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Razvoj titanskih RuO2/TiO2 anoda i uređaja za in situ proizvodnju aktivnog hlora

dc.creatorSpasojević, Miroslav
dc.creatorTrišović, Tomislav
dc.creatorRibić-Zelenović, Lenka
dc.creatorSpasojević, Pavle
dc.date.accessioned2017-06-10T15:45:07Z
dc.date.issued2013
dc.identifier.issn0367-598X (Print)
dc.identifier.issn2217-7426 (Online)
dc.identifier.urihttp://dais.sanu.ac.rs/123456789/379
dc.description.abstractChlorine is used worldwide for water disinfection purposes. However, due to its toxicity the EU has imposed a set of standards that must be applied when transporting and storing chlorine. In Serbia, numerous studies have been conducted attempting to develop the technology for the generation of active chlorine disinfectant but with a non-toxic aqueous solution of sodium chloride as the raw material. This study provides an overview of the titanium anodes activated by thermally obtained solid solution of ruthenium and titanium oxide development. It also presents new findings on the effect of the temperature of thermal treatment, the composition, the thickness of an active coating on its microstructural properties, and consequently on the catalytic activity, ion selectivity, and corrosion stability during active chlorine generation through the electrolysis of dilute sodium chloride solutions at room temperature. The study also evaluates the effect of the kinetic and operational parameters of the electrochemical process of active chlorine generation on both current and energy efficiencies. The results obtained were used to determine optimal values of technological parameters of the production process. This comprehensive research resulted in the construction of different types of remote-controlled and fully automated active chlorine generating plants.en
dc.description.abstractU radu je dat pregled razvoja aktivnih titanskih anoda za reakciju oksidacije hloridnih jona u istraživačkim laboratorijama u Srbiji. Prikazani su i novi rezultati istraživanja efekta temperature termičke obrade, sastava i debljine aktivne RuO2/TiO2 prevlake na titanu na njena mikrostrukturna svojstva i odraz ovih svojstava na katalitičku aktivnost, jonselektivnost i korozionu stabilnost u procesu dobijanja aktivnog hlora. Ustanovljen je i efekat kinetičkih i operativnih parametara procesa elektrolize razblaženih rastvora natrijum-hlorida na iskorišćenje struje i energije po aktivnom hloru. Na osnovu ovih ispitivanja konstruisana je ćelija za elektrolizu i utvrđene su optimalne vrednosti tehnoloških parametara procesa proizvodnje aktivnog hlora. Sveobuhvatna istraživanja rezultirala su konstrukcijom različitih tipova postrojenja za in situ proizvodnju aktivnog hlora.sr
dc.format67 2 (2013) 313-321
dc.formatapplication/pdf
dc.languagesr
dc.publisherBelgrade : Association of the Chemical Engineers of Serbia
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172057/RS//
dc.rightsopenAccess
dc.sourceHemijska industrijaen
dc.subjectdisinfection
dc.subjectactive chlorine
dc.subjectanode
dc.titleDevelopment of RuO2/TiO2 titanium anodes and a device for in situ active chlorine generationen
dc.title.alternativeRazvoj titanskih RuO2/TiO2 anoda i uređaja za in situ proizvodnju aktivnog hlorasr
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractСпасојевић, Мирослав; Тришовић, Томислав; Рибић-Зеленовић, Ленка; Спасојевић, Павле;
dc.citation.spage313
dc.citation.epage321
dc.citation.volume67
dc.citation.issue2
dc.identifier.wos000322208200014
dc.identifier.doi10.2298/HEMIND120414076S
dc.identifier.scopus2-s2.0-84877812461
dc.type.versionpublishedVersion
dc.identifier.fulltexthttp://dais.sanu.ac.rs/bitstream/handle/123456789/379/Spasojevic-M.D._Hemijska-Industrija_67_2013_313_321.pdf


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