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Ðorđević, Antonije

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Author's Bibliography

Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Savić, Slobodan; Đorđević, Antonije; Pavlović, Vladimir B.

(Springer, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10027
AB  - Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
SP  - 95
EP  - 107
VL  - 140
DO  - 10.1007/s10973-019-08846-w
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2020",
url = "https://dais.sanu.ac.rs/123456789/10027",
abstract = "Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "95-107",
volume = "140",
doi = "10.1007/s10973-019-08846-w"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Đorđević, A.,& Pavlović, V. B. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics.
Journal of Thermal Analysis and CalorimetrySpringer., 140, 95-107.
https://doi.org/10.1007/s10973-019-08846-w
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Đorđević A, Pavlović VB. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. Journal of Thermal Analysis and Calorimetry. 2020;140:95-107
Obradović Nina, Fahrenholtz William G., Filipović Suzana, Marković Smilja, Blagojević Vladimir A., Lević Steva, Savić Slobodan, Đorđević Antonije, Pavlović Vladimir B., "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" 140 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w .
1
2
2

Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Savić, Slobodan; Đorđević, Antonije; Pavlović, Vladimir B.

(Springer, 2020)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - http://dais.sanu.ac.rs/123456789/6910
AB  - Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
SP  - 95
EP  - 107
VL  - 140
DO  - 10.1007/s10973-019-08846-w
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2020",
url = "http://dais.sanu.ac.rs/123456789/6910",
abstract = "Solid-state mechanical activation of MgO and α-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 °C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)2 shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 °C for non-activated samples, and 1400 °C for activated samples.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "95-107",
volume = "140",
doi = "10.1007/s10973-019-08846-w"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Đorđević, A.,& Pavlović, V. B. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics.
Journal of Thermal Analysis and CalorimetrySpringer., 140, 95-107.
https://doi.org/10.1007/s10973-019-08846-w
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Đorđević A, Pavlović VB. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. Journal of Thermal Analysis and Calorimetry. 2020;140:95-107
Obradović Nina, Fahrenholtz William G., Filipović Suzana, Marković Smilja, Blagojević Vladimir A., Lević Steva, Savić Slobodan, Đorđević Antonije, Pavlović Vladimir B., "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" 140 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w .
1
2
2

The effect of ball milling on properties of sintered manganese-doped alumina

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Mitrić, Miodrag; Balać, Igor; Đorđević, Antonije; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Mitrić, Miodrag
AU  - Balać, Igor
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0921883119302596
UR  - http://dais.sanu.ac.rs/123456789/6951
AB  - Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - The effect of ball milling on properties of sintered manganese-doped alumina
SP  - 2533
EP  - 2540
VL  - 30
IS  - 11
DO  - 10.1016/j.apt.2019.07.033
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Mitrić, Miodrag and Balać, Igor and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0921883119302596, http://dais.sanu.ac.rs/123456789/6951",
abstract = "Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "The effect of ball milling on properties of sintered manganese-doped alumina",
pages = "2533-2540",
volume = "30",
number = "11",
doi = "10.1016/j.apt.2019.07.033"
}
Filipović, S., Obradović, N., Marković, S., Mitrić, M., Balać, I., Đorđević, A.,& Pavlović, V. B. (2019). The effect of ball milling on properties of sintered manganese-doped alumina.
Advanced Powder TechnologyElsevier., 30(11), 2533-2540.
https://doi.org/10.1016/j.apt.2019.07.033
Filipović S, Obradović N, Marković S, Mitrić M, Balać I, Đorđević A, Pavlović VB. The effect of ball milling on properties of sintered manganese-doped alumina. Advanced Powder Technology. 2019;30(11):2533-2540
Filipović Suzana, Obradović Nina, Marković Smilja, Mitrić Miodrag, Balać Igor, Đorđević Antonije, Pavlović Vladimir B., "The effect of ball milling on properties of sintered manganese-doped alumina" 30, no. 11 (2019):2533-2540,
https://doi.org/10.1016/j.apt.2019.07.033 .
1
2
3

Influence of mechanical activation on kinetics and formation of spinel monitored by DTA

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Marković, Smilja; Blagojević, Vladimir A.; Lević, Steva; Đorđević, Antonije; Pavlović, Vladimir B.

(Central and Eastern European Committee for Thermal Analysis and Calorimetry, 2019)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/7020
AB  - Magnesium aluminate and other alumina-based spinels are refractory ceramics with excellent properties, such as high hardness, high mechanical strength, and low dielectric constant, applicable in many modern industries. MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3 powders. Mechanical activation represents a very efficient method for increasing the reactivity of powders, accelerating chemical reactions and decreasing the sintering temperatures. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 60 minutes. Sintering was performed in air at temperatures ranging from 1200°C to 1600 °C with a 2 h dwell time. Initial powders and sintered samples were characterized using X-ray diffraction and scanning electron microscopy. Differential thermal analysis (DTA) and thermal gravimetry (TG) were used to determine the temperatures for synthesis reactions and phase transformations. Based on the DTA results, several different processes occured during heating, including evaporation of physisorbed water, decomposition of Mg(OH)2, and spinel formation. With mechanical activation, all characteristic temperatures shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of sintering temperature for all of the sintered specimens.
PB  - Central and Eastern European Committee for Thermal Analysis and Calorimetry
C3  - Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019)
T1  - Influence of mechanical activation on kinetics and formation of spinel monitored by DTA
SP  - 70
EP  - 70
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/7020",
abstract = "Magnesium aluminate and other alumina-based spinels are refractory ceramics with excellent properties, such as high hardness, high mechanical strength, and low dielectric constant, applicable in many modern industries. MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3 powders. Mechanical activation represents a very efficient method for increasing the reactivity of powders, accelerating chemical reactions and decreasing the sintering temperatures. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 60 minutes. Sintering was performed in air at temperatures ranging from 1200°C to 1600 °C with a 2 h dwell time. Initial powders and sintered samples were characterized using X-ray diffraction and scanning electron microscopy. Differential thermal analysis (DTA) and thermal gravimetry (TG) were used to determine the temperatures for synthesis reactions and phase transformations. Based on the DTA results, several different processes occured during heating, including evaporation of physisorbed water, decomposition of Mg(OH)2, and spinel formation. With mechanical activation, all characteristic temperatures shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of sintering temperature for all of the sintered specimens.",
publisher = "Central and Eastern European Committee for Thermal Analysis and Calorimetry",
journal = "Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019)",
title = "Influence of mechanical activation on kinetics and formation of spinel monitored by DTA",
pages = "70-70"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Đorđević, A.,& Pavlović, V. B. (2019). Influence of mechanical activation on kinetics and formation of spinel monitored by DTA.
Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019)Central and Eastern European Committee for Thermal Analysis and Calorimetry., 70-70.
Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Đorđević A, Pavlović VB. Influence of mechanical activation on kinetics and formation of spinel monitored by DTA. Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019). 2019;:70-70
Obradović Nina, Fahrenholtz William G., Filipović Suzana, Marković Smilja, Blagojević Vladimir A., Lević Steva, Đorđević Antonije, Pavlović Vladimir B., "Influence of mechanical activation on kinetics and formation of spinel monitored by DTA" (2019):70-70

Electrical and mechanical properties of alumina doped with transition metal oxides sintered at 1400°C

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Balać, Igor; Đorđević, Antonije; Pavlović, Vladimir B.

(Societa ceramica italiana, 2019)

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Balać, Igor
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/7025
AB  - Corundum (alpha-alumina) is one of the most exploited materials in ceramic industry due to its good physico-chemical properties, mechanical properties, and, importantly, due to its low cost. Advantageous properties, such as hardness, dielectric and thermal properties, and refractoriness, open the door to a wide range of applications of corundum. Porous alumina ceramics is often used for filters and as a catalytic substrate, whereas dense alumina ceramics is frequently used in automotive and aerospace industry. Hence, there is a great interest in exploring this type of ceramics. The aim of this work is to explain the influence of preparation parameters (mechanical activation, addition of transition metal oxides, and sintering conditions) on the final electrical and mechanical properties of alumina. 
As a starting powder, a mix of a few alumina modifications (α-, κ-,γ - Al2O3) was used. It was doped with 1 wt % of Mn2O3, Cr2O3, and NiO, respectively. Three of the obtained mixtures were homogenized and three were ball milled for 60 min. Particle size analysis, SEM, and EDS were performed in order to demonstrate changes in the microstructure after milling. DTA/TG analyses were used to determine all characteristic temperatures. After sintering at 1400 oC in an air atmosphere, mechanical, electrical, and physico-chemical properties of the obtained ceramics were determined. 
Results showed that the mechanical treatment lead to a decrease in temperatures of phase transitions and sintering for approximately 100 oC. Incorporation of cations of transition metals into the crystal lattice of alumina was noticed. Activated and sintered samples showed a higher tensile strength and higher relative dielectric permittivity then the sample doped with Cr2O3. 
The main conclusion of this investigation is that the mechanical activation has the dominant influence on lowering the characteristic temperatures of all detected phase transitions and sintering processes. Using a mixture of several crystalline phases of alumina as a starting powder alleviates the incorporation of transition-metal cations into the alumina crystal lattice, leading to changes in microstructures of the prepared ceramics. Finally, changes in the microstructure and lattice disordering have the dominant influence on the final mechanical properties.
PB  - Societa ceramica italiana
PB  - Politecnico di Torino
C3  - Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
T1  - Electrical and mechanical properties of alumina doped with transition metal oxides sintered at 1400°C
SP  - 682
EP  - 682
ER  - 
@conference{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Balać, Igor and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/7025",
abstract = "Corundum (alpha-alumina) is one of the most exploited materials in ceramic industry due to its good physico-chemical properties, mechanical properties, and, importantly, due to its low cost. Advantageous properties, such as hardness, dielectric and thermal properties, and refractoriness, open the door to a wide range of applications of corundum. Porous alumina ceramics is often used for filters and as a catalytic substrate, whereas dense alumina ceramics is frequently used in automotive and aerospace industry. Hence, there is a great interest in exploring this type of ceramics. The aim of this work is to explain the influence of preparation parameters (mechanical activation, addition of transition metal oxides, and sintering conditions) on the final electrical and mechanical properties of alumina. 
As a starting powder, a mix of a few alumina modifications (α-, κ-,γ - Al2O3) was used. It was doped with 1 wt % of Mn2O3, Cr2O3, and NiO, respectively. Three of the obtained mixtures were homogenized and three were ball milled for 60 min. Particle size analysis, SEM, and EDS were performed in order to demonstrate changes in the microstructure after milling. DTA/TG analyses were used to determine all characteristic temperatures. After sintering at 1400 oC in an air atmosphere, mechanical, electrical, and physico-chemical properties of the obtained ceramics were determined. 
Results showed that the mechanical treatment lead to a decrease in temperatures of phase transitions and sintering for approximately 100 oC. Incorporation of cations of transition metals into the crystal lattice of alumina was noticed. Activated and sintered samples showed a higher tensile strength and higher relative dielectric permittivity then the sample doped with Cr2O3. 
The main conclusion of this investigation is that the mechanical activation has the dominant influence on lowering the characteristic temperatures of all detected phase transitions and sintering processes. Using a mixture of several crystalline phases of alumina as a starting powder alleviates the incorporation of transition-metal cations into the alumina crystal lattice, leading to changes in microstructures of the prepared ceramics. Finally, changes in the microstructure and lattice disordering have the dominant influence on the final mechanical properties.",
publisher = "Societa ceramica italiana, Politecnico di Torino",
journal = "Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019",
title = "Electrical and mechanical properties of alumina doped with transition metal oxides sintered at 1400°C",
pages = "682-682"
}
Filipović, S., Obradović, N., Marković, S., Balać, I., Đorđević, A.,& Pavlović, V. B. (2019). Electrical and mechanical properties of alumina doped with transition metal oxides sintered at 1400°C.
Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019Politecnico di Torino., 682-682.
Filipović S, Obradović N, Marković S, Balać I, Đorđević A, Pavlović VB. Electrical and mechanical properties of alumina doped with transition metal oxides sintered at 1400°C. Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019. 2019;:682-682
Filipović Suzana, Obradović Nina, Marković Smilja, Balać Igor, Đorđević Antonije, Pavlović Vladimir B., "Electrical and mechanical properties of alumina doped with transition metal oxides sintered at 1400°C" (2019):682-682

The effect of ball milling on properties of sintered manganese-doped alumina

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Mitrić, Miodrag; Balać, Igor; Đorđević, Antonije; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Mitrić, Miodrag
AU  - Balać, Igor
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0921883119302596
UR  - http://dais.sanu.ac.rs/123456789/7027
AB  - Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - The effect of ball milling on properties of sintered manganese-doped alumina
SP  - 2533
EP  - 2540
VL  - 30
IS  - 11
DO  - 10.1016/j.apt.2019.07.033
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Mitrić, Miodrag and Balać, Igor and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0921883119302596, http://dais.sanu.ac.rs/123456789/7027",
abstract = "Alumina-based compounds have many technological applications and attract great attention even after decades of investigation, due to their good chemical, electrical, and mechanical properties. A mixture of several alumina modifications (α-, κ-, γ-Al2O3) doped with 1 wt% of Mn2O3 was used for this experiment. The powder was mechanically activated for 60 min in an ethanol medium. After compaction, green bodies were sintered in the temperature range from 1200 to 1400 °C. Microstructures of the obtained specimens were investigated by scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS). The influence of morphological changes on electrical and mechanical properties was examined in detail. We have developed a test fixture and corresponding software for measurement of the relative dielectric permittivity and the loss tangent of ceramic specimens. This new method overcomes the problems of dimensions and shape of samples, as well as the problem of applying silver paste. The accuracy is around 2% for ε'r and 0.003 for tanδ. We demonstrate that the mechanical activation (MA) has the dominant influence on lowering the characteristic temperatures and microstructure development, which further leads to increased permittivity and tensile strength.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "The effect of ball milling on properties of sintered manganese-doped alumina",
pages = "2533-2540",
volume = "30",
number = "11",
doi = "10.1016/j.apt.2019.07.033"
}
Filipović, S., Obradović, N., Marković, S., Mitrić, M., Balać, I., Đorđević, A.,& Pavlović, V. B. (2019). The effect of ball milling on properties of sintered manganese-doped alumina.
Advanced Powder TechnologyElsevier., 30(11), 2533-2540.
https://doi.org/10.1016/j.apt.2019.07.033
Filipović S, Obradović N, Marković S, Mitrić M, Balać I, Đorđević A, Pavlović VB. The effect of ball milling on properties of sintered manganese-doped alumina. Advanced Powder Technology. 2019;30(11):2533-2540
Filipović Suzana, Obradović Nina, Marković Smilja, Mitrić Miodrag, Balać Igor, Đorđević Antonije, Pavlović Vladimir B., "The effect of ball milling on properties of sintered manganese-doped alumina" 30, no. 11 (2019):2533-2540,
https://doi.org/10.1016/j.apt.2019.07.033 .
1
2
3

Influence of Mechanical Activation on Electrical Properties of Ceramic Materials in VHF Band

Obradović, Nina; Đorđević, Antonije

(Belgrade : ETRAN, 2019)

TY  - CONF
AU  - Obradović, Nina
AU  - Đorđević, Antonije
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6962
AB  - Mechanical activation is commonly used as a pre-sintering process in order to enhance the reactivity of materials, reduce the particle size, increase diffusion rates, accelerate the reaction, and lower the sintering temperature. The mechanical activation can affect the final electrical and mechanical characteristics. In this paper we consider the influence of the mechanical activation on the permittivity and the loss tangent. We outline methods for evaluation of these parameters, with emphasis on our coaxial-chamber technique for measurements in the VHF band.
PB  - Belgrade : ETRAN
PB  - Belgrade : Academic Mind
C3  - Proceedings of Papers – 6th International Conference on Electrical, Electronic and Computing Engineering, IcETRAN 2019, Silver Lake, Serbia, June 03 – 06, 2019 / Zbornik radova - 63. Konferencija za elektroniku, telekomunikacije, računarstvo, automatiku i nuklearnu tehniku, Srebrno jezero, 03 – 06. juna, 2019. godine
T1  - Influence of Mechanical Activation on Electrical Properties of Ceramic Materials in VHF Band
SP  - 636
EP  - 645
ER  - 
@conference{
author = "Obradović, Nina and Đorđević, Antonije",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/6962",
abstract = "Mechanical activation is commonly used as a pre-sintering process in order to enhance the reactivity of materials, reduce the particle size, increase diffusion rates, accelerate the reaction, and lower the sintering temperature. The mechanical activation can affect the final electrical and mechanical characteristics. In this paper we consider the influence of the mechanical activation on the permittivity and the loss tangent. We outline methods for evaluation of these parameters, with emphasis on our coaxial-chamber technique for measurements in the VHF band.",
publisher = "Belgrade : ETRAN, Belgrade : Academic Mind",
journal = "Proceedings of Papers – 6th International Conference on Electrical, Electronic and Computing Engineering, IcETRAN 2019, Silver Lake, Serbia, June 03 – 06, 2019 / Zbornik radova - 63. Konferencija za elektroniku, telekomunikacije, računarstvo, automatiku i nuklearnu tehniku, Srebrno jezero, 03 – 06. juna, 2019. godine",
title = "Influence of Mechanical Activation on Electrical Properties of Ceramic Materials in VHF Band",
pages = "636-645"
}
Obradović, N.,& Đorđević, A. (2019). Influence of Mechanical Activation on Electrical Properties of Ceramic Materials in VHF Band.
Proceedings of Papers – 6th International Conference on Electrical, Electronic and Computing Engineering, IcETRAN 2019, Silver Lake, Serbia, June 03 – 06, 2019 / Zbornik radova - 63. Konferencija za elektroniku, telekomunikacije, računarstvo, automatiku i nuklearnu tehniku, Srebrno jezero, 03 – 06. juna, 2019. godineBelgrade : Academic Mind., 636-645.
Obradović N, Đorđević A. Influence of Mechanical Activation on Electrical Properties of Ceramic Materials in VHF Band. Proceedings of Papers – 6th International Conference on Electrical, Electronic and Computing Engineering, IcETRAN 2019, Silver Lake, Serbia, June 03 – 06, 2019 / Zbornik radova - 63. Konferencija za elektroniku, telekomunikacije, računarstvo, automatiku i nuklearnu tehniku, Srebrno jezero, 03 – 06. juna, 2019. godine. 2019;:636-645
Obradović Nina, Đorđević Antonije, "Influence of Mechanical Activation on Electrical Properties of Ceramic Materials in VHF Band" (2019):636-645

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, A.; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, A.
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - http://dais.sanu.ac.rs/123456789/5763
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, A. and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884219306340, http://dais.sanu.ac.rs/123456789/5763",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics.
Ceramics InternationalElsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. Ceramics International. 2019;45(9):12015-12021
Obradović Nina, Fahrenholtz William G., Filipović Suzana, Kosanović Darko, Dapčević A., Đorđević Antonije, Balać Igor, Pavlović Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .
7
8
6

The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Kosanović, Darko; Dapčević, A.; Đorđević, Antonije; Balać, Igor; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, A.
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - http://dais.sanu.ac.rs/123456789/5272
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
SP  - 12015
EP  - 12021
VL  - 45
IS  - 9
DO  - 10.1016/j.ceramint.2019.03.095
ER  - 
@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, A. and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884219306340, http://dais.sanu.ac.rs/123456789/5272",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12015-12021",
volume = "45",
number = "9",
doi = "10.1016/j.ceramint.2019.03.095"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics.
Ceramics InternationalElsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095
Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. Ceramics International. 2019;45(9):12015-12021
Obradović Nina, Fahrenholtz William G., Filipović Suzana, Kosanović Darko, Dapčević A., Đorđević Antonije, Balać Igor, Pavlović Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 .
7
8
6

Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering

Obradović, Nina; Pavlović, Vera P.; Kachlik, Martin; Maca, Karel; Olćan, Dragan; Đorđević, Antonije; Tshantshapanyan, Ani; Vlahović, Branislav; Pavlović, Vladimir B.

(Taylor and Francis, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Pavlović, Vera P.
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Tshantshapanyan, Ani
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4557
AB  - Sintering of pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with the addition of 5 mass % TeO2 was studied. Green bodies were prepared from powder mixtures mechanically activated in a high-energy planetary mill, shaped by uniaxial (20 MPa) and cold isostatic pressing (1000 MPa). The pressure-less sintering of these specimens was performed at 1350°C for 1 h. High relative density over 95% of the theoretical value was obtained through solid-state reaction and pressure-less sintering of powder activated for 40 min, and for the first time reported in the literature. Phase composition and microstructures of sintered samples were determined by XRD and SEM, coupled with EDS mapping. The real part of the complex relative permittivity of the samples was measured at 200 MHz. The loss tangent of all samples was below the resolution of the measurement setup. A strong correlation between the relative permittivity and the density agrees with previously published data.
PB  - Taylor and Francis
T2  - Advances in Applied Ceramics
T1  - Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering
SP  - 241
EP  - 248
VL  - 118
IS  - 5
DO  - 10.1080/17436753.2018.1548150
ER  - 
@article{
author = "Obradović, Nina and Pavlović, Vera P. and Kachlik, Martin and Maca, Karel and Olćan, Dragan and Đorđević, Antonije and Tshantshapanyan, Ani and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/4557",
abstract = "Sintering of pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with the addition of 5 mass % TeO2 was studied. Green bodies were prepared from powder mixtures mechanically activated in a high-energy planetary mill, shaped by uniaxial (20 MPa) and cold isostatic pressing (1000 MPa). The pressure-less sintering of these specimens was performed at 1350°C for 1 h. High relative density over 95% of the theoretical value was obtained through solid-state reaction and pressure-less sintering of powder activated for 40 min, and for the first time reported in the literature. Phase composition and microstructures of sintered samples were determined by XRD and SEM, coupled with EDS mapping. The real part of the complex relative permittivity of the samples was measured at 200 MHz. The loss tangent of all samples was below the resolution of the measurement setup. A strong correlation between the relative permittivity and the density agrees with previously published data.",
publisher = "Taylor and Francis",
journal = "Advances in Applied Ceramics",
title = "Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering",
pages = "241-248",
volume = "118",
number = "5",
doi = "10.1080/17436753.2018.1548150"
}
Obradović, N., Pavlović, V. P., Kachlik, M., Maca, K., Olćan, D., Đorđević, A., Tshantshapanyan, A., Vlahović, B.,& Pavlović, V. B. (2019). Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering.
Advances in Applied CeramicsTaylor and Francis., 118(5), 241-248.
https://doi.org/10.1080/17436753.2018.1548150
Obradović N, Pavlović VP, Kachlik M, Maca K, Olćan D, Đorđević A, Tshantshapanyan A, Vlahović B, Pavlović VB. Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering. Advances in Applied Ceramics. 2019;118(5):241-248
Obradović Nina, Pavlović Vera P., Kachlik Martin, Maca Karel, Olćan Dragan, Đorđević Antonije, Tshantshapanyan Ani, Vlahović Branislav, Pavlović Vladimir B., "Processing and properties of dense cordierite ceramics obtained through solid-state reaction and pressure-less sintering" 118, no. 5 (2019):241-248,
https://doi.org/10.1080/17436753.2018.1548150 .
3
3
3

Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics

Terzić, Anja; Obradović, Nina; Kosanović, Darko; Stojanović, Jovica; Đorđević, Antonije; Andrić, Ljubiša; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Đorđević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884218329262
UR  - http://dais.sanu.ac.rs/123456789/4635
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
SP  - 3013
EP  - 3022
VL  - 45
IS  - 3
DO  - 10.1016/j.ceramint.2018.10.120
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Đorđević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884218329262, http://dais.sanu.ac.rs/123456789/4635",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3013-3022",
volume = "45",
number = "3",
doi = "10.1016/j.ceramint.2018.10.120"
}
Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Đorđević, A., Andrić, L.,& Pavlović, V. B. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics.
Ceramics InternationalElsevier., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120
Terzić A, Obradović N, Kosanović D, Stojanović J, Đorđević A, Andrić L, Pavlović VB. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. Ceramics International. 2019;45(3):3013-3022
Terzić Anja, Obradović Nina, Kosanović Darko, Stojanović Jovica, Đorđević Antonije, Andrić Ljubiša, Pavlović Vladimir B., "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 .
1
1

Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics

Terzić, Anja; Obradović, Nina; Kosanović, Darko; Stojanović, Jovica; Đorđević, Antonije; Andrić, Ljubiša; Pavlović, Vladimir B.

(Elsevier, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Đorđević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884218329262
UR  - http://dais.sanu.ac.rs/123456789/4645
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
SP  - 3013
EP  - 3022
VL  - 45
IS  - 3
DO  - 10.1016/j.ceramint.2018.10.120
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Đorđević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir B.",
year = "2019",
url = "http://www.sciencedirect.com/science/article/pii/S0272884218329262, http://dais.sanu.ac.rs/123456789/4645",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources – talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 °C and holding period conducted at 1250 °C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3013-3022",
volume = "45",
number = "3",
doi = "10.1016/j.ceramint.2018.10.120"
}
Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Đorđević, A., Andrić, L.,& Pavlović, V. B. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics.
Ceramics InternationalElsevier., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120
Terzić A, Obradović N, Kosanović D, Stojanović J, Đorđević A, Andrić L, Pavlović VB. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. Ceramics International. 2019;45(3):3013-3022
Terzić Anja, Obradović Nina, Kosanović Darko, Stojanović Jovica, Đorđević Antonije, Andrić Ljubiša, Pavlović Vladimir B., "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 .
1
1

Shungite – a carbon-mineral rock material: Its sinterability and possible applications

Obradović, Nina; Gigov, Mihajlo; Đorđević, Aleksandar; Kern, Frank; Dmitrović, S.; Matović, Branko; Ðorđević, Antonije; Tshantshapanyan, Ani; Vlahović, Branislav; Petrović, Predrag; Pavlović, Vladimir B.

(Novi Sad : Faculty of Technology, University of Novi Sad, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Gigov, Mihajlo
AU  - Đorđević, Aleksandar
AU  - Kern, Frank
AU  - Dmitrović, S.
AU  - Matović, Branko
AU  - Ðorđević, Antonije
AU  - Tshantshapanyan, Ani
AU  - Vlahović, Branislav
AU  - Petrović, Predrag
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6372
AB  - The paper presents results of the influence of mechanical activation of shungite, a carbon-mineral rock material rich in silica and carbon, on its sintering behaviour, and obtaining of pure SiC ceramics. The mechanical activation of the starting powder was performed in a high-energy ball mill in time intervals from 30 to 480 min. The phase composition of the starting powders and sintered samples was analysed by the X-ray diffraction method. The first traces of SiC were detected after sintering at 1350 °C for 2 h in an Ar atmosphere, along with traces of unreacted SiO2. The scanning electron microscopy was performed in order to determine changes in the microstructure. Sintering was performed at various temperatures for 2 h, in an Ar atmosphere and a vacuum. Dielectric properties of the sintered samples were measured in the frequency range from 1 to 500 MHz. The obtained results indicate that the sintered powder is a good candidate for applications as an absorber of electromagnetic waves in microwave engineering. © 2019 University of Novi Sad, Faculty of Technology. All rights reserved.
PB  - Novi Sad : Faculty of Technology, University of Novi Sad
T2  - Processing and Application of Ceramics
T1  - Shungite – a carbon-mineral rock material: Its sinterability and possible applications
SP  - 89
EP  - 97
VL  - 13
IS  - 1
DO  - 10.2298/PAC1901089O
ER  - 
@article{
author = "Obradović, Nina and Gigov, Mihajlo and Đorđević, Aleksandar and Kern, Frank and Dmitrović, S. and Matović, Branko and Ðorđević, Antonije and Tshantshapanyan, Ani and Vlahović, Branislav and Petrović, Predrag and Pavlović, Vladimir B.",
year = "2019",
url = "http://dais.sanu.ac.rs/123456789/6372",
abstract = "The paper presents results of the influence of mechanical activation of shungite, a carbon-mineral rock material rich in silica and carbon, on its sintering behaviour, and obtaining of pure SiC ceramics. The mechanical activation of the starting powder was performed in a high-energy ball mill in time intervals from 30 to 480 min. The phase composition of the starting powders and sintered samples was analysed by the X-ray diffraction method. The first traces of SiC were detected after sintering at 1350 °C for 2 h in an Ar atmosphere, along with traces of unreacted SiO2. The scanning electron microscopy was performed in order to determine changes in the microstructure. Sintering was performed at various temperatures for 2 h, in an Ar atmosphere and a vacuum. Dielectric properties of the sintered samples were measured in the frequency range from 1 to 500 MHz. The obtained results indicate that the sintered powder is a good candidate for applications as an absorber of electromagnetic waves in microwave engineering. © 2019 University of Novi Sad, Faculty of Technology. All rights reserved.",
publisher = "Novi Sad : Faculty of Technology, University of Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Shungite – a carbon-mineral rock material: Its sinterability and possible applications",
pages = "89-97",
volume = "13",
number = "1",
doi = "10.2298/PAC1901089O"
}
Obradović, N., Gigov, M., Đorđević, A., Kern, F., Dmitrović, S., Matović, B., Ðorđević, A., Tshantshapanyan, A., Vlahović, B., Petrović, P.,& Pavlović, V. B. (2019). Shungite – a carbon-mineral rock material: Its sinterability and possible applications.
Processing and Application of CeramicsNovi Sad : Faculty of Technology, University of Novi Sad., 13(1), 89-97.
https://doi.org/10.2298/PAC1901089O
Obradović N, Gigov M, Đorđević A, Kern F, Dmitrović S, Matović B, Ðorđević A, Tshantshapanyan A, Vlahović B, Petrović P, Pavlović VB. Shungite – a carbon-mineral rock material: Its sinterability and possible applications. Processing and Application of Ceramics. 2019;13(1):89-97
Obradović Nina, Gigov Mihajlo, Đorđević Aleksandar, Kern Frank, Dmitrović S., Matović Branko, Ðorđević Antonije, Tshantshapanyan Ani, Vlahović Branislav, Petrović Predrag, Pavlović Vladimir B., "Shungite – a carbon-mineral rock material: Its sinterability and possible applications" 13, no. 1 (2019):89-97,
https://doi.org/10.2298/PAC1901089O .
3
3
4

Physical Properties of Sintered Alumina Doped with Different Oxides

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Đorđević, Antonije; Balać, Igor; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Belgrade : ETRAN, 2018)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4537
AB  - Corundum (α-alumina) is a suitable material for usage in various industry fields owing to its chemical stability, electrical and mechanical features. It is known that properties of ceramics could be modified by addition of different oxides, as well as by changing the consolidation parameters. In this respect, alumina was doped with 1 wt.% of Cr2O3, Mn2O3 and NiO, followed by 1 hour of mechanical activation in a high-energy planetary ball mill. A sensitive dilatometer was used for sintering of powder mixtures up to 1400 oC and recording the obtained dilatation. The final density varied between cca. 1.9 and 3.3 g/cm3. Microstructural changes were detected by SEM measurements. Changes in electrical permittivity and loss tangent were associated with the preparation conditions (types of additives, duration of mechanical activation). For a given mixture, the sintering increases the relative permittivity and decreases losses, exhibiting the optimal values of 8.32 and 0.027, respectively, for the sample activated 60 minutes and sintered, with the addition of MnO2. Mechanical measurements indicate significant differences in strength with the addition of different transition metal oxides. Samples with Mn and Ni, activated and sintered, with strength of 121 and 86 MPa, respectively, have a significantly higher tensile strength than the other tested samples, due to their more compact microstructures.
PB  - Belgrade : ETRAN
T2  - Science of Sintering
T1  - Physical Properties of Sintered Alumina Doped with Different Oxides
SP  - 409
EP  - 419
VL  - 50
IS  - 4
DO  - 10.2298/SOS1804409F
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Đorđević, Antonije and Balać, Igor and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/4537",
abstract = "Corundum (α-alumina) is a suitable material for usage in various industry fields owing to its chemical stability, electrical and mechanical features. It is known that properties of ceramics could be modified by addition of different oxides, as well as by changing the consolidation parameters. In this respect, alumina was doped with 1 wt.% of Cr2O3, Mn2O3 and NiO, followed by 1 hour of mechanical activation in a high-energy planetary ball mill. A sensitive dilatometer was used for sintering of powder mixtures up to 1400 oC and recording the obtained dilatation. The final density varied between cca. 1.9 and 3.3 g/cm3. Microstructural changes were detected by SEM measurements. Changes in electrical permittivity and loss tangent were associated with the preparation conditions (types of additives, duration of mechanical activation). For a given mixture, the sintering increases the relative permittivity and decreases losses, exhibiting the optimal values of 8.32 and 0.027, respectively, for the sample activated 60 minutes and sintered, with the addition of MnO2. Mechanical measurements indicate significant differences in strength with the addition of different transition metal oxides. Samples with Mn and Ni, activated and sintered, with strength of 121 and 86 MPa, respectively, have a significantly higher tensile strength than the other tested samples, due to their more compact microstructures.",
publisher = "Belgrade : ETRAN",
journal = "Science of Sintering",
title = "Physical Properties of Sintered Alumina Doped with Different Oxides",
pages = "409-419",
volume = "50",
number = "4",
doi = "10.2298/SOS1804409F"
}
Filipović, S., Obradović, N., Marković, S., Đorđević, A., Balać, I., Dapčević, A., Rogan, J.,& Pavlović, V. B. (2018). Physical Properties of Sintered Alumina Doped with Different Oxides.
Science of SinteringBelgrade : ETRAN., 50(4), 409-419.
https://doi.org/10.2298/SOS1804409F
Filipović S, Obradović N, Marković S, Đorđević A, Balać I, Dapčević A, Rogan J, Pavlović VB. Physical Properties of Sintered Alumina Doped with Different Oxides. Science of Sintering. 2018;50(4):409-419
Filipović Suzana, Obradović Nina, Marković Smilja, Đorđević Antonije, Balać Igor, Dapčević Aleksandra, Rogan Jelena, Pavlović Vladimir B., "Physical Properties of Sintered Alumina Doped with Different Oxides" 50, no. 4 (2018):409-419,
https://doi.org/10.2298/SOS1804409F .
4
9
10

Sintering of alumina doped with different oxides, followed by sensitive dilatometer

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Đorđević, Antonije; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Đorđević, Antonije
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3634
AB  - Sintered alumina powder represents suitable material for usage in various industry fields (e.g., as chip carriers in electronics, microwaves, jewelry production), due to convenient physical properties, such as sinterability, electrical and mechanical features. Those properties can be modified by addition of different oxides and/or mechanical treatment. Therefore, in this investigation the alumina was doped with 1 wt. % of Cr2O3, Mn2O3 and NiO, respectively, followed by 1 hour of mechanical activation at 400 rpm in planetary ball mill. Sintering of powder mixtures was tracked by sensitive dilatometer up to 1400 °C. The final density values varied from cca. 2 ̶ 3.2 g/cm3. Changes in microstructure were observed by means of SEM. The influence of additives along with mechanical activation is monitored trough changes in electrical permittivity and loss tangent. Compared to pure alumina, the additives lower the relative permittivity and increase dielectric losses. For a given mixture, the sintering increases the relative permittivity and decreases losses.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - Sintering of alumina doped with different oxides, followed by sensitive dilatometer
SP  - 95
EP  - 95
ER  - 
@conference{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Đorđević, Antonije and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/3634",
abstract = "Sintered alumina powder represents suitable material for usage in various industry fields (e.g., as chip carriers in electronics, microwaves, jewelry production), due to convenient physical properties, such as sinterability, electrical and mechanical features. Those properties can be modified by addition of different oxides and/or mechanical treatment. Therefore, in this investigation the alumina was doped with 1 wt. % of Cr2O3, Mn2O3 and NiO, respectively, followed by 1 hour of mechanical activation at 400 rpm in planetary ball mill. Sintering of powder mixtures was tracked by sensitive dilatometer up to 1400 °C. The final density values varied from cca. 2 ̶ 3.2 g/cm3. Changes in microstructure were observed by means of SEM. The influence of additives along with mechanical activation is monitored trough changes in electrical permittivity and loss tangent. Compared to pure alumina, the additives lower the relative permittivity and increase dielectric losses. For a given mixture, the sintering increases the relative permittivity and decreases losses.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "Sintering of alumina doped with different oxides, followed by sensitive dilatometer",
pages = "95-95"
}
Filipović, S., Obradović, N., Marković, S., Đorđević, A., Dapčević, A., Rogan, J.,& Pavlović, V. B. (2018). Sintering of alumina doped with different oxides, followed by sensitive dilatometer.
Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018Belgrade : Materials Research Society of Serbia., 95-95.
Filipović S, Obradović N, Marković S, Đorđević A, Dapčević A, Rogan J, Pavlović VB. Sintering of alumina doped with different oxides, followed by sensitive dilatometer. Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018. 2018;:95-95
Filipović Suzana, Obradović Nina, Marković Smilja, Đorđević Antonije, Dapčević Aleksandra, Rogan Jelena, Pavlović Vladimir B., "Sintering of alumina doped with different oxides, followed by sensitive dilatometer" (2018):95-95

Shungite - a Russian mineral: possible application as a microwave absorber

Obradović, Nina; Gigov, Mihajlo; Đorđević, Aleksandar; Kern, Frank; Dmitrović, Svetlana; Matović, Branko; Đorđević, Antonije; Pavlović, Vladimir B.

(Belgrade : Materials Research Society of Serbia, 2018)

TY  - CONF
AU  - Obradović, Nina
AU  - Gigov, Mihajlo
AU  - Đorđević, Aleksandar
AU  - Kern, Frank
AU  - Dmitrović, Svetlana
AU  - Matović, Branko
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3667
AB  - The paper presents results of investigation of the influence of mechanical activation of shungite, a Russian natural mineral rich in silica and carbon, on its sintering behavior. The mechanical activation of the starting powder was performed in a high-energy ball mill in time intervals from 0 to 480 minutes. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. The scanning electron microscopy was performed in order to determine changes in the microstructure. Sintering was performed at various temperatures for 2 h, in an Ar and vacuum atmosphere. Dielectric properties of the sintered samples were measured in the frequency range from 1 to 500 MHz. The obtained results indicate that sintered shungite powder is a good candidate for applications as an absorber of electromagnetic waves in microwave engineering.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018
T1  - Shungite - a Russian mineral: possible application as a microwave absorber
SP  - 94
EP  - 94
ER  - 
@conference{
author = "Obradović, Nina and Gigov, Mihajlo and Đorđević, Aleksandar and Kern, Frank and Dmitrović, Svetlana and Matović, Branko and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/3667",
abstract = "The paper presents results of investigation of the influence of mechanical activation of shungite, a Russian natural mineral rich in silica and carbon, on its sintering behavior. The mechanical activation of the starting powder was performed in a high-energy ball mill in time intervals from 0 to 480 minutes. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. The scanning electron microscopy was performed in order to determine changes in the microstructure. Sintering was performed at various temperatures for 2 h, in an Ar and vacuum atmosphere. Dielectric properties of the sintered samples were measured in the frequency range from 1 to 500 MHz. The obtained results indicate that sintered shungite powder is a good candidate for applications as an absorber of electromagnetic waves in microwave engineering.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018",
title = "Shungite - a Russian mineral: possible application as a microwave absorber",
pages = "94-94"
}
Obradović, N., Gigov, M., Đorđević, A., Kern, F., Dmitrović, S., Matović, B., Đorđević, A.,& Pavlović, V. B. (2018). Shungite - a Russian mineral: possible application as a microwave absorber.
Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018Belgrade : Materials Research Society of Serbia., 94-94.
Obradović N, Gigov M, Đorđević A, Kern F, Dmitrović S, Matović B, Đorđević A, Pavlović VB. Shungite - a Russian mineral: possible application as a microwave absorber. Programme and The Book of Abstracts / Twentieth Annual Conference YUCOMAT 2018, Herceg Novi, September 3-7, 2018. 2018;:94-94
Obradović Nina, Gigov Mihajlo, Đorđević Aleksandar, Kern Frank, Dmitrović Svetlana, Matović Branko, Đorđević Antonije, Pavlović Vladimir B., "Shungite - a Russian mineral: possible application as a microwave absorber" (2018):94-94

Effects of ball-milling on properties of sintered alumina doped with Mn2O3

Filipović, Suzana; Obradović, Nina; Marković, Smilja; Mitrić, Miodrag; Đorđević, Antonije; Dapčević, Aleksandra; Rogan, Jelena; Pavlović, Vladimir B.

(Belgrade : Serbian Ceramic Society, 2018)

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Marković, Smilja
AU  - Mitrić, Miodrag
AU  - Đorđević, Antonije
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4114
AB  - Recently, with the huge use of smart gadgets, developing of smart jewelry represents a very interesting segment in material science, as well as in electronic science. Alumina is widely used ceramic in many industrial fields as pigments, catalysis, microelectronics, etc., mostly because of its low cost and appropriate mechanical and electrical properties, high surface area and thermal stability. Also, modified alumina could be applied in production of smart jewelry. Thus, the main objectives of this investigation is to improve features of sintered alumina doped with Mn2O3 along with mechanical treatment, in order to obtain strong ceramic with low values of dielectric loss and low relative dielectric permittivity, as well as esthetic. Commercial alumina powder was doped with 1 wt % of manganese oxide and treated in planetary ball mill for an hour. Characteristic temperatures of both powders (non-activated and activated one) were investigated in detail by DTA and TG analyses. After sintering at 1200, 1300, and 1400 oC for 2 h, XRD patterns and SEM images were recorded. Furthermore, mechanical and electrical properties were examined for all sintered samples.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
T1  - Effects of ball-milling on properties of sintered alumina doped with Mn2O3
SP  - 75
EP  - 75
ER  - 
@conference{
author = "Filipović, Suzana and Obradović, Nina and Marković, Smilja and Mitrić, Miodrag and Đorđević, Antonije and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2018",
url = "http://dais.sanu.ac.rs/123456789/4114",
abstract = "Recently, with the huge use of smart gadgets, developing of smart jewelry represents a very interesting segment in material science, as well as in electronic science. Alumina is widely used ceramic in many industrial fields as pigments, catalysis, microelectronics, etc., mostly because of its low cost and appropriate mechanical and electrical properties, high surface area and thermal stability. Also, modified alumina could be applied in production of smart jewelry. Thus, the main objectives of this investigation is to improve features of sintered alumina doped with Mn2O3 along with mechanical treatment, in order to obtain strong ceramic with low values of dielectric loss and low relative dielectric permittivity, as well as esthetic. Commercial alumina powder was doped with 1 wt % of manganese oxide and treated in planetary ball mill for an hour. Characteristic temperatures of both powders (non-activated and activated one) were investigated in detail by DTA and TG analyses. After sintering at 1200, 1300, and 1400 oC for 2 h, XRD patterns and SEM images were recorded. Furthermore, mechanical and electrical properties were examined for all sintered samples.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018",
title = "Effects of ball-milling on properties of sintered alumina doped with Mn2O3",
pages = "75-75"
}
Filipović, S., Obradović, N., Marković, S., Mitrić, M., Đorđević, A., Dapčević, A., Rogan, J.,& Pavlović, V. B. (2018). Effects of ball-milling on properties of sintered alumina doped with Mn2O3.
Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018Belgrade : Serbian Ceramic Society., 75-75.
Filipović S, Obradović N, Marković S, Mitrić M, Đorđević A, Dapčević A, Rogan J, Pavlović VB. Effects of ball-milling on properties of sintered alumina doped with Mn2O3. Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018. 2018;:75-75
Filipović Suzana, Obradović Nina, Marković Smilja, Mitrić Miodrag, Đorđević Antonije, Dapčević Aleksandra, Rogan Jelena, Pavlović Vladimir B., "Effects of ball-milling on properties of sintered alumina doped with Mn2O3" (2018):75-75

Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system

Obradović, Nina; Đorđević, Nataša; Kosanović, Darko; Filipović, Suzana; Kachlik, Martin; Maca, Karel; Olćan, Dragan; Đorđević, Antonije; Pavlović, Vladimir B.

(Belgrade : Materials Research Society of Serbia, 2017)

TY  - CONF
AU  - Obradović, Nina
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Filipović, Suzana
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/15444
AB  - In this study, sintering of two systems was investigated in parallel, pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with addition of 5 mass % TeO2. Green bodies were prepared from powder mixtures mechanically activated for 0, 10 and 40minutes by uniaxial pressing at 20 MPa followed by cold isostatic pressing (CIP) at 1000 MPa. The pressure-less sintering of these specimens was performed at a temperature of 1350 oC for 1 h, with 10 oC/min heating rate. Densities over 96 % of theoretical values were obtained for samples activated for 40 minutes. XRD measurements of MAS-40 sintered sample pointed at a mixture that consisted of several phases, majority of cordierite (> 73 %), spinel MgAl2O4 (> 22 %), ZrSiO4 (2.5 %), and Al2O3 (1.8%), while XRD pattern of MAS-40-TeO2 contained majority of cordierite (> 72 %), spinel MgAl2O4 (> 23 %), ZrSiO4 (1.9 %), and Al2O3 (1.9 %). The relative permittivities of the samples were measured in an open test fixture. The results for the real part of the complex relative permittivity of the samples, measured at 200 MHz, are shown in Table I. The loss tangent for all samples was very small, below the resolution of the measurement setup (0.005).
There is a strong correlation between the relative permittivity and the density, which agrees with our previous results.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
T1  - Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system
SP  - 70
EP  - 70
ER  - 
@conference{
author = "Obradović, Nina and Đorđević, Nataša and Kosanović, Darko and Filipović, Suzana and Kachlik, Martin and Maca, Karel and Olćan, Dragan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2017",
url = "http://dais.sanu.ac.rs/123456789/15444",
abstract = "In this study, sintering of two systems was investigated in parallel, pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with addition of 5 mass % TeO2. Green bodies were prepared from powder mixtures mechanically activated for 0, 10 and 40minutes by uniaxial pressing at 20 MPa followed by cold isostatic pressing (CIP) at 1000 MPa. The pressure-less sintering of these specimens was performed at a temperature of 1350 oC for 1 h, with 10 oC/min heating rate. Densities over 96 % of theoretical values were obtained for samples activated for 40 minutes. XRD measurements of MAS-40 sintered sample pointed at a mixture that consisted of several phases, majority of cordierite (> 73 %), spinel MgAl2O4 (> 22 %), ZrSiO4 (2.5 %), and Al2O3 (1.8%), while XRD pattern of MAS-40-TeO2 contained majority of cordierite (> 72 %), spinel MgAl2O4 (> 23 %), ZrSiO4 (1.9 %), and Al2O3 (1.9 %). The relative permittivities of the samples were measured in an open test fixture. The results for the real part of the complex relative permittivity of the samples, measured at 200 MHz, are shown in Table I. The loss tangent for all samples was very small, below the resolution of the measurement setup (0.005).
There is a strong correlation between the relative permittivity and the density, which agrees with our previous results.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017",
title = "Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system",
pages = "70-70"
}
Obradović, N., Đorđević, N., Kosanović, D., Filipović, S., Kachlik, M., Maca, K., Olćan, D., Đorđević, A.,& Pavlović, V. B. (2017). Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system.
Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017Belgrade : Materials Research Society of Serbia., 70-70.
Obradović N, Đorđević N, Kosanović D, Filipović S, Kachlik M, Maca K, Olćan D, Đorđević A, Pavlović VB. Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system. Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017. 2017;:70-70
Obradović Nina, Đorđević Nataša, Kosanović Darko, Filipović Suzana, Kachlik Martin, Maca Karel, Olćan Dragan, Đorđević Antonije, Pavlović Vladimir B., "Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system" (2017):70-70

Assessing electrical properties of ceramic samples

Olćan, Dragan; Obradović, Nina; Filipović, Suzana; Terzić, Anja; Pavlović, Vladimir B.; Kachlik, Martin; Maca, Karel; Đorđević, Antonije

(Belgrade : Serbian Ceramic Society, 2017)

TY  - CONF
AU  - Olćan, Dragan
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Terzić, Anja
AU  - Pavlović, Vladimir B.
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Đorđević, Antonije
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/4824
AB  - We present an overview of electromagnetic numerical techniques and measurement apparatus that have been used for assessing electrical properties of ceramic samples. The complex permittivity of the ceramics is typically the first electromagnetic property of interest. In the measurement approach that we use, ceramic samples, in the shape of pills with metalized faces, are placed in either a proprietary coaxial chamber or in an open fixture. The scattering parameter (reflection coefficient) is measured using a network analyzer. For the deembedding of the complex permittivity of a sample one needs precise electromagnetic simulations, including detailed models of the chamber or the open fixture. For lower and intermediate frequencies we use a numerical technique for electrostatic analysis, based on the method of moments with Galerkin testing. We create a database that is used afterwards for evaluation of the complex permittivity practically in real time. For higher frequencies, a full electrodynamic model of the chamber is developed with WIPL-D software. For all our deembedding techniques, we have also developed a detailed model of losses in the SMA coaxial connectors, which is essential for a precise evaluation of the imaginary part of the complex permittivity for low-loss dielectrics. We present results of several measurements in order to illustrate the used techniques.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
T1  - Assessing electrical properties of ceramic samples
SP  - 51
EP  - 52
ER  - 
@conference{
author = "Olćan, Dragan and Obradović, Nina and Filipović, Suzana and Terzić, Anja and Pavlović, Vladimir B. and Kachlik, Martin and Maca, Karel and Đorđević, Antonije",
year = "2017",
url = "http://dais.sanu.ac.rs/123456789/4824",
abstract = "We present an overview of electromagnetic numerical techniques and measurement apparatus that have been used for assessing electrical properties of ceramic samples. The complex permittivity of the ceramics is typically the first electromagnetic property of interest. In the measurement approach that we use, ceramic samples, in the shape of pills with metalized faces, are placed in either a proprietary coaxial chamber or in an open fixture. The scattering parameter (reflection coefficient) is measured using a network analyzer. For the deembedding of the complex permittivity of a sample one needs precise electromagnetic simulations, including detailed models of the chamber or the open fixture. For lower and intermediate frequencies we use a numerical technique for electrostatic analysis, based on the method of moments with Galerkin testing. We create a database that is used afterwards for evaluation of the complex permittivity practically in real time. For higher frequencies, a full electrodynamic model of the chamber is developed with WIPL-D software. For all our deembedding techniques, we have also developed a detailed model of losses in the SMA coaxial connectors, which is essential for a precise evaluation of the imaginary part of the complex permittivity for low-loss dielectrics. We present results of several measurements in order to illustrate the used techniques.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017",
title = "Assessing electrical properties of ceramic samples",
pages = "51-52"
}
Olćan, D., Obradović, N., Filipović, S., Terzić, A., Pavlović, V. B., Kachlik, M., Maca, K.,& Đorđević, A. (2017). Assessing electrical properties of ceramic samples.
Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017Belgrade : Serbian Ceramic Society., 51-52.
Olćan D, Obradović N, Filipović S, Terzić A, Pavlović VB, Kachlik M, Maca K, Đorđević A. Assessing electrical properties of ceramic samples. Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017. 2017;:51-52
Olćan Dragan, Obradović Nina, Filipović Suzana, Terzić Anja, Pavlović Vladimir B., Kachlik Martin, Maca Karel, Đorđević Antonije, "Assessing electrical properties of ceramic samples" (2017):51-52

Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials

Terzić, Anja; Obradović, Nina; Stojanović, Jovica; Pavlović, Vladimir B.; Andrić, Ljubiša; Olćan, Dragan; Đorđević, Antonije

(Elsevier, 2017)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Stojanović, Jovica
AU  - Pavlović, Vladimir B.
AU  - Andrić, Ljubiša
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/2356
AB  - The focus of the study was on providing insights into interconnections between sintering and development of the crystalline microstructure, and consequently variations in dielectric behavior of four steatites fabricated from a low-cost raw material, i.e. talc. The changes, induced by the alternations of the binders (bentonite, kaolin clay) and fluxing agents (BaCO3, feldspar), were monitored in the temperature range 1000° to 1250 °C in which complete densification and re-crystallization of the investigated structures were accomplished. The critical points in the synthesis of steatite materials were assessed by instrumental analyses. Crystallinity changes and mineral phase transition during sintering were monitored by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy accompanied with EDS mapping. The thermal stability was observed on the green mixtures using differential thermal and thermo gravimetric analyses. Electrical measurements recorded variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of the sintering temperature. The investigation highlighted critical design points, as well as the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.
PB  - Elsevier
T2  - Ceramics International
T1  - Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials
SP  - 13264
EP  - 13275
VL  - 43
IS  - 16
DO  - 10.1016/j.ceramint.2017.07.024
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Stojanović, Jovica and Pavlović, Vladimir B. and Andrić, Ljubiša and Olćan, Dragan and Đorđević, Antonije",
year = "2017",
url = "http://dais.sanu.ac.rs/123456789/2356",
abstract = "The focus of the study was on providing insights into interconnections between sintering and development of the crystalline microstructure, and consequently variations in dielectric behavior of four steatites fabricated from a low-cost raw material, i.e. talc. The changes, induced by the alternations of the binders (bentonite, kaolin clay) and fluxing agents (BaCO3, feldspar), were monitored in the temperature range 1000° to 1250 °C in which complete densification and re-crystallization of the investigated structures were accomplished. The critical points in the synthesis of steatite materials were assessed by instrumental analyses. Crystallinity changes and mineral phase transition during sintering were monitored by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy accompanied with EDS mapping. The thermal stability was observed on the green mixtures using differential thermal and thermo gravimetric analyses. Electrical measurements recorded variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of the sintering temperature. The investigation highlighted critical design points, as well as the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials",
pages = "13264-13275",
volume = "43",
number = "16",
doi = "10.1016/j.ceramint.2017.07.024"
}
Terzić, A., Obradović, N., Stojanović, J., Pavlović, V. B., Andrić, L., Olćan, D.,& Đorđević, A. (2017). Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials.
Ceramics InternationalElsevier., 43(16), 13264-13275.
https://doi.org/10.1016/j.ceramint.2017.07.024
Terzić A, Obradović N, Stojanović J, Pavlović VB, Andrić L, Olćan D, Đorđević A. Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials. Ceramics International. 2017;43(16):13264-13275
Terzić Anja, Obradović Nina, Stojanović Jovica, Pavlović Vladimir B., Andrić Ljubiša, Olćan Dragan, Đorđević Antonije, "Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials" 43, no. 16 (2017):13264-13275,
https://doi.org/10.1016/j.ceramint.2017.07.024 .
2
2
2

Electrical properties of magnesium titanate ceramics post-sintered by hot isostatic pressing

Đorđević, Antonije; Olćan, Dragan; Obradović, Nina; Paunović, Vesna; Filipović, Suzana; Pavlović, Vladimir B.

(Belgrade : International Institute for the Science of Sintering, 2017)

TY  - JOUR
AU  - Đorđević, Antonije
AU  - Olćan, Dragan
AU  - Obradović, Nina
AU  - Paunović, Vesna
AU  - Filipović, Suzana
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/2369
AB  - Post-sintering of magnesium titanate ceramics by hot isostatic pressing (HIP) in an oxygen-free atmosphere significantly alters various electrical properties of the product. In particular, the sintered material becomes a semiconductor. The aims of this paper are: to extend our investigations of the electrical properties of this material by expanding the frequency range of measurements, to design interpolation formulas for the frequency dependence of the complex relative permittivity, and to propose HIP-sintered magnesium titanate as a material for thermistors that have a negative-temperature-coefficient resistance (NTCR), as well as for varistors.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Electrical properties of magnesium titanate ceramics post-sintered by hot isostatic pressing
SP  - 373
EP  - 380
VL  - 49
IS  - 4
DO  - 10.2298/SOS1704373D
ER  - 
@article{
author = "Đorđević, Antonije and Olćan, Dragan and Obradović, Nina and Paunović, Vesna and Filipović, Suzana and Pavlović, Vladimir B.",
year = "2017",
url = "http://dais.sanu.ac.rs/123456789/2369",
abstract = "Post-sintering of magnesium titanate ceramics by hot isostatic pressing (HIP) in an oxygen-free atmosphere significantly alters various electrical properties of the product. In particular, the sintered material becomes a semiconductor. The aims of this paper are: to extend our investigations of the electrical properties of this material by expanding the frequency range of measurements, to design interpolation formulas for the frequency dependence of the complex relative permittivity, and to propose HIP-sintered magnesium titanate as a material for thermistors that have a negative-temperature-coefficient resistance (NTCR), as well as for varistors.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Electrical properties of magnesium titanate ceramics post-sintered by hot isostatic pressing",
pages = "373-380",
volume = "49",
number = "4",
doi = "10.2298/SOS1704373D"
}
Đorđević, A., Olćan, D., Obradović, N., Paunović, V., Filipović, S.,& Pavlović, V. B. (2017). Electrical properties of magnesium titanate ceramics post-sintered by hot isostatic pressing.
Science of SinteringBelgrade : International Institute for the Science of Sintering., 49(4), 373-380.
https://doi.org/10.2298/SOS1704373D
Đorđević A, Olćan D, Obradović N, Paunović V, Filipović S, Pavlović VB. Electrical properties of magnesium titanate ceramics post-sintered by hot isostatic pressing. Science of Sintering. 2017;49(4):373-380
Đorđević Antonije, Olćan Dragan, Obradović Nina, Paunović Vesna, Filipović Suzana, Pavlović Vladimir B., "Electrical properties of magnesium titanate ceramics post-sintered by hot isostatic pressing" 49, no. 4 (2017):373-380,
https://doi.org/10.2298/SOS1704373D .
1
4
4

Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique

Obradović, Nina; Đorđević, Nataša; Filipović, Suzana; Kosanović, Darko; Pavlović, Vladimir B.; Olćan, Dragan; Đorđević, Antonije; Kachlik, Martin; Maca, Karel

(Insternational Institute for the Science of Sintering, 2016)

TY  - JOUR
AU  - Obradović, Nina
AU  - Đorđević, Nataša
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/15996
AB  - Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of time of mechanical treatment.
PB  - Insternational Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique
SP  - 157
EP  - 165
VL  - 48
IS  - 2
DO  - 10.2298/SOS1602157O
ER  - 
@article{
author = "Obradović, Nina and Đorđević, Nataša and Filipović, Suzana and Kosanović, Darko and Pavlović, Vladimir B. and Olćan, Dragan and Đorđević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/15996",
abstract = "Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of time of mechanical treatment.",
publisher = "Insternational Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique",
pages = "157-165",
volume = "48",
number = "2",
doi = "10.2298/SOS1602157O"
}
Obradović, N., Đorđević, N., Filipović, S., Kosanović, D., Pavlović, V. B., Olćan, D., Đorđević, A., Kachlik, M.,& Maca, K. (2016). Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique.
Science of SinteringInsternational Institute for the Science of Sintering., 48(2), 157-165.
https://doi.org/10.2298/SOS1602157O
Obradović N, Đorđević N, Filipović S, Kosanović D, Pavlović VB, Olćan D, Đorđević A, Kachlik M, Maca K. Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique. Science of Sintering. 2016;48(2):157-165
Obradović Nina, Đorđević Nataša, Filipović Suzana, Kosanović Darko, Pavlović Vladimir B., Olćan Dragan, Đorđević Antonije, Kachlik Martin, Maca Karel, "Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique" 48, no. 2 (2016):157-165,
https://doi.org/10.2298/SOS1602157O .
6
12
12

Effect of consolidation parameters on structural, microstructural and electrical properties of magnesium titanate ceramics

Filipović, Suzana; Obradović, Nina; Pavlović, Vladimir B.; Mitrić, Miodrag; Đorđević, Antonije; Kachlik, Martin; Maca, Karel

(Elsevier, 2016)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Pavlović, Vladimir B.
AU  - Mitrić, Miodrag
AU  - Đorđević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/2310
AB  - The aim of this study is to explore the influence of the processing route on the structural and physical properties of bulk MgTiO3 ceramics. Commercially available MgO and TiO2 powders were mechanically activated in a planetary ball mill. Green bodies were formed by an isostatic pressure of 300 MPa. The sintering of these samples was done either by the Two-Step Sintering (TSS) approach or by conventional pressureless sintering followed by Hot Isostatic Pressing (post-HIPing). The first set of compacts was sintered by TSS in air at 1300 °C for 30 min and the next step was performed at 1200 °C for 20 h. The density of the obtained samples after the two-step sintering reached almost 90% of the theoretical density (%TD). The second set of compacts was sintered at 1400 °C for 30 min in air. The samples without open porosity were post-sintered by the HIP at 1200 °C for 2 h in an argon atmosphere at a pressure of 200 MPa. The density significantly increased up to 96%TD. The differences between samples prepared by these two techniques were also analyzed by XRD and SEM. The lattice vibration spectra were obtained using Raman spectroscopy and they indicate a high degree of lattice disorder, as well as high values of the oxygen vacancy concentration. Electrical characteristic were established in the frequency range from 10 kHz to 10 GHz. The choice of the processing route had considerable influence on structural and physical properties of MgTiO3 ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - Effect of consolidation parameters on structural, microstructural and electrical properties of magnesium titanate ceramics
SP  - 9887
EP  - 9898
VL  - 42
IS  - 8
DO  - 10.1016/j.ceramint.2016.03.088
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Pavlović, Vladimir B. and Mitrić, Miodrag and Đorđević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/2310",
abstract = "The aim of this study is to explore the influence of the processing route on the structural and physical properties of bulk MgTiO3 ceramics. Commercially available MgO and TiO2 powders were mechanically activated in a planetary ball mill. Green bodies were formed by an isostatic pressure of 300 MPa. The sintering of these samples was done either by the Two-Step Sintering (TSS) approach or by conventional pressureless sintering followed by Hot Isostatic Pressing (post-HIPing). The first set of compacts was sintered by TSS in air at 1300 °C for 30 min and the next step was performed at 1200 °C for 20 h. The density of the obtained samples after the two-step sintering reached almost 90% of the theoretical density (%TD). The second set of compacts was sintered at 1400 °C for 30 min in air. The samples without open porosity were post-sintered by the HIP at 1200 °C for 2 h in an argon atmosphere at a pressure of 200 MPa. The density significantly increased up to 96%TD. The differences between samples prepared by these two techniques were also analyzed by XRD and SEM. The lattice vibration spectra were obtained using Raman spectroscopy and they indicate a high degree of lattice disorder, as well as high values of the oxygen vacancy concentration. Electrical characteristic were established in the frequency range from 10 kHz to 10 GHz. The choice of the processing route had considerable influence on structural and physical properties of MgTiO3 ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effect of consolidation parameters on structural, microstructural and electrical properties of magnesium titanate ceramics",
pages = "9887-9898",
volume = "42",
number = "8",
doi = "10.1016/j.ceramint.2016.03.088"
}
Filipović, S., Obradović, N., Pavlović, V. B., Mitrić, M., Đorđević, A., Kachlik, M.,& Maca, K. (2016). Effect of consolidation parameters on structural, microstructural and electrical properties of magnesium titanate ceramics.
Ceramics InternationalElsevier., 42(8), 9887-9898.
https://doi.org/10.1016/j.ceramint.2016.03.088
Filipović S, Obradović N, Pavlović VB, Mitrić M, Đorđević A, Kachlik M, Maca K. Effect of consolidation parameters on structural, microstructural and electrical properties of magnesium titanate ceramics. Ceramics International. 2016;42(8):9887-9898
Filipović Suzana, Obradović Nina, Pavlović Vladimir B., Mitrić Miodrag, Đorđević Antonije, Kachlik Martin, Maca Karel, "Effect of consolidation parameters on structural, microstructural and electrical properties of magnesium titanate ceramics" 42, no. 8 (2016):9887-9898,
https://doi.org/10.1016/j.ceramint.2016.03.088 .
6
8
9

Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique

Obradović, Nina; Filipović, Suzana; Đorđević, Nataša; Kosanović, Darko; Pavlović, Vladimir B.; Olćan, Dragan; Đorđević, Antonije; Kachlik, Martin; Maca, Karel

(2016)

TY  - JOUR
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/2314
AB  - Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of time of mechanical treatment.
T2  - Science of Sintering
T1  - Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique
SP  - 157
EP  - 165
VL  - 48
IS  - 2
DO  - 10.2298/SOS1602157O
ER  - 
@article{
author = "Obradović, Nina and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Pavlović, Vladimir B. and Olćan, Dragan and Đorđević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/2314",
abstract = "Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of time of mechanical treatment.",
journal = "Science of Sintering",
title = "Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique",
pages = "157-165",
volume = "48",
number = "2",
doi = "10.2298/SOS1602157O"
}
Obradović, N., Filipović, S., Đorđević, N., Kosanović, D., Pavlović, V. B., Olćan, D., Đorđević, A., Kachlik, M.,& Maca, K. (2016). Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique.
Science of Sintering, 48(2), 157-165.
https://doi.org/10.2298/SOS1602157O
Obradović N, Filipović S, Đorđević N, Kosanović D, Pavlović VB, Olćan D, Đorđević A, Kachlik M, Maca K. Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique. Science of Sintering. 2016;48(2):157-165
Obradović Nina, Filipović Suzana, Đorđević Nataša, Kosanović Darko, Pavlović Vladimir B., Olćan Dragan, Đorđević Antonije, Kachlik Martin, Maca Karel, "Microstructural and electrical properties of cordierite-based ceramics obtained after two-step sintering technique" 48, no. 2 (2016):157-165,
https://doi.org/10.2298/SOS1602157O .
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Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics

Obradović, Nina; Filipović, Suzana; Đorđević, Nataša; Kosanović, Darko; Marković, Smilja; Pavlović, Vladimir B.; Olćan, Dragan; Đorđević, Antonije; Kachlik, Martin; Maca, Karel

(Elsevier, 2016)

TY  - JOUR
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Pavlović, Vladimir B.
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/2322
AB  - The mechanical activation can help reduce production costs and modify cordierite-based materials. In this study, the structure and electrical properties of the mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for time periods ranging from 0 to 160 min. Structural investigations were performed on the obtained powders. The effects of activation and a two-step sintering process on the microstructure and crystal structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The thermal stability was analyzed using DTA. Electrical measurements showed variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of the time of mechanical treatment.
PB  - Elsevier
T2  - Ceramics International
T1  - Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics
SP  - 13909
EP  - 13918
VL  - 42
IS  - 12
DO  - 10.1016/j.ceramint.2016.05.201
ER  - 
@article{
author = "Obradović, Nina and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Pavlović, Vladimir B. and Olćan, Dragan and Đorđević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/2322",
abstract = "The mechanical activation can help reduce production costs and modify cordierite-based materials. In this study, the structure and electrical properties of the mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for time periods ranging from 0 to 160 min. Structural investigations were performed on the obtained powders. The effects of activation and a two-step sintering process on the microstructure and crystal structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The thermal stability was analyzed using DTA. Electrical measurements showed variations of the dielectric constant (εr) and loss tangent (tan δ) as a function of the time of mechanical treatment.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics",
pages = "13909-13918",
volume = "42",
number = "12",
doi = "10.1016/j.ceramint.2016.05.201"
}
Obradović, N., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Pavlović, V. B., Olćan, D., Đorđević, A., Kachlik, M.,& Maca, K. (2016). Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics.
Ceramics InternationalElsevier., 42(12), 13909-13918.
https://doi.org/10.1016/j.ceramint.2016.05.201
Obradović N, Filipović S, Đorđević N, Kosanović D, Marković S, Pavlović VB, Olćan D, Đorđević A, Kachlik M, Maca K. Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics. Ceramics International. 2016;42(12):13909-13918
Obradović Nina, Filipović Suzana, Đorđević Nataša, Kosanović Darko, Marković Smilja, Pavlović Vladimir B., Olćan Dragan, Đorđević Antonije, Kachlik Martin, Maca Karel, "Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics" 42, no. 12 (2016):13909-13918,
https://doi.org/10.1016/j.ceramint.2016.05.201 .
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