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dc.creatorMarinković, Bojan A.
dc.creatorPontón, Patricia I.
dc.creatorResende, J. M.
dc.creatorLetichevsky, Sonia
dc.creatorHabran, Margarita
dc.creatorViol, J. B.
dc.creatorPandoli, Omar
dc.creatorMančić, Lidija
dc.date.accessioned2018-07-25T10:22:18Z
dc.date.available2018-07-25T10:22:18Z
dc.date.issued2015
dc.identifier.issn0264-1275
dc.identifier.urihttp://dais.sanu.ac.rs/123456789/3515
dc.description.abstractEfficient methods for the synthesis of layered structure nanomaterials (nanosheets), their complete exfoliation (delamination) into the layers of atomic thickness and design of organic-inorganic nanohybrids present important stages toward development of improved polymer-based nanocomposites and pillared heterostructures with potential application in purification technologies such as photocatalysis. A rapid and efficient exfoliation process of protonated layered ferrititanates with lepidocrocite-like structure and formation of organic-inorganic nanohybrids is performed starting from the nanosheets composed of only a few host layers and nanometric lateral dimensions using quaternary ammonium compounds. These nanosheets are initially synthesized from a highly abundant precursor through an alkaline hydrothermal route. We demonstrated that dimethyldioctadecylammonium cations strongly interact with the exfoliated single host layers (0.75. nm thick) providing thermal stability (~ 500 °C) to the as-prepared organic-inorganic nanohybrid over the temperature range commonly applied for the processing of thermoplastic nanocomposites. © 2015 Elsevier Ltd.
dc.publisherElsevier
dc.relationConselho Nacional de Desenvolvimento Científico e Tecnológico, Brazil, Research Productivity Grant
dc.relationFundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro, E-26/111.150/2011 PRONEM 25/2010
dc.rightsrestrictedAccess
dc.sourceMaterials and Design
dc.subjectexfoliation
dc.subjectlayered structure
dc.subjectnanosheet
dc.subjectorganic-inorganic nanohybrid
dc.subjectsmall-angle X-ray scattering
dc.subjectthermal stability
dc.titleLepidocrocite-like ferrititanate nanosheets and their full exfoliation with quaternary ammonium compounds
dc.typearticleen
dc.rights.licenseARR
dcterms.abstractПандоли, О.; Маринковић, Бојан A.; Понтóн, Патрициа И.; Ресенде, Ј. М.; Летицхевскy, С.; Хабран, М.; Виол, Ј. Б.; Манчић, Лидија;
dc.citation.spage197
dc.citation.epage204
dc.citation.volume85
dc.identifier.wos000364585000025
dc.identifier.doi10.1016/j.matdes.2015.06.171
dc.identifier.scopus2-s2.0-84940727205
dc.type.versionpublishedVersion
dc.identifier.fulltexthttp://dais.sanu.ac.rs/bitstream/handle/123456789/3515/Marinkovic_2015_Materials-and-Design_85_197.pdf


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