TY  - JOUR
AU  - Elezović, Nevenka R.
AU  - Babić, Biljana M.
AU  - Gajić Krstajić, Ljiljana
AU  - Radmilović, Velimir R.
AU  - Krstajić, Nedeljko
AU  - Vračar, Ljiljana
PY  - 2010
UR  - https://dais.sanu.ac.rs/123456789/3418
AB  - In order to point out the effect of the support to the catalyst for oxygen reduction reaction nano-crystalline Nb-doped TiO2 was synthesized through a modified sol-gel route procedure. The specific surface area of the support, SBET, and pore size distribution, were calculated from the adsorption isotherms using the gravimetric McBain method. The support was characterized by X-ray diffraction (XRD) technique. The borohydride reduction method was used to prepare Nb-TiO2 supported Pt (20 wt.%) catalyst. The synthesized catalyst was analyzed by TEM technique. Finally, the catalytic activity of this new catalyst for oxygen reduction reaction was investigated in acid solution, in the absence and the presence of methanol, and its activity was compared towards the results on C/Pt catalysts. Kinetic analysis reveals that the oxygen reduction reaction on Nb-TiO2/Pt catalyst follows four-electron process leading to water, as in the case of C/Pt electrode, but the Tafel plots normalized to the electrochemically active surface area show very remarkable enhancement in activity of Nb-TiO2/Pt expressed through the value of the current density at the constant potential. Moreover, Nb-TiO2/Pt catalyst exhibits higher methanol tolerance during the oxygen reduction reaction than the C/Pt catalyst. The enhancement in the activity of Nb-TiO2/Pt is consequence of both: the interactions of Pt nanoparticles with the support and the energy shift of the surface d-states with respect to the Fermi level what changes the surface reactivity. © 2010 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Power Sources
T1  - Synthesis, characterization and electrocatalytical behavior of Nb-TiO2/Pt nanocatalyst for oxygen reduction reaction
SP  - 3961
EP  - 3968
VL  - 195
IS  - 13
DO  - 10.1016/j.jpowsour.2010.01.035
UR  - https://hdl.handle.net/21.15107/rcub_dais_3418
ER  - 

@article{
author = "Elezović, Nevenka R. and Babić, Biljana M. and Gajić Krstajić, Ljiljana and Radmilović, Velimir R. and Krstajić, Nedeljko and Vračar, Ljiljana",
year = "2010",
abstract = "In order to point out the effect of the support to the catalyst for oxygen reduction reaction nano-crystalline Nb-doped TiO2 was synthesized through a modified sol-gel route procedure. The specific surface area of the support, SBET, and pore size distribution, were calculated from the adsorption isotherms using the gravimetric McBain method. The support was characterized by X-ray diffraction (XRD) technique. The borohydride reduction method was used to prepare Nb-TiO2 supported Pt (20 wt.%) catalyst. The synthesized catalyst was analyzed by TEM technique. Finally, the catalytic activity of this new catalyst for oxygen reduction reaction was investigated in acid solution, in the absence and the presence of methanol, and its activity was compared towards the results on C/Pt catalysts. Kinetic analysis reveals that the oxygen reduction reaction on Nb-TiO2/Pt catalyst follows four-electron process leading to water, as in the case of C/Pt electrode, but the Tafel plots normalized to the electrochemically active surface area show very remarkable enhancement in activity of Nb-TiO2/Pt expressed through the value of the current density at the constant potential. Moreover, Nb-TiO2/Pt catalyst exhibits higher methanol tolerance during the oxygen reduction reaction than the C/Pt catalyst. The enhancement in the activity of Nb-TiO2/Pt is consequence of both: the interactions of Pt nanoparticles with the support and the energy shift of the surface d-states with respect to the Fermi level what changes the surface reactivity. © 2010 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Power Sources",
title = "Synthesis, characterization and electrocatalytical behavior of Nb-TiO2/Pt nanocatalyst for oxygen reduction reaction",
pages = "3961-3968",
volume = "195",
number = "13",
doi = "10.1016/j.jpowsour.2010.01.035",
url = "https://hdl.handle.net/21.15107/rcub_dais_3418"
}

Elezović, N. R., Babić, B. M., Gajić Krstajić, L., Radmilović, V. R., Krstajić, N.,& Vračar, L.. (2010). Synthesis, characterization and electrocatalytical behavior of Nb-TiO2/Pt nanocatalyst for oxygen reduction reaction. in Journal of Power Sources
Elsevier., 195(13), 3961-3968.
https://doi.org/10.1016/j.jpowsour.2010.01.035
https://hdl.handle.net/21.15107/rcub_dais_3418

Elezović NR, Babić BM, Gajić Krstajić L, Radmilović VR, Krstajić N, Vračar L. Synthesis, characterization and electrocatalytical behavior of Nb-TiO2/Pt nanocatalyst for oxygen reduction reaction. in Journal of Power Sources. 2010;195(13):3961-3968.
doi:10.1016/j.jpowsour.2010.01.035
https://hdl.handle.net/21.15107/rcub_dais_3418 .

Elezović, Nevenka R., Babić, Biljana M., Gajić Krstajić, Ljiljana, Radmilović, Velimir R., Krstajić, Nedeljko, Vračar, Ljiljana, "Synthesis, characterization and electrocatalytical behavior of Nb-TiO2/Pt nanocatalyst for oxygen reduction reaction" in Journal of Power Sources, 195, no. 13 (2010):3961-3968,
https://doi.org/10.1016/j.jpowsour.2010.01.035 .,
https://hdl.handle.net/21.15107/rcub_dais_3418 .

TY  - JOUR
AU  - Elezović, Nevenka
AU  - Gajić Krstajić, Ljiljana
AU  - Vračar, Ljiljana
AU  - Krstajić, Nedeljko
PY  - 2010
UR  - https://dais.sanu.ac.rs/123456789/3410
AB  - The influence of poisoning of MoOx-Pt catalyst by CO on the kinetics of H2 oxidation reaction (HOR) at MoOx-Pt electrode in 0.5 mol dm-3 HClO4 saturated with H 2 containing 100 ppm CO, was examined on rotating disc electrode (RDE) at 25 °C. MoOx-Pt nano-catalyst prepared by the polyole method combined with MoOx post-deposition was supported on commercial carbon black, Vulcan XC-72. The MoOx-Pt/C catalyst was characterized by TEM technique. The catalyst composition is very similar to the nominal one and post-deposited MoOx species block only a small fraction of the active Pt particle surface area. MoOx deposition on the carbon support can be ruled out from the EDAX results and from the low mobility of these oxides under used conditions. Based on Tafel-Heyrovsky-Volmer mechanism the corresponding kinetic equations from a dual-pathway model were derived to describe oxidation current-potential behavior on RDE over entire potential range, at various CO coverages. The polarization RDE curves were fitted with derived polarization equations according to the proposed model. The fitting showed that the HOR proceeded most likely via the Tafel-Volmer (TV) pathway. A very high electrocatalytic activity observed at MoOx-Pt catalyst for the hydrogen oxidation reaction in the presence of 100 ppm CO is achieved through chemical surface reaction of adsorbed CO with Mo surface oxides. © 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T2  - International Journal of Hydrogen Energy
T1  - Effect of chemisorbed CO on MoOx-Pt/C electrode on the kinetics of hydrogen oxidation reaction
SP  - 12878
EP  - 12887
VL  - 35
IS  - 23
DO  - 10.1016/j.ijhydene.2010.09.004
UR  - https://hdl.handle.net/21.15107/rcub_dais_3410
ER  - 

@article{
author = "Elezović, Nevenka and Gajić Krstajić, Ljiljana and Vračar, Ljiljana and Krstajić, Nedeljko",
year = "2010",
abstract = "The influence of poisoning of MoOx-Pt catalyst by CO on the kinetics of H2 oxidation reaction (HOR) at MoOx-Pt electrode in 0.5 mol dm-3 HClO4 saturated with H 2 containing 100 ppm CO, was examined on rotating disc electrode (RDE) at 25 °C. MoOx-Pt nano-catalyst prepared by the polyole method combined with MoOx post-deposition was supported on commercial carbon black, Vulcan XC-72. The MoOx-Pt/C catalyst was characterized by TEM technique. The catalyst composition is very similar to the nominal one and post-deposited MoOx species block only a small fraction of the active Pt particle surface area. MoOx deposition on the carbon support can be ruled out from the EDAX results and from the low mobility of these oxides under used conditions. Based on Tafel-Heyrovsky-Volmer mechanism the corresponding kinetic equations from a dual-pathway model were derived to describe oxidation current-potential behavior on RDE over entire potential range, at various CO coverages. The polarization RDE curves were fitted with derived polarization equations according to the proposed model. The fitting showed that the HOR proceeded most likely via the Tafel-Volmer (TV) pathway. A very high electrocatalytic activity observed at MoOx-Pt catalyst for the hydrogen oxidation reaction in the presence of 100 ppm CO is achieved through chemical surface reaction of adsorbed CO with Mo surface oxides. © 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy, International Journal of Hydrogen Energy",
title = "Effect of chemisorbed CO on MoOx-Pt/C electrode on the kinetics of hydrogen oxidation reaction",
pages = "12878-12887",
volume = "35",
number = "23",
doi = "10.1016/j.ijhydene.2010.09.004",
url = "https://hdl.handle.net/21.15107/rcub_dais_3410"
}

Elezović, N., Gajić Krstajić, L., Vračar, L.,& Krstajić, N.. (2010). Effect of chemisorbed CO on MoOx-Pt/C electrode on the kinetics of hydrogen oxidation reaction. in International Journal of Hydrogen Energy
Elsevier., 35(23), 12878-12887.
https://doi.org/10.1016/j.ijhydene.2010.09.004
https://hdl.handle.net/21.15107/rcub_dais_3410

Elezović N, Gajić Krstajić L, Vračar L, Krstajić N. Effect of chemisorbed CO on MoOx-Pt/C electrode on the kinetics of hydrogen oxidation reaction. in International Journal of Hydrogen Energy. 2010;35(23):12878-12887.
doi:10.1016/j.ijhydene.2010.09.004
https://hdl.handle.net/21.15107/rcub_dais_3410 .

Elezović, Nevenka, Gajić Krstajić, Ljiljana, Vračar, Ljiljana, Krstajić, Nedeljko, "Effect of chemisorbed CO on MoOx-Pt/C electrode on the kinetics of hydrogen oxidation reaction" in International Journal of Hydrogen Energy, 35, no. 23 (2010):12878-12887,
https://doi.org/10.1016/j.ijhydene.2010.09.004 .,
https://hdl.handle.net/21.15107/rcub_dais_3410 .

TY  - CONF
AU  - Krstajić, Nedeljko
AU  - Elezović, Nevenka
AU  - Vračar, Ljiljana
AU  - Gajić Krstajić, Ljiljana
AU  - Radmilović, Velimir R.
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/266
AB  - Poster presented at the 11th Conference of the Materials Research Society of Serbia - YUCOMAT 2009, Herceg Novi, Montenegro, August 31 – September 4, 2009.
T1  - Kinetics of the Hydrogen Oxidation on Pt Modified Moox Nano-Sized Catalyst in the Presence of Carbon Monoxide
UR  - https://hdl.handle.net/21.15107/rcub_dais_266
ER  - 

@conference{
author = "Krstajić, Nedeljko and Elezović, Nevenka and Vračar, Ljiljana and Gajić Krstajić, Ljiljana and Radmilović, Velimir R.",
year = "2009",
abstract = "Poster presented at the 11th Conference of the Materials Research Society of Serbia - YUCOMAT 2009, Herceg Novi, Montenegro, August 31 – September 4, 2009.",
title = "Kinetics of the Hydrogen Oxidation on Pt Modified Moox Nano-Sized Catalyst in the Presence of Carbon Monoxide",
url = "https://hdl.handle.net/21.15107/rcub_dais_266"
}

Krstajić, N., Elezović, N., Vračar, L., Gajić Krstajić, L.,& Radmilović, V. R.. (2009). Kinetics of the Hydrogen Oxidation on Pt Modified Moox Nano-Sized Catalyst in the Presence of Carbon Monoxide. .
https://hdl.handle.net/21.15107/rcub_dais_266

Krstajić N, Elezović N, Vračar L, Gajić Krstajić L, Radmilović VR. Kinetics of the Hydrogen Oxidation on Pt Modified Moox Nano-Sized Catalyst in the Presence of Carbon Monoxide. 2009;.
https://hdl.handle.net/21.15107/rcub_dais_266 .

Krstajić, Nedeljko, Elezović, Nevenka, Vračar, Ljiljana, Gajić Krstajić, Ljiljana, Radmilović, Velimir R., "Kinetics of the Hydrogen Oxidation on Pt Modified Moox Nano-Sized Catalyst in the Presence of Carbon Monoxide" (2009),
https://hdl.handle.net/21.15107/rcub_dais_266 .

TY  - CONF
AU  - Krstajić, Nedeljko
AU  - Elezović, Nevenka R.
AU  - Vračar, Ljiljana
AU  - Gajić Krstajić, Ljiljana
AU  - Radmilović, Velimir R.
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/4956
AB  - Due to the importance of the HOR in fuel-cells technology, various Pt-based catalysts have been examined from the viewpoint of immunity of the electrocatalysis of the HOR from CO-poisoning of the anode catalysts. An appreciable improvement of the CO tolerance has been found at Pt with adatoms such as Ru, Sn [1,2], Pt-M (M=Ru, Rh, Os, W Sn) [3-5] based alloys, and Pt with oxides (RuOxHy) [6]. In the present work, the electrocatalytic of home made highly dispersed nano-sized MoOx-Pt/C catalysts prepared by the polyole method combined by MoOx post-deposition was investigated in the presence of CO, in 0.5 moldm-3 HClO4 solution. The partial pressure of CO in CO/H2 gas mixture was 100 ppm. Carbon monoxide was adsorbed on the RDE for various time interval with keeping the potential at 0.05 V (RHE). The coverage of CO was determined by applying the first potential sweep (from 0.04 to 1.20 V), in N2 saturated solution at potential scan rate of 0.1 Vs-1 and compared it with the sweep on the clean electrode, by measuring the decrease in the hydrogen desorption charge, ΔQH. MoOx(20%)Pt/C catalyst exhibits an excellent CO tolerance, as it was found that the reduction in kinetic current, Ik, is negligible even at ΘCO = 0.46. It was found for this catalyst too, that the CO adsorption rate was much slower than that of Pt and the Pt sites for HOR were not so rigidly blocked by adsorbed CO partially due to its enhanced mobility, resulting from their modified electronic structure of surface Pt sites. Voltammetric studies suggest that an excellent CO tolerance of this catalyst could be also result of the oxidation of adsorbed CO to CO2 by oxophilic MoOx species at low overpotentials by a redox-mediated mechanism.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Programme and The Book of Abstracts / Eleventh Annual Conference YUCOMAT 2009, Herceg Novi, August 31 – September 4, 2009
T1  - Kinetics of the hydrogen oxidation on pt modified MoOx nano-sized catalyst in the presence of carbon monoxide
SP  - 85
EP  - 85
UR  - https://hdl.handle.net/21.15107/rcub_dais_4956
ER  - 

@conference{
author = "Krstajić, Nedeljko and Elezović, Nevenka R. and Vračar, Ljiljana and Gajić Krstajić, Ljiljana and Radmilović, Velimir R.",
year = "2009",
abstract = "Due to the importance of the HOR in fuel-cells technology, various Pt-based catalysts have been examined from the viewpoint of immunity of the electrocatalysis of the HOR from CO-poisoning of the anode catalysts. An appreciable improvement of the CO tolerance has been found at Pt with adatoms such as Ru, Sn [1,2], Pt-M (M=Ru, Rh, Os, W Sn) [3-5] based alloys, and Pt with oxides (RuOxHy) [6]. In the present work, the electrocatalytic of home made highly dispersed nano-sized MoOx-Pt/C catalysts prepared by the polyole method combined by MoOx post-deposition was investigated in the presence of CO, in 0.5 moldm-3 HClO4 solution. The partial pressure of CO in CO/H2 gas mixture was 100 ppm. Carbon monoxide was adsorbed on the RDE for various time interval with keeping the potential at 0.05 V (RHE). The coverage of CO was determined by applying the first potential sweep (from 0.04 to 1.20 V), in N2 saturated solution at potential scan rate of 0.1 Vs-1 and compared it with the sweep on the clean electrode, by measuring the decrease in the hydrogen desorption charge, ΔQH. MoOx(20%)Pt/C catalyst exhibits an excellent CO tolerance, as it was found that the reduction in kinetic current, Ik, is negligible even at ΘCO = 0.46. It was found for this catalyst too, that the CO adsorption rate was much slower than that of Pt and the Pt sites for HOR were not so rigidly blocked by adsorbed CO partially due to its enhanced mobility, resulting from their modified electronic structure of surface Pt sites. Voltammetric studies suggest that an excellent CO tolerance of this catalyst could be also result of the oxidation of adsorbed CO to CO2 by oxophilic MoOx species at low overpotentials by a redox-mediated mechanism.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Programme and The Book of Abstracts / Eleventh Annual Conference YUCOMAT 2009, Herceg Novi, August 31 – September 4, 2009",
title = "Kinetics of the hydrogen oxidation on pt modified MoOx nano-sized catalyst in the presence of carbon monoxide",
pages = "85-85",
url = "https://hdl.handle.net/21.15107/rcub_dais_4956"
}

Krstajić, N., Elezović, N. R., Vračar, L., Gajić Krstajić, L.,& Radmilović, V. R.. (2009). Kinetics of the hydrogen oxidation on pt modified MoOx nano-sized catalyst in the presence of carbon monoxide. in Programme and The Book of Abstracts / Eleventh Annual Conference YUCOMAT 2009, Herceg Novi, August 31 – September 4, 2009
Belgrade : Institute of Technical Sciences of SASA., 85-85.
https://hdl.handle.net/21.15107/rcub_dais_4956

Krstajić N, Elezović NR, Vračar L, Gajić Krstajić L, Radmilović VR. Kinetics of the hydrogen oxidation on pt modified MoOx nano-sized catalyst in the presence of carbon monoxide. in Programme and The Book of Abstracts / Eleventh Annual Conference YUCOMAT 2009, Herceg Novi, August 31 – September 4, 2009. 2009;:85-85.
https://hdl.handle.net/21.15107/rcub_dais_4956 .

Krstajić, Nedeljko, Elezović, Nevenka R., Vračar, Ljiljana, Gajić Krstajić, Ljiljana, Radmilović, Velimir R., "Kinetics of the hydrogen oxidation on pt modified MoOx nano-sized catalyst in the presence of carbon monoxide" in Programme and The Book of Abstracts / Eleventh Annual Conference YUCOMAT 2009, Herceg Novi, August 31 – September 4, 2009 (2009):85-85,
https://hdl.handle.net/21.15107/rcub_dais_4956 .

TY  - JOUR
AU  - Elezović, Nevenka R.
AU  - Gajić Krstajić, Ljiljana
AU  - Radmilović, Velimir R.
AU  - Vračar, Ljiljana
AU  - Krstajić, Nedeljko
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/3485
AB  - The influence of poisoning of Pt catalyst by CO on the kinetics and mechanism of H2 oxidation reaction (HOR) at Pt/C electrode in 0.5 mol dm-3 HClO4, saturated with H2 containing 100 ppm CO, was examined with rotating disc electrode (RDE) at 22 °C. Commercial carbon black, Vulcan XC-72 was used as support, while Pt/C catalyst was prepared by modified polyol synthesis method in an ethylene glycol (EG) solution. The kinetically controlled current (Ik) for the HOR at Pt/C decreases significantly at CO coverage (ΘCO) > 0.6. For ΘCO < 0.6 the HOR takes place through Tafel-Volmer mechanism with Tafel reaction as rate-determining step at the low CO coverage, while Volmer step controls the overall reaction rate at the medium CO coverage. When CO coverage is higher then 0.6, Heyrovsky-Volmer mechanism is operative for the HOR with Heyrovsky as the rate-determining step (rds). © 2008 Elsevier Ltd. All rights reserved.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction
SP  - 1375
EP  - 1382
VL  - 54
IS  - 4
DO  - 10.1016/j.electacta.2008.08.067
UR  - https://hdl.handle.net/21.15107/rcub_dais_3485
ER  - 

@article{
author = "Elezović, Nevenka R. and Gajić Krstajić, Ljiljana and Radmilović, Velimir R. and Vračar, Ljiljana and Krstajić, Nedeljko",
year = "2009",
abstract = "The influence of poisoning of Pt catalyst by CO on the kinetics and mechanism of H2 oxidation reaction (HOR) at Pt/C electrode in 0.5 mol dm-3 HClO4, saturated with H2 containing 100 ppm CO, was examined with rotating disc electrode (RDE) at 22 °C. Commercial carbon black, Vulcan XC-72 was used as support, while Pt/C catalyst was prepared by modified polyol synthesis method in an ethylene glycol (EG) solution. The kinetically controlled current (Ik) for the HOR at Pt/C decreases significantly at CO coverage (ΘCO) > 0.6. For ΘCO < 0.6 the HOR takes place through Tafel-Volmer mechanism with Tafel reaction as rate-determining step at the low CO coverage, while Volmer step controls the overall reaction rate at the medium CO coverage. When CO coverage is higher then 0.6, Heyrovsky-Volmer mechanism is operative for the HOR with Heyrovsky as the rate-determining step (rds). © 2008 Elsevier Ltd. All rights reserved.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction",
pages = "1375-1382",
volume = "54",
number = "4",
doi = "10.1016/j.electacta.2008.08.067",
url = "https://hdl.handle.net/21.15107/rcub_dais_3485"
}

Elezović, N. R., Gajić Krstajić, L., Radmilović, V. R., Vračar, L.,& Krstajić, N.. (2009). Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction. in Electrochimica Acta
Elsevier., 54(4), 1375-1382.
https://doi.org/10.1016/j.electacta.2008.08.067
https://hdl.handle.net/21.15107/rcub_dais_3485

Elezović NR, Gajić Krstajić L, Radmilović VR, Vračar L, Krstajić N. Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction. in Electrochimica Acta. 2009;54(4):1375-1382.
doi:10.1016/j.electacta.2008.08.067
https://hdl.handle.net/21.15107/rcub_dais_3485 .

Elezović, Nevenka R., Gajić Krstajić, Ljiljana, Radmilović, Velimir R., Vračar, Ljiljana, Krstajić, Nedeljko, "Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction" in Electrochimica Acta, 54, no. 4 (2009):1375-1382,
https://doi.org/10.1016/j.electacta.2008.08.067 .,
https://hdl.handle.net/21.15107/rcub_dais_3485 .

TY  - JOUR
AU  - Babić, Biljana M.
AU  - Gulicovski, Jelena
AU  - Gajić Krstajić, Ljiljana
AU  - Elezović, Nevenka
AU  - Radmilović, Velimir R.
AU  - Krstajić, Nedeljko
AU  - Vračar, Ljiljana
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/3480
AB  - The kinetics and mechanism of the hydrogen oxidation reaction were studied in 0.5 mol dm-3 HClO4 solution on an electrode based on titanium oxide with Magneli phase structure-supported platinum electrocatalyst applied on rotation Au disk electrode. Pt catalyst was prepared by impregnation method from 2-propanol solution of Pt(NH3)2(NO2)2 and sub-stoichiometric titanium oxide powder. Sub-stiochiometric titanium oxide support was characterized by X-ray diffraction and BET techniques. The synthesized catalyst was analyzed by TEM technique. Based on Tafel-Heyrovsky-Volmer mechanism the corresponding kinetic equations were derived to describe the hydrogen oxidation current-potential behavior on RDE over the entire potential region. The polarization RDE curves were fitted with derived polarization equations according to proposed model. The fitting shows that the HOR on Pt proceeds most likely via the Tafel-Volmer (TV) pathway in the lower potential region, while the Heyrovsky-Volmer (HV) pathway is operative in the higher potential region. It is pointed out that Tafel equation that has been frequently used for the kinetics analysis in the HOR, can not reproduce the polarization curves measured with high mass-transport rates. Polarization measurements on RDE revealed that the Pt catalyst deposited on titanium suboxide support showed equal specific activity for the HOR compared to conventional carbon-supported Pt fuel cell catalyst. © 2008 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Power Sources
T1  - Kinetic study of the hydrogen oxidation reaction on sub-stoichiometric titanium oxide-supported platinum electrocatalyst in acid solution
SP  - 99
EP  - 106
VL  - 193
IS  - 1
DO  - 10.1016/j.jpowsour.2008.11.142
UR  - https://hdl.handle.net/21.15107/rcub_dais_3480
ER  - 

@article{
author = "Babić, Biljana M. and Gulicovski, Jelena and Gajić Krstajić, Ljiljana and Elezović, Nevenka and Radmilović, Velimir R. and Krstajić, Nedeljko and Vračar, Ljiljana",
year = "2009",
abstract = "The kinetics and mechanism of the hydrogen oxidation reaction were studied in 0.5 mol dm-3 HClO4 solution on an electrode based on titanium oxide with Magneli phase structure-supported platinum electrocatalyst applied on rotation Au disk electrode. Pt catalyst was prepared by impregnation method from 2-propanol solution of Pt(NH3)2(NO2)2 and sub-stoichiometric titanium oxide powder. Sub-stiochiometric titanium oxide support was characterized by X-ray diffraction and BET techniques. The synthesized catalyst was analyzed by TEM technique. Based on Tafel-Heyrovsky-Volmer mechanism the corresponding kinetic equations were derived to describe the hydrogen oxidation current-potential behavior on RDE over the entire potential region. The polarization RDE curves were fitted with derived polarization equations according to proposed model. The fitting shows that the HOR on Pt proceeds most likely via the Tafel-Volmer (TV) pathway in the lower potential region, while the Heyrovsky-Volmer (HV) pathway is operative in the higher potential region. It is pointed out that Tafel equation that has been frequently used for the kinetics analysis in the HOR, can not reproduce the polarization curves measured with high mass-transport rates. Polarization measurements on RDE revealed that the Pt catalyst deposited on titanium suboxide support showed equal specific activity for the HOR compared to conventional carbon-supported Pt fuel cell catalyst. © 2008 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Power Sources",
title = "Kinetic study of the hydrogen oxidation reaction on sub-stoichiometric titanium oxide-supported platinum electrocatalyst in acid solution",
pages = "99-106",
volume = "193",
number = "1",
doi = "10.1016/j.jpowsour.2008.11.142",
url = "https://hdl.handle.net/21.15107/rcub_dais_3480"
}

Babić, B. M., Gulicovski, J., Gajić Krstajić, L., Elezović, N., Radmilović, V. R., Krstajić, N.,& Vračar, L.. (2009). Kinetic study of the hydrogen oxidation reaction on sub-stoichiometric titanium oxide-supported platinum electrocatalyst in acid solution. in Journal of Power Sources
Elsevier., 193(1), 99-106.
https://doi.org/10.1016/j.jpowsour.2008.11.142
https://hdl.handle.net/21.15107/rcub_dais_3480

Babić BM, Gulicovski J, Gajić Krstajić L, Elezović N, Radmilović VR, Krstajić N, Vračar L. Kinetic study of the hydrogen oxidation reaction on sub-stoichiometric titanium oxide-supported platinum electrocatalyst in acid solution. in Journal of Power Sources. 2009;193(1):99-106.
doi:10.1016/j.jpowsour.2008.11.142
https://hdl.handle.net/21.15107/rcub_dais_3480 .

Babić, Biljana M., Gulicovski, Jelena, Gajić Krstajić, Ljiljana, Elezović, Nevenka, Radmilović, Velimir R., Krstajić, Nedeljko, Vračar, Ljiljana, "Kinetic study of the hydrogen oxidation reaction on sub-stoichiometric titanium oxide-supported platinum electrocatalyst in acid solution" in Journal of Power Sources, 193, no. 1 (2009):99-106,
https://doi.org/10.1016/j.jpowsour.2008.11.142 .,
https://hdl.handle.net/21.15107/rcub_dais_3480 .

TY  - JOUR
AU  - Krstajić, Nedeljko
AU  - Jović, Vladimir D.
AU  - Gajić Krstajić, Ljiljana
AU  - Jović, Borka M.
AU  - Antozzi, A. L.
AU  - Martelli, G. N.
PY  - 2008
UR  - https://dais.sanu.ac.rs/123456789/3579
AB  - The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution
SP  - 3676
EP  - 3687
VL  - 33
IS  - 14
DO  - 10.1016/j.ijhydene.2008.04.039
UR  - https://hdl.handle.net/21.15107/rcub_dais_3579
ER  - 

@article{
author = "Krstajić, Nedeljko and Jović, Vladimir D. and Gajić Krstajić, Ljiljana and Jović, Borka M. and Antozzi, A. L. and Martelli, G. N.",
year = "2008",
abstract = "The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution",
pages = "3676-3687",
volume = "33",
number = "14",
doi = "10.1016/j.ijhydene.2008.04.039",
url = "https://hdl.handle.net/21.15107/rcub_dais_3579"
}

Krstajić, N., Jović, V. D., Gajić Krstajić, L., Jović, B. M., Antozzi, A. L.,& Martelli, G. N.. (2008). Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in International Journal of Hydrogen Energy
Elsevier., 33(14), 3676-3687.
https://doi.org/10.1016/j.ijhydene.2008.04.039
https://hdl.handle.net/21.15107/rcub_dais_3579

Krstajić N, Jović VD, Gajić Krstajić L, Jović BM, Antozzi AL, Martelli GN. Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in International Journal of Hydrogen Energy. 2008;33(14):3676-3687.
doi:10.1016/j.ijhydene.2008.04.039
https://hdl.handle.net/21.15107/rcub_dais_3579 .

Krstajić, Nedeljko, Jović, Vladimir D., Gajić Krstajić, Ljiljana, Jović, Borka M., Antozzi, A. L., Martelli, G. N., "Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution" in International Journal of Hydrogen Energy, 33, no. 14 (2008):3676-3687,
https://doi.org/10.1016/j.ijhydene.2008.04.039 .,
https://hdl.handle.net/21.15107/rcub_dais_3579 .

TY  - JOUR
AU  - Elezović, Nevenka
AU  - Babić, Biljana M.
AU  - Krstajić, Nedeljko
AU  - Gajić Krstajić, Ljiljana
AU  - Vračar, Ljiljana
PY  - 2007
UR  - https://dais.sanu.ac.rs/123456789/12884
AB  - Home-made carbon cryogel synthesized by sol-gel polycondensation and freeze-drying is used as support for preparation of highly dispersed Pt catalyst that is made by a modified polyol synthesis method in an ethylene glycol (EG) solution. Specific surface area of carbon support and Pt/C catalyst is determined from nitrogen adsorption isotherm. The adsorption isotherm demonstrates a significant mesoporosity of carbon support. Specific surface area of the carbon support, calculated by the BET equation, is found to be 573 m(2) g(-1). X-ray diffraction (XRD) results demonstrate a successful reduction of the Pt precursor to its metallic form, and transmission electron microscopy (TEM) images show very uniform Pt particle size distribution with mean particle size of about 2.7 +/- 0.7 nm of the catalyst. Potentiodynamic studies of the underpotential deposition of hydrogen (H-upd) on Pt/C electrode in 0.5 mol dm(-3) HClO4 aqueous solution in the temperature range from 274 to 318 K are made, and thermodynamic state functions for the hydrogen adsorption are determined. The experimental results are analyzed assuming linear variation of the Gibbs energy of adsorption versus theta H-upd on the basis of the surface heterogeneity. The increase of Delta G(Hupd)(theta) with the surface coverage indicates the repulsive interactions between H-upd adatoms. From the temperature dependence of the Gibbs energy of adsorption, the enthalpy and the entropy of adsorption are calculated. The values of these functions are determined to be Delta H-Hupd(theta=0) = -5.6 kJ mol(-1) and Delta S-Hupd(theta=0) = 69.1 J mol(-1) K-1 The value of Delta H-Hupd(theta) allows determinations of the bond energy between electrode surface and H-upd that is found to be Ept-H = 223 kJ mol(-1) for theta = 0.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - International Journal of Hydrogen Energy
T1  - Specificity of the UPD of H to the structure of highly dispersed Pt on carbon support
SP  - 1991
EP  - 1998
VL  - 32
IS  - 12
DO  - 10.1016/j.ijhydene.2006.09.042
UR  - https://hdl.handle.net/21.15107/rcub_dais_12884
ER  - 

@article{
author = "Elezović, Nevenka and Babić, Biljana M. and Krstajić, Nedeljko and Gajić Krstajić, Ljiljana and Vračar, Ljiljana",
year = "2007",
abstract = "Home-made carbon cryogel synthesized by sol-gel polycondensation and freeze-drying is used as support for preparation of highly dispersed Pt catalyst that is made by a modified polyol synthesis method in an ethylene glycol (EG) solution. Specific surface area of carbon support and Pt/C catalyst is determined from nitrogen adsorption isotherm. The adsorption isotherm demonstrates a significant mesoporosity of carbon support. Specific surface area of the carbon support, calculated by the BET equation, is found to be 573 m(2) g(-1). X-ray diffraction (XRD) results demonstrate a successful reduction of the Pt precursor to its metallic form, and transmission electron microscopy (TEM) images show very uniform Pt particle size distribution with mean particle size of about 2.7 +/- 0.7 nm of the catalyst. Potentiodynamic studies of the underpotential deposition of hydrogen (H-upd) on Pt/C electrode in 0.5 mol dm(-3) HClO4 aqueous solution in the temperature range from 274 to 318 K are made, and thermodynamic state functions for the hydrogen adsorption are determined. The experimental results are analyzed assuming linear variation of the Gibbs energy of adsorption versus theta H-upd on the basis of the surface heterogeneity. The increase of Delta G(Hupd)(theta) with the surface coverage indicates the repulsive interactions between H-upd adatoms. From the temperature dependence of the Gibbs energy of adsorption, the enthalpy and the entropy of adsorption are calculated. The values of these functions are determined to be Delta H-Hupd(theta=0) = -5.6 kJ mol(-1) and Delta S-Hupd(theta=0) = 69.1 J mol(-1) K-1 The value of Delta H-Hupd(theta) allows determinations of the bond energy between electrode surface and H-upd that is found to be Ept-H = 223 kJ mol(-1) for theta = 0.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "International Journal of Hydrogen Energy",
title = "Specificity of the UPD of H to the structure of highly dispersed Pt on carbon support",
pages = "1991-1998",
volume = "32",
number = "12",
doi = "10.1016/j.ijhydene.2006.09.042",
url = "https://hdl.handle.net/21.15107/rcub_dais_12884"
}

Elezović, N., Babić, B. M., Krstajić, N., Gajić Krstajić, L.,& Vračar, L.. (2007). Specificity of the UPD of H to the structure of highly dispersed Pt on carbon support. in International Journal of Hydrogen Energy
Pergamon-Elsevier Science Ltd, Oxford., 32(12), 1991-1998.
https://doi.org/10.1016/j.ijhydene.2006.09.042
https://hdl.handle.net/21.15107/rcub_dais_12884

Elezović N, Babić BM, Krstajić N, Gajić Krstajić L, Vračar L. Specificity of the UPD of H to the structure of highly dispersed Pt on carbon support. in International Journal of Hydrogen Energy. 2007;32(12):1991-1998.
doi:10.1016/j.ijhydene.2006.09.042
https://hdl.handle.net/21.15107/rcub_dais_12884 .

Elezović, Nevenka, Babić, Biljana M., Krstajić, Nedeljko, Gajić Krstajić, Ljiljana, Vračar, Ljiljana, "Specificity of the UPD of H to the structure of highly dispersed Pt on carbon support" in International Journal of Hydrogen Energy, 32, no. 12 (2007):1991-1998,
https://doi.org/10.1016/j.ijhydene.2006.09.042 .,
https://hdl.handle.net/21.15107/rcub_dais_12884 .

TY  - CONF
AU  - Gajić Krstajić, Ljiljana
AU  - Krstajić, Nedeljko
AU  - Jović, Vladimir
AU  - Jović, Borka M.
PY  - 2007
UR  - https://dais.sanu.ac.rs/123456789/6280
AB  - The hydrogen evolution reaction on electrodeposited NiMo alloy coatings, as well as
their electrochemical properties in NaOH solutions have been investigated by polarization
measurements, cyclic voltammetry and EIS technique. It is shown that NiMo alloy coatings
electrodeposited from pyrophosphate-sodium bicarbonate bath possess high catalytic activity for
hydrogen evolution in NaOH solutions. Their stability in 1M NaOH at 25 0C under the condition
of reverse polarization is shown to be very good, while in 33% NaOH at 850C (conditions of
industrial electrolysis) electrodeposited NiMo alloy coatings exhibit also high catalytic activity,
but low stability, as a consequence of massive dissolution of alloy coatings under the condition
of reverse polarization.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Programme and The Book of Abstracts / Ninth Annual Conference YUCOMAT 2007, Herceg Novi, September 10-14, 2007
T1  - Electrodeposition of NiMo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution
SP  - 163
EP  - 163
UR  - https://hdl.handle.net/21.15107/rcub_dais_6280
ER  - 

@conference{
author = "Gajić Krstajić, Ljiljana and Krstajić, Nedeljko and Jović, Vladimir and Jović, Borka M.",
year = "2007",
abstract = "The hydrogen evolution reaction on electrodeposited NiMo alloy coatings, as well as
their electrochemical properties in NaOH solutions have been investigated by polarization
measurements, cyclic voltammetry and EIS technique. It is shown that NiMo alloy coatings
electrodeposited from pyrophosphate-sodium bicarbonate bath possess high catalytic activity for
hydrogen evolution in NaOH solutions. Their stability in 1M NaOH at 25 0C under the condition
of reverse polarization is shown to be very good, while in 33% NaOH at 850C (conditions of
industrial electrolysis) electrodeposited NiMo alloy coatings exhibit also high catalytic activity,
but low stability, as a consequence of massive dissolution of alloy coatings under the condition
of reverse polarization.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Programme and The Book of Abstracts / Ninth Annual Conference YUCOMAT 2007, Herceg Novi, September 10-14, 2007",
title = "Electrodeposition of NiMo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution",
pages = "163-163",
url = "https://hdl.handle.net/21.15107/rcub_dais_6280"
}

Gajić Krstajić, L., Krstajić, N., Jović, V.,& Jović, B. M.. (2007). Electrodeposition of NiMo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in Programme and The Book of Abstracts / Ninth Annual Conference YUCOMAT 2007, Herceg Novi, September 10-14, 2007
Belgrade : Institute of Technical Sciences of SASA., 163-163.
https://hdl.handle.net/21.15107/rcub_dais_6280

Gajić Krstajić L, Krstajić N, Jović V, Jović BM. Electrodeposition of NiMo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in Programme and The Book of Abstracts / Ninth Annual Conference YUCOMAT 2007, Herceg Novi, September 10-14, 2007. 2007;:163-163.
https://hdl.handle.net/21.15107/rcub_dais_6280 .

Gajić Krstajić, Ljiljana, Krstajić, Nedeljko, Jović, Vladimir, Jović, Borka M., "Electrodeposition of NiMo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution" in Programme and The Book of Abstracts / Ninth Annual Conference YUCOMAT 2007, Herceg Novi, September 10-14, 2007 (2007):163-163,
https://hdl.handle.net/21.15107/rcub_dais_6280 .