Živojinović, Jelena

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  • Živojinović, Jelena (29)
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Author's Bibliography

Structural characteristics of MgAl2O4 spinel

Peleš Tadić, Adriana; Živojinović, Jelena; Tadić, Nenad; Lević, Steva; Marković, Smilja; Pavlović, Vladimir B.; Filipović, Suzana; Obradović, Nina

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Peleš Tadić, Adriana
AU  - Živojinović, Jelena
AU  - Tadić, Nenad
AU  - Lević, Steva
AU  - Marković, Smilja
AU  - Pavlović, Vladimir B.
AU  - Filipović, Suzana
AU  - Obradović, Nina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15759
AB  - Magnesium aluminate spinel (MgAl2O4) is a material with good mechanical, chemical, and thermal properties, low dielectric permeability and loss tangent. Based on those properties, MgAl2O4 has found a significant application in refractory ceramics, ceramics windows, integrated electronic devices, etc. Also, it possesses a high chemical and radiation resistance. In this research, MgO was calcined at 1000ºC for an hour, with a step of 10ºC/min to avoid presence of hydroxide or carbonate. MgO and Al2O3 powders were mixed in a one-to-one molar ratio afterwards. The powders were mechanically activated for 15, 30, and 60 minutes. The mass ratio of powder and balls was 1:40. The mechanically activated powders are pressed in the tablets, under the pressure of 0.5 t. The pressed powders were heated up to 1300 ºC with a step of 10 ºC/min and held for 1 h for the reaction. Reacted pellets were crushed and sieved. Obtained spinel powders were sintered at 1450 ºC for 2 h. Both sintered and non-sintered samples were investigated by XRD and SEM. The particle size distribution of the reacted powders was investigated by laser diffraction analysis. Raman spectroscopy was used to determine the lattice vibration in the sintered samples. All results are in accordance with our previous results, and the pure dense spinel phase is obtained.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
T1  - Structural characteristics of MgAl2O4 spinel
SP  - 52
EP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_dais_15759
ER  - 
@conference{
author = "Peleš Tadić, Adriana and Živojinović, Jelena and Tadić, Nenad and Lević, Steva and Marković, Smilja and Pavlović, Vladimir B. and Filipović, Suzana and Obradović, Nina",
year = "2023",
abstract = "Magnesium aluminate spinel (MgAl2O4) is a material with good mechanical, chemical, and thermal properties, low dielectric permeability and loss tangent. Based on those properties, MgAl2O4 has found a significant application in refractory ceramics, ceramics windows, integrated electronic devices, etc. Also, it possesses a high chemical and radiation resistance. In this research, MgO was calcined at 1000ºC for an hour, with a step of 10ºC/min to avoid presence of hydroxide or carbonate. MgO and Al2O3 powders were mixed in a one-to-one molar ratio afterwards. The powders were mechanically activated for 15, 30, and 60 minutes. The mass ratio of powder and balls was 1:40. The mechanically activated powders are pressed in the tablets, under the pressure of 0.5 t. The pressed powders were heated up to 1300 ºC with a step of 10 ºC/min and held for 1 h for the reaction. Reacted pellets were crushed and sieved. Obtained spinel powders were sintered at 1450 ºC for 2 h. Both sintered and non-sintered samples were investigated by XRD and SEM. The particle size distribution of the reacted powders was investigated by laser diffraction analysis. Raman spectroscopy was used to determine the lattice vibration in the sintered samples. All results are in accordance with our previous results, and the pure dense spinel phase is obtained.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023",
title = "Structural characteristics of MgAl2O4 spinel",
pages = "52-52",
url = "https://hdl.handle.net/21.15107/rcub_dais_15759"
}
Peleš Tadić, A., Živojinović, J., Tadić, N., Lević, S., Marković, S., Pavlović, V. B., Filipović, S.,& Obradović, N.. (2023). Structural characteristics of MgAl2O4 spinel. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
Belgrade : Serbian Ceramic Society., 52-52.
https://hdl.handle.net/21.15107/rcub_dais_15759
Peleš Tadić A, Živojinović J, Tadić N, Lević S, Marković S, Pavlović VB, Filipović S, Obradović N. Structural characteristics of MgAl2O4 spinel. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023. 2023;:52-52.
https://hdl.handle.net/21.15107/rcub_dais_15759 .
Peleš Tadić, Adriana, Živojinović, Jelena, Tadić, Nenad, Lević, Steva, Marković, Smilja, Pavlović, Vladimir B., Filipović, Suzana, Obradović, Nina, "Structural characteristics of MgAl2O4 spinel" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023 (2023):52-52,
https://hdl.handle.net/21.15107/rcub_dais_15759 .

Electronic properties of BZT nano-ceramic grades at low frequency region

Kosanović, Darko; Blagojević, Vladimir; Aleksić, Stanko; Živojinović, Jelena; Peleš Tadić, Adriana; Pavlović, Vladimir B.; Obradović, Nina

(Belgrade : ETRAN, 2023)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir
AU  - Aleksić, Stanko
AU  - Živojinović, Jelena
AU  - Peleš Tadić, Adriana
AU  - Pavlović, Vladimir B.
AU  - Obradović, Nina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14971
AB  - BZT ceramics was prepared by using fine powder mixture of BaCO3, TiO2 and ZrO2 in the respective molar ratio to form Ba(Zr0.10Ti0.90)O3 via solid state reaction at elevated temperature. The prepared BZT was milled in the planetary ball mill from 0-120 min to achieve different powder grades from micron to nano-sized particles. After the powder characterization by XRD and SEM the samples were pressed in disc shape and sintered at different temperatures from 1100-1350°C in the air. The sintered samples were characterized by SEM and their density and average grain size was determined and presented vs. sintering temperature and powder grades (milling time). After that the silver epoxy electrodes were deposited on sintered disc samples. The disc samples capacity and resistivity were measured at low frequency region from 1 Hz to 200 kHz using low frequency impedance analyzer. The sintering temperatures and powder grades were used as parameters. Finally the specific resistance ρ, dielectric constant (ε' + jε") and tgδ where determined from the impedance measurements. The behavior of electronic properties where analyzed e.g. the relaxation effect of the space charge (inter-granular electric charges) vs. sintering temperature and ceramic grades. The results obtained were compared with best literature data for the losses in BZT ceramics at low frequencies.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Electronic properties of BZT nano-ceramic grades at low frequency region
SP  - 413
EP  - 423
VL  - 55
IS  - 3
DO  - 10.2298/SOS230717043K
UR  - https://hdl.handle.net/21.15107/rcub_dais_14971
ER  - 
@article{
author = "Kosanović, Darko and Blagojević, Vladimir and Aleksić, Stanko and Živojinović, Jelena and Peleš Tadić, Adriana and Pavlović, Vladimir B. and Obradović, Nina",
year = "2023",
abstract = "BZT ceramics was prepared by using fine powder mixture of BaCO3, TiO2 and ZrO2 in the respective molar ratio to form Ba(Zr0.10Ti0.90)O3 via solid state reaction at elevated temperature. The prepared BZT was milled in the planetary ball mill from 0-120 min to achieve different powder grades from micron to nano-sized particles. After the powder characterization by XRD and SEM the samples were pressed in disc shape and sintered at different temperatures from 1100-1350°C in the air. The sintered samples were characterized by SEM and their density and average grain size was determined and presented vs. sintering temperature and powder grades (milling time). After that the silver epoxy electrodes were deposited on sintered disc samples. The disc samples capacity and resistivity were measured at low frequency region from 1 Hz to 200 kHz using low frequency impedance analyzer. The sintering temperatures and powder grades were used as parameters. Finally the specific resistance ρ, dielectric constant (ε' + jε") and tgδ where determined from the impedance measurements. The behavior of electronic properties where analyzed e.g. the relaxation effect of the space charge (inter-granular electric charges) vs. sintering temperature and ceramic grades. The results obtained were compared with best literature data for the losses in BZT ceramics at low frequencies.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Electronic properties of BZT nano-ceramic grades at low frequency region",
pages = "413-423",
volume = "55",
number = "3",
doi = "10.2298/SOS230717043K",
url = "https://hdl.handle.net/21.15107/rcub_dais_14971"
}
Kosanović, D., Blagojević, V., Aleksić, S., Živojinović, J., Peleš Tadić, A., Pavlović, V. B.,& Obradović, N.. (2023). Electronic properties of BZT nano-ceramic grades at low frequency region. in Science of Sintering
Belgrade : ETRAN., 55(3), 413-423.
https://doi.org/10.2298/SOS230717043K
https://hdl.handle.net/21.15107/rcub_dais_14971
Kosanović D, Blagojević V, Aleksić S, Živojinović J, Peleš Tadić A, Pavlović VB, Obradović N. Electronic properties of BZT nano-ceramic grades at low frequency region. in Science of Sintering. 2023;55(3):413-423.
doi:10.2298/SOS230717043K
https://hdl.handle.net/21.15107/rcub_dais_14971 .
Kosanović, Darko, Blagojević, Vladimir, Aleksić, Stanko, Živojinović, Jelena, Peleš Tadić, Adriana, Pavlović, Vladimir B., Obradović, Nina, "Electronic properties of BZT nano-ceramic grades at low frequency region" in Science of Sintering, 55, no. 3 (2023):413-423,
https://doi.org/10.2298/SOS230717043K .,
https://hdl.handle.net/21.15107/rcub_dais_14971 .

Characterization of mechanically activated ZrO2-C powder mixtures

Obradović, Nina; Feng, Lun; Filipović, Suzana; Mirković, M.; Kosanović, Darko; Živojinović, Jelena; Rogan, Jelena; Fahrenholtz, William G.

(Belgrade : University of Belgrade - Faculty of Mechanical Engineering, 2023)

TY  - CONF
AU  - Obradović, Nina
AU  - Feng, Lun
AU  - Filipović, Suzana
AU  - Mirković, M.
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Rogan, Jelena
AU  - Fahrenholtz, William G.
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15008
AB  - Mechanical activation represents a very useful technique for powder processing prior to sintering process. First of all, it makes powders homogenized, leads to attrition of powder particles, and makes powder mixtures more reactive. Secondly, it can lead to mechano-chemical reaction, and finally, lowering of sintering time and temperature. Mixtures of ZrO2 and C were mechanically activated by high-energy ball milling. Powders were milled for times from 0 to 120 minutes in air atmosphere. Mechanically activated powder mixtures were characterized by various techniques, such as particle size analysis (PSA), X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, Raman spectroscopy, and diffraction scanning calorimetry along with thermo gravimetry (DSC-TGA). As milling time increased, surface area of powders increased, indicating significant particle size reduction. Mechanical activation for 15 minutes provides the best balance between particle size reduction and reactivity for the powders.
PB  - Belgrade : University of Belgrade - Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2023, 04 – 07 July 2023, Zlatibor, Serbia
T1  - Characterization of mechanically activated ZrO2-C powder mixtures
SP  - 78
UR  - https://hdl.handle.net/21.15107/rcub_dais_15008
ER  - 
@conference{
author = "Obradović, Nina and Feng, Lun and Filipović, Suzana and Mirković, M. and Kosanović, Darko and Živojinović, Jelena and Rogan, Jelena and Fahrenholtz, William G.",
year = "2023",
abstract = "Mechanical activation represents a very useful technique for powder processing prior to sintering process. First of all, it makes powders homogenized, leads to attrition of powder particles, and makes powder mixtures more reactive. Secondly, it can lead to mechano-chemical reaction, and finally, lowering of sintering time and temperature. Mixtures of ZrO2 and C were mechanically activated by high-energy ball milling. Powders were milled for times from 0 to 120 minutes in air atmosphere. Mechanically activated powder mixtures were characterized by various techniques, such as particle size analysis (PSA), X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, Raman spectroscopy, and diffraction scanning calorimetry along with thermo gravimetry (DSC-TGA). As milling time increased, surface area of powders increased, indicating significant particle size reduction. Mechanical activation for 15 minutes provides the best balance between particle size reduction and reactivity for the powders.",
publisher = "Belgrade : University of Belgrade - Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2023, 04 – 07 July 2023, Zlatibor, Serbia",
title = "Characterization of mechanically activated ZrO2-C powder mixtures",
pages = "78",
url = "https://hdl.handle.net/21.15107/rcub_dais_15008"
}
Obradović, N., Feng, L., Filipović, S., Mirković, M., Kosanović, D., Živojinović, J., Rogan, J.,& Fahrenholtz, W. G.. (2023). Characterization of mechanically activated ZrO2-C powder mixtures. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2023, 04 – 07 July 2023, Zlatibor, Serbia
Belgrade : University of Belgrade - Faculty of Mechanical Engineering., 78.
https://hdl.handle.net/21.15107/rcub_dais_15008
Obradović N, Feng L, Filipović S, Mirković M, Kosanović D, Živojinović J, Rogan J, Fahrenholtz WG. Characterization of mechanically activated ZrO2-C powder mixtures. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2023, 04 – 07 July 2023, Zlatibor, Serbia. 2023;:78.
https://hdl.handle.net/21.15107/rcub_dais_15008 .
Obradović, Nina, Feng, Lun, Filipović, Suzana, Mirković, M., Kosanović, Darko, Živojinović, Jelena, Rogan, Jelena, Fahrenholtz, William G., "Characterization of mechanically activated ZrO2-C powder mixtures" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2023, 04 – 07 July 2023, Zlatibor, Serbia (2023):78,
https://hdl.handle.net/21.15107/rcub_dais_15008 .

Uticaj mehaničke aktivacije na smešu SrTiO3 i Fe2O3 kao aditiva

Živojinović, Jelena; Peleš Tadić, Adriana; Kosanović, Darko; Filipović, Suzana; Stanković, Ana; Obradović, Nina

(Beograd : Savez inženjera i tehničara Srbije, 2023)

TY  - JOUR
AU  - Živojinović, Jelena
AU  - Peleš Tadić, Adriana
AU  - Kosanović, Darko
AU  - Filipović, Suzana
AU  - Stanković, Ana
AU  - Obradović, Nina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/14970
AB  - Istraživanja predstavljena u ovom radu prate uticaj mehaničke aktivacije na strukturu smeše stroncijumtitanata (SrTiO3) sa dodatkom 6 težinskih % gvožđe(III)oksida (Fe2O3) kao aditiva. Prahovi su mehanički aktivirani u visoko-energetskom planetarnom mlinu sa volfram-karbidnim (WC) kuglicama u vremenskom intervalu od 0 do 120 minuta. Korišćena je metoda rendgenske difrakcije (XRD) radi identifikacije faznog sastava smeša, a metode skenirajuće elektronske mikroskopije (SEM) i raspodele veličine čestica (PSA) korišćene su za praćenje promene u morfologiji i raspodeli veličina čestica aktiviranih prahova. Promene u kristalnoj rešetki SrTiO3 su praćene i ramanskom spektrometrijom, a izračunata je i širina zabranjene zone uzoraka. Cilj mehaničke aktivacije prahova je sniženje temperature i skraćivanje vremena procesa sinterovanja radi dobijanja finalnog proizvoda.
AB  - The authors investigated the influence of mechanical activation on the structure of SrTiO3 mixture with 6 wt.% Fe2O3. Powders were mechanically activated in a planetary ball mill with WC balls in time intervals from 0 to 120 minutes. XRD method was used for the identification of phase structure, while SEM and PSA were employed for monitoring of changes in morphology and particle size distribution. Structural changes were followed by Raman spectroscopy, and band gap values were calculated as well. The purpose of mechanical activation is lowering the temperature and time of sintering in the process of obtaining the final product.
PB  - Beograd : Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Uticaj mehaničke aktivacije na smešu SrTiO3 i Fe2O3 kao aditiva
SP  - 395
EP  - 400
VL  - 78
IS  - 4
DO  - 10.5937/tehnika2304395Z
UR  - https://hdl.handle.net/21.15107/rcub_dais_14970
ER  - 
@article{
author = "Živojinović, Jelena and Peleš Tadić, Adriana and Kosanović, Darko and Filipović, Suzana and Stanković, Ana and Obradović, Nina",
year = "2023",
abstract = "Istraživanja predstavljena u ovom radu prate uticaj mehaničke aktivacije na strukturu smeše stroncijumtitanata (SrTiO3) sa dodatkom 6 težinskih % gvožđe(III)oksida (Fe2O3) kao aditiva. Prahovi su mehanički aktivirani u visoko-energetskom planetarnom mlinu sa volfram-karbidnim (WC) kuglicama u vremenskom intervalu od 0 do 120 minuta. Korišćena je metoda rendgenske difrakcije (XRD) radi identifikacije faznog sastava smeša, a metode skenirajuće elektronske mikroskopije (SEM) i raspodele veličine čestica (PSA) korišćene su za praćenje promene u morfologiji i raspodeli veličina čestica aktiviranih prahova. Promene u kristalnoj rešetki SrTiO3 su praćene i ramanskom spektrometrijom, a izračunata je i širina zabranjene zone uzoraka. Cilj mehaničke aktivacije prahova je sniženje temperature i skraćivanje vremena procesa sinterovanja radi dobijanja finalnog proizvoda., The authors investigated the influence of mechanical activation on the structure of SrTiO3 mixture with 6 wt.% Fe2O3. Powders were mechanically activated in a planetary ball mill with WC balls in time intervals from 0 to 120 minutes. XRD method was used for the identification of phase structure, while SEM and PSA were employed for monitoring of changes in morphology and particle size distribution. Structural changes were followed by Raman spectroscopy, and band gap values were calculated as well. The purpose of mechanical activation is lowering the temperature and time of sintering in the process of obtaining the final product.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Uticaj mehaničke aktivacije na smešu SrTiO3 i Fe2O3 kao aditiva",
pages = "395-400",
volume = "78",
number = "4",
doi = "10.5937/tehnika2304395Z",
url = "https://hdl.handle.net/21.15107/rcub_dais_14970"
}
Živojinović, J., Peleš Tadić, A., Kosanović, D., Filipović, S., Stanković, A.,& Obradović, N.. (2023). Uticaj mehaničke aktivacije na smešu SrTiO3 i Fe2O3 kao aditiva. in Tehnika
Beograd : Savez inženjera i tehničara Srbije., 78(4), 395-400.
https://doi.org/10.5937/tehnika2304395Z
https://hdl.handle.net/21.15107/rcub_dais_14970
Živojinović J, Peleš Tadić A, Kosanović D, Filipović S, Stanković A, Obradović N. Uticaj mehaničke aktivacije na smešu SrTiO3 i Fe2O3 kao aditiva. in Tehnika. 2023;78(4):395-400.
doi:10.5937/tehnika2304395Z
https://hdl.handle.net/21.15107/rcub_dais_14970 .
Živojinović, Jelena, Peleš Tadić, Adriana, Kosanović, Darko, Filipović, Suzana, Stanković, Ana, Obradović, Nina, "Uticaj mehaničke aktivacije na smešu SrTiO3 i Fe2O3 kao aditiva" in Tehnika, 78, no. 4 (2023):395-400,
https://doi.org/10.5937/tehnika2304395Z .,
https://hdl.handle.net/21.15107/rcub_dais_14970 .

Influence of Fe Doping on the Crystal Structure and Optical Properties of Mechanically Activated SrTiO3 Powders

Živojinović, Jelena; Peleš Tadić, Adriana; Kosanović, Darko; Tadić, Nenad; Vasiljević, Zorka Ž.; Lević, Steva; Obradović, Nina

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Peleš Tadić, Adriana
AU  - Kosanović, Darko
AU  - Tadić, Nenad
AU  - Vasiljević, Zorka Ž.
AU  - Lević, Steva
AU  - Obradović, Nina
PY  - 2023
UR  - https://dais.sanu.ac.rs/123456789/15007
AB  - Iron-doped strontium-titanate (SrTiO3) powders with various iron(III) oxide (Fe2O3) weight percentages (1.5, 3 and 6 wt%) were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 min). A systematic investigation by XRD, SEM and Raman spectroscopy has been undertaken to evaluate the role of dopant on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different iron-doped and activated Fe-SrTiO3 powders have been also evaluated. The results demonstrated that Fe has been substituted into the lattice and surface layers of particles of SrTiO3 powders and the absorption edge shifted to higher wavelength values with increasing activation time and dopant weight percentage. The lowest value of the band gap (Eg=3.20 eV) was registered for the longest activation (120 min) and the highest weight percentage of dopant (6 wt%). Combining doping with mechanical activation, led to lower values of Eg and that fact could be used in subsequent studies to make Fe-SrTiO3 more suitable photocatalysts.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
T1  - Influence of Fe Doping on the Crystal Structure and Optical Properties of Mechanically Activated SrTiO3 Powders
SP  - 51
EP  - 51
UR  - https://hdl.handle.net/21.15107/rcub_dais_15007
ER  - 
@conference{
author = "Živojinović, Jelena and Peleš Tadić, Adriana and Kosanović, Darko and Tadić, Nenad and Vasiljević, Zorka Ž. and Lević, Steva and Obradović, Nina",
year = "2023",
abstract = "Iron-doped strontium-titanate (SrTiO3) powders with various iron(III) oxide (Fe2O3) weight percentages (1.5, 3 and 6 wt%) were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 min). A systematic investigation by XRD, SEM and Raman spectroscopy has been undertaken to evaluate the role of dopant on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different iron-doped and activated Fe-SrTiO3 powders have been also evaluated. The results demonstrated that Fe has been substituted into the lattice and surface layers of particles of SrTiO3 powders and the absorption edge shifted to higher wavelength values with increasing activation time and dopant weight percentage. The lowest value of the band gap (Eg=3.20 eV) was registered for the longest activation (120 min) and the highest weight percentage of dopant (6 wt%). Combining doping with mechanical activation, led to lower values of Eg and that fact could be used in subsequent studies to make Fe-SrTiO3 more suitable photocatalysts.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023",
title = "Influence of Fe Doping on the Crystal Structure and Optical Properties of Mechanically Activated SrTiO3 Powders",
pages = "51-51",
url = "https://hdl.handle.net/21.15107/rcub_dais_15007"
}
Živojinović, J., Peleš Tadić, A., Kosanović, D., Tadić, N., Vasiljević, Z. Ž., Lević, S.,& Obradović, N.. (2023). Influence of Fe Doping on the Crystal Structure and Optical Properties of Mechanically Activated SrTiO3 Powders. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
Belgrade : Serbian Ceramic Society., 51-51.
https://hdl.handle.net/21.15107/rcub_dais_15007
Živojinović J, Peleš Tadić A, Kosanović D, Tadić N, Vasiljević ZŽ, Lević S, Obradović N. Influence of Fe Doping on the Crystal Structure and Optical Properties of Mechanically Activated SrTiO3 Powders. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023. 2023;:51-51.
https://hdl.handle.net/21.15107/rcub_dais_15007 .
Živojinović, Jelena, Peleš Tadić, Adriana, Kosanović, Darko, Tadić, Nenad, Vasiljević, Zorka Ž., Lević, Steva, Obradović, Nina, "Influence of Fe Doping on the Crystal Structure and Optical Properties of Mechanically Activated SrTiO3 Powders" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023 (2023):51-51,
https://hdl.handle.net/21.15107/rcub_dais_15007 .

Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics

Živojinović, Jelena; Kosanović, Darko; Blagojević, Vladimir A.; Pavlović, Vera P.; Tadić, Nenad; Vlahović, Branislav; Pavlović, Vladimir B.

(2022)

TY  - JOUR
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vera P.
AU  - Tadić, Nenad
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13510
AB  - In this study, microstructure evolution and dielectric properties of SrTiO3 ceramic have been investigated, whereby mechanical activation of SrTiO3 powders was used to modify the functional properties of ceramic materials. Microstructural SEM analysis of SrTiO3 ceramics showed that the increase in mechanical activation time results in less porous samples. Raman spectroscopy indicated changes in the broadening and asymmetry of the TO2 mode with a change in the time of mechanical activation. TO2 mode showed a Fano asymmetry due to its interaction with polarization fluctuations in polar micro-regions, which are a consequence of the presence of oxygen vacancies caused by activation. The maximum value of dielectric permittivity was observed in the sample activated for 10 min. Also, the sample activated for 10 min exhibits relatively low values of loss tangent, compared to the other mechanically activated samples, providing the best overall dielectric performance compared to other samples.
T2  - Science of Sintering
T1  - Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics
SP  - 401
EP  - 414
VL  - 54
IS  - 4
DO  - 10.2298/SOS2204401Z
UR  - https://hdl.handle.net/21.15107/rcub_dais_13510
ER  - 
@article{
author = "Živojinović, Jelena and Kosanović, Darko and Blagojević, Vladimir A. and Pavlović, Vera P. and Tadić, Nenad and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2022",
abstract = "In this study, microstructure evolution and dielectric properties of SrTiO3 ceramic have been investigated, whereby mechanical activation of SrTiO3 powders was used to modify the functional properties of ceramic materials. Microstructural SEM analysis of SrTiO3 ceramics showed that the increase in mechanical activation time results in less porous samples. Raman spectroscopy indicated changes in the broadening and asymmetry of the TO2 mode with a change in the time of mechanical activation. TO2 mode showed a Fano asymmetry due to its interaction with polarization fluctuations in polar micro-regions, which are a consequence of the presence of oxygen vacancies caused by activation. The maximum value of dielectric permittivity was observed in the sample activated for 10 min. Also, the sample activated for 10 min exhibits relatively low values of loss tangent, compared to the other mechanically activated samples, providing the best overall dielectric performance compared to other samples.",
journal = "Science of Sintering",
title = "Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics",
pages = "401-414",
volume = "54",
number = "4",
doi = "10.2298/SOS2204401Z",
url = "https://hdl.handle.net/21.15107/rcub_dais_13510"
}
Živojinović, J., Kosanović, D., Blagojević, V. A., Pavlović, V. P., Tadić, N., Vlahović, B.,& Pavlović, V. B.. (2022). Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics. in Science of Sintering, 54(4), 401-414.
https://doi.org/10.2298/SOS2204401Z
https://hdl.handle.net/21.15107/rcub_dais_13510
Živojinović J, Kosanović D, Blagojević VA, Pavlović VP, Tadić N, Vlahović B, Pavlović VB. Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics. in Science of Sintering. 2022;54(4):401-414.
doi:10.2298/SOS2204401Z
https://hdl.handle.net/21.15107/rcub_dais_13510 .
Živojinović, Jelena, Kosanović, Darko, Blagojević, Vladimir A., Pavlović, Vera P., Tadić, Nenad, Vlahović, Branislav, Pavlović, Vladimir B., "Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics" in Science of Sintering, 54, no. 4 (2022):401-414,
https://doi.org/10.2298/SOS2204401Z .,
https://hdl.handle.net/21.15107/rcub_dais_13510 .
3

Study of influence of Mn dopant on dielectric response of SrTiO3 ceramics

Živojinović, Jelena; Kosanović, Darko; Pavlović, Vera P.; Tadić, Nenad; Pavlović, Vladimir B.

(Belgrade : Materials Research Society of Serbia, 2022)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Pavlović, Vera P.
AU  - Tadić, Nenad
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13596
AB  - The influence of Mn incorporation into the Sr and Ti sites of SrTiO3 ceramics on the structure, microstructure and dielectric tunability was studied. Manganese doped SrTiO3 ceramics with various manganese dioxide weight percentages (1.5, 3 and 6 wt %) were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). According to Ritveld's analysis it was found that the size of the crystallite in doped activated SrTiO3 ceramics is smaller than the size of the crystallite in undoped ceramics. This lower degree of crystallinity is a consequence of additional distortion of the crystal structure due to ion substitution. SEM analysis showed that with increasing dopant concentration in the sample, at the same time as a time of mechanical activation, the grain size decreases, which is explained by the increasingly dominant incorporation of Mn4+ ions at sites of Ti4+ ions. On the Raman spectra of doped ceramic samples, the appearance of a peak at 750 cm-1 was observed, its change in intensity with the increase of dopant concentration indicates the incorporation of dopant in the SrTiO3 lattice. It was stated that mechanical activation leads to a more pronounced increase in the intensity of the mentioned peak, i.e. that activation leads to effectively higher incorporation of dopant into the strontium-titanate lattice. Higher values of relative dielectric permittivity of doped SrTiO3 ceramics were observed for 1.5 wt %, in relation to inactivated and activated undoped ceramics. Based on all previous analysis, it is estimated that this can be related not only to higher sample densities but also to the contribution of Mn2+ ion incorporation at Sr2+ ion positions in the lattice. Based on all the above, the optimal electrical properties of SrTiO3 ceramics can be achieved by the appropriate choice of mechanical activation time and dopant concentration.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
T1  - Study of influence of Mn dopant on dielectric response of SrTiO3 ceramics
SP  - 131
EP  - 131
UR  - https://hdl.handle.net/21.15107/rcub_dais_13596
ER  - 
@conference{
author = "Živojinović, Jelena and Kosanović, Darko and Pavlović, Vera P. and Tadić, Nenad and Pavlović, Vladimir B.",
year = "2022",
abstract = "The influence of Mn incorporation into the Sr and Ti sites of SrTiO3 ceramics on the structure, microstructure and dielectric tunability was studied. Manganese doped SrTiO3 ceramics with various manganese dioxide weight percentages (1.5, 3 and 6 wt %) were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). According to Ritveld's analysis it was found that the size of the crystallite in doped activated SrTiO3 ceramics is smaller than the size of the crystallite in undoped ceramics. This lower degree of crystallinity is a consequence of additional distortion of the crystal structure due to ion substitution. SEM analysis showed that with increasing dopant concentration in the sample, at the same time as a time of mechanical activation, the grain size decreases, which is explained by the increasingly dominant incorporation of Mn4+ ions at sites of Ti4+ ions. On the Raman spectra of doped ceramic samples, the appearance of a peak at 750 cm-1 was observed, its change in intensity with the increase of dopant concentration indicates the incorporation of dopant in the SrTiO3 lattice. It was stated that mechanical activation leads to a more pronounced increase in the intensity of the mentioned peak, i.e. that activation leads to effectively higher incorporation of dopant into the strontium-titanate lattice. Higher values of relative dielectric permittivity of doped SrTiO3 ceramics were observed for 1.5 wt %, in relation to inactivated and activated undoped ceramics. Based on all previous analysis, it is estimated that this can be related not only to higher sample densities but also to the contribution of Mn2+ ion incorporation at Sr2+ ion positions in the lattice. Based on all the above, the optimal electrical properties of SrTiO3 ceramics can be achieved by the appropriate choice of mechanical activation time and dopant concentration.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022",
title = "Study of influence of Mn dopant on dielectric response of SrTiO3 ceramics",
pages = "131-131",
url = "https://hdl.handle.net/21.15107/rcub_dais_13596"
}
Živojinović, J., Kosanović, D., Pavlović, V. P., Tadić, N.,& Pavlović, V. B.. (2022). Study of influence of Mn dopant on dielectric response of SrTiO3 ceramics. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
Belgrade : Materials Research Society of Serbia., 131-131.
https://hdl.handle.net/21.15107/rcub_dais_13596
Živojinović J, Kosanović D, Pavlović VP, Tadić N, Pavlović VB. Study of influence of Mn dopant on dielectric response of SrTiO3 ceramics. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022. 2022;:131-131.
https://hdl.handle.net/21.15107/rcub_dais_13596 .
Živojinović, Jelena, Kosanović, Darko, Pavlović, Vera P., Tadić, Nenad, Pavlović, Vladimir B., "Study of influence of Mn dopant on dielectric response of SrTiO3 ceramics" in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022 (2022):131-131,
https://hdl.handle.net/21.15107/rcub_dais_13596 .

Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders

Živojinović, Jelena; Kosanović, Darko; Blagojević, Vladimir A.; Pavlović, Vera P.; Ćirković, Jovana; Pavlović, Vladimir B.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2022)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vera P.
AU  - Ćirković, Jovana
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13600
AB  - Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher values of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme [Elektronski izvor] ; and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022, 05-08 July 2022, Zlatibor, Serbia
T1  - Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders
SP  - 82
EP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_dais_13600
ER  - 
@conference{
author = "Živojinović, Jelena and Kosanović, Darko and Blagojević, Vladimir A. and Pavlović, Vera P. and Ćirković, Jovana and Pavlović, Vladimir B.",
year = "2022",
abstract = "Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher values of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme [Elektronski izvor] ; and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022, 05-08 July 2022, Zlatibor, Serbia",
title = "Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders",
pages = "82-82",
url = "https://hdl.handle.net/21.15107/rcub_dais_13600"
}
Živojinović, J., Kosanović, D., Blagojević, V. A., Pavlović, V. P., Ćirković, J.,& Pavlović, V. B.. (2022). Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders. in Programme [Elektronski izvor] ; and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022, 05-08 July 2022, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 82-82.
https://hdl.handle.net/21.15107/rcub_dais_13600
Živojinović J, Kosanović D, Blagojević VA, Pavlović VP, Ćirković J, Pavlović VB. Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders. in Programme [Elektronski izvor] ; and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022, 05-08 July 2022, Zlatibor, Serbia. 2022;:82-82.
https://hdl.handle.net/21.15107/rcub_dais_13600 .
Živojinović, Jelena, Kosanović, Darko, Blagojević, Vladimir A., Pavlović, Vera P., Ćirković, Jovana, Pavlović, Vladimir B., "Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders" in Programme [Elektronski izvor] ; and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022, 05-08 July 2022, Zlatibor, Serbia (2022):82-82,
https://hdl.handle.net/21.15107/rcub_dais_13600 .

The influence of mechanical activation on microstructure and dielectric properties of SrTiO3 ceramics

Živojinović, Jelena; Blagojević, Vladimir A.; Pavlović, Vera P.; Kosanović, Darko; Tadić, Nenad B.; Pavlović, Vladimir B.

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vera P.
AU  - Kosanović, Darko
AU  - Tadić, Nenad B.
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12349
AB  - In recent years, a lot of interest has been shown in obtaining materials with predetermined properties. The aim is to establish a functional dependence between the synthesis parameters, structural characteristics, and properties of the material. Ceramic materials based on strontium titanate (SrTiO3) are of special interest due to their unique physical-chemical properties. Having in mind the importance of examining the influence of synthesis parameters on the process of obtaining and properties of functional electroceramic materials, and the importance of SrTiO3 as a perovskite material, the motive was to analyze and consider the influence of mechanical activation. It has been established that the time of mechanical activation (0, 10, 30, 60, 90, and 120 minutes) of SrTiO3 powders indirectly affects on electrical properties of SrTiO3 ceramics. It was noticed that in SrTiO3 ceramics the values of relative dielectric permittivity in the radio frequency range (0,3 MHz-3 GHz) are stable, which is important for the fabrication of electronic components. Microstructural SEM analysis showed that the increase in mechanical activation time results in less porous samples. It was found that the value of the relative dielectric permittivity of ceramic samples at room temperature changes following the combined effect of changes in sample density, grain size, as well as changes in the grain boundary region. The maximum value of dielectric permittivity was observed in the sample activated for 10 minutes. Also, the sample activated for 10 min exhibits relatively low values of loss tangent, compared to the other mechanically activated samples, providing the best overall dielectric performance compared to other samples.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
T1  - The influence of mechanical activation on microstructure and dielectric properties of SrTiO3 ceramics
SP  - 80
EP  - 80
UR  - https://hdl.handle.net/21.15107/rcub_dais_12349
ER  - 
@conference{
author = "Živojinović, Jelena and Blagojević, Vladimir A. and Pavlović, Vera P. and Kosanović, Darko and Tadić, Nenad B. and Pavlović, Vladimir B.",
year = "2021",
abstract = "In recent years, a lot of interest has been shown in obtaining materials with predetermined properties. The aim is to establish a functional dependence between the synthesis parameters, structural characteristics, and properties of the material. Ceramic materials based on strontium titanate (SrTiO3) are of special interest due to their unique physical-chemical properties. Having in mind the importance of examining the influence of synthesis parameters on the process of obtaining and properties of functional electroceramic materials, and the importance of SrTiO3 as a perovskite material, the motive was to analyze and consider the influence of mechanical activation. It has been established that the time of mechanical activation (0, 10, 30, 60, 90, and 120 minutes) of SrTiO3 powders indirectly affects on electrical properties of SrTiO3 ceramics. It was noticed that in SrTiO3 ceramics the values of relative dielectric permittivity in the radio frequency range (0,3 MHz-3 GHz) are stable, which is important for the fabrication of electronic components. Microstructural SEM analysis showed that the increase in mechanical activation time results in less porous samples. It was found that the value of the relative dielectric permittivity of ceramic samples at room temperature changes following the combined effect of changes in sample density, grain size, as well as changes in the grain boundary region. The maximum value of dielectric permittivity was observed in the sample activated for 10 minutes. Also, the sample activated for 10 min exhibits relatively low values of loss tangent, compared to the other mechanically activated samples, providing the best overall dielectric performance compared to other samples.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia",
title = "The influence of mechanical activation on microstructure and dielectric properties of SrTiO3 ceramics",
pages = "80-80",
url = "https://hdl.handle.net/21.15107/rcub_dais_12349"
}
Živojinović, J., Blagojević, V. A., Pavlović, V. P., Kosanović, D., Tadić, N. B.,& Pavlović, V. B.. (2021). The influence of mechanical activation on microstructure and dielectric properties of SrTiO3 ceramics. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 80-80.
https://hdl.handle.net/21.15107/rcub_dais_12349
Živojinović J, Blagojević VA, Pavlović VP, Kosanović D, Tadić NB, Pavlović VB. The influence of mechanical activation on microstructure and dielectric properties of SrTiO3 ceramics. in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia. 2021;:80-80.
https://hdl.handle.net/21.15107/rcub_dais_12349 .
Živojinović, Jelena, Blagojević, Vladimir A., Pavlović, Vera P., Kosanović, Darko, Tadić, Nenad B., Pavlović, Vladimir B., "The influence of mechanical activation on microstructure and dielectric properties of SrTiO3 ceramics" in Programme and The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2021,29 June - 02 July 2021, Zlatibor, Serbia (2021):80-80,
https://hdl.handle.net/21.15107/rcub_dais_12349 .

Point defects and their effect on dielectric permittivity in strontium titanate ceramics

Kosanović, Darko; Živojinović, Jelena; Vujančević, Jelena; Peleš, Adriana; Blagojević, Vladimir

(Belgrade : ETRAN, 2021)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Vujančević, Jelena
AU  - Peleš, Adriana
AU  - Blagojević, Vladimir
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12344
AB  - The origin of dielectric properties of strontium titanate ceramics is investigated using DFT calculations in periodic system. It was determined that the main factors contributing to the increase in dielectric permittivity are: tetragonal distortion of the normally cubic lattice, and charge imbalance induced displacement of titanium center from its central position. Oxygen vacancies were determined to create significantly larger effects than other types of vacancies, like Ti and SrO. The extent of tetragonal distortion was found to be determined by oxygen vacancy distribution, rather than total concentration: relatively symmetrical distribution of oxygen vacancies resulted in smaller tetragonal distortion of the lattice, and, consequently, smaller increase in dielectric permittivity. Charge imbalance naturally destabilizes the cubic lattice, forcing the Ti-atom out of its central position, resulting in tetragonal lattice with increased dielectric permittivity. The process stabilizes the strontium titanate lattice, while increasing the c/a ratio. Therefore, the dielectric permittivity of strontium titanate can be increased by changes to the system that increase tetragonal distortion of the lattice and/or introduce additional negative charge.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Point defects and their effect on dielectric permittivity in strontium titanate ceramics
SP  - 285
EP  - 299
VL  - 53
IS  - 3
DO  - 10.2298/SOS2103285K
UR  - https://hdl.handle.net/21.15107/rcub_dais_12344
ER  - 
@article{
author = "Kosanović, Darko and Živojinović, Jelena and Vujančević, Jelena and Peleš, Adriana and Blagojević, Vladimir",
year = "2021",
abstract = "The origin of dielectric properties of strontium titanate ceramics is investigated using DFT calculations in periodic system. It was determined that the main factors contributing to the increase in dielectric permittivity are: tetragonal distortion of the normally cubic lattice, and charge imbalance induced displacement of titanium center from its central position. Oxygen vacancies were determined to create significantly larger effects than other types of vacancies, like Ti and SrO. The extent of tetragonal distortion was found to be determined by oxygen vacancy distribution, rather than total concentration: relatively symmetrical distribution of oxygen vacancies resulted in smaller tetragonal distortion of the lattice, and, consequently, smaller increase in dielectric permittivity. Charge imbalance naturally destabilizes the cubic lattice, forcing the Ti-atom out of its central position, resulting in tetragonal lattice with increased dielectric permittivity. The process stabilizes the strontium titanate lattice, while increasing the c/a ratio. Therefore, the dielectric permittivity of strontium titanate can be increased by changes to the system that increase tetragonal distortion of the lattice and/or introduce additional negative charge.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Point defects and their effect on dielectric permittivity in strontium titanate ceramics",
pages = "285-299",
volume = "53",
number = "3",
doi = "10.2298/SOS2103285K",
url = "https://hdl.handle.net/21.15107/rcub_dais_12344"
}
Kosanović, D., Živojinović, J., Vujančević, J., Peleš, A.,& Blagojević, V.. (2021). Point defects and their effect on dielectric permittivity in strontium titanate ceramics. in Science of Sintering
Belgrade : ETRAN., 53(3), 285-299.
https://doi.org/10.2298/SOS2103285K
https://hdl.handle.net/21.15107/rcub_dais_12344
Kosanović D, Živojinović J, Vujančević J, Peleš A, Blagojević V. Point defects and their effect on dielectric permittivity in strontium titanate ceramics. in Science of Sintering. 2021;53(3):285-299.
doi:10.2298/SOS2103285K
https://hdl.handle.net/21.15107/rcub_dais_12344 .
Kosanović, Darko, Živojinović, Jelena, Vujančević, Jelena, Peleš, Adriana, Blagojević, Vladimir, "Point defects and their effect on dielectric permittivity in strontium titanate ceramics" in Science of Sintering, 53, no. 3 (2021):285-299,
https://doi.org/10.2298/SOS2103285K .,
https://hdl.handle.net/21.15107/rcub_dais_12344 .
1
2

Raman spectra of the materials based on mechanically activated alkaline earth metal titanates

Pavlović, Vera P.; Tshantshapanyan, Ani; Vlahović, Branislav; Živojinović, Jelena; Kosanović, Darko; Pavlović, Vladimir B.

(Belgrade : ETRAN Society, 2020)

TY  - CONF
AU  - Pavlović, Vera P.
AU  - Tshantshapanyan, Ani
AU  - Vlahović, Branislav
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/14758
AB  - The changes in the Raman spectra of electronic materials obtained from mechanically activated BaTiO3 and SrTiO3 powders, with or without additives, are presented in this paper. Mechanical activation, performed in a high-energy planetary ball mill, was chosen as the method for the production of fine-grained nanocrystalline powders with an increased surface activity and an altered micro and/or crystal structure. Having in mind the growing relevance of the development of multiferroic materials, the analysis of Raman spectra was used not only for the structural investigations of the mechanically activated undoped titanate powder, but also for the examination of the mechanically activated Fe/BaTiO3 system and the subsequent hexaferrite formation during the sintering process. Additionally, Raman spectroscopy was applied in the study of the emergence of electroactive crystalline phases in nanocomposites based on semi-crystalline fluoropolymers, such as PVDF (polyvinylidene fluoride), in the case when mechanically activated BaTiO3 powder was used as a filler in the polymer matrix. Furthermore, the effects of the mechanical activation of SrTiO3 powder on the occurrence of polar nano and micro-regions at room temperature, as well as the simultaneous influence of activation and MnO2 addition on structural changes in ceramic SrTiO3 samples, have also been analysed using Raman spectroscopy.
PB  - Belgrade : ETRAN Society
PB  - Belgrade : Academic Mind
C3  - Зборник радова [Електронски извор] / 64. годишњa конференција за електронику, телекомуникације, рачунарство, аутоматику и нуклеарну технику EТРАН 2020 и 7. интернационалнa конференцијa за електротехнику, електронику и рачунарство ИцЕТРАН 2020 = 7th International Conference on Electrical, Electronic and Computing Engineering IcETRAN 2020 and 64th National Conference on Electrоnics, Telecommunication, Computing, Automatic Control and Nuclear Engineering ETRAN 2020
T1  - Raman spectra of the materials based on mechanically activated alkaline earth metal titanates
SP  - NMI 1.1.1
EP  - NMI 1.1.8
UR  - https://hdl.handle.net/21.15107/rcub_dais_14758
ER  - 
@conference{
author = "Pavlović, Vera P. and Tshantshapanyan, Ani and Vlahović, Branislav and Živojinović, Jelena and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2020",
abstract = "The changes in the Raman spectra of electronic materials obtained from mechanically activated BaTiO3 and SrTiO3 powders, with or without additives, are presented in this paper. Mechanical activation, performed in a high-energy planetary ball mill, was chosen as the method for the production of fine-grained nanocrystalline powders with an increased surface activity and an altered micro and/or crystal structure. Having in mind the growing relevance of the development of multiferroic materials, the analysis of Raman spectra was used not only for the structural investigations of the mechanically activated undoped titanate powder, but also for the examination of the mechanically activated Fe/BaTiO3 system and the subsequent hexaferrite formation during the sintering process. Additionally, Raman spectroscopy was applied in the study of the emergence of electroactive crystalline phases in nanocomposites based on semi-crystalline fluoropolymers, such as PVDF (polyvinylidene fluoride), in the case when mechanically activated BaTiO3 powder was used as a filler in the polymer matrix. Furthermore, the effects of the mechanical activation of SrTiO3 powder on the occurrence of polar nano and micro-regions at room temperature, as well as the simultaneous influence of activation and MnO2 addition on structural changes in ceramic SrTiO3 samples, have also been analysed using Raman spectroscopy.",
publisher = "Belgrade : ETRAN Society, Belgrade : Academic Mind",
journal = "Зборник радова [Електронски извор] / 64. годишњa конференција за електронику, телекомуникације, рачунарство, аутоматику и нуклеарну технику EТРАН 2020 и 7. интернационалнa конференцијa за електротехнику, електронику и рачунарство ИцЕТРАН 2020 = 7th International Conference on Electrical, Electronic and Computing Engineering IcETRAN 2020 and 64th National Conference on Electrоnics, Telecommunication, Computing, Automatic Control and Nuclear Engineering ETRAN 2020",
title = "Raman spectra of the materials based on mechanically activated alkaline earth metal titanates",
pages = "NMI 1.1.1-NMI 1.1.8",
url = "https://hdl.handle.net/21.15107/rcub_dais_14758"
}
Pavlović, V. P., Tshantshapanyan, A., Vlahović, B., Živojinović, J., Kosanović, D.,& Pavlović, V. B.. (2020). Raman spectra of the materials based on mechanically activated alkaline earth metal titanates. in Зборник радова [Електронски извор] / 64. годишњa конференција за електронику, телекомуникације, рачунарство, аутоматику и нуклеарну технику EТРАН 2020 и 7. интернационалнa конференцијa за електротехнику, електронику и рачунарство ИцЕТРАН 2020 = 7th International Conference on Electrical, Electronic and Computing Engineering IcETRAN 2020 and 64th National Conference on Electrоnics, Telecommunication, Computing, Automatic Control and Nuclear Engineering ETRAN 2020
Belgrade : ETRAN Society., NMI 1.1.1-NMI 1.1.8.
https://hdl.handle.net/21.15107/rcub_dais_14758
Pavlović VP, Tshantshapanyan A, Vlahović B, Živojinović J, Kosanović D, Pavlović VB. Raman spectra of the materials based on mechanically activated alkaline earth metal titanates. in Зборник радова [Електронски извор] / 64. годишњa конференција за електронику, телекомуникације, рачунарство, аутоматику и нуклеарну технику EТРАН 2020 и 7. интернационалнa конференцијa за електротехнику, електронику и рачунарство ИцЕТРАН 2020 = 7th International Conference on Electrical, Electronic and Computing Engineering IcETRAN 2020 and 64th National Conference on Electrоnics, Telecommunication, Computing, Automatic Control and Nuclear Engineering ETRAN 2020. 2020;:NMI 1.1.1-NMI 1.1.8.
https://hdl.handle.net/21.15107/rcub_dais_14758 .
Pavlović, Vera P., Tshantshapanyan, Ani, Vlahović, Branislav, Živojinović, Jelena, Kosanović, Darko, Pavlović, Vladimir B., "Raman spectra of the materials based on mechanically activated alkaline earth metal titanates" in Зборник радова [Електронски извор] / 64. годишњa конференција за електронику, телекомуникације, рачунарство, аутоматику и нуклеарну технику EТРАН 2020 и 7. интернационалнa конференцијa за електротехнику, електронику и рачунарство ИцЕТРАН 2020 = 7th International Conference on Electrical, Electronic and Computing Engineering IcETRAN 2020 and 64th National Conference on Electrоnics, Telecommunication, Computing, Automatic Control and Nuclear Engineering ETRAN 2020 (2020):NMI 1.1.1-NMI 1.1.8,
https://hdl.handle.net/21.15107/rcub_dais_14758 .

Effects of Mechanical Activation on the Formation and Sintering Kinetics of Barium Strontium Titanate Ceramics

Kosanović, Darko; Labus, Nebojša; Živojinović, Jelena; Peleš Tadić, Adriana; Blagojević, Vladimir A.; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2020)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Labus, Nebojša
AU  - Živojinović, Jelena
AU  - Peleš Tadić, Adriana
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10039
AB  - The influence of mechanical activation on the formation, sintering kinetics and morphology was investigated in sintered barium strontium titanate (BST) ceramics with different Ba-to-Sr ratios. Initial powders were mechanically activated for 20 and 120 min, leading to mechano-chemical reaction and formation of BaxSr1-xTiO3 phases. Agglomeration was found to represent an important factor in the process of formation of BaxSr1-xTiO3 phases around 800 oC and during sintering. It reduces the effectiveness of mechanical activation on formation of BaxSr1-xTiO3 phases beyond the short period (20 min), while in the process of sintering, prolonged mechanical activation (120 min) leads to a significant reduction in sintering temperature and the corresponding value of activation energy. In addition, all three systems show a phase transformation around 1100 oC, attributed to the hexagonal-to-cubic phase transition. Morphology of the final sintered ceramics can be correlated primarily with the state of the pre-sintered powder, where mechanically activated powders with smaller particle size produced more compact and less porous final product.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Effects of Mechanical Activation on the Formation and Sintering Kinetics of Barium Strontium Titanate Ceramics
SP  - 371
EP  - 385
VL  - 52
IS  - 4
DO  - 10.2298/SOS2004371K
UR  - https://hdl.handle.net/21.15107/rcub_dais_10039
ER  - 
@article{
author = "Kosanović, Darko and Labus, Nebojša and Živojinović, Jelena and Peleš Tadić, Adriana and Blagojević, Vladimir A. and Pavlović, Vladimir B.",
year = "2020",
abstract = "The influence of mechanical activation on the formation, sintering kinetics and morphology was investigated in sintered barium strontium titanate (BST) ceramics with different Ba-to-Sr ratios. Initial powders were mechanically activated for 20 and 120 min, leading to mechano-chemical reaction and formation of BaxSr1-xTiO3 phases. Agglomeration was found to represent an important factor in the process of formation of BaxSr1-xTiO3 phases around 800 oC and during sintering. It reduces the effectiveness of mechanical activation on formation of BaxSr1-xTiO3 phases beyond the short period (20 min), while in the process of sintering, prolonged mechanical activation (120 min) leads to a significant reduction in sintering temperature and the corresponding value of activation energy. In addition, all three systems show a phase transformation around 1100 oC, attributed to the hexagonal-to-cubic phase transition. Morphology of the final sintered ceramics can be correlated primarily with the state of the pre-sintered powder, where mechanically activated powders with smaller particle size produced more compact and less porous final product.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Effects of Mechanical Activation on the Formation and Sintering Kinetics of Barium Strontium Titanate Ceramics",
pages = "371-385",
volume = "52",
number = "4",
doi = "10.2298/SOS2004371K",
url = "https://hdl.handle.net/21.15107/rcub_dais_10039"
}
Kosanović, D., Labus, N., Živojinović, J., Peleš Tadić, A., Blagojević, V. A.,& Pavlović, V. B.. (2020). Effects of Mechanical Activation on the Formation and Sintering Kinetics of Barium Strontium Titanate Ceramics. in Science of Sintering
Belgrade : ETRAN., 52(4), 371-385.
https://doi.org/10.2298/SOS2004371K
https://hdl.handle.net/21.15107/rcub_dais_10039
Kosanović D, Labus N, Živojinović J, Peleš Tadić A, Blagojević VA, Pavlović VB. Effects of Mechanical Activation on the Formation and Sintering Kinetics of Barium Strontium Titanate Ceramics. in Science of Sintering. 2020;52(4):371-385.
doi:10.2298/SOS2004371K
https://hdl.handle.net/21.15107/rcub_dais_10039 .
Kosanović, Darko, Labus, Nebojša, Živojinović, Jelena, Peleš Tadić, Adriana, Blagojević, Vladimir A., Pavlović, Vladimir B., "Effects of Mechanical Activation on the Formation and Sintering Kinetics of Barium Strontium Titanate Ceramics" in Science of Sintering, 52, no. 4 (2020):371-385,
https://doi.org/10.2298/SOS2004371K .,
https://hdl.handle.net/21.15107/rcub_dais_10039 .
6

Analysis of the initial-stage sintering of mechanically activated SrTiO3

Živojinović, Jelena; Pavlović, Vera P.; Labus, Nebojša; Blagojević, Vladimir A.; Kosanović, Darko; Pavlović, Vladimir B.

(ETRAN, 2019)

TY  - JOUR
AU  - Živojinović, Jelena
AU  - Pavlović, Vera P.
AU  - Labus, Nebojša
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6885
AB  - The initial-stage of sintering plays a significant role in determining the final microstructure that defines the main characteristics of electroceramics materials such as functional properties. In this article non-isothermal sintering of non-activated and mechanically activated SrTiO3 samples was investigated up to 1300 °C. Dilatometric curves indicate that mechanical activation leads to an earlier onset of sintering, suggesting that it should lead to a more homogenous and denser sintered product. Analysis of the initial stage of sintering reveals that the sintering process of all examinated samples consists of two or three overlapping single-step processes, with a change in the dominant mass transport mechanism. The values of apparent activation energy of the considered single-step process exhibit a significant decrease with an increase in mechanical activation time. The values of the density of samples after isothermal sintering indicate that the final stage of sintering has not been reached by 1300 °C. © 2018 Authors.
PB  - ETRAN
T2  - Science of Sintering
T1  - Analysis of the initial-stage sintering of mechanically activated SrTiO3
SP  - 199
EP  - 208
VL  - 51
IS  - 2
DO  - 10.2298/SOS1902199Z
UR  - https://hdl.handle.net/21.15107/rcub_dais_6885
ER  - 
@article{
author = "Živojinović, Jelena and Pavlović, Vera P. and Labus, Nebojša and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2019",
abstract = "The initial-stage of sintering plays a significant role in determining the final microstructure that defines the main characteristics of electroceramics materials such as functional properties. In this article non-isothermal sintering of non-activated and mechanically activated SrTiO3 samples was investigated up to 1300 °C. Dilatometric curves indicate that mechanical activation leads to an earlier onset of sintering, suggesting that it should lead to a more homogenous and denser sintered product. Analysis of the initial stage of sintering reveals that the sintering process of all examinated samples consists of two or three overlapping single-step processes, with a change in the dominant mass transport mechanism. The values of apparent activation energy of the considered single-step process exhibit a significant decrease with an increase in mechanical activation time. The values of the density of samples after isothermal sintering indicate that the final stage of sintering has not been reached by 1300 °C. © 2018 Authors.",
publisher = "ETRAN",
journal = "Science of Sintering",
title = "Analysis of the initial-stage sintering of mechanically activated SrTiO3",
pages = "199-208",
volume = "51",
number = "2",
doi = "10.2298/SOS1902199Z",
url = "https://hdl.handle.net/21.15107/rcub_dais_6885"
}
Živojinović, J., Pavlović, V. P., Labus, N., Blagojević, V. A., Kosanović, D.,& Pavlović, V. B.. (2019). Analysis of the initial-stage sintering of mechanically activated SrTiO3. in Science of Sintering
ETRAN., 51(2), 199-208.
https://doi.org/10.2298/SOS1902199Z
https://hdl.handle.net/21.15107/rcub_dais_6885
Živojinović J, Pavlović VP, Labus N, Blagojević VA, Kosanović D, Pavlović VB. Analysis of the initial-stage sintering of mechanically activated SrTiO3. in Science of Sintering. 2019;51(2):199-208.
doi:10.2298/SOS1902199Z
https://hdl.handle.net/21.15107/rcub_dais_6885 .
Živojinović, Jelena, Pavlović, Vera P., Labus, Nebojša, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir B., "Analysis of the initial-stage sintering of mechanically activated SrTiO3" in Science of Sintering, 51, no. 2 (2019):199-208,
https://doi.org/10.2298/SOS1902199Z .,
https://hdl.handle.net/21.15107/rcub_dais_6885 .
2
4
5

The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders

Živojinović, Jelena; Pavlović, Vera P.; Kosanović, Darko; Marković, Smilja; Krstić, Jugoslav; Blagojević, Vladimir A.; Pavlović, Vladimir B.

(Elsevier, 2017)

TY  - JOUR
AU  - Živojinović, Jelena
AU  - Pavlović, Vera P.
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Krstić, Jugoslav
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/4617
AB  - Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 μm in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders
SP  - 863
EP  - 870
VL  - 695
DO  - 10.1016/j.jallcom.2016.10.159
UR  - https://hdl.handle.net/21.15107/rcub_dais_4617
ER  - 
@article{
author = "Živojinović, Jelena and Pavlović, Vera P. and Kosanović, Darko and Marković, Smilja and Krstić, Jugoslav and Blagojević, Vladimir A. and Pavlović, Vladimir B.",
year = "2017",
abstract = "Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 μm in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders",
pages = "863-870",
volume = "695",
doi = "10.1016/j.jallcom.2016.10.159",
url = "https://hdl.handle.net/21.15107/rcub_dais_4617"
}
Živojinović, J., Pavlović, V. P., Kosanović, D., Marković, S., Krstić, J., Blagojević, V. A.,& Pavlović, V. B.. (2017). The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds
Elsevier., 695, 863-870.
https://doi.org/10.1016/j.jallcom.2016.10.159
https://hdl.handle.net/21.15107/rcub_dais_4617
Živojinović J, Pavlović VP, Kosanović D, Marković S, Krstić J, Blagojević VA, Pavlović VB. The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds. 2017;695:863-870.
doi:10.1016/j.jallcom.2016.10.159
https://hdl.handle.net/21.15107/rcub_dais_4617 .
Živojinović, Jelena, Pavlović, Vera P., Kosanović, Darko, Marković, Smilja, Krstić, Jugoslav, Blagojević, Vladimir A., Pavlović, Vladimir B., "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders" in Journal of Alloys and Compounds, 695 (2017):863-870,
https://doi.org/10.1016/j.jallcom.2016.10.159 .,
https://hdl.handle.net/21.15107/rcub_dais_4617 .
21
13
24

The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders

Živojinović, Jelena; Pavlović, Vera P.; Kosanović, Darko; Marković, Smilja; Krstić, Jugoslav; Blagojević, Vladimir A.; Pavlović, Vladimir B.

(Elsevier, 2017)

TY  - JOUR
AU  - Živojinović, Jelena
AU  - Pavlović, Vera P.
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Krstić, Jugoslav
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/2355
AB  - Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 μm in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders
SP  - 863
EP  - 870
VL  - 695
DO  - 10.1016/j.jallcom.2016.10.159
UR  - https://hdl.handle.net/21.15107/rcub_dais_2355
ER  - 
@article{
author = "Živojinović, Jelena and Pavlović, Vera P. and Kosanović, Darko and Marković, Smilja and Krstić, Jugoslav and Blagojević, Vladimir A. and Pavlović, Vladimir B.",
year = "2017",
abstract = "Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 μm in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders",
pages = "863-870",
volume = "695",
doi = "10.1016/j.jallcom.2016.10.159",
url = "https://hdl.handle.net/21.15107/rcub_dais_2355"
}
Živojinović, J., Pavlović, V. P., Kosanović, D., Marković, S., Krstić, J., Blagojević, V. A.,& Pavlović, V. B.. (2017). The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds
Elsevier., 695, 863-870.
https://doi.org/10.1016/j.jallcom.2016.10.159
https://hdl.handle.net/21.15107/rcub_dais_2355
Živojinović J, Pavlović VP, Kosanović D, Marković S, Krstić J, Blagojević VA, Pavlović VB. The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds. 2017;695:863-870.
doi:10.1016/j.jallcom.2016.10.159
https://hdl.handle.net/21.15107/rcub_dais_2355 .
Živojinović, Jelena, Pavlović, Vera P., Kosanović, Darko, Marković, Smilja, Krstić, Jugoslav, Blagojević, Vladimir A., Pavlović, Vladimir B., "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders" in Journal of Alloys and Compounds, 695 (2017):863-870,
https://doi.org/10.1016/j.jallcom.2016.10.159 .,
https://hdl.handle.net/21.15107/rcub_dais_2355 .
21
13
24

Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites

Živojinović, Jelena; Peleš, Adriana; Blagojević, Vladimir A.; Kosanović, Darko; Pavlović, Vladimir B.

(2016)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Peleš, Adriana
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/861
AB  - Mechanical activation leads to the creation of new surfaces and decrease in particle size of the initial powder particles, which affects the crystallization of PVDF matrix.  In addition, prolonged mechanical activation leads to agglomeration of nanoparticles agglomerates of different sizes. 
Microstructural changes due to mechanical activation in ZnO, BaTiO3, SrTiO3 and TiO2 powders were investigated using electron microscopy (TEM and SEM), x-ray diffraction (XRD) and particle size analysis (PSA). These were correlated with molecular simulations of mechanical properties of PVDF-nanocluster composites with different oxide nanocluster sizes (1, 1.5 and 2 nm) 
Each system was simulated using a periodic system of metal oxide nanocrystal inside β-PVDF matrix. β-PVDF was chosen for its superior properties over α- and γ- phases. Geometry of each system was optimized prior to the calculation of mechanical properties using GULP v4.3 software package. 
Molecular simulations show that, in general, mechanical properties (Young modulus as an indication of elasticity, Shear modulus as an indication of hardness) for all systems improve with decrease in nanocluster size. This suggests that mechanical activation of fillers in PVDF-metal oxide nanoparticle composites should have a positive effect on the mechanical properties of composite systems. 
This suggests mechanical activation as an easy an inexpensive method of improving mechanical properties of polymer-nanocrystal composite materials.
T1  - Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites
UR  - https://hdl.handle.net/21.15107/rcub_dais_861
ER  - 
@conference{
author = "Živojinović, Jelena and Peleš, Adriana and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2016",
abstract = "Mechanical activation leads to the creation of new surfaces and decrease in particle size of the initial powder particles, which affects the crystallization of PVDF matrix.  In addition, prolonged mechanical activation leads to agglomeration of nanoparticles agglomerates of different sizes. 
Microstructural changes due to mechanical activation in ZnO, BaTiO3, SrTiO3 and TiO2 powders were investigated using electron microscopy (TEM and SEM), x-ray diffraction (XRD) and particle size analysis (PSA). These were correlated with molecular simulations of mechanical properties of PVDF-nanocluster composites with different oxide nanocluster sizes (1, 1.5 and 2 nm) 
Each system was simulated using a periodic system of metal oxide nanocrystal inside β-PVDF matrix. β-PVDF was chosen for its superior properties over α- and γ- phases. Geometry of each system was optimized prior to the calculation of mechanical properties using GULP v4.3 software package. 
Molecular simulations show that, in general, mechanical properties (Young modulus as an indication of elasticity, Shear modulus as an indication of hardness) for all systems improve with decrease in nanocluster size. This suggests that mechanical activation of fillers in PVDF-metal oxide nanoparticle composites should have a positive effect on the mechanical properties of composite systems. 
This suggests mechanical activation as an easy an inexpensive method of improving mechanical properties of polymer-nanocrystal composite materials.",
title = "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites",
url = "https://hdl.handle.net/21.15107/rcub_dais_861"
}
Živojinović, J., Peleš, A., Blagojević, V. A., Kosanović, D.,& Pavlović, V. B.. (2016). Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. .
https://hdl.handle.net/21.15107/rcub_dais_861
Živojinović J, Peleš A, Blagojević VA, Kosanović D, Pavlović VB. Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. 2016;.
https://hdl.handle.net/21.15107/rcub_dais_861 .
Živojinović, Jelena, Peleš, Adriana, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir B., "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites" (2016),
https://hdl.handle.net/21.15107/rcub_dais_861 .

Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites

Živojinović, Jelena; Peleš, Adriana; Blagojević, Vladimir A.; Kosanović, Darko; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2016)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Peleš, Adriana
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - https://dais.sanu.ac.rs/123456789/882
AB  - The influence of mechanically activated fillers (ZnO, BaTiO3 and SrTiO3 ultra-fine powders) on mechanical properties of poly(vinylidene) fluoride (PVDF) and oxide nanoparticle composite was investigated using molecular simulations. Mechanical activation leads to the creation of new surfaces and the comminution of the initial powder particles, which affects the crystallization of PVDF matrix. In addition, prolonged mechanical activation leads to agglomeration of nanoparticles into “soft” and “hard” agglomerates of different sizes. All of this has a significant effect on mechanical properties of PVDF-nanoparticle composites. Microstructural changes due to mechanical activation in ZnO, BaTiO3 and SrTiO3 powders were investigated using SEM and XRD, while dependence of mechanical properties on nanoparticle size was investigated using molecular simulation. These show that smaller nanoparticles significantly enhance the mechanical properties of PVDF-nanoparticle composite and allow use of mechanical activation as a means of reducing the amount of nanoparticle filler in the composite, while achieving the same of superior mechanical properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
T1  - Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites
SP  - 63
EP  - 64
UR  - https://hdl.handle.net/21.15107/rcub_dais_882
ER  - 
@conference{
author = "Živojinović, Jelena and Peleš, Adriana and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2016",
abstract = "The influence of mechanically activated fillers (ZnO, BaTiO3 and SrTiO3 ultra-fine powders) on mechanical properties of poly(vinylidene) fluoride (PVDF) and oxide nanoparticle composite was investigated using molecular simulations. Mechanical activation leads to the creation of new surfaces and the comminution of the initial powder particles, which affects the crystallization of PVDF matrix. In addition, prolonged mechanical activation leads to agglomeration of nanoparticles into “soft” and “hard” agglomerates of different sizes. All of this has a significant effect on mechanical properties of PVDF-nanoparticle composites. Microstructural changes due to mechanical activation in ZnO, BaTiO3 and SrTiO3 powders were investigated using SEM and XRD, while dependence of mechanical properties on nanoparticle size was investigated using molecular simulation. These show that smaller nanoparticles significantly enhance the mechanical properties of PVDF-nanoparticle composite and allow use of mechanical activation as a means of reducing the amount of nanoparticle filler in the composite, while achieving the same of superior mechanical properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade",
title = "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites",
pages = "63-64",
url = "https://hdl.handle.net/21.15107/rcub_dais_882"
}
Živojinović, J., Peleš, A., Blagojević, V. A., Kosanović, D.,& Pavlović, V. B.. (2016). Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
Belgrade : Serbian Ceramic Society., 63-64.
https://hdl.handle.net/21.15107/rcub_dais_882
Živojinović J, Peleš A, Blagojević VA, Kosanović D, Pavlović VB. Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade. 2016;:63-64.
https://hdl.handle.net/21.15107/rcub_dais_882 .
Živojinović, Jelena, Peleš, Adriana, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir B., "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade (2016):63-64,
https://hdl.handle.net/21.15107/rcub_dais_882 .

The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics

Kosanović, Darko; Živojinović, Jelena; Obradović, Nina; Pavlović, Vera P.; Pavlović, Vladimir B.; Peleš, Adriana; Ristić, Momčilo M.

(Elsevier, 2014)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Obradović, Nina
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Peleš, Adriana
AU  - Ristić, Momčilo M.
PY  - 2014
UR  - https://dais.sanu.ac.rs/123456789/544
AB  - Ferroelectric barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using as the starting compounds powder of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2–anatase). Non-activated mixtures and mixtures mechanically activated in a high-energy planetary ball mill (0, 5, 10, 20, 40, 80 and 120 min) were sintered at 1100, 1200, 1300 and 1400 °C for 2 h in air atmosphere. Defects and the effect of the beginning of the sintering process on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent and resistivity as the function of frequency XC=f(log ν)) were performed for ceramics sintered at 1400 °C for 2 h. It has been found that mechanical activation can reduce the sintering temperature by around 100 °C, which leads to significant energy savings. Furthermore, activated for 80 min and sintered at 1400 °C for 2 h exhibit the largest density values and have about 36% lower dielectric loss at a frequency of 1 kHz and about 57% at a frequency of 10 kHz than the samples obtained from the initial non-activated powder sintered under the same conditions.
PB  - Elsevier
T2  - Ceramics International
T1  - The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics
SP  - 11883
EP  - 11888
IS  - 8, Part A
DO  - 10.1016/j.ceramint.2014.04.023
UR  - https://hdl.handle.net/21.15107/rcub_dais_544
ER  - 
@article{
author = "Kosanović, Darko and Živojinović, Jelena and Obradović, Nina and Pavlović, Vera P. and Pavlović, Vladimir B. and Peleš, Adriana and Ristić, Momčilo M.",
year = "2014",
abstract = "Ferroelectric barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using as the starting compounds powder of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2–anatase). Non-activated mixtures and mixtures mechanically activated in a high-energy planetary ball mill (0, 5, 10, 20, 40, 80 and 120 min) were sintered at 1100, 1200, 1300 and 1400 °C for 2 h in air atmosphere. Defects and the effect of the beginning of the sintering process on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent and resistivity as the function of frequency XC=f(log ν)) were performed for ceramics sintered at 1400 °C for 2 h. It has been found that mechanical activation can reduce the sintering temperature by around 100 °C, which leads to significant energy savings. Furthermore, activated for 80 min and sintered at 1400 °C for 2 h exhibit the largest density values and have about 36% lower dielectric loss at a frequency of 1 kHz and about 57% at a frequency of 10 kHz than the samples obtained from the initial non-activated powder sintered under the same conditions.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics",
pages = "11883-11888",
number = "8, Part A",
doi = "10.1016/j.ceramint.2014.04.023",
url = "https://hdl.handle.net/21.15107/rcub_dais_544"
}
Kosanović, D., Živojinović, J., Obradović, N., Pavlović, V. P., Pavlović, V. B., Peleš, A.,& Ristić, M. M.. (2014). The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics. in Ceramics International
Elsevier.(8, Part A), 11883-11888.
https://doi.org/10.1016/j.ceramint.2014.04.023
https://hdl.handle.net/21.15107/rcub_dais_544
Kosanović D, Živojinović J, Obradović N, Pavlović VP, Pavlović VB, Peleš A, Ristić MM. The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics. in Ceramics International. 2014;(8, Part A):11883-11888.
doi:10.1016/j.ceramint.2014.04.023
https://hdl.handle.net/21.15107/rcub_dais_544 .
Kosanović, Darko, Živojinović, Jelena, Obradović, Nina, Pavlović, Vera P., Pavlović, Vladimir B., Peleš, Adriana, Ristić, Momčilo M., "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics" in Ceramics International, no. 8, Part A (2014):11883-11888,
https://doi.org/10.1016/j.ceramint.2014.04.023 .,
https://hdl.handle.net/21.15107/rcub_dais_544 .
5
5
7

The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics

Kosanović, Darko; Živojinović, Jelena; Obradović, Nina; Pavlović, Vera P.; Pavlović, Vladimir B.; Peleš, Adriana; Ristić, Momčilo M.

(2014)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Obradović, Nina
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Peleš, Adriana
AU  - Ristić, Momčilo M.
PY  - 2014
UR  - https://dais.sanu.ac.rs/123456789/543
AB  - Ferroelectric barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using as the starting compounds powder of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2–anatase). Non-activated mixtures and mixtures mechanically activated in a high-energy planetary ball mill (0, 5, 10, 20, 40, 80 and 120 min) were sintered at 1100, 1200, 1300 and 1400 °C for 2 h in air atmosphere. Defects and the effect of the beginning of the sintering process on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent and resistivity as the function of frequency XC=f(log ν)) were performed for ceramics sintered at 1400 °C for 2 h. It has been found that mechanical activation can reduce the sintering temperature by around 100 °C, which leads to significant energy savings. Furthermore, activated for 80 min and sintered at 1400 °C for 2 h exhibit the largest density values and have about 36% lower dielectric loss at a frequency of 1 kHz and about 57% at a frequency of 10 kHz than the samples obtained from the initial non-activated powder sintered under the same conditions.
T2  - Ceramics International
T1  - The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics
SP  - 11883
EP  - 11888
VL  - 40
IS  - 8, Part A
DO  - 10.1016/j.ceramint.2014.04.023
UR  - https://hdl.handle.net/21.15107/rcub_dais_543
ER  - 
@article{
author = "Kosanović, Darko and Živojinović, Jelena and Obradović, Nina and Pavlović, Vera P. and Pavlović, Vladimir B. and Peleš, Adriana and Ristić, Momčilo M.",
year = "2014",
abstract = "Ferroelectric barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using as the starting compounds powder of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2–anatase). Non-activated mixtures and mixtures mechanically activated in a high-energy planetary ball mill (0, 5, 10, 20, 40, 80 and 120 min) were sintered at 1100, 1200, 1300 and 1400 °C for 2 h in air atmosphere. Defects and the effect of the beginning of the sintering process on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent and resistivity as the function of frequency XC=f(log ν)) were performed for ceramics sintered at 1400 °C for 2 h. It has been found that mechanical activation can reduce the sintering temperature by around 100 °C, which leads to significant energy savings. Furthermore, activated for 80 min and sintered at 1400 °C for 2 h exhibit the largest density values and have about 36% lower dielectric loss at a frequency of 1 kHz and about 57% at a frequency of 10 kHz than the samples obtained from the initial non-activated powder sintered under the same conditions.",
journal = "Ceramics International",
title = "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics",
pages = "11883-11888",
volume = "40",
number = "8, Part A",
doi = "10.1016/j.ceramint.2014.04.023",
url = "https://hdl.handle.net/21.15107/rcub_dais_543"
}
Kosanović, D., Živojinović, J., Obradović, N., Pavlović, V. P., Pavlović, V. B., Peleš, A.,& Ristić, M. M.. (2014). The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics. in Ceramics International, 40(8, Part A), 11883-11888.
https://doi.org/10.1016/j.ceramint.2014.04.023
https://hdl.handle.net/21.15107/rcub_dais_543
Kosanović D, Živojinović J, Obradović N, Pavlović VP, Pavlović VB, Peleš A, Ristić MM. The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics. in Ceramics International. 2014;40(8, Part A):11883-11888.
doi:10.1016/j.ceramint.2014.04.023
https://hdl.handle.net/21.15107/rcub_dais_543 .
Kosanović, Darko, Živojinović, Jelena, Obradović, Nina, Pavlović, Vera P., Pavlović, Vladimir B., Peleš, Adriana, Ristić, Momčilo M., "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics" in Ceramics International, 40, no. 8, Part A (2014):11883-11888,
https://doi.org/10.1016/j.ceramint.2014.04.023 .,
https://hdl.handle.net/21.15107/rcub_dais_543 .
5
5
7

The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3

Kosanović, Darko; Živojinović, Jelena; Obradović, Nina; Pavlović, Vera P.; Pavlović, Vladimir B.; Peleš, Adriana; Ristić, Momčilo M.

(2013)

TY  - CONF
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Obradović, Nina
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Peleš, Adriana
AU  - Ristić, Momčilo M.
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/151
AB  - Poster presented at the conference Advanced Ceramics and Application II – Serbian Ceramic Society, Belgrade, September 30 – October 1, 2013
T1  - The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3
UR  - https://hdl.handle.net/21.15107/rcub_dais_151
ER  - 
@conference{
author = "Kosanović, Darko and Živojinović, Jelena and Obradović, Nina and Pavlović, Vera P. and Pavlović, Vladimir B. and Peleš, Adriana and Ristić, Momčilo M.",
year = "2013",
abstract = "Poster presented at the conference Advanced Ceramics and Application II – Serbian Ceramic Society, Belgrade, September 30 – October 1, 2013",
title = "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3",
url = "https://hdl.handle.net/21.15107/rcub_dais_151"
}
Kosanović, D., Živojinović, J., Obradović, N., Pavlović, V. P., Pavlović, V. B., Peleš, A.,& Ristić, M. M.. (2013). The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3. .
https://hdl.handle.net/21.15107/rcub_dais_151
Kosanović D, Živojinović J, Obradović N, Pavlović VP, Pavlović VB, Peleš A, Ristić MM. The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3. 2013;.
https://hdl.handle.net/21.15107/rcub_dais_151 .
Kosanović, Darko, Živojinović, Jelena, Obradović, Nina, Pavlović, Vera P., Pavlović, Vladimir B., Peleš, Adriana, Ristić, Momčilo M., "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3" (2013),
https://hdl.handle.net/21.15107/rcub_dais_151 .

Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods

Labus, Nebojša; Krstić, Jugoslav; Peleš, Adriana; Živojinović, Jelena; Nikolić, Maria Vesna

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Labus, Nebojša
AU  - Krstić, Jugoslav
AU  - Peleš, Adriana
AU  - Živojinović, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/411
AB  - Nanopowder density, as well as compact density, is due to powder particle size, different in their values, compared to micron powders. Also, the technique used for density determination induces large mutual value discrepancies. Scanning electron micrographs of as received powder are presented as an illustration of the shape and size of powder particles and agglomerates. The density of the loose powder pretreated differently was determined using mercury porosimetry and He pycnometry. The methods used for determining the apparent density of the compacts were pycnometry with water as the wetting liquid, mercury porosimetry and also a new approach using a combination of mercury pycnometry along with nitrogen adsorption. Bulk densities of compacts were determined by dimension measurement and mercury pycnometry. Conclusions about nanopowder usage as a charge for dry compaction as well as the most appropriate way for the determination of compact and powder densities are shown.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
T1  - Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods
SP  - 18
EP  - 18
UR  - https://hdl.handle.net/21.15107/rcub_dais_411
ER  - 
@conference{
author = "Labus, Nebojša and Krstić, Jugoslav and Peleš, Adriana and Živojinović, Jelena and Nikolić, Maria Vesna",
year = "2013",
abstract = "Nanopowder density, as well as compact density, is due to powder particle size, different in their values, compared to micron powders. Also, the technique used for density determination induces large mutual value discrepancies. Scanning electron micrographs of as received powder are presented as an illustration of the shape and size of powder particles and agglomerates. The density of the loose powder pretreated differently was determined using mercury porosimetry and He pycnometry. The methods used for determining the apparent density of the compacts were pycnometry with water as the wetting liquid, mercury porosimetry and also a new approach using a combination of mercury pycnometry along with nitrogen adsorption. Bulk densities of compacts were determined by dimension measurement and mercury pycnometry. Conclusions about nanopowder usage as a charge for dry compaction as well as the most appropriate way for the determination of compact and powder densities are shown.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade",
title = "Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods",
pages = "18-18",
url = "https://hdl.handle.net/21.15107/rcub_dais_411"
}
Labus, N., Krstić, J., Peleš, A., Živojinović, J.,& Nikolić, M. V.. (2013). Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
Belgrade : Serbian Ceramic Society., 18-18.
https://hdl.handle.net/21.15107/rcub_dais_411
Labus N, Krstić J, Peleš A, Živojinović J, Nikolić MV. Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade. 2013;:18-18.
https://hdl.handle.net/21.15107/rcub_dais_411 .
Labus, Nebojša, Krstić, Jugoslav, Peleš, Adriana, Živojinović, Jelena, Nikolić, Maria Vesna, "Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade (2013):18-18,
https://hdl.handle.net/21.15107/rcub_dais_411 .

Dilatometric Analysis of Mechanically Activated SrTiO3 Powder

Živojinović, Jelena; Kosanović, Darko; Obradović, Nina; Peleš, Adriana; Labus, Nebojša; Filipović, Suzana; Pavlović, Vladimir B.; Mitrić, Miodrag; Ristić, Momčilo M.

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Obradović, Nina
AU  - Peleš, Adriana
AU  - Labus, Nebojša
AU  - Filipović, Suzana
AU  - Pavlović, Vladimir B.
AU  - Mitrić, Miodrag
AU  - Ristić, Momčilo M.
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/414
AB  - Strontium-titanate powder was mechanically activated in a planetary ball mill for 0, 5, 10, 30, 60, 90 and 120 minutes. Non-isothermal sintering of non-activated and activated SrTiO3 powder samples in the temperature interval from 50 to 1300 0C with three different heating rates (10, 15 and 20 0C/min) was investigated on a dilatometer. X-ray powder diffraction and scanning electron microscopy (SEM) were used to determine the phase composition, lattice microstrains and microstructure morphology of the samples. XRD results showed the presence of new phases: SrCO3 (strontuim-carbonate) and TiO2 (anatase) after 30 minutes of  mechanical activation.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
T1  - Dilatometric Analysis of Mechanically Activated SrTiO3 Powder
SP  - 38
EP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_dais_414
ER  - 
@conference{
author = "Živojinović, Jelena and Kosanović, Darko and Obradović, Nina and Peleš, Adriana and Labus, Nebojša and Filipović, Suzana and Pavlović, Vladimir B. and Mitrić, Miodrag and Ristić, Momčilo M.",
year = "2013",
abstract = "Strontium-titanate powder was mechanically activated in a planetary ball mill for 0, 5, 10, 30, 60, 90 and 120 minutes. Non-isothermal sintering of non-activated and activated SrTiO3 powder samples in the temperature interval from 50 to 1300 0C with three different heating rates (10, 15 and 20 0C/min) was investigated on a dilatometer. X-ray powder diffraction and scanning electron microscopy (SEM) were used to determine the phase composition, lattice microstrains and microstructure morphology of the samples. XRD results showed the presence of new phases: SrCO3 (strontuim-carbonate) and TiO2 (anatase) after 30 minutes of  mechanical activation.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade",
title = "Dilatometric Analysis of Mechanically Activated SrTiO3 Powder",
pages = "38-38",
url = "https://hdl.handle.net/21.15107/rcub_dais_414"
}
Živojinović, J., Kosanović, D., Obradović, N., Peleš, A., Labus, N., Filipović, S., Pavlović, V. B., Mitrić, M.,& Ristić, M. M.. (2013). Dilatometric Analysis of Mechanically Activated SrTiO3 Powder. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
Belgrade : Serbian Ceramic Society., 38-38.
https://hdl.handle.net/21.15107/rcub_dais_414
Živojinović J, Kosanović D, Obradović N, Peleš A, Labus N, Filipović S, Pavlović VB, Mitrić M, Ristić MM. Dilatometric Analysis of Mechanically Activated SrTiO3 Powder. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade. 2013;:38-38.
https://hdl.handle.net/21.15107/rcub_dais_414 .
Živojinović, Jelena, Kosanović, Darko, Obradović, Nina, Peleš, Adriana, Labus, Nebojša, Filipović, Suzana, Pavlović, Vladimir B., Mitrić, Miodrag, Ristić, Momčilo M., "Dilatometric Analysis of Mechanically Activated SrTiO3 Powder" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade (2013):38-38,
https://hdl.handle.net/21.15107/rcub_dais_414 .

Characterization of mechanically activated ZnO powder

Peleš, Adriana; Pavlović, Vera P.; Obradović, Nina; Živojinović, Jelena; Mitrić, Miodrag; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Peleš, Adriana
AU  - Pavlović, Vera P.
AU  - Obradović, Nina
AU  - Živojinović, Jelena
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir B.
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/426
AB  - Materials based on ZnO structure have more frequently application as fillers in polymer ceramics nanocompozites. Performances of these materials depends on fillers morphology, surfaces texture and particles size. According to this, in this paper, the authors investigated the influence of mechanical activation of ZnO powder on crystal and micro structure. Commercially available ZnO powder was activated in a planetary ball mill for 2, 5, 10 and 30 minutes. Characterization of such obtained powders was performed using XRD, SEM and Raman spectroscopy. XRD patterns indicated at lowering of peak intensities along with its broadening wich is realted to partical fragmentation and amorphyzation. Micrographs show irregularly shaped particles at the beginning and with prolonged milling time, particles gained uniformed distibution, while after 30 minutes of activation agglomerates started forming. The results we got by investigation of dynamical structure by Raman spectroscopy are in correlation with the other results of structures analysis. Results presented here enable further optimization of, polymer nanocompozite based on ZnO and PVDF, making process.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
T1  - Characterization of mechanically activated ZnO powder
SP  - 47
EP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_dais_426
ER  - 
@conference{
author = "Peleš, Adriana and Pavlović, Vera P. and Obradović, Nina and Živojinović, Jelena and Mitrić, Miodrag and Pavlović, Vladimir B.",
year = "2013",
abstract = "Materials based on ZnO structure have more frequently application as fillers in polymer ceramics nanocompozites. Performances of these materials depends on fillers morphology, surfaces texture and particles size. According to this, in this paper, the authors investigated the influence of mechanical activation of ZnO powder on crystal and micro structure. Commercially available ZnO powder was activated in a planetary ball mill for 2, 5, 10 and 30 minutes. Characterization of such obtained powders was performed using XRD, SEM and Raman spectroscopy. XRD patterns indicated at lowering of peak intensities along with its broadening wich is realted to partical fragmentation and amorphyzation. Micrographs show irregularly shaped particles at the beginning and with prolonged milling time, particles gained uniformed distibution, while after 30 minutes of activation agglomerates started forming. The results we got by investigation of dynamical structure by Raman spectroscopy are in correlation with the other results of structures analysis. Results presented here enable further optimization of, polymer nanocompozite based on ZnO and PVDF, making process.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade",
title = "Characterization of mechanically activated ZnO powder",
pages = "47-47",
url = "https://hdl.handle.net/21.15107/rcub_dais_426"
}
Peleš, A., Pavlović, V. P., Obradović, N., Živojinović, J., Mitrić, M.,& Pavlović, V. B.. (2013). Characterization of mechanically activated ZnO powder. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
Belgrade : Serbian Ceramic Society., 47-47.
https://hdl.handle.net/21.15107/rcub_dais_426
Peleš A, Pavlović VP, Obradović N, Živojinović J, Mitrić M, Pavlović VB. Characterization of mechanically activated ZnO powder. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade. 2013;:47-47.
https://hdl.handle.net/21.15107/rcub_dais_426 .
Peleš, Adriana, Pavlović, Vera P., Obradović, Nina, Živojinović, Jelena, Mitrić, Miodrag, Pavlović, Vladimir B., "Characterization of mechanically activated ZnO powder" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade (2013):47-47,
https://hdl.handle.net/21.15107/rcub_dais_426 .

The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics

Kosanović, Darko; Živojinović, Jelena; Obradović, Nina; Pavlović, Vera P.; Pavlović, Vladimir B.; Ristić, Momčilo M.

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Kosanović, Darko
AU  - Živojinović, Jelena
AU  - Obradović, Nina
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Ristić, Momčilo M.
PY  - 2013
UR  - https://dais.sanu.ac.rs/123456789/415
AB  - Ferroelectric ceramic barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using starting powders of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2-anatase). Non-activated and mechanically activated mixtures with high-energy planetary ball mill (0, 5, 10, 20, 80 and 120 minutes) were sintered at 1100, 1200, 1300 and 1400 °C for two hours in air. The maximum value of ceramic density is about 86.20% TG. X-ray diffraction analysis was used to obtain information on the phase composition, as well as determining the influence of mechanical activation on the half height width of the diffraction lines (111) BST isothermally sintered samples at 1400 °C during two hours. Defects and the beginning process of sintering on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent of the angle, Nyquist diagrams and influence the activation time dependence of XC = f (log ν)) are made of ceramics sintered at 1400 °C for two hours.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
T1  - The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics
SP  - 39
EP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_dais_415
ER  - 
@conference{
author = "Kosanović, Darko and Živojinović, Jelena and Obradović, Nina and Pavlović, Vera P. and Pavlović, Vladimir B. and Ristić, Momčilo M.",
year = "2013",
abstract = "Ferroelectric ceramic barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using starting powders of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2-anatase). Non-activated and mechanically activated mixtures with high-energy planetary ball mill (0, 5, 10, 20, 80 and 120 minutes) were sintered at 1100, 1200, 1300 and 1400 °C for two hours in air. The maximum value of ceramic density is about 86.20% TG. X-ray diffraction analysis was used to obtain information on the phase composition, as well as determining the influence of mechanical activation on the half height width of the diffraction lines (111) BST isothermally sintered samples at 1400 °C during two hours. Defects and the beginning process of sintering on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent of the angle, Nyquist diagrams and influence the activation time dependence of XC = f (log ν)) are made of ceramics sintered at 1400 °C for two hours.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade",
title = "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics",
pages = "39-39",
url = "https://hdl.handle.net/21.15107/rcub_dais_415"
}
Kosanović, D., Živojinović, J., Obradović, N., Pavlović, V. P., Pavlović, V. B.,& Ristić, M. M.. (2013). The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
Belgrade : Serbian Ceramic Society., 39-39.
https://hdl.handle.net/21.15107/rcub_dais_415
Kosanović D, Živojinović J, Obradović N, Pavlović VP, Pavlović VB, Ristić MM. The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade. 2013;:39-39.
https://hdl.handle.net/21.15107/rcub_dais_415 .
Kosanović, Darko, Živojinović, Jelena, Obradović, Nina, Pavlović, Vera P., Pavlović, Vladimir B., Ristić, Momčilo M., "The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade (2013):39-39,
https://hdl.handle.net/21.15107/rcub_dais_415 .

The influence of mechanical activation on sintering process of BaCO3-SrCO3-TiO2 system

Kosanović, Darko; Obradović, Nina; Živojinović, Jelena; Maričić, Aleksa; Pavlović, Vera P.; Pavlović, Vladimir B.; Ristić, Momčilo M.

(Belgrade : International Institute for the Science of Sintering, 2012)

TY  - JOUR
AU  - Kosanović, Darko
AU  - Obradović, Nina
AU  - Živojinović, Jelena
AU  - Maričić, Aleksa
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Ristić, Momčilo M.
PY  - 2012
UR  - https://dais.sanu.ac.rs/123456789/195
AB  - In this article the influence of mechanical activation on sintering process of bariumstrontium-titanate ceramics has been investigated. Both non-activated and mixtures treated in a planetary ball mill for 5, 10, 20, 40, 80 and 120 minutes were sintered at 1100-1400°C for 2 hours in presence of air atmosphere. The influence of mechanical activation on phase composition and crystal structure has been analyzed by XRD, while the effect of activation and sintering process on microstructure was investigated by scanning electron microscopy. It has been established that temperature of 1100°C was too low to induce final sintering stage for this system. Electrical measurements have been conducted for the densest ceramics sintered at 1400°C for 2 hours. [Projekat Ministarstva nauke Republike Srbije, br. OI172057]
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - The influence of mechanical activation on sintering process of BaCO3-SrCO3-TiO2 system
SP  - 271
EP  - 280
VL  - 44
IS  - 3
DO  - 10.2298/SOS1203271K
UR  - https://hdl.handle.net/21.15107/rcub_dais_195
ER  - 
@article{
author = "Kosanović, Darko and Obradović, Nina and Živojinović, Jelena and Maričić, Aleksa and Pavlović, Vera P. and Pavlović, Vladimir B. and Ristić, Momčilo M.",
year = "2012",
abstract = "In this article the influence of mechanical activation on sintering process of bariumstrontium-titanate ceramics has been investigated. Both non-activated and mixtures treated in a planetary ball mill for 5, 10, 20, 40, 80 and 120 minutes were sintered at 1100-1400°C for 2 hours in presence of air atmosphere. The influence of mechanical activation on phase composition and crystal structure has been analyzed by XRD, while the effect of activation and sintering process on microstructure was investigated by scanning electron microscopy. It has been established that temperature of 1100°C was too low to induce final sintering stage for this system. Electrical measurements have been conducted for the densest ceramics sintered at 1400°C for 2 hours. [Projekat Ministarstva nauke Republike Srbije, br. OI172057]",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "The influence of mechanical activation on sintering process of BaCO3-SrCO3-TiO2 system",
pages = "271-280",
volume = "44",
number = "3",
doi = "10.2298/SOS1203271K",
url = "https://hdl.handle.net/21.15107/rcub_dais_195"
}
Kosanović, D., Obradović, N., Živojinović, J., Maričić, A., Pavlović, V. P., Pavlović, V. B.,& Ristić, M. M.. (2012). The influence of mechanical activation on sintering process of BaCO3-SrCO3-TiO2 system. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 44(3), 271-280.
https://doi.org/10.2298/SOS1203271K
https://hdl.handle.net/21.15107/rcub_dais_195
Kosanović D, Obradović N, Živojinović J, Maričić A, Pavlović VP, Pavlović VB, Ristić MM. The influence of mechanical activation on sintering process of BaCO3-SrCO3-TiO2 system. in Science of Sintering. 2012;44(3):271-280.
doi:10.2298/SOS1203271K
https://hdl.handle.net/21.15107/rcub_dais_195 .
Kosanović, Darko, Obradović, Nina, Živojinović, Jelena, Maričić, Aleksa, Pavlović, Vera P., Pavlović, Vladimir B., Ristić, Momčilo M., "The influence of mechanical activation on sintering process of BaCO3-SrCO3-TiO2 system" in Science of Sintering, 44, no. 3 (2012):271-280,
https://doi.org/10.2298/SOS1203271K .,
https://hdl.handle.net/21.15107/rcub_dais_195 .
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