy storage or harvesting devices, actuators, and so forth. Depending on the application, various electrical properties are of importance. Polymers usually have low dielectric permittivity, but increased dielectric permittivity can be achieved by the addition of the ceramic fillers with high dielectric constant. With the aim to enhance dielectric properties of the composite without loss of flexibility, 5 wt% of BaTiO3-Fe2O3 powder was added into a polyvinylidene fluoride matrix. The powder was prepared by different synthesis conditions to produce core/shell structures. The effect of the phase composition and morphology of the BaTiO3-Fe2O3 core/shell filler on the structure and lattice dynamics of the polymer composites was investigated. Based on the results of the thermal analysis, various parameters of ceramic/polymer composites were determined. Differences in the phase composition and morphology of the filler have an influence on the formation of various polyvinylidene fluoride allomorphs and the degree of crystallinity. Furthermore, the dielectric performances of pure polyvinylidene fluoride and the polymer/ceramic composites were measured. PB - Wiley T2 - Journal of Applied Polymer Science T1 - Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite SP - e55040 VL - 141 IS - 10 DO - 10.1002/app.55040 UR - https://hdl.handle.net/21.15107/rcub_dais_16516 ER -
@article{ author = "Filipović, Suzana and Obradović, Nina and Corlett, Cole and Fahrenholtz, William G. and Rosenschon, Martin and Füglein, Ekkehard and Dojčilović, Radovan and Tošić, Dragana and Petrović, Jovana and Đorđević, Antonije and Vlahović, Branislav and Pavlović, Vladimir B.", year = "2024", abstract = "Ceramic/polymer composites can be chemically stable, mechanically strong, and flexible, which make them candidates for electric devices, such as pressure or temperature sensors, energy storage or harvesting devices, actuators, and so forth. Depending on the application, various electrical properties are of importance. Polymers usually have low dielectric permittivity, but increased dielectric permittivity can be achieved by the addition of the ceramic fillers with high dielectric constant. With the aim to enhance dielectric properties of the composite without loss of flexibility, 5 wt% of BaTiO3-Fe2O3 powder was added into a polyvinylidene fluoride matrix. The powder was prepared by different synthesis conditions to produce core/shell structures. The effect of the phase composition and morphology of the BaTiO3-Fe2O3 core/shell filler on the structure and lattice dynamics of the polymer composites was investigated. Based on the results of the thermal analysis, various parameters of ceramic/polymer composites were determined. Differences in the phase composition and morphology of the filler have an influence on the formation of various polyvinylidene fluoride allomorphs and the degree of crystallinity. Furthermore, the dielectric performances of pure polyvinylidene fluoride and the polymer/ceramic composites were measured.", publisher = "Wiley", journal = "Journal of Applied Polymer Science", title = "Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite", pages = "e55040", volume = "141", number = "10", doi = "10.1002/app.55040", url = "https://hdl.handle.net/21.15107/rcub_dais_16516" }
Filipović, S., Obradović, N., Corlett, C., Fahrenholtz, W. G., Rosenschon, M., Füglein, E., Dojčilović, R., Tošić, D., Petrović, J., Đorđević, A., Vlahović, B.,& Pavlović, V. B.. (2024). Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite. in Journal of Applied Polymer Science Wiley., 141(10), e55040. https://doi.org/10.1002/app.55040 https://hdl.handle.net/21.15107/rcub_dais_16516
Filipović S, Obradović N, Corlett C, Fahrenholtz WG, Rosenschon M, Füglein E, Dojčilović R, Tošić D, Petrović J, Đorđević A, Vlahović B, Pavlović VB. Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite. in Journal of Applied Polymer Science. 2024;141(10):e55040. doi:10.1002/app.55040 https://hdl.handle.net/21.15107/rcub_dais_16516 .
Filipović, Suzana, Obradović, Nina, Corlett, Cole, Fahrenholtz, William G., Rosenschon, Martin, Füglein, Ekkehard, Dojčilović, Radovan, Tošić, Dragana, Petrović, Jovana, Đorđević, Antonije, Vlahović, Branislav, Pavlović, Vladimir B., "Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite" in Journal of Applied Polymer Science, 141, no. 10 (2024):e55040, https://doi.org/10.1002/app.55040 ., https://hdl.handle.net/21.15107/rcub_dais_16516 .