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Abazović, Nadica

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  • Abazović, Nadica (3)
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Author's Bibliography

Zirconium dioxide nanopowders with incorporated Si4+ions asefficient photocatalyst for degradation of trichlorophenol usingsimulated solar light

Carević, M. V.; Abazović, Nadica; Novaković, T. B.; Pavlović, Vladimir B.; Čomor, Mirjana

(Elsevier, 2016)

TY  - JOUR
AU  - Carević, M. V.
AU  - Abazović, Nadica
AU  - Novaković, T. B.
AU  - Pavlović, Vladimir B.
AU  - Čomor, Mirjana
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/15963
AB  - We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporatedSi4+ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powderswere annealed at 600◦C and characterized using structural (XRD), morphological (SEM and TEM) andoptical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties(BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol andRhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal syn-thesis method pure monoclinic ZrO2highly crystalline powder can be obtained. Incorporation of Si4+ionsinduced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes.Incorporation of Si4+ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIRmeasurements were used as proof for existence of Zr O Si bond. Effective band gap of zirconia pow-ders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ions. All zirconia powders showedsignificant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB(Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in thehost matrix. The source of this observation is discussed correlating all obtained properties of pure andSi-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia sam-ples obviously can lead to their photocatalytic activity comparable to Degussa TiO2powder, famous andcommercial photocatalyst.
PB  - Elsevier
T2  - Applied Catalysis B: Environmental
T1  - Zirconium dioxide nanopowders with incorporated Si4+ions asefficient photocatalyst for degradation of trichlorophenol usingsimulated solar light
SP  - 112
EP  - 120
VL  - 195
DO  - 10.1016/j.apcatb.2016.05.005
ER  - 
@article{
author = "Carević, M. V. and Abazović, Nadica and Novaković, T. B. and Pavlović, Vladimir B. and Čomor, Mirjana",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/15963",
abstract = "We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporatedSi4+ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powderswere annealed at 600◦C and characterized using structural (XRD), morphological (SEM and TEM) andoptical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties(BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol andRhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal syn-thesis method pure monoclinic ZrO2highly crystalline powder can be obtained. Incorporation of Si4+ionsinduced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes.Incorporation of Si4+ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIRmeasurements were used as proof for existence of Zr O Si bond. Effective band gap of zirconia pow-ders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ions. All zirconia powders showedsignificant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB(Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in thehost matrix. The source of this observation is discussed correlating all obtained properties of pure andSi-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia sam-ples obviously can lead to their photocatalytic activity comparable to Degussa TiO2powder, famous andcommercial photocatalyst.",
publisher = "Elsevier",
journal = "Applied Catalysis B: Environmental",
title = "Zirconium dioxide nanopowders with incorporated Si4+ions asefficient photocatalyst for degradation of trichlorophenol usingsimulated solar light",
pages = "112-120",
volume = "195",
doi = "10.1016/j.apcatb.2016.05.005"
}
Carević, M. V., Abazović, N., Novaković, T. B., Pavlović, V. B.,& Čomor, M. (2016). Zirconium dioxide nanopowders with incorporated Si4+ions asefficient photocatalyst for degradation of trichlorophenol usingsimulated solar light.
Applied Catalysis B: EnvironmentalElsevier., 195, 112-120.
https://doi.org/10.1016/j.apcatb.2016.05.005
Carević MV, Abazović N, Novaković TB, Pavlović VB, Čomor M. Zirconium dioxide nanopowders with incorporated Si4+ions asefficient photocatalyst for degradation of trichlorophenol usingsimulated solar light. Applied Catalysis B: Environmental. 2016;195:112-120
Carević M. V., Abazović Nadica, Novaković T. B., Pavlović Vladimir B., Čomor Mirjana, "Zirconium dioxide nanopowders with incorporated Si4+ions asefficient photocatalyst for degradation of trichlorophenol usingsimulated solar light" 195 (2016):112-120,
https://doi.org/10.1016/j.apcatb.2016.05.005 .
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Effect of PEO molecular weight on sunlight induced photocatalytic activity of ZnO/PEO composites

Marković, Smilja; Rajić, Vladimir B.; Stanković, Ana; Veselinović, Ljiljana; Belošević Čavor, Jelena; Batalović, Katarina; Abazović, Nadica; Škapin, Srečo Davor; Uskoković, Dragan

(Elsevier, 2016)

TY  - JOUR
AU  - Marković, Smilja
AU  - Rajić, Vladimir B.
AU  - Stanković, Ana
AU  - Veselinović, Ljiljana
AU  - Belošević Čavor, Jelena
AU  - Batalović, Katarina
AU  - Abazović, Nadica
AU  - Škapin, Srečo Davor
AU  - Uskoković, Dragan
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/2317
AB  - ZnO spheroidal nanoparticles, synthesized by microwave processing, were used for preparation of composites with polyethylene oxide (PEO). The phase purity and crystal structure of the composites were investigated by X-ray diffraction (XRD) and Raman spectroscopy. The composites’ particles morphology and size distributions were studied by FE-SEM and laser diffraction particle size analyzer, respectively. The optical properties were studied using UV–Vis diffuse reflectance and photoluminescence spectroscopy. It is found that in the wavelength range 550–800 nm, ZnO and ZnO/PEO composites absorb about 50% of the incident light intensity. Also red-shift of band gap energy (0.12–0.15 eV) compared to bulk ZnO was determined. The effect of PEO molecular weights, 200,000, 600,000 and 900,000 g/mol, on photocatalytic activity of ZnO/PEO composites were examined via de-colorization of methylene blue (MB) under direct sunlight irradiation. A large efficiency of MB de-colorization was found after 6 h of irradiation. The enhanced photocatalytic activity of ZnO/PEO composites is attributed to the: (1) lattice defects introduced in ZnO crystal structure by rapid microwave processing, and (2) presence of PEO as a source of oxygen interstitials. In order to confirm and further clarify the experimental results ab initio calculations based on density functional theory (DFT) were performed.
PB  - Elsevier
T2  - Solar Energy
T1  - Effect of PEO molecular weight on sunlight induced photocatalytic activity of ZnO/PEO composites
SP  - 124
EP  - 135
VL  - 127
DO  - 10.1016/j.solener.2016.01.026
ER  - 
@article{
author = "Marković, Smilja and Rajić, Vladimir B. and Stanković, Ana and Veselinović, Ljiljana and Belošević Čavor, Jelena and Batalović, Katarina and Abazović, Nadica and Škapin, Srečo Davor and Uskoković, Dragan",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/2317",
abstract = "ZnO spheroidal nanoparticles, synthesized by microwave processing, were used for preparation of composites with polyethylene oxide (PEO). The phase purity and crystal structure of the composites were investigated by X-ray diffraction (XRD) and Raman spectroscopy. The composites’ particles morphology and size distributions were studied by FE-SEM and laser diffraction particle size analyzer, respectively. The optical properties were studied using UV–Vis diffuse reflectance and photoluminescence spectroscopy. It is found that in the wavelength range 550–800 nm, ZnO and ZnO/PEO composites absorb about 50% of the incident light intensity. Also red-shift of band gap energy (0.12–0.15 eV) compared to bulk ZnO was determined. The effect of PEO molecular weights, 200,000, 600,000 and 900,000 g/mol, on photocatalytic activity of ZnO/PEO composites were examined via de-colorization of methylene blue (MB) under direct sunlight irradiation. A large efficiency of MB de-colorization was found after 6 h of irradiation. The enhanced photocatalytic activity of ZnO/PEO composites is attributed to the: (1) lattice defects introduced in ZnO crystal structure by rapid microwave processing, and (2) presence of PEO as a source of oxygen interstitials. In order to confirm and further clarify the experimental results ab initio calculations based on density functional theory (DFT) were performed.",
publisher = "Elsevier",
journal = "Solar Energy",
title = "Effect of PEO molecular weight on sunlight induced photocatalytic activity of ZnO/PEO composites",
pages = "124-135",
volume = "127",
doi = "10.1016/j.solener.2016.01.026"
}
Marković, S., Rajić, V. B., Stanković, A., Veselinović, L., Belošević Čavor, J., Batalović, K., Abazović, N., Škapin, S. D.,& Uskoković, D. (2016). Effect of PEO molecular weight on sunlight induced photocatalytic activity of ZnO/PEO composites.
Solar EnergyElsevier., 127, 124-135.
https://doi.org/10.1016/j.solener.2016.01.026
Marković S, Rajić VB, Stanković A, Veselinović L, Belošević Čavor J, Batalović K, Abazović N, Škapin SD, Uskoković D. Effect of PEO molecular weight on sunlight induced photocatalytic activity of ZnO/PEO composites. Solar Energy. 2016;127:124-135
Marković Smilja, Rajić Vladimir B., Stanković Ana, Veselinović Ljiljana, Belošević Čavor Jelena, Batalović Katarina, Abazović Nadica, Škapin Srečo Davor, Uskoković Dragan, "Effect of PEO molecular weight on sunlight induced photocatalytic activity of ZnO/PEO composites" 127 (2016):124-135,
https://doi.org/10.1016/j.solener.2016.01.026 .
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Influence of particle size and morphology of ZnO powders on their optical properties

Stanković, Ana; Stojanović, Zoran S.; Veselinović, Ljiljana; Abazović, Nadica; Škapin, Srečo Davor; Marković, Smilja; Uskoković, Dragan

(Belgrade : Serbian Ceramic Society, 2012)

TY  - CONF
AU  - Stanković, Ana
AU  - Stojanović, Zoran S.
AU  - Veselinović, Ljiljana
AU  - Abazović, Nadica
AU  - Škapin, Srečo Davor
AU  - Marković, Smilja
AU  - Uskoković, Dragan
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/529
AB  - In this work we present details of different synthesis procedures for preparation of ZnO powders and a possibility to create various particles morphology and average size; from micrometer rods to nanometer spherical particles. We studied two synthesis methods, low temperature hydrothermal processing (HT) and ultrasound processing (US). The morphology and average particle size of the ZnO particles were modified by adjusting the mole ratio of [Zn2+]/[OH] in the reactants solution. Agglomeration of the particles was prevented using a polyvinyl pyrrolidone (PVP) as a capping agent. The synthesized powders were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (FESEM) and UV-Vis - diffusion reflection spectroscopy (UV-Vis DRS). Based on the results of the scanning electron microscopy we proposed a possible growth mechanism of the ZnO particles depending on the mole ratio of [Zn2+]/[OH]. 
Also, we considered the influence of particle size and morphology on the optical properties of the prepared powders. The observed results sowed that the size and morphology of ZnO particles greatly affect the absorption of visible light (%) and the shift of the energy gap (eV).
PB  - Belgrade : Serbian Ceramic Society
C3  - Joint Event of the 11th Young Researchers’ Conference: Materials Science and Engineering and the 1st European Early Stage Researches’ Conference on Hydrogen Storage: Program and the Book of Abstracts
T1  - Influence of particle size and morphology of ZnO powders on their optical properties
SP  - 60
EP  - 60
ER  - 
@conference{
author = "Stanković, Ana and Stojanović, Zoran S. and Veselinović, Ljiljana and Abazović, Nadica and Škapin, Srečo Davor and Marković, Smilja and Uskoković, Dragan",
year = "2012",
url = "http://dais.sanu.ac.rs/123456789/529",
abstract = "In this work we present details of different synthesis procedures for preparation of ZnO powders and a possibility to create various particles morphology and average size; from micrometer rods to nanometer spherical particles. We studied two synthesis methods, low temperature hydrothermal processing (HT) and ultrasound processing (US). The morphology and average particle size of the ZnO particles were modified by adjusting the mole ratio of [Zn2+]/[OH] in the reactants solution. Agglomeration of the particles was prevented using a polyvinyl pyrrolidone (PVP) as a capping agent. The synthesized powders were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (FESEM) and UV-Vis - diffusion reflection spectroscopy (UV-Vis DRS). Based on the results of the scanning electron microscopy we proposed a possible growth mechanism of the ZnO particles depending on the mole ratio of [Zn2+]/[OH]. 
Also, we considered the influence of particle size and morphology on the optical properties of the prepared powders. The observed results sowed that the size and morphology of ZnO particles greatly affect the absorption of visible light (%) and the shift of the energy gap (eV).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Joint Event of the 11th Young Researchers’ Conference: Materials Science and Engineering and the 1st European Early Stage Researches’ Conference on Hydrogen Storage: Program and the Book of Abstracts",
title = "Influence of particle size and morphology of ZnO powders on their optical properties",
pages = "60-60"
}
Stanković, A., Stojanović, Z. S., Veselinović, L., Abazović, N., Škapin, S. D., Marković, S.,& Uskoković, D. (2012). Influence of particle size and morphology of ZnO powders on their optical properties.
Joint Event of the 11th Young Researchers’ Conference: Materials Science and Engineering and the 1st European Early Stage Researches’ Conference on Hydrogen Storage: Program and the Book of AbstractsBelgrade : Serbian Ceramic Society., 60-60.
Stanković A, Stojanović ZS, Veselinović L, Abazović N, Škapin SD, Marković S, Uskoković D. Influence of particle size and morphology of ZnO powders on their optical properties. Joint Event of the 11th Young Researchers’ Conference: Materials Science and Engineering and the 1st European Early Stage Researches’ Conference on Hydrogen Storage: Program and the Book of Abstracts. 2012;:60-60
Stanković Ana, Stojanović Zoran S., Veselinović Ljiljana, Abazović Nadica, Škapin Srečo Davor, Marković Smilja, Uskoković Dragan, "Influence of particle size and morphology of ZnO powders on their optical properties" (2012):60-60