Photocatalytic degradation of bisphenol A in aqueous solution using TiO2/clinoptilolite hybrid photocatalyst
Само за регистроване кориснике
2023
Аутори
Stojanović, SrnaRac, Vladislav
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Mojsilović, Kristina
Vasilić, Rastko
Marković, Smilja
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Damjanović Vasilić, Ljiljana
Чланак у часопису (Објављена верзија)
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Метаподаци
Приказ свих података о документуАпстракт
Photocatalytic degradation of bisphenol A (BPA) was investigated using commercial TiO2 P25 nanoparticles supported on natural zeolite clinoptilolite (Cli). Employing ultrasound assisted solid-state dispersion method hybrid photocatalyst containing 20 wt% of TiO2, marked TCli-20, was prepared. The structural, morphological and surface properties, and particle size distribution of TCli-20 were studied by X-ray powder diffraction, Fourier transform infrared spectroscopy, ultraviolet–visible diffuse reflectance spectroscopy, scanning electron microscopy with energy dispersive spectroscopy, atomic force microscopy, Brunner-Emmet-Teller method and laser diffraction. The results revealed a successful loading of TiO2 P25 nanoparticles on Cli surface and the preservation of both zeolitic structure and optical properties of TiO2. The influence of catalyst dose, pH value and the addition of hydrogen peroxide (H2O2) was evaluated. The optimal reaction conditions were 2 g/L of catalyst at near-neut...ral conditions (pH = 6.4) for complete BPA (5 mg/L) photodegradation after 180 min of exposure to simulated solar light. The addition of H2O2 was beneficial for the degradation process and led to the removal of BPA after 120 min of irradiation. BPA removal (60% for 180 min of irradiation) was reduced when TCli-20 was tested in bottled drinking water due to the presence of bicarbonate ions which acted as scavengers for hydroxyl radicals. Even though the photocatalytic activity of TCli-20 decreased after several cycles of usage, 70% of BPA was still successfully degraded during the fourth cycle. The reusability study showed easy separation, stability and good photocatalytic ability of investigated cost-effective hybrid photocatalyst. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
Кључне речи:
Bisphenol A / bottled drinking water / clinoptilolite / photodegradation / simulated solar irradiation / TiO2Извор:
Environmental Science and Pollution Research, 2023, 30, 84046-84060Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200146 (Универзитет у Београду, Факултет за физичку хемију) (RS-MESTD-inst-2020-200146)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200162 (Универзитет у Београду, Физички факултет) (RS-MESTD-inst-2020-200162)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200175 (Институт техничких наука САНУ, Београд) (RS-MESTD-inst-2020-200175)
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Stojanović, Srna AU - Rac, Vladislav AU - Mojsilović, Kristina AU - Vasilić, Rastko AU - Marković, Smilja AU - Damjanović Vasilić, Ljiljana PY - 2023 UR - https://dais.sanu.ac.rs/123456789/15132 AB - Photocatalytic degradation of bisphenol A (BPA) was investigated using commercial TiO2 P25 nanoparticles supported on natural zeolite clinoptilolite (Cli). Employing ultrasound assisted solid-state dispersion method hybrid photocatalyst containing 20 wt% of TiO2, marked TCli-20, was prepared. The structural, morphological and surface properties, and particle size distribution of TCli-20 were studied by X-ray powder diffraction, Fourier transform infrared spectroscopy, ultraviolet–visible diffuse reflectance spectroscopy, scanning electron microscopy with energy dispersive spectroscopy, atomic force microscopy, Brunner-Emmet-Teller method and laser diffraction. The results revealed a successful loading of TiO2 P25 nanoparticles on Cli surface and the preservation of both zeolitic structure and optical properties of TiO2. The influence of catalyst dose, pH value and the addition of hydrogen peroxide (H2O2) was evaluated. The optimal reaction conditions were 2 g/L of catalyst at near-neutral conditions (pH = 6.4) for complete BPA (5 mg/L) photodegradation after 180 min of exposure to simulated solar light. The addition of H2O2 was beneficial for the degradation process and led to the removal of BPA after 120 min of irradiation. BPA removal (60% for 180 min of irradiation) was reduced when TCli-20 was tested in bottled drinking water due to the presence of bicarbonate ions which acted as scavengers for hydroxyl radicals. Even though the photocatalytic activity of TCli-20 decreased after several cycles of usage, 70% of BPA was still successfully degraded during the fourth cycle. The reusability study showed easy separation, stability and good photocatalytic ability of investigated cost-effective hybrid photocatalyst. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. T2 - Environmental Science and Pollution Research T1 - Photocatalytic degradation of bisphenol A in aqueous solution using TiO2/clinoptilolite hybrid photocatalyst SP - 84046 EP - 84060 VL - 30 DO - 10.1007/s11356-023-28397-w UR - https://hdl.handle.net/21.15107/rcub_dais_15132 ER -
@article{ author = "Stojanović, Srna and Rac, Vladislav and Mojsilović, Kristina and Vasilić, Rastko and Marković, Smilja and Damjanović Vasilić, Ljiljana", year = "2023", abstract = "Photocatalytic degradation of bisphenol A (BPA) was investigated using commercial TiO2 P25 nanoparticles supported on natural zeolite clinoptilolite (Cli). Employing ultrasound assisted solid-state dispersion method hybrid photocatalyst containing 20 wt% of TiO2, marked TCli-20, was prepared. The structural, morphological and surface properties, and particle size distribution of TCli-20 were studied by X-ray powder diffraction, Fourier transform infrared spectroscopy, ultraviolet–visible diffuse reflectance spectroscopy, scanning electron microscopy with energy dispersive spectroscopy, atomic force microscopy, Brunner-Emmet-Teller method and laser diffraction. The results revealed a successful loading of TiO2 P25 nanoparticles on Cli surface and the preservation of both zeolitic structure and optical properties of TiO2. The influence of catalyst dose, pH value and the addition of hydrogen peroxide (H2O2) was evaluated. The optimal reaction conditions were 2 g/L of catalyst at near-neutral conditions (pH = 6.4) for complete BPA (5 mg/L) photodegradation after 180 min of exposure to simulated solar light. The addition of H2O2 was beneficial for the degradation process and led to the removal of BPA after 120 min of irradiation. BPA removal (60% for 180 min of irradiation) was reduced when TCli-20 was tested in bottled drinking water due to the presence of bicarbonate ions which acted as scavengers for hydroxyl radicals. Even though the photocatalytic activity of TCli-20 decreased after several cycles of usage, 70% of BPA was still successfully degraded during the fourth cycle. The reusability study showed easy separation, stability and good photocatalytic ability of investigated cost-effective hybrid photocatalyst. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.", journal = "Environmental Science and Pollution Research", title = "Photocatalytic degradation of bisphenol A in aqueous solution using TiO2/clinoptilolite hybrid photocatalyst", pages = "84046-84060", volume = "30", doi = "10.1007/s11356-023-28397-w", url = "https://hdl.handle.net/21.15107/rcub_dais_15132" }
Stojanović, S., Rac, V., Mojsilović, K., Vasilić, R., Marković, S.,& Damjanović Vasilić, L.. (2023). Photocatalytic degradation of bisphenol A in aqueous solution using TiO2/clinoptilolite hybrid photocatalyst. in Environmental Science and Pollution Research, 30, 84046-84060. https://doi.org/10.1007/s11356-023-28397-w https://hdl.handle.net/21.15107/rcub_dais_15132
Stojanović S, Rac V, Mojsilović K, Vasilić R, Marković S, Damjanović Vasilić L. Photocatalytic degradation of bisphenol A in aqueous solution using TiO2/clinoptilolite hybrid photocatalyst. in Environmental Science and Pollution Research. 2023;30:84046-84060. doi:10.1007/s11356-023-28397-w https://hdl.handle.net/21.15107/rcub_dais_15132 .
Stojanović, Srna, Rac, Vladislav, Mojsilović, Kristina, Vasilić, Rastko, Marković, Smilja, Damjanović Vasilić, Ljiljana, "Photocatalytic degradation of bisphenol A in aqueous solution using TiO2/clinoptilolite hybrid photocatalyst" in Environmental Science and Pollution Research, 30 (2023):84046-84060, https://doi.org/10.1007/s11356-023-28397-w ., https://hdl.handle.net/21.15107/rcub_dais_15132 .