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Synthesis, processing and applications of nanostructured multifunctional materials with defined properties

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info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45019/RS//

Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (en)
Синтеза, развој технологија добијања и примена наноструктурних мултифункционалних материјала дефинисаних својстава (sr)
Sinteza, razvoj tehnologija dobijanja i primena nanostrukturnih multifunkcionalnih materijala definisanih svojstava (sr_RS)

Publications

Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Bjelajac, Anđelika; Petrović, Rada; Vujančević, Jelena; Veltruska, Katerina; Matolin, Vladimir; Siketić, Zdravko; Provatas, George; Jakšić, Milko; Stan, George E.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Elsevier, 2020)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Vujančević, Jelena
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketić, Zdravko
AU  - Provatas, George
AU  - Jakšić, Milko
AU  - Stan, George E.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://www.sciencedirect.com/science/article/pii/S0022369719328525
UR  - https://dais.sanu.ac.rs/123456789/9541
AB  - We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F–SnO2 (FTO) glass. Annealing was carried out at 500 °C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO2 nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes’ surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.
PB  - Elsevier
T2  - Journal of Physics and Chemistry of Solids
T1  - Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye
SP  - 109609
VL  - 147
DO  - 10.1016/j.jpcs.2020.109609
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Vujančević, Jelena and Veltruska, Katerina and Matolin, Vladimir and Siketić, Zdravko and Provatas, George and Jakšić, Milko and Stan, George E. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2020",
url = "http://www.sciencedirect.com/science/article/pii/S0022369719328525, https://dais.sanu.ac.rs/123456789/9541",
abstract = "We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F–SnO2 (FTO) glass. Annealing was carried out at 500 °C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO2 nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes’ surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.",
publisher = "Elsevier",
journal = "Journal of Physics and Chemistry of Solids",
title = "Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye",
pages = "109609",
volume = "147",
doi = "10.1016/j.jpcs.2020.109609"
}
1
1

Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Bjelajac, Anđelika; Petrović, Rada; Vujančević, Jelena; Veltruska, Katerina; Matolin, Vladimir; Siketić, Zdravko; Provatas, George; Jakšić, Milko; Stan, George E.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Elsevier, 2020)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Vujančević, Jelena
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketić, Zdravko
AU  - Provatas, George
AU  - Jakšić, Milko
AU  - Stan, George E.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://www.sciencedirect.com/science/article/pii/S0022369719328525
UR  - https://dais.sanu.ac.rs/123456789/9540
AB  - We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F–SnO2 (FTO) glass. Annealing was carried out at 500 °C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO2 nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes’ surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.
PB  - Elsevier
T2  - Journal of Physics and Chemistry of Solids
T1  - Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye
SP  - 109609
VL  - 147
DO  - 10.1016/j.jpcs.2020.109609
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Vujančević, Jelena and Veltruska, Katerina and Matolin, Vladimir and Siketić, Zdravko and Provatas, George and Jakšić, Milko and Stan, George E. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2020",
url = "http://www.sciencedirect.com/science/article/pii/S0022369719328525, https://dais.sanu.ac.rs/123456789/9540",
abstract = "We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F–SnO2 (FTO) glass. Annealing was carried out at 500 °C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO2 nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes’ surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.",
publisher = "Elsevier",
journal = "Journal of Physics and Chemistry of Solids",
title = "Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye",
pages = "109609",
volume = "147",
doi = "10.1016/j.jpcs.2020.109609"
}
1
1

Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping

Vujančević, Jelena; Andričević, Pavao; Bjelajac, Anđelika; Đokić, Veljko; Popović, Maja; Rakočević, Zlatko; Horváth, Endre; Kollár, Márton; Náfrádi, Bálint; Schiller, Andreas; Domanski, Konrad; Forró, Laszlo; Pavlović, Vera P.; Janaćković, Đorđe

(Elsevier, 2019)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Popović, Maja
AU  - Rakočević, Zlatko
AU  - Horváth, Endre
AU  - Kollár, Márton
AU  - Náfrádi, Bálint
AU  - Schiller, Andreas
AU  - Domanski, Konrad
AU  - Forró, Laszlo
AU  - Pavlović, Vera P.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/5084
AB  - Highly ordered, anodically grown TiO 2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping (≤2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 ± 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO 2 /CH 3 NH 3 PbI 3 single crystals. The N-TiO 2 /perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures. © 2019
PB  - Elsevier
T2  - Ceramics International
T1  - Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping
SP  - 10013
EP  - 10020
VL  - 45
IS  - 8
DO  - 10.1016/j.ceramint.2019.02.045
ER  - 
@article{
author = "Vujančević, Jelena and Andričević, Pavao and Bjelajac, Anđelika and Đokić, Veljko and Popović, Maja and Rakočević, Zlatko and Horváth, Endre and Kollár, Márton and Náfrádi, Bálint and Schiller, Andreas and Domanski, Konrad and Forró, Laszlo and Pavlović, Vera P. and Janaćković, Đorđe",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/5084",
abstract = "Highly ordered, anodically grown TiO 2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping (≤2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 ± 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO 2 /CH 3 NH 3 PbI 3 single crystals. The N-TiO 2 /perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures. © 2019",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping",
pages = "10013-10020",
volume = "45",
number = "8",
doi = "10.1016/j.ceramint.2019.02.045"
}
2
2
1

Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping

Vujančević, Jelena; Andričević, Pavao; Bjelajac, Anđelika; Đokić, Veljko; Popović, Maja; Rakočević, Zlatko; Horváth, Endre; Kollár, Márton; Náfrádi, Bálint; Schiller, Andreas; Domanski, Konrad; Forró, Laszlo; Pavlović, Vera P.; Janaćković, Đorđe

(Elsevier, 2019)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Popović, Maja
AU  - Rakočević, Zlatko
AU  - Horváth, Endre
AU  - Kollár, Márton
AU  - Náfrádi, Bálint
AU  - Schiller, Andreas
AU  - Domanski, Konrad
AU  - Forró, Laszlo
AU  - Pavlović, Vera P.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/5765
AB  - Highly ordered, anodically grown TiO 2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping (≤2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 ± 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO 2 /CH 3 NH 3 PbI 3 single crystals. The N-TiO 2 /perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures. © 2019
PB  - Elsevier
T2  - Ceramics International
T1  - Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping
SP  - 10013
EP  - 10020
VL  - 45
IS  - 8
DO  - 10.1016/j.ceramint.2019.02.045
ER  - 
@article{
author = "Vujančević, Jelena and Andričević, Pavao and Bjelajac, Anđelika and Đokić, Veljko and Popović, Maja and Rakočević, Zlatko and Horváth, Endre and Kollár, Márton and Náfrádi, Bálint and Schiller, Andreas and Domanski, Konrad and Forró, Laszlo and Pavlović, Vera P. and Janaćković, Đorđe",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/5765",
abstract = "Highly ordered, anodically grown TiO 2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping (≤2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 ± 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO 2 /CH 3 NH 3 PbI 3 single crystals. The N-TiO 2 /perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures. © 2019",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping",
pages = "10013-10020",
volume = "45",
number = "8",
doi = "10.1016/j.ceramint.2019.02.045"
}
2
2
1

Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045

Vujančević, Jelena; Andričević, Pavao; Bjelajac, Anđelika; Đokić, Veljko; Popović, Maja; Rakočević, Zlatko; Horváth, Endre; Kollár, Márton; Náfrádi, Bálint; Schiller, Andreas; Domanski, Konrad; Forró, Laszlo; Pavlović, Vera P.; Janaćković, Đorđe

(2019)

@misc{
author = "Vujančević, Jelena and Andričević, Pavao and Bjelajac, Anđelika and Đokić, Veljko and Popović, Maja and Rakočević, Zlatko and Horváth, Endre and Kollár, Márton and Náfrádi, Bálint and Schiller, Andreas and Domanski, Konrad and Forró, Laszlo and Pavlović, Vera P. and Janaćković, Đorđe",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/5969",
journal = "Ceramics International",
title = "Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045"
}

Mg/Cu co-substituted hydroxyapatite – Biocompatibility, mechanical properties and antimicrobial activity

Veljović, Đorđe; Matić, Tamara; Stamenić, Tanja; Kojić, Vesna; Dimitrijević Branković, Suzana; Lukić, Miodrag J.; Jevtić, Sanja; Radovanović, Željko; Petrović, Rada; Janaćković, Đorđe

(Elsevier, 2019)

TY  - JOUR
AU  - Veljović, Đorđe
AU  - Matić, Tamara
AU  - Stamenić, Tanja
AU  - Kojić, Vesna
AU  - Dimitrijević Branković, Suzana
AU  - Lukić, Miodrag J.
AU  - Jevtić, Sanja
AU  - Radovanović, Željko
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219320413
UR  - http://dais.sanu.ac.rs/123456789/6504
AB  - The aim of this study was to improve the mechanical properties and to optimize antimicrobial activity of hydroxyapatite (HAP) by simultaneous doping with Mg and Cu ions in order to obtain material that would be able to assist in the bone/tooth healing process, prevent post-implementation infections and provide satisfying values of hardness and fracture toughness for biomedical application. Ion doping was done during the hydrothermal synthesis of HAP powders, whereby the content of Mg ions in the starting solution was varied between 1-20 mol. % with regard to Ca ions, while the amount of Cu ions was kept constant at 0.4 mol. %. The green compacts were sintered for 2 h at temperatures ranging 750–1200 °C depending on the Mg content, chosen in agreement with dilatometry results. Presence of Mg ions was found to favour transition from HAP to β−tricalcium phosphate phase (β−TCP), which enabled formation of biphasic HAP/β−TCP and pure β−TCP phase at 160 °C during hydrothermal synthesis. In vitro investigation of antimicrobial activity against Escherichia coli, Staphylococcus aureus and Enterococcus faecalis showed satisfactory antimicrobial activity. MTT assay performed on MRC-5 and L929 cell lines showed excellent cytocompatibility and cell proliferation. Maximum hardness by Vickers and fracture toughness values, 4.96 GPa and 1.75 MPa m1/2 respectively, were obtained upon addition of 5 mol. % Mg, as a consequence of the lowest grain size and porosity, as well as the highest densification rate. This is, to the best of our knowledge, the highest fracture toughness for HAP or β-TCP ceramics reported thus far.
PB  - Elsevier
T2  - Ceramics International
T1  - Mg/Cu co-substituted hydroxyapatite – Biocompatibility, mechanical properties and antimicrobial activity
SP  - 22029
SP  - 22039
VL  - 45
IS  - 17, Part A
DO  - 10.1016/j.ceramint.2019.07.219
ER  - 
@article{
author = "Veljović, Đorđe and Matić, Tamara and Stamenić, Tanja and Kojić, Vesna and Dimitrijević Branković, Suzana and Lukić, Miodrag J. and Jevtić, Sanja and Radovanović, Željko and Petrović, Rada and Janaćković, Đorđe",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884219320413, http://dais.sanu.ac.rs/123456789/6504",
abstract = "The aim of this study was to improve the mechanical properties and to optimize antimicrobial activity of hydroxyapatite (HAP) by simultaneous doping with Mg and Cu ions in order to obtain material that would be able to assist in the bone/tooth healing process, prevent post-implementation infections and provide satisfying values of hardness and fracture toughness for biomedical application. Ion doping was done during the hydrothermal synthesis of HAP powders, whereby the content of Mg ions in the starting solution was varied between 1-20 mol. % with regard to Ca ions, while the amount of Cu ions was kept constant at 0.4 mol. %. The green compacts were sintered for 2 h at temperatures ranging 750–1200 °C depending on the Mg content, chosen in agreement with dilatometry results. Presence of Mg ions was found to favour transition from HAP to β−tricalcium phosphate phase (β−TCP), which enabled formation of biphasic HAP/β−TCP and pure β−TCP phase at 160 °C during hydrothermal synthesis. In vitro investigation of antimicrobial activity against Escherichia coli, Staphylococcus aureus and Enterococcus faecalis showed satisfactory antimicrobial activity. MTT assay performed on MRC-5 and L929 cell lines showed excellent cytocompatibility and cell proliferation. Maximum hardness by Vickers and fracture toughness values, 4.96 GPa and 1.75 MPa m1/2 respectively, were obtained upon addition of 5 mol. % Mg, as a consequence of the lowest grain size and porosity, as well as the highest densification rate. This is, to the best of our knowledge, the highest fracture toughness for HAP or β-TCP ceramics reported thus far.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Mg/Cu co-substituted hydroxyapatite – Biocompatibility, mechanical properties and antimicrobial activity",
pages = "22029-22039",
volume = "45",
number = "17, Part A",
doi = "10.1016/j.ceramint.2019.07.219"
}
8
6
8

Mg/Cu co-substituted hydroxyapatite – Biocompatibility, mechanical properties and antimicrobial activity

Veljović, Đorđe; Matić, Tamara; Stamenić, Tanja; Kojić, Vesna; Dimitrijević Branković, Suzana; Lukić, Miodrag J.; Jevtić, Sanja; Radovanović, Željko; Petrović, Rada; Janaćković, Đorđe

(Elsevier, 2019)

TY  - JOUR
AU  - Veljović, Đorđe
AU  - Matić, Tamara
AU  - Stamenić, Tanja
AU  - Kojić, Vesna
AU  - Dimitrijević Branković, Suzana
AU  - Lukić, Miodrag J.
AU  - Jevtić, Sanja
AU  - Radovanović, Željko
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219320413
UR  - http://dais.sanu.ac.rs/123456789/6948
AB  - The aim of this study was to improve the mechanical properties and to optimize antimicrobial activity of hydroxyapatite (HAP) by simultaneous doping with Mg and Cu ions in order to obtain material that would be able to assist in the bone/tooth healing process, prevent post-implementation infections and provide satisfying values of hardness and fracture toughness for biomedical application. Ion doping was done during the hydrothermal synthesis of HAP powders, whereby the content of Mg ions in the starting solution was varied between 1-20 mol. % with regard to Ca ions, while the amount of Cu ions was kept constant at 0.4 mol. %. The green compacts were sintered for 2 h at temperatures ranging 750–1200 °C depending on the Mg content, chosen in agreement with dilatometry results. Presence of Mg ions was found to favour transition from HAP to β−tricalcium phosphate phase (β−TCP), which enabled formation of biphasic HAP/β−TCP and pure β−TCP phase at 160 °C during hydrothermal synthesis. In vitro investigation of antimicrobial activity against Escherichia coli, Staphylococcus aureus and Enterococcus faecalis showed satisfactory antimicrobial activity. MTT assay performed on MRC-5 and L929 cell lines showed excellent cytocompatibility and cell proliferation. Maximum hardness by Vickers and fracture toughness values, 4.96 GPa and 1.75 MPa m1/2 respectively, were obtained upon addition of 5 mol. % Mg, as a consequence of the lowest grain size and porosity, as well as the highest densification rate. This is, to the best of our knowledge, the highest fracture toughness for HAP or β-TCP ceramics reported thus far.
PB  - Elsevier
T2  - Ceramics International
T1  - Mg/Cu co-substituted hydroxyapatite – Biocompatibility, mechanical properties and antimicrobial activity
SP  - 22029
SP  - 22039
VL  - 45
IS  - 17, Part A
DO  - 10.1016/j.ceramint.2019.07.219
ER  - 
@article{
author = "Veljović, Đorđe and Matić, Tamara and Stamenić, Tanja and Kojić, Vesna and Dimitrijević Branković, Suzana and Lukić, Miodrag J. and Jevtić, Sanja and Radovanović, Željko and Petrović, Rada and Janaćković, Đorđe",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884219320413, http://dais.sanu.ac.rs/123456789/6948",
abstract = "The aim of this study was to improve the mechanical properties and to optimize antimicrobial activity of hydroxyapatite (HAP) by simultaneous doping with Mg and Cu ions in order to obtain material that would be able to assist in the bone/tooth healing process, prevent post-implementation infections and provide satisfying values of hardness and fracture toughness for biomedical application. Ion doping was done during the hydrothermal synthesis of HAP powders, whereby the content of Mg ions in the starting solution was varied between 1-20 mol. % with regard to Ca ions, while the amount of Cu ions was kept constant at 0.4 mol. %. The green compacts were sintered for 2 h at temperatures ranging 750–1200 °C depending on the Mg content, chosen in agreement with dilatometry results. Presence of Mg ions was found to favour transition from HAP to β−tricalcium phosphate phase (β−TCP), which enabled formation of biphasic HAP/β−TCP and pure β−TCP phase at 160 °C during hydrothermal synthesis. In vitro investigation of antimicrobial activity against Escherichia coli, Staphylococcus aureus and Enterococcus faecalis showed satisfactory antimicrobial activity. MTT assay performed on MRC-5 and L929 cell lines showed excellent cytocompatibility and cell proliferation. Maximum hardness by Vickers and fracture toughness values, 4.96 GPa and 1.75 MPa m1/2 respectively, were obtained upon addition of 5 mol. % Mg, as a consequence of the lowest grain size and porosity, as well as the highest densification rate. This is, to the best of our knowledge, the highest fracture toughness for HAP or β-TCP ceramics reported thus far.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Mg/Cu co-substituted hydroxyapatite – Biocompatibility, mechanical properties and antimicrobial activity",
pages = "22029-22039",
volume = "45",
number = "17, Part A",
doi = "10.1016/j.ceramint.2019.07.219"
}
8
6
8

ToF-ERDA/RBS analysis of annealed TiO2 nanotubes grown onto FTO glass

Vujančević, Jelena; Bjelajac, Anđelika; Provatas, Georgios; Siketić, Zdravko; Jakšić, Milko; Pavlović, Vladimir B.; Janaćković, Đorđe

(Novi Sad : Faculty of Technology, 2019)

TY  - CONF
AU  - Vujančević, Jelena
AU  - Bjelajac, Anđelika
AU  - Provatas, Georgios
AU  - Siketić, Zdravko
AU  - Jakšić, Milko
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6985
AB  - Different semiconductors have been studied as photoanode material for solar cells. Among them, TiO2 has been shown to be the best material due to its chemical stability and good charge transport capability. It is usually deposited onto FTO glass (F-SnO2), and then heated at high temperature in order to obtain inter-crystalline electric contact for improving electron conductivity. The focus of this research was chemical analysis of the TiO2 nanotubes (NTs) obtained by anodization of titanium film on FTO glass using NH4F in ethylene glycol electrolyte. There are only few studies suggesting that the electrolyte is a source of N dopant in TiO2, but also Sn diffusion from FTO support was reported. This study aims to show the chemical distribution of elements of interest along the nanotubes depth. For that purpose the time-of-flight elastic recoil detection analysis (ToF-ERDA) and Rutherford backscattering (RBS) methods were used as complementary techniques for chemical analysis of both light, such is N, and heavy elements, such is Sn. The TiO2 NTs films were annealed at different temperatures (450– 630 °C) and the impact of the heating temperature on the chemical distribution was followed.
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad
T1  - ToF-ERDA/RBS analysis of annealed TiO2 nanotubes grown onto FTO glass
SP  - 132
EP  - 132
ER  - 
@conference{
author = "Vujančević, Jelena and Bjelajac, Anđelika and Provatas, Georgios and Siketić, Zdravko and Jakšić, Milko and Pavlović, Vladimir B. and Janaćković, Đorđe",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/6985",
abstract = "Different semiconductors have been studied as photoanode material for solar cells. Among them, TiO2 has been shown to be the best material due to its chemical stability and good charge transport capability. It is usually deposited onto FTO glass (F-SnO2), and then heated at high temperature in order to obtain inter-crystalline electric contact for improving electron conductivity. The focus of this research was chemical analysis of the TiO2 nanotubes (NTs) obtained by anodization of titanium film on FTO glass using NH4F in ethylene glycol electrolyte. There are only few studies suggesting that the electrolyte is a source of N dopant in TiO2, but also Sn diffusion from FTO support was reported. This study aims to show the chemical distribution of elements of interest along the nanotubes depth. For that purpose the time-of-flight elastic recoil detection analysis (ToF-ERDA) and Rutherford backscattering (RBS) methods were used as complementary techniques for chemical analysis of both light, such is N, and heavy elements, such is Sn. The TiO2 NTs films were annealed at different temperatures (450– 630 °C) and the impact of the heating temperature on the chemical distribution was followed.",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 13th Conference for Young Scientists in Ceramics (CYSC-2017), October 16-19, 2019, Novi Sad",
title = "ToF-ERDA/RBS analysis of annealed TiO2 nanotubes grown onto FTO glass",
pages = "132-132"
}

Enhanced sorption of Cu2+ from sulfate solutions onto modified electric arc furnace slag

Nikolić, Irena; Marković, Smilja; Veselinović, Ljiljana; Radmilović, Vuk V.; Janković Častvan, Ivona; Radmilović, Velimir R.

(Elsevier, 2019)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana
AU  - Radmilović, Vuk V.
AU  - Janković Častvan, Ivona
AU  - Radmilović, Velimir R.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0167577X18315908
UR  - http://dais.sanu.ac.rs/123456789/4603
AB  - Pristine electric arc furnace slag (EAFS) as well as EAFS modified by alkali activation i.e. alkali activated slag (AAS) have found a novel application as adsorbents used in Cu2+ removal from sulfate solutions. The adsorption tests were carried in batch conditions and results have shown that alkali activation of EAFS enhances the Cu2+ adsorption. The adsorption process was found to follow a pseudo second-order kinetic model and occurs via formation of posnjakite (Cu4(SO4)(OH)6·H2O) on the surface of both, EAFS and AAS. Enhanced adsorption properties of AAS, compared to EAFS, are attributed to a more porous structure, larger specific surface area and an increased number of surface groups involved in the binding of Cu2+.
PB  - Elsevier
T2  - Materials Letters
T1  - Enhanced sorption of Cu2+ from sulfate solutions onto modified electric arc furnace slag
SP  - 184
EP  - 188
VL  - 235
DO  - 10.1016/j.matlet.2018.10.027
ER  - 
@article{
author = "Nikolić, Irena and Marković, Smilja and Veselinović, Ljiljana and Radmilović, Vuk V. and Janković Častvan, Ivona and Radmilović, Velimir R.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0167577X18315908, http://dais.sanu.ac.rs/123456789/4603",
abstract = "Pristine electric arc furnace slag (EAFS) as well as EAFS modified by alkali activation i.e. alkali activated slag (AAS) have found a novel application as adsorbents used in Cu2+ removal from sulfate solutions. The adsorption tests were carried in batch conditions and results have shown that alkali activation of EAFS enhances the Cu2+ adsorption. The adsorption process was found to follow a pseudo second-order kinetic model and occurs via formation of posnjakite (Cu4(SO4)(OH)6·H2O) on the surface of both, EAFS and AAS. Enhanced adsorption properties of AAS, compared to EAFS, are attributed to a more porous structure, larger specific surface area and an increased number of surface groups involved in the binding of Cu2+.",
publisher = "Elsevier",
journal = "Materials Letters",
title = "Enhanced sorption of Cu2+ from sulfate solutions onto modified electric arc furnace slag",
pages = "184-188",
volume = "235",
doi = "10.1016/j.matlet.2018.10.027"
}
1
1

A novel type of building material derived from the by-products of steel making industry

Nikolić, Irena; Milašević, Ivana; Cupara, Nevena; Ivanović, Ljubica; Đurović, Dijana; Marković, Smilja; Veselinović, Ljiljana; Radmilović, Vuk V.; Radmilović, Velimir R.

(Belgrade : Materials Research Society of Serbia, 2019)

TY  - CONF
AU  - Nikolić, Irena
AU  - Milašević, Ivana
AU  - Cupara, Nevena
AU  - Ivanović, Ljubica
AU  - Đurović, Dijana
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana
AU  - Radmilović, Vuk V.
AU  - Radmilović, Velimir R.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6678
AB  - Electric arc furnace slag (EAFS) and electric arc furnace dust (EAFD) are the waste materials generated during the iron and steel scrap remelting in electric arc furnace. EAFS is non-hazardous material which has found its application in different field of civil engineering. On the other hand, EAFD is classified as hazardous matreials due to the presence of heavy metals (Zn, Pb, Cu Cr and Cd) and their potential leaching into environment. Stabilization/solidification (S/S) of toxic waste is a widely investigated as simply method for production of stable product. Cement binder was mainly used for this purpose but important shift in the use of different waste materials as a cement replacement was observed. The aim of this study was to investigate the possibility of S/S of heavy metals from EAFD using the alkali activated binders based on EAFS. The alkali activated slag with a different content of EAFS was synthesised and characterized using the SEM/EDS, XRDP, FTIR. The binding of Zn into the reaction product of slag alkali activation was founded. The immobilization efficacy was evaluated using TCLP Method No. 1311 (USEPA) and EN 12457-2 (EULFD) leaching tests.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
T1  - A novel type of building material derived from the by-products of steel making industry
SP  - 84
VL  - 84
ER  - 
@conference{
author = "Nikolić, Irena and Milašević, Ivana and Cupara, Nevena and Ivanović, Ljubica and Đurović, Dijana and Marković, Smilja and Veselinović, Ljiljana and Radmilović, Vuk V. and Radmilović, Velimir R.",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/6678",
abstract = "Electric arc furnace slag (EAFS) and electric arc furnace dust (EAFD) are the waste materials generated during the iron and steel scrap remelting in electric arc furnace. EAFS is non-hazardous material which has found its application in different field of civil engineering. On the other hand, EAFD is classified as hazardous matreials due to the presence of heavy metals (Zn, Pb, Cu Cr and Cd) and their potential leaching into environment. Stabilization/solidification (S/S) of toxic waste is a widely investigated as simply method for production of stable product. Cement binder was mainly used for this purpose but important shift in the use of different waste materials as a cement replacement was observed. The aim of this study was to investigate the possibility of S/S of heavy metals from EAFD using the alkali activated binders based on EAFS. The alkali activated slag with a different content of EAFS was synthesised and characterized using the SEM/EDS, XRDP, FTIR. The binding of Zn into the reaction product of slag alkali activation was founded. The immobilization efficacy was evaluated using TCLP Method No. 1311 (USEPA) and EN 12457-2 (EULFD) leaching tests.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019",
title = "A novel type of building material derived from the by-products of steel making industry",
pages = "84",
volume = "84"
}

The effect of ball milling on properties of sintered manganese-doped alumina

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Mitrić, Miodrag; Balać, Igor; Đorđević, Antonije; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Mitrić, Miodrag
AU  - Balać, Igor
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0921883119302596
UR  - http://dais.sanu.ac.rs/123456789/6951
AB  - Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - The effect of ball milling on properties of sintered manganese-doped alumina
SP  - 2533
EP  - 2540
VL  - 30
IS  - 11
DO  - 10.1016/j.apt.2019.07.033
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Mitrić, Miodrag and Balać, Igor and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0921883119302596, http://dais.sanu.ac.rs/123456789/6951",
abstract = "Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "The effect of ball milling on properties of sintered manganese-doped alumina",
pages = "2533-2540",
volume = "30",
number = "11",
doi = "10.1016/j.apt.2019.07.033"
}
2
2

The effect of ball milling on properties of sintered manganese-doped alumina

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Mitrić, Miodrag; Balać, Igor; Đorđević, Antonije; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Mitrić, Miodrag
AU  - Balać, Igor
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0921883119302596
UR  - http://dais.sanu.ac.rs/123456789/7027
AB  - Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - The effect of ball milling on properties of sintered manganese-doped alumina
SP  - 2533
EP  - 2540
VL  - 30
IS  - 11
DO  - 10.1016/j.apt.2019.07.033
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Mitrić, Miodrag and Balać, Igor and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0921883119302596, http://dais.sanu.ac.rs/123456789/7027",
abstract = "Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "The effect of ball milling on properties of sintered manganese-doped alumina",
pages = "2533-2540",
volume = "30",
number = "11",
doi = "10.1016/j.apt.2019.07.033"
}
2
2

Supporting material for the article: Georgijević, R., Vujković, M., Gutić, S., Aliefendić, M., Jugović, D., Mitrić, M., Đokić, V., Mentus, S., 2019. The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution. Journal of Alloys and Compounds 776, 475–485. https://doi.org/10.1016/j.jallcom.2018.10.246

Georgijević, Radovan; Vujković, Milica; Gutić, Sanjin; Aliefendić, Meho; Jugović, Dragana; Mitrić, Miodrag; Đokić, Veljko; Mentus, Slavko

(2019)

@misc{
author = "Georgijević, Radovan and Vujković, Milica and Gutić, Sanjin and Aliefendić, Meho and Jugović, Dragana and Mitrić, Miodrag and Đokić, Veljko and Mentus, Slavko",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0925838818339185, http://dais.sanu.ac.rs/123456789/5975",
journal = "Journal of Alloys and Compounds",
title = "Supporting material for the article: Georgijević, R., Vujković, M., Gutić, S., Aliefendić, M., Jugović, D., Mitrić, M., Đokić, V., Mentus, S., 2019. The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution. Journal of Alloys and Compounds 776, 475–485. https://doi.org/10.1016/j.jallcom.2018.10.246"
}

The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution

Georgijević, Radovan; Vujković, Milica; Gutić, Sanjin; Aliefendić, Meho; Jugović, Dragana; Mitrić, Miodrag; Đokić, Veljko; Mentus, Slavko

(Elsevier, 2019)

TY  - JOUR
AU  - Georgijević, Radovan
AU  - Vujković, Milica
AU  - Gutić, Sanjin
AU  - Aliefendić, Meho
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Đokić, Veljko
AU  - Mentus, Slavko
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0925838818339185
UR  - http://dais.sanu.ac.rs/123456789/4569
AB  - To contribute to the knowledge on the influence of synthesis procedure on the intercalation kinetics of lithium ions into phospho-olivines, LiFePO4/C composite samples (LFPC) were synthesized in two ways, the first one in a sol-gel procedure (SG), and the other in a solid-state reaction (SS). The X-ray diffractograms (XRD) of both samples overlapped with that of pure LiFePO4, taken from the crystallographic database. Scanning electron microscopy pictures indicated the high degree of interparticle sintering, which caused a considerable agglomerate growth. The results of potentiodynamic measurements in aqueous LiNO3 solution revealed that for SS sample, three times higher initial capacity from that of SG one, (amounting to 74 mAh g−1 at 5 mV s−1). However, capacity fade on rising scan rate is much more expressed for SS sample than for SG one. We suggest that a different degree of material utilization due to the incomplete coverage of olivine particles by carbon explains this difference. The technique of separation of diffusion and capacitance currents was applied in a kinetic analysis, but it was shown to be inappropriate. We suggest the inapplicability of classic CV theory to the intercalation system accompanied by phase transition. Instead, a model of ohmic resistance determination of process kinetics was considered. LFPC-SS sample delivers three times larger capacity in LiNO3, amounting to 74 mAh g−1 at 1 mV s−1.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution
SP  - 475
EP  - 485
VL  - 776
DO  - 10.1016/j.jallcom.2018.10.246
ER  - 
@article{
author = "Georgijević, Radovan and Vujković, Milica and Gutić, Sanjin and Aliefendić, Meho and Jugović, Dragana and Mitrić, Miodrag and Đokić, Veljko and Mentus, Slavko",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0925838818339185, http://dais.sanu.ac.rs/123456789/4569",
abstract = "To contribute to the knowledge on the influence of synthesis procedure on the intercalation kinetics of lithium ions into phospho-olivines, LiFePO4/C composite samples (LFPC) were synthesized in two ways, the first one in a sol-gel procedure (SG), and the other in a solid-state reaction (SS). The X-ray diffractograms (XRD) of both samples overlapped with that of pure LiFePO4, taken from the crystallographic database. Scanning electron microscopy pictures indicated the high degree of interparticle sintering, which caused a considerable agglomerate growth. The results of potentiodynamic measurements in aqueous LiNO3 solution revealed that for SS sample, three times higher initial capacity from that of SG one, (amounting to 74 mAh g−1 at 5 mV s−1). However, capacity fade on rising scan rate is much more expressed for SS sample than for SG one. We suggest that a different degree of material utilization due to the incomplete coverage of olivine particles by carbon explains this difference. The technique of separation of diffusion and capacitance currents was applied in a kinetic analysis, but it was shown to be inappropriate. We suggest the inapplicability of classic CV theory to the intercalation system accompanied by phase transition. Instead, a model of ohmic resistance determination of process kinetics was considered. LFPC-SS sample delivers three times larger capacity in LiNO3, amounting to 74 mAh g−1 at 1 mV s−1.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution",
pages = "475-485",
volume = "776",
doi = "10.1016/j.jallcom.2018.10.246"
}
3
5
6

The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution

Georgijević, Radovan; Vujković, Milica; Gutić, Sanjin; Aliefendić, Meho; Jugović, Dragana; Mitrić, Miodrag; Đokić, Veljko; Mentus, Slavko

(Elsevier, 2019)

TY  - JOUR
AU  - Georgijević, Radovan
AU  - Vujković, Milica
AU  - Gutić, Sanjin
AU  - Aliefendić, Meho
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Đokić, Veljko
AU  - Mentus, Slavko
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0925838818339185
UR  - http://dais.sanu.ac.rs/123456789/4568
AB  - To contribute to the knowledge on the influence of synthesis procedure on the intercalation kinetics of lithium ions into phospho-olivines, LiFePO4/C composite samples (LFPC) were synthesized in two ways, the first one in a sol-gel procedure (SG), and the other in a solid-state reaction (SS). The X-ray diffractograms (XRD) of both samples overlapped with that of pure LiFePO4, taken from the crystallographic database. Scanning electron microscopy pictures indicated the high degree of interparticle sintering, which caused a considerable agglomerate growth. The results of potentiodynamic measurements in aqueous LiNO3 solution revealed that for SS sample, three times higher initial capacity from that of SG one, (amounting to 74 mAh g−1 at 5 mV s−1). However, capacity fade on rising scan rate is much more expressed for SS sample than for SG one. We suggest that a different degree of material utilization due to the incomplete coverage of olivine particles by carbon explains this difference. The technique of separation of diffusion and capacitance currents was applied in a kinetic analysis, but it was shown to be inappropriate. We suggest the inapplicability of classic CV theory to the intercalation system accompanied by phase transition. Instead, a model of ohmic resistance determination of process kinetics was considered. LFPC-SS sample delivers three times larger capacity in LiNO3, amounting to 74 mAh g−1 at 1 mV s−1.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution
SP  - 475
EP  - 485
VL  - 776
DO  - 10.1016/j.jallcom.2018.10.246
ER  - 
@article{
author = "Georgijević, Radovan and Vujković, Milica and Gutić, Sanjin and Aliefendić, Meho and Jugović, Dragana and Mitrić, Miodrag and Đokić, Veljko and Mentus, Slavko",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0925838818339185, http://dais.sanu.ac.rs/123456789/4568",
abstract = "To contribute to the knowledge on the influence of synthesis procedure on the intercalation kinetics of lithium ions into phospho-olivines, LiFePO4/C composite samples (LFPC) were synthesized in two ways, the first one in a sol-gel procedure (SG), and the other in a solid-state reaction (SS). The X-ray diffractograms (XRD) of both samples overlapped with that of pure LiFePO4, taken from the crystallographic database. Scanning electron microscopy pictures indicated the high degree of interparticle sintering, which caused a considerable agglomerate growth. The results of potentiodynamic measurements in aqueous LiNO3 solution revealed that for SS sample, three times higher initial capacity from that of SG one, (amounting to 74 mAh g−1 at 5 mV s−1). However, capacity fade on rising scan rate is much more expressed for SS sample than for SG one. We suggest that a different degree of material utilization due to the incomplete coverage of olivine particles by carbon explains this difference. The technique of separation of diffusion and capacitance currents was applied in a kinetic analysis, but it was shown to be inappropriate. We suggest the inapplicability of classic CV theory to the intercalation system accompanied by phase transition. Instead, a model of ohmic resistance determination of process kinetics was considered. LFPC-SS sample delivers three times larger capacity in LiNO3, amounting to 74 mAh g−1 at 1 mV s−1.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "The influence of synthesis conditions on the redox behaviour of LiFePO4 in aqueous solution",
pages = "475-485",
volume = "776",
doi = "10.1016/j.jallcom.2018.10.246"
}
3
5
6

Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size

Taleb, Khaled; Markovski, Jasmina; Veličković, Zlate; Rusmirović, Jelena; Rančić, Milica P.; Pavlović, Vladimir B.; Marinković, Aleksandar

(Elsevier, 2019)

TY  - JOUR
AU  - Taleb, Khaled
AU  - Markovski, Jasmina
AU  - Veličković, Zlate
AU  - Rusmirović, Jelena
AU  - Rančić, Milica P.
AU  - Pavlović, Vladimir B.
AU  - Marinković, Aleksandar
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/16007
AB  - Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g−1) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg−1 min−1). Lower capacity of arsenite, As(III), removal, 68.3 mg g−1 for NC-MA/L-MG and 17.8 mg g−1 for MC-O/L-MG, were obtained. Calculated activation energies, 13.28 and 10.87 kJ mol−1 for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption.
PB  - Elsevier
T2  - Arabian Journal of Chemistry
T1  - Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size
SP  - 4675
EP  - 4693
VL  - (2016)
VL  - 12
IS  - 8
DO  - 10.1016/j.arabjc.2016.08.006
ER  - 
@article{
author = "Taleb, Khaled and Markovski, Jasmina and Veličković, Zlate and Rusmirović, Jelena and Rančić, Milica P. and Pavlović, Vladimir B. and Marinković, Aleksandar",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/16007",
abstract = "Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g−1) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg−1 min−1). Lower capacity of arsenite, As(III), removal, 68.3 mg g−1 for NC-MA/L-MG and 17.8 mg g−1 for MC-O/L-MG, were obtained. Calculated activation energies, 13.28 and 10.87 kJ mol−1 for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption.",
publisher = "Elsevier",
journal = "Arabian Journal of Chemistry",
title = "Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size",
pages = "4675-4693",
volume = "(2016), 12",
number = "8",
doi = "10.1016/j.arabjc.2016.08.006"
}
21
20
26

Enhanced sorption of Cu2+ from sulfate solutions onto modified electric arc furnace slag

Nikolić, Irena; Marković, Smilja; Veselinović, Ljiljana; Radmilović, Vuk V.; Janković Častvan, Ivona; Radmilović, Velimir R.

(Elsevier, 2019)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana
AU  - Radmilović, Vuk V.
AU  - Janković Častvan, Ivona
AU  - Radmilović, Velimir R.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0167577X18315908
UR  - http://dais.sanu.ac.rs/123456789/4551
AB  - Pristine electric arc furnace slag (EAFS) as well as EAFS modified by alkali activation i.e. alkali activated slag (AAS) have found a novel application as adsorbents used in Cu2+ removal from sulfate solutions. The adsorption tests were carried in batch conditions and results have shown that alkali activation of EAFS enhances the Cu2+ adsorption. The adsorption process was found to follow a pseudo second-order kinetic model and occurs via formation of posnjakite (Cu4(SO4)(OH)6·H2O) on the surface of both, EAFS and AAS. Enhanced adsorption properties of AAS, compared to EAFS, are attributed to a more porous structure, larger specific surface area and an increased number of surface groups involved in the binding of Cu2+.
PB  - Elsevier
T2  - Materials Letters
T1  - Enhanced sorption of Cu2+ from sulfate solutions onto modified electric arc furnace slag
SP  - 184
EP  - 188
VL  - 235
DO  - 10.1016/j.matlet.2018.10.027
ER  - 
@article{
author = "Nikolić, Irena and Marković, Smilja and Veselinović, Ljiljana and Radmilović, Vuk V. and Janković Častvan, Ivona and Radmilović, Velimir R.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0167577X18315908, http://dais.sanu.ac.rs/123456789/4551",
abstract = "Pristine electric arc furnace slag (EAFS) as well as EAFS modified by alkali activation i.e. alkali activated slag (AAS) have found a novel application as adsorbents used in Cu2+ removal from sulfate solutions. The adsorption tests were carried in batch conditions and results have shown that alkali activation of EAFS enhances the Cu2+ adsorption. The adsorption process was found to follow a pseudo second-order kinetic model and occurs via formation of posnjakite (Cu4(SO4)(OH)6·H2O) on the surface of both, EAFS and AAS. Enhanced adsorption properties of AAS, compared to EAFS, are attributed to a more porous structure, larger specific surface area and an increased number of surface groups involved in the binding of Cu2+.",
publisher = "Elsevier",
journal = "Materials Letters",
title = "Enhanced sorption of Cu2+ from sulfate solutions onto modified electric arc furnace slag",
pages = "184-188",
volume = "235",
doi = "10.1016/j.matlet.2018.10.027"
}
1
1

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, A.; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, A.
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - http://dais.sanu.ac.rs/123456789/5763
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, A. and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884219306340, http://dais.sanu.ac.rs/123456789/5763",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095"
}
6
7
5

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, A.; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, A.
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - http://dais.sanu.ac.rs/123456789/5272
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, A. and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884219306340, http://dais.sanu.ac.rs/123456789/5272",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095"
}
6
7
5

Structure and photocatalytic properties of sintered TiO2 nanotube arrays

Vujančević, Jelena; Bjelajac, Anđelika; Ćirković, Jovana; Pavlović, Vera P.; Horvath, Endre; Forró, László; Vlahović, Branislav; Mitrić, Miodrag; Janaćković, Đorđe; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2018)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Bjelajac, Anđelika
AU  - Ćirković, Jovana
AU  - Pavlović, Vera P.
AU  - Horvath, Endre
AU  - Forró, László
AU  - Vlahović, Branislav
AU  - Mitrić, Miodrag
AU  - Janaćković, Đorđe
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4528
AB  - One-dimensional (1D) TiO2 nanotubes perpendicular to the substrate were obtained by electrochemical oxidation of titanium foil in an acid electrolyte. In order to alter the crystallinity and the morphology of films the as-anodized amorphous TiO2 nanotube films were sintered at elevated temperatures. The evolution of the morphology was visualized via scanning electron microscopy (SEM), while the crystalline structure was investigated by X-ray diffraction (XRD) and Raman spectroscopy. The chemical composition was studied by X-ray photoelectron spectroscopy (XPS). The effects of crystallinity and morphology of TiO2 nanotube (NTs) films on photocatalytic degradation of methyl orange (MO) in an aqueous solution under UV light irradiation were also investigated. The TiO2 nanotubes sintered at 650°C for 30 min had the highest degree of crystallinity and exhibited the best photocatalytic activity among the studied TiO2 nanotube films. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. OI 172057 and Grant no. III 45019]
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T2  - Science of Sintering
T1  - Structure and photocatalytic properties of sintered TiO2 nanotube arrays
SP  - 39
EP  - 50
VL  - 50
IS  - 1
DO  - 10.2298/SOS1801039V
ER  - 
@article{
author = "Vujančević, Jelena and Bjelajac, Anđelika and Ćirković, Jovana and Pavlović, Vera P. and Horvath, Endre and Forró, László and Vlahović, Branislav and Mitrić, Miodrag and Janaćković, Đorđe and Pavlović, Vladimir B.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/4528",
abstract = "One-dimensional (1D) TiO2 nanotubes perpendicular to the substrate were obtained by electrochemical oxidation of titanium foil in an acid electrolyte. In order to alter the crystallinity and the morphology of films the as-anodized amorphous TiO2 nanotube films were sintered at elevated temperatures. The evolution of the morphology was visualized via scanning electron microscopy (SEM), while the crystalline structure was investigated by X-ray diffraction (XRD) and Raman spectroscopy. The chemical composition was studied by X-ray photoelectron spectroscopy (XPS). The effects of crystallinity and morphology of TiO2 nanotube (NTs) films on photocatalytic degradation of methyl orange (MO) in an aqueous solution under UV light irradiation were also investigated. The TiO2 nanotubes sintered at 650°C for 30 min had the highest degree of crystallinity and exhibited the best photocatalytic activity among the studied TiO2 nanotube films. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. OI 172057 and Grant no. III 45019]",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering, Science of Sintering",
title = "Structure and photocatalytic properties of sintered TiO2 nanotube arrays",
pages = "39-50",
volume = "50",
number = "1",
doi = "10.2298/SOS1801039V"
}
2
4
6

Synthesis and characterization of bioactive glass doped with lithium and strontium ions

Veljović, Đorđe; Radovanović, Željko; Rogan, Jelena; Dapčević, Aleksandra; Dimitrijević, Suzana; Dimitrijević Branković, Suzana; Kojić, Vesna; Janaćković, Đorđe

(Belgrade : Institute of Technical Sciences of SASA, 2018)

TY  - CONF
AU  - Veljović, Đorđe
AU  - Radovanović, Željko
AU  - Rogan, Jelena
AU  - Dapčević, Aleksandra
AU  - Dimitrijević, Suzana
AU  - Dimitrijević Branković, Suzana
AU  - Kojić, Vesna
AU  - Janaćković, Đorđe
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4718
AB  - Bioactive glasses have been used for over three decades in biomedical applications owing to high bioactivity, biocompatibility, as well as the possibility to stimulate regeneration of the bone. The aim of this work was to synthesized bioactive glasses, which contain lithium and strontium, by commercial method melting-quenching, as well as determining the properties, affected by mentioned ions. Differential thermal/thermogravimetric analysis, particle size distribution, energy-dispersive X-ray spectroscopy, inductively coupled plasma optical emission spectrometry, evaluation of the antimicrobial activity, in vitro bioactivity and biocompatibility test and scanning electron microscopy were used for characterization. The results showed that glass transition and crystallization temperatures are decreasing with addition of lithium and strontium ions. Furthermore, the samples showed high inhibition rate of Escherichia coli growth, as well as high bioactivity and biocompatibility. The crystal apatite layer, formed on the surface of synthesized glasses after seven days in simulated body fluid, differs in shape, size and interconnection of the glass particles, which depends on concentration of lithium and strontium ions.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia
T1  - Synthesis and characterization of bioactive glass doped with lithium and strontium ions
SP  - 20
EP  - 20
ER  - 
@conference{
author = "Veljović, Đorđe and Radovanović, Željko and Rogan, Jelena and Dapčević, Aleksandra and Dimitrijević, Suzana and Dimitrijević Branković, Suzana and Kojić, Vesna and Janaćković, Đorđe",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/4718",
abstract = "Bioactive glasses have been used for over three decades in biomedical applications owing to high bioactivity, biocompatibility, as well as the possibility to stimulate regeneration of the bone. The aim of this work was to synthesized bioactive glasses, which contain lithium and strontium, by commercial method melting-quenching, as well as determining the properties, affected by mentioned ions. Differential thermal/thermogravimetric analysis, particle size distribution, energy-dispersive X-ray spectroscopy, inductively coupled plasma optical emission spectrometry, evaluation of the antimicrobial activity, in vitro bioactivity and biocompatibility test and scanning electron microscopy were used for characterization. The results showed that glass transition and crystallization temperatures are decreasing with addition of lithium and strontium ions. Furthermore, the samples showed high inhibition rate of Escherichia coli growth, as well as high bioactivity and biocompatibility. The crystal apatite layer, formed on the surface of synthesized glasses after seven days in simulated body fluid, differs in shape, size and interconnection of the glass particles, which depends on concentration of lithium and strontium ions.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia",
title = "Synthesis and characterization of bioactive glass doped with lithium and strontium ions",
pages = "20-20"
}

Physical Properties of Sintered Alumina Doped with Different Oxides

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Đorđević, Antonije; Balać, Igor; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2018)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4537
AB  - Corundum (α-alumina) is a suitable material for usage in various industry fields owing to its chemical stability, electrical and mechanical features. It is known that properties of ceramics could be modified by addition of different oxides, as well as by changing the consolidation parameters. In this respect, alumina was doped with 1 wt.% of Cr2O3, Mn2O3 and NiO, followed by 1 hour of mechanical activation in a high-energy planetary ball mill. A sensitive dilatometer was used for sintering of powder mixtures up to 1400 oC and recording the obtained dilatation. The final density varied between cca. 1.9 and 3.3 g/cm3. Microstructural changes were detected by SEM measurements. Changes in electrical permittivity and loss tangent were associated with the preparation conditions (types of additives, duration of mechanical activation). For a given mixture, the sintering increases the relative permittivity and decreases losses, exhibiting the optimal values of 8.32 and 0.027, respectively, for the sample activated 60 minutes and sintered, with the addition of MnO2. Mechanical measurements indicate significant differences in strength with the addition of different transition metal oxides. Samples with Mn and Ni, activated and sintered, with strength of 121 and 86 MPa, respectively, have a significantly higher tensile strength than the other tested samples, due to their more compact microstructures.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Physical Properties of Sintered Alumina Doped with Different Oxides
SP  - 409
EP  - 419
VL  - 50
IS  - 4
DO  - 10.2298/SOS1804409F
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Đorđević, Antonije and Balać, Igor and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/4537",
abstract = "Corundum (α-alumina) is a suitable material for usage in various industry fields owing to its chemical stability, electrical and mechanical features. It is known that properties of ceramics could be modified by addition of different oxides, as well as by changing the consolidation parameters. In this respect, alumina was doped with 1 wt.% of Cr2O3, Mn2O3 and NiO, followed by 1 hour of mechanical activation in a high-energy planetary ball mill. A sensitive dilatometer was used for sintering of powder mixtures up to 1400 oC and recording the obtained dilatation. The final density varied between cca. 1.9 and 3.3 g/cm3. Microstructural changes were detected by SEM measurements. Changes in electrical permittivity and loss tangent were associated with the preparation conditions (types of additives, duration of mechanical activation). For a given mixture, the sintering increases the relative permittivity and decreases losses, exhibiting the optimal values of 8.32 and 0.027, respectively, for the sample activated 60 minutes and sintered, with the addition of MnO2. Mechanical measurements indicate significant differences in strength with the addition of different transition metal oxides. Samples with Mn and Ni, activated and sintered, with strength of 121 and 86 MPa, respectively, have a significantly higher tensile strength than the other tested samples, due to their more compact microstructures.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Physical Properties of Sintered Alumina Doped with Different Oxides",
pages = "409-419",
volume = "50",
number = "4",
doi = "10.2298/SOS1804409F"
}
4
7
10

New multifunctional materials based on steel slag

Milašević, Ivana; Ivanović, Ljubica; Nikolić, Irena; Đurović, Dijana; Marković, Smilja; Radmilović, Vuk V.; Radmilović, Velimir R.

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Milašević, Ivana
AU  - Ivanović, Ljubica
AU  - Nikolić, Irena
AU  - Đurović, Dijana
AU  - Marković, Smilja
AU  - Radmilović, Vuk V.
AU  - Radmilović, Velimir R.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3665
AB  - Electric arc furnace slag (EAFS) is the by-product of steel production in an electric arc furnace. In a pass two decade a special attention is paid to the valorization of metallurgical slags by alkali activation. The process involves a chemical reaction of slag with the alkaline activator followed by the condensation and hardening processes. Aluminium-containing calcium silicate hydrate gel i.e. C–(A)–S–H gel with a low C/S ratio has been identified as a reaction product of slag alkali activation. We have synthesized the AAS using the EAFS as the precursor and Na2SiO3 solution as an activator. The AAS samples are characterized by XRD, SEM/EDS and FTIR analysis. Moreover, investigation of mechanical properties dilatometric and porosity analysis were performed as well so as to build up a detailed illustration of AAS properties and possible application of these materials. The results have shown that AAS may reach the compressive strength (~ 40 MPa) which enables its application in a civil engineering. Moreover, the AAS sample exhibits improved strength (~ 50 MPa) at elevated temperatures thus potential application of these materials in a high temperature conditions should be considered. On the other hand, these materials may be used as an effective adsorbent for the Cu2+ removal from sulfate bearing wastewater. The Cu2 + ions have been found to be attached on the surface of AAS by formation of stable hydrooxocomplexes that are sorbed on the adsorbent surface via hydroxyl groups in the form of posnjakite crystal phase.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - New multifunctional materials based on steel slag
SP  - 123
EP  - 123
ER  - 
@conference{
author = "Milašević, Ivana and Ivanović, Ljubica and Nikolić, Irena and Đurović, Dijana and Marković, Smilja and Radmilović, Vuk V. and Radmilović, Velimir R.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/3665",
abstract = "Electric arc furnace slag (EAFS) is the by-product of steel production in an electric arc furnace. In a pass two decade a special attention is paid to the valorization of metallurgical slags by alkali activation. The process involves a chemical reaction of slag with the alkaline activator followed by the condensation and hardening processes. Aluminium-containing calcium silicate hydrate gel i.e. C–(A)–S–H gel with a low C/S ratio has been identified as a reaction product of slag alkali activation. We have synthesized the AAS using the EAFS as the precursor and Na2SiO3 solution as an activator. The AAS samples are characterized by XRD, SEM/EDS and FTIR analysis. Moreover, investigation of mechanical properties dilatometric and porosity analysis were performed as well so as to build up a detailed illustration of AAS properties and possible application of these materials. The results have shown that AAS may reach the compressive strength (~ 40 MPa) which enables its application in a civil engineering. Moreover, the AAS sample exhibits improved strength (~ 50 MPa) at elevated temperatures thus potential application of these materials in a high temperature conditions should be considered. On the other hand, these materials may be used as an effective adsorbent for the Cu2+ removal from sulfate bearing wastewater. The Cu2 + ions have been found to be attached on the surface of AAS by formation of stable hydrooxocomplexes that are sorbed on the adsorbent surface via hydroxyl groups in the form of posnjakite crystal phase.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "New multifunctional materials based on steel slag",
pages = "123-123"
}

Alkali Activated Slag as Adsorbents for Cu2+ Removal from Wastewaters

Nikolić, Irena; Đurović, Dijana; Milašević, Ivana; Marković, Smilja; Veselinović, Ljiljana; Radmilović, Vuk V.; Janković Častvan, Ivona; Radmilović, Velimir R.

(Belgrade : Serbian Academy of Sciences and Arts, 2018)

TY  - CONF
AU  - Nikolić, Irena
AU  - Đurović, Dijana
AU  - Milašević, Ivana
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana
AU  - Radmilović, Vuk V.
AU  - Janković Častvan, Ivona
AU  - Radmilović, Velimir R.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3629
AB  - The removal of heavy metals from wastewaters is presently a global imperative primarily due to their well-known toxic nature and detrimental effects on the environment, and more importantly, on human health. Currently, special attention is paid to the use of novel slag based materials – alkali activated slag (AAS) as potential novel adsorbents. Our previous studies have shown that electric arc furnace slag (EAFS) can be successfully used as a precursor for the production of AAS. Generally, alkaline activation involves a chemical reaction between solid aluminosilicate materials and a highly alkaline activator. The alkali activation mechanism of slag involves the dissolution of slag in a highly alkaline, which is followed by the condensation and hardening processes. Dependent on the pH and type of alkaline activator, calcium (alumina) silicate hydrate or C–(A)–S–H gel has been identified as a reaction product of slag alkali activation. The objective of this research was to investigate the removal of Cu2+ from aquatic solution using alkali activated slag (AAS) obtained by alkaline activation of EAFS.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
T1  - Alkali Activated Slag as Adsorbents for Cu2+ Removal from Wastewaters
SP  - 198
EP  - 200
ER  - 
@conference{
author = "Nikolić, Irena and Đurović, Dijana and Milašević, Ivana and Marković, Smilja and Veselinović, Ljiljana and Radmilović, Vuk V. and Janković Častvan, Ivona and Radmilović, Velimir R.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/3629",
abstract = "The removal of heavy metals from wastewaters is presently a global imperative primarily due to their well-known toxic nature and detrimental effects on the environment, and more importantly, on human health. Currently, special attention is paid to the use of novel slag based materials – alkali activated slag (AAS) as potential novel adsorbents. Our previous studies have shown that electric arc furnace slag (EAFS) can be successfully used as a precursor for the production of AAS. Generally, alkaline activation involves a chemical reaction between solid aluminosilicate materials and a highly alkaline activator. The alkali activation mechanism of slag involves the dissolution of slag in a highly alkaline, which is followed by the condensation and hardening processes. Dependent on the pH and type of alkaline activator, calcium (alumina) silicate hydrate or C–(A)–S–H gel has been identified as a reaction product of slag alkali activation. The objective of this research was to investigate the removal of Cu2+ from aquatic solution using alkali activated slag (AAS) obtained by alkaline activation of EAFS.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia",
title = "Alkali Activated Slag as Adsorbents for Cu2+ Removal from Wastewaters",
pages = "198-200"
}

Structural properties of the multiwall carbon nanotubes/poly(methyl methacrylate) nanocomposites: effect of the multiwall carbon nanotubes covalent functionalization

Brković, Danijela V.; Pavlović, Vladimir B.; Pavlović, Vera P.; Obradović, Nina; Mitrić, Miodrag; Stevanović, Sanja; Vlahović, Branislav; Uskoković, Petar S.; Marinković, Aleksandar D.

(Hoboken, NJ : John Wiley & Sons, 2017)

TY  - JOUR
AU  - Brković, Danijela V.
AU  - Pavlović, Vladimir B.
AU  - Pavlović, Vera P.
AU  - Obradović, Nina
AU  - Mitrić, Miodrag
AU  - Stevanović, Sanja
AU  - Vlahović, Branislav
AU  - Uskoković, Petar S.
AU  - Marinković, Aleksandar D.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/16014
AB  - The structural characteristics of polymer nanocomposites with functionalized multiwall carbon nanotubes (MWCNTs) in poly(methyl methacrylate) matrix have been studied in relation to nanofiller loading and surface functionality. Different functional groups have been covalently attached on the MWCNTs sidewalls in order to induce interfacial interactions at nanofiller/polymer interface, which resulted in an improved nanomechanical features. Structural properties of nanocomposites, studied with XRD and Raman analysis, indicated the most pronounced decrease in a degree of amorphousness for samples containing 0.5 and 1 wt% of MWCNTs functionalized with dapsone (dapson-MWCNT) and diethyl malonate (dem-MWCNT). SEM and TEM micrographs confirmed improved dispersibility of the MWCNTs modified with aromatic structure of dapsone inside PMMA matrix. A significant increase in a glass transition temperature of over 60°C has been found for the 1 wt% dapson-MWCNT nanocomposite. Additional modification of dapson-MWCNT by further increasing aromaticity and voluminosity of attached moiety (fid-MWCNT), showed 30°C increases in a glass transition temperature at 4 wt% of nanofiller loading, which is similar to shift of 37°C with loading of MWCNTs modified with ester terminal group. A maximum increase of 56% of reduced modulus and 86% of hardness was obtained for 1 wt% loading of dapson-MWCNT nanofiller.
PB  - Hoboken, NJ : John Wiley & Sons
T2  - Polymer Composites
T1  - Structural properties of the multiwall carbon nanotubes/poly(methyl methacrylate) nanocomposites: effect of the multiwall carbon nanotubes covalent functionalization
SP  - E472
EP  - E489
VL  - 38
IS  - S1
DO  - 10.1002/pc.23996
ER  - 
@article{
author = "Brković, Danijela V. and Pavlović, Vladimir B. and Pavlović, Vera P. and Obradović, Nina and Mitrić, Miodrag and Stevanović, Sanja and Vlahović, Branislav and Uskoković, Petar S. and Marinković, Aleksandar D.",
year = "2017",
url = "http://dais.sanu.ac.rs/123456789/16014",
abstract = "The structural characteristics of polymer nanocomposites with functionalized multiwall carbon nanotubes (MWCNTs) in poly(methyl methacrylate) matrix have been studied in relation to nanofiller loading and surface functionality. Different functional groups have been covalently attached on the MWCNTs sidewalls in order to induce interfacial interactions at nanofiller/polymer interface, which resulted in an improved nanomechanical features. Structural properties of nanocomposites, studied with XRD and Raman analysis, indicated the most pronounced decrease in a degree of amorphousness for samples containing 0.5 and 1 wt% of MWCNTs functionalized with dapsone (dapson-MWCNT) and diethyl malonate (dem-MWCNT). SEM and TEM micrographs confirmed improved dispersibility of the MWCNTs modified with aromatic structure of dapsone inside PMMA matrix. A significant increase in a glass transition temperature of over 60°C has been found for the 1 wt% dapson-MWCNT nanocomposite. Additional modification of dapson-MWCNT by further increasing aromaticity and voluminosity of attached moiety (fid-MWCNT), showed 30°C increases in a glass transition temperature at 4 wt% of nanofiller loading, which is similar to shift of 37°C with loading of MWCNTs modified with ester terminal group. A maximum increase of 56% of reduced modulus and 86% of hardness was obtained for 1 wt% loading of dapson-MWCNT nanofiller.",
publisher = "Hoboken, NJ : John Wiley & Sons",
journal = "Polymer Composites",
title = "Structural properties of the multiwall carbon nanotubes/poly(methyl methacrylate) nanocomposites: effect of the multiwall carbon nanotubes covalent functionalization",
pages = "E472-E489",
volume = "38",
number = "S1",
doi = "10.1002/pc.23996"
}
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