Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study
Само за регистроване кориснике
2022
Аутори
Bosnar, SanjaRac, Vladislav
Stošić, Dušan
Travert, Arnaud
Postole, Georgeta
Auroux, Aline
Škapin, Srečo Davor
Damjanović-Vasilić, Ljiljana S.
Bronić, Josip
Du, Xuesen
Marković, Smilja
Pavlović, Vladimir B.
Rakić, Vesna M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Dual templating approach, using hexadecyltrimethylammonium bromide (CTAB), was employed in an attempt to synthesize hierarchical ZSM-5 zeolite. Amount of mesoporogen and the duration of aging of the precursor were varied. Majority of the synthesis routes resulted in phase separation, yielding separate ZSM-5 and amorphous mesoporous material. The relative amounts of the two phases were dependent on the CTAB amount ratio and also significantly on the duration of precursor aging before CTAB addition. One particular combination of the two factors led to the formation of a homogeneous hierarchical form of ZSM-5 with leafy morphology, consisting of intergrown thin crystalline sheets which formed flower-like structures. The hierarchical ZSM-5 possessed significant microporous (≈95 m2/g) and highly developed mesoporous surface (≈470 m2/g), with a relatively broad distribution of mesopore sizes (<20 nm). The acidity of all samples was studied in detail. Isothermal microcalorimetry/volumetry of ...ammonia adsorption provided quantitative data on the number and distribution of strength of acidic sites. In situ FTIR of pyridine and collidine adsorption was used to quantify Brønsted and Lewis acid sites, and to provide information on their location - in the micropores or mesopores/external surface. The hierarchical ZSM-5 possessed both Lewis and Brønsted acidity, with Brønsted sites located mainly in the micropores. All samples were fully characterized using XRD, low temperature nitrogen adsorption, FESEM and EDS. The synthetic route used for obtaining the ZSM-5 zeolite with flower-like morphology is a simple strategy for preparing hierarchical ZSM-5 forms targeting enhanced diffusivity and accessibility of catalytically active sites.
Кључне речи:
acidity / dual template / flower-like morphology / hierarchical ZSM-5 / FTIR / microcalorimetryИзвор:
Microporous and Mesoporous Materials, 2022, 329, 111534-Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200146 (Универзитет у Београду, Факултет за физичку хемију) (RS-MESTD-inst-2020-200146)
- Croatian Science Foundation [IP-2016-06-224]
- Providence Health Care [40861UH, 451-03-01963/2017-09/18]
- Chinese-Serbian project [451-03-1205/2021-09]
DOI: 10.1016/j.micromeso.2021.111534
ISSN: 1387-1811
WoS: 000718039200004
Scopus: 2-s2.0-85118483367
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Bosnar, Sanja AU - Rac, Vladislav AU - Stošić, Dušan AU - Travert, Arnaud AU - Postole, Georgeta AU - Auroux, Aline AU - Škapin, Srečo Davor AU - Damjanović-Vasilić, Ljiljana S. AU - Bronić, Josip AU - Du, Xuesen AU - Marković, Smilja AU - Pavlović, Vladimir B. AU - Rakić, Vesna M. PY - 2022 UR - https://dais.sanu.ac.rs/123456789/13631 AB - Dual templating approach, using hexadecyltrimethylammonium bromide (CTAB), was employed in an attempt to synthesize hierarchical ZSM-5 zeolite. Amount of mesoporogen and the duration of aging of the precursor were varied. Majority of the synthesis routes resulted in phase separation, yielding separate ZSM-5 and amorphous mesoporous material. The relative amounts of the two phases were dependent on the CTAB amount ratio and also significantly on the duration of precursor aging before CTAB addition. One particular combination of the two factors led to the formation of a homogeneous hierarchical form of ZSM-5 with leafy morphology, consisting of intergrown thin crystalline sheets which formed flower-like structures. The hierarchical ZSM-5 possessed significant microporous (≈95 m2/g) and highly developed mesoporous surface (≈470 m2/g), with a relatively broad distribution of mesopore sizes (<20 nm). The acidity of all samples was studied in detail. Isothermal microcalorimetry/volumetry of ammonia adsorption provided quantitative data on the number and distribution of strength of acidic sites. In situ FTIR of pyridine and collidine adsorption was used to quantify Brønsted and Lewis acid sites, and to provide information on their location - in the micropores or mesopores/external surface. The hierarchical ZSM-5 possessed both Lewis and Brønsted acidity, with Brønsted sites located mainly in the micropores. All samples were fully characterized using XRD, low temperature nitrogen adsorption, FESEM and EDS. The synthetic route used for obtaining the ZSM-5 zeolite with flower-like morphology is a simple strategy for preparing hierarchical ZSM-5 forms targeting enhanced diffusivity and accessibility of catalytically active sites. T2 - Microporous and Mesoporous Materials T1 - Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study SP - 111534 VL - 329 DO - 10.1016/j.micromeso.2021.111534 UR - https://hdl.handle.net/21.15107/rcub_dais_13631 ER -
@article{ author = "Bosnar, Sanja and Rac, Vladislav and Stošić, Dušan and Travert, Arnaud and Postole, Georgeta and Auroux, Aline and Škapin, Srečo Davor and Damjanović-Vasilić, Ljiljana S. and Bronić, Josip and Du, Xuesen and Marković, Smilja and Pavlović, Vladimir B. and Rakić, Vesna M.", year = "2022", abstract = "Dual templating approach, using hexadecyltrimethylammonium bromide (CTAB), was employed in an attempt to synthesize hierarchical ZSM-5 zeolite. Amount of mesoporogen and the duration of aging of the precursor were varied. Majority of the synthesis routes resulted in phase separation, yielding separate ZSM-5 and amorphous mesoporous material. The relative amounts of the two phases were dependent on the CTAB amount ratio and also significantly on the duration of precursor aging before CTAB addition. One particular combination of the two factors led to the formation of a homogeneous hierarchical form of ZSM-5 with leafy morphology, consisting of intergrown thin crystalline sheets which formed flower-like structures. The hierarchical ZSM-5 possessed significant microporous (≈95 m2/g) and highly developed mesoporous surface (≈470 m2/g), with a relatively broad distribution of mesopore sizes (<20 nm). The acidity of all samples was studied in detail. Isothermal microcalorimetry/volumetry of ammonia adsorption provided quantitative data on the number and distribution of strength of acidic sites. In situ FTIR of pyridine and collidine adsorption was used to quantify Brønsted and Lewis acid sites, and to provide information on their location - in the micropores or mesopores/external surface. The hierarchical ZSM-5 possessed both Lewis and Brønsted acidity, with Brønsted sites located mainly in the micropores. All samples were fully characterized using XRD, low temperature nitrogen adsorption, FESEM and EDS. The synthetic route used for obtaining the ZSM-5 zeolite with flower-like morphology is a simple strategy for preparing hierarchical ZSM-5 forms targeting enhanced diffusivity and accessibility of catalytically active sites.", journal = "Microporous and Mesoporous Materials", title = "Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study", pages = "111534", volume = "329", doi = "10.1016/j.micromeso.2021.111534", url = "https://hdl.handle.net/21.15107/rcub_dais_13631" }
Bosnar, S., Rac, V., Stošić, D., Travert, A., Postole, G., Auroux, A., Škapin, S. D., Damjanović-Vasilić, L. S., Bronić, J., Du, X., Marković, S., Pavlović, V. B.,& Rakić, V. M.. (2022). Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study. in Microporous and Mesoporous Materials, 329, 111534. https://doi.org/10.1016/j.micromeso.2021.111534 https://hdl.handle.net/21.15107/rcub_dais_13631
Bosnar S, Rac V, Stošić D, Travert A, Postole G, Auroux A, Škapin SD, Damjanović-Vasilić LS, Bronić J, Du X, Marković S, Pavlović VB, Rakić VM. Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study. in Microporous and Mesoporous Materials. 2022;329:111534. doi:10.1016/j.micromeso.2021.111534 https://hdl.handle.net/21.15107/rcub_dais_13631 .
Bosnar, Sanja, Rac, Vladislav, Stošić, Dušan, Travert, Arnaud, Postole, Georgeta, Auroux, Aline, Škapin, Srečo Davor, Damjanović-Vasilić, Ljiljana S., Bronić, Josip, Du, Xuesen, Marković, Smilja, Pavlović, Vladimir B., Rakić, Vesna M., "Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study" in Microporous and Mesoporous Materials, 329 (2022):111534, https://doi.org/10.1016/j.micromeso.2021.111534 ., https://hdl.handle.net/21.15107/rcub_dais_13631 .