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dc.creatorLukić, Ivana
dc.creatorKesić, Željka
dc.creatorMaksimović, Svetolik
dc.creatorZdujić, Miodrag
dc.creatorKrstić, Jugoslav
dc.creatorSkala, Dejan
dc.date.accessioned2017-06-10T15:45:07Z
dc.date.issued2014
dc.identifier.issn1451-9372 (Print)
dc.identifier.issn2217-7434 (Online)
dc.identifier.urihttp://dais.sanu.ac.rs/123456789/655
dc.description.abstractThe kinetics of heterogeneous methanolysis of sunflower oil was studied at 60°C using mechanochemically synthesized CaO∙ZnO as catalyst. Influence of agitation speed, catalyst amount and methanol to oil molar ratio on the rate of reaction was analyzed. The rate of the process depends on the two resistances - mass transfer of triglycerides to the catalyst surface and chemical reaction on the catalyst surface, which are defined as the values of the overall triglyceride volumetric mass transfer coefficient, kmt,TG, and the effective pseudo first-order reaction rate constant, k, respectively. These kinetic parameters actually determine the value of the apparent reaction rate constant, kapp, whose change with time is defined with the change of triglyceride (TG) conversion. The kinetic model was proposed and the model parameters determined. [Projekat Ministarstva nauke Republike Srbije, br. 45001]en
dc.formatapplication/pdf
dc.languageen
dc.publisherBelgrade: Association of the Chemical Engineers of Serbia
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//
dc.rightsopenAccess
dc.sourceChemical Industry and Chemical Engineering Quarterlyen
dc.subjectbiodisel
dc.subjectheterogeneous catalyst
dc.subjectkinetics
dc.subjectCaO
dc.subjectZnO
dc.titleKinetics of heterogeneous methanolysis of sunflower oil with CaO∙ZnO catalyst: Influence of different hydrodynamic conditionsen
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractСкала, Дејан; Крстић, Југослав; Здујић, Миодраг; Максимовић, Светолик; Кесић, Жељка; Лукић, Ивана;
dc.citation.spage425
dc.citation.epage439
dc.citation.volume20
dc.citation.issue3
dc.identifier.wos000343922200014
dc.identifier.doi10.2298/CICEQ130514025L
dc.identifier.scopus2-s2.0-84919783679
dc.type.versionpublishedVersion
dc.identifier.fulltexthttp://dais.sanu.ac.rs/bitstream/id/21625/652.pdf


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