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Crystallographic Information for the article: Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm, Royal Society of Chemistry (RSC), 23(27), 4799-4815. https://doi.org/10.1039/D1CE00394A
dc.creator | Ristić, Predrag | |
dc.creator | Filipović, Nenad | |
dc.creator | Blagojević, Vladimir A. | |
dc.creator | Ćirković, Jovana | |
dc.creator | Holló, Berta Barta | |
dc.creator | Đokić, Veljko R. | |
dc.creator | Donnard, Morgan | |
dc.creator | Gulea, Mihaela | |
dc.creator | Marjanović, Ivana | |
dc.creator | Klisurić, Olivera R. | |
dc.creator | Todorović, Tamara R. | |
dc.date.accessioned | 2021-08-04T12:06:29Z | |
dc.date.available | 2021-08-04T12:06:29Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 1466-8033 | |
dc.identifier.uri | https://dais.sanu.ac.rs/123456789/11761 | |
dc.description.abstract | Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume. | |
dc.format.mimetype | application/pdf | |
dc.publisher | Royal Society of Chemistry (RSC) | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200168/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200116/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200175/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200125/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS// | |
dc.relation | Matériaux hiérarchiques et fonctionnels pour la santé, l’environnement et l’énergie (HiFunMat) | |
dc.relation.isreferencedby | https://hdl.handle.net/21.15107/rcub_dais_11753 | |
dc.relation.isreferencedby | https://hdl.handle.net/21.15107/rcub_dais_11757 | |
dc.relation.isreferencedby | https://hdl.handle.net/21.15107/rcub_dais_11759 | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | CrystEngComm | en |
dc.subject | coordination polymers | |
dc.subject | thiomorpholine-4-carbonitrile | |
dc.subject | piperazine-1,4-dicarbonitrile | |
dc.subject | photocatalysis | |
dc.subject | thermal behavior | |
dc.subject | intermolecular interactions | |
dc.subject | silver | |
dc.title | Crystallographic Information for the article: Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm, Royal Society of Chemistry (RSC), 23(27), 4799-4815. https://doi.org/10.1039/D1CE00394A | en |
dc.type | dataset | en |
dc.rights.license | BY | |
dcterms.abstract | Благојевић, Владимир A.; Тодоровић, Тамара Р.; Гулеа, Михаела; Доннард, Морган; Ђокић, Вељко Р.; Холлó, Берта Барта; Ћирковић, Јована; Филиповић, Ненад; Ристић, Предраг; Марјановић, Ивана; Клисурић, Оливера Р.; | |
dc.citation.volume | 23 | |
dc.citation.issue | 27 | |
dc.description.other | Related to the peer-reviewed manuscript: [https://hdl.handle.net/21.15107/rcub_dais_11757] | |
dc.description.other | Related to supplementary information: [https://hdl.handle.net/21.15107/rcub_dais_11759] | |
dc.description.other | Related to the article: [https://hdl.handle.net/21.15107/rcub_dais_11753] | |
dc.description.other | Software is freely available for graphical display of the structure(s) in this CIF, see [https://www.iucr.org/resources/cif/software] | |
dc.type.version | publishedVersion | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_dais_11761 |